Abstract: The present invention provides a process for the preparation of Ti-doped alkali metal and/or alkaline-earth metal aluminium hydride, comprising intimately mixing: an alkali metal and/or alkaline-earth metal aluminium hydride, or at least one alkali metal hydride and/or alkaline-earth metal hydride, metallic aluminium and H2, with in the range of from 0.5 to 20 mol % of Ti(OCH3)4, based on the moles of Al in the prepared Ti-doped alkali metal and/or alkaline-earth metal aluminium hydride.

Abstract: Method for reducing the segregated seams of a steel which has high mechanical strength and high wear resistance and whose composition comprises by weight: 0.30%?C?1.42%; 0.05%?Si?1.5%; Mn?1.95%; Ni?2.9%; 1.1%?Cr?7.9%; 0.61%?Mo?4.4%; optionally V?1.45%, Nb?1.45%, Ta?1.45% and V+Nb/2+Ta/4?1.45%; less than 0.1% of boron, less than 0.19% of (S+Se/2+Te/4), less than 0.01% of calcium, less than 0.5% of rare earths, less than 1% of aluminum, less than 1% of copper; the balance being iron and impurities resulting from the production operation. The composition further complies with: 800?D?1150 with D=540(C)0.25+245(Mo+3V+1.5Nb+0.75Ta)0.30+125Cr0.20+15.8Mn+7.4Ni+18Si. According to the method, the molybdenum is completely or partially replaced with double the proportion of tungsten so that W>0.21%, and Ti, Zr, C are adjusted so that, after adjustment, Ti+Zr/2?0.2W, (Ti+Zr/2)×C?0.07, Ti+Zr/2?1.49% and D is unchanged at approximately 5%. Steel obtained and method for producing a steel workpiece.

Abstract: A method of producing metals and alloys, the method comprising heating raw materials comprising at least one metal oxide, and agglomerates comprising a carbonaceous reducing agent and a cured binder to effect reduction of the metal oxide to the metal, wherein each agglomerate has at least one molded open channel, and an apparent density not greater than 99% of the apparent density of an identical agglomerate except without the channel.

Abstract: The invention includes solder materials having low concentrations of alpha particle emitters, and includes methods of purification of materials to reduce a concentration of alpha particle emitters within the materials. The invention includes methods of reducing alpha particle flux in various lead-containing and lead-free materials through purification of the materials. The invention also includes methods of estimating the fractionation of a low concentration of one or more alpha particle emitters during purification of a material.

Abstract: Methods for preparing nc-Ge/GeO2 composites by under reductive thermal processing conditions are described. Also described are methods of preparing freestanding nc-Ge via release from the nc-Ge/GeO2 composites.

Abstract: A process and an apparatus for producing sponge iron from iron-oxide-containing material in lump form by direct reduction in a reduction shaft using a reducing gas, wherein the entire reducing gas is introduced by means of a number of reducing gas distribution ducts in a star-like arrangement or arranged parallel to one another, preferably into the lower quarter of the reduction shaft, and evenly distributed over the entire cross-section of the reduction shaft.

Abstract: A method of alleviating dust in the early stages of metal ore processing, such as copper ore, through mining the ore through concentration involves spraying and wetting crushed ore rock and ground particles and dust at least several of a series of locations with a dust suppressant containing major amounts of water plus minor amounts of an additive combination of glycerol and a selected non-ionic surfactant, and passing the wetted particles and dust to a metal concentrator where the additive combination does not interfere with metal concentration yield.

Abstract: A method for preparing a redox flow battery electrolyte is provided. In some embodiments, the method includes the processing of raw materials containing sources of chromium ions and/or iron ions. The method further comprises the removal of impurities such as metal ions from those raw materials. In some embodiments, a reductant may be used to remove metal impurities from an aqueous electrolyte containing chromium ions and/or nickel ions. In some embodiments, the reductant is an amalgam. In some embodiments, the reductant is a zinc amalgam. Also provided is a method for removing ionic impurities from an aqueous acid solution. Further provided a redox flow battery comprising at least one electrolyte prepared from the above-identified methods.

