Abstract: A method of depositing a hard wear resistant surface onto a porous or non-porous base material of a medical implant. The medical implant device formed by a Laser Based Metal Deposition (LBMD) method. The porous material of the base promotes bone ingrowth allowing the implant to fuse strongly with the bone of a host patient. The hard wear resistant surface provides device longevity when applied to bearing surfaces such as artificial joint bearing surface or a dental implant bearing surface.

Abstract: A package is configured as a composite component with a substrate, at least one semiconductor component, and an enclosure, which are joined to one another. The heat-dissipating substrate is a single-layer or multilayer substrate with a thermal conductivity, transversely with respect to a joining surface to which the semiconductor component is joined, of greater than 170 W/m. The substrate may be a layered structure and/or a structure of graduated material composition, and it has an asymmetrical thermal expansion characteristic. By suitable selection the layers or the material graduation, it is possible to reduce and limit the shear distortion of the composite component formed of the substrate, the semiconductor component, and the enclosure.

Abstract: A coated article includes formed of an alloy having a composition including nickel and aluminum, and a protective coating overlying and contacting the substrate. The protective coating is a mixture of a quasicrystalline metallic phase, and a non-quasicrystalline metallic phase comprising nickel and aluminum. The aluminum is present in an amount of from about 3 to about 35 percent by weight of the non-quasicrystalline metallic phase.

Abstract: A process for the production of thin walled parts of steel, wherein there are layers that are at least partly differently treatable relating to their strength and hardness qualities. This process can include creating a composite material from a plurality of different layers by connecting at least one core layer and at least one surface layer together. At least one layer of the core or surface layer is cast adjacent to another layer to form a composite material having an alloy gradient that is flat at each interface between any of the core layer or the surface layer. Next, the process can include deforming the composite material along a length of these layers. Finally the process can include heat treating the layers to transform the strength and hardness qualities of at least one of these layers.

Abstract: A substrate processing chamber component is a structure having an integral surface coating comprising an yttrium-aluminum compound. The component may be fabricated by forming a metal alloy comprising yttrium and aluminum into the component shape and anodizing its surface to form an integral anodized surface coating. The chamber component may be also formed by ion implanting material in a preformed metal shape. The component may be one or more of a chamber wall, substrate support, substrate transport, gas supply, gas energizer and gas exhaust.

Abstract: A protective overlay coating for articles used in hostile thermal environments, and more particularly a predominantly beta-phase NiAl intermetallic overlay coating for use as an environmental coating or as a bond coat for a thermal barrier coating deposited on the overlay coating. The overlay coating has inner and outer regions, with the inner region containing more chromium than the outer region. The lower chromium content of the outer region promotes the oxidation resistance of the overlay coating, while the higher chromium content of the inner region promotes the hot corrosion resistance of the coating interior. Under hot corrosion conditions, hot corrosion may attack the outer region, but further hot corrosion attack will substantially cease once the relatively high-chromium inner region of the overlay coating is encountered.

Abstract: An article protected by a protective coating has a substrate and a protective coating having an outer layer deposited upon the substrate surface and a diffusion zone formed by interdiffusion of the outer layer and the substrate. The protective coating includes platinum, aluminum, no more than about 2 weight percent hafnium, and substantially no silicon. The outer layer is substantially a single phase.

Abstract: The invention relates to a series of extra strong and durable aluminium alloy brazing sheets with enhanced corrosion resistance for brazed heat exchangers. The alloy sheets are based on recycled materials and are suitable for manufacturing of fins, welded tubes, headers and sideplates. The alloy sheets showed improved corrosion performance with respect to pitting corrosion, excellent high temperature sagging resistance and post braze strength, and a good brazeability. By optimising the material combination of fin, tube, header and sideplates it is possible to produce a heat exchanger with adequate corrosion performance in SWAAT.

Abstract: Guide wires and catheters made from a functionally graded alloy comprising 3-10 weight % Al and 5-20 weight % Mn, the balance being substantially Cu and inevitable impurities. The functionally graded alloy is produced by forming the copper-based alloy, maintaining it at a temperature of at least 500° C. and rapidly cooling it, and then subjecting the alloy to an aging treatment by a gradient temperature heater.

