Producing Or Treating Free Metal Patents (Class 75/392)
  • Publication number: 20090095133
    Abstract: The present invention provides methods and devices for the safe and cost efficient storage, transport and disposal of mercury. A puncture resistant container is provided having an interior element comprising a mercury sequestering substance to permit the safe storage, transport or disposal of mercury containing light bulbs and to capture mercury vapor by chemical sequestration in the event that the bulb breaks during storage, transport or disposal. The mercury sequestering element may be removable to facilitate further processing and reclamation of sequestered mercury using various methods known in the art.
    Type: Application
    Filed: October 10, 2008
    Publication date: April 16, 2009
    Inventor: Edward T. Maggio
  • Patent number: 7491348
    Abstract: The present invention relates to new compositions of matter, particularly metals and alloys, and methods of making such compositions. The new compositions of matter exhibit long-range ordering and unique electronic character.
    Type: Grant
    Filed: April 13, 2004
    Date of Patent: February 17, 2009
    Assignee: Electromagnetics Corporation
    Inventor: Christopher J. Nagel
  • Publication number: 20090013826
    Abstract: The present invention provides an improved alkali metal dispenser which is pure and free of contaminant gases, and provides for controlled releasing, delivery and recycling of the alkali metal in multiple stages in a controlled manner. The present invention also provides an alkali metal pump or getter.
    Type: Application
    Filed: May 15, 2008
    Publication date: January 15, 2009
    Inventors: Sterling Eduardo McBride, Steven Alan Lipp, Joey John Michalchuk, Dana Z. Anderson, William Frederick Holmgren, Matthew B. Squires
  • Publication number: 20090014694
    Abstract: The present invention is directed at providing fine nickel particles with a sharp particle size distribution, and providing an electroconductive paste using the nickel particles. In order to obtain the nickel particles capable of achieving the purpose, a method for producing the nickel particle by elevating a temperature of the reactive solution containing a nickel salt and a polyol to a reduction temperature, and reducing the nickel salt in the reactive solution which is characterized in that the reactive solution is prepared to contain a carboxylic acid or an amine having a carboxyl functional group and/or an amino functional group, and a precious metal catalyst before the solution temperature is elevated to the reduction temperature. Nickel particles obtained with the production method have an average image analytical particle diameter of 1 nm to 300 nm.
    Type: Application
    Filed: June 30, 2006
    Publication date: January 15, 2009
    Applicant: Mitsui Mining & Smelting Co., Ltd
    Inventors: Takashi Mukuno, Katsuhiko Yoshimaru
  • Publication number: 20090007728
    Abstract: In a method for producing an alloy containing a metal of a low melting point, a low boiling point and a high vapor pressure such as Mg, Ca, Li, Zn, Mn, Sr or the like, a helium containing gas is used as an atmosphere gas for the melting. As a result, the alloy containing the above metal can be produced as an alloy having a targeted chemical composition precisely and safely at a low cost without causing the risk of firing, contamination or the like by active metal fine powder being vaporized. Furthermore, by using the helium containing gas as the atmosphere gas, the quench-solidification of the molten metal can be conducted due to a high thermal conductivity inherent to the helium gas, so that a special alloy can be produced even by the usual melting apparatus.
    Type: Application
    Filed: March 2, 2006
    Publication date: January 8, 2009
    Applicants: JAPAN METALS AND CHEMICALS CO., LTD, National Institute of Advanced Industrial Science and Technology
    Inventors: Etsuo Akiba, Hirotoshi Enoki, Naoyoshi Terashita, Shigeru Tsunokake
  • Publication number: 20080264207
    Abstract: In the case of a device for the melting and/or crystallizing of non-ferrous metals, especially of silicon, provision is made, for improving the quality of the crystallized and block-shaped non-ferrous metal, for there to be arranged around a container for receiving the non-ferrous metal at least one controllable cooling element for the active removal of heat from the non-ferrous metal.
    Type: Application
    Filed: March 11, 2006
    Publication date: October 30, 2008
    Inventors: Armin Muller, Michael Ghosh, Jens Seidel, Bert Geyer
  • Publication number: 20080245187
    Abstract: A man made method, utilizing particles bombardment technique, is used to produce Gold and Platinum. The particles bombardment technique uses particle accelerator to accelerate Lithium particles to high speed. These high speed Lithium particles contain high energy. These high energy Lithium particles are used to bombard Osmium element. Then elements Lithium and Osmium undergo cold fusion process that they are combined to produce element Gold. By the same method, Helium particles are accelerated by particle accelerator to high speed. These high speed Helium particles contain high energy. These high energy Helium particles are used to bombard Osmium element. Then elements Helium and Osmium undergo cold fusion process that they are combined to produce element Platinum.
