Patents Assigned to Mitsui
  • Patent number: 5214738
    Abstract: A positive coefficient thin-film thermistor which is a thin film exhibiting a positive temperature coefficient (PTC) characteristic and having a thickness of 0.005 to 5 .mu.m and electrodes as constituting elements, and wherein the thin film is compound of a barium titanate based composition and the PTC characteristic is represented by a resistance variation in the transition of region of 1-10 orders of magnitude and a maximum resistance temperature variation rate of 1-20 orders/.degree.C.
    Type: Grant
    Filed: March 22, 1991
    Date of Patent: May 25, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Shigeaki Nakajima, Hiroshi Waki, Nobuhiro Fukuda, Hiroyuki Hyakutake, Masanaga Kikuzawa
  • Patent number: 5214125
    Abstract: A polyamide comprising a recurring unit of the formula (I), ##STR1## wherein each of R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 is independently a hydrogen atom, a halogen atom, a hydroxyl group, or a group of a carbon skeleton which may contain a hetero atom or a halogen atom, and A.sup.1 is a divalent hydrocarbon group; and a process for the production of a polyamide comprising the recurring unit of the formula (I), which comprises subjecting to a polycondensation reaction a dicarboxylic acid comprising an alicyclic dicarboxylic acid of the formula (a)-1, ##STR2## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 are as defined in the formula (I), and a diamine of the formula (b)-1,H.sub.2 N-A.sup.1 -NH.sub.2 (b)-1wherein A.sup.1 is as defined in the formula (I).
    Type: Grant
    Filed: September 19, 1991
    Date of Patent: May 25, 1993
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Makoto Mitani, Toshimasa Takata
  • Patent number: 5212247
    Abstract: Disclosed herein is a polypropylene resin composition of a high syndiotacticity comprising a substantial homopolymer of propylene, in which the ratio of the intensity of the peak attributable to the syndiotactic pentad bonds to the sum of the intensities of all the peaks attributable to the methyl groups in the spectrum of the methyl groups measured by .sup.13 C-NMR is 0.7 or more, and a copolymer of ethylene and propylene, and a preparation process thereof.
    Type: Grant
    Filed: June 6, 1990
    Date of Patent: May 18, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tadashi Asanuma, Tetsunosuke Shiomura, Nobutaka Uchikawa, Tutomu Iwatani, Katsumi Takeuchi
  • Patent number: 5212121
    Abstract: This invention is concerned with ceramic substrates for multilayer interconnection. This invention is also concerned with a raw batch for ceramic substrates which require a calcining temperature as low as 1,000.degree. C. or lower upon their production, are low in dielectric constant and have a coefficient of thermal expansion close to that of silicon and also with a process for the production of the substrates. This invention makes use of a raw batch which permits the use of a low resistance conductor such as Ag-Pd, Ag, Au or Cu and also the production of substrates by low-temperature calcination. The raw batch contains borosilicate silicate glass powder, and aluminum borate powder and at a weight ratio of 40-80 percent to 20-60 percent. The raw batch can additionally contain one or more specific oxides in particular proportions.
    Type: Grant
    Filed: June 17, 1992
    Date of Patent: May 18, 1993
    Assignee: Mitsui Mining Company, Limited
    Inventors: Takahisa Omata, Masaru Yanagimachi, Tosio Matsuuchi, Yoshinori Koyanagi
  • Patent number: 5211507
    Abstract: Disclosed is a method of making a huge elongated space of square or rectangular cross section under the ground. The outer shell of the huge elongated space is built in the form of integral arrangement of lateral shell-units having shielded passages therein. Such a huge underground space can be made without requiring any large-scale equipments on the ground. The huge outer shell can be made with accuracy and efficiency by skiving and jointing adjacent parallel lateral shell-units and by using selected lateral passage of shell-units to discharge the soil or mud removed in making the underground space.
    Type: Grant
    Filed: April 3, 1992
    Date of Patent: May 18, 1993
    Assignees: Toda Corporation, Mitsui Engineering & Shipbuilding Co. Ltd.
