Patents Represented by Attorney Robert L. Stone
  • Patent number: 4020154
    Abstract: Gas-free paste or gel dentifrices are made by a process which includes producing a degassed gel of a gelling agent in a polyhydric alcohol, and admixing it with other dentifrice constituents, including powdered light weight polishing agent, under vacuum. Preferably, the powdered polishing agent is degassed in a vacuum hopper, before addition to the gel base in a mixer. Where no vacuum hopper or similar facilities are available, however, powdered polishing agent may be added to the gel in a suitable mixer with adequate head space and any gas present is removed from it by vacuum while it is resting on the surface of the gel, after which the polishing agent is mixed in with the gel.
    Type: Grant
    Filed: December 9, 1974
    Date of Patent: April 26, 1977
    Assignee: Colgate-Palmolive Company
    Inventors: Giulio Perla, Giuseppe Mannara, Domenico Milesi
  • Patent number: 4016040
    Abstract: Granular free-flowing non-dusting, spherical enzyme-containing beads for use in detergents are prepared by spraying droplets of a blend consisting essentially of a molten nonionic detergent and an enzyme concentrate from a spray nozzle into cool air in a cooling tower to solidify the droplets and form tiny spherical beads.
    Type: Grant
    Filed: November 1, 1974
    Date of Patent: April 5, 1977
    Assignee: Colgate-Palmolive Company
    Inventors: Maung Hla Win, Walter Anthony DiSalvo, Edward Joseph Kenney
  • Patent number: 4007709
    Abstract: Post-larval lobsters are raised to a size for marketing in a series of divided trays suitable for stacking and having therein a hollow tube in the center of the trays. Small holes are present on the wall of the hollow tube, the dividers in the trays and the floors of the trays. A pressure pump can be inserted in the hollow tube to aerate the water and to feed the lobsters by pumping air and food from the pump to pass through the holes.
    Type: Grant
    Filed: March 24, 1975
    Date of Patent: February 15, 1977
    Inventor: Frederick B. Wishner
  • Patent number: 4007281
    Abstract: Quaternary ammonium carbamate, thiocarbamate, dithiocarbamate and carbamide compounds. Typical examples are[C.sub.4 H.sub.9 NHCOO(CH.sub.2).sub.2 N.sup.+(CH.sub.3).sub.2 C.sub.12 H.sub.25 ]Br.sup.-[C.sub.4 H.sub.9 NHOSO(CH 2).sub.2 N.sup.+(CH.sub.3).sub.2 C.sub.12 H.sub.25 ]Br.sup.-[CH.sub.3 NHCSS(CH.sub.2).sub.2 N.sup.+(CH.sub.3).sub.2 C.sub.12 H.sub.25 ]Br.sup.-[C.sub.2 H.sub.5 NHCONH(CH.sub.2).sub.2 N.sup.+(CH.sub.3).sub.2 C.sub.12 H.sub.25 ]Br.sup.-.
    Type: Grant
    Filed: February 20, 1976
    Date of Patent: February 8, 1977
    Assignee: Colgate-Palmolive Company
    Inventor: Robert Andrew Bauman
  • Patent number: 4003971
    Abstract: Dentifrice speckles of substantially uniform shape and size are made by agitating the material of such speckles (binder plus dentifrice component) in a liquid dispersing medium at a temperature at which the binder is liquid but undissolved and unemulsified in the dispersing medium, and cooling the dispersion to a temperature below the solidification point of the speckling material so as to solidify it into speckles of desired size. Such speckles may be separated from the dispersing medium or may remain in it and be utilized with it. Preferably the speckles are incorporated in dentifrices and contain dentifrice components desirably maintained separate from the rest of the dentifrice. Also included within the invention described are the speckles and dentifrices containing them.