    Type: Application
    Filed: April 4, 2007
    Publication date: October 9, 2008
    Inventor: Kuai-Teng Hsu
  • Publication number: 20080236337
    Abstract: The present invention provides a method for recovering rhodium sponge in high yield from ammonium hexachloro rhodate solution. The method comprises adding formic acid to ammonium hexachloro rhodate solution to reduce the rhodate, recovering reduced rhodium as rhodium black, and calcining the rhodium black under hydrogen atmosphere without water-washing to obtain rhodium sponge.
    Type: Application
    Filed: February 1, 2008
    Publication date: October 2, 2008
    Inventors: Shoujirou Usui, Yoshio Ito
  • Publication number: 20080236336
    Abstract: A method of dispersing flux in molten metal includes providing a source of flux powder and a source of gas. An impeller is disposed on an end of a shaft inside the impeller chamber of a base made of heat resistant material. The base is submerged in the molten metal and includes a molten metal inlet opening into the impeller chamber and a molten metal discharge passageway extending from the impeller chamber to an exterior of the base. Molten metal is drawn through the inlet opening into the impeller chamber by rotation of the impeller in the impeller chamber. The molten metal is moved out of the impeller chamber through the discharge passageway by the rotation of the impeller. A discharge stream of molten metal travels through the discharge passageway into the molten metal exterior to the base. The gas flows from the gas source into a refractory flux conduit. The flux conduit extends from outside the molten metal into fluid communication with the discharge passageway.
    Type: Application
    Filed: March 27, 2007
    Publication date: October 2, 2008
    Inventors: Bruno H. Thut, Thomas Moore, David L. Baldwin
  • Publication number: 20080229881
    Abstract: A direct reduction process for a solid metalliferous material having a particle size distribution that at least in part contains micron sized particles includes supplying the metalliferous material, a solid carbonaceous material, an oxygen-containing gas, and a fluidizing gas into a fluidized bed in a vessel and maintaining the fluidized bed in the vessel, at least partially reducing metalliferous material in the vessel, and discharging a product stream that comprises the partially reduced metalliferous material from the vessel. The process includes (a) establishing and maintaining a carbon-rich zone within the fluidized bed; (b) passing metalliferous material, including metallized material (which term includes partially metallized material), through the carbon-rich zone; and (c) injecting the oxygen-containing gas into the carbon-rich zone and oxidizing metallized material, solid carbonaceous material and other oxidizable solids and gases and causing controlled agglomeration of particles.
    Type: Application
    Filed: May 20, 2005
    Publication date: September 25, 2008
    Applicant: OUTOKUMPU TECHNOLOGY OYJ
    Inventors: Andreas Orth, Heinz Eichberger, Donald Keith Philp, Jeantine Van Gemund, Rod Dry
  • Publication number: 20080226528
    Abstract: The product of a molten alkali metal metalate phase separation can be processed into a purified metal from a metal source. Metal sources include native ores, recycled metal, metal alloys, impure metal stock, recycle materials, etc. The method uses a molten alkali metal metalate as a process medium or solvent in purifying or extracting high value metal or metal oxides from metal sources. Vitrification methods using the silicate glass separation phase can be prepared as is or can be prepared with a particulate phase distributed throughout the silica glass phase and encapsulated and fixed within the continuous glass phase. Tungsten metal can be obtained from an alkali metal tungstate. A typically finely divided tungsten metal powder can be obtained from a variety of tungsten sources including recycled tungsten scrap, tungsten carbide scrap, low grade tungsten ore typically comprising tungsten oxide or other form of tungsten in a variety of oxidation states.
    Type: Application
    Filed: December 7, 2007
    Publication date: September 18, 2008
    Inventor: RODNEY KIETH WILLIAMS
  • Publication number: 20080216605
    Abstract: The purpose of the present invention is to separate excess coppers leached out in a lead-free solder bath and recover tin with high efficiency. An element X for forming a (CuX)6Sn5 compound between copper and tin in molten lead-free solders is added to separate out a (CuX)6Sn5 compound. Tin is recovered by binding the (CuX)6Sn5 compound by passing thereof through a multi-perforated plate, further generating swirling currents to precipitate and separate the bound (CuX)6Sn5 compounds and removing thereof.
    Type: Application
    Filed: July 25, 2006
    Publication date: September 11, 2008
    Applicant: NIHON SUPERIOR SHA CO., LTD.
    Inventor: Tetsuro Nishimura
  • Publication number: 20080196549
    Abstract: A direct reduction process for a metalliferous material includes supplying the metalliferous material, a solid carbonaceous material, an oxygen-containing gas, and a fluidizing gas into a fluidized bed in a vessel and maintaining the fluidized bed in the vessel, at least partially reducing metalliferous material in the vessel, and discharging a product stream that includes the partially reduced metalliferous material from the vessel. The process comprises (a) reducing the metalliferous material in a solid state in a metal-rich zone in the vessel; (b) injecting the oxygen-containing gas into a carbon-rich zone in the vessel with a downward flow in a range of ±40° to the vertical and generating heat by reactions between oxygen and the metalliferous material (including metallized material), the solid carbonaceous material and other oxidizable solids and gases in the fluidized bed, and (c) transferring heat from the carbon-rich zone to the metal-rich zone by movement of solids within the vessel.
