Producing Alloy Patents (Class 75/351)
  • Publication number: 20140283650
    Abstract: A method of manufacturing a powder having a high surface area is provided. According to the method of manufacturing a powder having a high surface area, a metal electrolyte in which metal ions of different kinds of first metals are dissociated is prepared. Subsequently, a metal alloy powder formed of the first metals is formed by soaking a second metal having a higher reducing power than the first metals in the metal electrolyte to induce a first spontaneous substitution reaction. Therefore, it is possible to form a powder having an improved specific surface area.
    Type: Application
    Filed: October 23, 2012
    Publication date: September 25, 2014
    Applicant: Research & Business Foundation Sungkyunkwan University
    Inventors: Chan-Hwa Chung, Myung Gi Jeong
  • Patent number: 8840701
    Abstract: Disclosed are methods of making multi-element, finely divided, metal powders containing one or more reactive metals and one or more non-reactive metals. Reactive metals include metals or mixtures thereof from titanium (Ti), zirconium (Zr), hafnium (Hf), tantalum (Ta), niobium (Nb), vanadium (V), nickel (Ni), cobalt (Co), molybdenum (Mo), manganese (Mn), and iron (Fe). Non-reactive metals include metals or mixtures such as silver (Ag), tin (Sn), bismuth (Bi), lead (Pb), antimony (Sb), zinc (Zn), germanium (Ge), phosphorus (P), gold (Au), cadmium (Cd), berrylium (Be), tellurium (Te).
    Type: Grant
    Filed: August 12, 2009
    Date of Patent: September 23, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventors: William J. Borland, Howard David Glicksman
  • Patent number: 8834785
    Abstract: A method for producing a metal article according to one embodiment may involve the steps of: Providing a composite metal powder including a substantially homogeneous dispersion of molybdenum and molybdenum disulfide sub-particles that are fused together to form individual particles of the composite metal powder; and compressing the molybdenum/molybdenum disulfide composite metal powder under sufficient pressure to cause the mixture to behave as a nearly solid mass.
    Type: Grant
    Filed: July 11, 2011
    Date of Patent: September 16, 2014
    Assignee: Climax Engineered Materials, LLC
    Inventors: Matthew C. Shaw, Carl V. Cox, Yakov Epshteyn
  • Publication number: 20140251801
    Abstract: Provided are a sputtering target which has excellent machinability and is capable of forming a compound film that mainly contains Cu and Ga and a method for producing the sputtering target. The sputtering target of the present invention has a component composition that contains 15 to 40 at % of Ga, 0.1 to 5 at % of Bi, and the balance composed of Cu and unavoidable impurities with respect to all metal elements in the sputtering target. The method for producing the sputtering target includes a step of melting at least Cu, Ga and Bi as simple substances or an alloy that contains two or more of these elements at 1,050° C. or higher to produce an ingot.
    Type: Application
    Filed: July 6, 2012
    Publication date: September 11, 2014
    Applicants: MITSUBISHI MATERIALS CORPORATION, Showa Shell Sekiyu K.K.
    Inventors: Shoubin Zhang, Masahiro Shoji, Keita Umemoto
  • Patent number: 8821611
    Abstract: A titanium metal or a titanium alloy having submicron titanium boride substantially uniformly dispersed therein and a method of making same is disclosed. Ti power of Ti alloy powder has dispersed within the particles forming the powder titanum boride which is other than whisker-shaped or spherical substantially uniformly dispersed therein.
    Type: Grant
    Filed: December 6, 2012
    Date of Patent: September 2, 2014
    Assignee: Cristal Metals Inc.
    Inventors: Lance Jacobsen, Adam Benish
  • Patent number: 8821610
    Abstract: A method and a device are described for the production of metal powder or alloy powder of a moderate grain sizes less than 10 ?m, comprising or containing at least one of the reactive metals zirconium, titanium, or hafnium, by metallothermic reduction of oxides or halogenides of the cited reactive metals with the aid of a reducing metal, wherein said metal powder or alloy powder is phlegmatized by adding a passivating gas or gas mixture during and/or after the reduction of the oxides or halogenides and/or is phlegmatized by adding a passivating solid before the reduction of the oxides or halogenides, wherein both said reduction and also said phlegmatization are performed in a single gas-tight reaction vessel which can be evacuated.
    Type: Grant
    Filed: January 8, 2009
    Date of Patent: September 2, 2014
    Assignee: Tradium GmbH
    Inventor: Ulrich Gerhard Baudis
  • Patent number: 8815151
    Abstract: Nanowire preparation methods, compositions, and articles are disclosed. Such methods which reduce metal ions to metal nanowires in the presence complexes comprising metal-metal bonds, are capable of producing long, narrow, nanowires useful for electronics and optical applications.
    Type: Grant
    Filed: April 23, 2012
    Date of Patent: August 26, 2014
    Assignee: Carestream Health, Inc.