    Type: Grant
    Filed: November 4, 1974
    Date of Patent: January 18, 1977
    Assignee: Colgate-Palmolive Company
    Inventor: Giuseppe Mannara
  • Patent number: 4002732
    Abstract: Functional speckle particle suitable for use in dentifrice containing allantoin, aluminum dihydroxy allantoinate (ALDA) or aluminum chlorohydroxyallantoinate (ALCA). The speckle is effective in promoting healing of inflamed and bleeding gums or periodontal tissue.
    Type: Grant
    Filed: September 15, 1975
    Date of Patent: January 11, 1977
    Assignee: Colgate-Palmolive Company
    Inventor: Ian Ray Gault
  • Patent number: 3992431
    Abstract: Novel quaternary ammonium compounds which include the adamantane ring system linked to the quaternary ammonium group by a hydrocarbon chain or by other functional groups, such as ether, carboxylic ester, carboxamide, keto, carbamate ester, thiocarbamate ester, etc.
    Type: Grant
    Filed: August 20, 1975
    Date of Patent: November 16, 1976
    Assignee: Colgate-Palmolive Company
    Inventor: Robert Andrew Bauman
  • Patent number: 3991000
    Abstract: A bleaching detergent composition, in which the bleaching component is a water soluble inorganic percompound, such as sodium perborate, includes an alkali metal builder salt, such as pentasodium tripolyphosphate, a water soluble organic builder salt, such as trisodium nitrilotriacetate and an organic detergent, such as sodium linear higher alkyl benzene sulfonate, and is improved in bleaching effectiveness by inclusion therein of a particular concentration of a water soluble copper salt, such as copper sulfate hydrate, which results in the presence of a particular desirable proportion of copper ions in the bleaching detergent solution resulting from normal use of the composition.
    Type: Grant
    Filed: November 1, 1974
    Date of Patent: November 9, 1976
    Assignee: Colgate-Palmolive Company
    Inventors: Georges Jean Paul Chazard, Yvon Demangeon
  • Patent number: 3991177
    Abstract: Oral compositions containing dextranase and a stabilizer/activator selected from the group consisting of manganeous ions, calcium ions, and mixtures thereof.
    Type: Grant
    Filed: March 12, 1975
    Date of Patent: November 9, 1976
    Assignee: Colgate-Palmolive Company
    Inventors: James David Vidra, Julius Harvey Nachtigal
  • Patent number: 3989814
    Abstract: Dentifrice possessing enhanced polishing characteristics containing abrasive system including at least calcium pyrophosphate and a non-toxic zinc compound in an amount to provide at least about 0.0065% of zinc to the dentifrice.
    Type: Grant
    Filed: March 17, 1975
    Date of Patent: November 2, 1976
    Assignee: Colgate-Palmolive Company
    Inventors: Martin Cordon, James Norfleet
  • Patent number: 3989813
    Abstract: Dentifrice containing flavoring oil and phosphate ion and 1,6-di-(p-chlorophenyl biguanidohexane) and ethanol to stabilize the dentifrice against separation.
    Type: Grant
    Filed: October 9, 1975
    Date of Patent: November 2, 1976
    Assignee: Colgate-Palmolive Company
    Inventors: Joseph Paul Januszewski, Tayseer George Bahouth, deceased, by Zaher G. Bahouth, administrator
  • Patent number: 3984537
    Abstract: The invention relates to an oral preparation, i.e. dentifrice, which contains non-toxic amino-cyano polymeric diguanide or salt thereof as an anti-bacterial agent.
    Type: Grant
    Filed: March 12, 1975
    Date of Patent: October 5, 1976
    Assignee: Colgate-Palmolive Company
    Inventors: Michael Harrison, Kenneth Tomlinson
  • Patent number: 3976765
    Abstract: Stable bis-biguanido hexane-containing oral products are disclosed which retain therapeutic activity against plaque and breath odor and concurrently possess desirable foaming properties. The oral products contain polyoxyethylene-polyoxypropylene nonionic surfactant in combination with a foam booster which is a long-chain tertiary amine oxide of C.sub.10 -C.sub.18 chain length or monoethanolamide of a fatty acid having from 10 to 18 carbon atoms.