    Type: Application
    Filed: May 20, 2005
    Publication date: August 21, 2008
    Applicant: Outokumpu Technology OYJ
    Inventors: Andreas Orth, Heinz Eichberger, Donald Keith Philp, Jeantine Van Gemund, Rod Dry
  • Publication number: 20080184847
    Abstract: A method for processing ore using carbonates so as to minimize the production of acidic wastes. The method includes adding the carbonates to the ore and after the carbonates have been added to the ore, substantially jointly grinding the ore and the carbonates to produce a treated ore mixture. Substantially jointly grinding the ore and the carbonates substantially mixes and homogenizes the ore and the carbonates so that acids subsequently created within the treated ore mixture are substantially neutralized within the treated ore mixture by the carbonates.
    Type: Application
    Filed: August 17, 2006
    Publication date: August 7, 2008
    Inventors: Gilles Fiset, Edmond St-Jean
  • Publication number: 20080184848
    Abstract: Systems and corresponding methods are described herein that provide an effective inert blanket over a metal surface (hot solid (charge) metal or molten metal) in a container such as an induction furnace. The system includes a container of metal and a system configured to delivery biphasic inert cryogen toward the metal. The delivery system may include a lance disposed at the top of the container. The lance has a hood that directs both a flow of liquid cryogen and a flow of vaporous gas toward the metal surface. The liquid cryogen contacts the metal surface, generating a volume of expanding gas over the metal surface. The vaporous cryogen creates a reinforcing vapor that slows the expansion rate of the expanding gas, localizing the expanding gas over the metal surface.
    Type: Application
    Filed: July 27, 2007
    Publication date: August 7, 2008
    Inventor: Terence D. La Sorda
  • Publication number: 20080173543
    Abstract: A method of forming Heusler or Heusler-like alloys of formula X2YZ or XYZ comprises providing a crucible comprised of at least one metal oxide material thermodynamically stable to molten transition metals; supplying predetermined amounts of constituent elements or master alloy materials of the alloy to the crucible; and melting the constituent elements or master alloy materials under vacuum or a partial pressure of an inert gas to form alloys containing less than about 50 ppm oxygen. Crack-free alloys are formed by casting the alloys in a mold utilizing a multi-stage stress-relieving, heat-assisted casting process. Also disclosed are crack-free Heusler and Heusler-like alloys of formula X2YZ or XYZ containing less than about 50 ppm oxygen and deposition sources, e.g., sputtering targets, fabricated therefrom.
    Type: Application
    Filed: January 17, 2008
    Publication date: July 24, 2008
    Applicant: HERAEUS INC.
    Inventor: Abdelouahab ZIANI
  • Publication number: 20080168864
    Abstract: A method for making lithium-containing magnesium alloy is provided. The method includes carrying out a diffusive electrolysis in an electrolyte, essentially including lithium chloride and potassium chloride, by using a graphite material as an anode and a material of a magnesium or magnesium alloy as a cathode. Therefore, the lithium is diffused into the cathode to form a raw material, lithium-magnesium master alloy, with higher weight percentage of lithium. Further, the lithium-magnesium master alloy is smelted and cast into a lithium-containing magnesium alloy with a desired lithium content.
    Type: Application
    Filed: January 15, 2007
    Publication date: July 17, 2008
    Inventors: Te-Chang Tsai, Jun-Yen Uan
  • Publication number: 20080166571
    Abstract: A surface treating method for metallizing the surface of a polymer containing silicon by the use of a non-expensive material and a method for metallizing the surface of or forming a pattern of a metal layer such as a wiring on the surface of a substrate comprising an arbitrary material, or a method for producing fine particles of a specific transition metal are provided. The method for treating the surface of a silicon-containing polymer or a method for preparing fine transition metal particles involves contacting an organosilicon compound with a solid, a solution or a suspension of a specific transition metal salt, to reduce and precipitate the transition metal and thereby precipitate fine particles of the transition metal on the surface of said organosilicon compound or in the organosilicon compound.
    Type: Application
    Filed: November 22, 2005
    Publication date: July 10, 2008
    Applicant: Mitsui Chemicals Inc.
    Inventors: Masaki Takahashi, Akiko Kitamura, Kenji Iwata, Hiroshi Watanabe, Kenichi Goto, Jun Kamada
  • Publication number: 20080156145
    Abstract: The present invention relates to a calcium-silicate based slag having a phosphorous content of less than 3 ppmw. The invention further relates to a method for producing a low phosphorous calcium-silicate based slag, where molten calcium-silicate based slag is treated with a molten ferrosilicon alloy in a vessel, whereby phosphorous in the calcium-silicate based slag is transferred to the ferrosilicon alloy, and a low phosphorous calcium-silicate to based slag is removed from the vessel.
