Silver Compound Sensitizer Containing Patents (Class 430/564)
  • Patent number: 5397687
    Abstract: The preparation of x-ray materials, especially suitable for non-destructive testing applications, is described. The emulsion layers of said material are comprising silver halide emulsion grains containing at least 75 mole % of silver chloride and less than 25 mole % of silver bromide and are characterized by a ratio between the amount of gelatin and the amount of silver halide, being expressed as the equivalent amount of silver nitrate, of less than 0.6. Hardening of said material is performed in such a way that the amount of demineralized water of 25.degree. C. absorbed in 3 minutes is less than 2.5 g per gram of gelatin present in said material. A rapid processing system is available with a total processing time of less than 3 minutes with a developer and fixer being substantially free from hardening agents and the fixer being substantially free from ammonium ions.
    Type: Grant
    Filed: December 14, 1993
    Date of Patent: March 14, 1995
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Peter Willems, Freddy Henderickx, Gino De Rycke, Romain Bollen
  • Patent number: 5354650
    Abstract: Photographic elements are described which contain a release compound that during photographic processing provides an imagewise distribution of a photographically inert compound which can react with a uniform distribution of a second compound contained in the element to form a photographically active compound.
    Type: Grant
    Filed: November 5, 1993
    Date of Patent: October 11, 1994
    Assignee: Eastman Kodak Company
    Inventors: David T. Southby, Daniel L. Kapp, Wojciech Slusarek, Louis E. Friedrich, Zbyslaw R. Owczarczyk, Xiqiang Yang
  • Patent number: 5326680
    Abstract: A silver halide color photographic light-sensitive material having at least one light-sensitive silver halide emulsion layer formed on a support wherein the light-sensitive material contains a compound represented by the following general formula (I): ##STR1## wherein A is a coupler residual or an oxidation-reduction group, X.sub.1 is an oxygen atom or a sulfur atom, X.sub.2 is an oxygen atom, a sulfur atom or NX.sub.6 group, W is a carbon atom or a sulfur atom, X.sub.3, X.sub.4, X.sub.5 and X.sub.6 are each a hydrogen atom or an organic residual, any two of X.sub.3, X.sub.4 and X.sub.5 can be bivalent groups which form a ring, PUG is a photographically useful group capable of bonding at a hetero-atom and, in the formula (I), n.sub.1 is 1 if W is a carbon atom, and either 1 or 2 if W is a sulfur atom. If n.sub.1 is 2, two X.sub.1 can either be identical or different. On the other hand, n.sub.2 is either 1 or 2. If n.sub.2 is 2, two X.sub.3, two X.sub.4, and two x.sub.5 are either identical or different.
    Type: Grant
    Filed: May 19, 1992
    Date of Patent: July 5, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Atsuhiro Ohkawa, Tatsuhiko Obayashi, Keiji Mihayashi
  • Patent number: 5310642
    Abstract: A silver halide photographic light-sensitive material for development in a development solution at a pH of at least 11.4 is disclosed. The material comprises a support having a silver halide emulsion layer comprising a compound capable of releasing a development inhibitor having a decomposition half-life in the range of above 4 to 225 hours at pH 10, said inhibitor after decomposition having substantially no photographic inhibitor properties, the compound having the formula:CAR--(TIME).sub.n --INH--L--Y (I).
    Type: Grant
    Filed: January 22, 1993
    Date of Patent: May 10, 1994
    Assignee: Eastman Kodak Company
    Inventors: J. Ramon Vargas, Paul A. Burns, Phillip D. Knight
  • Patent number: 5284726
    Abstract: The present disclosure describes a method called the rinse test for determining where silver is being lost and the variability of this loss in a photographic emulsion manufacturing process. Results from this method can be used to determine what parts of the emulsion manufacturing process should be improved to increase silver yield thereby reducing manufacturing costs and what parts of the emulsion manufacturing process should be improved to reduce silver loss variability thereby improving an emulsion's sensitometric response. The photographic emulsion manufacturing process includes at least one kettle and a plurality of processing equipment which may include sections of pipe, permeators, mixers and pumps. The silver loss is determined by adding water to a kettle after the product has been removed from but prior to cleaning of this kettle. The concentration of silver in this rinse water is measured and the amount of silver is determined.
    Type: Grant
    Filed: August 6, 1992
    Date of Patent: February 8, 1994
    Assignee: Eastman Kodak Company
    Inventors: William D. Munch, Kamala E. Huron, Douglas A. Neusch
  • Patent number: 5283162
    Abstract: There are described photographic elements containing novel release compounds which release a blocked photographically useful group, such as a blocked development inhibitor. The blocking group is removed during processing as a result of reaction with sulfite ion contained in one of the processing baths.
