Polymers From Only Ethylenic Monomers Or Processes Of Polymerizing, Polymerizable Compositions Containing Only Ethylenic Monomers As Reactants Or Processes Of Preparing Patents (Class 526/72)
  • Patent number: 8546461
    Abstract: The present invention relates to a method for producing water-absorbing polymer particles by radiation-inducing polymerization on a continuously revolving belt, electromagnetic radiation having a wavelength of greater than 400 nm being shielded.
    Type: Grant
    Filed: November 24, 2008
    Date of Patent: October 1, 2013
    Assignee: BASF SE
    Inventors: Matthias Weismantel, Rüdiger Funk, Leigh R. Blair, Kevin D. Heitzhaus
  • Patent number: 8541528
    Abstract: A process for producing water-absorbing polymer particles, wherein an aqueous polymer gel is dried in a forced-air belt drier on a circulating conveyor belt and the surface of the conveyor belt has a multitude of elevations or depressions which are suitable for restricting the mobility of the aqueous polymer gel in transverse direction.
    Type: Grant
    Filed: February 22, 2011
    Date of Patent: September 24, 2013
    Assignee: BASF SE
    Inventors: Rüdiger Funk, Thomas Pfeiffer, Matthias Weismantel, Stefan Blei, Wilfried Heide, Volker Braig, Thomas Gieger, Andreas Brockmeyer
  • Patent number: 8524260
    Abstract: The invention consists of a method for manufacturing an aqueous formulation containing at least one oil, and comprising the steps of mixing at least one associative polymer, one oil, and water, encapsulating the oil by increasing the pH to a value greater than 8, potentially precipitating the mixture by reducing the pH to a value less than 6, and potentially isolating the resulting particles by removing the water. The aqueous formulations, as with the aqueous dispersions, and the resulting solid particles constitute other objects of the invention.
    Type: Grant
    Filed: December 3, 2008
    Date of Patent: September 3, 2013
    Assignee: Coatex S.A.S.
    Inventors: Jean Moro, David Platel, Jean-Marc Suau, Olivier Guerret
  • Patent number: 8524859
    Abstract: In the production of isobutylene-based elastomers the product obtained from the polymerization process is often in the form of a stream. Described herein are an apparatus and a process for removal of hydrocarbon liquids from the elastomer. The process comprises the steps of obtaining a stream comprising hydrocarbon liquids, either solvents or diluents, and an isobutylene-based elastomer; passing the stream through a kneader to volatize the hydrocarbon liquids from the elastomer.
    Type: Grant
    Filed: March 23, 2011
    Date of Patent: September 3, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Yu Feng Wang, Richard C-M Yeh
  • Patent number: 8519094
    Abstract: Process for heating a polymer-containing stream being transferred from a polymerization reactor to a separation zone or device, by passing the stream through at least two heaters operating in parallel, each heater having at least one transfer line for the stream and a heater for heating the transfer line. The average particle of the polymer is below 3 mm, the temperature of the polymer-containing stream at the outlet of all heaters is maintained above the dew point of the stream, and no heater has a volumetric flowrate of polymer-containing stream more than three times that of any other heater.
    Type: Grant
    Filed: April 15, 2009
    Date of Patent: August 27, 2013
    Assignee: Ineos Manufacturing Belgium NV
    Inventors: Daniel Marissal, Marc Parisel, Brent Walworth
  • Patent number: 8497337
    Abstract: A process for producing water-absorbing polymer particles, wherein at least one aliphatic aldehyde or reaction product thereof with an aliphatic alcohol, an aliphatic amine, ammonia, a hypophosphite or a phosphite is added.
    Type: Grant
    Filed: November 15, 2010
    Date of Patent: July 30, 2013
    Assignee: BASF SE
    Inventors: Norbert Herfert, Thomas Daniel
  • Patent number: 8476383
    Abstract: The present invention deals with a process of producing a polymer of at least one olefin in two consecutive reactors in gas phase in the presence of an olefin polymerization catalyst where an olefin is polymerized in a first polymerization reactor in the presence of an olefin polymerization catalyst and a first reaction gas mixture to form a fluidized bed comprising an olefin polymer and said first reaction gas mixture.
    Type: Grant
    Filed: November 3, 2010
    Date of Patent: July 2, 2013
    Assignee: Borealis AG
    Inventors: Tapio Kokko, Erno Elovainio, Jouni Kivela, Klaus Nyfors, Kai Hagane
  • Patent number: 8470198
    Abstract: The invention relates to novel calamitic mesogenic compounds which are especially suitable for use in birefringent films with negative optical dispersion, to novel liquid crystal (LC) formulations and polymer films comprising them, and to the use of the compounds, formulations and films in optical, electrooptical, electronic, semiconducting or luminescent components or devices.
