Abstract: A process for the manufacture of acicular magnetic gamma-iron(III) oxide by reducing acicular alpha-iron(III) oxide to magnetite and then oxidizing it to gamma-iron(III) oxide, wherein the alpha-iron(III) oxide is treated with a water-soluble alkaline earth metal compound and an alkylphenol with one to three alkyl radicals, each of 4 to 24 carbon atoms, on the benzene nucleus. Gamma-iron(III) oxides manufactured in this way show better magnetic orientability in the binder-containing dispersion, and a higher coercive force than prior art magnetic pigments.
Type:
Grant
Filed:
September 25, 1975
Date of Patent:
April 19, 1977
Assignee:
BASF Aktiengesellschaft
Inventors:
Eberhard Koester, Gerd Wunsch, Eduard Schoenafinger, Hans Henning Schneehage, Helmut Jakusch
Abstract: Magnetic recording tape especially suitable for use as video tape and computer tape, comprising a base carrying a magnetic coating which consists essentially of a dispersion of a finely divided magnetic pigment and at least one lubricant in an organic binder. The lubricant is a compound of the formula ##STR1## IN WHICH N IS AN INTEGER OF FROM 3 TO 8 AND R.sup.1 and R.sup.2 are an alkoxy or aralkoxy radical or conjointly are an alkyldioxy radical of 3 to 18 carbon atoms. A magnetic recording tape prepared with a high proportion of such a lubricant is distinguished by high abrasion resistance coupled with a minimum transfer of material to the magnetic heads even under fluctuating climatic conditions.
Type:
Grant
Filed:
September 19, 1974
Date of Patent:
April 19, 1977
Assignee:
BASF Aktiengesellschaft
Inventors:
Hermann Roller, Werner Senkpiel, Gerd Wunsch, Job-Werner Hartmann, Friedrich Fuchs, Joachim Hack, Volker Kiener, Herbert Motz, Werner Ostertag
Abstract: Mono- or di-alkyl phosphate or their alkali metal salts or optionally substituted ammonium salts for use as antifoaming and hydrophobizing additives for hydraulic binders.
Type:
Grant
Filed:
October 29, 1974
Date of Patent:
April 19, 1977
Assignee:
BASF Aktiengesellschaft
Inventors:
Rolf Petri, Harry Distler, Bertold Bechert
Abstract: For the preparation of anhydrous sodium dithionite by the reaction of sulfur dioxide with sodium formate and caustic soda in the presence of organic solvents, sulfur dioxide is passed, together with the formate, into a liquid containing all of the caustic soda required for the reaction. This initial liquid may contain, in addition to the caustic soda, a portion of the sulfur dioxide or formate required for the reaction.
Abstract: A process and apparatus for the production of exposed printing plates consisting of a resin layer and a support, said resin layer being prepared from a fluid photopolymerizable material which is introduced into a mold having at least one transparent wall which is covered with an image-bearing transparency, and being exposed through said image-bearing transparency, which causes photopolymerization of the exposed areas of the resin layer and bonds these areas to the support which is provided with an adhesive layer.
Type:
Grant
Filed:
February 19, 1975
Date of Patent:
April 12, 1977
Assignee:
BASF Aktiengesellschaft
Inventors:
Werner Lenz, Josef Woellhaf, Klaus Spreng, Manfred Zuerger, Paul Hecke, Gerhard Hoffmann, Milan Obradovic
Abstract: Soiled hot end coated glassware having a substantially colorless and transparent thin protective coating thereon including an organic coating material is washed in an inhibited aqueous caustic soda cleaning solution to inhibit the deleterious effects of repeated washings and thereby increase the effective life of the protective coating. The cleaning solution comprises on a weight basis from 0.3 to 6% of caustic soda, from 0.01% to 0.3% of at least one soluble zinc containing compound when calculated as zinc oxide, and the remainder water. Other ingredients which may be present include from 0.002 to 0.05% of a synthetic organic phosphate ester anionic surfactant having hydrotrophic properties, from 0.001 to 0.03% of a low foaming synthetic alkoxylated nonionic surfactant, and from 0.008 to 0.2% of a hard water conditioning sequesterant.
Abstract: A gas phase process for the production of triethylenediamine or 1,4-diaza-bicyclo-(2,2,2)-octane from N,N'-dihydroxyethylpiperazine, wherein aluminum oxide is used as a catalyst.
Type:
Grant
Filed:
September 3, 1975
Date of Patent:
April 12, 1977
Assignee:
BASF Aktiengesellschaft
Inventors:
Horst Guenter Bosche, Karl Baer, Kurt Schneider
Abstract: Impact-resistant thermoplastic molding compositions containing from 70 to 98 percent by weight of a polyoxymethylene and from 30 to 2 percent by weight of a block copolymer of the general formula A -- B -- A, wherein A is a polyalkylene oxide block and B is a diene polymer block.
Type:
Grant
Filed:
February 13, 1975
Date of Patent:
April 12, 1977
Assignee:
BASF Aktiengesellschaft
Inventors:
Franz Schmidt, Gerhard Fahrbach, Wolfgang Schenk, Erhard Seiler
Abstract: A process for the manufacture of acicular ferromagnetic metal pigments containing iron, having a reduced field strength distribution and a steeper residual magnetization curve, by applying an alkaline earth metal cation and an organic compound having at least one group capable of forming a chelate to appropriate acicular iron oxides and then reducing the treated oxides.
