Patents Assigned to Mitsui
  • Patent number: 5219968
    Abstract: A substantially syndiotactic propylene copolymer which comprises propylene and at least one cyclic diolefin having 6 to 25 carbon atoms or an alkadiene having 6 to 25 carbon atoms and at least one terminal double bond, in the .sup.13 C-NMR spectrum of the copolymer measured in a 1,2,4-trichlorobenzene solution, a peak intensity observed at about 20.2 ppm as the reference of tetramethylsilane at 0.0 ppm being 0.5 or more of the total peak intensity attributed to methyl groups of propylene; the content of the cyclic diolefin or the alkadiene being from 0.01 to 20 mol %; the intrinsic viscosity [.eta.] of the copolymer measured in a tetralin solution at 135.degree. C. being from 0.1 to 10 dl/g.This copolymer can contain an .alpha.-olefin other than propylene, particularly ethylene.
    Type: Grant
    Filed: November 12, 1991
    Date of Patent: June 15, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tetsunosuke Shiomura, Tadashi Asanuma, Masashiro Kouno, Norihide Inoue, Satoshi Fukushima, Yoshiho Sonobe, Kazumi Mizutani, Tutomu Iwatani, Ryuichi Sugimoto
  • Patent number: 5220088
    Abstract: A process for the dimerization of n-butene wherein a Ziegler catalyst system composed of a nickel compound and an organoalkylaluminum is added, as a third component, with an amine and/or a quaternary ammonium chloride. The amine can be a primary, secondary or tertiary amine. This process makes it possible to selectively prepare isooctene having a low degree of branching while maintaining high catalytic activity.
    Type: Grant
    Filed: November 22, 1991
    Date of Patent: June 15, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Kenji Fujiwara, Toshiyuki Fukushima, Masaru Takeshita, Nobukiyo Okawa, Noboru Takada, Akira Othu
  • Patent number: 5219984
    Abstract: According to the present invention, a process which comprises bringing polyethylene terephthalate having an intrinsic viscosity of at least 0.50 dl/g and a density of 1.38 g/cm.sup.3 or more into contact with water is provided.In the water-treated polyethylene terephthalate obtained in the present invention, amounts of oligomers and acetaldehyde formed at the time of molding said polyethylene terephthalate into molded articles are small, and the contamination of the mold therewith is difficult to occur and further the contents of said molded articles does not change in flavor and fragrance.
    Type: Grant
    Filed: February 18, 1992
    Date of Patent: June 15, 1993
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Shigemi Shiraki, Yasuhiro Tanaka, Masayuki Sakai
  • Patent number: 5220049
    Abstract: A method for preparing an unsaturated compound mainly comprising monoolefins, or a mixture of .alpha., .beta.-unsaturated nitriles and monoolefins comprises coming a mixed gas which comprises paraffins and oxygen, or paraffins, oxygen and ammonia in contact with a catalyst which comprises (1) an oxide of phosphorus and (2) at least one oxide selected from the group consisting of indium oxide and tin oxide or comprises, in addition to the foregoing catalytic components, (3) at least one oxide selected from the group consisting of vanadium oxide, tungsten oxide and molybdenum oxide. The method makes it possible to prepare monoolefins, or a mixture of .alpha., .beta.-unsaturated nitriles and monoolefins in high yield and high selectivity from cheap starting materials, parafins.
    Type: Grant
    Filed: November 17, 1992
    Date of Patent: June 15, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tadatoshi Honda, Kazuhiro Terada
  • Patent number: 5220038
    Abstract: Disclosed are novel fluoran compounds represented by the formula (I): ##STR1## wherein R.sub.1 and R.sub.2 are different groups selected from cyclohexyl, n-butyl and isobutyl, e.g., in the form of crystals characterized by a specific X-ray diffraction diagram; crystalline toluene adducts thereof; and recording materials containing these fluoran compounds.