Abstract: The present invention is directed to a coated substrate, comprising: an antitarnish layer deposited on a substrate in an amount effective to prevent tarnishing of said coated substrate; and an outer layer deposited onto said antitarnish layer, said outer layer comprising tin or tin alloys having at least 50% by weight tin. The present invention is also directed to coated substrates having a concentration gradient of antitarnish agent diffused into the coating, as well as methods of forming such coated substrates.

Abstract: It is to propose an internal member for a plasma treating vessel having excellent resistances to chemical corrosion and plasma erosion under an environment containing a halogen gas and an advantageous method of producing the same, which is a member formed by covering a surface of a substrate with a multilayer composite layer consisting of a metal coating formed as an undercoat, Al2O3 film formed on the undercoat as a middle layer and Y2O3 sprayed coating formed on the middle layer as a top coat.

Abstract: A surface processing method and power transmission component includes refining a surface region of a metal from a first roughness to a second roughness less than the first roughness. A solid lubricous coating or a hard coating is then deposited on the surface region. The metal has a surface hardness above 50 Rc to reduce the risk that the metal will deform under the coating and leave the coating unsupported. The surface region of the metal may be transformed into a nitrogen-containing compound or solid solution surface region before the surface refining step and deposition of the coating.

Abstract: The present invention relates to a method of fabrication and a product, which forms a composite body made of metal and a porous ceramic blank, which adjoins the metallic portion and is infiltrated by the metal, wherein a gradient in properties across the composite portion of the composite body is formed by a heat treatment that reduces some of the oxides across the thickness of the porous ceramic blank. In one embodiment, a gradient from substantial chemical reaction to incomplete chemical reaction of the reducible oxides of the blank with the infiltrated metal is formed inside the composite portion.

Abstract: A coated superalloy article is prepared by furnishing a nickel-base superalloy article substrate having a rhenium content of not less than about 4.0 percent by weight, and thereafter depositing an aluminum-containing coating onto a surface of the article substrate. The aluminum-containing coating includes an additive zone having an average aluminum content of not greater than about 27 percent by weight, and a diffusion zone of interdiffusion with the article substrate. A ratio of a thickness of the additive zone to a thickness of the diffusion zone is not greater than about 3:1, and is preferably about 1:1.

Abstract: The present invention provides a method of producing a bonded body of a beryllium member and a copper or copper alloy member, in which the bonding strength and thermal cycle resistance property are further increased. When the beryllium member and the copper or copper alloy member are bonded to each other, a thin layer of titanium, chromium, molybdenum, or silicon is formed as a diffusion inhibition layer on the surface of the beryllium; a copper layer is formed as a bonding layer on the surface of the diffusion inhibition layer; a thin layer of aluminum or zinc is formed as a bonding promotion layer on the surface of the bonding layer; and the beryllium member and the copper or copper alloy member are diffusion bonded to each other with the intermediate layer formation side being the bonding surface.

Abstract: A laser shock processing treatment enables a selectively adjustable and customized compressive residual stress distribution profile to be developed within a workpiece by tailoring the size and shape of the laser beam spots. One peening operation applies to the workpiece a first pattern having relatively large laser beam spots and then applies a second pattern having relatively small laser beam spots. The composite use of such small and large beam spots enables the stress distribution profile to be tailored to the part specifications. The large beam spots maximize the depth of compressive residual stress in the part, while the small beam spots optimize the surface compressive residual stresses of the part. The use of small spot beam patterns allows untreated or improperly processed areas to be laser peened.

Abstract: An aluminum-coated structural member includes an Al—Si—Fe alloy layer formed on a steel substrate layer. The alloy layer includes a softer region having a hardness smaller than or equal to a hardness of the steel substrate layer, extends from the surface of the steel substrate layer toward a surface of the alloy layer, over a depth range greater than or equal to 50% of a thickness of the alloy layer. The Al—Si—Fe alloy layer has an oxide weight smaller than or equal to 500 mg/dm2.