Abstract: The Razor Process™ is a unique pyrometallurgical lead refining process. Benefits from the Razor process™ include: lower energy costs; improved working environment; reduced recycling costs; increased refining productivity; reduced cycle time and labor requirements; and production of secondary recyclable products, therefore yielding unique and immediate benefits.

Abstract: It is an object of the present invention to make it possible to recover and recycle the rare metals such as gallium and indium safely from the III-V group compound semiconductors. A method for recovering the metals according to the present invention is characterized by recovering at least one metal selected from the group comprising gallium, indium and aluminum from the III-V group compound semiconductors or the semiconducting materials of them containing at least one element selected from the group comprising arsenic, antimony and selenium, and comprising the step of adsorbing the arsenic, antimony and selenium selectively to an adsorbent containing the rare-earth metal compound with the use of the adsorbent.

Abstract: The invention relates to a process for recycling fuel cell components containing fluorine-containing and precious metal-containing constituents: in this process, the fluorine-containing constituents are separated off from the precious metal-containing constituents by treatment with a medium present in the supercritical state. Preference is given to using water as supercritical medium. After the fluorine-containing constituents have been separated off, the precious metal-containing residues can be recovered in a recycling process without harmful fluorine or hydrogen fluoride emissions. The fluorine-containing constituents can likewise be recovered. The process is used in the recovery of precious metals and/or fluorine-containing constituents from membrane fuel cells, electrolysis cells, batteries, sensors and other electrochemical devices.

Abstract: Dried copper concentrate is introduced to a smelter/converter that utilizes oxygen enrichment in the smelter/convert process. The copper concentrate was previously dried in a gas suspension or fluid bed dryer by contact with nitrogen gas that was a byproduct from the oxygen plants utilized to support the smelter.

Abstract: The present invention relates generally to a metallic alloy composed of Titanium and Tungsten that together form an alloy having a Coefficient of Thermal Expansion (CTE), wherein the content of the respective constituents can be adjusted so that the alloy material can be nearly perfectly matched to that of a commonly used semiconductor and ceramic materials. Moreover, alloys of Titanium-Tungsten have excellent electrical and thermal conductivities making them ideal material choices for many electrical, photonic, thermoelectric, MMIC, NEMS, nanotechnology, power electronics, MEMS, and packaging applications. The present invention describes a method for designing the TiW alloy so as to nearly perfectly match the coefficient of thermal expansion of a large number of different types of commonly used semiconductor and ceramic materials.

Abstract: The present invention relates to tailored materials, particularly metals and alloys, and methods of making such materials. The new compositions of matter exhibit long-range ordering and unique electronic character.

Abstract: A method for recovering valuable metals, which include at least one M element selected from the group consisting of Mo, Ni and Co, and V, in the form of iron-based alloys from a waste containing the valuable metals, comprising the steps of (a) roasting the waste to form a roasted ore containing oxides of the valuable metals; (b-1) heating the roasted ore together with an iron source and a flux, to form an iron-based alloy melt; (b-2) adding a reducing agent having higher affinity for oxygen than V at a reduction temperature to the melt, thereby reducing the oxides of the valuable metals to form an Fe-M-V alloy melt; (c) oxidizing substantially only V in the Fe-M-V alloy melt to form a V-oxide-containing slag and an Fe-M alloy melt; and (d) separating the V-oxide-containing slag from the Fe-M alloy melt.

Abstract: An object of the present invention is to provide an industrially excellent method for removing lead that is high in removal effect of lead, capable of implementing the removal even in small facilities and of suppressing capital investment cost. A material to be treated selected from the group consisting of a pure metal and an alloy is heated to obtain a melt. The melt is contacted with at least one of a metal halide and a metal oxyhalide to remove lead in the material to be treated.

Abstract: The present invention provides a novel separation reagent capable of obtaining a high extraction % of rhodium in a chlorine-based acid solution, which has never existed heretofore, and a method for separating and recovering a platinum group metal using the same. An organic phase composed of an amide-containing tertiary amine separation reagent represented by the structural formula shown below is brought into contact with an acid solution containing a platinum group metal, thereby extracting rhodium, platinum and palladium with the organic phase.

