Abstract: Liquid, aqueous disinfectant preparations containing a combination of(a) at least one microbicidal quaternary ammonium compound(b) at least one microbicidal biguanide compound and(c) at least one microbicidal phenolic compound,components (a) and (b) being present in a ratio by weight a:b of (16 - 2); 1 while components (a) and (c) are present in a ratio by weight a:c of (16 - 2):1.
Type:
Grant
Filed:
February 8, 1990
Date of Patent:
July 9, 1991
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Klaus Bansemir, Karlheinz Disch, Klaus Hachmann
Abstract: The invention seeks to improve the preheating resistance and high temperature resistance during vulcanization of a cement for the vulcanization of rubber onto metals. Such cements conventionally contain metal-binding polymers, dinitrosobenzene, organic solvents and, optionally, other components, such as acid-binding agents and reinforcing fillers. The goals of the invention are achieved by partial replacement of the usual metal-binding polymers by substituted aromatic compounds bearing two or more substituent groups having the formula --CH.sub.2 Br.
Abstract: Drilling mud additives based on a polymer mixture of 20 to 80% by weight carboxymethyl cellulose and 80 to 20% by weight of a polycarboxylic acid selected from polyacrylate, polymethacrylate and/or copolymers thereof and/or salts thereof, in which the carboxymethyl cellulose, which has been obtained from raw linters and/or wood cellulose by the slurry process, is mixed in wet, alcohol-moist form with the polycarboxylic acid and dried, to their use in drilling muds or workover and packer liquids, and to a process for their production.
Type:
Grant
Filed:
September 29, 1989
Date of Patent:
July 2, 1991
Assignees:
Henkel Kommanditgesellschaft auf Aktien, Phrikolat Chemische Erzeugnisse GmbH
Inventors:
Willy Opitz, Heinz Mueller, Claus-Peter Herold, Stephan Von Tapavicza
Abstract: An improved process for recovery for precious metals such as gold and silver from aqueous cyanide solutions by contact with certain guanidine reagents. The guanidine reagents not only extract the precious metal but may provide advantages in selectivity of gold over other metals, such as tetra- and pentahydrocarbon substituted non-resin guanidine reagents and tri- and tetra-hydrocarbon substituted resin guanidine reagents.
Type:
Grant
Filed:
March 6, 1991
Date of Patent:
July 2, 1991
Assignee:
Henkel Research Corporation
Inventors:
Lon-Tang W. Lin, Phillip L. Mattison, Michael J. Virnig
Abstract: The adhesion of, and corrosion protection provided by, organic surface coatings to underlying metal can be significantly improved if the degreased, etched, and pickled metal surfaces to be coated are first treated with an aqueous solution and/or dispersion of aluminum-zirconium complexes, which are obtainable as the reaction-product of a chelated aluminum component, an organo-functional ligand component, and a zirconium oxyhalide component, with the organo-functional ligand being chemically bonded to the chelated aluminum unit and the zirconium unit in the complex, and are subsequently treated with dilute aqueous solutions, emulsions, and/or dispersions of one or more inorganic and/or organic film-forming materials prior to coating the surfaces with conventional organic surface coatings.
Type:
Grant
Filed:
August 24, 1989
Date of Patent:
June 25, 1991
Assignee:
Gerhard Collardin GmbH
Inventors:
Cornelia Finnenthal, Wolf-Achim Roland, Roland Morlock
Abstract: In the production of epoxidized fatty alcohols by reaction of fatty alcohols containing at least one olefinic double bond with hydrogen peroxide and formic acid, the formation of secondary products is reduced by carrying out the epoxidation in the presence of a buffer.
Abstract: A radially expandable hair curler comprising a generally cylindrical hollow body, a detachable holding strap stretching from one longitudinal end of the body to the other, and internal mechanical devices for expanding and contracting the curler body.
Type:
Grant
Filed:
July 17, 1989
Date of Patent:
June 4, 1991
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Detlef Hollenberg, Hans Schneider, Georg Weihrauch
Abstract: Esters and mixtures of esters of polyhydric alcohols, e.g., of pentaerythritol, in which at least 22 number percent of the acyl groups in the esters are either branched or contain no more than six carbon atoms, are effective lubricants and/or lubricant base stocks for chlorine-free fluorocarbon refrigerant heat transfer fluids, particularly for chlorine-free heat transfer fluids such as Refrigerant 134a (1,1,1,2-tetrafluoroethane).
Abstract: A pearlescent concentrate in the form of a free-flowing dispersion containing from 5 to 15% by weight of one or more ester corresponding to the following formulaR.sup.1 --(OC.sub.n H.sub.2n).sub.x --OR.sup.2and from 1 to 6% by weight of one or more fatty acid monoethanolamide may be prepared using from 2 to 8% by weight of one or more compound selected from the group alkyl (oligo) glucoside, sorbitan fatty acid ester, fatty amine ethoxylate, ether carboxylic acid, or fatty acid monoester or diester of glycerol ethoxylate as an emulsifier.