Type:
Grant
Filed:
July 14, 1975
Date of Patent:
April 12, 1977
Assignee:
BASF Aktiengesellschaft
Inventors:
Eberhard Koester, Gerd Wunsch, Paul Deigner, Werner Stumpfi, Hans Henning Schneehage
Abstract: The manufacture of 1,4-butanediol by hydroformylation of cyclic acetals of acrolein in the presence of phosphine-modified cobalt carbonyl complexes or rhodium carbonyl complexes and hydrogenation of the 3-formylpropionaldehyde-acetals which are the principal products first formed.
Abstract: A method of simultaneously purifying crude caprolactams obtained from the Beckmann rearrangement of cyclohexanone oxime in oleum and the gas-phase rearrangement of cyclohexanone oxime in the presence of catalysts. The improvement consists in that the crude caprolactam obtained from the catalytic gas-phase rearrangement is added to the acid rearrangement mixture derived from the Beckmann rearrangement in oleum and the mixture is maintained at temperatures of from 100.degree. to 200.degree. C with thorough mixing, whereupon it is neutralized and worked up. Advantageously, the content of lactam in the catalytic gas-phase rearrangement is from 5 to 30% of the content of lactam in the acid rearrangement mixture obtained from the Beckmann rearrangement.
Abstract: A dye of the formula ##STR1## wherein D is the radical of a diazo component, especially phenyl, phenylazophenyl, benzthiazolyl, benzisothiazolyl, thienyl, thiazolyl, thiadiazolyl and substituted derivatives thereof,R is hydrogen or alkyl of 1 to 7 carbon atoms,X is cyano or carbamoyl,A is a hydrocarbon radical, the twoA's together with the nitrogen form a saturated heterocyclic ring, andA.sup.1 is hydrogen or a hydrocarbon radical.The dyes are eminently suitable for coloring synthetic fibers, particularly polyesters, brilliant shades.
Abstract: An improved method of preparing amines by reaction of alcohols with ammonia or primary or secondary amines at elevated temperature and superatmospheric pressure in the presence of hydrogen and a hydrogenation catalyst containing cobalt, nickel and copper, the improvement comprising using a catalyst which contains (calculated on the metal content of the catalyst) from 70 to 95% by weight of a mixture of cobalt and nickel and from 5 to 30% by weight of copper, the ratio by weight of cobalt to nickel being from 4:1 to 1:4. The amines prepared in this way are suitable for the production of emulsifying agents, plant protection agents and vulcanization accelerators.
Abstract: Filaments or filament bundles, which are conveyed by a heated gas, are crimped by treating them in a preheat chamber and crimping them in an elongate chamber from which the heated gas medium issues through longitudinal slits. A stream of cold gas is made to impinge on the outside of the lower one-third of the elongate chamber without allowing significant amounts of this cold gas to enter the said chamber. The resulting filaments or filament bundles have very good dyeing characteristics.
Type:
Grant
Filed:
March 15, 1976
Date of Patent:
March 29, 1977
Assignee:
BASF Farben & Fasern Aktiengesellschaft
Inventors:
Wolfgang Bauer, Wolfgang Martin, Erwin Lehrer
Abstract: New and valuable 4-benzofuranyl esters having a good herbicidal action, herbicides containing these compounds as active ingredients, a process for controlling the growth of unwanted plants with these compounds, and a process for their manufacture.
Type:
Grant
Filed:
December 20, 1974
Date of Patent:
March 29, 1977
Assignee:
BASF Aktiengesellschaft
Inventors:
Adolf Fischer, deceased, Wolfgang Rohr, Christian Reitel
Abstract: Azo dyes containing sulfonic acid groups laked with barium and derived from an anilinesulfonic acid as diazo component and a .beta.-naphtholsulfonic acid as coupling component for example a dye of the formula ##STR1## The dyes are eminently suitable as pigments for coloring surface coating compositions, printing inks and particlarly resins.
Abstract: The production of .beta.-haloalkylaminosulfonyl halides by the reaction of an aziridine with a sulfuryl halide, and the new .beta.-haloalkylaminosulfonyl halides. The new compounds which can be prepared by the process of the invention are valuable starting materials for the manufacture of plant protection agents, dyes and pharmaceutical substances.
Abstract: Low-viscous, stable polymer dispersions are prepared by blending a hydroxy-containing finely divided solid polymer with a polyol having an equivalent weight between 500 and 10,000. The resulting dispersions are particularly useful in the preparation of polyurethanes having enhanced physical properties particularly load bearing or hardness, tensile strength and tear resistance.
Type:
Grant
Filed:
April 29, 1974
Date of Patent:
March 29, 1977
Assignee:
BASF Wyandotte Corporation
Inventors:
Gerhard G. Ramlow, Louis C. Pizzini, John T. Patton, Jr., John R. Murphy
Abstract: Self-extinguishing reinforced molding compositions based on aromatic polycarbonates and containing from 0.5 to 15% by weight, based on the weight of polycarbonate, of red phosphorus and a reinforcing agent such as glass fibers or glass spheres or a filler such as asbestos. The molding compositions are suitable for processing to shaped articles.
Abstract: New and valuable substituted fluorophosphazenes, pesticides containing these compounds, and a process for controlling pests with these compounds.
Type:
Grant
Filed:
July 1, 1974
Date of Patent:
March 22, 1977
Assignee:
BASF Aktiengesellschaft
Inventors:
Heinrich Adolphi, Gerd Wunsch, Volker Kiener