    Type: Grant
    Filed: May 29, 1992
    Date of Patent: February 1, 1994
    Assignee: Eastman Kodak Company
    Inventors: Daniel L. Kapp, Wojciech Slusarek, David T. Southby
  • Patent number: 5273859
    Abstract: A method for forming an image is disclosed. The method comprises the step of developing an imagewise exposed silver halide photographic material which contains a redox compound, with a developer which contains a silver halide developing agent and at least 0.1 mol/l of a sulfite and has a pH of 9 to 12, wherein the redox compound contains a redox group which is a hydrazine derivative which is capable of releasing a development inhibitor as a result of oxidation with the oxidized developer, and wherein after said oxidation, at least a portion of the development inhibitor is released into a developer where it reacts with a developer component and changes into a compound having little inhibiting effect. A silver halide photographic material used in that method is also disclosed.
    Type: Grant
    Filed: September 23, 1991
    Date of Patent: December 28, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazunobu Katoh, Hisashi Okamura, Morio Yagihara
  • Patent number: 5266442
    Abstract: A method for the production of a silver image with improved contrast by the development of an image-wise exposed photographic silver halide emulsion layer material with a developer liquid containing a hydroquinone in the presence of an auxiliary developing agent, wherein said developer liquid is applied to said photographic material containing silver halide grains that have been chemically sensitized with organic thiosulphonic acid anions in combination with a gold sensitizer in the absence of thiosulphate ions.
    Type: Grant
    Filed: December 17, 1991
    Date of Patent: November 30, 1993
    Assignee: Agfa-Gevaert N.V.
    Inventor: Richard A. Ooms
  • Patent number: 5256523
    Abstract: A compound (I) having a carrier moiety (CAR) and a releasable development inhibitor moiety (INH) capable of being released during photographic processing by means of at least one timing group (T) bonded to and releasable from the carrier moiety provides improved images in a photographic silver halide element and process when the inhibitor moiety (INH) comprises (R.sup.1) a non-aromatic, sterically hindered substituent group having (a) a tertiary carbon atom bonded directly to the releasable development inhibitor moiety or (b) a secondary carbon atom bonded directly to the releasable development inhibitor moiety and wherein the secondary carbon atom is not part of an unsubstituted carbocyclic ring containing at least 6 carbon atoms. Such compounds, particularly as couplers, are useful in photographic silver halide materials and processes to provide improved acutance and interimage effects.
    Type: Grant
    Filed: June 17, 1991
    Date of Patent: October 26, 1993
    Assignee: Eastman Kodak Company
    Inventors: Richard P. Szajewski, Jerrold N. Poslusny
  • Patent number: 5252449
    Abstract: A photographic silver halide emulsion comprising silver halide grains having a chloride content of at least 90 mole percent and a rhodium salt, wherein said grains have been sensitized with a black and white developing agent, provides a substantial improvement in bright room tolerance as compared to emulsions sensitized with more conventional sensitizing agents, without loss of speed or contrast. A process for improving the bright room tolerance of a photographic emulsion comprising silver halide grains having a chloride content of at least 90 mole percent and a rhodium salt comprises the step of sensitizing the grains with a black and white developing agent.
    Type: Grant
    Filed: September 25, 1992
    Date of Patent: October 12, 1993
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: John R. Shock
  • Patent number: 5242783
    Abstract: A novel blocked photographically useful compound element and process are based on a new blocking group that comprises a beta-ketocarbonyl group that is part of a 5- to 7-member heterocyclic ring containing a hetero-atom not adjacent to the beta-ketocarbonyl group. Such a blocked photographically useful compound provides a photographic material and process enabling more rapid release of the photographically useful group upon processing.
    Type: Grant
    Filed: July 23, 1992
    Date of Patent: September 7, 1993
    Assignee: Eastman Kodak Company
    Inventors: John M. Buchanan, Gary S. Proehl
  • Patent number: 5204213
    Abstract: A silver halide photographic material comprising at least one silver halide emulsion layer on a support, characterized in that there is contained a compound represented by the general formula ##STR1## wherein R.sup.1 and R.sup.2 each represents a hydrogen atom, aliphatic group, aromatic group or heterocyclic group, with the proviso that R.sup.1 and R.sup.2 may be connected to each other to form a ring; L represents a divalent linking group; V represents a carbonyl group, ##STR2## group, sulfonyl group, sulfoxy group, ##STR3## group (in which R.sub.0 represents an alkoxy group or aryloxy group), iminomethylene group or thiocarbonyl group; Time represents a divalent linking group; m represents an integer 0 or 1; n represents an integer 0 or 1; PUG represents a photographically useful group; and X represents an atomic group required to form a 5- or 6-membered ring with ##STR4## wherein R.sup.1, R.sup.
    Type: Grant
    Filed: February 13, 1991
    Date of Patent: April 20, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okada, Morio Yagihara
  • Patent number: 5202225
    Abstract: Disclosed is a silver halide photographic material comprising a support, having thereon at least one silver halide emulsion layer, wherein there is contained in the silver halide emulsion layer or other hydrophilic colloid layer a compound of which an oxidized form is produced in accordance with development of the silver halide and is capable of releasing a photographically useful group by means of a conjugated addition-elimination mechanism due to an intramolecular nucleophilic group attack.
