Abstract: In various embodiments, tubular sputtering targets are produced by forming a tubular billet at least by pressing molybdenum powder in a mold and sintering the pressed molybdenum powder, working the tubular billet to form a worked billet, and heat treating the worked billet.
Type:
Grant
Filed:
December 30, 2011
Date of Patent:
April 23, 2013
Assignee:
H.C. Starck Inc.
Inventors:
Brad Lemon, Joseph Hirt, Timothy Welling, James G. Daily, III, David Meendering, Gary Rozak, Jerome O'Grady, Peter R. Jepson, Prabhat Kumar, Steven A. Miller, Richard Wu, David G. Schwarz
Abstract: The present invention relates to a stabilized monomer composition comprising at least 50 wt.-%, based on the total weight of the stabilized monomer composition, of a thiophene derivative monomer having the general formula (I) in which R1 and R2 stand, independently of one another, for hydrogen, for an optionally substituted C1-C20-alkyl group or C1-C20-oxyalkyl group, optionally interrupted by 1 to 5 oxygen atoms and/or sulfur atoms, or jointly for an optionally substituted C1-C20-dioxyalkylene group or C6-C20-dioxyarylene group, and 0.001 to 10 wt.-%, based on the total weight of the stabilized monomer composition, of a stabilizer. The present invention also relates to a method for the manufacture of a capacitor, a capacitor obtained by this method, the use of a stabilized monomer composition and to the use of a stabilizer.
Type:
Grant
Filed:
September 30, 2010
Date of Patent:
April 16, 2013
Assignee:
H.C. Starck Clevios GmbH
Inventors:
Knud Reuter, Klaus Wussow, Udo Merker, Andreas Elschner
Abstract: A dispersion comprising hard material particles and at least one organic binder and/or at least one plasticizer. The hard material particles comprise an inner core comprising a fused tungsten carbide and an outer shell comprising tungsten carbide.
Abstract: A process for digesting molybdenum oxide concentrates includes suspending a molybdenum-containing starting material in an aqueous solution so as to obtain a suspension. While stirring, an oxidizing agent and an alkali solution of at least one alkali metal are metered to the suspension so as to set a pH and produce a product having a molybdenum content of at least 98% of the molybdenum-containing starting material. The alkali metal is selected from the group consisting of Na, K and Li.
Type:
Grant
Filed:
November 4, 2008
Date of Patent:
February 26, 2013
Assignee:
H. C. Starck GmbH
Inventors:
Josef Schmoll, Brigitte Schimrosczyk, Gisbert Ebeling, Joerg Henze
Abstract: The invention relates to a pulverulent zirconium oxide containing metal oxides from the group consisting of scandium, yttrium, rare earths and mixtures thereof, processes for producing them and their use in fuel cells, in particular for the production of electrolyte substrates for ceramic fuel cells.
Type:
Grant
Filed:
July 24, 2007
Date of Patent:
February 26, 2013
Assignee:
H.C. Starck GmbH
Inventors:
Jörg Laube, Alfred Gügel, Ralph Otterstedt
Abstract: The invention is directed to ammonium paratungstate decahydrate containing at least 75% of crystals having a length of at least 200 ?m and having a ratio of length to width of less than 4.5:1.
Type:
Application
Filed:
May 29, 2012
Publication date:
January 31, 2013
Applicant:
H.C. Starck GmbH
Inventors:
Viktor Stoller, Michael Erb, Juliane Meese-Marktscheffel, Michael Lohse, Klaus-Jürgen Marschall, Frank Schrumpf
Abstract: A method for producing a workpiece comprising a layer of an additive-free silicon nitride includes providing a base body of the workpiece. A layer of a slip comprising a silicon powder is applied to an inside of the base body so as to obtain a coated base body. The coated base body is subjected to a reactive firing under nitrogen so as to convert the silicon powder to the additive-free silicon nitride.
Abstract: In various embodiments, low-oxygen metal powder is produced by heating a metal powder to a temperature at which an oxide of the metal powder becomes thermodynamically unstable and applying a pressure to volatilize the oxygen.
Type:
Application
Filed:
June 21, 2012
Publication date:
November 22, 2012
Applicant:
H. C. Starck Inc.
Inventors:
Leonid N. Shekhter, Steven a. Miller, Leah F. Haywiser, Rong-Chein R. Wu
Abstract: A sputtering target that includes at least two consolidated blocks, each block including an alloy including molybdenum in an amount greater than about 30 percent by weight and at least one additional alloying ingredient; and a joint between the at least two consolidated blocks, the joint being free of any microstructure due to an added bonding agent (e.g., powder, foil or otherwise), and being essentially free of any visible joint line the target that is greater than about 200 ?m width (e.g., less than about 50 ?m width). A process for making the target includes hot isostatically pressing, below a temperature of 1080° C., consolidated perform blocks that may be surface prepared (e.g., roughened to a predetermined roughness value) prior to pressing.