    Type: Grant
    Filed: July 16, 2009
    Date of Patent: June 25, 2013
    Assignee: Merck Patent GmbH
    Inventors: Kevin Adlem, Owain Llyr Parri
  • Patent number: 8470205
    Abstract: An aqueous dispersion and a method for making an aqueous dispersion. The dispersion including at least one conductive polymer, such as a polythienothiophene, at least one hyperbranched polymer and optionally at least one colloid-forming polymeric acid and one non-fluorinated polymeric acid. Devices utilizing layers formed of the aqueous dispersions are also disclosed.
    Type: Grant
    Filed: June 5, 2009
    Date of Patent: June 25, 2013
    Assignee: Air Products and Chemicals, Inc.
    Inventor: Shiying Zheng
  • Patent number: 8461278
    Abstract: A process for producing water-absorbing polymer particles, wherein heated water-absorbing polymer particles are remoisturized and cooled in a high-speed mixer.
    Type: Grant
    Filed: March 24, 2011
    Date of Patent: June 11, 2013
    Assignee: BASF SE
    Inventors: Rüdiger Funk, Thomas Pfeiffer
  • Patent number: 8454857
    Abstract: A polymerizable liquid crystal compound shown by the following formula, a polymerizable liquid crystal composition that includes the polymerizable liquid crystal compound and a chiral compound polymerizable with the polymerizable liquid crystal compound, a liquid crystalline polymer obtained by polymerizing the polymerizable liquid crystal compound or the polymerizable liquid crystal composition, and an optically anisotropic article that includes the liquid crystalline polymer, are disclosed.
    Type: Grant
    Filed: June 17, 2009
    Date of Patent: June 4, 2013
    Assignee: Zeon Corporation
    Inventors: Kei Sakamoto, Yasushi Nakano
  • Publication number: 20130137827
    Abstract: A process for producing an olefin-based polymer in a polymerization reactor including a fluidized bed, a disengaging section and a neck connecting the bed and disengaging section, at least one monomer, in the gas phase, in the presence of at least one catalyst containing at least two transition metals, one of the at least two transition metals being Ti, at least one cocatalyst, a composition having at least one compound selected from formula (I), and/or at least one compound selected from formula (II): (R1CO2)2AlOH (I), (R2)xN(R3OH)y (II); wherein R1 is a hydrocarbon radical containing from 13 to 25 carbons; R2 is a hydrocarbon radical containing from 14 to 26 carbons; R3 is a hydrocarbon radical containing from 1 to 4 carbons; and x+y=3, and x has a value of 1 or 2; and wherein the reactor is operated in a condensed mode and the average height of the fluidized bed is maintained above the neck of the polymerization reactor is provided. The reaction product of the process is also provided.
    Type: Application
    Filed: April 4, 2011
    Publication date: May 30, 2013
    Applicant: Dow Global Technologies LLC
    Inventors: Robert J. Jorgensen, Robert Reib, Stephanie M. Whited, Timothy J. Hogan, Darin G. Clark, Troy M. Tambling
  • Patent number: 8419971
    Abstract: A process for producing water-absorbing polymer particles by polymerizing droplets of a monomer solution in a gas phase surrounding the droplets, wherein the particle surface is coated at least partly with at least one polymer and/or wax.
    Type: Grant
    Filed: December 12, 2007
    Date of Patent: April 16, 2013
    Assignee: BASF SE
    Inventors: Uwe Stueven, Rüdiger Funk, Matthias Weismantel, Wilfried Heide, Marco Krüger
  • Patent number: 8404797
    Abstract: An end-modified soluble polyfunctional vinyl aromatic copolymer, which is improved in heat resistance, thermal stability, solvent solubility, and compatibility with acrylate compounds, and a curable resin composition using the same are disclosed. The end-modified soluble polyfunctional vinyl aromatic copolymer is obtained by allowing a divinyl aromatic compound (a), a monovinyl aromatic compound (b), and an aromatic ether compound (c) to react with each other, and has, at an end, an end group derived from the aromatic ether compound and having an acrylate bond. The copolymer has a number average molecular weight Mn of 500 to 100,000, an introduction amount (c1) of the end group derived from the aromatic ether compound satisfies (c1)?1.0 (group/molecule), a molar fraction a? of a structural unit derived from the divinyl aromatic compound and a molar fraction b? of a structural unit derived from the monovinyl aromatic compound in the copolymer satisfy 0.05?a?/(a?+b?)?0.95.
    Type: Grant
    Filed: March 3, 2009
    Date of Patent: March 26, 2013
    Assignee: Nippon Steel Chemical Co., Ltd.