    Type: Grant
    Filed: August 14, 1991
    Date of Patent: April 13, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takeshi Nakamine, Takayuki Ito, Naoto Matsuda, Koki Nakamura, Hiroyuki Hirai
  • Patent number: 5198327
    Abstract: For formation of a photographic image by development of a silver halide photographic material with an automatic developing machine, a certain period of time or not longer than 15 seconds is set as the time of the development step and a silver halide photographic material is used which, when developed for a period of one-half of said certain period of time after such an exposure that the exposed silver halide photographic material, when developed for said certain period of time, would give a value of (Dmax-fog).times.1/2, gives a value of (D-fog) having 70% or more of the value of (Dmax-fog).times.1/2. The silver halide photographic material comprises at least one of a combination of (1), (2) and (3) or (2) and (4): where: (1) represents a silver halide emulsion containing a water-soluble iridium salt; (2) represents a silver halide emulsion layer with a silver amount from 1 to 3.5 grams/m.sup.2 coated on one surface of said emulsion layer; (3) represents silver halide grains wherein the mean grain size is 1.
    Type: Grant
    Filed: December 23, 1991
    Date of Patent: March 30, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Minoru Yamada, Naoki Arai, Kazuo Kagawa
  • Patent number: 5190846
    Abstract: A silver halide photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer, wherein the silver halide photographic material contains at least one photographic agent represented by the following formula (I): ##STR1## wherein X represents a hydrogen atom or a group capable of forming a hydrogen atom upon hydrolysis; Time represents a divalent linking group; PUG represents a photographically useful group; V represents ##STR2## wherein R.sub.0 represents n alkoxy group or an aryloxy group, ##STR3## an iminomethylene group or ##STR4## R.sub.1 represents a hydrogen atom, an aliphatic group, an aromatic group, a heterocyclic group, an alkoxy group, an aryloxy group, an amino group or --CHR.sub.2 --(Time).sub.m PUG; R.sub.2 represents a hydrogen atom, an aliphatic group, an aromatic group or a heterocyclic group; m represents 0 or 1; and n represents 0 or 1.
    Type: Grant
    Filed: November 13, 1990
    Date of Patent: March 2, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Hisashi Okamura, Kazunobu Katoh
  • Patent number: 5190852
    Abstract: Disclosed is a silver halide photographic material comprising a support having thereon at least one layer containing a compound represented by general formula (I): ##STR1## wherein EAG represents an electron-accepting group; A represents a group which undergoes a reaction triggered by the cleavage of the oxygen-nitrogen single bond in the general formula to release PUG; B represents a hydrogen atom or an alkyl group, an aralkyl group, an aryl group, a heterocylic group, an acyl group, a sulfonyl group, a carbamoyl group, a sulfamoyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, an alkoxysulfonyl group or an aryloxysulfonyl group which may contain substituents; the solid lines indicate a single bond; the broken lines indicate that either of these line is a bond, with the proviso that when the broken line between N and A represents a bond, B is not present; EAG and B, and A and B may be connected to each other to form a ring; EAG may be connected to a polymer residue to fix the compound of general f
    Type: Grant
    Filed: February 12, 1992
    Date of Patent: March 2, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naoto Matsuda, Michio Ono
  • Patent number: 5171559
    Abstract: A process for removing heavy metals from a silver nitrate solution is disclosed. The process comprises the step of bringing said silver nitrate solution into contact with activated alumina having a surface acidity of at least 8 and an average pore diameter of not more than 50 .ANG..
    Type: Grant
    Filed: July 19, 1991
    Date of Patent: December 15, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kikuo Ando
  • Patent number: 5156946
    Abstract: A silver halide photographic material comprising at least one silver halide emulsion layer on a support, wherein the latent image distribution of silver halide grains contained in the at least one emulsion layer has at least one peak value within the grains, the location of the peak value is at a depth of less than 0.01 .mu.m from the surface of the grains, and the average silver iodide content of the grains is about 15 mol % or less.
    Type: Grant
    Filed: May 25, 1989
    Date of Patent: October 20, 1992
    Assignee: Fuji Photo Film Co., Ltd
    Inventors: Katsuro Nagaoka, Shinsuke Bando, Takefumi Hara
  • Patent number: 5134055
    Abstract: A silver halide photographic material is disclosed, which has at least one compound represented general formula (1): ##STR1## wherein R represents an aliphatic group, an aromatic group, or a heterocyclic group; both L and Time represent a divalent organic group; t represents 0 or 1; PUG represents a photographically useful group; Y represents --SO.sub.2 --, --Y'--SO.sub.2 --, or ##STR2## and Y' represents --O--, --NH--, or ##STR3## The material has a broad exposure latitude in line image-taking work and has a high resolving power in the work. It can form an ultrahard image having a high gamma value of 10 or more. The material may excellently reproduce a line original to form an ultrahard image having a high background density. It also has a broad exposure latitude in halftone dot image-taking work and can form a halftone dot image having ultrahigh contrast with high image quality.
