Polymeric Diazonium Compound Patents (Class 430/175)
  • Patent number: 9851637
    Abstract: A resist composition which generates acid upon exposure and exhibits changed solubility in a developing solution under action of acid, the resist composition including a base component (A) which exhibits changed solubility in a developing solution under action of acid, and a compound (D1) represented by general formula (d1), wherein Z? represents an anion having an aromatic ring containing a hydroxybenzoic acid skeleton, provided that at least one hydrogen atom of the aromatic ring has been substituted with a halogen atom; m represents an integer of 1 or more; and Mm+ represents an organic cation having a valency of m.
    Type: Grant
    Filed: October 4, 2016
    Date of Patent: December 26, 2017
    Assignee: TOKYO OHKA KOGYO CO., LTD.
    Inventors: Takashi Nagamine, Kotaro Endo, Hideto Nito
  • Patent number: 9606439
    Abstract: A conductive pattern can be formed using a polymeric layer that contains a reactive composition that comprises a reactive polymer that is metal ion-complexing, water-soluble, and crosslinkable. This reactive polymer comprises photosensitive non-aromatic heterocyclic groups each of these groups comprising a carbon-carbon double bond in conjugation with an electron withdrawing group, as well as metal ion-complexing and water solubilizing groups. The reactive composition can be patternwise exposed to suitable radiation to induce crosslinking within the reactive polymer. The reactive composition and reactive polymer in the non-exposed regions can be removed due to their aqueous solubility, but the exposed regions of the polymeric layer are contacted with electroless seed metal ions, which are then reduced. The resulting electroless seed metal nuclei are electrolessly plated with a suitable metal to form the desired conductive pattern.
    Type: Grant
    Filed: July 15, 2014
    Date of Patent: March 28, 2017
    Assignee: EASTMAN KODAK COMPANY
    Inventors: Thomas B. Brust, Grace Ann Bennett
  • Patent number: 9499662
    Abstract: Disclosed is a method for inhibiting the formation of foam in aqueous systems by adding foam control composition including a polyoxyethylene and/or a polyoxypropylene nonionic fatty acid derivative and a quaternary ammonium surfactant.
    Type: Grant
    Filed: April 4, 2011
    Date of Patent: November 22, 2016
    Assignee: CHEMTREAT, INC.
    Inventors: John Richardson, Mark Puchovich, Vladimir Djukanovic, Karen Williams
  • Patent number: 8771923
    Abstract: A radiation-sensitive composition includes a low-molecular-weight compound, a solvent and a radiation-sensitive acid-generator other than the low-molecular-weight compound. The low-molecular-weight compound has one or more acid-dissociable groups which decompose by an action of an acid to enhance solubility in an alkaline developing solution and one or more radiation-sensitive acid-generating groups which generate an acid upon application of an active ray or radiation per molecule. The low-molecular-weight compound has a polystyrene-reduced number-average molecular weight (Mn) measured by gel permeation chromatography (GPC) of 500 to 4,000. The low-molecular-weight compound is not obtained from chain growth polymerization of a monomer with an unsaturated bond. A content of the low-molecular-weight compound is 80 mass % or more of 100 mass % of a total solid component of the radiation-sensitive composition. The low-molecular-weight compound is a compound shown by a following formula (1).
    Type: Grant
    Filed: December 19, 2012
    Date of Patent: July 8, 2014
    Assignee: JSR Corporation
    Inventors: Nobuji Matsumura, Daisuke Shimizu, Toshiyuki Kai
  • Patent number: 7935776
    Abstract: The present invention relates to a radiation curable and developable polyurethane which is characterized by having a carboxy group in its main chain and a acryloyl group in its side chain and comprising the following repeat units (I), (II), and (II) in a random arrangement: wherein R1, R2, R3, R4, and T are defined in the specification. The polyurethane has a weight molecular weight measured by GPC in a range of from 3,000 to 400,000; an acid value in a range of from 5 to 120 mgKOH/g. The present invention also relates to a radiation curable and developable composition containing the polyurethane.
    Type: Grant
    Filed: March 20, 2008
    Date of Patent: May 3, 2011
    Assignee: AGI Corporation
    Inventors: Wei Hsiang Huang, Ying Jen Chen, Jui Ming Chang, Chun Hung Kuo, Hong Ye Lin, Li Chung Chang
  • Patent number: 7914965
    Abstract: A resist composition comprises (A) a compound having a molecular weight of 3,000 or lower which has in its molecule a structure having two or more monovalent anions and a structure having two or more monovalent cations.
    Type: Grant
    Filed: September 20, 2005
    Date of Patent: March 29, 2011
    Assignee: FUJIFILM Corporation
    Inventors: Hyou Takahashi, Kenji Wada
  • Patent number: 7887994
    Abstract: Disclosed herein is a photoresist composition suitable for coating onto a large substrate and having improved coating uniformity to prevent occurrence of stains, a coating method thereof, a method of forming an organic film pattern using the same, and a display device fabricated thereby. The present invention thus provides a photoresist composition comprising a polymeric resin with an incorporated polysiloxane resin, a photosensitive compound, and an organic solvent. Accordingly, the photoresist composition can be coated onto a large substrate by a spinless coating method, and thereby coating uniformity can be improved, the occurrence of stains such as cumulous stains and resin streaks can be prevented, and the coating rate and quality of a final product prepared using the photoresist composition can also thereby be enhanced.
