Silver Compound Sensitizer Containing Patents (Class 430/564)
  • Patent number: 4565778
    Abstract: Silver halide photographic materials with higher sensitivity and less fogging having at least one silver halide emulsion layer over a photographic base or support wherein the emulsion of said emulsion layer substantially contains core/shell-type silver halide grains or core/shell-type monodisperse silver halide grains, core portion of said grain containing silver iodide in a greater amount than that contained in shell portion of said grain and said emulsion is subjected to chemical ripening in the presence of a labile selenium compound, optionally with coexistence of a silver halide solvent, and said emulsion may contain further a specific phenol compound.
    Type: Grant
    Filed: March 26, 1984
    Date of Patent: January 21, 1986
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Akihiko Miyamoto, Hideki Takiguchi, Shoji Matsuzaka, Hiroshi Kashiwagi, Yoshiyuki Nonaka
  • Patent number: 4560638
    Abstract: An unballasted arylhydrazide is disclosed the aryl moiety of which is substituted with a group of the formula ##STR1## where one of X and X' represents --NH--, the other represents a divalent chalcogen, and R represents an aliphatic or aromatic residue. The arylhydrazides, when applied to halftone imaging in conjunction with silver halide emulsions, photographic elements, and imaging processes, produce images of improved dot quality and low levels of pepper fog.
    Type: Grant
    Filed: October 9, 1984
    Date of Patent: December 24, 1985
    Assignee: Eastman Kodak Company
    Inventors: James C. Loblaw, Barbara B. Lussier
  • Patent number: 4554245
    Abstract: A color reversal photographic light-sensitive material is disclosed. The material is comprised of a support base having thereon a silver halide emulsion layer, an organic compound and colloid grains of a metal or metal sulfide or silver halide grains the surface of which is previously fogged. The silver halide emulsion layer includes fine grains of silver halide particles having a particle size of 0.3.mu. or less. The fine grain particles are present in the emulsion in an amount in the range of about 30% to about 95% based on the total number of silver halide grains in the emulsion. The silver halide emulsion also includes coarse grains having a particle size of more than 0.3.mu.. The organic compound has a solubility product constant of 10.sup.-14 or less when forming a salt with a silver ion.
    Type: Grant
    Filed: January 30, 1984
    Date of Patent: November 19, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yasuhiro Hayashi, Naoyasu Deguchi, Hiroyuki Yamagami, Kensuke Goda, Kazunori Hasebe
  • Patent number: 4552834
    Abstract: The bleaching from photographic elements of silver produced by the development of silver halide having a dye adsorbed to its surface by employing as a bleaching agent a ferric complex of a polycarboxylic acid is improved by the presence of a compound of the formula: ##STR1## wherein Ar is an aromatic linking group,R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are hydroxy substituted lower alkyl groups,R.sup.5 and R.sup.6 are lower alkanediyl groups,X is a charge balancing counter ion,x and y are 0 or 1, andz is 0, 1, or 2.
    Type: Grant
    Filed: March 28, 1985
    Date of Patent: November 12, 1985
    Assignee: Eastman Kodak Company
    Inventors: Philip T. S. Lau, Gary M. Einhaus
  • Patent number: 4529690
    Abstract: A color photographic element contains a compound of the following formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represent hydrogen atom, or an alkyl or aryl group; Ar.sub.1 and Ar.sub.2 each represent an aryl group; and n and m each represent 1 or 2. The color element containing the above compound displays excellent sensitivity, gradation, and color-developability even when developing it with a color developer not substantially containing any benzyl alcohol.
    Type: Grant
    Filed: August 23, 1984
    Date of Patent: July 16, 1985
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Keiji Ohbayashi, Shinichi Nakamura
  • Patent number: 4522917
    Abstract: A photographic silver halide light-sensitive material is disclosed. The material is comprised of a support and a photographic layer or layers on the support. The photographic layer contains at least one of the compounds represented by the general formula: A--OCH.sub.2 --Z (wherein A is a group capable of undergoing cleavage on application of alkali hydrolysis, and Z is a photographically useful group containing a nitrogen atom through which it is linked to the group A--OCH.sub.2 --). The compounds, i.e., photographically useful group precursors, as used herein are stable during the storage of the raw film and can release the photographically useful group at a controlled speed during development.