    Type: Grant
    Filed: April 20, 1990
    Date of Patent: July 28, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okamura, Hisashi Okada, Morio Yagihara, Kazunobu Katoh, Keiji Mihayashi
  • Patent number: 5134061
    Abstract: Photographically useful organic compounds containing secondary-branched alkyl radicals with at least 15 C atoms corresponding to formula I have a low melting point, good solubility in oil formers and a low tendency towards crystallization which makes them particularly suitable for photographic applications. ##STR1## In formula I: PNOV is the residue of a photographically useful organic compound, for example a coupler or oil former;L is a chemical bond or a link between PNOV and X;X represents --O--, --S--, --SO--, --SO.sub.2 --, --NH--, --NR-- (R.dbd.alkyl or acyl), --CO-- or alkylidene;R.sup.1 and R.sup.2 are unbranched alkyl radicals containing at least 6 C atoms, with the proviso that R.sup.1 and R.sup.2 together contain at least 14 C atoms and, where X represents --CO-- or --CH.sub.2, at least 17 C atoms.
    Type: Grant
    Filed: March 18, 1991
    Date of Patent: July 28, 1992
    Assignee: Agfa Gevaert Aktiengesellschaft
    Inventor: Erich Wolff
  • Patent number: 5132201
    Abstract: A silver halide photographic material composed of a support having thereon at least one light-sensitive silver halide emulsion layer, at least one layer of the material containing a compound represented by formula (I): ##STR1## wherein X represents hydrogen or a group capable of providing hydrogen upon hydrolysis; Time represents a divalent linking group; t is 0 or 1; PUG represents a photographically useful group; V represents a carbonyl group, a sulfonyl group, a sulfoxy group, an iminomethylene group, ##STR2## wherein W represents an electrophilic group, or V represents ##STR3## wherein R.sub.0 represents an alkoxy group or an aryloxy group; and R represents hydrogen, an aliphatic group, an aromatic group or ##STR4## wherein PUG, Time, t, and W are as defined above. The redox compound is capable of releasing a photographically useful reagent using any conventional developing agent, has excellent storage stability, and provides rapid release of the photographically useful reagent.
    Type: Grant
    Filed: November 12, 1991
    Date of Patent: July 21, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Hisashi Okada
  • Patent number: 5116717
    Abstract: A silver halide photographic material composed of a support having thereon at least one silver halide photosensitive emulsion layer, at least one layer of the material containing a blocked photographic reagent precursor represented by formula (I): ##STR1## wherein X.sub.1 represents a divalent linking group containing a hetero atom bonded to the carbon atom, provided that X.sub.1 is linked to the carbon atom by a group other than ##STR2## PUG represents a photographically useful group containing a hetero atom bonded to X.sub.1 ; W represents .dbd.N-- or ##STR3## Y.sub.1 represents hydrogen or a group capable of being substituted; Z represents an atomic group necessary for forming a heterocyclic ring, provided that when W represents a ##STR4## the group adjacent to W in the heterocyclic ring is a group other than ##STR5## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.
    Type: Grant
    Filed: February 25, 1991
    Date of Patent: May 26, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsunori Matsushita, Morio Yagihara
  • Patent number: 5075208
    Abstract: A silver halide photographic material containing a compound having a structure represented by formula (I) ##STR1## wherein EAG represents a group capable of accepting an electron from a reducing material; E represents an electron-attracting group; R.sup.3 represents an atomic group necessary for forming a 5-membered to 8-membered single ring or condensed ring by combining with the carbon atom carrying EAG and E; ETG represents an electron-transmitting group; n represents 0 or 1; R.sup.1 and R.sup.2, which may be the same or different, each represents a hydrogen atom, a hydrocarbon group, a heterocyclic group, or a single bond for forming a ring with EAG; Time represents a group releasing PUG upon cleavage of the bond between the carbon atom carrying R.sup.1 and R.sup.2 and Time; t represents 0 or 1; and PUG represents a photographically useful group.
    Type: Grant
    Filed: September 11, 1990
    Date of Patent: December 24, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Watanabe, Keizo Koya, Yasuhiro Yoshioka, Koki Nakamura
  • Patent number: 5070008
    Abstract: A light-sensitive silver halide photographic material which comprises a support and provided thereon a silver halide emulsion layer containing silver halide grains of which silver chloride content is not less than 90 mol %, and which have been formed in the presence of an iridium compound and a nitrogen containing heterocyclic compound, and under acidic condition is disclosed.
    Type: Grant
    Filed: November 14, 1990
    Date of Patent: December 3, 1991
    Assignee: Konica Corporation
    Inventors: Hideaki Maekawa, Masanobu Miyoshi
  • Patent number: 5064752
    Abstract: A silver halide photographic material comprising a support having provided thereon at least two hydrophilic colloid layers, wherein at least one of the hydrophilic layers comprises water or a hydrophilic colloid and a compound represented by formula (I) dispersed therein using water or a water-soluble organic solvent:PWR-(Time).sub.t -PUG (I)wherein PWR represents a group capable of releasing (Time).sub.t -PUG upon reduction;Time represents a group capable of releasing the PUG residual group by the successive reaction, after being released as (Time).sub.t -PUG;t represents 0 or 1;PUG represents a photographically useful group; and at least one water-soluble group exists in one molecule of the compound.
