Abstract: It is supposed to be possible to achieve an essentially uniform water film protecting the corresponding metal panels, in a gasification reactor for producing crude gas containing CO or H2, by gasification of ash-containing fuel with oxygen-containing gas, at temperatures above the melting temperature of the ash, wherein a reaction chamber formed by a membrane wall through which cooling medium flows, a transition area as well as a quench chamber with a slag collection container that follows in the direction of gravity are provided within a pressure container. This is achieved in that, in addition to a device (14, 15) forming a water film (16) in the quench chamber (11), at least a part of the cylinder forming the quench chamber wall (17) is designed with a double wall and with a coolant overflow (21) for additionally wetting (18) the inner surface of the quench chamber wall (17), and a tangential coolant supply (20) in the bottom area of the double walled cylinder (19) which is closed at the bottom.

Abstract: A cooling shield is to be made available, in particular within the pressure container, with conical regions for the exit of gas or slag, in a gasification reactor (1) for producing crude gas containing CO or H2, having a pressure container (2) and a reaction chamber (4) formed by a membrane wall (3) of cooling pipes, wherein an annular space is formed between the inner wall of the pressure container (2) and the membrane wall (3), wherein elements such as burners (17) or the like are provided, which elements horizontally pass through the pressure container wall in the membrane wall substantially on the same plane (18), wherein the suspension or connection between the cooling shield and pressure container (load removal) is optimized, while avoiding difference expansions. This is achieved in that, for removal of the load on the membrane wall (3), direct or indirect support takes place at the cooling inlet lines (5) or mixture outlet lines (14).

Abstract: A heat-resistant door device for closing a horizontal coke oven chamber is made of a refractory material, using a material containing silica or a material containing silica and aluminum oxides, in particular. The material has a low temperature expansion coefficient and it is thermally well insulating so that the door is not deformed and/or distorted during the coal carbonization process. The door device is built of a coke oven wall mainly located above the door and embracing the door as well as of a mobile door located underneath. Thereby less cold ambient air enters into the coke oven chamber and radiation losses are minimized. The door may be comprised of an ellipsoidal bulge by, which the coke can be better pushed into the coking chamber. The oven wall embracing the oven door can also be made of a refractory material containing silica or of a material containing silica and aluminum oxides.

Abstract: The invention relates to a method for simultaneously producing iron and a crude syngas containing CO and H2 by means of a blast furnace that is charged with iron ore and carbon-containing reducing agents. The amount of carbon-containing reducing agents fed to the blast furnace is greater than the amount of fuel required for producing the iron. Technically pure oxygen is fed into the blast furnace for the blast furnace process and for producing the crude syngas. In addition, CO2 and/or steam are fed to the blast furnace in order to control the ratio between CO and H2 in the crude syngas discharged from the blast furnace as top gas and/or moderate the temperature at which the oxygen is injected.

Abstract: Combined removal of both ammonia from an ammonia-containing waste gas and nitrogen oxides from a nitrogen oxide-containing waste gas in a combined ammonia/urea synthesis plant is accomplished by mixing the gases and employing one or both of selective non-catalytic reduction at a temperature of 850° C. to 1100° C. or selective catalytic reduction at a temperature of 150° C. to 550° C., in which the ammonia and the nitrogen oxides react with one another to give nitrogen and water, the ammonia-containing waste gas derived from a low-pressure and/or atmospheric absorber of the urea synthesis plant, and the nitrogen oxide-containing waste gas derived from a flue gas duct of a primary reformer of the ammonia synthesis plant, both the ammonia and the nitrogen oxides of the mixed waste gas flows being depleted simultaneously during the same process step.

Abstract: A process for the recovery of a pure aromatics-containing product is disclosed. This product is obtained by extractive distillation of a gasoline rich in aromatics, in which olefins, diolefins and polyolefins are separated, and this extractive distillation is followed by a hydrogenation of the recovered aromatics-rich, olefin-lean product stream, in which the alkylated aromatics, especially toluene and xylene, are dealkylated and the paraffinic dealkylation products further converted into methane so that a significant portion of hydrogen can be saved by carrying out the hydrogenation subsequent to the extractive distillation, as the aromatics mixture is then free of olefins and no hydrogen is required for an olefin hydrogenation, with extractive distillation and recovery of the extracting solvent taking place in one column. An apparatus for carrying out the process described is also disclosed.

Abstract: The invention relates to a fission reactor (1) for a Claus plant, comprising a fireproof lined boiler (9), which contains a combustion chamber (2) with an influx opening for a mixture of fuel gas, air and acid gas containing H2S, a catalyst chamber (10) with a catalyst bed and a chamber on the outflow side (11) comprising a gas outlet for a hot process gas that contains elemental sulphur. According to the invention, the boiler is configured as a horizontal cylindrical boiler, in which the combustion chamber (2), the catalyst chamber and the chamber on the outflow side (11) are located next to one another. The catalyst chamber is delimited on both sides in the flow direction by gas-permeable chequer bricks (14) and has a fill opening (15) on the shell side for introducing the catalyst bed.

Abstract: The invention relates to a process and a device for an as constant as possible supply of steam flow from an alkane dehydrogenation, the process being carried out by passing a hydrocarbonaceous gas through reaction tubes loadable with a catalyst, and the reaction tubes, which are sealed towards the outside, running through a heating chamber which is heatable by means of burners, and the catalyst being regenerated for the reaction in a cyclic operating mode, in which the reaction is endothermic and the regeneration of the catalyst non-endothermic, and the capacity of the main burners is reduced during the regeneration of the catalyst, in which auxiliary burners, which serve to keep up the production of hot flue gas during the regeneration of the catalyst, are installed at the inlet of the flue gas duct to produce additional hot flue gas which is used for generating an as constant as possible amount of steam from the waste heat of the process.