Abstract: A niobium suboxide powder comprising niobium suboxide particles having a bulk nitrogen content of between 500 to 20,000 ppm. The nitrogen is distributed in the bulk of the powder particles. The nitrogen at least partly is present in the form of at least one of Nb2N crystals or niobium oxynitride crystals.
Type:
Application
Filed:
May 9, 2012
Publication date:
September 27, 2012
Applicant:
H.C. STARCK GMBH
Inventors:
CHRISTOPH SCHNITTER, Holger Brumm, Christine Rawohl, Colin McCracken
Abstract: The invention relates to a method of recovering molybdenum from a molybdenum bearing sulfide material. The material is contacted with a leaching solution in the presence of iron compounds and mesophilic or thermophilic iron oxidizing microorganisms and subsequently, a leaching process is performed by controlling the molar ratio of dissolved ferric iron to dissolved molybdenum. Preferably, a high amount and molar excess of dissolved iron is used. The presence of high concentrations of ferric iron in bioleach solutions allows iron-oxidizing microorganisms to grow and oxidize iron and bioleach molybdenite at dissolved Mo concentrations as high as 4.4 g/L. Organic metabolites were not required for protecting cells from Mo toxicity. Maximum dissolution rates depend on reactor configuration, with agglomerated material simulating heap leaching of almost 1% Mo/day, but up to 10.2% Mo/day in suspension/stirred reactor configurations, with rate highly dependent on temperature within the range of 25° C. to 40° C.
Type:
Grant
Filed:
July 19, 2007
Date of Patent:
September 18, 2012
Assignee:
H.C. Starck GmbH
Inventors:
Wolfgang Kummer, Wilfried Gutknecht, James Gregory Olson, Thomas R. Clark
Abstract: Methods and apparatus for rolling metal sheet or plate are provided. The method comprises the step of feeding the metal plate or sheet into a rolling mill at an angle. The apparatus comprises a rolling mill having a tilted feed table, or an apron upon which a transfer table and tilted feed table can rest. Through-thickness gradient and shear texture can be improved using the methods and apparatus of the invention.
Abstract: Refractory metal powders are dehydrided in a device which includes a preheat chamber for retaining the metal powder fully heated in a hot zone to allow diffusion of hydrogen out of the powder. The powder is cooled in a cooling chamber for a residence time sufficiently short to prevent re-absorption of the hydrogen by the powder. The powder is consolidated by impact on a substrate at the exit of the cooling chamber to build a deposit in solid dense form on the substrate.
Type:
Grant
Filed:
September 9, 2008
Date of Patent:
August 21, 2012
Assignee:
H.C. Starck Inc.
Inventors:
Steven A. Miller, Mark Gaydos, Leonid N. Shekhter, Gokce Gulsoy
Abstract: The present invention is directed to a process for the preparation of a metal powder having a purity at least as high as the starting powder and having an oxygen content of 10 ppm or less comprising heating said metal powder containing oxygen in the form of an oxide, with the total oxygen content being from 50 to 3000 ppmf in an inert atmosphere at a pressure of from 1 bar to 10?7 to a temperature at which the oxide of the metal powder becomes thermodynamically unstable and removing the resulting oxygen via volatilization. The metal powder is preferably selected from the group consisting of tantalum, niobium, molybdenum, hafnium, zirconium, titanium, vanadium, rhenium and tungsten. The invention also relates to the powders produced by the process and the use of such powders in a cold spray process.
Type:
Grant
Filed:
October 3, 2007
Date of Patent:
July 24, 2012
Assignee:
H.C. Starck, Inc.
Inventors:
Leonid N. Shekhter, Steven A. Miller, Leah F. Haywiser, Rong-Chein Richard Wu
Abstract: The invention is directed to a method for the production of ammonium paratungstate tetrahydrate by thermal treatment of ammonium paratungstate decahydrate in an aqueous suspension. The ammonium paratungstate tetrahydrate can be produced with high purity and high yield. The production method may furthermore be carried out in a simple and energy-efficient manner.
Type:
Grant
Filed:
November 12, 2010
Date of Patent:
July 24, 2012
Assignee:
H.C. Starck GmbH
Inventors:
Viktor Stoller, Michael Erb, Juliane Meese-Marktscheffel, Michael Lohse, Wolfgang Mathy