Free Metal Is Iron(fe), Cobalt(co), Or Nickel(ni) Only Patents (Class 75/242)
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Patent number: 5348806Abstract: A cermet alloy having a structure comprising a hard phase and a bonding phase, said hard phase comprising (1) at least one of MC, MN, and MCN, wherein M is at least one element selected from Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, and W (2) at least one compound selected from (M,Mo)(B,C), M,Mo)(B,N) and (M,Mo)(B,CN) and (3) at least one Mo--Co--B compound; said bonding phase comprising Co. The cermet alloy has superior toughness and hardness, and can be worked by conventional sintering methods. The invention also includes a method for producing the cermet alloy.Type: GrantFiled: September 18, 1992Date of Patent: September 20, 1994Assignee: Hitachi Metals, Ltd.Inventors: Katsuhiko Kojo, Akibumi Negishi, Masayuki Gonda
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Patent number: 5330553Abstract: A sintered titanium-based carbonitride alloy contains hard constituents based on, in addition to Ti, W and/or Mo, one or more of the metals Zr, Hf, V, Nb, Ta or Cr in 5-30% binder phase based on Cobalt and/or nickel. The content of tungsten and/or molybdenum, preferably molybdenum in the binder phase is >1.5 times higher than in the rim and >3.5 times higher than in the core of adjacent hard constituent grains. The alloy is produced by a particular method.Type: GrantFiled: May 22, 1992Date of Patent: July 19, 1994Assignee: Sandvik ABInventors: Gerold Weinl, Rolf G. Oskarsson, Per Gustafsson
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Patent number: 5328500Abstract: A method for producing a metal composite powder, such as a high alloy metal composite powder, which includes pretreating the alloying components prior to milling with a base iron powder. A short milling time is used, yielding a metal composite powder which exhibits good compactability, microstructure, controllable flow, post-sintering homogeneity, and offers a more economical production method.Type: GrantFiled: June 22, 1992Date of Patent: July 12, 1994Inventors: Robert J. Beltz, Joseph D. Dankoff, Melvin L. McClellan
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Patent number: 5306326Abstract: A sintered body of titanium based carbonitride alloy containing hard constituents based on, in addition to titanium, one or more of the metals Zr, Hf, V, Nb, Ta, Cr, No or W in 5-30% binder phase based on Co and/or Ni is disclosed. The body has a binder phase enriched surface zone with a higher binder phase content than in the inner portion of the body in combination with an enrichment of simple hard constituents, i.e., the share of grains with core-rim structure is lower in the surface zone than in the inner of the body.Type: GrantFiled: May 22, 1992Date of Patent: April 26, 1994Assignee: Sandvik ABInventors: Rolf G. Oskarsson, Gerold Weinl
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Patent number: 5294239Abstract: In section bars and shaped bodies made of nickel-base superalloys having a structure consisting of columnar grains, a complete recrystallization cannot be effected unless the heating-up rate is kept below a maximum heating-up rate T.sub.max, which depends on the ratio V of one or more of the metal carbide-forming elements hafnium, niobium, tantalum, titanium and zirconium to one or both of the metal carbide-forming elements tungsten and molybdenum.Type: GrantFiled: May 6, 1991Date of Patent: March 15, 1994Assignee: PM Hochtemperatur-Metall GmbHInventors: Klaus Zoltzer, Klaus Lempenauer, Hellmut Fischmeister
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Patent number: 5288676Abstract: A cemented carbide of the invention contains at least one of cobalt and nickel; calcium, sulfur, aluminum, silicon and phosphorus; balance tungsten carbide; and unavoidable impurities. The content of cobalt or nickel should range from 4 to 35% by weight. The content of each of calcium, sulfur, aluminum and silicon should be no greater than 50 ppm by weight, while the content of phosphorus should be no greater than 20 ppm by weight. The tungsten carbide has an average crystal grain size of 0.2 to 1.5 micrometers. The cemented carbide may further contain 0.1 to 40% by weight of at least one compound which may be carbides of metals in Groups IVa, Va and VIa of the Periodic Table other than tungsten, nitrides of metals in Groups IVa and Va of the Periodic Table and solid solution of at least two of the carbides and nitrides.Type: GrantFiled: December 24, 1992Date of Patent: February 22, 1994Assignee: Mitsubishi Materials CorporationInventors: Fumio Shimada, Tadashi Kainuma
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Patent number: 5281260Abstract: A sintered hard metal compact for use in earth-boring bits comprises 80 to 94% by weight tungsten carbide particles, 5.4 to 18% by weight cobalt particles and 0.6 to 2.0% by weight nickel particles wherein the ratio of cobalt to nickel is approximately 9:1 by weight. These materials are formed according to conventional powder-metallurgy techniques to provide a hard, sintered compact for use in earth-boring bits having superior properties for drilling applications.Type: GrantFiled: February 28, 1992Date of Patent: January 25, 1994Assignee: Baker Hughes IncorporatedInventors: Anil Kumar, Larry P. Pelty