    Type: Grant
    Filed: June 25, 1990
    Date of Patent: November 12, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazunobu Katoh, Kozo Sato, Keisuke Shiba
  • Patent number: 5059499
    Abstract: A hologram is directly recorded in a sensitized metal substrate. The hologram may be an amplitude hologram, or may be treated to produce a phase relief hologram which may be stamped into a plastic material for reproduction, be archivally stored, or used as a master for electroforming a second durable surface relief hologram for use as an embossing master. A suitable material is prepared from a polished silver plate exposed to halogen vapors. After exposure, the plate is developed and fixed, and the surface is differentially etched to form a surface relief suitable for hologram embossing. Daguerreotype processes are modified to make surface amplitude holograms and phase holograms. By etching through a metal film a semiconductor mask is obtained. By depositing a silver film directly on a wafer, masks are made with very high feature definition.
    Type: Grant
    Filed: June 3, 1988
    Date of Patent: October 22, 1991
    Inventor: Michael Teitel
  • Patent number: 5051336
    Abstract: A negative type silver halide photographic material is disclosed. The material comprises a support having provided thereon at least one silver halide emulsion layer containing silver halide grains sensitized with gold and sulfur sensitizers, the emulsion layer or at least one other hydrophilic colloid layer containing at least one high contrast-imparting hydrazine derivative and at least one compound represented by the following general formula (I): ##STR1## wherein Z represents N or C--X wherein X represents a substituted or unsubstituted alkyl or aryl group, Y represents a substituted or unsubstituted alkyl or aryl group, and M represents a hydrogen atom, a metallic atom, or ammonium which may be substituted.
    Type: Grant
    Filed: May 11, 1990
    Date of Patent: September 24, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuaki Inoue, Senzo Sasaoka, Tetsuo Yoshida
  • Patent number: 5047317
    Abstract: A silver halide photographic light-sensitive material having at least one light-sensitive silver halide emulsion layer on a support, wherein the ratio of the total weight of potassium ion in the photographic light-sensitive material to the total weight of silver in the photographic light-sensitive material is 1.times.10.sup.-3 or less. The silver halide photosensitive material is improved in long-term storage stability.
    Type: Grant
    Filed: October 5, 1990
    Date of Patent: September 10, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeru Shibayama, Shunichi Aida, Toshio Aizu, Shunji Takada
  • Patent number: 5026628
    Abstract: Photographic compound (A) capable of releasing a photographically useful group is represented by the formula: SOL-CAR-LINK-PUG wherein SOL is a water-solubilizing group; CAR is a carrier moiety that, upon reaction with oxidized developing agent, is capable of releasing LINK-PUG and capable of forming a compound that is washed out of the photographic element during photographic processing; LINK-PUG is in turn capable of releasing a photographically useful group (PUG) during photographic processing and LINK-PUG is represented by the formula: ##STR1## wherein X, R.sub.1, R.sub.2, R.sub.3, R.sub.4 and PUG are as defined in the application. The photographic compound (A) enables formation of easily removable compounds in photographic elements and processes that provide images having improved acutance.
    Type: Grant
    Filed: February 22, 1990
    Date of Patent: June 25, 1991
    Assignee: Eastman Kodak Company
    Inventors: William J. Begley, Teh-Hsuan Chen, Kenneth N. Kilminster, Jerrold N. Poslusny, Wojciech Slusarek
  • Patent number: 4994363
    Abstract: A novel silver halide light-sensitive material is provided, comprising a compound represented by the general formula (I): ##STR1## wherein EAG represents an aromatic group which receives electrons from a reducing substance; R.sup.1 represents hydrogen atom or a substituent; R.sup.2 represents an electrophilic group, with the proviso that R.sup.1 and R.sup.2 may be in the position of cis or trans to each other; R.sup.3 and R.sup.4 each represents hydrogen atom or a hydrocarbon group; ETG represents a group capable of transferring electrons; e represents an integer 0 or 1; Time represents a group which undergoes reaction triggered by the cleavage from the carbon carrying R.sup.3 and R.sup.4 to release PUG; t represents an integer 0 or 1; and PUG represents a photographically useful group.In a preferred embodiment, R.sup.1 represents an aromatic group, heterocyclic group or group represented by --Y.sup.1 --R.sup.5 in which Y.sup.1 represents a hetero atom or hetero atomic group and R.sup.
    Type: Grant
    Filed: December 19, 1988
    Date of Patent: February 19, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keizo Koya, Koki Nakamura, Hiroyuki Watanabe, Yasuhiro Yoshioka
  • Patent number: 4942114
    Abstract: A silver halide photographic material having at least one silver halide emulsion layer on a support, comprising a compound of formula (I):PWR--(Time).sub.t --FWA (I)in which PWR represents a group capable of releasing (Time).sub.t --FWA upon reduction; FWA represents a group which functions as a brightening agent; Time represents a group capable of releasing FWA through a reaction which follows the release of (Time).sub.t --FWA from PWR; and t represents an integer of 0 or 1.