    Type: Grant
    Filed: November 18, 1983
    Date of Patent: June 11, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Ichijima, Keiji Mihayashi, Isamu Itoh
  • Patent number: 4521591
    Abstract: Compounds of the formula ##STR1## in which X.sub.1 is hydrogen, alkyl, alkoxy, --NL.sub.1 COM.sub.1, in which L.sub.1 is hydrogen or alkyl and M.sub.1 is alkyl or alkoxy, or is --NL.sub.1 P(O)(OG.sub.1).sub.2, in which G.sub.1 is alkyl, or is alkylsulfonamide or hydroxyl, Y.sub.1 is hydrogen, alkyl, alkoxy, carbalkoxy, N-alkyl-substituted or N,N-dialkyl-substituted amino or --NL.sub.2 COM.sub.2, in which L.sub.2 is hydrogen or alkyl and M.sub.2 is alkyl or alkoxy, Z.sub.1 is hydrogen, alkyl, alkoxy, --NL.sub.2 COM.sub.3, in which M.sub.3 is alkyl, or is carbalkoxy or halogen or represents those atoms which are required to form a ring with Y.sub.1, W.sub.1 is hydrogen, alkyl or alkoxy, R.sub.1 and R.sub.2 independently of one another are hydrogen, halogen, cyano, nitro or --SO.sub.2 U.sub.3, in which U.sub.3 is alkyl or phenyl, R.sub.3 is hydrogen or alkyl or, if R.sub.4 is a direct chemical bond, the two radicals R.sub.3 together are a link member and R.sub.
    Type: Grant
    Filed: February 8, 1982
    Date of Patent: June 4, 1985
    Assignee: Ciba-Geigy AG
    Inventors: Gerald Jan, John Lenoir
  • Patent number: 4521508
    Abstract: A silver halide photographic light-sensitive material is disclosed. The material is comprised of a support base having thereon a silver halide emulsion layer and a protective layer. The material contains a photosensitive silver halide emulsion and inside fogged silver halide emulsion as well as a disulfide compound. The disulfide compound is a compound represented by the general formula (I):A--S--S--B (I)wherein A and B independently represent an alkyl group, an aralkyl group, an aryl group, a heterocyclic group or ##STR1## wherein R represents an alkyl group, an aryl group, an aralkyl group, a heterocyclic group or an amino group. The material can form images having high contrast and a high maximum density. Further, the material has high sensitivity to light and can be developed at a low temperature in a reduced amount of time.
    Type: Grant
    Filed: November 7, 1983
    Date of Patent: June 4, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadao Sugimoto, Hideo Ikeda, Hiroyuki Mifune, Koki Nakamura
  • Patent number: 4510229
    Abstract: A lithographic photosensitive material which comprises a support having thereon at least one silver halide emulsion layer and that, contains as a lithographic development accelerating agent a compound represented by the following general formula (I) in its silver halide emulsion layer or another hydrophilic colloidal layer: ##STR1## wherein R.sub.1 to R.sub.5 may be the same or different, and they each represent hydrogen, a halogen atom, an alkyl group, an alkoxy group, an aryl group, ##STR2## (wherein R.sub.6 and R.sub.7 each represents hydrogen or an alkyl group, or they may combine with each other to form a 5- or 6-membered nitrogen containing saturated hetero ring), --NH--CO--R.sub.8 or --NHSO.sub.2 --R.sub.9 (wherein R.sub.8 and R.sub.9 each represents an alkyl group, an aryl group or an aralkyl group), or R.sub.3 and R.sub.4, or R.sub.4 and R.sub.5 may combine with each other to form a benzene ring and that, it is necessary to said compound that at least one of substituents R.sub.1, R.sub.3 and R.sub.
    Type: Grant
    Filed: March 19, 1984
    Date of Patent: April 9, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yutaka Oka, Naomi Saeki, Yoshiharu Fuseya
  • Patent number: 4508816
    Abstract: An improved method for bleaching color photosensitive materials with a persulfate is provided. This method is free of offensive odors, can bleach efficiently color photosensitive materials containing a large amount of silver by using a persulfate, and can effectively bleach color photosensitive materials having colloidal silver layers by using a persulfate. The color photosensitive material used in the present invention contains at least one of the compounds represented by the formula I, salts thereof and precursors thereof: ##STR1## where R.sup.1 and R.sup.2 each independently represents a hydrogen atom, or an aliphatic residue and R.sup.1 and R.sup.2 may form a ring together with the N atom; R.sup.3 represents --R.sup.4 -- or --R.sup.4 --S, said --R.sup.4 -- being a divalent aliphatic residue; and X represents a divalent heterocyclic ring residue containing at least one atom selected from the group consisting of a nitrogen atom, an oxygen atom, and a sulfur atom.
    Type: Grant
    Filed: October 21, 1983
    Date of Patent: April 2, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kiyohiko Yamamuro, Shigeo Hirano, Isamu Itoh, Yasuo Iwasa
  • Patent number: 4504577
    Abstract: A silver halide photographic material is disclosed which is comprised of a support having formed thereon a light-sensitive silver halide layer and a particular compound represented by the general formulae (I), (II) and (III). The compound is utilized in the photographic material in order to prevent the occurrence of contaminations which are caused by metals intermixed in the silver halide photographic materials during production, packaging, preservation and/or processing. The presence of such compounds also prevents the deterioration of photographic materials caused by metal ions existing in processing solutions and aids in preventing the reduction in the uniformity of processing.