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Patent number: 5273571Abstract: A nonmagnetic, NiWC cemented carbide composition and articles made from the same. The addition of chromium renders the composition nonmagnetic independent of the free carbon level in the composition. The composition is useful as wear resistant parts in electronic instruments and as punches to deep draw aluminum beverage cans.Type: GrantFiled: December 21, 1992Date of Patent: December 28, 1993Assignee: Valenite Inc.Inventors: Prakash K. Mirchandani, Laszlo J. Kastura, John W. Friederichs
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Patent number: 5223020Abstract: The invention relates to a hard-metal body whose hard-metal phase consist of tungsten carbide and whose binder metal phase consists of nickel and chrome.Especially for the enhancement of the corrosion resistance it is proposed that the hard metal contain also TiN in addition to the hard-metal phase, whereby the content of TiN and and binder metal phase amounts to 5 to 25% by mass and is composed by 0.1 to 10% by mass TiN, 5 to 15% by mass chrome, the balance being made up by nickel.Type: GrantFiled: April 24, 1991Date of Patent: June 29, 1993Assignee: Krupp Widia GmbHInventor: Hans Kolaska
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Patent number: 5181953Abstract: A coated cemented carbide alloy, excellent in toughness as well as wear resistance and which is used for cutting tools and wear resistance tools is provided herein. This coated cemented carbide alloy is composed of a cemented carbide substrate consisting of a hard phase of at least one member selected from carbides, nitrides and carbonitrides of Group IVb, Vb and VIb metals of the Periodic Table and a binder phase consisting of at least one member selected from the iron group metals, and a monolayer or multilayer, provided on the substrate consisting of at least one member selected from carbides, nitrides, oxides and borides of Group IVb, Vb and VIb metals of Periodic Table, solid solutions thereof and aluminum oxide, and wherein a binder phase-enriched layer is provided in a space 0.01 mm and 2 mm below the surface of the substrate with A-type and/or B-type pores inside the binder phase-enriched layer.Type: GrantFiled: December 27, 1990Date of Patent: January 26, 1993Assignee: Sumitomo Electric Industries, Ltd.Inventors: Minoru Nakano, Toshio Nomura
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Patent number: 5149595Abstract: A cermet alloy having a structure comprising a hard phase and a bonding phase, said hard phase comprising (1) at least one of MC, MN and MCN, wherein M is at least one element selected from Ti, Zr, Hf, Th, V, Nb, Ta, Pa, Cr, Mo, U and W and (2) at least one W-Co-B compound; said bonding phase comprising Co. The cermet has superior toughness and hardness, and can be worked by conventional sintering methods. The invention also includes a method for producing the cermet.Type: GrantFiled: September 11, 1991Date of Patent: September 22, 1992Assignees: Hitachi Metals Ltd., Hitachi Tool Engineering Ltd.Inventors: Katsuhiko Kojo, Akibumi Negishi, Hisaaki Ida
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Patent number: 5149362Abstract: An Ag-Cu-WC contact forming material for a vacuum interrupter comprising a highly conductive component comprising Ag and Cu and an arc-proof component comprising WC wherein the content of the highly conductive component is such that the total amount of Ag and Cu(Ag+Cu) is from 25% to 65% by weight and the percentage of Ag based on the total amount of Ag and Cu[Ag/(Ag+Cu)] is from 40% to 80% by weight; wherein the content of the arc-proof component is from 35% to 75% by weight; wherein the structure of the highly conductive component comprises a matrix and a discontinuous phase, the discontinuous phase having a thickness or width of no more than 5 micrometers and wherein said arc-proof component comprises a discontinuous grain having a grain size of no more than 1 micrometer.Type: GrantFiled: July 28, 1989Date of Patent: September 22, 1992Assignee: Kabushiki Kaisha ToshibaInventors: Tsutomu Okutomi, Atsushi Yamamoto, Seishi Chiba, Tsuneyo Seki, Mikio Okawa, Mitsutaka Honma, Kiyofumi Otobe, Yoshinari Satoh, Tadaaki Sekiguchi
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Patent number: 5143540Abstract: Substantially dense, void-free ceramic-metal composites are prepared from components characterized by chemical incompatibility and non-wetting behavior. The composites have a final chemistry similar to the starting chemistry and microstructures characterized by ceamic grains similar in size to the starting powder and the presence of metal phase. A method for producing the composites requires forming a homogeneous mixture of ceramic-metal, heating the mixture to a temperature that approximates but is below the temperature at which the metal begins to flow and pressing the mixture at such pressure that compaction and densification of the mixture occurs and an induced temperature spike occurs that exceeds the flowing temperature of the metal such that the mixture is further compacted and densified. The temperature spike and duration thereof remains below that at which significant reaction between metal and ceramic occurs. The method requires pressures of 60-250 kpsi employed at a rate of 5-250 kpsi/second.Type: GrantFiled: September 18, 1990Date of Patent: September 1, 1992Assignee: The Dow Chemical CompanyInventors: Aleksander J. Pyzik, Irving G. Snyder, Jr., Robert R. McDonald, Alexander Pecnenik
