Abstract: Using a method and installation for separating acid components, dust and tar from hot gases of gasification installations, an economical method using a corresponding installation is to be created, which enables acid compounds HF, HCl, H2S, dust and tar to be reliably separated in the highest possible temperature range. The aim is achieved in that the media flow leaving the gasification at above 700° C. is fed with additives to a desulfurization process and subsequently to a combined cyclone 9 having associated filter cartridges 17 in a common vessel 8, and the gas is withdrawn for further use downstream of the filter cartridges.
Abstract: With a device for feeding a fluid, such as a gas or a liquid, into a solid-conveying line, wherein the fluid is first passed into a ring space that surrounds the solid-conveying line, and from there into the solid-conveying line, conveying of coal in the form of dust or flue ash, for example, is to be undertaken in gasification systems, at elevated temperatures, at great output and great operational reliability. This is achieved in that the solid-conveying line is shorter, in the ring space for forming a ring gap, than the length of the ring space, wherein installations for producing a vortex flow of the fluid that is introduced are provided in the ring space.
Abstract: Device for burning coking gas in a coking chamber of a coke oven of the “non-recovery type” or “heat-recovery type”, a multiplicity of inlet openings for primary air being arranged in the roof of each oven chamber in such a way that the coking gas produced during the coking is brought into uniform contact with the desired quantity of primary air for the partial combustion of the coking gas, these inlet openings for primary air being combined above the oven for each chamber separately by an air feed system, the air feed systems of the individual oven chambers being connected to an air feed system common to many oven chambers, and a respective control member for varying the primary air quantity over the carbonizing time being provided between the common air feed system and the air feeds of the individual oven chambers. A slight, constant positive pressure can be applied to the common air feed system.
Abstract: A method of removing acid gases from a fluid flow, using an absorption agent comprising an aqueous solution of 2,2?-(ethylenedioxy)-bis-(ethylamine).
Abstract: A method for extracting flue gases from a coke oven chamber, wherein the flue gases that develop briefly during the process of discharging and charging the coke cake from and to the coke oven chamber are extracted by a vacuum generated in the headspace above the coke cake. The vacuum in the headspace above the coke oven chamber is generated via channels through the lateral walls of the coke oven chamber or in the coke cake. The vacuum is generated in the secondary heating chamber and, by way of example, can be extracted again from a vacuum supply tank which, for the time that the coke oven chamber doors are open, is connected to the secondary heating chamber by opening shut-off devices in the connecting line. The method avoids the undesirable emission of flue gases into the atmosphere. A device whereby the method can be carried out is also disclosed.
Abstract: The invention relates to a method for producing hydrogen and power from a synthesis gas that contains CO, H2 and H2S. The synthesis gas is separated into two partial streams, vapor is added to the first partial stream of synthesis gas, out a CO conversion is carried out at a temperature of 220° C. to 500° C., pure hydrogen is obtained from the converted synthesis gas in a pressure swing absorption device and a residual PSA gas is produced. The second partial stream of synthesis gas is fed to a power-generating gas turbine for combustion, H2S and optionally other sulfur-containing components are removed in one or more separators that are arranged in any position in the process, however, before entry into the gas turbine, the residual PSA gas is mixed with nitrogen, the gas mixture so obtained is compressed and the compressed gas mixture is admixed to the partial stream of synthesis gas that is fed to the power-generating gas turbine.
Abstract: A method for production of coke chamber-compatible coal briquettes. Horizontally feeding coal into a pressing mould formed from a plate having two parallel terminating walls, which are stationary with respect to the direction of movement of the plate, and a terminating stop wall disposed transversely to the direction of movement of the plate. The side of the pressing mould open to coal is closed by a stationary wall, and the plate is locked in the horizontal direction for the pressing operation. The coal is compacted by a tamping device, having a vertically acting force onto pressing mould to produce a coal briquette. After completion of the coal briquette, the plate is moved horizontally in the longitudinal direction so that the space in the pressing mould becoming free in the horizontal direction is used for producing the next coal briquette. A device for carrying out the method is also disclosed.