    Inventors: Ayao Siseki, Koji Tada, Toru Taniguchi, Masahiro Nakagawa, Yuji Tachikawa, Makoto Ukegawa
  • Patent number: 5210138
    Abstract: Disclosed is an ionomer composition comprising (A) an ionomer formed by neutralizing a carboxyl group of an ethylene/unsaturated carboxylic acid copolymer with an transition metal cation, (B) a polyamide and (C) a polyamide oligomer having a terminal group of the molecule chain blocked with a primary amino group. Since two polyamide components differing in the degree of polymerization are incorporated in this ionomer composition, excellent characteristics of the ionomer resin are related in the ionomer composition, and the mechanical strength at high temperatures, the formability and the transparency are prominently improved.
    Type: Grant
    Filed: February 12, 1991
    Date of Patent: May 11, 1993
    Assignee: Dupont-Mitsui Polychemicals Co., Ltd.
    Inventors: Yoshimasa Yamamoto, Eisaku Hirasawa
  • Patent number: 5210132
    Abstract: A process for preparing rubber modified high impact resins by dissolving a rubbery polymer in a monomer containing an aromatic vinyl monomer or a mixture of an aromatic vinyl monomer and a vinyl cyanide monomer followed by polymerizing the monomer, the two steps being carried out in at least two polymerization reactors with a particle disperser placed between the first and second reactors. High impact resins having excellent surface properties are obtained with a savings in a power consumption by controlling:(1) the relationship between the concentration of the polymerized monomer and the content of the rubbery polymer in the first reactor;(2) the relationship between the volume occupied by the polymerizing liquid in the first reactor and the inner volume of the particle disperser; and(3) the peripheral linear velocity of a shearing stirrer in the particle disperser.
    Type: Grant
    Filed: October 14, 1992
    Date of Patent: May 11, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsuyuki Matsubara, Norifumi Ito, Mune Iwamoto, Kazuo Sugazaki, Toshihiko Ando, Yasuo Furuta, Kouzo Ichikawa, Hitoshi Ozawa
  • Patent number: 5210065
    Abstract: A color-forming recording material containing:(a) an aromatic diamine,(b) an oxidizing agent such as a quinoid type electron-accepting compound, and(c) an acidic substance such as an aromatic carboxylic acid.
    Type: Grant
    Filed: October 2, 1991
    Date of Patent: May 11, 1993
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Michio Tanaka, Koji Kawai, Hiroyoshi Tarumoto, Hisaya Miki, Keiki Kishikawa, Masato Kawamura, Masatoshi Nitabaru, Terunori Fujita
  • Patent number: 5210066
    Abstract: A heat-sensitive recording material wherein a copolymer emulsion is employed, the copolymer emulsion being obtained by copolymerizing a monomer component which comprises (meth)acrylamide and an optional unsaturated monomer component copolymerizable with (meth)acrylamide in the presence of a seed emulsion serving as a nucleating particle. In the heat-sensitive recording material, the intermediate layer, the heat-sensitive recording layer or the protective layer comprises the copolymer emulsion. The recordinq layer and the resulting recorded images of such a heat-sensitive recording material have sufficient durability (such as water resistance, heat resistance, resistance to plasticizers and resistance to solvents) and the resistance to heat softening of the protective layer. The heat-sensitive recording material can be produced through easy process control and is excellent in color developing sensitivity.
    Type: Grant
    Filed: December 21, 1990
    Date of Patent: May 11, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Shinziro Sakurai, Akihiro Yamazaki, Takeshi Yanagihara, Makoto Nakano, Masaya Kusumoto
  • Patent number: 5210286
    Abstract: Herein disclosed are an .alpha.-(aminocyclohexyl)alkylamine represented by the following general formula (II): ##STR1##wherein R represents hydrogen atom or a lower alkyl group having 1 to 5 carbon atoms, provided that the amino group bonded to the cyclohexyl group may be in either of the 2-, 3- and 4-positions and a method for preparing it; an .alpha.-(isocyanatocyclohexyl)alkylisocyanate of Formula (II) wherein the amino groups are replaced with isocyanato groups and a method for preparing it; polyisocyanato-isocyanurate represented by the following general formula (IV): ##STR2##wherein R.sub.1, R.sub.2 and R.sub.