    Type: Grant
    Filed: February 27, 1984
    Date of Patent: March 12, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshinobu Yoshida, Nobuo Sakai, Takatoshi Ishikawa
  • Patent number: 4503139
    Abstract: There are described novel photographic products and processes which utilize compounds which release a photographic reagent in the presence of alkali. The compounds include an imidazole blocking group and cleave in alkali to release the photographic reagent. Also described are novel compounds.
    Type: Grant
    Filed: May 9, 1983
    Date of Patent: March 5, 1985
    Assignee: Polaroid Corporation
    Inventors: James R. Bartels-Keith, Roger A. Boggs, Anthony J. Puttick, Nancy M. Sofen
  • Patent number: 4499181
    Abstract: A photographic recording material. On a support are provided a silver emulsion halide layer and a photographic layer. The photographic layer contains an indole compound represented by the general formula (I): ##STR1## wherein PUG represents a photographically useful group, Ball represents an organic group which has enough molecular weight and/or disposition to render the compound non-diffusible during processing of the photographic recording material with an alkaline medium and wherein the Ball contains a nitrogen atom which is directly attached to the 5th or 6th position of the indole ring. R.sub.1 represents a halogen atom or a monovalent organic group. R.sub.2 represents a hydrogen atom or a low molecular group attached, through a carbon atom, to the 2nd position of the indole ring. "m" represents an integer of zero to 3.
    Type: Grant
    Filed: June 2, 1983
    Date of Patent: February 12, 1985
    Assignee: Konishiroku Photo Ind., Co., Ltd.
    Inventors: Kazumasa Watanabe, Hidetaka Deguchi, Shunji Suginaka
  • Patent number: 4497894
    Abstract: Disclosed is a silver halide photographic photosensitive material which contains at least one dye analogous to a diaminotriphenylmethane dye having sulfo group but which contains, instead of the phenyl group which is not an aminophenyl group, a benzo]b]furan or benzo[b]thiophene which prevents irradiation and halation without discoloration or change during preparation of coating solution or emulsion and giving any adverse effects on photographic characteristics and which is completely and rapidly decolorized during photographic processing procedure.
    Type: Grant
    Filed: September 19, 1983
    Date of Patent: February 5, 1985
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Akira Itoh, Akira Takemura
  • Patent number: 4481285
    Abstract: A method of treating a direct positive silver halide sensitive material is disclosed. The material is comprised of a base having thereon a compound represented by the general formula (I), a sensitive silver halide photographic emulsion layer and a hydrophilic colloid layer. The exposed material is developed in the presence of the compound represented by the general formula (II) ##STR1## wherein R.sup.1 and R.sup.2 independently represent a hydrogen atom, an aliphatic residue, an aromatic residue or a heterocyclic residue, R.sup.3 represents a hydrogen atom or an aliphatic residue, R.sup.4 represents a hydrogen atom, an aliphatic residue or an aromatic residue, and X represents a divalent aromatic residue; ##STR2## wherein R.sup.1 and R.sup.2 represent each a hydrogen atom or an aliphatic residue, and R.sup.1 and R.sup.2 may form a ring by linking together, R.sup.
    Type: Grant
    Filed: April 14, 1983
    Date of Patent: November 6, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshihiro Takagi, Shigeo Hirano, Tadao Sugimoto
  • Patent number: 4477561
    Abstract: A silver halide photographic material having formed on a support two or more layers that are sensitive to the lights of substantially the same spectral region but different in light sensitivity is disclosed. At least one of the layers other than the one having maximum light sensitivity contains at least 40 mg, per 100 g of silver, of a water-soluble compound containing an element of Group VIII of the periodic table which has a molecular weight of 100 or more. The material has a wide latitude for exposure, and this latitude will not vary greatly with time during storage.
    Type: Grant
    Filed: February 17, 1983
    Date of Patent: October 16, 1984
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Hiroshi Menjo, Yoshikazu Watanabe, Nobuo Sakamoto
  • Patent number: 4468449
    Abstract: This invention relates to photographic processes and products for forming an image in dye from a colorless precursor of a preformed image dye which is substituted with a moiety containing a thiazolidinyl group, said thiazolidinyl group (a) being capable of undergoing cleavage imagewise in the presence of an imagewise distribution of silver ion and/or soluble silver complex and (b) possessing a substituent on the carbon atom in the 2-position that undergoes a .beta.-elimination reaction upon said imagewise cleavage, which moiety maintains the precursor in its colorless form at least until said thiazolidinyl group undergoes said cleavage. In a further embodiment, an imagewise distribution of a photographically useful reagent, which reagent may be, for example, a photographically active reagent, is released as a carbamic acid by a .beta.-elimination reaction following the cleavage of a thiazolidinyl group whereby said reagent is provided with a solubilizing group at least during the initial stages of processing.