    Type: Application
    Filed: March 3, 2008
    Publication date: July 3, 2008
    Applicant: ELKEM ASA
    Inventors: Erik ENEBAKK, Gabriella Maria TRANELL, Ragnar TRONSTAD
  • Publication number: 20080156147
    Abstract: Methods for reducing carbon contamination when melting highly reactive alloys involving providing a graphite crucible having an interior, applying at least a first protective layer to the interior of the graphite crucible, placing a highly reactive alloy into the crucible having the first protective layer, and melting the highly reactive alloy to obtain a melted alloy having reduced carbon contamination.
    Type: Application
    Filed: December 27, 2006
    Publication date: July 3, 2008
    Inventors: Thomas Joseph Kelly, Michael James Weimer, Bernard Patrick Bewlay, Michael Francis Xavier Gigliotti
  • Publication number: 20080141828
    Abstract: The invention relates to a method for processing a metal-bearing sludge in conjunction with a metal separation process. According to the invention, the sludge (13) produced in the metal separation is classified based on a predetermined property of the sludge into a better (15) and a worse (17) substance fraction, as the process is concerned, and the worse substance fraction (17) is removed from the process and the better substance fraction (15) is returned to the process.
    Type: Application
    Filed: July 22, 2004
    Publication date: June 19, 2008
    Applicant: Outokumpu Technology Oy
    Inventors: Kai Judin, Yrjo Oinonen
  • Publication number: 20080134837
    Abstract: Embodiments of a method and a system for recovering a metal, such as uranium, from a metal-containing material are disclosed. The metal-containing material is exposed to an extractant containing a liquid or supercritical-fluid solvent and an acid-base complex including an oxidizing agent and a complexing agent. Batches of the metal-containing material are moved through a series of stations while the extractant is moved through the stations in the opposite direction. After the extraction step, the metal is separated from the solvent, the complexing agent and/or other metals by exposing the extract to a stripping agent in a countercurrent stripping column. The complexing agent and the solvent exit the column and are separated from each other by reducing the pressure. The recovered complexing agent is recharged with fresh oxidizing agent and recombined with fresh or recovered solvent to form a recovered extractant, which is distributed through the extraction stations.
    Type: Application
    Filed: January 12, 2006
    Publication date: June 12, 2008
    Applicant: IDAHO RESEARCH FOUNDATION, INC.
    Inventors: Chien M. Wai, Sydney S. Koegler
  • Publication number: 20080134364
    Abstract: The invention relates to recovering metals, such as nickel and cobalt, by phytomining or phytoextracting soils rich in metals wherein the desired metal is selectively accumulated in hyperaccumulator plants by adjusting the soil pH. The metals are ultimately recovered from above-ground plant tissues at economically acceptable levels without further contaminating the metal-containing sites. The invention also relates to metal-hyperaccumulating plants.
    Type: Application
    Filed: August 29, 2007
    Publication date: June 5, 2008
    Inventors: Rufus L. Chaney, J. Scott Angle, Yin-Ming Li, Alan J.M. Baker
  • Patent number: 7217312
    Abstract: A method of recycling metallic coated scrap pieces wherein the coating layer liquidus temperature is lower than the core layer solidus temperature, such as brazing sheet scrap pieces, or metallic coated scrap pieces wherein the upper part of the melting range of the coating layer overlaps the lower part of the melting range of the core layer, by at least partially removing the coating layer from the core layer of the scrap pieces making use of a heat resistant metallurgical vessel having an opening for introducing the scrap pieces into the vessel and an exit for discharging essentially molten alloy. The vessel being rotatable around an axis of rotation.
    Type: Grant
    Filed: April 16, 2002
    Date of Patent: May 15, 2007
    Assignees: Corus Aluminium Voerde GmbH, Aleris Aluminum Koblenz GmbH
    Inventors: Jakob Boetje, Patrik Schraven
  • Patent number: 6921497
    Abstract: The present invention relates to new compositions of matter, particularly metals and alloys, and methods of making such compositions. The new compositions of matter exhibit long-range ordering and unique electronic character.
    Type: Grant
    Filed: April 12, 2002
    Date of Patent: July 26, 2005
    Assignee: Electromagnetics Corporation
    Inventor: Christopher J. Nagel
  • Patent number: 6641641
    Abstract: An object of the present invention is to provide a method for preventing concentration of a radioactive substance in a generated extraction residue in a method of producing tantalum, niobium, or a similar substance including collecting and refining a raw material containing the substances through a fluoridation process by use of a hydrofluoric acid-containing solution. The object can be attained by employing an ingredient-regulated raw material prepared from an ore or a concentrate and, as an additive, a substance insoluble to hydrofluoric acid or a mixed acid containing hydrofluoric acid as an essential component; or by increasing the amount of the extraction residue through addition of the insoluble substance to a solvent during the fluoridation process, to thereby reduce the relative radioactive substance content to an arbitrary value.