    Type: Grant
    Filed: July 18, 1990
    Date of Patent: June 15, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masakatsu Nakatsuka, Atsuo Otsuji, Kiyoharu Hasegawa, Masatoshi Takagi, Akihiro Yamaguchi
  • Patent number: 5219614
    Abstract: The present invention provides a method capable of lining a multibranch piping with a coating material within the pot life of the coating material without leaving an area uncoated or having to apply excessive repeated coatings. Lining of a main pipe is performed by pouring the coating material into the main pipe from an end portion of the pipe, and the lining of branch pipes is effected by the feed of the coating material and air for each of the branch pipes. A completed time point of lining in each branch pipe is detected by any one of the following methods:(A) A method wherein the time required for lining a branch pipe is estimated in advance and upon lapse of the estimated time it is determined that the lining of the branch pipe was completed.
    Type: Grant
    Filed: April 22, 1992
    Date of Patent: June 15, 1993
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Masato Kawazoe, Takaharu Tomoyasu
  • Patent number: 5219738
    Abstract: By screening an animal cell transformant, which has been obtained by introducing into wild-type animal cells a wild-type DHFR gene and a structural gene which codes a desired useful substance, with a medium containing methotrexate (MTX) at a concentration of 50 .mu.M or lower, both genes can be amplified effectively within an MTX resistant strain and a stable amplified transformant can also be obtained. The screening may be repeated using an increasing concentration of MTX. It is also possible to obtain stably the desired foreign gene product in a high yield by using the thus-obtained amplified transformant.
    Type: Grant
    Filed: May 4, 1987
    Date of Patent: June 15, 1993
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Noboru Tomioka, Fumio Omae, Eriko Mine, Tomoko Ishii
  • Patent number: 5219868
    Abstract: Herein disclosed are novel imidazolidine derivatives of the formula (I) and intermediates of the formula (II) ##STR1## wherein each R represents a hydrogen atom, an alkyl group having from 1 to 6 carbon atoms, a halogen atom, an alkoxy group having from 1 to 6 carbon atoms, a methylenedioxy group, an alkylthio group having from 1 to 4 carbon atoms, a haloalkyl group having from 1 to 2 carbon atoms, a haloalkoxy group having from 1 to 4 carbon atoms, an alkylcarbonyl group having from 1 to 6 carbon atoms, an alkoxycarbonyl.group having from 1 to 6 carbon atoms, a hydroxy group, a cyano group, a nitro group, an alkylamino group having from 1 to 8 carbon atoms, a phenyl group, a phenoxy group, a benzyl group or a halopyridylmethyloxy group, and n is an integer of from 1 to 3, ##STR2## wherein R and n have, respectively, the same meanings as defined above. Processes for preparing the compounds of the formulas (I) and (II) are also described.
    Type: Grant
    Filed: December 4, 1991
    Date of Patent: June 15, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Kenji Kodaka, Katsutoshi Kinoshita, Michihiko Nakaya, Koichi Ebihara, Shirou Shiraishi, Eiichi Yamada, Satoshi Numata
  • Patent number: 5220090
    Abstract: A method for preparing an unsaturated compound mainly comprising monoolefins, or a mixture of .alpha., .beta.-unsaturated nitriles and monoolefins comprises coming a mixed gas which comprises paraffins and oxygen, or paraffins, oxygen and ammonia in contact with a catalyst which comprises (1) an oxide of phosphorus and (2) at least one oxide selected from the group consisting of indium oxide and tin oxide or comprises, in addition to the foregoing catalytic components, (3) at least one oxide selected from the group consisting of vanadium oxide, tungsten oxide and molybdenum oxide. The method makes it possible to prepare monoolefins, or a mixture of .alpha., .beta.-unsaturated nitriles and monoolefins in high yield and high selectivity from cheap starting materials, parafins.
