Abstract: Described is an electrolytic capacitor that includes: (a) a layer of an oxidizable metal; (b) a layer of an oxide of the oxidixable metal; (c) a solid electrolyte; and (d) a plurality of contacts. The solid electrolyte includes a polythiophene having recurring units represented by the following formulas (I-a) and/or (I-b), Also described are processes for producing electrolytic capacitors, and conductive layers that include such polythiophenes.
Abstract: High purity refractory metals, valve metals, refractory metal oxides, valve metal oxides, or alloys thereof suitable for a variety of electrical, optical and mill product/fabricated parts usages are produced from their respective oxides by metalothermic reduction of a solid or liquid form of such oxide using a reducing agent that establishes (after ignition) a highly exothermic reaction, the reaction preferably taking place in a continuously or step-wise moving oxide such as gravity fall with metal retrievable at the bottom and an oxide of the reducing agent being removable as a gas or in other convenient form and unreacted reducing agent derivatives being removable by leaching or like process.
Type:
Grant
Filed:
March 3, 2004
Date of Patent:
December 19, 2006
Assignee:
H.C. Starck Inc.
Inventors:
Leonid N. Shekhter, Terrance B. Tripp, Leonid L. Lanin, Anastasia M. Conlon, Howard V. Goldberg
Abstract: Process for the electrochemical decomposition of precursors in powder form by introducing a powder batch between two electrodes of an electrolysis cell, electrodes being designed to be liquid-permeable, and the electrolyte flowing through the powder batch perpendicularly to the electrode surfaces, and electrolysis cell suitable therefor, which is essentially characterized in that at least one electrode has a structure which consists of a supporting pierced plate (5), an electrode plate (3) provided with perforations, and a filter cloth (4) arranged between the supporting pierced plate (5) and the electrode plate (3), and in that the cathode (6) is shielded from the cell by means of a liquid-permeable separator (7).
Type:
Grant
Filed:
April 15, 2003
Date of Patent:
December 5, 2006
Assignee:
H.C. Starck GmbH
Inventors:
Armin Olbrich, Juliane Meese-Marktscheffel, Gerhard Gille, Viktor Stoller, Wolfgang Mathy
Abstract: The invention relates to a process for the production of electrolyte capacitors having a low equivalent series resistance and low residual current, and which comprise a solid electrolyte of conductive polymers and an outer layer comprising conductive polymers applied in the form of a dispersion. Electrolyte capacitors produced by this process and the use of such electrolyte capacitors are also provided.
Type:
Application
Filed:
April 10, 2006
Publication date:
October 26, 2006
Applicant:
H. C. Starck GmbH
Inventors:
Udo Merker, Klaus Wussow, Friedrich Jonas
Abstract: The invention relates to a method for producing wolfram carbides by gas-phase carburetion of wolfram powders and/or suitable wolfram precursor compounds in powder form at temperatures above 850° C. According to the method a CO2/CO mixture with a CO2 content greater than the Boudouard equilibrium content corresponding to the carburetion temperature is used as carburetion gas phase.
Type:
Grant
Filed:
November 3, 1999
Date of Patent:
October 10, 2006
Assignee:
H. C. Starck GmbH & Co. KG
Inventors:
Gerhard Gille, Benno Gries, Jörg Bredthauer
Abstract: Disclosed herein is a water-dispersible powder consisting essentially of polymers T comprising recurring thiophene units and at least one further polyanionic polymer P and process for preparing and using the same.
Type:
Grant
Filed:
November 20, 2001
Date of Patent:
October 10, 2006
Assignee:
H. C. Starck GmbH
Inventors:
Bernhard Wessling, Stephan Kirchmeyer, Dietrich Gehrmann
Abstract: The invention relates to a process for preparing compounds of the general formula (I) to novel compounds of this substance class and also to their use as important precursors or for preparing important precursors for ?-conjugated polymers.
Abstract: Process for preparing specific oxidants which in mixtures with precursors for preparing conductive polymers display a long processing time during the polymerization; oxidants obtainable by this process; mixtures comprising such specific (retarding) oxidants and the use of said oxidants for preparing solid electrolyte capacitors and conductive layers.
Type:
Application
Filed:
March 20, 2004
Publication date:
August 17, 2006
Applicant:
H.C. Starck GmbH
Inventors:
Udo Merker, Stephan Kirchmeyer, Klaus Wussow
Abstract: A process for producing dielectric layers with low dielectric constants by thermal treatment of a sol-gel product of a multifunctional carbosilane, corresponding layers, and their use in the production of electronic components, are described.
Type:
Grant
Filed:
December 13, 2002
Date of Patent:
August 15, 2006
Assignee:
H.C. Starck GmbH
Inventors:
Stephan Kirchmeyer, Detlef Gaiser, Harald Kraus, Udo Merker
Abstract: Process for the production of shaped articles of niobium or tantalum by electrochemical etching of a niobium or tantalum sheet covered by a structured photoresist mask in an aqueous solution containing hydrofluoric acid, the etching being effected under electrochemical conditions under which strong noise is superposed on the etching current and the etching solution contains a water-soluble polymer.