    Type: Grant
    Filed: May 7, 2002
    Date of Patent: November 4, 2003
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Yoshio Sohama, Hiromichi Isaka, Hiroyuki Watanabe
  • Publication number: 20030196517
    Abstract: The present invention provides a method of purifying polluted soil and/or burned ash containing heavy metals and/or organic compounds with a higher throughput than a conventional method. In this method, polluted soil and/or burned ash is dried by, for example, a rotary dryer so that the moisture content is 5% by mass or less, preferably 3% by mass or less, and then large lumps having a particle diameter of 10 mm or more are removed by a vibrating screen. Only an undersize portion is formed into a briquette having a volume of about 6 cm3 by a press molding machine. The briquette is charged in a rotary hearth furnace together with the large lumps, and heated in the furnace to remove or detoxify the heavy metals and organic compounds by evaporation with high efficiency.
    Type: Application
    Filed: March 26, 2003
    Publication date: October 23, 2003
    Applicant: Kabushiki Kaisha Kobe Seiko Sho(Kobe Steel, Ltd.)
    Inventors: Takao Harada, Haruyasu Michishita, Hidetoshi Tanaka, Hiroshi Tamazawa, Hiroshi Sugitatsu
  • Patent number: 6569358
    Abstract: The method of preparing the porous material incorporating ultrafine metal particles comprises the following steps: (1) preparing surface-protected ultrafine metal particles by reducing metal ions in the presence of molecules such as dodecanethiol molecules; (2) immersing a wet gel in a solution of the ultrafine metal particles, thus forming an ultrafine metal particle/wet gel composite in which the ultrafine metal particles are incorporated in the wet gel; and (3) drying the ultrafine metal particle/wet gel composite to form a porous body.
    Type: Grant
    Filed: March 20, 2002
    Date of Patent: May 27, 2003
    Assignee: National Institute of Advanced Industrial Science and Technology
    Inventors: Yutaka Tai, Koji Tajiri, Masao Watanabe, Sakae Tanemura
  • Patent number: 6565773
    Abstract: There is provided conductive paste wherein conductive fillers composed of copper micro-fibers are mixed into thermoplastic resin or thermosetting resin.
    Type: Grant
    Filed: March 28, 2001
    Date of Patent: May 20, 2003
    Assignee: Yazaki Corporation
    Inventors: Hitoshi Ushijima, Yoshinobu Akiha
  • Patent number: 6537345
    Abstract: A method for decomposition and treatment of a bond magnet, has: a decomposition process for making a bond magnet which is made by blending magnetic powder-like material with binder and being molded, contact with decomposition material which can decompose said binder, within a decomposition vessel; a removing process for removing oxygen in the decomposition vessel; and a heating process for heating the decomposition vessel in temperatures ranging from 250° C. to just under a critical temperature.
    Type: Grant
    Filed: November 4, 1999
    Date of Patent: March 25, 2003
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Takahiko Terada, Hiroshi Onishi
  • Publication number: 20030019328
    Abstract: A method of converting metal-containing compounds into a metal or metal oxide by rapidly heating the metal-containing compound to an elevated temperature to instigate conversion and holding the metal-containing compound at the elevated temperature for a time sufficient to effect formation of the metal or metal oxide is an efficient and economical method of producing metals and metal oxides.
    Type: Application
    Filed: February 22, 2001
    Publication date: January 30, 2003
    Inventors: Stephen Dunmead, Kauko Johannes Karpale, Alan W. Weimer, Karen J. Buechler, Jacob A. Johnson
  • Publication number: 20030000068
    Abstract: Method for producing a sputtering target with a lowered oxygen content by providing an alloy selected from the group consisting of NiFe, CoCrPt, CoCrPtB, CoPt, PtMn, FeAlSi, FeCo, and FeMn; adding an oxygen scavenger element to the molten alloy selected from the group consisting of Group 4A, 3B and 4B elements; melting the alloy and the oxygen scavenger; reacting the oxygen scavenger element with oxygen in the melt to reduce the oxygen content of the alloy to a level of not more than 50 ppm and achieving a residual oxygen scavenger element content of not more than 100 ppm.
    Type: Application
    Filed: August 28, 2002
    Publication date: January 2, 2003
    Applicant: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Satoru Kobayashi, Yoshihiro Sera, Norioki Ikeda, Masato Imamura, Shuji Shihara, Hiroyuki Sakai
  • Publication number: 20020121157
    Abstract: The invention relates to a process for producing metal foam and to a metal body produced using this process.