    Type: Grant
    Filed: November 9, 1990
    Date of Patent: June 15, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tadatoshi Honda, Kazuhiro Terada
  • Patent number: 5220010
    Abstract: There is here disclosed a method for preparing an alkoxyphthalocyanine represented by the formula (1): ##STR1##
    Type: Grant
    Filed: December 24, 1991
    Date of Patent: June 15, 1993
    Assignees: Mitsui Toatsu Chemicals, Incorporated, Yamamoto Chemicals, Incorporated
    Inventors: Takahisa Oguchi, Kenichi Sugimoto, Shin Athara, Hisato Itoh, Mansuke Matsumoto, Toshihiro Masaoka, Masakazu Nakamura
  • Patent number: 5218071
    Abstract: In accordance with the present invention, there are provided ethylene copolymers composed of structural units (a) derived from ethylene and structural units (b) derived from .alpha.-olefin of 3.about.20 carbon atoms, said ethylene copolymers having[A] a density of 0.85.about.0.92 g/cm.sup.3,[B] an intrinsic viscosity [.eta.] as measured in decalin at 135.degree. C. of 0.1.about.10 dl/g,[C] a ratio (Mw/Mn) of a weight average molecular weight (Mw) to a number average molecular weight (Mn) as measured by GPC of 1.2.about.4, and[D] a ratio (MFR.sub.10 /MFR.sub.2) of MFR.sub.10 under a load of 10 kg to MFR.sub.2 under a load of 2.16 kg at 190.degree. C. of 8.about.50, and being narrow in molecular weight distribution and excellent in flowability.
    Type: Grant
    Filed: June 22, 1992
    Date of Patent: June 8, 1993
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Toshiyuki Tsutsui, Ken Yoshitsugu, Akinori Toyota
  • Patent number: 5218049
    Abstract: A sheet or a film composed of at least one cyclo-olefin polymer selected from the group consisting of ring-opened polymers derived from at least one cyclo-olefin of formula (I) ##STR1## wherein R.sup.1 to R.sup.12, independently from each other, represent a member selected from the class consisting of a hydrogen atom, halogen atoms and hydrocarbon groups; two of R.sup.9 to R.sup.12 may be linked to each other together with the carbon atoms to which they are bonded to form a monocyclic or polycyclic group which may contain a double bond; R.sup.9 and R.sup.10, or R.sup.11 and R.sup.12 may each form an alkylidene group together with the carbon atoms to which they are bonded; and n is 0 or a positive integer,ring-opened copolymers derived from the cyclo-olefins of formula (I), hydrogenation products of said polymer or copolymers and addition polymers of the cyclo-olefins of formula (I) with ethylene, said cyclo-olefin polymer having an intrinsic viscosity [.eta.], measured in decalin at 135.degree. C., of 0.
    Type: Grant
    Filed: February 20, 1990
    Date of Patent: June 8, 1993
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Yohzoh Yamamoto, Takasi Nakagawa
  • Patent number: 5217701
    Abstract: Disclosed is a process for producing carbon materials which comprises the steps of preparing a raw material composition by mixing a methylene type linkage-containing condensation product of an aromatic sulfonic acid or a salt thereof with a solvent, the condensation product having been formed by means of a linkage of the formula--(CH.sub.2).sub.n --T.sub.x --(CHR).sub.m -- (1)where T is a benzene or naphthalene ring, R is a hydrogen atom, an alkyl group of 1 to 4 carbon atoms, or a benzene ring, and each of n, m and x is 0 or 1, but n and m should not be zero at the same time; spinning or molding the raw material composition; and carbonizing the spun fiber or molded article. Preferably, the aforesaid linkage is --CH.sub.2 --.
    Type: Grant
    Filed: May 14, 1990
    Date of Patent: June 8, 1993
    Assignee: Mitsui Mining Company, Limited
    Inventors: Koji Sakata, Kouji Sakawaki
  • Patent number: 5215043
    Abstract: A steam generator for a steam bath for generating steam from hot water supplied thereto. The steam generator for a steam bath has a closed main part equipped with a hot-water supply port, an air inlet, a discharge port and a steam outlet. Hot water received from the hot-water supply port is distributed in the main part so as to contact with air coming through the air inlet,and the thus generated steam is discharged through the steam outlet. Warm water formed as a result of steam generation is discharged from the discharge port.
    Type: Grant
    Filed: October 13, 1992
    Date of Patent: June 1, 1993
    Assignee: Mitsui Mining Company, Ltd.