Abstract: The properties of a metal piece are altered by laser peening the piece on the first side using an acoustic coupling material operatively connected to the second side and subsequently laser peening the piece on the second side using an acoustic coupling material operatively connected to the first side.

Abstract: A gradient material molded body, obtained in continuous casting from at least one metal alloy solidified in an outer shell of the molded body, outside the thermodynamic equilibrium.

Abstract: A comparatively high vacuum pressure method of manufacturing two-way shape memory effect devices produces devices having a compositional gradient through the thickness of a film of shape memory alloy. The shape memory alloy film exhibits two-way shape memory effect, which is useful for fabricating cyclical actuating devices without need of a biasing mechanism. Examples of shape memory alloys include Ni:Ti-, Au:Cd-, Fe:Mn:Si- and Cu:Ni:Al-based binary, ternary and higher order alloys. Three-dimensional devices may be mass produced using the shape memory alloy and process.

Abstract: The present invention relates to a color cathode ray tube provided with a pressed-type shadow mask. As material for constituting the shadow mask 6, a single plate body made of a composite gradient alloy plate consisting of three layers 6A, 6B, 6C or more in which an alloy element has the concentration gradient which is continuously changed from one surface to the other surface is used. The present invention can realize a pressed mask having a large radius of curvature by self-correcting the thermal deformation such as a doming or the like.

Abstract: It is disclosed a method of deposting a seal coating and a seal system comprising at least two layers (3, 4) on the surface of an article (1). The upper or surface layer (4) has a higher chromium activity than a bottom layer (3) to reduce a diffusion of cobalt and the formation of cobalt oxide is reduced. The coating (2) of invention may be heat-treated to reduce or optimize the formation of cobalt oxide to sustin the wear property.

Abstract: The present invention is process for forming diffusion aluminide coatings on an uncoated surface of a substrate, without interdiffusing a sufficient amount of aluminum into a coating layer to adversely affect the coating growth potential and mechanical properties of said coating layer. A metal substrate is provided comprising an external surface and an internal passage therein defined by an internal surface, at least a portion of the external surface of the substrate being coated with a coating layer selected from the group consisting of &bgr;-NiAl-base, MCrAlX, a line-of-sight diffusion aluminide, a non-line-of-sight diffusion aluminide, a pack diffusion aluminide, and a slurry diffusion aluminide on said substrate. The external surface of the substrate is cleaned. The metal substrate is subjected to a aluminum vapor phase deposition process performed using a fluorine-containing activator selected from the group consisting of AiF3, CrF3, NH4F, and combinations thereof, at a rate in the range of about 0.

Abstract: A coated article, a coating for protecting an article, and a method for protecting an article are provided. The article comprises a metallic substrate and a substantially single-phase coating disposed on the substrate, wherein the coating comprises nickel (Ni) and at least about 30 atomic percent aluminum (Al); the coating further comprises a gradient in Al composition, the gradient extending from a first Al concentration level at an outer surface of the coating to a second Al concentration level at an interface between the substantially single-phase coating and the substrate, wherein the first Al concentration level is greater than the second Al concentration level and the second concentration level is at least about 30 atomic percent Al.

Abstract: A cast slab has a negative segregation zone composed of a multilayer structure of negative segregation layers disposed between dendrite or crystalline layers. The dendrite or crystalline layers are a deflection structure caused by vibration during formation of the cast slab. The negative segregation layers have a distance between them of not more than 2 mm and the number of negative segregation layers is not less than 3. The cast slab has an equi-axed crystal ratio of not less than 50% inside the multilayer negative segregation zone.

Abstract: A coated article, a coating for protecting an article, and a method for protecting an article are provided. The article comprises a metallic substrate and a substantially single-phase coating disposed on the substrate, wherein the coating comprises nickel (Ni) and at least about 30 atomic percent aluminum (Al); the coating further comprises a gradient in Al composition, the gradient extending from a first Al concentration level at an outer surface of the coating to a second Al concentration level at an interface between the substantially single-phase coating and the substrate, wherein the first Al concentration level is greater than the second Al concentration level and the second concentration level is at least about 30 atomic percent Al.