    Inventor: David R. Whitcomb
  • Publication number: 20140224067
    Abstract: Branched nanowire preparation methods, compositions, and articles are disclosed. Such branched nanowires are useful for electronics and optical applications.
    Type: Application
    Filed: April 15, 2014
    Publication date: August 14, 2014
    Applicant: Carestream Health, Inc.
    Inventor: David R. Whitcomb
  • Patent number: 8790615
    Abstract: A method of synthesizing carbon-magnetite nanocomposites. In one embodiment, the method includes the steps of (a) dissolving a first amount of an alkali salt of lignosulfonate in water to form a first solution, (b) heating the first solution to a first temperature, (c) adding a second amount of iron sulfate (FeSO4) to the first solution to form a second solution, (d) heating the second solution at a second temperature for a first duration of time effective to form a third solution of iron lignosulfonate, (e) adding a third amount of 1N sodium hydroxide (NaOH) to the third solution of iron lignosulfonate to form a fourth solution with a first pH level, (f) heating the fourth solution at a third temperature for a second duration of time to form a first sample, and (g) subjecting the first sample to a microwave radiation for a third duration of time effective to form a second sample containing a plurality of carbon-magnetite nanocomposites.
    Type: Grant
    Filed: March 22, 2011
    Date of Patent: July 29, 2014
    Assignee: Board of Trustees of the University of Arkansas
    Inventor: Tito Viswanathan
  • Patent number: 8765025
    Abstract: A metal nanoparticle composition includes an organic-stabilized metal nanoparticle and a solvent in which the solvent selected has the following Hansen solubility parameters: a dispersion parameter of about 16 MPa0.5 or more, and a sum of a polarity parameter and a hydrogen bonding parameter of about 8.0 MPa0.5 or less. The metal nanoparticle composition is suitable for printing conductive lines that are uniform, smooth and narrow on various substrate surfaces. The metal nanoparticle composition is able to form printed conductive features having a coffee ring effect ratio of about 1.2 to about 0.8, a surface roughness of about 15 or less and a line width of about 200 microns or less.
    Type: Grant
    Filed: June 9, 2010
    Date of Patent: July 1, 2014
    Assignee: Xerox Corporation
    Inventors: Yiliang Wu, Yulin Wang, Mahya Mohktari, Roger E. Gaynor, Nan-Xing Hu, Marko D. Saban
  • Patent number: 8758900
    Abstract: The present invention provides nanometer-size spherical particles. Each of the particles is made of at least one selected from the group consisting of a metal, an alloy, and a metal compound. The particles include one or both of a polycrystalline region and a single-crystalline region. The particles have a particle size of less than 1 ?m; and a sphericity of ?10% to +10%.
    Type: Grant
    Filed: May 27, 2010
    Date of Patent: June 24, 2014
    Assignee: Napra Co., Ltd.
    Inventors: Shigenobu Sekine, Yurina Sekine
  • Patent number: 8721762
    Abstract: A process for synthesizing metal submicron and nano-scale powders for use in articles of manufacture. In a suitable reactor, single metal or multiple metal complexes are heated to a temperature whereby, upon contact with hydrogen gas, an exothermic reaction begins. The further temperature rise in response to the exothermic reaction is minimized by reducing the external heat input, thereby minimizing the agglomeration or sintering of the metal nano-scale particles resulting from the process. Preferably, after drawing a vacuum on the metal complexes in the reactor, the hydrogen is introduced at about, equal to or below ambient pressure and the reaction is purposely made slow to prevent agglomeration or sintering.
    Type: Grant
    Filed: June 10, 2010
    Date of Patent: May 13, 2014
    Assignee: Chemano, Inc.
    Inventor: Wei Wu
  • Patent number: 8709126
    Abstract: Various embodiments provide methods of forming metallic particles or carbon/graphite coated metallic particles with zero-valence from metal precursor compounds by a reductive/expansion synthesis method using nitrogen-hydrogen containing molecules.
    Type: Grant
    Filed: February 3, 2011
    Date of Patent: April 29, 2014
    Assignee: STC.UNM
    Inventors: Claudia Catalina Luhrs, Zayd Leseman, Jonathan Phillips, Hugo Ricardo Zea-Ramirez
  • Publication number: 20140113139
    Abstract: A method of producing inorganic compound particles is provided. It includes a step of impregnating a melt liquid of second raw particles into first raw particles by heating a raw material including them at a temperature, which equals to or higher than an eutectic temperature between a region-II (solid-liquid phase range) and a region-I (solid phase range) in a phase diagram and lower than the melting temperature of the inorganic compound. The first raw particles contain an element with a melting point equals to or higher than a melting point of the inorganic compound. The second raw particles contain an element with a melting point lower than the inciting point of the inorganic compound. The method also includes a step of synthesizing inorganic compound particles by a synthetic reaction in the first raw particles between the elements contained in the first and second raw particles.