    Type: Grant
    Filed: June 2, 1983
    Date of Patent: August 28, 1984
    Assignee: Polaroid Corporation
    Inventors: Roberta R. Arbree, James W. Foley, Frank A. Meneghini
  • Patent number: 4468450
    Abstract: This invention relates to photographic processes and products for forming an image in dye from a colorless precursor of a preformed image dye which is substituted with a moiety containing a thiazolidinyl group, said thiazolidinyl group (a) being capable of undergoing cleavage imagewise in the presence of an imagewise distribution of silver ion and/or soluble silver complex and (b) possessing a substituent on the carbon atom in the 2-position which upon cleavage of said thiazolidinyl group, undergoes a .beta.-elimination reaction followed by an intramolecularly accelerated nucleophilic displacement reaction, which moiety maintains the precursor in its colorless form at least until said thiazolidinyl group undergoes said cleavage. In a further embodiment, this sequence of reactions is used to release an imagewise distribution of a photographically useful reagent which reagent may be, for example, a photographically active reagent.
    Type: Grant
    Filed: June 2, 1983
    Date of Patent: August 28, 1984
    Assignee: Polaroid Corporation
    Inventors: Frank A. Meneghini, Paul S. Palumbo
  • Patent number: 4468451
    Abstract: This invention relates to photographic processes and products for forming an image in dye from a colorless precursor of a preformed image dye which is substituted with a moiety comprising a 1,3-sulfur-nitrogen group, said 1,3-sulfur-nitrogen group (a) being capable of undergoing cleavage in the presence of silver ion and/or soluble silver complex, and (b) possessing an amide substituent on the carbon atom in the 2-position that undergoes an intramolecularly accelerated cleavage reaction following the cleavage of said 1,3-sulfur-nitrogen group, which moiety maintains said precursor in its colorless form at least until the 1,3-sulfur-nitrogen group undergoes said cleavage. In a further embodiment, the cleavage of the amide substituent following the cleavage of the 1,3-sulfur-nitrogen group is used to provide an imagewise distribution of a photographically useful reagent, which reagent may be, for example, a photographically active reagent.
    Type: Grant
    Filed: June 2, 1983
    Date of Patent: August 28, 1984
    Assignee: Polaroid Corporation
    Inventor: James W. Foley
  • Patent number: 4460682
    Abstract: A novel silver halide photographic element which contains a nondiffusible complex capable of releasing a diffusible, photographically useful material is disclosed.Said nondiffusible complex becomes active for ligand exchange upon reduction under alkalin conditions to release a diffusible, photographically useful material, said complex being represented by the following formula: ##STR1## wherein La is a quadridentate ligand group; Lb is a didentate ligand group; BALL is a ballast group; PHOTO is a photographically useful material group; Y is a counter ion; and r is the number of counter ions necessary for neutralizing the electric charge on the CO(III) complex.
    Type: Grant
    Filed: December 15, 1982
    Date of Patent: July 17, 1984
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Noboru Mizukura, Satoru Ikeuchi, Shunji Suginaka, Noriko Fujita
  • Patent number: 4459351
    Abstract: A redox release compound that is capable upon oxidation of releasing a silver ion complexing heterocyclic thio moiety enables reduction of the concentration of silver required in a photographic silver halide material comprising a combination of (i) photographic silver halide capable of forming a surface latent image, and (ii) a photographic silver halide capable of forming an internal latent image. The silver halide capable of forming an internal latent image preferably has lower photosensitivity than the silver halide capable of forming a surface latent image. The redox release compound preferably comprises a silver ion complexing 1,2,4-triazolium-3-thio moiety. An image is developed in such an exposed photographic silver halide element by means of a surface type silver halide developer.
    Type: Grant
    Filed: June 22, 1983
    Date of Patent: July 10, 1984
    Assignee: Eastman Kodak Company
    Inventors: Anthony Adin, Henry W. Altland
  • Patent number: 4450223
    Abstract: A photographic silver halide material comprising a compound which is capable of being reduced by a silver halide developing agent at a rate slower than that of image-wise developable silver halide and in reduced state is capable of releasing a photographically useful group, characterized in that said compound corresponds to the following formula: ##STR1## wherein: R.sup.10 and R.sup.20 (same or different)(1) represent an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group or an aralkyl group including said groups in substituted form,(2) represent an aryl group including a substituted aryl group, or(3) represent a heterocyclic ring residue including such residue in substituted form, orR.sup.10 and R.sup.20 are ringclosed, either R.sup.10 or R.sup.20 containing a ballasting group conferring diffusion resistance to the compound in hydrophilic colloid media when penetrated by an aqueous alkaline liquid;L.sup.1 and L.sup.2 (same or different) represent a ##STR2## --SO.sub.
    Type: Grant
    Filed: February 14, 1983
    Date of Patent: May 22, 1984
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Raphael K. Van Poucke, Christian C. Van de Sande, Andree Verhecken
  • Patent number: 4447523
    Abstract: Useful scavengers for oxidized developing agents in photographic elements are 2,4-disulfonamidophenols, or alkali labile precursors of such phenols.