Abstract: A multilayer film formed body comprises an outermost layer comprising a diamondlike carbon film, a substrate comprising an iron material, and an intermediate layer comprising a first layer on the substrate side, and a second layer on the outermost layer side. The first layer comprises at least either metal of Cr and Al, and a second layer comprises an amorphous layer including carbon and at least either metal of Cr and Al. The second layer has a gradient structure where the metal decreases as the position becomes closer to the outermost layer. The hardness of the second layer increases stepwise or continuously as the position becomes closer to the outermost layer. The hardness of the second layer close to the first layer is close to the hardness of the first layer. The hardness of the second layer close to the outermost layer is close to the hardness of the outermost layer.

Abstract: A method of ion implantation using oxygen backfill and a modified surface layer formed therefrom are provided. The method of ion implantation includes the steps of placing a substrate metal in an ion implantation vacuum chamber, introducing oxygen into the ion implantation vacuum chamber and directing a beam of ions at the substrate metal. The modified surface includes a substrate metal and implanted atoms at a surface of the substrate metal. The implanted atoms are integrated with the substrate metal. The substrate metal has an implanted atom concentration of at least 5 atomic % to a depth of over 250 Å.

Abstract: The present invention discloses devices and a method of fabrication of devices using a shape memory effect, thin film with a compositional gradient through the thickness of the film. Specifically, a NiTi SME thin film is disclosed that can be used in actuators, MEMS devices and flow control. The process of fabrication includes a gradual heating of the target over time during the sputter deposition of a thin film on a substrate under high vacuum, without compositional modification. The resulting thin film exhibits two-way shape memory effect that can be cyclically applied without an external bias force.

Abstract: A method of prestressing a component (30) includes the use of an electrical discharge or current to produce a plasma (39) within a medium (32) located adjacent the component (30). The plasma generates a shock wave which impacts a surface of the component to produce a region of compressive residual stress within the component.

Abstract: The coating plant includes a device for running a sheet to be coated along a traveling path past a window for the evaporation or sublimation of elements A an B, sources for the evaporation or sublimation of elements A and element B placed successively in a direction parallel to the traveling path so as to emit elements A and B through the window and a screen for reducing the angle of emission from the source of element B below the limit represented by an exit edge of the window, the screen being mounted so as to move translationally perpendicular to the traveling path and to move along the traveling path between the source of element A and the source of element B so as to obtain either a —A—AB—A— or a —B—AB—B—coating.

Abstract: An aluminum alloy heat exchanger having a tube composed of a thin aluminum alloy clad material, wherein, in the clad material, one face of an aluminum alloy core material containing Si 0.05-0.

Abstract: A metallic component exposed to high temperature steam is provided with a coating comprising a thin primer layer deposited on the surface of the metallic component and a thicker overlay layer on top of the primer layer. The primer layer consists of highly ductile, oxidation resistant material such that it remains free of any defects over a long period of exposure. The overlay layer consists of an oxidation resistant, less ductile, and low-cost material. It protects the thin primer layer from mechanical damage and chemical degradation. The primer layer protects the base material of the metallic component from oxidizing steam that may penetrate through cracks of the overlay layer. Due to suitable choice of coating materials and thicknesses of the layers the coating is low-cost.

Abstract: High energy flux infrared heaters are used to treat an object having a surface section and a base section such that a desired characteristic of the surface section is physically, chemically, or phasically changed while the base section remains unchanged.

Abstract: A method for preparing compositionally graded metallic plates and compositionally graded metallic plates suitable for use as interconnects for solid oxide fuel cells are provided. The method of the invention, utilizing powder metallurgy, enables making metallic plates of generally any desired composition to meet the corrosion requirements of fuel cells and other applications, and enables making metallic plates of graded composition from one surface of the plate to the other. A powder of the desired alloy composition is obtained, then solvents, dispersants, a plasticizer and an organic binder are added to form a slip. The slip is then formed into a layer on a desired substrate that can be flat or textured. Once dried, the layer is removed from the substrate and the binder is burned out. The layer is sintered in a reducing atmosphere at a set temperature for a predefined duration specific to the materials used and the desired final properties.