    Type: Application
    Filed: January 30, 2002
    Publication date: September 5, 2002
    Inventors: Wilfried Knott, Benno Niedermann, Manfred Recksik, Andreas Weier
  • Patent number: 6372156
    Abstract: In one aspect, the invention encompasses a method of chemically converting a first material to a second material. A first plasma and a second plasma are formed, and the first plasma is in fluid communication with the second plasma. The second plasma comprises activated hydrogen and oxygen, and is formed from a water vapor. A first material is flowed into the first plasma to at least partially ionize at least a portion of the first material. The at least partially ionized first material is flowed into the second plasma to react at least some components of the first material with at least one of the activated hydrogen and activated oxygen. Such converts at least some of the first material to a second material. In another aspect, the invention encompasses a method of forming a synthetic gas by flowing a hydrocarbon-containing material into a hybrid-plasma system.
    Type: Grant
    Filed: August 19, 1999
    Date of Patent: April 16, 2002
    Assignee: Bechtel BWXT Idaho, LLC
    Inventors: Peter C. Kong, Jon D. Grandy
  • Patent number: 6365555
    Abstract: A process for the preparation of nanostructured materials in high phase purities using cavitation is disclosed. The method comprises mixing a metal containing solution with a precipitating agent and passing the mixture into a cavitation chamber. The chamber consists of a first element to produce cavitation bubbles, and a second element that creates a pressure zone sufficient to collapse the bubbles. The process is useful for the preparation of mixed metal oxide catalysts and materials for piezoelectrics and superconductors.
    Type: Grant
    Filed: October 25, 1999
    Date of Patent: April 2, 2002
    Assignee: Worcester Polytechnic Institute
    Inventors: William R. Moser, Oleg V. Kozyuk, Josef Find, Sean Christian Emerson, Ivo M. Krausz
  • Patent number: 6332909
    Abstract: A processing apparatus capable of separating and recovering resins and metals, respectively, from an object being processed, which has resins and metals as its constituent, comprises a first gastight area (102), in which temperature and pressure are regulated so as to permit selective thermal decomposition of resins from the object (150) being processed, a second gastight area (103), which is partitioned from the first gastight area by an openable and closeable partition (105C) and in which temperature and pressure are regulated so as to permit selective vaporization of metals from the object, first recovering chamber (111) connected to the first gastight area for recovering gases produced by thermal decomposition of resins, and second recovering chamber (115) connected to the second gastight area for recovering vaporized metals.
    Type: Grant
    Filed: February 23, 1999
    Date of Patent: December 25, 2001
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Kouichi Teshima, Tomohiro Todoroki, Terunobu Hayata, Fuminobu Tezuka, Masao Koyama, Naohiko Oyasato, Tomiaki Furuya, Yoshiaki Yokoyama, Teruhisa Ogihara, Kaichiro Ogihara
  • Patent number: 6165247
    Abstract: Platinum powders and methods for producing platinum powders. The powders preferably have a small particle size, narrow size distribution and a spherical morphology. The method includes forming the particles by a spray pyrolysis technique. The invention also includes novel devices and products formed from the platinum powders.
    Type: Grant
    Filed: February 24, 1998
    Date of Patent: December 26, 2000
    Assignee: Superior MicroPowders, LLC
    Inventors: Toivo T. Kodas, Mark J. Hampden-Smith, James Caruso, Daniel J. Skamser, Quint H. Powell, Clive D. Chandler
  • Patent number: 5968229
    Abstract: A process for the purification of solutions containing metals comprising neutralization of the solution, reduction of Fe(III) present, and elimination of ingoing dissolved zinc, whereby the ingoing solution containing metals is neutralized using magnetite and/or metallic iron, that the ingoing iron (III) is reduced to iron (II) by means of an addition of metallic iron, that ingoing heavy metals are precipitated by the addition of a precipitating amount of a sulphide, whereby the metal sulphides precipitated are recovered by means of filtration, that the solution is, optionally, subjected to an ion exchange operation to transfer ingoing zinc into non-complex bound form, whereupon zinc is recovered as zinc carbonate, that iron (II) in the remaining solution is oxidized to iron (III), whereupon the solution is used as such or is further treated for increasing the metal content for the purpose intended.
    Type: Grant
    Filed: September 3, 1997
    Date of Patent: October 19, 1999
    Assignee: Kemira Kemi AB
    Inventor: Stefan Jafverstrom
  • Patent number: 5925165
    Abstract: In a method for processing solid residues from refuse incineration plants the slag is melted and heavy metals from the melt (16) are separated for reutilization. The slag is directly transferred from the refuse incineration plant into a first heating chamber (2) and melted there under oxidizing conditions. The melt (16) produced therefrom is transferred to a second heating chamber (3), in which the heavy metal compounds are reduced to their metallic form. Furthermore, additional finely divided residues, such as fly ash, boiler ash and filter dust, are introduced into the second heating chamber (3) via a hollow graphite electrode (19). The melt (16) is then passed on to a third heating chamber (4), in which the residual readily volatile metals are vaporized and the residual non-volatile metals are sedimented. The essentially heavy-metal-free melt is then cooled to form vitreous granules.