    Type: Grant
    Filed: June 9, 1983
    Date of Patent: May 8, 1984
    Assignee: Eastman Kodak Company
    Inventors: Robert E. Ross, Wilbur S. Gaugh
  • Patent number: 4444865
    Abstract: Blended emulsions for use in forming a direct-positive image are disclosed. The emulsions are comprised of a first, radiation-sensitive core-shell grain population having a relatively low coefficient of variation and a second, substantially smaller size grain population capable of internally trapping photolytically generated electrons. Photographic elements incorporating the blended emulsions exhibit improved covering power and can exhibit enhanced speed.
    Type: Grant
    Filed: September 15, 1982
    Date of Patent: April 24, 1984
    Assignee: Eastman Kodak Company
    Inventors: Robert A. Silverman, Harry A. Hoyen
  • Patent number: 4444874
    Abstract: Photographic elements particularly adapted for forming direct-positive images are disclosed in which a radiation-sensitive core-shell emulsion layer and a silver halide emulsion layer incapable of forming a surface latent image within the direct-positive exposure latitude of the first emulsion layer and containing a grain population capable of internally trapping photolytically generated electrons are both present. The photographic elements are capable of exhibiting increased covering power, greater maximum density, and increased speed.
    Type: Grant
    Filed: September 15, 1982
    Date of Patent: April 24, 1984
    Assignee: Eastman Kodak Company
    Inventors: Robert A. Silverman, Harry A. Hoyen
  • Patent number: 4444866
    Abstract: Photographic light-sensitive materials particularly useful in connection with instant photography are disclosed. The disclosed photographic materials include films for instant photography which have a reduced image appearing time, a high Dmax and low Dmin. The disclosed materials include force-oxidized carbon black in liquid phase, which has a dispersibility of at least 4 in water.
    Type: Grant
    Filed: March 3, 1983
    Date of Patent: April 24, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takeo Sakai, Mitsugu Tanaka, Shigetoshi Ono, Seiji Suzuki, Hirohisa Suzuki
  • Patent number: 4444867
    Abstract: Sulfilimine compounds of formula I ##STR1## wherein X is the integrating residue of a photographically active compound H.sub.2 N--A--X andA is a linking member between X and N consisting of a benzene ring having at least two electron-attracting groupsare suitable compounds for photographic recording materials. The compounds can be split reductively to release the photographically active compound. Where the photographically active compound is a dye or dye precursor the sulfilimine compounds are suitable dye releasers for color diffusion transfer processes.
    Type: Grant
    Filed: April 18, 1983
    Date of Patent: April 24, 1984
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventor: Hans-Heinrich Credner
  • Patent number: 4439520
    Abstract: High aspect ratio chemically and spectrally sensitized tabular grain silver halide emulsions, photographic elements incorporating these emulsions, and processes for the use of the photographic elements are disclosed. In the tabular grain emulsions the silver halide grains having a thickness of less than 0.3 micron and a diameter of at least 0.6 micron have a high aspect ratio and account for at least 50 percent of the total projected area of the silver halide grains present.
    Type: Grant
    Filed: September 30, 1982
    Date of Patent: March 27, 1984
    Assignee: Eastman Kodak Company
    Inventors: James T. Kofron, Robert E. Booms, Cynthia G. Jones, John A. Haefner, Herbert S. Wilgus, Francis J. Evans
  • Patent number: 4436811
    Abstract: Compounds of the formula ##STR1## in which R.sub.1, R.sub.2 and R.sub.3 independently of one another are hydrogen, alkyl or alkoxy and R.sub.2 additionally represents a radical of the formula ##STR2## in which R.sub.1 and R.sub.3 have the abovementioned meanings, R.sub.4 is unsubstituted or substituted phenoxy or unsubstituted or substituted amino and R.sub.5 is hydrogen or a radical of the formula ##STR3## in which R.sub.1, R.sub.3 and R.sub.4 have the abovementioned meanings and R.sub.2 ' has the same meanings as R.sub.1 and R.sub.3 are suitable development accelerators in the development of exposed, photographic materials containing silver halide.They accelerate the reduction of the exposed silver salt to silver and increase the speed of photographic material.
    Type: Grant
    Filed: June 22, 1982
    Date of Patent: March 13, 1984
    Assignee: Ciba-Geigy AG
    Inventors: Mario Fryberg, Viktor Weiss
  • Patent number: 4433047
    Abstract: Photographic elements particularly adapted for forming direct-positive images are disclosed in which a radiation-sensitive core-shell emulsion layer and a silver halide emulsion layer incapable of forming a surface latent image within the direct-positive exposure latitude of the first emulsion layer and containing a grain population capable of internally trapping photolytically generated electrons are both present. The photographic elements are capable of exhibiting increased covering power, greater maximum density, and increased speed.
    Type: Grant
    Filed: September 15, 1982
    Date of Patent: February 21, 1984
    Assignee: Eastman Kodak Company
    Inventors: Robert A. Silverman, Harry A. Hoyen
  • Patent number: 4433050
    Abstract: A direct positive type light sensitive silver halide photographic material is disclosed. At least one layer containing an unfogged internal latent image type silver halide emulsion, is provided on a support, and an internal latent image type silver halide emulsion having fog centers in silver halide grains, is incorporated in said layer or in another constituent layer of the photographic material. A dye image forming substance may be incorporated in the same layer or in a separate layer to form a color diffusion transfer type light sensitive photograhic material. The photographic materials present a positive image having a high maximum density and a low minimum density.