Abstract: The invention pertains to a method for operating a coke furnace arrangement, wherein the coke oven gas accumulated during the coking process is utilized as a working gas. According to the invention, a synthesis gas produced from fossil fuel, preferably coal, by means of a gasification process is supplied as fuel gas in order to provide at least part of the thermal energy required for the coking process.
Abstract: A method for compensating flue gas enthalpy losses of heat-recovery coke ovens, having a coke oven bank, connected to one or more boilers by one or more a flue gas channels. The operation of the coke oven chambers is periodically interrupted, during which time the coke cake is removed, and the individual coke oven chambers are kept hot during the interruption of the operation by an an externally fired additional burner providing hot flue gas. The resulting heat flow remains the same in comparison to the normal operation. In this way, the boilers, which are typically used to produce steam, can be operated economically.
Type:
Application
Filed:
September 29, 2010
Publication date:
August 23, 2012
Applicant:
THYSSENKRUPP UHDE GMBH
Inventors:
Ronald Kim, Rainer Worberg, Manfred Heyer, Hans-Joachim Reichelt
Abstract: A porously coated, densely sintered ceramic membrane, which can be produced from a green membrane and subsequent sintering. The membrane is coated with ceramic material, which contains noble metals, which can be produced by application and subsequent thermal treatment. The noble metals are contained at a concentration of 2.5 to 5 mass percent.
Type:
Application
Filed:
May 19, 2010
Publication date:
August 16, 2012
Applicants:
BORSIG PROCESS HEAT EXCHANGER GMBH, THYSSENKRUPP UHDE GMBH
Abstract: The invention relates to a method of removing aromatic hydrocarbons from coke-oven gas. The coke-oven gas is contacted with a wash liquid in a gas scrubber, and aromatic hydrocarbons are separated by absorption from the coke-oven gas. Subsequently the wash liquid enriched with aromatic hydrocarbons is heated, and the aromatic hydrocarbons are stripped from the wash liquid using water vapor. After cooling the wash liquid is finally returned to the gas scrubber. According to the invention biodiesel is used as the wash liquid.
Abstract: Collecting line for removing hot process gases conducted in process gas tubes from tubular reformers, wherein the collecting line has on the inside at least one insulation layer made of fire-resistant concrete or fire-resistant brick, and on the outside a wall made of a metallic outer tube, comprises a plurality of stubs via which the process gas tubes of the tubular furnace can be connected to the collecting line, wherein in the region of the stubs, the process gas tubes are at least in part conducted in guide tubes, and each gas outlet connected to the respective process gas tube projects into the collecting line, by means of which the process gas is introduced into the collecting line in correct functioning, and at least one gas outlet is constructed as a pipe bend.
Abstract: Process for the continuous treatment of soot water which arises during partial oxidation of liquid hydrocarbons containing heavy metals. The soot water is centrifuged at a pressure of up to 5 bar and a temperature of up to 150° C. in a pre-dewatering stage, without the addition of additives, to 10% solids content, a pasty sludge rich in heavy metals is obtained and a centrate low in heavy metals arises. The centrate at least to some extent, is fed back into the gasification process again as useable water.
Type:
Application
Filed:
July 14, 2010
Publication date:
August 2, 2012
Applicant:
ThyssenKrupp Uhde GmbH
Inventors:
Karl-Heinz Jass, Daniel Oryan, Andreas Alke, Sascha Wenzel
Abstract: A device for cooling the solid matter from a coal gasification. The device includes a container with a feed part, a cooling part and a venting part. Lines arranged transverse to the flow direction are located inside of the cooling part that are grouped in two kinds, the one carrying liquid and the other carrying gas. The liquid carrying lines are closed in the interior of the cooling part and are provided for the heat exchange. The gas carrying lines that are gas permeable into the interior of the cooling part in such a way that solid matter comprising primarily cooled slag, ash and flue dust is cooled and the remaining gas present in and between the solid matter particles is exchanged. A method for cooling down the solid matter and for removing the remaining gas from the particles is also disclosed.