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Patent number: 5141571Abstract: A hard surfacing alloy which has a Rockwell C hardness of greater than about 50 and which includes tungsten carbide, chromium carbide and bi-metallic chromium and tungsten carbide crystals which are precipitated in the alloy. Alloys of the present invention in their nominal composition comprise from about 12% to about 20% tungsten; from about 13% to about 30% chromium; an effective amount of carbon for forming carbides with the tungsten and chromium and include effective amounts of fluxes and melting point depressants and the like. The balance of the composition is nickel. The alloys include precipitated carbide crystals of chromium, tungsten and bi-metallic mixtures thereof which are interspersed through the hard surfacing alloy and are metallurgically bonded in the metal matrix of the alloy. The alloys have extremely low porosities and therefore are suitable for glass plunger and other applications where low porosity is essential.Type: GrantFiled: May 7, 1991Date of Patent: August 25, 1992Assignee: Wall Colmonoy CorporationInventor: Samuel C. DuBois
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Patent number: 5141554Abstract: An alloy steel for use in injection-molded sinterings produced by powder metallurgy which comprises by weight, from 0.5 to 3% of Cr and/or Mn, from 0.3 to 1% of C, and balance Fe, is claimed.The alloy steel according to the present invention provides injection-molded sinterings having favorable post workability well-comparable to that of Fe-Ni-C alloys, and further improved in abrasion resistance when hardened and tempered to give a high Vickers hardness of over Hv 700.Type: GrantFiled: June 14, 1991Date of Patent: August 25, 1992Assignee: Sumitomo Metal Mining Co., Ltd.Inventor: Yoshio Kijima
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Patent number: 5122203Abstract: This invention relates to a process for producing a rare earth-containing material capable of being formed into a permanent magnet comprising crushing a rare earth-containing alloy and treating the alloy with a passivating gas at a temperature below the phase transformation temperature of the alloy. This invention further relates to a process for producing a rare earth-containing powder comprising crushing a rare earth-containing alloy in a passivating gas at a temperature from ambient temperature to a temperature below the phase transformation temperature of the material. This invention also relates to a process for producing a rare earth-containing powder comprising crushing a rare earth-containing alloy in water, drying the crushed alloy material at a temperature below the phase transformation temperature of the material, and treating the crushed alloy material with a passivating gas at a temperature from the ambient temperature to a temperature below the phase transformation temperature of the material.Type: GrantFiled: June 8, 1990Date of Patent: June 16, 1992Assignee: SPS Technologies, Inc.Inventor: Yakov Bogatin
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Patent number: 5110349Abstract: A cutting insert of a sintered carbonitride alloy and with a complicated geometry, the insert having improved efficiency. This is obtained by giving the powder non-uniform compaction during pressing of the powder into a press-body so that the ultimate working edges will have a higher relative density than the surrounding, more "supporting" material in the press-body. By these means are often obtained surface defects in the form of cracks because of dissolved strains during the sintering.Type: GrantFiled: November 14, 1990Date of Patent: May 5, 1992Assignee: Sandvik ABInventors: Kenneth Westergren, Gerold Weinl, Rolf Oskarsson
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Patent number: 5108491Abstract: A rolling bearing comprise a bearing ring having inner and outer rings, and rolling elements. At least one of the inner and outer rings and the rolling elements is formed of a sintered alloy steel and has pores and carbides present therein. The largest one of the pores has a diameter equal to or smaller than 3 .mu.m in terms of a diameter assued if the largest pore were converted to a spherical shape. The largest one of the carbides has a diameter equal to or smaller than 12 .mu.m in terms of a diameter assumed if the largest carbide were converted to a spherical shape. The at least one of the inner and outer rings and the rolling elements has hardness higher than 64 and lower than 69 in terms of HRC.Type: GrantFiled: May 29, 1991Date of Patent: April 28, 1992Assignee: Nippon Seiko Kabushiki KaishaInventors: Yoichi Matsumoto, Kousuke Nonaka
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Patent number: 5089047Abstract: A dense cermet article including about 80-95% by volume of a granular hard phase and about 5-20% by volume of a metal phase. The granular hard phase consists essentially of a ceramic material selected from the hard refractory carbides, nitrides, carbonitrides, oxycarbides, oxynitrides, carboxynitrides, and borides of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, boron, and mixtures thereof. The metal phase consists essentially of a combination of nickel and aluminum having a weight ratio of nickel to aluminum of from about 90:10 to about 70:30 and 0-5% by weight of an additive selected from the group consisting of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, cobalt, boron, or carbon, or combinations thereof. In the preferred metal phase, an amount of about 15-80% by volume of the metal phase component exhibits a Ni.sub.3 Al ordered crystal structure.Type: GrantFiled: December 20, 1990Date of Patent: February 18, 1992Assignee: GTE Laboratories IncorporatedInventors: Sergej T. Buljan, Helmut Lingertat, Steven F. Wayne