    Type: Application
    Filed: December 27, 2013
    Publication date: April 24, 2014
    Applicants: Mitsuba Corporation, National Institute for Materials Science
    Inventors: Yukihiro Isoda, Naoki Shioda
  • Publication number: 20140106241
    Abstract: An electrochemical cell has an electrode which includes a zinc-indium alloy as electrochemically active material, wherein the alloy is present in the form of particles and the entirety of the particles is composed of at least two particle fractions differing in indium concentration.
    Type: Application
    Filed: October 15, 2013
    Publication date: April 17, 2014
    Applicant: VARTA Microbattery GmbH
    Inventors: Cornelia Csrenko, Ulrich Kohls, Bernd Kreidler, Hermann Löffelmann, Andreas Rupp
  • Patent number: 8685137
    Abstract: The invention relates to a process for producing an iron-and/or tungsten containing powder or powder agglomerate including the steps of: a) mixing at least a first powder fraction comprising a tungsten carbide containing powder, and at least a second powder fraction comprising an iron oxide powder and/or a tungsten oxide containing powder and optionally an iron powder, the weight of the first fraction being in the range of 50-90% by weight of the mix and the weight of the second fraction being in the range of 10-50% by weight of the mix, b) heating the mix of step a) to a temperature in the range of 400-1300° C., preferably 1000-1200° C. The invention also relates to an iron-and/or tungsten containing powder or powder agglomerate.
    Type: Grant
    Filed: October 26, 2010
    Date of Patent: April 1, 2014
    Assignee: Minpro Aktiebolag
    Inventor: Johan Arvidsson
  • Publication number: 20140047950
    Abstract: The present invention relates to a continuous reactor a method for manufacturing nanoparticles. The reactor of the present invention includes: a plurality of first inputs for individually inputting a plurality of reagents; a first mixing part connected to the first inputs to mix the reagents; N number of first reaction units, each comprising a plurality of first diverging channels and a first converging channel to form a channel having the first diverging channels and the first converging channels alternately connected to one another in series for N times of diverging-converging actions, wherein N?1, and the first diverging channels of a 1st one of the first reaction units are connected to the first mixing part; and a first output connected to the first converging channel of an Nth one of the first reaction units, so as to output a product of nanoparticles.
    Type: Application
    Filed: November 21, 2012
    Publication date: February 20, 2014
    Applicant: National Tsing Hua University
    Inventors: Kan-Sen CHOU, Yu-Chun CHANG, Yi-Chu CHEN, Yu-Chieh LU
  • Patent number: 8641798
    Abstract: A one-step process for synthesizing gold-copper bimetallic nanocubes. The process comprises the step of simultaneously reducing a copper II salt and a gold halide by 1,2-hexadecanediol in diphenyl ether, and 1-dodecanethiol as well as surfactants 1-adamantanecarboxylic acid and 1-hexadecylamine. The copper II salt may be copper (II) acetylacetonate, copper chloride, copper sulfate, or copper phosphate. The gold halide may be chloroauric acid, gold chloride, gold bromide, or tetrabromoauric acid. The reduction may occur at a temperature between about 160 and 180 degrees Celsius. The copper II salt may be copper (II) acetylacetonate and the gold halide may be chloroauric acid.
    Type: Grant
    Filed: July 12, 2011
    Date of Patent: February 4, 2014
    Assignee: The United States of America, as represented by the Secretary of Commerce, NIST
    Inventors: Angela R. Hight-Walker, Yonglin Liu
  • Publication number: 20140027667
    Abstract: Superparamagnetic core shell nanoparticles having a core of a iron cobalt ternary alloy and a shell of a silicon oxide directly on the core and a particle size of 2 to 200 nm are provided. Methods to prepare the nanoparticles are also provided.
    Type: Application
    Filed: July 26, 2012
    Publication date: January 30, 2014
    Applicant: Toyota Motor Engineering & Manufacturing NA
    Inventor: Michael Paul Rowe
  • Patent number: 8617290
    Abstract: The present invention relates to a method for manufacturing a Fe—Si alloy powder. A method for manufacturing a Fe—Si alloy powder includes: providing a mixture of an Al2O3 powder, an active agent powder, a Si powder, and a Fe powder; heating the mixture with a temperature of 700° C. to 1200° C. in the hydrogen atomosphere; magnetically separating a Fe-containing material from the mixture; and separating a Fe—Si alloy powder by soaking the Fe-containing material in an alkali solution. In the heating of the mixture, the Si powder is deposited on the surface of the Fe powder and diffused into the Fe powder.
    Type: Grant
    Filed: October 22, 2010
    Date of Patent: December 31, 2013
    Assignee: Korea Institute of Science and Technology
    Inventors: Ji-Young Byun, Yoon-Bae Kim, Hyun-Kwang Seok, Jang-Won Kim, Dow-Bin Hyun, Heon-Phil Ha, Do-Hyung Kim
  • Publication number: 20130343945
    Abstract: A titanium metal or a titanium alloy having submicron titanium boride substantially uniformly dispersed therein and a method of making same is disclosed. Ti power of Ti alloy powder has dispersed within the particles forming the powder titanum boride which is other than whisker-shaped or spherical substantially uniformly dispersed therein.