    Type: Grant
    Filed: September 9, 1981
    Date of Patent: February 21, 1984
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Takao Abe, Satoru Hohnishi
  • Patent number: 4431730
    Abstract: A process for the preparation of an internal latent image type silver halide emulsion containing silver halide grains comprising a central core of silver halide doped with metal ions, chemically sensitized or a combination thereof and an outer shell of silver halide covering at least light-sensitive sites of the central core characterized in that the surface of the silver halide grains are chemically sensitized in the presence of a polymer containing the repeating unit represented by general formula (I) ##STR1## wherein symbols R.sup.1 and Q are defined in the specification.
    Type: Grant
    Filed: February 17, 1982
    Date of Patent: February 14, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeharu Urabe, Shinji Sakaguchi, Ichizo Toya, Tadao Sugimoto
  • Patent number: 4421846
    Abstract: A photographic element containing a nondiffusible metal complex capable of releasing a diffusible photographically useful group. The complex contains at least one poly-dentate ligand which contains the photographically useful group. The complex may be activated when reduced under alkaline conditions to release the photographically useful group.
    Type: Grant
    Filed: December 23, 1981
    Date of Patent: December 20, 1983
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Satoru Ikeuchi, Masaru Kanbe, Jiro Takahashi, Ryuichiro Kobayashi, Shunji Suginaka, Noboru Mizukura
  • Patent number: 4418139
    Abstract: Solid compositions are disclosed comprising a complex of water; a benzotriazole of the formula ##STR1## wherein R.sup.1 and R.sup.2 are independently hydrogen, a monovalent organic radical, halogen, or nitro; and at least one water-soluble base having a basicity greater than that of the benzotriazole and capable of dissociating to provide an anion and a monovalent or divalent metal cation. The compositions have melting ranges above 35.degree. C. and are capable of releasing a substantial portion of the water contained therein to the surrounding environment when melted. The compositions can be employed in thermally developable photographic film units as thermally induced water-releasing materials which provide water to the internal environment of the film unit when the film unit is heated sufficiently to melt the composition.
    Type: Grant
    Filed: September 30, 1982
    Date of Patent: November 29, 1983
    Assignee: Polaroid Corporation
    Inventors: Howard G. Rogers, Robert D. Eckert, Ronald A. Sahatjian, Robert A. Sulesky
  • Patent number: 4416980
    Abstract: High-contrast light-sensitive silver halide photographic material which comprises a support, a silver halide emulsion layer containing silver halide and another hydrophilic colloidal layer coated on the support, at least one of said silver halide emulsion layer and another hydrophilic colloidal layer containing a substantially non-diffusible compound having oxidizing power on a hydroquinone developing agent, and the thickness, in an aqueous solution having the composition described as in the specification kept at 23.degree. C., of said at least one layer being from 1.2-4.5 times that of said layer dried in an atmosphere at 23.degree. C. at a relative humidity of 55%.
    Type: Grant
    Filed: September 4, 1980
    Date of Patent: November 22, 1983
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Mitsuto Fujiwhara, Syunji Matsuo, Toyoaki Masukawa, Yutaka Kaneko, Mikio Kawasaki
  • Patent number: 4415610
    Abstract: A method and apparatus for simulating a process carried out on a moving web in which the web is held stationary while movement through a sequence of processing zones is simulated by means for rapidly changing the process conditions to which the web is exposed, and methods and apparatus for rapidly changing the operative parameters in a processing zone.
    Type: Grant
    Filed: May 4, 1981
    Date of Patent: November 15, 1983
    Assignee: Polaroid Corporation
    Inventor: Edward J. Choinski
  • Patent number: 4407935
    Abstract: The compounds of the formula ##STR1## in which R is amino, cyclic amino, aryloxy or a group of the formula ##STR2## in which L is a radical of the formula .dbd.N-Z, with Z being alkyl or cycloalkyl, or is a heterocyclic radical, aryleneoxy or oxyaryleneoxy and R' and R" are hydrogen, alkyl or halogen, and x and y are 0, 1, 2 or 3, are suitable development accelerators for the development of exposed photographic materials containing silver halide. They accelerate the reduction of the exposed silver salt to silver and thus enhance the sensitivity of the photographic material.