Abstract: An improved method for processing of nickel-bearing ores, laterite ores, saprolite and limonite ores, oxidic and sulfide ores, metallurgical wastes, and other metal-bearing materials, to recover the valuable minerals contained therein, comprising comminuting ore to a desired size; leaching the ore at about 70 C to 130 C for about 30 minutes to 4 hours with nitric acid, raising the temperature of the solution to form a liquid/solid residue in which nickel, cobalt and magnesium values are in solution, and iron, manganese, and aluminum are solid residues in oxide form; conducting a liquid-solid separation and removing the solids; and recovering the nickel, cobalt, and manganese from the liquid-metal concentrate. The leachate is recovered and the nitric acid from the leachate is recycled.

Abstract: A process to prepare elemental iron by contacting an iron ore feed with a reducing gas at a pressure of between 1 and 10 bar to obtain iron and an off-gas includes preparing the reducing gas by performing the following steps: (a) partially oxidizing a mixture comprising a solid or liquid carbonaceous fuel and oxygen at a pressure of between 10 and 80 bar, thereby obtaining a gas comprising H2 and CO; (b) removing CO2 and H2S from the gas obtained in step (a) to obtain an intermediate gas comprising H2 and CO; (c) supplying the intermediate gas obtained in step (b) to a H2-selective membrane to obtain a H2-rich permeate gas and a CO-rich retentate; and (d) heating H2-rich permeate to obtain a heated H2-rich permeate as the reducing gas.

Abstract: A system for combusting carbon-containing fuel includes a reactor 10 for simultaneously supporting oxidation of the fuel and conversion of CO2 within the reactor. A metal oxide or metal is input to the reactor to convert the CO2 to a mineralized CO2 product. A cold trap 44 is provided for capturing exhaust gases from the reactor and returning condensate to the reactor, and a gas pump 50 maintains a desired vacuum or pressure within the reactor and the cold trap. Combustion products may be recycled to increase their energy value.

Abstract: A hearth furnace 10 for producing metallic iron material has a furnace housing 11 with a drying/preheat zone 12 capable of providing a drying/preheat atmosphere for reducible material, a conversion zone 13 capable of providing a reducing atmosphere for reducible material, a fusion zone 14 capable of providing an atmosphere to at least partially reduced metallic iron material, and optionally a cooling zone 15 capable of providing a cooling atmosphere for reduced material containing metallic iron material. A hearth 20 is movable within the furnace housing 11 in a direction through the drying/preheat zone 12, then the conversion zone 13, then the fusion zone 14, and then the cooling zone 15.

Abstract: A nickel powder exhibits superior oxidation behavior, reduction behavior and sintering behavior in a production process for a multilayer ceramic capacitor and is suitable for the capacitor; a production method therefor is also provided. The nickel powder, which may be used as a raw material, is treated with a sulfur-containing compound, and the sulfur-containing compound is coated on the surface thereof, or alternatively, a nickel-sulfur compound layer is formed on the surface thereof.

Abstract: Each of the metal nano-particles present in a dispersion, which comprises at least one metal selected from the group consisting of precious metals and transition metals or an alloy of at least two metals selected from the foregoing metals, comprises a metal particle in which an organic metal compound of a fatty acid and/or an amine-metal complex is adhered to the periphery of the metal particle. This organic metal compound and the amine-metal complex are admixed together in a solvent and then the resulting mixture is subjected to a reducing treatment to thus form a dispersion containing metal nano-particles in a concentration of not less than 5% by mass and not more than 90% by mass. The resulting dispersion is applied onto the surface of a base material, followed by drying the applied layer of the dispersion and then firing the dried layer of the dispersion at a low temperature to thus form a thin metallic wire or a metal film having conductivity.

Abstract: According to one embodiment of the invention, there is provided a lead-free solder including an alloy rolled into a shape of sheet. The alloy includes: tin; from 10 wt % to less than 25 wt % of silver; and from 3 wt % to 5 wt % of copper. The alloy is free from lead.

Abstract: The purpose of the present invention is to separate excess coppers leached out in a lead-free solder bath and recover tin with high efficiency. An element X for forming a (CuX)6Sn5 compound between copper and tin in molten lead-free solders is added to separate out a (CuX)6Sn5 compound. Tin is recovered by binding the (CuX)6Sn5 compound by passing thereof through a multi-perforated plate, further generating swirling currents to precipitate and separate the bound (CuX)6Sn5 compounds and removing thereof.