    Type: Application
    Filed: December 6, 2012
    Publication date: December 26, 2013
    Applicant: CRISTAL METALS INC.
    Inventors: Amy Simpson, Cristal Metals Inc.
  • Publication number: 20130309160
    Abstract: A process for preparing a composition of mixed crystalline particles from columns 13-15 in which a liquid solution is produced by solubilization in a non-aqueous solvent medium of at least one first precursor chosen from coordination complexes including at least one element E1 from column 13, then the liquid solution is brought into contact with at least one second precursor chosen from the hydrides of at least one element E2 from column 15.
    Type: Application
    Filed: December 15, 2011
    Publication date: November 21, 2013
    Applicant: CENTRE NATIONAL DE AL RECHERCHE SCIENTIFIQUE (C.N.R.S.)
    Inventors: Myrtil Kahn, Sebastien Graule, Gregory Spataro
  • Patent number: 8574337
    Abstract: A method of producing carbon-metal nanocomposites includes (a) treating a material containing at least one o-catechol unit with a first solution of hexamine such that the material becomes hexamine treated; (b) treating the material with a second solution having a plurality of metal ions such that the material becomes metal treated; (c) treating the material with a third solution of alkali such that the material becomes alkali treated; and (d) heating the alkali, metal and hexamine treated material after (a), (b), and (c) for a predetermined period of time such that a plurality of carbon-metal nanocomposites having metal nanoparticles dispersed in the material are produced.
    Type: Grant
    Filed: December 22, 2011
    Date of Patent: November 5, 2013
    Assignee: Board of Trustees of the University of Arkansas
    Inventor: Tito Viswanathan
  • Patent number: 8535573
    Abstract: A method for producing copper fine particles by heating and reducing an oxide, hydroxide, or salt of copper included in a solution of ethylene glycol, diethylene glycol, or triethylene glycol, the method comprising controlling a total halogen content of the solution to be less than 20 ppm by mass relative to copper and adding a water-soluble polymer as a dispersant such as polyethyleneimine and a noble metal compound or noble metal colloid for nucleation to the solution. This method makes it possible to provide copper fine particles for use in a wiring material, which are very fine as small as 50 nm or less in average particle size and high dispersibility, extremely low undesirable halogen content, and can be sintered at a low temperature.
    Type: Grant
    Filed: October 31, 2008
    Date of Patent: September 17, 2013
    Assignee: Sumitomo Metal Mining Co., Ltd.
    Inventors: Kazuomi Ryoshi, Yasumasa Hattori, Hiroko Oshita
  • Publication number: 20130192986
    Abstract: Provided are a method for producing a Cu—Ga alloy powder, by which a high quality Cu—Ga alloy powder to be produced readily; a Cu—Ga alloy powder; a method for producing a Cu—Ga alloy sputtering target; and a Cu—Ga alloy sputtering target. Specifically, a Cu—Ga alloy powder is produced by stirring a mixed powder containing a Cu powder and a Ga in a mass ratio of 85:15 to 55:45 at a temperature of 30 to 700° C. in an inert atmosphere thereby accomplishing alloying. Also a Cu—Ga alloy sputtering target is produced by molding the Cu—Ga alloy powder followed by sintering.
    Type: Application
    Filed: April 7, 2011
    Publication date: August 1, 2013
    Applicant: SUMITOMO METAL MINING CO., LTD.
    Inventors: Toshio Morimoto, Tatsuya Takahashi, Isao Ando, Tetsufumi Komukai, Masanori Takagi, Eriko Sato, Hirotaka Minami
  • Patent number: 8491697
    Abstract: [Problem]To provide a method for producing an electrocatalyst having no compositional scatter, wherein nano-level alloy catalyst molecules with an ordered particle size are supported in a highly dispersed state. [Means of Solution] The method includes the steps of preparing a reverse micelle solution by mixing two or more catalyst precursors selected from among metal salts and/or metal complexes, a solvent having hydrophilic groups and a non-aqueous solvent, forming alloy particles in the reverse micelle by adding a non-aqueous solution having a reducing action to the reverse micelle and heating, and supporting the alloy particles on a carrier.
    Type: Grant
    Filed: October 6, 2005
    Date of Patent: July 23, 2013
    Assignee: Yamanashi University
    Inventors: Masahiro Watanabe, Hiroyuki Uchida
  • Patent number: 8460584
    Abstract: Processes for producing carboxylic acid-stabilized silver nanoparticles are disclosed. The processes comprise (a) forming a suspension of silver salt particles in a carboxylic acid; (b) forming a solution of an organohydrazine and a first organic solvent; (c) heating the suspension; (d) adding the solution to the suspension to form a mixture; and (e) reacting the mixture to form carboxylic acid-stabilized silver nanoparticles.