Abstract: The invention relates to compounds having a core-shell structure, to a process for preparing them and to their use as semiconductors in electronic components.
Abstract: Process for producing a valve metal powder by producing a precursor of desired morphology, converting the precursor into an oxide of the valve metal, stabilizing the structure of the oxide by heat treatment and reducing the stabilized oxide while retaining the morphology. Valve metal powders obtainable in this way, in particular comprising spherical agglomerates with a mean agglomerate size of 10–80 ?m, preferably 20–40 ?m, and use of these valve metal powders to produce solid electrolyte capacitors.
Abstract: A capacitor-grade wire made from powder metallurgy containing at least niobium and silicon, wherein the niobium is the highest weight percent metal present in the niobium wire. The wire having a controlled tensile strength at finish diameter exceeds the strength of capacitor-grade wire formed by ingot metallurgy. Also, the powder metallurgy wire hardness exceeds capacitor-grade wire formed from ingot metallurgy with electrical leakage meeting the specifications normally applied to capacitor grade tantalum, niobium or niobium-zirconium lead wire at sinter temperatures of about 1150° C. and above.
Abstract: The invention relates to a method for producing metal hydroxides or alkaline metal carbonates by anode dissolution of the corresponding metals and precipitation of the hydroxides or alkaline carbonates in an aqueous medium. The anode dissolution of the metal components is carried out in the anode compartment of a three-compartment electrolytic cell. An aqueous auxiliary salt solution is fed to an intermediate compartment that is disposed between the anode compartment and the cathode compartment and that is separated therefrom by a porous membrane. An at least not alkaline metal salt solution is continuously taken from the anode compartment while an alkaline auxiliary salt solution is continuously taken from the cathode compartment. The at least not alkaline metal salt solution and the alkaline auxiliary salt solution are combined outside the electrolytic cell for the purpose of precipitating metal hydroxides or alkaline metal carbonates.
Type:
Grant
Filed:
June 6, 2001
Date of Patent:
May 23, 2006
Assignee:
H.C. Starck GmbH
Inventors:
Armin Olbrich, Astrid Görge, Frank Schrumpf, Juliane Meese-Marktscheffel, Viktor Stoller, Gerhard Gille, Josef Schmoll, Michael Kruft, Dirk Naumann
Abstract: Disclosed herein are capacitors having an anode based on niobium and a barrier layer based on niobium pentoxide, at least the barrier layer having a content of vanadium and process for their preparation and use.
Type:
Grant
Filed:
June 8, 2001
Date of Patent:
January 31, 2006
Assignee:
H. C. Starck GmbH
Inventors:
Karlheinz Reichert, Christoph Schnitter
Abstract: The method for producing an aqueous dispersion containing a complex of poly(3,4-dialkoxythiophene) and a polyanion comprises: a process of polymerizing 3,4-dialkoxythiophene in the presence of a polyanion by using an oxidizing agent in an aqueous solvent, in which polystyrene-sulfonic acid having a specific molecular weight and a sulfonation degree or polystyrenesulfonic acid having another specific sulfonation degree is used as the polyanion, or in which pH of the reaction mixture during the reaction is set to a specific value.
Abstract: The invention relates to compounds containing optionally substituted 3,4-methylenedioxythiophene units (thieno[3,4-d]-1,3-dioxole units), the production thereof and their use as organic semi-conductors.
Type:
Application
Filed:
May 3, 2005
Publication date:
January 19, 2006
Applicant:
H. C. Starck GmbH
Inventors:
Lutz Brassat, Stephan Kirchmeyer, Knud Reuter
Abstract: Electrolytic capacitors having low equivalent series resistance and low leakage current are described. The electrolytic capacitors include a solid electrolyte layer of a conductive material in particular a conductive polymer, and an outer layer that includes binders, polymeric anions and conductive polymers (e.g., polythiophenes). Also described is a method of preparing electrolytic capacitors that involves forming the conductive polymer of the solid electrolyte layer in situ by means of chemical oxidative polymerization or electrochemical polymerization. Electronic circuits that include the electrolytic capacitors are also described.
Type:
Grant
Filed:
October 13, 2004
Date of Patent:
January 17, 2006
Assignee:
H.C. Starck GmbH
Inventors:
Udo Merker, Klaus Wussow, Friedrich Jonas
Abstract: Process for the production of electrolytic capacitors with low equivalent series resistance and low residual current, comprised of a solid electrolyte formed from conducting polymers and an outer layer containing conducting polymers and a binder, electrolytic capacitors produced by the process and their use.
Abstract: A mixed metal hydroxide with brucite structure is described, which contains nickel hydroxide as its main component and at least one trivalent metal selected from the group consisting of Co, Fe, Al, Ga, In, Sc, Y and La in an amount of from about 12 to about 30 atom % relative to the sum of the metal components including Ni. The invention also relates to a rechargeable battery containing a mixed metal hydroxide according to the invention as an electrochemically active material as well as a secondary batter containing the mixed metal hydroxide. The invention also relates to a process for producing a mixed metal hydroxide having a brucite structure.