    Inventors: Masanao Kawabe, Hiroko Terao, Natsuko Okazaki
  • Patent number: 8377625
    Abstract: A method of producing a copolymer solution for semiconductor lithography having a copolymer and a solvent for coating film formation, which copolymer contains at least one repeating unit selected from the group consisting of: a repeating unit (A) having a hydroxyl group; a repeating unit (B) having a structure in which a hydroxyl group is protected by a group which suppresses dissolution into an alkaline developer and which dissociates in the action of an acid; a repeating unit (C) having a lactone structure; and a repeating unit (D) having a cyclic ether structure, the difference in the copolymer concentration among a plurality of containers which were filled with copolymer solution from the same manufacturing lot is not more than a certain range, or the method includes a certain production step.
    Type: Grant
    Filed: October 28, 2009
    Date of Patent: February 19, 2013
    Assignee: Maruzen Petrochemical Co., Ltd.
    Inventors: Takanori Yamagishi, Ichiro Kato, Akiko Tanaka, Miyako Asano
  • Patent number: 8361302
    Abstract: The invention relates to a process for the preparation of polymers by free radical polymerization of monomers in the presence of water, electrochemically produced free radicals being used for initiating the free radical polymerization.
    Type: Grant
    Filed: March 12, 2009
    Date of Patent: January 29, 2013
    Assignee: Construction Research & Technology GmbH
    Inventors: Harald Grassl, Jochen Mezger, Alexander Kraus, Gerhard Albrecht
  • Patent number: 8349264
    Abstract: Methods and systems for preparing catalyst, such as chromium catalysts, are provided. The valence of at least a portion of the catalyst sent to an activator is changed from Cr(III) to Cr(VI). The catalyst is prepared or activated continuously using a fluidization bed catalyst activator.
    Type: Grant
    Filed: January 5, 2012
    Date of Patent: January 8, 2013
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Elizabeth A. Benham, Max P. McDaniel, Ted H. Cymbaluk, Charles K. Newsome, Charles R. Nease, H. Kenneth Staffin, Thomas R. Parr
  • Patent number: 8349980
    Abstract: A polyol having a substituent of formula (I) attached via a carbon-carbon single bond to a saturated carbon atom in a fatty acid hydrocarbyl group; wherein R1 and R2 are esterified residues of aliphatic or cycloaliphatic diols; and from 0 to 15 wt % of esterified residues of at least one C4-C12 anhydride, C4-C12 diacid or C4-C12 lactone, not including units of formula (I) attached to a fatty acid hydrocarbyl group.
    Type: Grant
    Filed: February 23, 2010
    Date of Patent: January 8, 2013
    Assignee: Rohm and Haas Company
    Inventor: Joseph James Zupancic
  • Patent number: 8343311
    Abstract: A method for producing paper, cardboard or similar materials, comprising, separately or in a mixture, adding to a fibrous suspension: at least one main retention agent comprising a cationic (co)polymer, and at least one dual retention agent comprising a crosslinked cationic (co)polymer obtained in the form of a dispersion and placed in solution prior to its introduction into the fibrous suspension with gentle stirring. The crosslinked cationic (co)polymer having—a UL viscosity of between 1.3 and 2.7 cps, preferably between 1.5 and 2.4 cps, and—an apparent cationicity ratio of between 25 and 75%. Optionally, before or after the dual agent or the main retention agent are added, one or more tertiary retention agent(s) selected from the group comprising mineral particles and organic polymers carrying anionic charges, is added to the suspension.
    Type: Grant
    Filed: April 10, 2009
    Date of Patent: January 1, 2013
    Assignee: S.P.C.M. SA
    Inventors: Rene Hund, Gatien Faucher
  • Patent number: 8344192
    Abstract: The invention provides a technique enabling the separation and recovery of an unreacted fluoromonomer from an aqueous fluoropolymer dispersion obtained by emulsion polymerization, without using any extraction solvent, and enabling the prevention of a hydrolysis of —SO2F and a like sulfonic acid precursor functional group convertible to sulfonic acid group. Thus, the invention provides a recovering method fluoromonomer having a sulfonic acid precursor functional group convertible to a sulfonic acid group and remaining unreacted from an aqueous fluoropolymer dispersion obtained by emulsion polymerization of the fluoromonomer, wherein the unreacted fluoromonomer is recovered from the aqueous fluoropolymer dispersion by evaporation, wherein the aqueous fluoropolymer dispersion has an acidic pH.
    Type: Grant
    Filed: December 7, 2007
    Date of Patent: January 1, 2013
    Assignee: Daikin Industries, Ltd.
    Inventors: Tadaharu Isaka, Tadashi Ino, Masaharu Nakazawa, Masahiro Kondo
  • Patent number: 8337824
    Abstract: The present invention is directed to compositions of a linear polyol and a salt of a crosslinked cation exchange polymer comprising a fluoro group and an acid group. These compositions are useful to bind potassium in the gastrointestinal tract.
    Type: Grant
    Filed: August 22, 2009
    Date of Patent: December 25, 2012
    Assignee: Relypsa, Inc.