Abstract: Compositions for coating steel wire to facilitate the cold drawing thereof comprising:A. from about 50 to about 99.9% by weight of K.sub.2 SO.sub.4 ;B. from about 0 to about 49.99% by weight of K.sub.2 B.sub.4 O.sub.7 and/or KBO.sub.2 ; andC. from about 0.01 to about 5% by weight of an ammonium and/or a potassium soap;wherein up to 50% by weight of the total potassium plus ammonium ions in the composition can be replaced by sodium ions. These compositions form coatings which have good crystalline structure and drawability with low hygroscopicity.
Abstract: An autodeposition bath for coating steel and similar metals is operated initially with a low content of dissolved iron and at a high oxidizing potential. After the iron content has increased beyond a specific level, such as 1.5 g/l, the oxidizing potential is reduced. This permits continued satisfactory operation of the bath with lower rates of iron accumulation in the bath, so that the need for bath stabilization by removing dissolved iron is deferred.
Abstract: Imidazoles are alkylated at the 1-position by adding an alkyl halide a mixture comprising an imidazole, a non-reactive aromatic solvent and a base at temperature of from about 75.degree. C. to about 115.degree. C. and then maintaining the temperature for a period of time sufficient to produce the 1-alkylimidazole and then separating any inorganic material from the product.
Type:
Grant
Filed:
June 19, 1990
Date of Patent:
April 30, 1991
Assignee:
Henkel Research Corporation
Inventors:
Heinz-Guenther Schulte, Jeffrey L. Narum, Michael R. Johnson
Abstract: Stabilizers for chlorine-containing olefin polymers containing Ca complexes of 1,3-diketones, hydrocarbon waxes and esters and/or partial esters of saturated, straight-chain C.sub.12 -C.sub.34 monocarboxylic acids, in conjunction with zinc salts of saturated, straight-chain C.sub.8 -C.sub.22 monocarboxylic acids and esters of phosphorous acid, provide the polymers with excellent properties in regard to processibility and temperature stability.
Type:
Grant
Filed:
April 4, 1989
Date of Patent:
April 23, 1991
Assignee:
Neynaber Chemie GmbH
Inventors:
Kurt Worschech, Peter Wedl, Erwin Fleischer, Frido Loeffelholz, Manfred Jaeckel
Abstract: The invention is a process for the continuous liquid-phase esterification of C.sub.2 -C.sub.24 fatty acids with alkanols in countercurrent contact and reaction in a reaction column, the catalysts and fatty acids are introduced at the top plate and the alkanols below the lowest plate, at a head pressure of the reaction column of 200 to 900 hPa. The process reduces dehydration of the alkanols.
Type:
Grant
Filed:
March 21, 1989
Date of Patent:
April 16, 1991
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Norbert Bremus, Bernhard Gutsche, Lutz Jeromin, Eberhard Peukert, Bernard Schleper
Abstract: A liquid detergent based on nonionic and anionic surfactants, and optionally particulate builder materials, contains a non-surfactant component which increases the wash efficiency, comprising the combination of low-polarity and mid- to high-polarity organic liquids. The low-polarity liquids are hydrocarbons, while the mid- to high-polarity liquids are esters, ethers, ketones or alcohols. The detergents have a satisfactory viscosity behavior, good miscibility with water and good wash efficiency.
Abstract: Copolymers of long-chain alkyl acrylates or methacrylates of the formulaCH.sub.2 .dbd.CR.sup.1 --CO--OR.sup.2 (I)in which R.sup.1 is a hydrogen atom or a methyl group and OR.sup.2 is a fatty alcohol radical with 16 to 34 carbon atoms and nitrogen-containing olefins can be used as flow improvers for crude oils.
Type:
Grant
Filed:
March 21, 1989
Date of Patent:
April 9, 1991
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Bernd Wahle, Claus-Peter Herold, Wolfgang Zoellner, Ludwig Schieferstein, Doris Oberkobusch
Abstract: New isocyanate prepolymers obtainable from polyethers and/or polyesters containing 2 OH groups and diisocyanates and triols in a two-step process and their use as principal component in sealing compounds, adhesives and coating compositions.
Abstract: Joint-sealing materials and coating materials which contain aqueous dispersions of polyacrylates or acrylate copolymers, plasticizers and the usual additives, such as pigments and the like, have excellent properties particularly with regard to brushability, smoothing behavior and wash-out resistance when they contain a nonionic cellulose ether selected from the group consisting of hydroxyethyl cellulose, hydroxyethyl-methyl cellulose, hydroxypropyl-methyl cellulose and hydroxypropyl cellulose having a Brookfield viscosity in a 2% aqueous solution at 20.degree. C. of at least 3000 mPa.s.
Type:
Grant
Filed:
April 24, 1989
Date of Patent:
April 2, 1991
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Helmut Loth, Klaus Helpenstein, Tore Podola, Bernhard Knop
Abstract: The invention relates to the use of mixtures containing (A) alkali metal, ammonium and/or amine salts of sulfonated unsaturated fatty acids and (B) alkoxylated alkyl and/or alkenyl alcohols and/or sulfosuccinic acid alkyl esters as wetting agents.