Abstract: The invention relates to a synthetic slag forming briquette encased in an aluminum shell. The briquette may include a deoxidizing agent, calcium oxide, calcium fluoride, calcium aluminate, magnesia, or dolomitic lime, or combinations thereof. The deoxidizing agent may include calcium carbide, powdered aluminum or magnesium, or combinations thereof. The aluminum shell may be formed from molten aluminum, or aluminum sheet or foil.

Abstract: The present invention relates to a desulfurizing agent of improved oxidation resistance, ignition resistance and productivity, and a method for manufacturing the desulfurizing agent. The desulfurizing agent may include a plurality of magnesium-aluminum alloy grains with grain boundaries, and a compound of one selected from consisting of magnesium and aluminum and one selected from consisting of alkaline metal and alkaline earth metal, the compound exists in the grain boundaries and is not inside but outside of the magnesium-aluminum alloy grains.

Abstract: Disclosed is a radiation shielding member having improved radiation absorption performance, including 80.0˜99.0 wt % of a polymer matrix or metal matrix and 1.0˜20.0 wt % of a radiation shielding material in the form of nano-particles having a size of 10˜900 nm as a result of pulverization, wherein the radiation shielding material is homogeneously dispersed in the matrix through powder mixing or melt mixing after treatment with a surfactant which is the same material as the matrix or which has high affinity for the matrix. A preparation method thereof is also provided. This radiation shielding member including the nano-particles as the shielding material further increases the collision probability of the shielding material with radiation, compared to conventional shielding members including micro-particles, thus reducing the mean free path of radiation in the shielding member, thereby exhibiting superior radiation shielding effects.

Abstract: A high-temperature, heat-resistant fill material is disclosed. The high-temperature, heat-resistant fill material includes an alumina refractory waste material having one or more of a used alumina-magnesium-carbon material, a used high-alumina material and a used fused-grain alumina material is disclosed. A method for method for manufacturing a material is also disclosed.

Abstract: Embodiments disclosed herein provide hydrocarbon additives and methods of making and using the same. The additives are suitable for use in conjunction with gasifiers, furnaces, or other high-temperature vessels. The additives may be part of an input stream to a reaction vessel of a hydrocarbon gasifier. The additives may include materials that at least partially reduce the infiltration of slag into the refractory material.

Abstract: A method and composition for removing sulfur from molten ferrous material, particularly molten iron. The desulfurization agent includes reclaimed magnesium scrap, a gas-producing compound and a calcium compound.

Abstract: A technique for producing iron utilizes agglomerations, such as briquettes or tablets, or powders, that include a sulfur-containing material such as iron sulfide, and and oxygen containing material such as iron oxide. The agglomerations or powders are substantially free of chemical binders and utilize iron and aluminum metal powders and pressure for compaction on either roll presses or tablet machines. Addition of metal powders provides rapid dissolution of the alloy and improved heat transfer. Iron sulfide agglomerations also provide consistent and improved sulfur recoveries compared to granulated iron sulfide additions with little to no sulfur odor.

Abstract: An aluminothermic reduction mixture includes aluminum powder and iron oxide formed of ferric oxide (Fe2O3) particles with a special shape and other constituent parts.

Abstract: A technique for producing compacted graphite iron utilizes agglomerations, such as briquettes or tablets that include a sulfur-containing material such as iron sulfide. The agglomerations are free of chemical binders and utilize iron and aluminum metal powders and pressure for compaction on either roll presses or tablet machines. Addition of metal powders provides rapid dissolution of the alloy and improved heat transfer. Iron sulfide agglomerations also provide consistent and improved sulfur recoveries compared to granulated iron sulfide additions with little to no sulfur odor.

Abstract: A method and composition for removing sulfur from molten ferrous material, particularly molten iron. The desulfurization agent includes reclaimed magnesium scrap, a gas-producing compound and a calcium compound.

Abstract: Deoxidizing compositions and two-stage methods for deoxidizing molten steel produce purer steel products, at lower cost, than traditional aluminum and silicon-based deoxidation technologies. A first deoxidizing composition is free from elemental aluminum and reduces oxygen content primarily by the conversion of carbon to carbon monoxide, along with the conversion of silicon to silica. A subsequently-added second deoxidizing composition lowers the oxygen content to a highly desirable level, with the production of substantially less alumina impurities than the prior art technologies.