    Inventors: Detlef Albrecht, Michael Burdick, Han-Ting Chang, Dominique Charmot, Ramakrishnan Chidambaram, Eric Connor, Sherin Halfon, I-Zu Huang, Mingjun Liu, Jonathan Mills, Werner Strüver
  • Patent number: 8329622
    Abstract: Alcohol compatible, water-soluble copolymer useful as a corrosion inhibitor. The copolymer includes at least one olefinically unsaturated carboxylic acid monomer, at least one olefinically unsaturated mono- or di-alkyl ester of a di-carboxylic acid monomer, and at least one olefinically unsaturated hydrophilic, non-ionic monomer. The molar ratio of the alkyl ester groups of the mono- or di-alkyl ester of the dicarboxylic acid monomer to the hydrophilic groups of the hydrophilic, non-ionic monomers is from about 0.01:1 to 1000:1, and the molar ratio of the sum of the alkyl ester groups and hydrophilic groups of the hydrophilic, non-ionic monomers to the carboxylic acid groups, is from about 0.001:1 to 100:1. No haze or precipitate occurs in a mixture of the water-soluble copolymer at 4° C. for 15 hrs or more as a 20 weight % aqueous copolymer solution in alcohol at a water-soluble copolymer to methanol weight-ratio of not more than 25 to 100.
    Type: Grant
    Filed: May 6, 2005
    Date of Patent: December 11, 2012
    Assignee: Akzo Nobel N.V.
    Inventors: Martin Crossman, Stuart Holt, Jannifer Sanders
  • Patent number: 8308902
    Abstract: A method of improving retention and drainage in a papermaking process is disclosed. The addition of an associative polymer, a poly(vinylamine) and optionally a siliceous material to the papermaking slurry to improve retention and drainage is disclosed. Additionally a method to improve retention and drainage comprising addition of an organic microparticle, a poly(vinylamine) and optionally a siliceous material to the papermaking slurry is disclosed. A composition comprising an associative polymer, and a poly(vinylamine) and optionally further comprising cellulose fiber is disclosed.
    Type: Grant
    Filed: May 8, 2009
    Date of Patent: November 13, 2012
    Assignee: Hercules Incorporated
    Inventors: Frank Sutman, John Harrington, Robert Gelman
  • Patent number: 8298520
    Abstract: Disclosed is a deodorant particle having a BET specific surface area of 10 m2/g or more that are obtained by copolymerizing a monomer system including a crosslinkable vinyl monomer and a vinyl monomer having a heteroaromatic ring. The deodorant particles may contain a metal ion. Also disclosed is a process of producing the deodorant particles including the step of copolymerizing a monomer system containing a crosslinkable vinyl monomer and a vinyl monomer having a heteroaromatic ring by oil-in-water emulsion polymerization or precipitation polymerization using an organic solvent whose solubility parameter is different from that of the monomers by an absolute difference of 0 to 2.0. The process can further include the step of bringing the particles obtained by the polymerization into contact with a solvent having a metal salt dissolved therein to support a metal ion on the particle.
    Type: Grant
    Filed: June 27, 2007
    Date of Patent: October 30, 2012
    Assignee: Kao Corporation
    Inventors: Takashi Itoi, Koji Mimura, Daisuke Yamazaki, Masafumi Miyamoto, Tetsuji Kito, Seiichi Miyanaga, Hirohiko Ishida
  • Patent number: 8293852
    Abstract: This invention relates to an oil-absorbent polymer and the preparation method thereof, and disclosed a preparation method of quick oil absorbent material, which comprises: (1) Mixing and stirring well monomer A, vinyl monomer, initiator and vesicant to form a copolymerization system, wherein the amount of monomer A is in the range of approximately 10-50 wt %, the amount of vinyl monomer is in the range of approximately 48-88 wt %, the amount of initiator is in the range of approximately 0.01-5 wt %, the amount of vesicant is in the range of approximately 1-5 wt %; (2) And then immersing fiber carriers into the liquid of above-said copolymerization system to adsorb the liquid on the fiber carriers, then heating the fiber carriers under a temperature between 60˜80° C. for 1˜4 hours to synthesize polymers on the fiber carriers.
    Type: Grant
    Filed: August 18, 2010
    Date of Patent: October 23, 2012
    Assignee: Suzhou Timelyblue Environmental Technology, Co., Ltd.
    Inventors: Jianmei Lu, Jun Jiang
  • Patent number: 8288606
    Abstract: A solid, hydrocarbon-insoluble, catalyst component useful in polymerizing olefins containing magnesium, titanium, and halogen further contains an internal electron donor comprising a compound containing electron donating substituents with a structure: wherein D1 and D2 are selected individually from and R, R1, R2, R3, R4, R5, R6, and R7 individually are hydrocarbon or substituted hydrocarbon groups containing 1 to 20 carbon atoms and R1, R2, R3, R4, R6, and R7 may be hydrogen; R4 may be —NR2; and wherein groups R1 and R2, R2 and R3, R3 and R4, R3 and R5, and groups R6 and R7 may be joined to form a cyclic structure.