    Type: Grant
    Filed: October 14, 2008
    Date of Patent: June 11, 2013
    Assignee: Xerox Corporation
    Inventors: Mahya Mokhtari, Marko Saban, Roger Earl Gaynor
  • Publication number: 20130133483
    Abstract: Selective gas-reducing methods for making shape-defined metal-based nanoparticles. By avoiding the use of solid or liquid reducing reagents, the gas reducing reagent can be used to make shape well-defined metal- and metal alloy-based nanoparticles without producing contaminates in solution. Therefore, the post-synthesis process including surface treatment become simple or unnecessary. Weak capping reagents can be used for preventing nanoparticles from aggregation, which makes the further removing the capping reagents easier. The selective gas-reducing technique represents a new concept for shape control of nanoparticles, which is based on the concepts of tuning the reducing rate of the different facets. This technique can be used to produce morphology-controlled nanoparticles from nanometer- to submicron- to micron-sized scale. The Pt-based nanoparticles show improved catalytic properties (e.g., activity and durability).
    Type: Application
    Filed: March 8, 2011
    Publication date: May 30, 2013
    Applicant: UNIVERSITY OF ROCHESTER
    Inventors: Hong Yang, Jianbo Wu, Miao Shi, Adam Gross
  • Patent number: 8414678
    Abstract: A method for generating metallic nanomaterials using acetylenic-bridged metal-carbonyl complexes as a precursor allows control of nanoparticle properties. The novel method produced metallic nanomaterials resistant to oxidation.
    Type: Grant
    Filed: September 14, 2007
    Date of Patent: April 9, 2013
    Assignee: Board of Supervisors of Lousiana State University And Agricultural and Mechanical College
    Inventors: Challa S. S. R. Kumar, Rohini M. de Silva, Josef Hormes
  • Publication number: 20130084502
    Abstract: A process for preparing intermetallic nanoparticles of two or more metals is provided. In particular, the process includes the steps: a) dispersing nanoparticles of a first metal in a solvent to prepare a first metal solution, b) forming a reaction mixture with the first metal solution and a reducing agent, c) heating the reaction mixture to a reaction temperature; and d) adding a second metal solution containing a salt of a second metal to the reaction mixture. During this process, intermetallic nanoparticles, which contain a compound with the first and second metals are formed. The intermetallic nanoparticles with uniform size and a narrow size distribution is also provided. An electrochemical device such as a battery with the intermetallic nanoparticles is also provided.
    Type: Application
    Filed: September 30, 2011
    Publication date: April 4, 2013
    Inventors: Dileep Singh, Yusuf Yusufoglu, Elena Timofeeva, Jules Routbort
  • Patent number: 8409371
    Abstract: A method for producing a soft magnetic metal powder coated with a Mg-containing oxide film, comprising the steps of adding and mixing a Mg powder with a soft magnetic metal powder which has been subjected to heating treatment in an oxidizing atmosphere at a temperature of 40 to 500° C. to obtain a mixed powder, and heating the mixed powder at a temperature of 150 to 1,100° C. in an inert gas or vacuum atmosphere under a pressure of 1×10?12 to 1×10?1 MPa, while optionally tumbling; and a method for producing a composite soft magnetic material from the soft magnetic metal powder coated with a Mg-containing oxide film.
    Type: Grant
    Filed: September 7, 2011
    Date of Patent: April 2, 2013
    Assignee: Diamet Corporation
    Inventors: Muneaki Watanabe, Ryoji Nakayama, Gakuji Uozumi
  • Patent number: 8382877
    Abstract: The present invention provides an approach to control the generation and grow of nanocrystal with membrane diffusion method and related apparatuses to produce inorganic oxide nanopowders and metal nanoparticles. With this method, the size and size distribution of inorganic oxide nanopowders and metal nanoparticles can be tuned. It overcomes the shortcomings possessed by the common chemical and physical method of preparing nanoparticles.
    Type: Grant
    Filed: July 5, 2011
    Date of Patent: February 26, 2013
    Assignee: Beijing University of Technology
    Inventors: Hong He, Hongxing Dai, Xuehong Zi
  • Patent number: 8349467
    Abstract: The present invention provides metal nanowires including at least silver, and a metal other than silver, wherein the metal other than silver has a standard electrode potential more positive than the standard electrode potential of silver, and the metal nanowires have a long-axis length of 1 ?m or more and a short-axis length of 300 nm or less.