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Patent number: 5080713Abstract: A material for valve seats comprising a wear resisting sintered ferro alloy formed by dispersing particles of a high speed steel in a matrix in which hard alloy particles are dispersed. Steps for forming include mixing particles of a matrix material, carbide material and a hard alloy, and blending the mixture with high speed steel particles, pressurizing and compacting the mixture after blending, then sintering them at 1000.degree. to 1200.degree. C. In the preferred method, at least one element of Fe, C, Ni, Co, Si or Mn is included as the matrix material, and at least one element of Fe, Cr, Mo or V as the carbide material and at least one element of Fe, Cr, Mo, Co, C or W as the hard alloy are prepared. Furthermore, the ferro alloy preferably includes the following amounts of the above mentioned elements, 0.5 to 2.0 wt % of C, 1 to 25 wt % of one or more of Cr, Mo, V, or W and 1 to 15 wt % of one or more of Co, Ni, Mn, or Si.Type: GrantFiled: April 14, 1989Date of Patent: January 14, 1992Assignees: Kabushiki Kaisha Riken, Nissan Motor Company, LimitedInventors: Akiyoshi Ishibashi, Kazutoshi Takemura, Makoto Abe, Akira Fujiki, Kimitsugu Kiso, Takaaki Ito
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Patent number: 5068148Abstract: A tool member includes a tungsten carbide based cemented carbide substrate and a diamond coating deposited on the substrate. The substrate has two diffraction peaks K.alpha..sub.1 and K.alpha..sub.2 indexed by index of pane (211) for tungsten carbide in X-ray diffraction. The peaks satisfy the relationship of 1.sub.1 /1.sub.2 .ltoreq.35, where 1.sub.1 and 1.sub.2 are heights of the peaks K.alpha..sub.1 and K.alpha..sub.2 measured from a base of a trough between the two diffraction peaks. For manufacturing the tool member, a green compact is first sintered to provide a tungsten carbide based cemented carbide substrate. Subsequently the substrate is ground and subsequently heat-treated at a temperature between 1000.degree. C. and 1600.degree. C. in a vacuum or in a non-oxidizing atmosphere. Thereafter, a diamond coating is formed on the substrate by vapor-deposition method.Type: GrantFiled: December 21, 1989Date of Patent: November 26, 1991Assignee: Mitsubishi Metal CorporationInventors: Kei Nakahara, Keiichi Sakurai, Toshihiko Okamura, Hironori Yoshimura, Hiroyuki Eto, Noribumi Kikuchi
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Patent number: 5053074Abstract: A dense cermet article including about 80-90% by volume of a granular hard phase and about 5-20% by volume of a metal phase. The hard phase is a carbide, nitride, carbonitride, oxycarbide, oxynitride, or carboxynitride of a cubic solid solution selected from W-Ti, W-Hf, W-Nb, W-Ta, Zr-Ti, Hf-Ti, Hf-Zr, V-Ti, Nb-Ti, Ta-Ti, or Mo-Ti. The metal phase consists essentially of a combination of nickel and aluminum having a ratio of nickel to aluminum of from about 90:10 to about 70:30 by weight, and 0-5% by weight of an additive selected from titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, cobalt, boron, and/or carbon. The preferred hard phase is a cubic solid solution of tungsten and titanium. In the preferred metal phase, an amount of about 15-80% by volume of the metal phase component exhibits a Ni.sub.3 Al ordered crystal structure. The article may be produced by presintering the hard phase - metal phase component mixture in a vacuum or inert atmosphere at about 1475.Type: GrantFiled: December 20, 1990Date of Patent: October 1, 1991Assignee: GTE Laboratories IncorporatedInventors: Sergej T. Buljan, Helmut Lingertat, Steven F. Wayne
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Patent number: 5051126Abstract: A cermet contains 70 to 95 volume percentage of a hard dispersed phase and 30 to 5 volume percentage of a binder phase comprising one or more metals in group VIII (the iron group), wherein the hard dispersed phase contains as its components transitional metals in group IVb, transitional metals in group Vb, W alone of transitional metals in group VIb, C, and N, and consists of two structurally different types of particles. One type of the particles are single phase particles constituting 5% to 50% of the hard dispersed phase, whereas the other type of the particles are dual phase particles constituting 95% to 5% of the same. The cermet is for use in tools such as coating tools, spike pins, hobs, reamers, screw drivers, and so forth.Type: GrantFiled: January 12, 1990Date of Patent: September 24, 1991Assignee: NGK Spark Plug Co., Ltd.Inventors: Hajime Yasui, Junichiro Suzuki
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Patent number: 5041261Abstract: A method for manufacturing a dense cermet article including about 80-95% by volume of a granular hard phase and about 5-20% by volume of a metal binder phase. The hard phase is (a) the hard refractory carbides, nitrides, carbonitrides, oxycarbides, oxynitrides, carboxynitrides, borides, and mixtures thereof of the elements selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, and B, or (b) the hard refractory carbides, nitrides, carbonitrides, oxycarbides, oxynitrides, and carboxynitrides, and mixtures thereof of a cubic solid solution of Zr--Ti, Hf--Ti, Hf--Zr, V--Ti, Nb--Ti, Ta--Ti, Mo--Ti, W--Ti, W--Hf, W--Nb, or W--Ta. The binder phase is a combination of Ni and Al having a Ni:Al weight ratio of from about 85:15 to about 88:12, and 0-5% by weight of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Co, B, and/or C. The method involves presintering the hard phase/binder phase mixture in a vacuum or inert atmosphere at about 1475.degree.-1675.degree. C., then HIPing at about 1575.degree.-1675.degree. C.Type: GrantFiled: December 21, 1990Date of Patent: August 20, 1991Assignee: GTE Laboratories IncorporatedInventors: Sergej T. Buljan, Helmut Lingertat, Steven F. Wayne