    Type: Grant
    Filed: February 1, 2008
    Date of Patent: February 15, 2011
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Yeong Beom Lee, Kyung Seop Kim, Jun Young Lee, Sung Wook Kang
  • Patent number: 7695875
    Abstract: The invention pertains to a photo-sensitive composition which comprises a photochemical initiator, a polyacid or a salt thereof, and a poly(3,4-alkylenedioxythiophene) wherein the alkylene moiety is —(CH2)n-, n being an integer from 1 to 3, or 1,2-cyclo-hexylene, which may optionally be substituted, characterized in that the photochemical initiator is a water-soluble polymer comprising at least two azide or diazonium groups. Preferably, the water-soluble polymer is chemically stable at pH 6 or less, more preferably at pH 2 or less.
    Type: Grant
    Filed: February 5, 2003
    Date of Patent: April 13, 2010
    Assignee: Koninklijke Philips Electronics
    Inventor: Fredericus Johannes Touwslager
  • Patent number: 7368215
    Abstract: The present invention provides a radiation sensitive composition suitable for us in on-press developable printing plates. The radiation sensitive composition comprises an initiator system including an onium salt and a radiation absorber. The initiator system is combined with a polymerizable material, and a polymeric binder including polyethylene oxide segments.
    Type: Grant
    Filed: May 12, 2003
    Date of Patent: May 6, 2008
    Assignee: Eastman Kodak Company
    Inventors: Heidi M. Munnelly, Geoffrey Horne, Jianbing Huang
  • Patent number: 7332477
    Abstract: The present invention provides visible light sensitive and ultraviolet (UV) light sensitive composition for DNA transfer comprising acid sensitive polyacetals developed as DNA/RNA delivery agents, a photoacid generator and optionally a photosensitizer.
    Type: Grant
    Filed: July 2, 2004
    Date of Patent: February 19, 2008
    Assignee: Nitto Denko Corporation
    Inventors: J. Kevin Cammack, Sang Van, Peng Wang
  • Patent number: 7316892
    Abstract: Disclosed is a process of preparing a planographic printing plate from a light sensitive planographic printing plate material comprising a hydrophilic support and provided thereon, an image formation layer containing (A) a polymerization initiator selected from a hexaarylbisimidazole compound and a diazo resin, and (B) an alkali soluble resin with an acid value of 5 to 200 having an acryloyl group or a methacryloyl group, the alkali soluble resin being obtained by reacting a vinyl copolymer having a monomer unit derived from acrylic acid or methacrylic acid with an epoxy compound having an acryloyl group or a methacryloyl group in the molecule, and, the process comprising the steps of imagewise exposing the light sensitive planographic printing plate material to ultraviolet laser, and removing an image formation layer at non-exposed portions with an aqueous alkali solution to form an image.
    Type: Grant
    Filed: March 10, 2005
    Date of Patent: January 8, 2008
    Assignee: Konica Minolta Medical & Graphic Inc.
    Inventors: Yasuhiko Takamuki, Toshiyuki Matsumura
  • Patent number: 7314698
    Abstract: The present invention provides a polymerizable composition comprising (A) a compound including a polymerizable unsaturated group and (B) a macromolecular compound including, at a side chain thereof, a structure represented by the following general formula (I): Z?M+??General formula (I) wherein Z? represents COCOO?, COO?, SO3?, or SO2—N?—R where R represents a monovalent organic group and M+ represents an onium cation. The present invention also provides a negative type planographic printing plate precursor responsive to an infrared laser, the precursor being superior in recording sensitivity and printing durability and using the polymerizable compound as a recording layer.
    Type: Grant
    Filed: February 10, 2006
    Date of Patent: January 1, 2008
    Assignee: FUJIFILM Corporation
    Inventors: Kazuto Shimada, Takahiro Goto
  • Patent number: 7303849
    Abstract: A planographic printing plate precursor comprises a support and two or more positive recording layers which are formed on the support, contain a resin and an infrared absorbing agent and exhibit an increase in solubility in an aqueous alkali solution by exposure to infrared laser light, wherein the positive recording layer closest to the support among these two or more positive recording layers contains at least two types of resins among which at least one type forms a dispersion phase. It is preferable that the dispersion phase be formed of (1) a high-polymer compound incompatible with a high-polymer matrix or (2) a granular polymer selected from a microcapsule and a latex, and contains an infrared absorbing agent and an acid generator.