Abstract: A process for the dehydrogenation of alkanes. In several reactors of the adiabatic, allothermal or isothermal type or combinations thereof a gaseous alkane-containing material stream is passed through a catalyst bed in continuous operating mode. The gas stream produced contains an alkene, hydrogen and a non-converted alkane. In order to achieve a constant product composition, at least one of the process parameters of temperature, pressure or steam/hydrocarbon ratio is recorded in the form of measured values at one or several points of at least one of the reactors, where at least one of the process parameters is selectively controlled and influenced such that the composition of the product gas at the outlet of one reactor remains constant throughout the operating period.
Type:
Application
Filed:
July 16, 2010
Publication date:
August 2, 2012
Applicant:
THYSSENKRUPP UHDE GMBH
Inventors:
Helmut Gehrke, Rolf Schwass, Max Heinritz-Adrian, Oliver Noll, Sascha Wenzel
Abstract: In the case of a gasification reactor for the production of crude gas, containing CO or H2, by gasification of ash-containing fuel with oxygen-containing gas, at temperatures above the melting temperature of the ash, wherein a reaction chamber formed by a membrane wall through which coolant flows, within a pressure container, is provided, with a narrowing transition channel into a gas cooling chamber, wherein spin-reducing, cooled bulkheads are provided in the transition channel, a solution is to be created, with which a strand formation of the outflowing ash can be achieved, for one thing, and, for another, a further slag drip edge that ensures optimal slag outflow is made available.
Type:
Application
Filed:
July 16, 2010
Publication date:
July 26, 2012
Applicant:
THYSSENKRUPP UHDE GMBH
Inventors:
Eberhard Kuske, Johannes Dostal, Reinald Schulze Eckel, Lothar Semrau
Abstract: Catalyst-coated support, method for producing the same, reactor comprising the same and use thereof. Supports having a catalytic coating comprising at least one porous and cavity-containing catalyst layer are described, cavities being irregular spaces having dimensions greater than 5 ?m in at least two dimensions or having cross-sectional areas of at least 10 ?m2. The catalytic coatings are distinguished by a high adhesive strength and can preferably be used in microreactors.
Type:
Grant
Filed:
June 9, 2011
Date of Patent:
July 24, 2012
Assignees:
Evonik Degussa GmbH, Uhde GmbH
Inventors:
Steffen Schirmeister, Karsten Bueker, Martin Schmitz-Niederau, Bernd Langanke, Andreas Geisselmann, Georg Markowz, Klaus Thomas Schwarz, Elias Johannes Klemm, Frank Becker, Reinhard Machnik
Abstract: In the case of a gasification reactor for the production of crude gas, containing CO or H2, by gasification of ash-containing fuel with oxygen-containing gas, at temperatures above the melting temperature of the ash, wherein a reaction chamber formed by a membrane wall through which coolant flows, within a pressure container, subsequently a transition region and a quench chamber are provided, with a slag/water bath following in the direction of gravity, a solution is to be created, with which the slag container, in particular, is given an economically advantageous configuration, while simultaneously multiplying the method of functioning.
Type:
Application
Filed:
July 16, 2010
Publication date:
July 5, 2012
Applicant:
THYSSENKRUPP UHDE GMBH
Inventors:
Eberhard Kuske, Johannes Dostal, Reinald Schulze Eckel, Lothar Semrau
Abstract: The invention relates to a method and an installation for producing sulfuric acid. First of all, a product gas flow (5) containing sulfur dioxide is produced. The product gas flow (5) is supplied to a reaction chamber (1). A catalyst (3) is located in the reaction chamber (1). In the presence of the catalyst sulfur dioxide reacts to form sulfur trioxide. In further parts of the installation the resulting sulfur trioxide is converted to sulfuric acid. According to the invention, an oxidizing gas flow (6) is supplied to the reaction chamber (1) alternately with the product gas flow (5).