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Patent number: 5034282Abstract: Process for the powder-metallurgical production of work pieces, particularly tools, containing high-melting point carbides and/or carbonitrides homogeneously distributed in a matrix, in which an amount of elements of the IVa and Va groups, or secondary groups, of the periodic table is adjusted to at least 3 weight percent of the alloy, a low carbon and/or nitrogen concentration is established, and primary precipitates are prevented; and a desired carbon and/or nitrogen content is created by atomization of the melt into powder vaporizing medium.Type: GrantFiled: March 5, 1990Date of Patent: July 23, 1991Assignee: Boehler Gesellschaft m.b.H.Inventors: Bruno Hribernik, Gerhard Hackl
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Patent number: 4985070Abstract: There are disclosed a high strength nitrogen-containing cermet which comprises 7 to 20% by weight of a binder phase composed mainly of Co and/or Ni, with the balance being a hard phase composed mainly of TiC, TiN and/or Ti(C,N) and inevitable impurities, wherein the hard phase comprises 35 to 59% by weight of Ti, 9 to 29% by weight of W, 0.4 to 3.5% by weight of Mo, 4 to 24% by weight of at least one of Ta, Nb, V and Zr, 5.5 to 9.5% by weight of N and 4.5 to 12% by weight of C; and a process for preparing the same which comprises via the formulating, mixing, drying, molding and sintering steps of Co and/or Ni powder, at least one powder of TiC, Ti(C,N) and TiN, WC powder, Mo and/or Mo.sub.2 C, and at least one powder of carbides of Ta, Nb, V and Zr, wherein the sintering step is carried out by elevating the temperature up to 1350.degree. C. in vacuum, with the nitrogen atmosphere being made 1 torr at 1350.degree. C.Type: GrantFiled: July 21, 1989Date of Patent: January 15, 1991Assignee: Toshiba Tungaloy Co., Ltd.Inventors: Kozo Kitamura, Takeshi Saitoh, Mitsuo Ueki, Keiichi Kobori
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Patent number: 4983212Abstract: Disclosed are a cermet alloy having excellent wear resistance and strength at elevated temperatures, and a composite mechanical part containing a strong layer of any such cermet alloy formed on the outer or inner surface of an alloy base.The materials which are used for making rolls, dies, punches, etc. are required to have excellent toughness, impact resistance, high-temperature strength and wear resistances. The conventional ultrahard WC--Co alloys are, however, unsatisfactory in high-temperature strength, through they have a satisfactorily high level of wear resistance. The conventional cermet alloys are low in toughness and impact strength, though they have high oxidation resistance. There has not been availabe any alloy that satisfies all of the requirements as herein-above stated.Type: GrantFiled: June 23, 1989Date of Patent: January 8, 1991Assignee: Hitachi Metals, Ltd.Inventors: Yuusuke Iyori, Hidetoshi Yokoo
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Patent number: 4977710Abstract: The metal bonded diamond wheel of the invention has a sintered body of a mixture of a diamond powder and a bonding metal powder. The particles of the bonding metal powder or, preferably, particles of both of the diamond powder and the bonding metal powder are provided, prior to powder metallurgical sintering, with a coating layer of iron, cobalt or nickel, in a thickness of 0.5 to 15 .mu.m. When sintered under adequate conditions, the sintered body has pores in a porosity of 10 to 25% and exhibits greatly improved grinding performance relative to the durability in grinding works and sharpness of grinding with a decreased resistance of grinding.Type: GrantFiled: February 1, 1989Date of Patent: December 18, 1990Assignee: Asahi Diamond Industrial Co., Ltd.Inventor: Kouji Une
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Patent number: 4973356Abstract: The present invention relates to a method of preparing an alloy for use as a cutting tool material comprising hard principles and binder phase by which a uniform distribution of the hard principles in the binder phase is obtained, and the resulting product.Type: GrantFiled: October 23, 1989Date of Patent: November 27, 1990Assignee: Sandvik ABInventors: Peder von Holst, Hakan Morberg, Rolf Oskarsson
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Patent number: 4961778Abstract: Substantially dense, void-free ceramic-metal composites are prepared from components characterized by chemical incompatibility and non-wetting behavior. The composites have a final chemistry similar to the starting chemistry and microstructures characterized by ceramic grains similar in size to the starting powder and the presence of metal phase. A method for producing the composites requires forming a homogeneous mixture of ceramic-metal, heating the mixture to a temperature that approximates but is below the temperature at which the metal begins to flow and presssing the mixture at such pressure that compaction and densification of the mixture occurs and an induced temperature spike occurs that exceeds the flowing temperature of the metal such that the mixture is further compacted and densified. The temperature spike and duration thereof remains below that at which significant reaction between metal and ceramic occurs. The method requires pressure of 60-250 kpsi employed at a rate of 5-250 kpsi/second.Type: GrantFiled: January 13, 1988Date of Patent: October 9, 1990Assignee: The Dow Chemical CompanyInventors: Aleksander J. Pyzik, Irving G. Snyder, Jr., Alexander Pechenik, Robert R. McDonald