Abstract: The invention concerns a crack-free insulating refractory material made from a composition comprising 20-80% by weight of a ceramic matrix, 5-40% by weight of insulating microspheres, 0.5-15% by weight of one more binders, 5-20% by weight of a metal or a metal alloy able to melt during the preheating or the first minute of use and 0-25% by weight of water. The ceramic matrix is preferably comprised of vitreous and non-vitreous grains.

Abstract: A method and composition for removing sulfur from molten ferrous material, particularly molten pig iron. The desulfurization agent includes a magnesium particle coated with a heat absorbing compound. The heat absorbing compound absorbs heat around the magnesium particle to reduce the rate the magnesium particle vaporizes in the molten iron. The particle size of the magnesium particle is at least about twice the particle size of the heat absorbing compound. A bonding agent can be used to bond the particles of the heat absorbing compound to the particle of magnesium.

Abstract: A particulate carrier material for use with particulate passivated magnesium for injection into molten iron to desulfurize the iron, improve characteristics of the slag and increase iron yield. Material flow of a transport gas and the carrier material is established in a lance prior to inserting the lance into a ladle-contained molten iron, then following insertion the passivated magnesium is added to the material flow. A second embodiment of the invention for iron desulfurization, blends the carrier material and passivated magnesium into a single desulfurization agent. In both embodiments the particulate magnesium is 14-20 mesh with the remaining particulate material being about 200 mesh. The composition of the carrier material is 54-74% calcium oxide, 19-32% aluminum oxide, no more than 4% magnesium oxide, no more than 10% calcium fluoride, no more than 2.5% silicon dioxide, no more than 1.0% iron oxide, no more than 0.025% phosphorus pentoxide, no more than 0.025% titanium dioxide, no more than 0.

Abstract: A treatment agent and method to introduce magnesium into ferrous material. The treatment agent includes a mixture of high melting temperature particles and magnesium particles. The content of high melting temperature particles in the particle mixture is present in an effective amount to inhibit the complete conversion of the magnesium particles into molten magnesium prior to the magnesium particles entering the ferrous material. The method describes the efficient treatment of molten ferrous material with these particles.

Abstract: A method and composition for removing sulfur from molten ferrous material, particularly molten pig iron. The desulfurization agent includes a magnesium particle coated with a heat absorbing compound. The heat absorbing compound absorbs heat around the magnesium particle to reduce the rate the magnesium particle vaporizes in the molten iron. The particle size of the magnesium particle is at least about twice the particle size of the heat absorbing compound. A bonding agent can be used to bond the particles of the heat absorbing compound to the particle of magnesium.

Abstract: The invention relates to a process to minimize metallic aluminum fines loss to parasitic reactions during their introduction into the tap stream of molten steel from Basic Oxygen Furnaces or Electric Arc Furnaces in the ladle, or at the secondary steelmaking vessel, by premixing oxide-free steel or iron fines, prior to briquetting, increasing the apparent density of the aluminum-containing briquette thereby decreasing its flotation into the highly oxidized slag and minimizing the aluminum losses and increasing predictability in the molten steel properties.

Abstract: The invention provides a new and improved process and exothermic reaction mixture for producing molten weld metal. The molten weld metal is used in joining one metallic piece with at least one other metallic piece. The process and exothermic reaction mixture have distinct advantages over the prior art. These advantages include a higher filler metal yield, an increased tensile strength, and a higher quality corrosion resistant weld. These advantages are accomplished by a process wherein a reactant mixture is provided which has a reducing agent, a metallic compound, and at least two filler metals that at least in part do not chemically react with the metallic compound, one of which is aluminum. The metallic compound subsequently forms, with the reducing agent, having a high heat of formation which provides an exothermic reaction with sufficient heat to melt the filler metals.

Abstract: An article that comprises a fine-grain, homogeneous microstructure is essentially oxide- and sulfide-free and segregation defect free. The article is produced by a process that comprises forming a source of clean refined metal that has oxides and sulfides refined out by electroslag refining; and forming the article by nucleated casting. The invention also sets forth the article made by a system for implementing the clean metal nucleated casting process.

Abstract: Compositions suitable for use as an inoculant for cast iron. The composition includes granules of intermetallic alloys selected from Al4Sr, Al2Sr, and AlSr. The composition consists essentially of 40 to 81 percent strontium by weight.