    Type: Grant
    Filed: February 28, 2005
    Date of Patent: December 4, 2007
    Assignee: FUJIFILM Corporation
    Inventor: Hiroshi Tashiro
  • Patent number: 7291438
    Abstract: There are provided a negative-working photosensitive composition which can be cured by infrared rays and is less likely to suffer polymerization inhibition by oxygen during radical polymerization, and also exhibits high adhesion with a metal, and a negative-working photosensitive lithographic printing plate which is capable of directly forming images by irradiation with infrared rays from a solid or semiconductor laser based on digital signals, and also has high sensitivity and excellent printing durability. The negative-working photosensitive composition contains an infrared absorber (A), an organoboron compound (B) which functions as a polymerization initiator by using in combination with the infrared absorber (A), a compound having a polymerizable unsaturated group (C) and a diazo resin (D), and the negative-working photosensitive lithographic printing plate comprises a support, and a photosensitive layer containing the negative-working photosensitive composition formed on the support.
    Type: Grant
    Filed: June 17, 2004
    Date of Patent: November 6, 2007
    Assignee: Eastman Kodak Company
    Inventors: Hideo Sakurai, Eiji Hayakawa
  • Patent number: 7172847
    Abstract: The present invention provides a planographic printing plate precursor comprising a substrate and a negative image recording layer provided on the substrate containing: a compound that generates a radical or an acid by light or heat; a polymerizable compound or a crosslinking compound; and an infrared ray absorbing agent, wherein a dynamic friction coefficient of the outermost surface of the planographic printing plate precursor, at the side of the negative image recording layer being provided toward an inserting paper inserted into between the planographic printing plate precursors when the planographic printing plate precursors are laminated, is within a range from 0.2 to 0.7, as well as a planographic printing plate precursor laminate comprising the pluralty of the planographic printing plate precursors and inserting paper.
    Type: Grant
    Filed: March 28, 2003
    Date of Patent: February 6, 2007
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Takahiro Goto
  • Patent number: 7147991
    Abstract: Disclosed is a process of preparing a planographic printing plate from a light sensitive planographic printing plate material comprising a hydrophilic support and provided thereon, an image formation layer containing (a) an alkali soluble resin with an acid value of 5 to 200 having an acryloyl group or a methacryloyl group, the alkali soluble resin being obtained by reacting a vinyl copolymer having a monomer unit derived from acrylic acid or methacrylic acid with an epoxy compound having an acryloyl group or a methacryloyl group in the molecule, and (b) a diazo resin, the process comprising the steps of imagewise exposing the light sensitive planographic printing plate material to ultraviolet light using an exposure device comprising a digital mirror device (DMD), and removing an image formation layer at non-exposed portions with an aqueous alkali solution to form an image.
    Type: Grant
    Filed: February 24, 2005
    Date of Patent: December 12, 2006
    Assignee: Konica Minolta Medical & Graphic, Inc.
    Inventor: Toshiyuki Matsumura
  • Patent number: 7090957
    Abstract: The present invention provides a polymerizable composition comprising (A) a compound including a polymerizable unsaturated group and (B) a macromolecular compound including, at a side chain thereof, a structure represented by the following general formula (I). The present invention also provides a negative type planographic printing plate precursor responsive to an infrared laser, the precursor being superior in recording sensitivity and printing durability and using the polymerizable compound as a recording layer. General Formula (I) Z?M+ wherein Z? represents COCOO?, COO?, SO3? or SO2—N?—R where R represents a monovalent organic group and M30 represents an onium cation.
    Type: Grant
    Filed: September 10, 2003
    Date of Patent: August 15, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazuto Shimada, Takahiro Goto
  • Patent number: 7056639
    Abstract: The present invention provides an imageable composition including an acid curable composition, an acid generator, an infrared absorber having a counter anion derived from a non-volatile acid, and a strong acid such as a sulfonic acid. The imageable composition may include components such as a crosslinkable binder or a colorant. In one embodiment, the imageable composition further includes a colorant having a counter anion derived from a non-volatile acid. The present invention further provides an imageable element, which includes a substrate and an imageable coating on a surface of the substrate. Also provided is method of producing an imaged element according to the invention.
    Type: Grant
    Filed: August 20, 2004
    Date of Patent: June 6, 2006
    Assignee: Eastman Kodak Company
    Inventors: Eiji Hayakawa, Jianbing Huang, Thomas R. Jordan, Yasushi Miyamoto, Jeffrey J. Collins, Neil F. Haley, John Kalamen
  • Patent number: 6960419
    Abstract: Negative working imageable compositions and imageable elements comprising a layer of the imageable composition over a support are disclosed. The imageable compositions comprise a free-radical polymerizable system and an effective amount of curcumin. The curcumin is effective as an antihalation agent, but does not substantially reduce the photospeed of the imageable composition.
    Type: Grant
    Filed: December 12, 2003
    Date of Patent: November 1, 2005
    Assignee: Kodak Polychrome Graphics LLC
    Inventors: Paul R. West, Lee Korionoff
  • Patent number: 6911291
    Abstract: The invention relates to a recording material having a dimensionally stable, two-dimensional support, preferably an aluminium support, and a negative-working, radiation-sensitive layer which comprises a diazonium salt, a polymeric binder and a sulphobetaine. In addition, the layer may also comprise a polymerizable monomer or oligomer and a photopolymerization initiator. The front of the recording material may be matted or pigmented, and the back may be coated with an organic polymeric material. The sulphobetaine improves the solubility of the diazonium salts in aqueous-alkaline developers without reducing the resistance of the offset printing plates produced from the recording material.