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Patent number: 4950328Abstract: An end mill formed of a tungsten carbide-base sintered hard alloy comprising a binder phase including a Co-base alloy, and a hard disperse phase consisting essentially of WC in proportions of:binder phase: 6-23 wt. %, andhard disperse phase: 77-94 wt %,the binder phase having a composition of:Cr: 1-15 wt. %,W: not more than 5 wt. %, andthe balance of Co and inevitable impurities, the hard disperse phase having a mean grain size of 0.5-2 .mu.m.Type: GrantFiled: July 6, 1989Date of Patent: August 21, 1990Assignee: Mitsubishi Metal CorporationInventors: Niro Odani, Katsuhisa Yamamoto, Hitoshi Mayumi
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Patent number: 4948425Abstract: New ceramics have excellent mechanical properties such as high density, strength, hardness and toughness. The new ceramics are prepared by sintering a mixture prepared by adding 1 to 90 percent by weight of chromium carbide to titanium carbo-nitride together with some elements selected from the group of transition metals of groups IV, V, VI and VII, ferrous metals and semi-metals. For some types of new ceramics, boron carbide is added, too.Type: GrantFiled: April 6, 1989Date of Patent: August 14, 1990Assignee: Agency of Industrial Science and TechnologyInventors: Tadahiko Watanabe, Tsuyoshi Doutsu, Osamu Yagishita, Hideki Yamamoto, Yukio Kai
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Patent number: 4944800Abstract: A sintered hard metal body having improved heat resistance and higher cutting performance is produced by a process including mixing together at least one hard substance, at least one binder material, and at least one of at least one complex carbide and at least one complex nitride to form a starting mixture each constituent of which is in powdered form. The at least one hard substance is selected from the group consisting of carbides, nitrides, and carbonitrides of transition metals of Groups IVB, VB and VIB of the Periodic Table of Elements, is present as at least one of a carbide, a mixed carbide, a nitride, a mixed nitride, a carbonitride, and a mixed carbonitride, and has a cubic crystal form. The at least one binder metal is selected from the group including iron, nickel and cobalt.Type: GrantFiled: March 2, 1989Date of Patent: July 31, 1990Assignee: Krupp Widia GmbHInventors: Hans Kolaska, Peter Ettmayer
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Patent number: 4925490Abstract: A mechanical seal is, at a sliding surface and at its vicinity, formed of a pore-dispersed cemented carbide, so that the lubricating characteristics can be improved and the strength maintained by strictly stipulating the magnitude, shape, and volumetric ratio of the pores, such that pores are contained in an amount of 0.5 to 20 volume %, formed in at least one shape selected from the group of a substantially spherical shape and a substantially cylindrical shape, the pores in the substantially spherical shape having an average diameter of 3 to 20 .mu.m, the pores in the substantially cylindrical shape having an average diameter of 3 to 20 .mu.m and an average length in the range from the average diameter up to 300 .mu.m, and that the pores are prevented from linking to each other to give a length greater than 2 mm.Type: GrantFiled: December 15, 1988Date of Patent: May 15, 1990Assignees: Tanken Seiko Kabushiki Kaisha, Nihon Tungsten Kabushiki KaishaInventors: Yataro Nagai, Mitsuyoshi Matsushita, Osamu Ishibashi, Kiyoshi Terasaki, Kei Tokumoto
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Patent number: 4923511Abstract: Disclosed is a hardfacing powder to be deposited by plasma-transferred-arc welding on a substrate so as to provide a facing of super-hard material that can be utilized as a wear resistant surface. Particular examples of use include mining, agricultural, construction, railroad and plastic extrusion molding equipment.The hardfacing powder of the present invention includes a plurality of different types of tungsten carbide, particularly W.sub.2 C and WC-Co, within a matrix alloy of carbon 0.017-0.52% by weight, silicon 4.3-4.7% by weight, boron 2.7-3.3% by weight, iron 0.27-0.40% by weight and the balance nickel. The total content of tungsten carbide is at least 50% of the total powder by weight.The result is a facing that is improved in compression as well as shear impact resistance that lasts longer in use and has a lower manufacturing cost than conventional hardened metals.Type: GrantFiled: June 29, 1989Date of Patent: May 8, 1990Assignee: W S Alloys, Inc.Inventors: James A. Krizan, Richard S. Szereto
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Patent number: 4915734Abstract: The present invention relates to a cemented carbonitride alloy in which the toughness has been improved by the incorporation in the structure of whiskers of nitrides, carbides and/or carbonitrides of titanium, zirconium and/or hafnium.Type: GrantFiled: April 26, 1988Date of Patent: April 10, 1990Assignee: Sandvik ABInventors: Nils G. L. Brandt, Zeljka D. Senesan
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Patent number: 4913877Abstract: A cemented carbide cutting tool substrate has enhanced surface toughness due to binder enrichment and depletion of aluminum nitride near the peripheral surface.Type: GrantFiled: January 3, 1989Date of Patent: April 3, 1990Assignee: GTE Valenite CorporationInventor: Warren C. Yohe