Abstract: Briquettes or tablets to be added to an aluminium melt, are made up by the combination of an agglutinated powder which include, at least, an aluminium powder, a powder of one or more metals or alloys including those to be added, and a wax-type organic compound, all in adequate proportions. This combination allows the increase of the dissolution velocity of the added metals, the recoveries of the added metal, a better stirring of the melting aluminium, and the reduction of impurities and of accumulated metal in the bottom of the furnace.

Abstract: An additive for use in producing spheroidal graphite cast iron of the present invention contains a fine particle of magnesium oxide having a purity of 90 weight % or more and at least one selected from the group consisting of a graphite-spheroidizing material, an inoculant and a graphite-spheroidizing inoculant. The fine particle of highly pure magnesium oxide increases the number of nuclei in a melt, and as a result thereof, increases the graphite spheroid count of a spheroidal graphite cast iron being produced. Another additive for use in producing spheroidal graphite cast iron of the present invention contains at least one selected from the group consisting of a graphite-spheroidizing material, an inoculant and a graphite-spheroidizing inoculant, and an oxide of a metal which has, at a temperature of a melt at a time when subjected to a graphite-spheroidizing treatment, an affinity for oxygen smaller than that of a graphite-spheroidizing element being used in the graphite-spheroidizing treatment.

Abstract: An additive for the deoxidation of molten steel comprised of between 35 and 65 percent by weight aluminum, between 5 and 15 percent by weight silicon, and between 20 and 40 percent by weight manganese.

Abstract: A desulfurization composition contains from about 3% to about 20% particulate metallic aluminum, about 5% to about 30% particulate alumina, about 0.5% to about 12% particulate hydrocarbon material or other gas generating composition and the balance lime plus impurities. Preferably aluminum dross is the source of aluminum and alumina. The desulfurization composition is injected into molten iron from a blast furnace preferably in an amount of 4 to 20 pounds desulfurizer per ton of hot metal. The desulfurizing composition can be injected as a blend or co-injected into the hot metal through a lance using a carrier gas or dumped into the hot metal as it is being poured into the ladle. At least for torpedo ladles, the desulfurization composition can be placed in the ladle before the hot metal is poured into it.

Abstract: The invention relates to an aluminothermic mixture consisting of a finely particulate base portion of iron oxides and aluminum as well as metallic additives, wherein a master alloy, namely a ferrochromium alloy consisting of (in % by weight)C: 0.1 to 20Si: 2 to 40Cr: 5 to 80and iron with impurities resulting from manufacture and, if appropriate, other alloying elements, is added in a quantity of from 5 to 50% by weight, relative to the base portion, as metallic additive.

Abstract: A desulfurization composition contains from about 3% to about 20% particulate metallic aluminum, about 5% to about 30% particulate alumina, about 0.5% to about 12% particulate hydrocarbon material or other gas generating composition and the balance lime plus impurities. Preferably aluminum dross is the source of aluminum and alumina. The desulfurization composition is injected into molten iron from a blast furnace preferably in an amount of 4 to 20 pounds desulfurizer per ton of hot metal. The desulfurizing composition can be injected as a blend or co-injected into the hot metal through a lance using a carrier gas or dumped into the hot metal as it is being poured into the ladle. At least for torpedo ladles, the desulfurization composition can be placed in the ladle before the hot metal is poured into it.

Abstract: The present invention relates to a highly efficient aluminum covering flux and a process for its preparation. The said covering flux comprises potassium chloride, sodium chloride, lithium chloride, potassium fluoride and sodium hydrosulfate, wherein the composition of the mentioned covering flux is: potassium chloride, 20-65 parts by weight; sodium chloride, 20-65 parts by weight; lithium chloride, 1-20 parts by weight; potassium fluoride, 0.3-5 parts by weight, sodium hydrosulfate, 0.2-3 parts by weight. The said covering flux can effectively prevent the oxidization of aluminum in the process of smelting aluminum and can increase the yield of aluminum.

Abstract: A method for agglomerating iron ore particles pre-reduced to produce hot pig iron, wherein hot iron ore particles pre-reduced in the pre-reduction furnace are simply mixed with aluminum powder or aluminum-containing metal powder before being loaded in the smelting reduction furnace so that they will be agglomerated, thereby being capable of not only simplifying the agglomeration, but also eliminating the adverse effect on the quality of ingot iron caused by impurities such as S or P. Aluminum dross, which is a waste, may be used as the aluminum-containing metal powder for agglomerating the iron ore particles. In this case, a reduced energy consumption and disposal of wastes can be achieved.