    Type: Grant
    Filed: May 2, 1988
    Date of Patent: July 17, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keisuke Shiba, Keizo Koya
  • Patent number: 4942119
    Abstract: Silver sodalites with cages containing anions such as oxalate, formate, halide, carbonate, sulphide etc. have silver compositions entrapped or encapsulated in the cages of a microporous sodalite lattice. The cages of the sodalite lattice have very small but very even sizes e.g. 6.6 A diameters, so that the silver compositions trapped therein are also of very small but very even sizes. The silver compositions may be sensitive to the application of light, and may be sensitive to thermal or pressure stimuli. Thus, images produced by, for example, irradiation of the materials can be of very high resolution. The silver sodalite materials are prepared by a silver ion exchange process, from synthetic sodium sodalites.
    Type: Grant
    Filed: August 3, 1988
    Date of Patent: July 17, 1990
    Inventors: Geoffrey A. Ozin, John Godber, Andreas Stein
  • Patent number: 4923790
    Abstract: A silver halide photographic material composed of a support having thereon at least one light-sensitive silver halide emulsion layer, wherein the material contains the combination of (i) at least one compound represented by formula (I) and (ii) and at least one compound represented by formulae (II) and/or (III): ##STR1## wherein R.sub.1 represents hydrogen, an alkyl group, an aryl group or an aralkyl group; X represents a halogen atom, a nitro group, a hydroxyl group, a cyano group, a lower alkyl group, a lower alkoxy group, --COR.sub.2, ##STR2## or --SO.sub.3 M; R.sub.2 represents hydrogen, --OM, a lower alkyl group, an aryl group, an aralkyl group, a lower alkoxy group, an aryloxy group, an aralkyloxy group or ##STR3## R.sub.3 and R.sub.4 each represents hydrogen, a lower alkyl group, an aryl group, an aralkyl group, --COR.sub.7 or --SO.sub.2 R.sub.7 ; R.sub.5 and R.sub.6 each represents hydrogen, a lower alkyl group, an aryl group or an aralkyl group; R.sub.
    Type: Grant
    Filed: September 22, 1988
    Date of Patent: May 8, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hirohiko Kato, Keiji Mihayashi, Kazuhiro Aikawa
  • Patent number: 4916047
    Abstract: A silver halide light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, and containing a compound containing a repeating unit, said compound containing a repeating unit being connected at the repeating unit to a compound represented by formula (I) at the position of the PWR or Time moiety:PWR--Time.sub.t PUG (I)wherein PWR represents a moiety capable of releasing (Time.sub.t PUG upon reduction, and PUG represents a group which can fulfil a photographically useful function after the release; Time represents a moiety capable of releasing PUG through a reaction subsequent to the release from PWR in the form of --Time.sub.t PUG; and t represents 0 or 1.
    Type: Grant
    Filed: April 29, 1988
    Date of Patent: April 10, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keizo Koya, Junichi Yamanouchi, Masaharu Toriuchi, Yoshisada Nakamura
  • Patent number: 4912029
    Abstract: Silver halide photographic materials of which the distinguishing features are that surface latent image type mono-disperse silver chlorobromide emulsions consisting of silver chlorobromide which is essentially silver iodide free, obtained by subjecting the surface of silver halide grains which have a plurality of layers which have different halogen compositions within the grains to halogen conversion, are included in at least one emulsion layer on a support.
    Type: Grant
    Filed: May 13, 1988
    Date of Patent: March 27, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Masahiro Asami
  • Patent number: 4912028
    Abstract: Intramolecular nucleophilic displacement compound or a precursor thereof wherefrom during photographic processing a photographically useful group can be split off, said intramolecular nucleophilic displacement compound or precursor thereof corresponding to the following general structure (I): ##STR1## wherein Nu.sup.1 represents a nucelophilic group e.g. HO, H.sub.2 N or Hs, or a precursor of such nucleophilic group e.g. an oxidized nucleophilic group e.g. O.dbd. or HN.dbd., or RO wherein R is an alkyl, an acyl, an aryl or a trialkylsilanyl group, which groups may be substituted, the said nucleophilic group or precursor thereof being located in adjacent position to C(R.sup.1 R.sup.2) so as to make possible elimination of PUG through a nucleophilic displacement reaction;Ar represents an aryl group or a heteroaryl group (e.g. pyridine), which groups may be substituted by one or more mono-atomic or poly-atomic groups, e.g.
    Type: Grant
    Filed: June 2, 1988
    Date of Patent: March 27, 1990
    Assignee: AGFA-GEVAERT, N.V.
    Inventor: Luc J. Vanmaele
  • Patent number: 4897340
    Abstract: A silver halide photographic material is disclosed which has at least one hydrophilic colloidal layer on a support, said photographic material having a water content of 10-20 g/m.sup.2 at the time when the washing step of processing with a roller transport type automatic processor is completed.