    Type: Grant
    Filed: May 22, 1996
    Date of Patent: July 20, 1999
    Assignees: Von Roll Umwelttechnik AG, Holderbank Financiere Glarus AG
    Inventors: Karl Heinz Pflugl, Norbert Kiethe, Ernst Hugentobler, Hans Ruegg, Ruedi Frey, Anton Mayer, Theo Rey, Alfred Edlinger
  • Patent number: 5902374
    Abstract: The present invention relates to a molten steel refining method for refining molten steel, the carbon content of which is not more than 0.1 weight %, by blowing oxygen gas for decarburization at a blowing speed so that a cavity, the depth of which is 150 to 400 mm, can be formed on the surface of molten steel in a straight barrel type vacuum refining apparatus in which a straight barrel type vacuum vessel having no vessel bottom and a ladle are arranged.
    Type: Grant
    Filed: March 28, 1997
    Date of Patent: May 11, 1999
    Assignee: Nippon Steel Corporation
    Inventors: Shinya Kitamura, Kimitoshi Yonezawa, Kenichiro Miyamoto, Shinji Sasakawa, Kunihiko Fujiwara
  • Patent number: 5885324
    Abstract: Synthetic Rutile is prepared from raw ilmenite ore by a method comprising activating ilmenite and subjecting it to a multi-stage countercurrent leaching process in hot hydrochloric acid.
    Type: Grant
    Filed: August 30, 1996
    Date of Patent: March 23, 1999
    Assignee: Tiomin Resources, Inc.
    Inventors: Graham F.. Balderson, Charles A. MacDonald
  • Patent number: 5882377
    Abstract: In this invention, the smelting reduction operation can be carried out in a high efficiency by charging a carbonaceous material in such an amount that total surface area is not less than 60 m.sup.2 per 1 ton of slag weight. Carbon substance finely particulating through thermal crumbling under a high-temperature atmosphere inside the vessel is used as the carbonaceous material, whereby it is possible to stably conduct the smelting reduction while controlling the scattering of the carbonaceous material, and also the erosion, particularly locally erosion of refractory in the smelting reduction furnace, which was a serious problem in the conventional technique, can considerably be decreased to largely prolong the service life of refractory.
    Type: Grant
    Filed: March 5, 1997
    Date of Patent: March 16, 1999
    Assignee: Kawasaki Steel Corporation
    Inventors: Kimiharu Aida, Shuji Takeuchi, Nagayasu Bessho, Tomomichi Terabatake, Yasuo Kishimoto, Hiroshi Nishikawa, Fumio Sudo
  • Patent number: 5868817
    Abstract: The present invention provides a process for efficiently dephosphorizing, dephosphorizing and decarbonizing, or desulfurizing, dephosphorizing and decarbonizing a hot metal in a converter. The amount of flux to be charged and the amount of bottom-blown gas are adjusted so that the bottom-blowing agitation power and the CaO/SiO.sub.2 ratio subsequent to the treatment become at least 0.1 kW/ton and from 0.7 to 2.5, respectively and the hot metal temperature at the treatment end point becomes from 1,200.degree. to 1,450.degree. C. Furthermore, the operation of the process is controlled so that the sum of a T.Fe concentration and a MnO concentration in the slag subsequent to the treatment becomes from 10 to 35% by weight by adjusting the top-blown oxygen feed rate, the flow rate of bottom-blown gas or the top-blowing lance height.
    Type: Grant
    Filed: July 15, 1996
    Date of Patent: February 9, 1999
    Assignee: Nippon Steel Corporation
    Inventors: Masataka Yano, Yuji Ogawa, Masayuki Arai, Fumio Koizumi, Noriyuki Masumitsu, Hideaki Sasaki, Hiroshi Hirata, Yoshiaki Kusano, Hirobumi Maede, deceased, by Noriko Kawai, by Keiko Ikemizu
  • Patent number: 5849061
    Abstract: A process for refining high-impurity blister copper to anode quality copper is disclosed. In an oxidation step of a blister copper refining stage, soda ash fluxing removes antimony and arsenic while also removing sulfur and iron. In a deoxidation step of the blister copper refining stage, sulfur hexafluoride is injected at a controlled oxygen concentration to remove bismuth while reducing the oxygen content. Slag is continuously or periodically skimmed from the surface of the molten blister copper to prevent re-entry of impurities. The process may be carried out in batch operation or, in a preferred embodiment, in continuous flow-through operation.
    Type: Grant
    Filed: September 20, 1996
    Date of Patent: December 15, 1998
    Assignee: The Trustees of Columbia University in the City of New York
    Inventors: Nickolas J. Themelis, Baozhong Zhao
  • Patent number: 5804424
    Abstract: The invention relates to Proteobacteria that show unusually high level resistance to a wide range of metal oxides and oxyanions and to methods using selected Proteobacteria subgroups for efficient reduction of certain metal oxides and oxyanions to the free metal. High level resistance was shown to be affected by growth conditions, and was observed in facultative photoheterotrophs such as Rhodobacter sphaeroides grown either chemoheterotrophically or photoheterotrophically. The disclosed methods are adaptable to the production of hydrogen from cultures of Peoteobacteria grown in the presence of tellurite class oxyanions with carbon dioxide and nitrogen as carbon and nitrogen sources. The methods have commercial application for efficient bioremediation of carbon dioxide and nitrogen.