    Inventor: Hidemi Tsutsumi
  • Patent number: 5215671
    Abstract: The present invention is directed to a method for recovering 2-chloropropionic acid so that this compound can be separated in a high-purity form. According to the method, crude 2-chloropropionic acid is heat-treated in the presence of a metal compound at a temperature in the range of 130.degree.-180.degree. C. where dichloro derivatives are contained as impurities or at a temperature not exceeding 160.degree. C. where no dichloro derivatives are contained. The metal compound is then removed at 160.degree. C. or lower. Final purification is thereafter conducted to obtain 2-chloropropionic acid as a high-purity product.
    Type: Grant
    Filed: June 11, 1991
    Date of Patent: June 1, 1993
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Yuzo Ono, Thutomu Kajikuri, Shoji Kitado, Kenji Senoo
  • Patent number: 5216112
    Abstract: A phenolic resin can be obtained by a condensation reaction between a specific trifunctional aromatic compound and a phenolic compound. This resin can be reacted with a curing agent such as a hexamine to give cured articles having excellent heat resistance, electrical properties, wear resistance and chemical resistance, and the phenolic resin is also much more excellent in curing reactivity as compared with conventional techniques.
    Type: Grant
    Filed: August 15, 1991
    Date of Patent: June 1, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Shinji Ando, Yukio Fukui, Shigeru Iimuro
  • Patent number: 5216044
    Abstract: A synthetic resin emulsion whose polymer particles are solid core-shell particles in which form pores spontaneously upon drying is produced by the steps of preparing as core particles from 2 to 60 parts by weight of polymer (A) by emulsion polymerization of from 10 to 80 parts by weight of acrylate ester (a.sub.1) having an alkyl group of from 1 to 3 carbon atoms and from 90 to 20 parts by weight another of vinyl-type monomer (a.sub.2) copolymerizable therewith, forming a shell of a polymer (B) on the surface of the core particles of polymer (A) by emulsion polymerization in the presence thereof of from 98 to 40 parts by weight of vinyl-type monomer (b), different from polymer (a.sub.1) and successively hydrolyzing the core portion of the particles with an alkaline material. Organic pigments prepared from the synthetic resin emulsion can improve the hiding power, brightness, gloss and other properties of articles coated therewith.
    Type: Grant
    Filed: October 26, 1990
    Date of Patent: June 1, 1993
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Futoshi Hoshino, Makoto Nakano, Kousuke Someya, Junko Morita, Takeshi Yanagihara
  • Patent number: 5213166
    Abstract: A pile driving and pile removing method comprises the step of causing a water-in-oil type water swellable polymer particle emulsion to be present on the pile surface or in the vicinity thereof during driving or extraction. The presence of the emulsion reduces the frictional resistance between the pile and the ground, enabling smooth and easy driving and removing of the pile.
    Type: Grant
    Filed: February 10, 1992
    Date of Patent: May 25, 1993
    Assignee: Mitsui-Cyanamid, Ltd.
    Inventors: Naotaka Watanabe, Hiroshi Itoda, Akio Kitamura
  • Patent number: 5214659
    Abstract: Angles of inclination of the two wavelength selection elements arranged on an optical path of a laser beam source are varied to make a laser output variable. Light transmitting ranges of the two wavelength selection elements are coincided with each other so as to adjust the light wavelength bands, thereby the laser beam is narrowed without increasing its fineness.
    Type: Grant
    Filed: October 29, 1990
    Date of Patent: May 25, 1993
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Mitsugu Terada, Ken Ohmata, Kazuo Shimazaki, Yasuo Oeda, Yuichiro Terashi
  • Patent number: 5214034
    Abstract: Catechol derivatives which relate to the production of nerve growth factor in particular tissues of brain are disclosed.Methods for the synthesis, data on the physiological activity, and data on the toxicity of these derivatives as well as examples of preparation for their administration are also disclosed.The disclosed derivatives provide preventive and remedial effect for regressive disorders in the central nervous system including senile dementia of Alzheimer type.
    Type: Grant
    Filed: December 3, 1991
    Date of Patent: May 25, 1993
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Shigenobu Nakayama, Fumiaki Ikeda