    Type: Grant
    Filed: December 5, 1988
    Date of Patent: January 30, 1990
    Assignee: Konica Corporation
    Inventors: Shinichi Ohtani, Teruo Kashino, Katsushi Fujita, Akio Suzuki, Eiji Yoshida, Satoru Nagasaki
  • Patent number: 4892811
    Abstract: A silver halide photographic material which comprises a support having coated thereon a light-sensitive silver halide emulsion layer, wherein the photographic material contains a blocked photographic agent represented by the following general formula (I): ##STR1## wherein A represents a photographic agent moiety which is bonded to a blocking moiety through a hetero atom, or a precursor thereof; R.sup.1 represents a hydrogen atom or a substituent group; and Z represents atoms necessary to form a carboxylic ring or a heterocyclic ring. The blocked photographic agent is completely stable upon storage of the photographic material, and releases a photographic agent at a desired time upon processing of the photographic material. The blocked photographic agent also exhibits its function to a substantial degree over a wide range.
    Type: Grant
    Filed: November 16, 1987
    Date of Patent: January 9, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Mitsunori Ono, Akihiko Ikegawa
  • Patent number: 4891304
    Abstract: A silver halide photographic material comprising a support having provided thereon at least one silver halide emulsion layer containing a compound represented by formula (I): ##STR1## wherein EAG represents an aromatic group bonding to N.sub.A and capable of accepting an electron;N.sub.A and N.sub.B each represents a nitrogen atom;R.sup.1 represents a lone pair, a .pi.-bond, a .sigma.-bond, or a substituent other than a hyudrogen atom;n represents 2 or 3;m represents 0 when n represents 2, or m represents 1 and N.sub.B has a positive charge when n represents 3;X.sup..crclbar. represents an anion;the groups or bonds represented by R.sup.1 may be combined with each other or may be combined with EAG to form a ring;R.sup.2 represents R.sup.3 --CO--, R.sup.3 --SO.sub.2 --, R.sup.3 --CO--N.dbd.CH--, or R.sup.3 --SO.sub.2 --N.dbd.CH--, wherein R.sup.3 represents an alkyl group, an aryl group, or a heterocyclic group;the group represented by R.sup.2 may be combined with at least one of R.sup.
    Type: Grant
    Filed: March 30, 1989
    Date of Patent: January 2, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Koki Nakamura
  • Patent number: 4886738
    Abstract: A silver halide color photographic material comprising a support having thereon at least one silver halide photographic emulsion layer and at least one layer containing colloidal silver, wherein said colloidal silver-containing layer comprises at least one compound selected from compounds of general formula (I) and (II) below, and at least one photosensitive or non-photosensitive layer selected from a silver halide photosensitive layer positioned farthest from said support and any layers positioned between said farthest photosensitive layer and said support comprises a silver halide emulsion containing internally-fogged or surface-fogged silver halide grains: ##STR1## wherein the substituent groups on general formula (I) and (II) are as defined in the specification.
    Type: Grant
    Filed: October 5, 1987
    Date of Patent: December 12, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naoyasu Deguchi, Sadao Kamei, Kensuke Goda, Sadanobu Shuto, Yasuhiro Hayashi
  • Patent number: 4879207
    Abstract: A safelight for use in handling a silver halide photographic light-sensitive material and a process for manufacturing a silver halide photographic light-sensitive material using the safelight. The safelight has an electroluminescence element as a light source and an effect to lower the fog formation tendency of the photographic material. And a silver halide photographic light-sensitive material manufactured in the safelight is improved on the allowable handling time in safelight.
    Type: Grant
    Filed: April 12, 1988
    Date of Patent: November 7, 1989
    Assignee: Konica Corporation
    Inventors: Kazuhiro Yoshida, Yasuhiko Takamuki
  • Patent number: 4873179
    Abstract: A method for processing a silver halide color photographic material which comprises, after color development of a silver halide color photographic material comprising a support having thereon at least one light-sensitive silver halide emulsion layer and at least one compound capable of releasing, upon a reaction with an oxidation product of a developing agent, a compound which is capable of releasing a development inhibitor upon a reaction with another molecule of an oxidation product of a developing agent, treating said photographic material with a liquid having a fixing ability, followed by processing thereof while replenishing washing water or a stabilizing solution in an amount of from 2 to 50 times the amount carried over from the preceding bath per unit area of the silver halide color photographic material.
    Type: Grant
    Filed: May 20, 1987
    Date of Patent: October 10, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akira Abe, Keiji Mihayashi, Seiji Ichijima
  • Patent number: 4863838
    Abstract: A direct positive photographic material having a support and a silver halide emulsion layer thereon contains internal latent image type silver halide grains. These grains have a core/shell structure and have not been previously fogged. Each grain comprises a conversion type silver halide core and a silver halide shell over the core.The layer would produce, when exposed for a given time upto one second and developed at 20.degree. C. for 4 minutes with a certain internal developing solution, a maximum density which is at least five times that obtained when the layer is similarly exposed and developed with a particular surface developing solution.
    Type: Grant
    Filed: May 2, 1988
    Date of Patent: September 5, 1989
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Keiji Ogi, Yasuo Tosaka
  • Patent number: 4861701
    Abstract: Photographic compounds capable of releasing a photographically useful group are more effective in photographic materials when the photographic compounds comprise at least two differing timing groups in sequence between a carrier moiety and the photographically useful group. The two timing groups in sequence enable improved timing and control of release of the photographically useful group.