Abstract: The present invention relates generally to an oxidation and corrosion resistant coating composition produced by a vapor phase co-deposition of transition metals on metallic components. In particular, this coating includes aluminum and silicon and the coated substrate may comprise precious metal, nickel, cobalt or MCrALY. Such coatings are particularly useful in protecting nickel and cobalt and iron-based superalloys from heat corrosion and oxidation attack, especially during high temperature operation, e.g., gas turbine and jet engine hot zones.

Abstract: A system and method for producing a corrosion-resistant article includes a metal substrate and a multi-layer resistant coating disposed over the metal substrate. The coating is operable to resist corrosion and hydrogen embrittlement of the metal substrate. The coating includes a first layer comprising a material galvanically similar to the metal substrate. The coating also includes a second layer disposed over the first layer. The second layer comprises a metal anodic to the metal substrate. The corrosion resistant article may also include a corrosion resistant interface layer at the boundary of the first and second layers. The interface layer may be formed by diffusing a portion of the second layer into the first layer.

Abstract: The present invention discloses devices and a method of fabrication of devices using a shape memory effect, thin film with a compositional gradient through the thickness of the film. Specifically, a NiTi SME thin film is disclosed that can be used in actuators, MEMS devices and flow control. The process of fabrication includes a gradual heating of the target over time during the sputter deposition of a thin film on a substrate under high vacuum, without compositional modification. The resulting thin film exhibits two-way shape memory effect that can be cyclically applied without an external bias force.

Abstract: A metal alloy solder ball comprising a first metal and a second metal, the first metal having a sputtering yield greater than the second metal. The solder ball comprises a bulk portion having a bulk ratio of the first metal to the second metal, an outer surface, and a surface gradient having a depth and a gradient ratio of the first metal to the second metal that is less than the bulk ratio. The gradient ratio increases along the surface gradient depth from a minimum at the outer surface. The solder ball may be formed by the process of exposing the ball to energized ions of a sputtering gas for an effective amount of time to form the surface gradient.

Abstract: Method for forming on a superalloy or other metallic substrate a platinum graded, outward single phase diffusion aluminide coating on a surface of the substrate by depositing a layer comprising Pt on the substrate and then gas phase aluminizing the substrate in a coating chamber having a solid source of aluminum (e.g. aluminum alloy particulates) disposed therein close enough to the surface of the substrate to form at an elevated substrate coating temperature a diffusion aluminide coating having an inner diffusion zone and outer additive single (Ni,Pt)Al phase layer having a concentration of platinum that is relatively higher at an outermost coating region than at an innermost coating region adjacent the diffusion zone.

Abstract: A Ti-base wire rod for forming molten metal excellent both in rod feeding smoothness and arc stability is disclosed. A wire rod 301 is composed of Ti metal, and has in the surficial portion including the surface thereof an oxygen enriched layer having an oxygen concentration higher than that in an inner portion. Ratio Tw/Dw of the thickness Tw of the oxygen enriched layer and the diameter Dw of the wire rod is adjusted within a range of 1×10−3 to 1×10−1, and the average oxygen concentration of the oxygen enriched layer is adjusted to 1 wt % or above.

Abstract: A functional film includes a transition layer having a first constituent having SiO as a dielectric material and at least one second constituent selected from aluminum (Al), silver (Ag), silicon (Si), germanium (Ge), yttrium (Y), zinc (Zn), zirconium (Zr), tungsten (W) and tantalum (Ta). The first and second constituents have corresponding gradual content gradients according to a thickness of the functional film.

Abstract: A heat treatable coated article (e.g., vehicle windshield, IG unit, etc.) is provided with a dual-silver low-E coating. Before and/or after heat treatment (HT), the coating and/or coated article has a visible transmittance of at least 70%, more preferably at least 75%. Moreover, the coating and/or coated article is designed so as to have approximately the same color when viewed over a wide range of viewing angles. In certain embodiments, at least one contact layer (e.g., of or including NiCrOx) that contacts an infrared (IR) reflecting layer (e.g., Ag) is oxidation graded so that it progressively becomes less oxidized through its thickness as it nears the IR reflecting layer. In still other embodiments, a Si-rich silicon nitride layer(s) may be utilized to reduce haze.