    Type: Grant
    Filed: December 14, 2001
    Date of Patent: June 28, 2005
    Assignee: Agfa-Gevaert
    Inventors: Michael Dörr, Andreas Elsässer
  • Patent number: 6884561
    Abstract: A negative-working lithographic printing plate has a coating which is imaged by heating an area of the coating with an infrared laser and actinically reacting the coating in the heated area with ultraviolet or visible radiation. The coating contains an infrared absorber but the coating is not imageable by infrared radiation or by the heat generated. The imaging time is reduced since the actinic reaction rate is increased at the elevated temperature.
    Type: Grant
    Filed: September 16, 2002
    Date of Patent: April 26, 2005
    Assignee: Anocoil Corporation
    Inventors: Howard A. Fromson, William J. Rozell
  • Patent number: 6861196
    Abstract: The present invention includes an imageable element, which can be: (a) an imageable element comprising an imaging layer which comprises: an aromatic diazonium salt containing compound having an alkoxy substituent and an aromatic diazonium salt containing compound free of an alkoxy substituent; a polyvinyl acetal binder; and a sheet substrate; or (b) an imageable element comprising an imaging layer which comprises: an aromatic diazonium salt containing compound having an alkoxy substituent and an aromatic diazonium salt containing compound free of an alkoxy substituent; and a sheet substrate. The imaging layer includes a total aromatic diazonium salt containing compound content of at least 10 weight percent. The molar ratio of the aromatic diazonium salt containing compound having an alkoxy substituent to the aromatic diazonium salt containing compound that is free of an alkoxy substituent is from about 1.0:1 to 70:1. Upon imagewise exposure and development, an imaged element is obtained.
    Type: Grant
    Filed: September 17, 2003
    Date of Patent: March 1, 2005
    Assignee: Kodak Polychrome Graphics LLC
    Inventors: Stephan J. Platzer, Maria T. Sypek, Paul Perron, Harald Baumann, Melinda Alden
  • Patent number: 6824947
    Abstract: Photosensitive compositions comprising a phenol resin having a urea bond in the main chain, planographic printing plate precursors containing the photosensitive compositions, and methods for preparing planographic printing plates using the planographic printing plate precursors are disclosed. Planographic printing plates that exhibit good durability, good exposure visual image property, and good solvent resistance; particularly superior resistance to washing oil used in UV ink printing; and superior baking property are produced.
    Type: Grant
    Filed: February 19, 2003
    Date of Patent: November 30, 2004
    Assignee: Kodak Polychrome Graphics, LLC
    Inventors: Yasuhiro Ishizuka, Yasuhiko Kojima
  • Patent number: 6824946
    Abstract: A lithographic printing plate precursor comprising a support having a hydrophilic surface having provided thereon an image-forming layer containing a hydrophobic high molecular compound having at least either a functional group represented by formula (1) or a functional group represented by formula (2): wherein X+ represents an iodonium ion, a sulfonium ion or a diazonium ion.
    Type: Grant
    Filed: September 28, 2001
    Date of Patent: November 30, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hidekazu Oohashi, Kazuto Shimada
  • Patent number: 6808858
    Abstract: The present invention relates to a light-sensitive composition containing: (i) at least one diazonium polycondensation product or at least one system that can be radically polymerized and consists of photoinitiators and unsaturated compounds which can be radically polymerized or at least one hybrid system consisting of a diazonium polycondensation product and a system that can be radically polymerized and consists of photo initiators and unsaturated compounds which can be radically polymerized, (ii) at least one binding agent and optionally one or more exposure indicators, one or more dyes for increasing the image contrast and one or more acids for stabilizing the light-sensitive composition which is characterized in that the binding agent essentially consists of units (A, B, C, D), whereby A corresponds to formula (I), B corresponds to formula (II), C corresponds to formula (III) and D corresponds to formula (IV). The invention also relates to the use thereof for coating printing plates.
    Type: Grant
    Filed: December 10, 2002
    Date of Patent: October 26, 2004
    Assignee: Kodak Polychrome Graphics LLC
    Inventors: Robert Fuss, Harald Baumann, Udo Dwars, Hans-Joachim Timpe
  • Patent number: 6806020
    Abstract: The present invention provides a thermally imageable composition, which includes an acid curable composition, an acid generator, a strong acid and optionally an infrared absorber. The present invention further provides an imageable element, which includes a substrate and a thermally imageable composition according to the present invention coated on a surface of the substrate. Also provided are methods of producing an imaged element according to the present invention.