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Patent number: 4904445Abstract: A tough cermet made from 20-92 weight % of TiC and/or TiCN, 5-50 weight % of WC and 3-30 weight % of an iron-gorup metal. This tough cermet has a three phase grain microstructure and is made is mixing titanium carbonitride powder and up to 70 weight % of the total amount of the tungsten carbide fine powder. The resulting mixture is melted to form a solid solution, pulverized, mixed with the remaining amount of tungsten carbide fine powder, and sintered at temperatures of 1325.degree.-1650.degree. C.Type: GrantFiled: March 23, 1988Date of Patent: February 27, 1990Assignees: Hitachi Metals, Ltd., Hitachi Carbide Tools, Inc.Inventors: Yusuke Iyori, Hisaaki Ida
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Patent number: 4886637Abstract: A presinter treatment is provided to reduce oxygen contamination prior to sintering a predominantly iron powder compact comprising carbon powder and a liquating diffusible boron source, such as nickel boride powder optionally in combination with iron boride powder. A preferred treatment is carried out at a temperature effective to dissociate iron oxide within the compact but not to initiate a liquid phase by said boron source and further is carried out in a vacuum to evacuate oxygen released thereby from compact pores prior to sintering. The presinter treatment enhances carbon and boron diffusion into the iron during sintering. In a preferred embodiment, the fraction of borocementite particles formed by diffused carbon and boron in the sintered iron structure is increased by the presinter treatment of this invention.Type: GrantFiled: April 17, 1989Date of Patent: December 12, 1989Assignee: General Motors CorporationInventors: William F. Jandeska, Jr., Vadim Rezhets, Carlo Ligotti
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Patent number: 4885132Abstract: The present invention relates to an alloy for cutting tools comprising 75-97 % by weight of a hard carbonitride component and 3-25 % by weight of a binder metal, the hard component comprising titanium as the main metallic component besides tungsten, molybdenum, tantalum and optionally vanadium and as non metallic components carbon and nitrogen. The binder metal is selected from the group consisting of iron, cobalt and nickel.The plastic deformation resistance of the alloy has been improved by adding tantalum as a mixed carbide (Ti,Ta)C possibly also including Nb.Type: GrantFiled: May 3, 1989Date of Patent: December 5, 1989Assignee: Sandvik ABInventors: Nils G. L. Brandt, Ake B. Byhlin
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Patent number: 4885030Abstract: Methods are disclosed of making and of using a high density high strength titanium diboride comprising material. The method of making comprises (a) compacting a mixture of titanium diboride, 5-20% by weight of a metal group binder, and up to 1% oxygen and up to 2% graphite, the mixture having a maximum particle size of 5 microns, and (b) sintering the compact to substantially full density. The TiB.sub.2 may be replaced by up to 10% TiC. The method of use is as a cutting tool at relatively high speeds against aluminum based materials.Type: GrantFiled: July 15, 1989Date of Patent: December 5, 1989Assignee: Ford Motor CompanyInventors: David Moskowitz, Charles W. Phillips
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Patent number: 4844738Abstract: A carbide-dispersed type Fe-base sintered alloy which has excellent wear resistance and consists essentially of: 4-6.5% by weight C; 10-40% by weight Cr; 2-25% by weight Mo; 0.1-5% by weight at least one element selected from the group consisting of Ti, Zr, Hf, V, Nb, and Ta; and the balance of Fe and inevitable impurities. If required, the alloy may further contain 0.1-15% by weight at least one element selected from the group consisting of Co and Ni, and/or 0.1-10% by weight W. The alloy has a structure wherein carbides are dispersed throughout the matrix in an amount of at least 71% by volume, and the alloy has at least 97% theoretical density ratio.Type: GrantFiled: October 16, 1987Date of Patent: July 4, 1989Assignee: Mitsubishi Kinzoku Kabushiki KaishaInventors: Teruyoshi Tanase, Hatiro Matsunaga
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Patent number: 4843039Abstract: The present invention relates to a sintered body for chip forming machining containing at least one hard constituent comprising a carbide, nitride and/or carbonitride of a metal of group IVB, VB or VIB in the periodical system and a binder metal based upon Co, No and/or Fe, in which the body comprises a core containing eta-phase or an intermediate phase, substantially free of carbon and/or nitrogen surrounded by a hard constituent- and binder phase-containing surface zone, free of said eta-phase or intermediate phase.Type: GrantFiled: May 12, 1987Date of Patent: June 27, 1989Assignee: Santrade LimitedInventors: Leif A. E. Akesson, Marian Mikus
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Patent number: 4828584Abstract: A tungsten carbide ceramic material which cuts titanium alloys four to five times faster than cemented carbide, ceramic-coated cemented carbides, or state-of-the-art ceramic cutting tools can be densified with or without applied pressure at temperatures below 1700.degree. C. Grain growth inhibitors or sintering aids can be added to control grain size in the final product. The polycrystalline tungsten carbode ceramic can be formed into wear components having improved performance in comparison to cemented tungsten carbides in a variety of drilling, cutting, milling, and other wear applications.Type: GrantFiled: January 9, 1986Date of Patent: May 9, 1989Assignee: Ceramatec, Inc.Inventor: Raymond A. Cutler