    Type: Grant
    Filed: December 12, 1974
    Date of Patent: August 24, 1976
    Assignee: Colgate-Palmolive Company
    Inventor: Julius Harvey Nachtigal
  • Patent number: 3965545
    Abstract: A belt buckle formed of a single piece of hard material having a front face and parallel thereto when the buckle is closed, a back face, connected at an adjacent end of each face by two hinges at the sides of each face and an integral frictional wedged prong connected to the other end of one of said faces, essentially perpendicular thereto, which engages the opposite face in a locking manner.
    Type: Grant
    Filed: May 28, 1975
    Date of Patent: June 29, 1976
    Inventor: Lars Johansson
  • Patent number: 3966901
    Abstract: The present invention relates to a dentifrice preparation containing a water-soluble monofluorophosphate and a polishing material containing at least a major proportion of dimagnesium orthophosphate.
    Type: Grant
    Filed: February 21, 1975
    Date of Patent: June 29, 1976
    Assignee: Colgate-Palmolive Company
    Inventors: Douglas Charles Cullum, Joan Collinge
  • Patent number: 3961075
    Abstract: Novel quaternary ammonium compounds containing one large aliphatic group, and an adamantyl group linked to the quaternary nitrogen by an ether group.
    Type: Grant
    Filed: May 9, 1975
    Date of Patent: June 1, 1976
    Assignee: Colgate-Palmolive Company
    Inventor: Robert Andrew Bauman
  • Patent number: 3961074
    Abstract: Novel keto-quaternary ammonium compounds which include the adamantane ring system linked to the quaternary ammonium group by a keto group.
    Type: Grant
    Filed: May 9, 1975
    Date of Patent: June 1, 1976
    Assignee: Colgate-Palmolive Company
    Inventor: Robert Andrew Bauman
  • Patent number: 3957968
    Abstract: Dentifrices containing flat flakes of alpha-alumina.
    Type: Grant
    Filed: March 25, 1975
    Date of Patent: May 18, 1976
    Assignee: Colgate-Palmolive Company
    Inventor: Martin Cordon
  • Patent number: 3956480
    Abstract: Treatment of teeth by sorbing onto the tooth surfaces a combination of a cationic germicide and an anionic polymer.
    Type: Grant
    Filed: July 1, 1974
    Date of Patent: May 11, 1976
    Assignee: Colgate-Palmolive Company
    Inventors: Michael Dichter, Durydehan Mangaraj, William James King
  • Patent number: 3956479
    Abstract: Quaternary ammonium carbamate, thiocarbamate, dithiocarbamate and carbamide compounds. Typical examples are[C.sub.4 H.sub.9 NHCOO(CH.sub.2).sub.2 N.sup.+(CH.sub.3).sub.2 C.sub.12 H.sub.25 ]Br.sup.-[C.sub.4 H.sub.9 NHCSO(CH.sub.2).sub.2 N.sup.+(CH.sub.3).sub.2 C.sub.12 H.sub.25 ]Br.sup.-[CH.sub.3 NHCSS(CH.sub.2).sub.2 N.sup.+(CH.sub.3).sub.2 C.sub.12 H.sub.25 ]Br.sup.-[C.sub.2 H.sub.5 NHCONH(CH.sub.2).sub.2 N.sup.+(CH.sub.3).sub.2 C.sub.12 H.sub.25 ]Br.sup.-These compounds are effective against gram positive bacteria and fungi and reduce caries and inhibit formation of oral calculus. The thiocarbamates can be prepared by converting amino alcohols to sodium salts thereof with metallic sodium and reacting isothiocyanates with the sodium salts followed by quaternization. The carbamates can be prepared by reacting isocyanates with amino alcohols followed by quaternization. The dithiocarbamates can be prepared by reacting isothiocyanates with sodium salts of aminoalkanethiols followed by quaternization.
    Type: Grant
    Filed: April 16, 1971
    Date of Patent: May 11, 1976
    Assignee: Colgate-Palmolive Company
    Inventor: Robert Andrew Bauman