    Type: Grant
    Filed: August 21, 2001
    Date of Patent: October 19, 2004
    Assignee: Kodak Polychrome Graphics LLC
    Inventors: Neil Haley, John Kalamen
  • Patent number: 6783913
    Abstract: Polymeric acetal resins useful in lithographic printing are disclosed. The polymeric acetal resin contains units (A), (B), (C), (D), and (E). Unit (A) is a vinyl alcohol unit. Unit; (B) is a polyvinyl acetal unit containing an R group, where R is hydrogen, an aliphatic group, an aromatic group, or an arylaliphatic group. Unit (C) is a vinyl carboxylate unit. Unit (D) is an acidic vinyl acetal unit and/or a residue of an acidic vinyl monomer. Unit (E) is a free radical polymerization-inhibiting vinyl acetal unit and/or a free radical polymerization-inhibiting vinyl alcohol ester unit. The resin comprises about 10 to about 60 mol % of unit (A), about 5 to about 60 mol % of unit (B), about 0.3 to about 30 mol % of unit (C), about 1 to about 40 mol % of unit (D), and about 0.01 to about 2 mol % of unit (E).
    Type: Grant
    Filed: April 5, 2002
    Date of Patent: August 31, 2004
    Assignee: Kodak Polychrome Graphics LLC
    Inventors: Hans-Horst Glatt, Udo Dwars, Harald Baumann, Ingrid Glatt
  • Publication number: 20040146800
    Abstract: A planographic printing plate precursor of the present invention includes a hydrophilic support, and a lower layer and an image recording layer disposed on the hydrophilic support in this order. The lower layer includes a water-insoluble and alkali-soluble resin, and wherein the image recording layer includes a novolak type phenolic resin containing phenol as a structural unit thereof and a light-to-heat conversion agent, and exhibits increased solubility in an alkaline aqueous solution when exposed to an infrared laser.
    Type: Application
    Filed: January 20, 2004
    Publication date: July 29, 2004
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Kotaro Watanabe, Kaoru Iwato, IKuo Kawauchi
  • Patent number: 6727031
    Abstract: An infrared-sensitive image forming material with which a plate can be directly formed by an infrared laser. The infrared-sensitive image forming material has a support having disposed thereon a recording layer whose solubility in an aqueous alkaline solution is altered by irradiation with an infrared laser. The recording layer has a binder phase formed of a polymer compound, a dispersion phase that is dispersed in the binder phase, and an infrared absorbent present in either one of the binder phase and the dispersion phase. Within a total incorporated amount of the infrared absorbent in the recording layer, a mass present in the dispersion binder is greater than a mass present in the binder phase. Namely, within the recording layer, the infrared absorbent is localized in the dispersion phase.
    Type: Grant
    Filed: January 22, 2001
    Date of Patent: April 27, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazuto Shimada, Kazuto Kunita
  • Publication number: 20040063022
    Abstract: The present invention includes an imageable element, which can be: (a) an imageable element comprising an imaging layer which comprises: an aromatic diazonium salt containing compound having an alkoxy substituent and an aromatic diazonium salt containing compound free of an alkoxy substituent; a polyvinyl acetal binder; and a sheet substrate; or (b) an imageable element comprising an imaging layer which comprises: an aromatic diazonium salt containing compound having an alkoxy substituent and an aromatic diazonium salt containing compound free of an alkoxy substituent; and a sheet substrate. The imaging layer includes a total aromatic diazonium salt containing compound content of at least 10 weight percent. The molar ratio of the aromatic diazonium salt containing compound having an alkoxy substituent to the aromatic diazonium salt containing compound that is free of an alkoxy substituent is from about 1.0:1 to 70:1. Upon imagewise exposure and development, an imaged element is obtained.
    Type: Application
    Filed: September 17, 2003
    Publication date: April 1, 2004
    Applicant: Kodak Polychrome Graphics, LLC.
    Inventors: Stephan J. Platzer, Maria T. Sypek, Paul Perron, Harald Baumann, Melinda Alden
  • Publication number: 20030224281
    Abstract: Photosensitive compositions comprising a phenol resin having a urea bond in the main chain, planographic printing plate precursors containing the photosensitive compositions, and methods for preparing planographic printing plates using the planographic printing plate precursors are disclosed. Planographic printing plates that exhibit good durability, good exposure visual image property, and good solvent resistance; particularly superior resistance to washing oil used in UV ink printing; and superior baking property are produced.
    Type: Application
    Filed: February 19, 2003
    Publication date: December 4, 2003
    Inventors: Yasuhiro Ishizuka, Yasuhiko Kojima
  • Patent number: 6638679
    Abstract: The present invention includes an imageable element, which can be: (a) an imageable element comprising an imaging layer which comprises: an aromatic diazonium salt containing compound having an alkoxy substituent and an aromatic diazonium salt containing compound free of an alkoxy substituent; a polyvinyl acetal binder; and a sheet substrate; or (b) an imageable element comprising an imaging layer which comprises: an aromatic diazonium salt containing compound having an alkoxy substituent and an aromatic diazonium salt containing compound free of an alkoxy substituent; and a sheet substrate. The imaging layer includes a total aromatic diazonium salt containing compound content of at least 10 weight percent. The molar ratio of the aromatic diazonium salt containing compound having an alkoxy substituent to the aromatic diazonium salt containing compound that is free of an alkoxy substituent is from about 1.0:1 to 70:1.