    Type: Grant
    Filed: March 1, 2006
    Date of Patent: October 16, 2012
    Assignee: Ineos USA LLC
    Inventors: Roger Uhrhammer, John P. Lalka
  • Patent number: 8262931
    Abstract: A polymerizable liquid crystal compound represented by formula (I) is disclosed. R0 and R1 represent a hydrogen atom, or C1-4 alkyl; L0 and L1 represent a hydrogen atom, or C1-4 alkyl group; A0 and A1 represent a divalent linking group having a 5- to 12-membered cyclic structure; B0 and B1 represent a single bond or a divalent linking group having a 5- to 12-membered cyclic structure; D0 and D1 represent —O—, —S—, or —NR2—; X0 and X1 represent a hydrogen atom, acyl group or cyano; Y0 and Y1 represent a single bond or a divalent group; Q0 and Q1 represent a C1-20 divalent aliphatic group; Z0 and Z1 represent a hydrogen atom, cyano, halogen atom or polymerizable group; and n and m each independently represent an integer of from 0 to 2.
    Type: Grant
    Filed: March 28, 2011
    Date of Patent: September 11, 2012
    Assignee: FUJIFILM Corporation
    Inventors: Shunya Katoh, Yasuhiro Ishiwata, Masaomi Kimura, Mitsuyoshi Ichihashi
  • Patent number: 8257493
    Abstract: The present invention relates to conjugated polymers and a method for their synthesis. Furthermore, the present invention relates to electro-synthesis methods for producing polymers that include the use of at least one Lewis acid and at least one proton trap to form organic conjugated polymers having elevated refractive indices. In one embodiment, the present invention relates to an organic polymer having an elevated refractive index, the organic polymer formed by a process comprising the steps of: providing a solution of unsaturated organic monomer units and at least one acidic component; impeding saturation of the unsaturated organic-monomer units by at least one protic element in the solution; and polymerizing the unsaturated organic monomer units to form a conjugated organic polymer having a refractive index of at least about 2.3 for electromagnetic energy having a wavelength of about 700 nm.
    Type: Grant
    Filed: August 19, 2005
    Date of Patent: September 4, 2012
    Assignee: The University of Akron
    Inventors: Stephen Z. Cheng, Matthew J. Graham, Frank W. Harris, Shi Jin
  • Patent number: 8252399
    Abstract: Plastic tanks comprising a propylene-hexene-1 copolymer having a xylene soluble fraction lower than 5% wt with respect to the total weight of the copolymer and satisfying the following relation: A · T m B > 70 wherein A is the MFR measured according to the method ISO 1133 (230° C., 5 kg) expressed in g/10 min, Tm is the melting temperature measured by DSC expressed in ° C. and B is the hexene-1 content expressed in percentage by weight with respect to total weight of the copolymer.
    Type: Grant
    Filed: December 19, 2008
    Date of Patent: August 28, 2012
    Assignee: Basell Poliolefine Italia s.r.l.
    Inventor: Claudio Cavalieri
  • Patent number: 8217130
    Abstract: Disclosed herein is a curable composition excellent in workability, adhesion properties, rubber-like properties, storage stability, and quick curability. The curable composition comprises (A) a crosslinkable silyl group-containing organic polymer and (B) a (meth)acrylic polymer obtained by polymerizing a (meth)acrylic monomer having a polymerizable unsaturated bond in the presence of a metallocene compound and a crosslinkable silyl group-containing thiol compound, at least one end of the (meth)acrylic polymer being bonded to a residue, —S—R3 (where R3 represents a group having a crosslinkable silyl group) obtained by removing a hydrogen atom from the crosslinkable silyl group-containing thiol compound.
    Type: Grant
    Filed: June 25, 2010
    Date of Patent: July 10, 2012
    Assignee: Cemedine Co., Ltd.
    Inventors: Atsushi Saito, Tomonori Saito, Naomi Okamura
  • Patent number: 8206553
    Abstract: A method of improving retention and drainage in a papermaking process is disclosed. The method provides for the addition of an associative polymer, prepared by an inverse emulsion polymerization process that utilizes multiple, discrete additions of initiator. Additionally, a process for preparation of an associative polymer, prepared by an inverse emulsion polymerization process that utilizes multiple discrete additions of initiator is disclosed.
    Type: Grant
    Filed: December 21, 2005
    Date of Patent: June 26, 2012
    Assignee: Hercules Incorporated
    Inventors: Robert A. Gelman, Erin A. S. Doherty
  • Patent number: 8207291
    Abstract: Process for devolatilization of a polymer of an aromatic alkylene, such as styrene and, in particular, an improved process using water as a stripping agent (i) in which the total amount of water to be disposed of can be reduced, (ii) which allows at least a portion of the water to be recycled as stripping agent, reducing make-up requirements for the stripping agent, and (iii) which allows at least a portion of the aromatic alkylene monomer in the water to be recycled to the polymerization process (via the devolatilization steps) rather than being disposed.