Abstract: A method of separation and/or recovery of a precious metal from a solution containing said precious metal in ionic form, optionally in the presence of impurities, including the step of contacting a solution containing said precious metal in ionic form with a conducting polymer. The method is generally applicable to precious metals including platinum (Pt), palladium (Pd) and more particularly gold (Au). The ionic species may be anionic (for example [AuCl4]?) or cationic. The polymer may be for example, a polypyrrole or polythiophene, optionally doped and are preferably in a high surface area form eg. coated onto cloth or RVC or in self supporting colloidal form. The polymer may also contain species to give further functionality, eg magnetic or heat sensitive species.

Abstract: Magnesium-copper compositions are used for the evaporation of magnesium and container up to 43.34% by weight magnesium.

Abstract: A method of using scrap rubber and other scrap materials, such as tires or parts or pieces of tires, to manufacture or melt steel and other metals in a furnace is disclosed. The scrap rubber may be used as a carbon source for the manufacture of steel and other metals, and may be used as an energy source to melt the scrap metal used to make the steel and other metals. The net benefit of this method includes reducing the amount of scrap rubber, such as tires, to be sent to a waste disposal facility or landfill, thereby improving the environment. In addition, by increasing the use of scrap rubber as a source of energy for steel or metal production, less energy is required from other sources.

Abstract: The invention relates to a method for obtaining valuable products using red mud, which accumulates during the manufacture of aluminum by the Bayer method. The method according to the invention comprises the steps: a) reduction of at least one part of the iron(III) oxide and/or iron(III) hydroxide using at least one reductant that contains at least one hydrocarbon; and b) separation of at least one solid phase of the reaction mixture from at least one liquid and/or gaseous phase, the solid and/or liquid and/or gaseous phase comprising at least one valuable product that at least contains magnetite and the reductant comprising methane and/or natural gas and/or ethanol and/or carbon.

Abstract: The invention relates to a process for recovering valuable metals from a superalloy which has the steps of digesting the superalloy in a salt melt. The salt melt contains 60-95% by weight of NaOH and 5-40% by weight of Na2SO4.

Abstract: A method for producing metal oxide from a metal salt selected from nickel hydroxide, cobalt hydroxide, mixed nickel-cobalt hydroxide, nickel carbonate, cobalt carbonate, mixed nickel-cobalt carbonate and combinations thereof includes providing a mixture of the metal salt, mixing the metal salt with a binder selected from the group consisting of inorganic binder, organic binder and combinations thereof, forming the mixture into agglomerates, and calcining the agglomerates to produce metal oxide.

Abstract: A process for generating energy comprises process comprises exothermically reacting Mg with SiO2 to yield at least Mg2Si and Si; b)reacting the Mg2Si to yield at least lower silanes, and at least one magnesium product; c) generating at least higher silanes from at least a portion of the lower silanes; d) combusting the higher silanes and the Si to yield at least one silicon product.

Abstract: A hearth furnace 10 for producing metallic iron material has a furnace housing 11 having a drying/preheat zone 12, a conversion zone 13, a fusion zone 14, and optionally a cooling zone 15, the conversion zone 13 is between the drying/preheat zone 12 and the fusion zone 14. A moving hearth 20 is positioned within the furnace housing 11. A hood or separation barrier 30 within at least a portion of the conversion zone 13, fusion zone 14 or both separates the fusion zone 14 into an upper region and a lower region with the lower region adjacent the hearth 20 and the upper region adjacent the lower region and spaced from the hearth 20. An injector introduces a gaseous reductant into the lower region adjacent the hearth 20. A combustion region may be formed above the hood or separation barrier.

Abstract: A process for reducing iron ore particles in a moving bed reduction reactor comprising an upper reduction zone and a lower discharge zone, wherein the coke oven gas, preferably forming all the make-up for the reducing gas circulating through and reacting in said reduction zone, is first fed to said discharge (cooling) zone and thereafter said coke oven gas, conditioned by the DRI in the lower zone, is withdrawn from the reactor and fed preferably into the recycled reducing gas for injection into the reduction zone of the reactor. Heavy hydrocarbons and other components of coke oven gas which may otherwise cause fouling, corrosion, or deposits in the direct reduction plant are removed from coke oven gas by catalytic and/or adsorptive action of the DRI present in said lower zone, before being externally transferred to the reduction zone of the reduction reactor.