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Patent number: 4820482Abstract: The present invention relates to a cemented carbide body, preferably for rock drilling, mineral cutting and wear parts, in which the content of binder phase in the surface is lower and in the center higher than the nominal content. In the center there is a zone having a uniform content of binder phase. The WC grain size is uniform throughout the body.Type: GrantFiled: May 5, 1987Date of Patent: April 11, 1989Assignee: Santrade LimitedInventors: Udo K. R. Fischer, Erik T. Hartzell, Jan G. H. Akerman
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Patent number: 4743425Abstract: A method of producing ferrous sintered alloys comprises the steps of preparing mixed alloy powder containing Fe-P-C eutectic alloy powder which includes phosphorus within the range of 2.0% to 3.0% by weight, carbon not more than 4.0% by weight and one of molybdenum within the range of 8.0% to 11.0% by weight and boron within the range of 0.5% to 3.0% by weight, graphite, and ferroalloy powder containing chromium within the range of 11% to 14% by weight; causing the mixed alloy powder to be subjected to compression molding to have a green compact; and sintering the green compact to have a ferrous sintered alloy containing compound carbides in a matrix structure thereof. The graphite is so selected that the sum total of the graphite and the carbon included in the Fe-P-C eutectic alloy powder constitutes a part within the range of 5% to 8% by weight of the sum total of the graphite and the Fe-P-C eutectic alloy powder.Type: GrantFiled: September 3, 1987Date of Patent: May 10, 1988Assignees: Mazda Motor Corporation, Kawasaki Steel Corp.Inventors: Shigemi Ohsaki, Sumio Kamino, Minoru Nitta
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Patent number: 4731116Abstract: Sputter targets and a process for producing sputter targets are provided, comprised of carbides and/or nitrides and/or borides of refractory metals. In a first step, a dense composite body is produced comprised of one or more carbides and/or nitrides and/or borides of the metals of Groups IV A-VI A of the periodic table and a metallic binding agent comprised of one or more metals of the iron group of the periodic table. This composite body in the form of a shaped blank is machined, if necessary, and the binding agent is removed by chemical or electrochemical treatment. The sputter target as so produced has excellent mechanical strength and high thermal shock resistance. Levels of contaminating elements and the residual metallic binding agent are extremely low, meeting the requirements typically placed on sputter targets.Type: GrantFiled: December 18, 1986Date of Patent: March 15, 1988Assignee: Schwarzkopf Development CorporationInventor: Erich Kny
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Patent number: 4723999Abstract: A method of powder metallurgically manufacturing an object is disclosed, whereinplacing a first powder (4) selected from the group consisting of a metal powder, a mixture of metal powders, a metal alloy powder, a metal alloy mixture, a mixture of metal powder or metal alloy powder and fibres, particulate ceramic materials, and or other particulate material, and mixtures thereof, in an open mould (1),embedding the mould filled with first powder in a powdered pressure medium (8) made of a material which has a melting point less than the melting point of said first powder or less than the melting point of a component in said first powder which has the lowest melting point, said pressure medium essentially not evaporating at the consolidation temperature of said first powder,melting and pressure medium,raising the temperature of the first powder to a temperature between the liquidus and solidus temperatures of the metal or alloy from which the first powder is manufactured, or, if the first powder is a mixture ofType: GrantFiled: March 20, 1987Date of Patent: February 9, 1988Assignee: Uddeholm Tooling AktiebolagInventor: Per Hasselstrom
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Patent number: 4722405Abstract: A composite sintered rock bit insert for use in a rolling cutter is fabricated from two tungsten carbide components. The first component is formed of a tungsten carbide composite that is less wear resistant, but tougher, than the second component. The two components are joined at a parting plane which extends to an earth-engaging surface of the insert. The insert is mounted on a rolling cutter such that the component having the lower wear resistant properties is on the leading face of the insert. With this combination, the wear pattern of the insert maintains a crest-like configuration at its rock engaging surface.Type: GrantFiled: October 1, 1986Date of Patent: February 2, 1988Assignee: Dresser Industries, Inc.Inventor: James W. Langford, Jr.
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Patent number: RE34180Abstract: Cemented carbide substrates having substantially A or B type porosity and a binder enriched layer near its surface are described. A refractory oxide, nitride, boride, and/or carbide coating is deposited on the binder enriched surface of the substrate. Binder enrichment is achieved by incorporating Group IVB or VB transition elements. These elements can be added as the metal, the metal hydride, nitride or carbonitride.Type: GrantFiled: September 9, 1988Date of Patent: February 16, 1993Assignee: Kennametal Inc.Inventors: Bela J. Nemeth, deceased, George P. Grab