    Type: Grant
    Filed: June 3, 2008
    Date of Patent: June 26, 2012
    Assignee: Ineos Europe Limited
    Inventor: Jean-Marc Galewski
  • Patent number: 8198384
    Abstract: A method for preventing or reducing clogging of a fines ejector in a gas-phase olefin polymerization process is disclosed. The process involves injecting a liquid into the motive gas stream entering the fines ejector.
    Type: Grant
    Filed: January 10, 2011
    Date of Patent: June 12, 2012
    Assignee: Westlake Longview Corporation
    Inventors: Glenn Edward Moore, Jeremy Bruce Mann
  • Patent number: 8153744
    Abstract: There is provided a novel hyperbranched polymer in which the refractive index is precisely controlled while retaining its hyperbranched structure, and a method for producing the hyperbranched polymer. Further, there is also provided an optically and thermally stable novel hyperbranched polymer in which the desired refractive index is precisely controlled, and a method for producing the hyperbranched polymer. The hyperbranched polymer has, as a branched structure, a repeating unit structure produced from two dithiocarbamate compounds each having a vinyl structure, at the polymerization initiation site having a vinyl structure. A specific example of the hyperbranched polymer can be produced by subjecting to a living radical polymerization N,N-diethyldithiocarbamylmethylstyrene in the presence of N,N-diethyldithiocarbamylethyl methacrylate.
    Type: Grant
    Filed: September 4, 2007
    Date of Patent: April 10, 2012
    Assignees: Nissan Chemical Industries, Ltd., Tokyo Institute of Technology
    Inventors: Hiroki Takemoto, Masaaki Ozawa, Koji Ishizu
  • Patent number: 8142681
    Abstract: Surfactant compositions which comprise (i) 10 to 90% by weight of one or more compounds selected from the group (a) to (e), and (ii) 10 to 90% by weight of water, based on the composition, are disclosed, where the compounds (a) to (e) are defined as follows: (a) addition products of ethylene oxide and/or propylene oxide with allyl alcohol, (b) addition products of ethylene oxide and/or propylene oxide with allyl alcohol, terminally capped with C1-20 alkyl, (c) compounds of the formula R1—O—X—R2, where X is 1 to 40 ethylene oxide and/or propylene oxide units and where R1 and R2 independently are C1-20 alkyl, excluding allyl, (d) compounds of the formula R3—O—X—H, where X is 1 to 40 ethylene oxide and/or propylene oxide units and where R3 is C1-20 alkyl, excluding allyl, (e) compounds of the formula H—O—X—H, where X is 1 to 40 ethylene oxide and/or propylene oxide units. The surfactant compositions are liquid and pourable at 20° C., with a pour point below 0° C.
    Type: Grant
    Filed: May 20, 2009
    Date of Patent: March 27, 2012
    Assignee: Cognis IP Management GmbH
    Inventors: Ronald Klagge, Markus Scherer, Thomas Schliwka, Katharina Hömberg, Uwe Held, Thomas Mausberg
  • Patent number: 8133958
    Abstract: One aspect of the invention relates to a methacrylate resin prepared by suspension polymerization using a polyalkylacrylate-acrylic acid as a suspension stabilizer. The suspension stabilizer is used in an amount of about 0.05 to about 0.25 parts by weight per 100 parts by weight of a monomer mixture. Another aspect of the invention relates to a method for preparing a methacrylate resin, which comprises: preparing a mixture by mixing an initiator and a chain-transfer agent with a monomer mixture comprising at least about 50% by weight of alkyl methacrylate; and adding the mixture to an aqueous solution of polyalkylacrylate-acrylic acid to conduct suspension polymerization.
    Type: Grant
    Filed: December 20, 2007
    Date of Patent: March 13, 2012
    Assignee: Cheil Industries Inc.
    Inventors: Jae Hoon Jeong, Doo Han Ha, Jung Ho Jang
  • Patent number: 8128877
    Abstract: A manufacturing process for producing polyolefin, having a feed system, a reactor system including at least one polymerization reactor, a diluent/monomer recovery system, a fractionation system, and an extrusion/loadout system having an extruder. The manufacturing process is configured to consume less than 325 kilowatt-hours of electricity per metric ton of polyolefin produced.