Abstract: A method of making a cobalt-boron alloy includes contacting an aqueous suspension of an oxide of cobalt, particularly a highly crystalline cobalt oxide, with a borohydride such as sodium borohydride. The resulting alloy may be used as a catalyst to produce gaseous hydrogen by hydrolysis of aqueous sodium borohydride.

Abstract: A carbothermic process for producing an aluminium carbide containing mass by injecting carbon and alumina into molten aluminium superheated above 1400° C. The carbon reacts with molten aluminium to produce an aluminium carbide and alumina mass. The mass can be heated in the range of 1700° C. to 2000° C. to produce aluminium metal and carbon monoxide.

Abstract: A method and apparatus for conducting a metallurgical process. In one form, iron oxides in the form of mill scale is placed in a container and subjected to heat thereby largely reducing the mill scale and largely converting it to metallic iron that can then be used in steel making processes, such as electric arc furnaces and the like. In one form, the container prevents volatile gases (such as gases given off when oily mill scale is heated) for a sufficient time so that the volatile gases heated to a high enough temperature to maximize pyrolysis and decomposition. In one form, vents are provided in the containers that are aligned with collection vents in the heating furnace so that any volatile gases may be easily removed without loss of large quantities of heat.

Abstract: A process for producing a metal from the corresponding metal halide by reaction of the metal halide at elevated temperature in a reactor comprising a fluidised bed, the fluidised bed comprising seed particles of an inert material that has a melting point higher than that of the metal.

Abstract: The present invention relates generally to a process and chemical composition for the removal of adherent niobium-rich second-phase particles (SPPs) from pickled niobium-containing zirconium alloys which includes applying to the alloy surface a chemical composition comprising alkaline hydrogen peroxide; an alkali metal meta-silicate; and a magnesium salt.

Abstract: A method for recovering a catalyst for a fuel cell includes a collection step in which a catalyst is collected by attracting, using a magnetic force, a magnetic material contained in at least one of the catalyst and a carrier on which the catalyst is supported. A system for recovering a catalyst for a fuel cell includes a collection device that attracts, using a magnetic force, a magnetic material contained in at least one of a catalyst and a carrier on which the catalyst is supported.

Abstract: Methods and systems for preparing catalyst, such as chromium catalysts, are provided. The valence of at least a portion of the catalyst sent to an activator is changed from Cr(III) to Cr(VI). The catalyst is prepared or activated continuously using a fluidization bed catalyst activator.

Abstract: A method of forming metal parts or components from strip stock or roll stock without yielding is accomplished by first placing the part/components into fixtures that hold the stock in a non-yielding position therein. The fixture and metal stock parts are placed in a liquid, gas, or pack carburizing heat treatment process. Once the carburization process is complete, the part is released from the fixture with little or no spring back, maintaining the shape it was held in while in the fixture, resisting returning to its original shape, and optionally imparting spring-like qualities not associated with the stock before treatment.

Abstract: In order to provide a method for supplying a cover gas which has sufficient preventive effects of oxidation-combustion and prevents cost-increase by containing a necessary and sufficient amount of fluoroketone in the cover gas which is supplied in a melting furnace of magnesium, the present invention provides a method for supplying a cover gas containing fluoroketone in a melt furnace to prevent oxidation and combustion of a melt of magnesium in the melt furnace, wherein the moisture concentration of gas in the melt furnace is measured, and the concentration of fluoroketone in the cover gas is adjusted to a range from 1/50 to 1/5 relative to the moisture concentration.

Abstract: A recycling method of wastes of an electrical appliance containing an article having a circuit soldered with parts soldered with a lead free solder. The method includes discriminating a first article having a circuit soldered with lead free parts from a second article having a circuit soldered with lead containing parts; recovering, grinding and melting each of the first and second articles to separate materials of the first article and materials of the second article; recycling reusable valuables contained in the materials of the first article and second article; and shredding a portion of the first and second article not containing the reusable valuables and burying/treating the portion at a stabilizing dumping ground or a controlled dumping ground for disposal.