Abstract: A metallothermal reaction mixture consisting of a metal oxide, a metal that is more electronegative than the metal of the metal oxide and, optionally, further additives, the individual components being present in the form of small particles, is prepared in which at least 20% by weight of the metal oxide is present in the form of spherical or at least approximately spherical particles ranging in size from >0 to 3.0 mm. A stabilization and evening out of the reaction is achieved by the invention composition of the reaction mixture.

Abstract: A method for desulphurizing molten pig-iron involving injecting a gas-evolving desulphurizing agent which includes a calcium compound and a gas-forming material comprising of a liquid gas-producing compound absorbed in a porous slag-forming agent and at least 50% wt. magnesium.

Abstract: The present invention describes an agent for the desulfurization of pig iron or cast iron, based on finely granulated magnesium and at least 3 w. % of an metallurgically silicious mineral with a bond, blend or crystal structure and/or one of the minerals syenite and/or rhyolite pure or as a mixture.The desulfurizing agent may contain as an additional compound calciumcarbide and/or calciumoxide. The magnesium granule may be coated with these components.This agent is preferrably fed to the iron melt either as a mixture or in the co-injection process as one compound through a lance where mixing is achieved with the second compound before entering into the iron melt.

Abstract: Scrap aluminum is reclaimed by a salt flux-based reclamation process using potassium chloride in place of the commonly used sodium chloride. The spent flux which remains after the recovery of the aluminum is useful as a soil fertilizer, with the potassium content of the flux serving as a source of potassium nutrient for the soil. The potassium in the spent flux is highly water soluble at all values of pH while the aluminum in the spent flux remains at a limited solubility, particularly under the conditions expected to be encountered in soil. Thus, despite the known phytotoxicity of aluminum and the presence of aluminum in the spent flux, the spent flux is discovered to be useful as a plant fertilizer with the maximum benefit from the potassium and minimal if any harm from the aluminum.

Abstract: A hydrogen battery alloy is prepared which is substantially free of inclusions of chromium by preparing a first precursor alloy or master alloy containing vanadium, nickel, and chromium using relatively equal amounts of vanadium and nickel and then adding from 5% to 12% by weight of chromium. The alloy materials are introduced into an aluminothermic reaction as vanadium pentoxide, nickel powder and chromium powder with the aluminum metal being in slight excess of its stoichiometric amount. The first precursor alloy described further alloyed with preselected amounts of nickel, zirconium, titanium, cobalt, manganese, aluminum, and chromium to form an alloy suitable for use as an electrode material in rechargeable electrochemical hydrogen storage cells.

Abstract: A feedstock for metal injection molding comprises a reactive metal powder selected from the group consisting of aluminum, magnesium and titanium coated with a less reactive metal selected from the group consisting of cobalt, copper, iron, nickel, tin and zinc dispersed in a binder.

Abstract: An additive for use in the desulfurization of molten iron is disclosed. The additive comprises a granular mixture of metallic magnesium, calcium oxide and a small amount of a hydrocarbon-containing material which provides a volatile gas producing component to the mixture. The hydrocarbon-containing material is preferably coal, carbon black, wood flour or a high density polyethylene. The additive is intended to be pneumatically injected into the melt in a stream of nonoxygenated carrier gas.

Abstract: A granular additive alloy designed for addition of calcium to molten steel to obtain maximum calcium effects with minimal additions, especially in steels which cannot tolerate the other elements commonly accompanying calcium additions. An alloy is described which contains a ratio of not more than 2.85:1 nor less than 0.35:1 calcium to aluminum, and can contain other reactive metals such as, but not limited to, rare earths, boron, titanium, and zirconium in amounts up to 40% by weight of the alloy. The preferred embodiment is an alloy with 60% by weight calcium and 40% by weight aluminum. The particles are intended to dissolve in the molten steel and form a boundary layer adjacent their surfaces. The particles are sized such that substantially all of the particle is consumed in the formation of this boundary layer, according to a given relationship based on the concentration of calcium and aluminum in the alloy.

Abstract: An article of manufacture is provided in the form of a composite pig comprising a matrix of a ferro-aluminum alloy containing over about 55% and ranging up to about 75% aluminum and the balance essentially iron, the matrix alloy having distributed therethrough pieces of iron or steel in an amount sufficient to provide an overall pig composition of about 25% to 55% aluminum and the balance iron, including a densith of at least about 5 gr/cm.sup.3. The composite pig has particular use as a deoxidation agent for steel.