    Type: Grant
    Filed: April 10, 1992
    Date of Patent: May 11, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Ryuji Haseyama, Masatoshi Takagi, Kouzou Hayashi, Katsuyoshi Sasagawa, Kazuyuki Kuroda, Taisaku Kano, Kiyoshi Shikai
  • Patent number: 5210174
    Abstract: In a process for the preparation of polyimide by reacting a diamine compound with tetracarboxylic dianhydride in a phenol based solvent, an improved process for reacting the diamine compound with tetracarboxylic dianhydride in a solution by forming separate solutions of the tetracarboxylic dianhydride and the diamine compound and mixing the solutions and/or by dissolving tetracarboxylic dianhydride in the phenol-based solvent containing an organic base.
    Type: Grant
    Filed: November 14, 1990
    Date of Patent: May 11, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Shoji Tamai, Hideaki Oikawa, Masahiro Ohta, Akihiro Yamaguchi
  • Patent number: 5210221
    Abstract: Disclosed are a crystal of a fluoran compound having the formula (I) comprising exhibiting high peaks at diffraction angles (2.theta.) of 7.5.degree. and 17.0.degree. and relatively high peaks at diffraction angles (2.theta.) of 15.1.degree., 19.1.degree., 21.5.degree. and 25.3.degree. in an X-ray diffraction diagram by the Cu-K.alpha. beam and a crystal of a fluoran compound having the formula (II) comprising exhibiting high peaks at diffraction angles (2.theta.) of 5.5.degree. and 19.2.degree. in an X-ray diffraction diagram by the Cu-K.alpha. beam, which is useful as a color forming compound in recording materials.
    Type: Grant
    Filed: September 10, 1991
    Date of Patent: May 11, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masakatsu Nakatsuka, Atsuo Otsuji, Kiyoharu Hasegawa, Kazuyoshi Kikkawa, Akihiro Yamaguchi
  • Patent number: 5208209
    Abstract: Novel fluoran compounds represented by the formula (I): ##STR1## wherein R.sup.1 is an alkyl group having from 1 to 4 carbon atoms, preparation process of the fluoran compounds, and a heat-sensitive and a pressure-sensitive recording material comprising the fluoran compound, are disclosed.
    Type: Grant
    Filed: December 19, 1991
    Date of Patent: May 4, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Atsuo Otsuji, Masakatsu Nakatsuka, Kiyoharu Hasegawa, Masatoshi Takagi, Akihiro Yamaguchi
  • Patent number: 5208400
    Abstract: An improved process for producing allyl bromides by halogen exchange by reaction of an allyl chloride, with a metal bromide, wherein the reaction is conducted in an aprotic polar solvent. The allyl bromides obtained by the process of the invention are useful as intermediates for producing medicines, agricultural chemicals, dyes, and the like.
    Type: Grant
    Filed: January 2, 1992
    Date of Patent: May 4, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Ryuichi Mita, Yuji Fukunaga, Hironobu Horie, Mitsumasa Umemoto, Yasuhiro Matsuki
  • Patent number: 5206339
    Abstract: Polyimide which is obtained by polymerization and consists essentially of recurring structural units of the formula (I): ##STR1## wherein X is a single bond or a hexafluoroisopropylidene group, is processed to a form of pellet, followed by heat-treating to obtain crystallinity of 5% or more, and fed to an extruder to obtain articles.