    Type: Grant
    Filed: August 10, 2011
    Date of Patent: March 6, 2012
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Robert R. McElvain, John D. Hottovy, Ralph W. Romig, Donald W. Verser, David H. Burns, John H. Tait, Richard Peacock, James E. Hein, Scott E. Kufeld, Carl W. Fenderson, Anurag Gupta, Dale A. Zellers, Penny A. Zellers, legal representative
  • Patent number: 8119751
    Abstract: A photoresist material for lithography using a light of 220 nm or less which comprises at least a polymer represented by the following formula (2) and a photo-acid generator for generating an acid by exposure: wherein R1, R2, R3 and R5 are each a hydrogen atom or a methyl group; R4 is an acid-labile group or one of a specified subset of alicyclic hydrocarbon groups, alicyclic hydrocarbon groups, or hydrocarbon groups; R6 is a hydrogen atom or one of a specified subset of hydrocarbon groups or alicyclic hydrocarbon groups; x, y and z are optional values which meet x+y+z=1, 0<x?1, 0?y<1 and 0?z<1. Also disclosed is a resin having a (meth)acrylate unit of an alicyclic lactone structure represented by the formula (3): wherein R8 is a hydrogen atom or a methyl group, and R9 is one of a specified subset of hydrocarbon groups.
    Type: Grant
    Filed: August 29, 2008
    Date of Patent: February 21, 2012
    Assignee: NEC Corporation
    Inventors: Katsumi Maeda, Shigeyuki Iwasa, Kaichiro Nakano, Etsuo Hasegawa
  • Patent number: 8105547
    Abstract: A polymerization reactor having at least three side wall surfaces and a bottom wall surface forming a reservoir and at least one heat exchanger plate in fluid communication with a coolant source, wherein each of the at least one heat exchanger plate is disposed on a lid. The polymerization reactors of the present invention permit large amounts of polymer to be formed in each reactor batch. Preferably, polymers are formed in the polymerization reactor by bulk polymerization. Methods for forming polymers is also disclosed.
    Type: Grant
    Filed: August 21, 2006
    Date of Patent: January 31, 2012
    Assignee: Beta Technologie AG
    Inventors: Gerald B. Eaton, Patrick Trainor
  • Patent number: 8097126
    Abstract: The present invention relates to an aqueous composition comprising at least one finely divided filler and at least one water-soluble amphoteric copolymer, a process for the preparation of such a composition and its use as an additive in the production of paper, cardboard and board.
    Type: Grant
    Filed: July 15, 2005
    Date of Patent: January 17, 2012
    Assignee: BASF SE
    Inventors: Hans-Joachim Haehnle, Anton Esser, Volker Braig, Rainer Blum, Peter Baumann, Jacques Dupuis, Josef Neutzner
  • Patent number: 8084556
    Abstract: In a process for producing water-absorbing polymeric particles by suspension polymerization, a monomer solution is metered into a stirred reactor via at least one feed line, the stirred reactor has a volume of at least 1 m3 and the at least one feed line ends in the stirred reactor at a point less than 25 cm above the liquid surface.
    Type: Grant
    Filed: December 3, 2007
    Date of Patent: December 27, 2011
    Assignee: BASF SE
    Inventor: Rüdiger Funk
  • Publication number: 20110294971
    Abstract: Olefin metathesis polymerization reactions are disclosed, and more particularly ring-opening metathesis polymerization of cyclic olefins with olefinic compounds, such as are derived from seed oils and the like, to form telechelic polymers. In one aspect, a method is provided for carrying out a catalytic ring-opening metathesis polymerization reaction, comprising contacting at least one olefinic compound with at least one cyclic olefin, in the presence of a ruthenium alkylidene olefin metathesis catalyst under conditions effective to allow ring-opening metathesis polymerization of the cyclic olefin, whereby the cyclic olefin polymer formed is terminated with the olefinic compound. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and industrial chemistry.
    Type: Application
    Filed: August 21, 2009
    Publication date: December 1, 2011
    Applicant: MATERIA, INC.
    Inventors: Simon C. Jones, Farshad J. Motamedi, Li-Sheng Wang, Brian Edgecombe, Michael A. Giardello
  • Patent number: 8067506
    Abstract: Water-soluble fluorescent particles are formed in a simple process. A mixture comprising a solvent, water, a fluorescent polymer dissolved in the solvent, and an amphiphilic molecule is provided. The fluorescent polymer comprises a hydrophobic segment. The amphiphilic molecule comprises hydrophilic and hydrophobic segments. The solvent is removed from the mixture to allow the fluorescent polymer and the amphiphilic molecule to entangle in the presence of water, thus forming the water-soluble fluorescent particles. In the formed particles, the hydrophilic segments of the amphiphilic molecule are entangled with one another, and the hydrophobic segments of the fluorescent polymer and amphiphilic molecule are entangled with one another. The amphiphilic molecule encapsulates the fluorescent polymer and at least some of the hydrophilic segments are exposed to render the particle soluble in water.