    Type: Grant
    Filed: March 5, 2009
    Date of Patent: January 8, 2013
    Assignee: FUJIFILM Corporation
    Inventor: Kenji Naoi
  • Patent number: 8343668
    Abstract: A porous tin particle and its preparation method are provided in the present invention. The method includes steps of: (a) performing a reductive (or reductive electrochemical) reaction on a tin particle which simultaneously reacts with lithium ions to form a tin-lithium (Sn—Li) alloy; and (b) performing an oxidative (or oxidative electrochemical) reaction on Sn—Li alloy to release the lithium ions therefrom, and the porous tin particle is formed. The porous tin particle could be further applied in manufacturing the electrochemical electrode for lithium-ion battery with longer cycle life and higher reversibility.
    Type: Grant
    Filed: November 1, 2010
    Date of Patent: January 1, 2013
    Assignee: National Taiwan University
    Inventors: Nae-Lih Wu, Sung-Chieh Chao
  • Publication number: 20120301353
    Abstract: Nanowire preparation methods, compositions, and articles are disclosed. Such methods which reduce metal ions to metal nanowires in the presence complexes comprising metal-metal bonds, are capable of producing long, narrow, nanowires useful for electronics and optical applications.
    Type: Application
    Filed: April 23, 2012
    Publication date: November 29, 2012
    Inventor: David R. Whitcomb
  • Publication number: 20120295110
    Abstract: The invention relates to a composition for synthesizing bimetallic nanoparticles, wherein the composition contains a first organometallic precursor and a second organometallic precursor having different decomposition rates and contained within an ionic liquid solution. The invention also relates to a method for synthesizing bimetallic nanoparticles, in which the composition is transformed under a hydrogen gas pressure between 0.1 and 10 MPa at a temperature between 0 and 150° C. until a suspension of bimetallic nanoparticles is obtained. The resulting nanoparticles are useful in diverse fields including the fields of catalysis and microelectronics.
    Type: Application
    Filed: April 20, 2012
    Publication date: November 22, 2012
    Applicants: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENE ALT, CPE LYON, UNIVERSITE CLAUDE BERNARD LYON 1, CNRS -Centre National de la Recherche Scientifique
    Inventors: Philippe Arquilliere, Paul-Henri Haumesser, Inga Helgadottir, Catherine Santini
  • Patent number: 8313551
    Abstract: The present invention provides a novel process for synthesis of a copper-alloy particle with improved grain boundary properties. The process comprises the steps of: forming a solution from an alcoholic agent and a branched dispersing agent; forming a reaction mixture with the solution and a copper precursor and optionally a nickel precursor; heating the reaction mixture; cooling the reaction mixture; adding an additional amount of copper precursor and at least one precursor selected from the group consisting of: nickel, zinc, and bismuth; heating the reaction mixture; and maintaining the reaction mixture for a time sufficient to reduce the reaction mixture to copper-alloy particles.
    Type: Grant
    Filed: March 17, 2010
    Date of Patent: November 20, 2012
    Assignee: Energetic Materials LLC
    Inventor: Joshua M. Deinzer
  • Publication number: 20120288440
    Abstract: The present invention relates to pulverulent materials suitable for storing hydrogen, and more particularly to a method of preparing such a material, in which: (A) a composite metallic material having a specific granular structure is prepared by co-melting the following mixtures: a first metallic mixture (m1), which is an alloy (a1) of body-centred cubic crystal structure, based on titanium, vanadium, chromium and/or manganese, or a mixture of these metals in the proportions of the alloy (a1); and a second mixture (m2), which is an alloy (a2), comprising 38 to 42% zirconium, niobium, molybdenum, hafnium, tantalum and/or tungsten and 56 to 60 mol % of nickel and/or copper, or else a mixture of these metals in the proportions of the alloy (a2), with a mass ratio (m2)/(m1+m2) ranging from 0.1 wt % to 20 wt %; and (B) the composite metallic material thus obtained is hydrogenated, whereby the composite material is fragmented (hydrogen decrepitation).
    Type: Application
    Filed: July 30, 2012
    Publication date: November 15, 2012
    Applicant: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (C.N.R.S.)
    Inventors: Jean Charbonnier, Patricia De Rango, Daniel Fruchart, Salvatore Miraglia, Sophie Rivoirard, Natalia Skryabina
  • Publication number: 20120282130
    Abstract: A carbothermic reduction method is provided for reducing a rare earth element-containing oxide including at least one of neodymium (Nd) and praseodymium (Pr) and possibly other rare earth elements (La, Ce, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Sc, and Y) as alloying agents in the presence of carbon and a source of a reactant element including one or more of silicon, germanium, tin, lead, arsenic, antimony and bismuth to form a rare earth element-containing intermediate alloy as a master alloy for making permanent magnet material. The process is a more efficient, lower cost and environmentally friendly technology than current methods of manufacturing rare earth metals. The intermediate material is useful as a master alloy for making a permanent magnet material comprising at least one of neodymium and praseodymium, and possibly other rare earth metals as alloying additives.