    Type: Grant
    Filed: October 5, 1987
    Date of Patent: August 29, 1989
    Assignee: Eastman Kodak Company
    Inventors: Paul A. Burns, Terry R. Taber
  • Patent number: 4861702
    Abstract: A silver halide photographic light-sensitive material and a process for processing it are disclosed. The light-sensitive material is improved in photographic sensitivity, drying property and anti-roller-mark property and is suitable for the disclosed ultra-rapid processing by an automatic processor in which the photographic material is processed for the time of 20 sec to 60 sec in total. The light-sensitive material comprises a support having on at least one side thereof one or more hydrophilic layers containing gelatin which comprise at least one light-sensitive silver halide emulsion layer. An amount of the gelatin contained in said hydrophilic layer or layers is within the range of from 1.90 to 3.50 g/m.sup.2 and a swelling amount of said hydrophilic layer or layers is within the range of from 30 to 58 g/m.sup.2 when said light-sensitive material is treated in a specific condition for 15 sec. at 35.degree. C.
    Type: Grant
    Filed: January 11, 1989
    Date of Patent: August 29, 1989
    Assignee: Konica Corporation
    Inventors: Akio Suzuki, Eiji Yoshida, Satoru Nagasaki, Masumi Arai, Nobuaki Tsuji
  • Patent number: 4859576
    Abstract: A silver halide photographic material having a high covering power with improved pressure resistance and antistatic properties upon development, which comprises at least one silver halide photographic emulsion layer disposed on at least one side of a support, wherein at least one of the silver halide photographic emulsion layer(s) contains a photosensitive silver halide emulsion containing silver iodide and an internally fogged silver halide emulsion, and at least one of the silver halide photographic emulsion layer(s) and an auxiliary layer(s) which is disposed on the same side of the support as that of the support having said emulsion containing silver iodide contains at least one polyoxyethylenic surface active agent selected from the group consisting of compounds represented by formula (I) and (II) ##STR1## wherein R.sub.1, R.sub.2, R.sub.6, R.sub.8, R.sub.10, and R.sub.
    Type: Grant
    Filed: March 29, 1988
    Date of Patent: August 22, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuaki Miyasaka, Shigeki Yokoyama, Shuzo Suga, Takashi Naoi, Masaki Satake
  • Patent number: 4857440
    Abstract: Photographic compound (A) capable of releasing a photographically useful group by means of intramolecular nucleophilic displacement exhibits increased resistance to hydrolysis when the compound contains in a coupling position a coupling-off group represented by the formula: ##STR1## wherein Q, R.sub.q, R.sub.1, R.sub.2, R.sub.3, n and PUG are as defined in the application. Such a compound (A) is useful in a photographic silver halide material and process.
    Type: Grant
    Filed: June 30, 1988
    Date of Patent: August 15, 1989
    Assignee: Eastman Kodak Company
    Inventors: William J. Begley, Michael J. Carmody, John M. Buchanan
  • Patent number: 4847185
    Abstract: Photographic compounds capable of releasing a photographically useful group (PUG) by means of an intramolecular nucleophilic displacement provide increased image acutance when a coupling-off group in the coupling position of the compound is a group of the formula: ##STR1## wherein PUG is a photographically useful group; Q is N or C--R where R is hydrogen or a substituent that does not adversely affect imaging; and Z represents atoms completing a non-aromatic, heterocyclic ring. The photographic compounds are useful in photographic materials and processes.
    Type: Grant
    Filed: June 30, 1988
    Date of Patent: July 11, 1989
    Assignee: Eastman Kodak Company
    Inventors: William J. Begley, Michael J. Carmody, John M. Buchanan
  • Patent number: H662
    Abstract: In a process for producing a silver halide emulsion through mixing a halide solution and a silver nitrate solution in the presence of a hydrophilic colloid, the improvement is disclosed wherein any part of the equipment that is employed in the process starting with the initiation of silver halide formation and ending with the coating of the emulsion on a support and with which the reaction solution will come in contact is made of a stainless steel having a molybdenum content of 2.2-5.0 wt %.
    Type: Grant
    Filed: April 16, 1987
    Date of Patent: August 1, 1989
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Toshio Saito, Akihiko Kabasawa, Masami Ishikura, Sadayuki Miyazawa, Nobuo Suzuki
  • Patent number: H830
    Abstract: A novel silver halide color photographic material containing a desilvering accelerator releasing compound, which comprises at least one light-sensitive silver halide emulsion layer on a support, wherein at least one of said emulsion layer and a non-light sensitive hydrophilic layer(s) contains at least one compound represented by the formula (I)PWR--Time--.sub.t BA (I)wherein PWR represents a group which undergoes reduction to release (Time--.sub.t BA; BA represents a group which becomes a desilvering accelerator after being released; Time represents a group which releases BA through a reaction after being released from PWR as (Time--.sub.t BA; and t represents an integer of 0 or 1.
    Type: Grant
    Filed: May 2, 1988
    Date of Patent: October 2, 1990
    Inventors: Naoyasu Deguchi, Shinji Ueda, Koki Nakamura