Abstract: The invention is directed to a process to prepare elemental iron by contacting an iron ore feed with a reducing gas to obtain iron and an off-gas. The reducing gas is prepared by performing the following steps (a) partially oxidizing a mixture comprising a sulphur containing solid carbonaceous fuel and gaseous CO2 as carrier medium with oxygen, by supplying an oxygen containing gas and the solid carbonaceous fuel to a burner, thereby obtaining a gas comprising H2, CO, CO2 and H2S; (b) removing CO2 and H2S from the gas obtained in step (a) to obtain the reducing gas comprising H2 and CO and a first stream comprising CO2 and H2S; (c) reducing the content of H2S in the first stream comprising CO2 and H2S obtained in step (b) in a liquid redox type process and (d) recycling at least part of the CO2 obtained in step (c) to step (a).

Abstract: A method of manufacturing high purity hafnium is provided and includes the steps of making aqueous solution of chloride of hafnium, thereafter removing zirconium therefrom via solvent extraction, performing neutralization treatment to obtain hafnium oxide, further performing chlorination to obtain hafnium chloride, obtaining hafnium sponge via reducing said hafnium chloride, and performing electron beam melting to the hafnium sponge in order to obtain a hafnium ingot, as well as a high purity hafnium material obtained thereby and a target and thin film formed from such material. The present invention relates to a high purity hafnium material with reduced zirconium content contained in the hafnium, a target and thin film formed from such material, and the manufacturing method thereof, and provides efficient and stable manufacturing technology, a high purity hafnium material obtained according to such manufacturing technology, and a target and high purity hafnium thin film formed from such material.

Abstract: The invention relates to a method for treating solids-containing process gas in a suspension smelting furnace, comprising directing the process gas from the reaction shaft of the suspension smelting furnace to a lower furnace and, further, through a raised shaft to a waste heat boiler to cool the process gas, whereby, through one or more gas nozzles placed on the lower furnace top wall, oxidizing gas is fed into the process gas flowing in the lower furnace, whereby the amount of oxidizing gas is adjusted during the process so that the amount of sulphides contained in the solid matter of the process gas that is directed to the waste heat boiler is minimized. The invention also relates to the equipment.

Abstract: A process of producing a metal from the corresponding metal halide by reaction of the metal halide with a reducing agent to form the metal and a halide of the reducing agent, the reaction taking place at elevated temperature and at atmospheric pressure in a reactor comprising a fluidised bed of seed particles of the metal, which process comprises: injecting into the reactor an inert gas at a rate and in an amount effective to form a fluidised bed of the seed particles and to ensure that unreacted reductant and the halide of the reducing agent do not condense in the reactor under the prevailing conditions of temperature and pressure; maintaining the maximum temperature in the reactor below the melting point of the metal; and delivering the metal halide and reducing agent into the fluidised bed in a manner that favours formation of the metal on the seed particles over formation of the metal by homogeneous gas phase reaction between the metal halide and reducing agent.

Abstract: A liquid for the preparation of powder mixtures on the basis of hard metals, comprising water and an inhibitor, wherein the inhibitor is in the form of at least one of the following materials: polyvinyllactam or wax emulsion, or the inhibitor is in the form of at least one of the following materials: carboxylic acid, amines or their derivatives.

Abstract: A process and apparatus for regeneration of acid and metal from spent acid liquors includes the steps of, optionally, concentrating (110) the liquor to a concentrated liquor or solid, pyrohydrolysing (114) to regenerate the acid and form metal oxide pellets, and reducing the oxide to metal in a two stage reduction reactor (116, 118) using a partially combusted fuel as reducing agent. Also disclosed is a two-stage reduction process and reactor for production of direct reduced iron (DRI) from iron oxide ores or wastes, including a first stage (416) in which the oxide feed is contacted with a fuel and a sub-stoichiometric amount of an oxygen source to produce a lower oxidation state oxide, and a second stage (418) in which the lower oxidation stage oxide is contacted with off-gases from the first stage to produce iron metal.