    Type: Application
    Filed: April 18, 2012
    Publication date: November 8, 2012
    Inventors: Karl A. Gschneidner, JR., Frederick A. Schmidt, Ralph W. McCallum
  • Publication number: 20120272790
    Abstract: The invention relates to Sn—Cu—Ag alloy nanoparticles, preparation method thereof and ink or paste using the alloy nanoparticles in which the alloy nanoparticles are suitable for metal ink having excellent electrical conductivity or solder materials having low calcinating temperature.
    Type: Application
    Filed: June 13, 2012
    Publication date: November 1, 2012
    Applicant: Samsung Electro-Mechanics Co., Ltd.
    Inventors: Kwi-Jong Lee, Hyuck-Mo Lee, Hyun-Joon Song, Yun-Hwan Jo, Ji-Chan Park, Jung-Up Bang, Dong-Hoon Kim
  • Patent number: 8287617
    Abstract: A method for producing an alloy fine particle colloid by heating and evaporating a raw material binary alloy which is in a solid state in an ambient temperature and pressure environment in a reduced-pressure environment, cooling a generated vapor for condensation and solidification and collecting a formed alloy fine particle in a liquid medium, wherein (1) when an atomic fraction of a component element in the raw material alloy is defined as X, a component ratio of each of the elements of the raw material alloy is regulated such that a fraction of a vapor pressure of the component element to the total vapor pressure of the raw material alloy falls within the range of from (X?0.1) to (X+0.1); and (2) the raw material binary alloy is an alloy species which forms a homogeneous alloy phase in an alloy ingot. Thus, an alloy fine particle colloid is rationally and efficiently produced.
    Type: Grant
    Filed: April 25, 2007
    Date of Patent: October 16, 2012
    Assignee: National Institute for Materials Science
    Inventor: Isao Nakatani
  • Publication number: 20120251380
    Abstract: The invention relates to a process for producing an iron-and/or tungsten containing powder or powder agglomerate including the steps of: a) mixing at least a first powder fraction comprising a tungsten carbide containing powder, and at least a second powder fraction comprising an iron oxide powder and/or a tungsten oxide containing powder and optionally an iron powder, the weight of the first fraction being in the range of 50-90% by weight of the mix and the weight of the second fraction being in the range of 10-50% by weight of the mix, b) heating the mix of step a) to a temperature in the range of 400-1300° C., preferably 1000-1200° C. The invention also relates to an iron-and/or tungsten containing powder or powder agglomerate.
    Type: Application
    Filed: October 26, 2010
    Publication date: October 4, 2012
    Applicant: MINPRO AKTIEBOLAG
    Inventor: Johan Arvidsson
  • Publication number: 20120244030
    Abstract: Provided are a powder for a magnet, which provides a rare-earth magnet having excellent magnet properties and which has excellent formability, a method for producing the powder for a magnet, a powder compact, a rare-earth-iron-based alloy material, and a rare-earth-iron-nitrogen-based alloy material which are used as materials for the magnet, and methods for producing the powder compact and these alloy materials. Magnetic particles 1 constituting the powder for a magnet each have a texture in which grains of a phase 3 of a hydride of a rare-earth element are dispersed in a phase 2 of an iron-containing material, such as Fe. The uniform presence of the phase 2 of the iron-containing material in each magnetic particle 1 results in the powder having excellent formability, thereby providing a powder compact 4 having a high relative density.
    Type: Application
    Filed: December 2, 2010
    Publication date: September 27, 2012
    Applicant: Sumitomo Electric Industries, Ltd.
    Inventor: Toru Maeda
  • Publication number: 20120238443
    Abstract: The present invention is directed to a process for manufacture of base metal nano-particles using precious metal seed particles. The process comprises the steps of mixing at least one base metal precursor and at least one precious metal precursor in one or more polyol solvents, reacting the mixture at a temperature in the range of 110 to 150° C. to form precious metal seed particles (STEP A) and reacting the mixture at a temperature in the range of 180 to 220° C. to form the final metal particles (STEP B). Base metal particles of Co, Ni and Cu containing 100 to 10000 ppm of precious metals Ru, Pd, Pt or Ir are obtained. The resulting metal nano-particles with medium diameters of 20 to 200 nm are useful for electronic and catalytic applications and can be used as core materials for the manufacture core/shell type catalysts.
    Type: Application
    Filed: March 16, 2011
    Publication date: September 20, 2012
    Inventors: Dan V. Goia, Marco Lopez, Igor V. Sevonkaev
  • Publication number: 20120230860
    Abstract: A method for purifying metal M1 particles manufactured by an electrochemical reduction process, the method comprising the steps of introducing the metal M1 particles into a heat source (13) at a temperature substantially equal to or higher than the melting point of M1 so as to cause vaporisation of some or substantially all of the contaminating impurities present, removing the vaporised impurities from the vicinity of the particles, and cooling the purified metal M1 particles. The purified particles can be used directly in lower temperature powder metallurgy processes and have a fully dense spherical particle morphology, imparting good flowability. The purification process can also be incorporated as an integral stage of sheet or stock production processes based on particle feedstocks that have been produced by electrochemical reduction.