    Type: Grant
    Filed: July 12, 2001
    Date of Patent: October 28, 2003
    Assignee: Kodak Polychrome Graphics, LLC
    Inventors: Stephan J. Platzer, Maria T. Sypek, Paul Perron, Harald Baumann, Melinda Alden
  • Publication number: 20030198887
    Abstract: Polymeric acetal resins useful in lithographic printing are disclosed. The polymeric acetal resin contains units (A), (B), (C), (D), and (E). Unit (A) is a vinyl alcohol unit. Unit; (B) is a polyvinyl acetal unit containing an R group, where R is hydrogen, an aliphatic group, an aromatic group, or an arylaliphatic group. Unit (C) is a vinyl carboxylate unit. Unit (D) is an acidic vinyl acetal unit and/or a residue of an acidic vinyl monomer. Unit (E) is a free radical polymerization-inhibiting vinyl acetal unit and/or a free radical polymerization-inhibiting vinyl alcohol ester unit. The resin comprises about 10 to about 60 mol % of unit (A), about 5 to about 60 mol % of unit (B), about 0.3 to about 30 mol % of unit (C), about 1 to about 40 mol % of unit (D), and about 0.01 to about 2 mol % of unit (E).
    Type: Application
    Filed: April 5, 2002
    Publication date: October 23, 2003
    Inventors: Hans-Horst Glatt, Udo Dwars, Harald Baumann, Ingrid Glatt
  • Publication number: 20030194632
    Abstract: Multi-layer, negative working imageable elements useful as lithographic printing plate precursors are disclosed. The elements contain, in order, a support; an underlayer; and an imageable layer. The imageable layer comprises a negative working imageable composition; and the underlayer is soluble or dispersible in a developer. Elements that can be imaged with ultraviolet or visible radiation and elements that can be imaged with infrared radiation or with heat are disclosed.
    Type: Application
    Filed: April 5, 2002
    Publication date: October 16, 2003
    Inventors: Kevin Ray, Joanne Ray
  • Publication number: 20030180654
    Abstract: The present invention relates to a light-sensitive composition containing: (i) at least one diazonium polycondensation product or at least one system that can be radically polymerized and consists of photoinitiators and unsaturated compounds which can be radically polymerized or at least one hybrid system consisting of a diazonium polycondensation product and a system that can be radically polymerized and consists of photo initiators and unsaturated compounds which can be radically polymerized, (ii) at least one binding agent and optionally one or more exposure indicators, one or more dyes for increasing the image contrast and one or more acids for stabilizing the light-sensitive composition which is characterized in that the binding agent essentially consists of units (A, B, C, D), whereby A corresponds to formula (I), B corresponds to formula (II), C corresponds to formula (III) and D corresponds to formula (IV). The invention also relates to the use thereof for coating printing plates.
    Type: Application
    Filed: December 10, 2002
    Publication date: September 25, 2003
    Inventors: Robert Fuss, Harald Baumann, Udo Dwars, Hans-Joachim Timpe
  • Publication number: 20030165769
    Abstract: The invention concerns a novel photosensitive composition for photoresist and a system comprising a substrate and a photoresist obtained from said novel composition. The photosensitive composition for photoresist comprises a copolymer with hydrophobic blocks whereof at least one block is an hydrophobic block capable of generating a hydrophilic block and comprising at its end a group selected among dithioesters, thioesters-thiones, dithiocarbamates and xanthates, and a photoactive compound capable of generating under the effect of a radiation an active species reacting with the hydrophobic block to generate the hydrophilic block.
    Type: Application
    Filed: March 19, 2003
    Publication date: September 4, 2003
    Inventors: Evelyne Prat, Mathias Destarac
  • Patent number: 6596456
    Abstract: Copolymers containing the units A, B, C, D and optionally E are used to prepare radiation sensitive compositions and lithographic printing plates. The copolymer contains about 25 to 55 mol % of unit A which has the formula The copolymer contains about 0.5 to 25 mol % of unit B which has the formula wherein R1 is selected from the group consisting of alkyl, aryl and aralkyl. The copolymer contains about 0.5 to 40 mol % of unit C which has the formula wherein X is an aliphatic or aromatic spacer group, and Ac is an acidic group selected from the group consisting of —COOH, —SO3H, —SO2NR9R10 with R9 and R10 independently being selected from hydrogen and alkyl; and when X is phenylene, Ac can also be OH.
    Type: Grant
    Filed: April 11, 2002
    Date of Patent: July 22, 2003
    Assignee: Kodak Polychrome Graphics LLC
    Inventors: Harald Baumann, Michael Flugel, Eduard Kottmair
  • Publication number: 20030091925
    Abstract: Copolymers containing the units A, B, C, D and optionally E are used to prepare radiation sensitive compositions and lithographic printing plates.