    Type: Grant
    Filed: July 13, 1994
    Date of Patent: September 8, 1998
    Inventors: Samuel Kaplan, Mark D. Moore
  • Patent number: 5755853
    Abstract: This process comprises; mixing (1) the solid residues with a solid reducing agent; treating (2) the mixture in a furnace at a temperature above 1000.degree. C. to obtain (3) a vitrified product rendered poor in metals and an emission of gas enriched in metallic elements in a vapour phase; air quenching (4) the gases rich in metals; filtering (5) the products resulting from the air quenching to obtain secondary ashes rich in metallic salts; at the end of the filtering operation, washing the smoke (6) for discharging it to the atmosphere; and subjecting the secondary ashes rich in metallic salts to a treatment for producing a product rich in valuable metals (7 to 10).
    Type: Grant
    Filed: December 11, 1996
    Date of Patent: May 26, 1998
    Assignee: Electricite de France - Service National
    Inventors: Pierre Pasquini, Roger Meunier, Olivier Leclerc, Fabrice Lebrun
  • Patent number: 5749940
    Abstract: The known method comprises the following steps. (1) the de-copperized anode slime is chlorination-leached with HCl and H.sub.2 O.sub.2. (2) Na.sub.2 CO.sub.3 is added to the chlorination-leach residue of (1). (3) NH.sub.3 is added to the residue of (2). (4) Distillation of NH.sub.3 to remove NH.sub.3 contained in the ammonia leach solution of (3). (5) Distillation residue is washed with water to yield refined AgCl. (6) Conversion of AgCl to Ag.sub.2 O. (7) Reduction of Ag.sub.2 O to Ag. In order to enhance the purity of the reduced silver, the present invention provides the following improvements (a) to (d). (a) Dechlorination (2) with the use of Na.sub.2 CO.sub.3 is carried out at ambient temperature. (b) After dechlorination, the residue is washed with hot water. (c) Sulfuric acid is added instead of carrying out distillation (4). (d) Prior to conversion (6), the chlorination is again carried out.
    Type: Grant
    Filed: March 11, 1997
    Date of Patent: May 12, 1998
    Assignee: Nippon Mining & Metals Co., Inc.
    Inventor: Katutoshi Narita
  • Patent number: 5623725
    Abstract: Process for producing very pure platinum materials dispersion-reinforced with Y.sub.2 O.sub.3 and having high strength and extensibility, even in the temperature range >800.degree. C., from platinum powder by mechanical alloying, which comprises the process stepspreparing platinum powder of high purity and low particle size of from 2 to 10 .mu.m,introducing and dispersing Y.sub.2 O.sub.3 particles >1 .mu.m in the platinum powder by milling in a platinum vessel using milling media of zirconium oxide,degassing the milled product under a vacuum of better than 10.sup.-3 mbar and with an increase in temperature to at least 1200.degree. C. in a platinum capsule for a period of up to 48 hours,gastight welding of the evacuated capsule and hot isostatic pressing at 1350.degree. C.
    Type: Grant
    Filed: May 16, 1995
    Date of Patent: April 22, 1997
    Assignee: Schott Glaswerke
    Inventors: Joachim Disam, Gerhard Jangg, Johannes Zbiral, Gerhard Schreier, Christian Edtmaier
  • Patent number: 5366891
    Abstract: A method of solubilizing metal salts such as metal sulfides in a geothermal sludge using mutant Thiobacilli selected for their ability to metabolize metal salts at high temperature is disclosed, The method includes the introduction of mutated Thiobacillus ferrooxidans and Thiobacillus thiooxidans to a geothermal sludge or brine. The microorganisms catalyze the solubilization of metal salts, For instance, in the case of metal sulfides, the microorganisms catalyze the solubilization to form soluble metal sulfates.
    Type: Grant
    Filed: September 3, 1993
    Date of Patent: November 22, 1994
    Assignee: Associated Universities, Inc.
    Inventors: Eugene T. Premuzic, Mow S. Lin
  • Patent number: 5354688
    Abstract: A process is provided for solubilizing coprecipitated metals. Metals in wastestreams are concentrated by treatment with an iron oxide coprecipitating agent. The coprecipitated metals are solubilized by contacting the coprecipitate with a bacterial culture of a Clostridium species ATCC 53464. The remobilized metals can then be recovered and recycled.
    Type: Grant
    Filed: April 16, 1992
    Date of Patent: October 11, 1994
    Assignee: Associated Universities, Inc.
    Inventors: Arokiasamy J. Francis, Cleveland J. Dodge