    Type: Grant
    Filed: January 15, 1982
    Date of Patent: October 4, 1983
    Assignee: Ciba-Geigy AG
    Inventors: Mario Fryberg, David G. Leppard
  • Patent number: 4400463
    Abstract: Radiation-sensitive photographic emulsions are disclosed comprised of a dispersing medium and silver halide grains the halide content of which is at least 50 mole percent chloride, based on silver. The silver halide grains include tabular grains having a thickness of less than 0.5 micron, a diameter of at least 0.6 micron, and an average aspect ratio greater than 8:1 which account for at least 50 percent of the total projected area of the silver halide grains. The tabular grains have two opposed substantially parallel major crystal faces lying in {111} crystal planes and exhibiting at least one of the following features: (1) at least one peripheral edge lying parallel to a <211> crystallographic vector lying in the plane of one of the major faces and (2) bromide and/or iodide incorporated in a central grain region. The tabular grains are formed in the presence of an aminoazaindene and a peptizer having a thioether linkage.
    Type: Grant
    Filed: September 30, 1982
    Date of Patent: August 23, 1983
    Assignee: Eastman Kodak Company
    Inventor: Joe E. Maskasky
  • Patent number: 4379837
    Abstract: Silver halide emulsions are prepared by precipitating a silver halide emulsion I on a more sparingly soluble silver halide emulsion II in the presence of a silver halide solvent wherein the emulsion I has been prepared in the presence of a compound inhibiting grain growth.
    Type: Grant
    Filed: May 20, 1981
    Date of Patent: April 12, 1983
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Otto Lapp, Harald von Rintelen, Franz Moll, Lothar Endres
  • Patent number: 4377634
    Abstract: A method for forming a high contrast negative photographic image, which comprises imagewise exposing a photographic material comprising a support having thereon at least one photographic silver halide emulsion layer with the photographic silver halide emulsion layer or at least one hydrophilic colloid layer of the photographic material containing a compound of the general formula (I)R.sup.1 --NHNHCO--R.sup.2 (I)wherein R.sup.1 represents an aryl group, and R.sup.2 represents a hydrogen atom, a phenyl group, or an unsubstituted alkyl group containing 1 to 3 carbon atoms, and then developing the imagewise exposed material in the presence of a hydroquinone compound of the general formula (II) ##STR1## wherein R.sup.3, R.sup.4, R.sup.5 and R.sup.6, which may be the same or different, each represents a hydrogen atom, a sulfo group, an alkyl group, an aryl group, an aralkyl group, a heterocyclic group, or a group of the formula --O--R.sup.7 or --S--R.sup.7 where R.sup.
    Type: Grant
    Filed: March 11, 1980
    Date of Patent: March 22, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Mifune, Shunji Takada, Yoshitaka Akimura, Yoshiharu Fuseya
  • Patent number: 4377635
    Abstract: A photographic light-sensitive material which has on a support at least one silver halide emulsion layer containing large-size silver halide grains formed in the presence of at least one compound acting as a silver halide solvent and having the following general formual (I): ##STR1## wherein l and m each represents an integer of 2 or 3; n represents zero or an integer of 1 or 2; and R.sup.1 and R.sup.5 may be the same as or different from one another, each being an alkyl group, a hydroxyalkyl group or carboxyalkyl group, and when n equals zero, at least one of the substituents of R.sup.1 to R.sup.4, must be a hydroxyalkyl group, while when n does not equal zero, at least two of the substitutents of R.sup.1 to R.sup.5, must be hydroxyalkyl groups. Use of the compound of the present invention results in emulsions exhibiting excellent reproducibility with respect to gain sizes of silver halides.
    Type: Grant
    Filed: May 28, 1982
    Date of Patent: March 22, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Mifune, Nobuaki Inoue, Yoshiharu Fuseya
  • Patent number: 4371604
    Abstract: A photographic material for diffusion transfer photography containing a quinonoid compound, which is capable in reduced state and under alkaline conditions of releasing a photographically useful group and corresponds to one of the following general formulae: ##STR1## wherein: each of (Nuox).sup.1 and (Nuox).sup.2 (same or different) represents an oxidized nucleophilic group,Z represents a bivalent atom or bivalent atomic group, which is electro-negative,Q together with the group Z represents a releasable photographically useful group,Y.sup.1 and Y.sup.2 together represent the necessary atoms to close a p-quinonoid ring substituted with (a) directly linked monovalent organic ring or ring system substituent(s) having aromatic character,Y.sup.3 represents the necessary atoms to close a o-quinonoid ring substituted with (a) directly linked monovalent organic ring or ring system substituent(s) having aromatic character, andeach of R.sup.1 and R.sup.
    Type: Grant
    Filed: March 31, 1981
    Date of Patent: February 1, 1983
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Christian C. Van de Sande, Wilhelmus Janssens, Wolfgang Lassig, Ernst Meier
  • Patent number: 4368258
    Abstract: In the process for preparing impregnated polymer latex compositions by impregnating a hydrophobic substance in dispersed polymer particles in an aqueous polymer latex, the improvement comprises impregnating said hydrophobic substance, wherein the impregnation is effected by mixing said hydrophobic substance which is solid state, a water-miscible organic solvent and aqueous polymer latex wherein a polymer of the polymer latex is prepared from ethene monomers and containing at least one hydrophilic group.