    Type: Application
    Filed: April 11, 2002
    Publication date: May 15, 2003
    Inventors: Harald Baumann, Michael Flugel, Eduard Kottmair
  • Patent number: 6562527
    Abstract: A method of manufacturing a selectively relief-treated image member that comprises: (a) providing a precursor of the image member, the precursor comprising a surface having an image-forming layer comprising a photosensitive resist composition comprising: (i) a polymerizable material, and (ii) a binder; (b) delivering radiation image-wise to the precursor; (c) developing the precursor in a developer in order to selectively remove the image-forming layer in regions to which said radiation was not delivered image-wise in step (b); and (d) contacting the image-wise exposed precursor with a relief-treatment material, in order to selectively relief-treat regions of the surface of the precursor in which the image-forming layer was removed on development in step (c).
    Type: Grant
    Filed: August 17, 2001
    Date of Patent: May 13, 2003
    Assignee: Kodak Polychrome Graphics LLC
    Inventors: Kevin Barry Ray, Hans-Horst Glatt, Ali Cam
  • Publication number: 20030082474
    Abstract: The present invention provides a thermally imageable composition, which includes an acid curable composition, an acid generator, a strong acid and optionally an infrared absorber. The present invention further provides an imageable element, which includes a substrate and a thermally imageable composition according to the present invention coated on a surface of the substrate. Also provided are methods of producing an imaged element according to the present invention.
    Type: Application
    Filed: August 21, 2001
    Publication date: May 1, 2003
    Applicant: Kodak Polychrome Graphics, L.L.C
    Inventors: Neil Haley, John Kalamen
  • Publication number: 20030054282
    Abstract: A negative-working lithographic printing plate has a coating which is imaged by heating an area of the coating with an infrared laser and actinically reacting the coating in the heated area with ultraviolet or visible radiation. The coating contains an infrared absorber but the coating is not imageable by infrared radiation or by the heat generated. The imaging time is reduced since the actinic reaction rate is increased at the elevated temperature.
    Type: Application
    Filed: September 16, 2002
    Publication date: March 20, 2003
    Inventors: Howard A. Fromson, William J. Rozell
  • Patent number: 6514657
    Abstract: The present invention provides a photosensitive lithographic printing plate with a long press life, high sensitivity, and excellent storage stability, and a photosensitive composition for a lithographic printing plate for producing such a photosensitive lithographic printing plate. The photosensitive composition for the lithographic printing plate includes (A) a binder resin, (B) a diazo resin, (C) a monomer or oligomer, a molecule of which has at least two polymerizable ethylenically unsaturated double bonds, (D) a photopolymerization initiator, (E) an o-tert-butylphenol derivative, and (F) a 2-mercaptoimidazole derivative such as 2-mercaptobenzimidazole.
    Type: Grant
    Filed: July 17, 2001
    Date of Patent: February 4, 2003
    Assignee: Kodak Polychrome Graphics, L.L.C.
    Inventors: Hideo Sakurai, Eiji Hayakawa
  • Publication number: 20030013035
    Abstract: The present invention includes an imageable element, which can be: (a) an imageable element comprising an imaging layer which comprises: an aromatic diazonium salt containing compound having an alkoxy substituent and an aromatic diazonium salt containing compound free of an alkoxy substituent; a polyvinyl acetal binder; and a sheet substrate; or (b) an imageable element comprising an imaging layer which comprises: an aromatic diazonium salt containing compound having an alkoxy substituent and an aromatic diazonium salt containing compound free of an alkoxy substituent; and a sheet substrate. The imaging layer includes a total aromatic diazonium salt containing compound content of at least 10 weight percent. The molar ratio of the aromatic diazonium salt containing compound having an alkoxy substituent to the aromatic diazonium salt containing compound that is free of an alkoxy substituent is from about 1.0:1 to 70:1.
    Type: Application
    Filed: July 12, 2001
    Publication date: January 16, 2003
    Applicant: Kodak Polychrome Graphics, L.L.C.
    Inventors: Stephan J. Platzer, Maria T. Sypek, Paul Perron, Harald Baumann, Melinda Alden
  • Patent number: 6503683
    Abstract: The invention resides in a photosensitive composition for screen printing. Preferably, the composition of the invention comprises a polymer comprising a vinylpyridine monomer or polymer having a pyridinium salt character and a photoreactable constituent. The resulting stencil, once dried, exposed, cured, and subjected to alkaline treatment obtains enhanced solvent/water resistance but can be reclaimed using an acidic wash. In use, the stencil provides a screen/stencil assembly or blockout utility of high structural integrity through repeated use and screen printing images of high resolution and quality.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: January 7, 2003
    Assignee: The Chromaline Corporation
    Inventors: Alexander S. Gybin, Kyle K. Johnson, Toshifumi Komatsu, Lawrence C. Vaniseghem
  • Publication number: 20020146633
    Abstract: A novel fluorinated aromatic acetal polymer comprises at least one unit of A and at least one unit of B or C, or at least one unit of each of A, B and C and optionally further comprises at least one unit of either D or E or at least one unit of each of D and E, wherein the units A and B and/or C, and optionally D and/or E are linked together by single covalent C-C bonds and have the formulae: 1
    Type: Application
    Filed: March 8, 2001
    Publication date: October 10, 2002
    Applicant: Kodak Polychrome Graphics L.L.C.