    Type: Grant
    Filed: August 30, 2006
    Date of Patent: November 29, 2011
    Assignee: Agency for Science, Technology and Research
    Inventors: Zhikuan Chen, Xu Li
  • Patent number: 8058370
    Abstract: The object of the present invention is to provide a process for producing high-quality polymer microparticles having uniform particle size of the order of several micrometers to tens of micrometers by inverse suspension polymerization at high productivity while keeping excellent dispersion stability without causing aggregation among particles. The process is one for the production of polymer microparticles by inverse suspension polymerization of a vinyl monomer and includes steps of preparing in a dispersing tank a water-in-oil (W/O) type emulsion in which an organic solvent is a continuous phase and an aqueous solution of a vinyl-based monomer is a dispersing phase, and conducting the inverse suspension polymerization while feeding the water-in-oil (W/O) type emulsion to a continuous stirred tank reactor.
    Type: Grant
    Filed: January 22, 2009
    Date of Patent: November 15, 2011
    Assignee: Toagosei Co., Ltd.
    Inventors: Shinji Hibino, Hideo Matsuzaki, Akihiro Gotou
  • Patent number: 8034896
    Abstract: The present invention relates to a method for degassing polymer powder comprising flushing the polymer powder in a first chamber with a first flow of flushing gas, transferring the polymer powder into a second chamber and flushing the polymer powder with a second flow of flushing gas in said second chamber. The present invention also relates to a system suitable for carrying out this method.
    Type: Grant
    Filed: March 6, 2007
    Date of Patent: October 11, 2011
    Assignee: Total Petrochemicals Research Feluy
    Inventors: Eric Damme, Marc Moers, Lieven Van Looveren
  • Patent number: 8034884
    Abstract: Gas-phase fluidized-bed reactor for polymerizing ethylenically unsaturated monomers, comprising a reactor chamber (1) in the form of a vertical tube, if desired a calming zone (2) following the upper section of the reactor chamber, a circulation gas line (3), a circulation gas compressor (4) and a cooling device (5), where, in the region of transition of the reaction gas from the circulation gas line into the reactor chamber and in the lower section of the reactor chamber itself, there is either no gas distributor plate at all or only a gas distributor plate the total surface area of whose gas orifices is more than 20% of the total surface area of said gas distributor plate.
    Type: Grant
    Filed: September 7, 2009
    Date of Patent: October 11, 2011
    Inventors: Rainer Karer, Kaspar Evertz, Wolfgang Micklitz, Hans-Jacob Feindt, Philipp Rosendorfer, Peter Kölle
  • Publication number: 20110244249
    Abstract: An intermediate transfer media, such as a belt, that includes a cyclo olefin polymer.
    Type: Application
    Filed: March 30, 2010
    Publication date: October 6, 2011
    Applicant: XEROX CORPORATION
    Inventor: Jin Wu
  • Patent number: 8030419
    Abstract: To provide a method for producing a polymer for semiconductor lithography which can attain high uniformity in the polymer from lot to lot. The method for producing a polymer for semiconductor lithography includes the step (P) of heating a polymerizable monomer and a polymerization initiator in a solvent, to thereby polymerize the monomer, the step (P) having the step of controlling a polymerization pressure by regulating a liquid level in a container (WO) which is disposed between a polymerization tank and the atmospheric air and which provides liquid sealing.
    Type: Grant
    Filed: December 20, 2007
    Date of Patent: October 4, 2011
    Assignee: Maruzen Petrochemical Co., Ltd.
    Inventors: Takanori Yamagishi, Ichiro Kato, Satoshi Yamaguchi, Kouzo Osaki, Yasuo Shibata, Isao Magara, Hideki Omori, Kensuke Iuchi
  • Patent number: 8022030
    Abstract: The present invention relates to the field of perfumery. More particularly, it concerns co-polymers, derived from a maleic anhydride derivative and a ethylenic derivative, comprising at least one ?-oxy or ?-thio carbonyl moiety capable of liberating an active molecule such as, for example, an ?,?-unsaturated ketone, aldehyde or carboxylic ester. The present invention concerns also the use of polymers or co-polymers in perfumery as well as the perfuming compositions or perfumed articles comprising the invention's compounds.
    Type: Grant
    Filed: October 5, 2007
    Date of Patent: September 20, 2011
    Assignee: Firmenich SA
    Inventors: Damien Berthier, Andreas Herrmann
  • Patent number: RE43983
    Abstract: Multi-modal vinyl ester resins having one or more of good fracture toughness, good processing viscosity, and low volatile organic compound emissions are provided. The multi-modal vinyl ester resins are the reaction product of a liquid or crystalline epoxy and an amorphous, solid epoxy, as determined at 25° C., with a vinyl carboxylic acid. The multi-modal vinyl ester resins may contain a reactive diluent, though generally, lower reactive diluent contents are required for such resins than for similar, commercially available vinyl ester resins.
    Type: Grant
    Filed: May 6, 2005
    Date of Patent: February 5, 2013
    Assignees: Drexel University, The United States of America as Represented by the Secretary of the Army
    Inventors: Giuseppe Raffaello Palmese, John Joseph La Scala, James Matthew Sands