    Type: Grant
    Filed: March 11, 1981
    Date of Patent: January 11, 1983
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Mitsuto Fujiwhara, Syunji Matsuo, Tsuneo Wada, Naoto Abe, Toyoaki Masukawa, Akio Iijima, Keiji Oishi
  • Patent number: 4363871
    Abstract: A multi-layer light-sensitive photographic material comprising a support and a light-sensitive layer, which have a surface layer which does not adhere even under a high temperature and high humidity conditions when the front surface layer thereof is contacted with the other surface layer and which is hardly subject to scratching and free from the so-called "blooming" phenomenon.The light-sensitive material according to this invention comprises, in at least one of the front and back sides thereof, at least one light-insensitive layer containing a high polymer having at least 20% by weight of a repeating unit represented by the formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom or a methyl group, and R.sup.2 represents a straight chain alkyl group having 12 to 24 carbon atoms.
    Type: Grant
    Filed: April 27, 1981
    Date of Patent: December 14, 1982
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Toshiaki Shibue, Koichi Nagayasu, Tohru Kobayashi, Kouji Tokitou
  • Patent number: 4359525
    Abstract: A photosensitive silver halide element comprising a support carrying single effective silver halide grains in a predetermined spaced array is prepared by coalescing fine-grain silver halide in a plurality of spaced depressions in a surface by melting said fine-grain silver halide.
    Type: Grant
    Filed: November 23, 1981
    Date of Patent: November 16, 1982
    Assignee: Polaroid Corporation
    Inventor: Arthur M. Gerber
  • Patent number: 4359526
    Abstract: A method for forming a photosensitive element comprising a plurality of single effective silver halide grains in a predetermined spaced array which comprises coalescing a fine-grain silver halide emulsion in a plurality of predetermined spaced depressions in a surface, wherein said coalescence is carried out by contacting said fine-grain emulsion with a silver halide solvent in the vapor phase.
    Type: Grant
    Filed: September 2, 1981
    Date of Patent: November 16, 1982
    Assignee: Polaroid Corporation
    Inventor: Vivian K. Walworth
  • Patent number: 4358525
    Abstract: Photographically useful compounds such as photographic reagents and photographic dyes are blocked with a grouping which, under alkaline conditions, is cleaved from the compound by an intramolecular nucleophilic displacement reaction. The compounds are resistant to unblocking under storage conditions, but are uniformly unblocked under conditions encountered during photographic processing.
    Type: Grant
    Filed: August 12, 1981
    Date of Patent: November 9, 1982
    Assignee: Eastman Kodak Company
    Inventors: Jared B. Mooberry, William C. Archie, Jr.
  • Patent number: 4358532
    Abstract: A photographic element containing a compound represented by formula (I) ##STR1## wherein G represents --OR.sup.1 or --NHR.sup.2, R.sup.1 represents hydrogen or a hydrolyzable moiety, R.sup.2 represents hydrogen or an alkyl group containing from 1 to 50 carbon atoms, Z represents a photographically useful group, A represents an atomic group forming an aromatic ring, Ball represents an organic immobilizing group on the aromatic ring, which cntains from 8 to 50 carbon atoms, m represents an integer of 1 or 2, X represents a divalent organic group, Nu represents a nucleophilic group, and n represents an integer of 1 or 2, and X with the nucleophilic group Nu is capable of forming a 5- to 12-membered ring by oxidation having an electrophilic center at the carbon atom substituted by the --NHSO.sub.2 Z group.
    Type: Grant
    Filed: July 15, 1981
    Date of Patent: November 9, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Koichi Koyama, Shinsaku Fujita
  • Patent number: 4358533
    Abstract: A silver halide photographic material having a hydrophilic colloid layer comprising fine polymer particles loaded with a hydrophobic photographic addenda provided on a support wherein the polymer has repeating units formed from a nonionic hydrophobic monomer. The nonionic hydrophobic monomer has the formula ##STR1## R.sub.1 and R.sub.2 individually are a hydrogen atom or methyl group, R.sub.3 is a hydrogen atom, an alkyl or aryl group, and m and n are integers of from 2 to 100 individually.
    Type: Grant
    Filed: March 11, 1981
    Date of Patent: November 9, 1982
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Kouji Tokitou, Tsuneo Wada
  • Patent number: 4358530
    Abstract: A photosensitive lithographic printing plate precursor and a method for the preparation of a lithographic printing plate is described, said precursor comprising a support, a non-silver photosensitive layer and a photographic silver halide emulsion coating, and exhibiting photographic camera speed and a printing durability equivalent to the conventional type presensitized plate due to the underlying non-silver photosensitive layer; the silver halide emulsion coating contains a compound represented by the formual (I)R.sup.1 NHNHCOR.sup.2 (I)in which R.sup.1 represents an aryl group and R.sup.2 represents hydrogen, an aryl group, or an aliphatic group.
    Type: Grant
    Filed: October 2, 1980
    Date of Patent: November 9, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Keisuke Shiba