Abstract: The present invention provides a method of producing a bonded body of a beryllium member and a copper or copper alloy member, in which the bonding strength and thermal cycle resistance property are further increased. When the beryllium member and the copper or copper alloy member are bonded to each other, a thin layer of titanium, chromium, molybdenum, or silicon is formed as a diffusion inhibition layer on the surface of the beryllium; a copper layer is formed as a bonding layer on the surface of the diffusion inhibition layer; a thin layer of aluminum or zinc is formed as a bonding promotion layer on the surface of the bonding layer; and the beryllium member and the copper or copper alloy member are diffusion bonded to each other with the intermediate layer formation side being the bonding surface.

Abstract: An aluminum alloy plate for a planographic printing plate capable of being provided with a satisfactory roughed surface by electrolytic etching. The aluminum alloy plate contains 0.1 to 0.6% of Fe, 0.01 to 0.2% of Si, 5 to 150 ppm of Cu, and balance of Al and unavoidable impurities and has a surface layer portion formed of a metastable phase dispersion layer in which metastable phase AlFe-based intermetallic compound particles are dispersed. The metastable intermetallic compound particles each act as a starting point for pits. The alloy plate is formed with a roughed surface which is reduced in unetching and uniformly formed with pits, by electrolytic etching.

Abstract: A method is described for producing composite multilayer materials which exhibit optimum properties throughout their entire service life. The composite multilayer material comprises a backing layer, a bearing metal layer, an intermediate layer and an electrodeposited overlay, which exhibits a hardness which increases continuously from its surface in the direction of the bearing metal layer. The method provides for the electrodeposition as overlay of a lead-free alloy with at least one hard and one soft component, the current density being modified within the range of from 0.3 to 20 A/dm2 during the deposition process and/or the temperature of the electroplating bath being modified within the range of from 15° C. to 80° C.

Abstract: A method for applying, in a non-oxidizing atmosphere, a diffusion aluminide coating to a metallic surface of an article combines use of a relatively low aluminide coating temperature in the range of about 1650-1800° F. with a relatively high Al activity Al source material including Al of at least about 40 weight %. Such combination results in an as-deposited aluminide coating comprising a diffusion portion bonded between a metallic substrate and a coating outer portion of a thickness of no greater than about 60% of the thickness of the coating outer portion, typically less than about 1 mil.

Abstract: An article protected by a protective coating includes a substrate made of a first nickel-base superalloy substrate material that is susceptible to the formation of a secondary reaction zone when overlaid by a diffusion aluminide coating or an aluminide overlay coating. A protective coating including a deposited coating at the substrate surface. The deposited coating is a second nickel-base superalloy different from the first nickel-base superalloy and which does not produce a secondary reaction zone when interdiffused with the first nickel-base superalloy. In one version, the deposited coating has a nominal composition, in weight percent, of about 3.1 percent cobalt, about 7.6 percent chromium, about 7.8 percent aluminum, about 5.45 percent tantalum, about 3.85 percent tungsten, about 1.65 percent rhenium, about 0.02 percent carbon, about 0.016 percent hafnium, about 0.015 percent boron, about 0.5 percent silicon, balance nickel and incidental impurities.

Abstract: A high temperature resistant article with improved protective coating bonding and method of manufacturing the article is provided. In one embodiment, the high temperature resistant article comprises a base body having a surface at least partly coated with an oxidation and corrosion protective coating containing a carbide forming element, wherein said base body is made from a metallic alloy having a medium carbon content and wherein the carbon content in a depth of 50 &mgr;m or deeper from said coated surface is less than 0.3% of said medium carbon content.

Abstract: Valve metal articles such as wire, sheet or powder having a second metal, preferably in a peripheral margin, prepared by coating the valve metal with a salt solution of the metal additive and heat treating in the presence of an oxygen getter to remove the oxygen from the valve metal and the anion of the metal salt to form the metal additive. For tantalum wire a preferred second metal is nickel. A preferred oxygen getter is magnesium. Nickel-containing tantalum wire is useful for enhance bonding to sintered pressed tantalum powder pellets in the production of electrolytic capacitors.