    Type: Application
    Filed: May 22, 2012
    Publication date: September 13, 2012
    Applicant: METALYSIS LIMITED
    Inventors: Charles M. WARD-CLOSE, Alastair B. Godfrey, Paul S. Goodwin
  • Patent number: 8257464
    Abstract: The present invention relates to pulverulent materials suitable for storing hydrogen, and more particularly to a method of preparing such a material, in which: (A) a composite metallic material having a specific granular structure is prepared by co-melting the following mixtures: a first metallic mixture (m1), which is an alloy (a1) of body-centered cubic crystal structure, based on titanium, vanadium, chromium and/or manganese, or a mixture of these metals in the proportions of the alloy (a1); and a second mixture (m2), which is an alloy (a2), comprising 38 to 42% zirconium, niobium, molybdenum, hafnium, tantalum and/or tungsten and 56 to 60 mol % of nickel and/or copper, or else a mixture of these metals in the proportions of the alloy (a2), with a mass ratio (m2)/(m1+m2) ranging from 0.1 wt % to 20 wt %; and (B) the composite metallic material thus obtained is hydrogenated, whereby the composite material is fragmented (hydrogen decrepitation).
    Type: Grant
    Filed: February 22, 2007
    Date of Patent: September 4, 2012
    Assignee: Centre National de la Recherche Scientifique (C.N.R.S.)
    Inventors: Jean Charbonnier, Patricia De Rango, Daniel Fruchart, Salvatore Miraglia, Sophie Rivoirard, Natalia Skryabina
  • Patent number: 8216508
    Abstract: A method for preparing an article of a base metal alloyed with an alloying element includes the steps of preparing a compound mixture by the steps of providing a chemically reducible nonmetallic base-metal precursor compound of a base metal, providing a chemically reducible nonmetallic alloying-element precursor compound of an alloying element, and thereafter mixing the base-metal precursor compound and the alloying-element precursor compound to form a compound mixture. The compound mixture is thereafter reduced to a metallic alloy, without melting the metallic alloy. The step of preparing or the step of chemically reducing includes the step of adding an other additive constituent. The metallic alloy is thereafter consolidated to produce a consolidated metallic article, without melting the metallic alloy and without melting the consolidated metallic article.
    Type: Grant
    Filed: August 7, 2008
    Date of Patent: July 10, 2012
    Assignee: General Electric Company
    Inventors: Andrew Philip Woodfield, Eric Allen Ott, Clifford Earl Shamblen, Michael Francis Xavier Gigliotti
  • Patent number: 8197885
    Abstract: A method for producing a metal article according to one embodiment may include: Providing a supply of a sodium/molybdenum composite metal powder; compacting the sodium/molybdenum composite metal powder under sufficient pressure to form a preformed article; placing the preformed article in a sealed container; raising the temperature of the sealed container to a temperature that is lower than a sintering temperature of molybdenum; and subjecting the sealed container to an isostatic pressure for a time sufficient to increase the density of the article to at least about 90% of theoretical density.
    Type: Grant
    Filed: February 25, 2009
    Date of Patent: June 12, 2012
    Assignee: Climax Engineered Materials, LLC
    Inventors: Dave Honecker, Christopher Michaluk, Carl Cox, James Cole
  • Publication number: 20120114962
    Abstract: A system and method to tailor the optical properties of nanomaterials using a core-alloy-shell nano-ultrastructure. Atomic diffusion is used at the nanoscale in order to process as-synthesized nanomaterials into core-alloy-shell architectures. The alloy formation is controlled by the deposition of the alloy solute atoms, and then by alloy interdiffusion of the solute into the core nanoparticle. By controlling temperature, it is possible to control how far the solute diffuses into the core, which in turn allows the tailoring of the optical response of the particle itself. The alloy formation and subsequent interdiffusion allows tailoring of the nanoparticle composition and ultrastructure, resulting in a dramatic tunability of the metal nanostructures surface plasmon response.
    Type: Application
    Filed: November 8, 2011
    Publication date: May 10, 2012
    Applicant: SYRACUSE UNIVERSITY
    Inventors: Mathew Maye, Peter Njoki, Wenjie Wu, Hyunjoo Han
  • Patent number: 8167972
    Abstract: The present invention has an object of providing a single-stage production method that enables the production of ultra fine metal nanoparticles and ordered alloy nanoparticles within solution. The production method includes irradiating a solution of a salt or complex of a metal element, thereby decomposing and/or reducing the salt or complex within the solution and generating metal nanoparticles having an average particle size within a range from 0.3 to 100 nm within the solution.
    Type: Grant
    Filed: June 27, 2007
    Date of Patent: May 1, 2012
    Assignee: N.E. Chemcat Corporation
    Inventors: Takashi Ito, Hiroshi Sugai, Masato Watanabe