    Inventors: Stephan Platzer, Paul Perron, Melinda Alden
  • Patent number: 6458511
    Abstract: A radiation-sensitive composition comprises: (i) at least one component capable of absorbing IR radiation; and (ii) a diazonium polycondensation product soluble in an organic solvent; with the proviso that the composition does not contain components capable of reacting with decomposition products produced from IR radiation exposure of the diazonium polycondensation product. The composition may additionally comprise a polymeric binder of the type useful for conventional negative-working printing plates. The composition is suitable for preparing thermally imageable printing plate precursors and printing plates and may also be used in a method for providing an image on such plate precursors and printing plates.
    Type: Grant
    Filed: June 7, 2000
    Date of Patent: October 1, 2002
    Assignee: Kodak Polychrome Graphics LLC
    Inventors: Tobias Wittig, Hans-Joachim Timpe, Celin Savariar-Hauck
  • Patent number: 6458503
    Abstract: A novel fluorinated aromatic acetal polymer comprises at least one unit of A and at least one unit of B or C, or at least one unit of each of A, B and C and optionally further comprises at least one unit of either D or E or at least one unit of each of D and E, wherein the units A and B and/or C, and optionally D and/or E are linked together by single covalent C—C bonds and have the formulae: wherein RA is H or C1-C11 alky, or an aryl group that does not contain fluorine, and RB and RC are an aryl groups that contain fluorine. The polymer is prepared by reacting a hydrolyzed polyvinyl acetate polymer or copolymer with at least one non-fluorinated aldehyde component, and at least one fluorinated aromatic component. The polymer is useful is preparing a photosensitive composition which comprises at least one diazo resin and at least one such fluorinated aromatic acetal polymer.
    Type: Grant
    Filed: March 8, 2001
    Date of Patent: October 1, 2002
    Assignee: Kodak Polychrome Graphics LLC
    Inventors: Stephan Platzer, Paul Perron, Melinda Alden
  • Patent number: 6451491
    Abstract: A color ant dispersion having a pigment, a solvent composition of a C1-C8 aliphatic alcohol, a mono- or di-C1-C8 alkylene glycol C1-C8 alkyl ether, or a cyclic ketone; and an aqueous alkaline soluble or swellable polymeric compound which is the reaction product of a hydroxy containing polymer and an anhydride in the presence of a catalytic amount of a tertiary amine catalyst. The pigment and the polymeric compound are present in a high relative weight ratio of from about 0.75:1.25 to about 1.25:0.75. An admixture of the dispersion, a light sensitive component diazonium compound or photopolymerizable composition and an aqueous alkaline soluble or swellable polymeric binder, when coated and dried onto a substrate, forms a photographic element, which when imagewise exposed and developed has an exceptionally high contrast between image and removed non-image areas.
    Type: Grant
    Filed: October 16, 2000
    Date of Patent: September 17, 2002
    Assignee: Agfa Corporation
    Inventors: Major S. Dhillon, Stanley F. Wanat, Gerhard Sprintschnik
  • Publication number: 20020123001
    Abstract: The invention relates to a recording material having a dimensionally stable, two-dimensional support, preferably an aluminium support, and a negative-working, radiation-sensitive layer which comprises a diazonium salt, a polymeric binder and a sulphobetaine. In addition, the layer may also comprise a polymerizable monomer or oligomer and a photopolymerization initiator. The front of the recording material may be matted or pigmented, and the back may be coated with an organic polymeric material. The sulphobetaine improves the solubility of the diazonium salts in aqueous-alkaline developers without reducing the resistance of the offset printing plates produced from the recording material.
    Type: Application
    Filed: December 14, 2001
    Publication date: September 5, 2002
    Inventors: Michael Dorr, Andreas Elsasser
  • Patent number: 6426173
    Abstract: The present invention relates to a planographic printing plate employed in the field of offset printing, and more particularly, to a preparation method for a printing plate employing a conventional planographic printing original plate with a novel light source. In this method, an image is formed to a planographic printing original plate, in which at least one photosensitive layer sensitive in the region of 300 nm˜450 nm is provided on a substrate, by scan irradiating the plate with high density energy light in the form of the image, and then performing wet development and a post-treatment. This preparation method for the printing plate is characterized in that the output wavelength of the high density energy light is within the range of 300 nm or more, but less than 370 nm, and the high density energy light is high density energy light of the second or third harmonic obtained from a solid-state semiconductor or a solid-state exited by semiconductor.
    Type: Grant
    Filed: September 22, 2000
    Date of Patent: July 30, 2002
    Assignee: Kodak Polychrome Graphics LLC
    Inventors: Shinji Shimizu, Yasuhiko Kojima, Koji Oe