    Type: Grant
    Filed: May 10, 1991
    Date of Patent: April 27, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masumi Saruwatari, Syoichi Tsuji, Yasuhiro Fujii
  • Patent number: 5206324
    Abstract: Copolymers of butene-1 and propylene, having specific physical properties and substantially a syndiotactic structure; and easily heat-sealable polypropylene resin compositions comprising 5-50 parts by weight of one of the copolymers and 95-50 parts by weight of a stereoregular crystalline propylene-ethylene copolymer or propylene-ethylene-C.sub.4-12 -.alpha.-olefin copolymer having specific compositions and melt flow index.
    Type: Grant
    Filed: October 3, 1990
    Date of Patent: April 27, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tadashi Asanuma, Tetsunosuke Shiomura, Tateyo Sasaki, Tutomu Iwatani, Nobutaka Uchikawa, Kouji Kitabayashi
  • Patent number: 5206438
    Abstract: Disclosed is an aromatic diamine compound represented by the formula (I) ##STR1## wherein R is H or CH.sub.3. Also disclosed is a bismaleimide compound represented by the formula (IV) ##STR2## wherein R is H or CH.sub.3, A resin forming composition comprising these compounds is also disclosed. The compounds are useful as raw materials for resins, and the resin forming composition and the resin can provide excellent heat resistance and impact resistance and low hygroscopicity.
    Type: Grant
    Filed: October 23, 1990
    Date of Patent: April 27, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Keizaburo Yamaguchi, Tatsuhiro Urakami, Yoshimitsu Tanabe, Midori Yamazaki, Shoji Tamai, Norimasa Yamaya, Masahiro Ohta, Akihiro Yamaguchi
  • Patent number: 5205894
    Abstract: Polyimide having repeating units of the following formula (I) and its polyamic acid precursor having repeating units of the following formula (II) are disclosed; ##STR1## (where Y is a radical selected from the group consisting of a bond, divalent hydrocarbon having 1 to 10 carbons, hexafluorinated isopropylidene, carbonyl, thio, sulfinyl, sulfonyl and oxide, and R is a tetra-valent radical selected from the group consisting of aliphatic radical having 2 and more carbons, cyclo-aliphatic radical, monoaromatic radical, condensed polyaromatic radical, and non-condensed polyaromatic radical wherein aromatic radicals are mutually connected with a bond or a crosslinking function).Typical examples of polyimide and polyamic acid include where Y is thio radical and R is ##STR2## Y is a bond and R is III or IV, and Y is isopropylidene radical and R is IV.The polymers can be prepared from corresponding diamine and tetracarboxylic acid dianhydride.
    Type: Grant
    Filed: June 17, 1991
    Date of Patent: April 27, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masahiro Ohta, Saburo Kawashima, Yoshiho Sonobe, Shoji Tamai, Hideaki Oikawa, Kouji Ohkoshi, Akihiro Yamaguchi
  • Patent number: 5206413
    Abstract: A method for preparing .alpha.-L-aspartyl-L-phenylalanine methyl ester (.alpha.-APM), substantially free from acid ion contamination, is disclosed which comprises the steps of contacting a solution of a mineral acid salt or an organic sulfonic acid salt of .alpha.-APM in an aqueous solvent with an anion exchange resin in free base form, separating the resin from the thus-produced solution of .alpha.-APM; and isolating the .alpha.-APM therefrom, preferably with regeneration and recycling the resin.
    Type: Grant
    Filed: June 14, 1990
    Date of Patent: April 27, 1993
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Masanobu Ajioka, Takeshi Oura, Chojiro Higuchi, Toshio Katoh, Akihiro Yamaguchi
  • Patent number: 5206430
    Abstract: There is here disclosed a method for obtaining high-purity cinnamic acid containing less metals from crude cinnamic acid containing a metallic catalyst which is a mixture prepared by the synthetic reaction of a cinnamic acid ester. A disclosed purifying means is the combination of alkali hydrolysis, active carbon adsorption, solvent extraction and precipitation with an acid.
    Type: Grant
    Filed: October 24, 1991
    Date of Patent: April 27, 1993
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Hiroyuki Itoh, Yoshitsugu Kono, Ryoichi Taneda, Usaji Takaki