Abstract: With a device for influencing the flow, particularly in a horizontal connecting pipe (1) between a coal gasification reactor and a gas cooler/purifier, a solution is supposed to be created, whose task consists in being able to reduce or shut off the gas stream of a hot synthesis gas, if necessary, without being exposed to the great stresses caused by the corrosiveness and the high temperatures, while avoiding complicated valves or regulation devices. This is achieved by means of a Venturi constriction in the flow path of the gas in the pipe (1), as well as a flow cone (4a) positioned on a push rod (4) that is disposed centrally, whereby a connecting rod system (4b) that is guided to the outside is provided to move the push rod (4), whereby the connecting rod system (4b) that moves the push rod (4) is formed by a connecting rod arm guided in a dummy connector and a connecting rod arm guided out of the dummy connector (8) by way of a packed gland (6).

Abstract: A method for compacting coal in a manner suitable for coke oven chambers is disclosed. The coal is initially compressed by means of a suitable compressing device into one or more coal cakes, and the obtained coal cakes are divided into compacted products by a cutting device. The compacted products are stacked on top of the each other such that they can be loaded into a coke oven chamber for coking. The compacted products enable the coke oven chambers to be loaded in a precise and a coal loss-free manner. The coal compacted products are easy to store.

Abstract: A process for the generation of a syngas in an entrained-flow gasification process includes a solid, carbon-containing fuel which is introduced via burners into a reactor which also supplies the oxygen for gasification. The fuel is introduced on a burner level where the burners are arranged concentrically around the reaction chamber or in the head area. The syngas obtained is discharged from the reaction chamber via a discharge nozzle, so that the syngas is passed into a collecting chamber for cooling by addition of low-temperature gaseous, vaporous or liquid cooling agents. A quench chamber is provided between the reactor and the collecting chamber. Additional burner levels are in the quench chamber via which a fuel material of renewable fuels or biofuels is introduced into the syngas, so that the heat enthalpy of the syngas can be utilized for the endothermic gasification reaction of the biological raw material.

Abstract: The product gas from a dehydrogenation reaction is treated by a downstream gas scrub followed by depressurization in a high-pressure flash vessel equipped with mass transfer elements, wherein a fuel gas flows upwardly through the mass transfer elements in the high-pressure flash vessel countercurrent to depressurized solvent so that absorbed hydrocarbons are taken up by the fuel gas. The fuel gas is the heating gas for heating the dehydrogenation reactor and is, for example, natural gas. To increase efficiency, the hydrocarbon stream which has been separated from the acidic gas can be recirculated to the process gas path upstream of the gas scrub.

Abstract: Supports having a catalytic coating comprising at least one porous and cavity-containing catalyst layer are described, cavities being irregular spaces having dimensions greater than 5 ?m in at least two dimensions or having cross-sectional areas of at least 10 ?m2. The catalytic coatings are distinguished by a high adhesive strength and can preferably be used in microreactors.

Abstract: Improvement in carbonization in a carbonization furnace and simultaneous reduction in NOx emissions is achieved by recirculation of waste gas from a coking oven back to the oven chamber, the downcomers, or the sole channel system.

Abstract: Combined removal of both ammonia from an ammonia-containing waste gas and nitrogen oxides from a nitrogen oxide-containing waste gas in a combined ammonia/urea synthesis plant is accomplished by mixing the gases and employing one or both of selective non-catalytic reduction at a temperature of 850° C. to 1100° C. or selective catalytic reduction at a temperature of 150° C. to 550° C., in which the ammonia and the nitrogen oxides react with one another to give nitrogen and water, the ammonia-containing waste gas derived from a low-pressure and/or atmospheric absorber of the urea synthesis plant, and the nitrogen oxide-containing waste gas derived from a flue gas duct of a primary reformer of the ammonia synthesis plant, both the ammonia and the nitrogen oxides of the mixed waste gas flows being depleted simultaneously during the same process step.

Abstract: Coal compacts which are suitable for coking in coke oven chambers are prepared by pressing and compacting coal in a pressing device having a design which shapes the surface of the coal compacts to provide higher surface area. Already compacted coal blocks can be pressed to generate the surface shape. The resulting coal compacts exhibit significantly improved properties during the coking process, resulting in improved gas and heat exchange. A device for compacting coal preferably contains a plate provided with shaping elements on the pressing surface.

Abstract: Dosed proportioning and cutoff of combustion air into the primary heating space of a horizontal coke oven is provided by apertures in the ceiling of the coke oven chamber, the apertures covered with a withdrawable cover device which controls the amount of air admitted, manually or in an automatic mode. By way of this device, ventilation of a coke oven chamber with primary air can be so controlled that primary air is introduced in an exactly dosed manner and, depending on its place of installation, exactly distributed into the primary heating space of a coke oven chamber.

Abstract: With a device for removal of fine-grained or dust-like solids from a container that is to be pressurized or is pressurized, whereby the container is equipped with a double-walled discharge cone or funnel, a solution is supposed to be created with which the use of porous materials, such as sintered metals or the like, in particular, is avoided, while making available good conveyance properties in the transfer funnel, without restricting the grain sizes of the material, in each instance, whereby even particle-charged gas can be used for conveyance. This is achieved in that the gas exit openings are larger than the largest particles of the solid to be removed, and that the gas exit openings (4) are provided with a pipe connector or gas feed channel (4a) that projects into the interior of the ring chamber (6) and has at least one angle with an imaginary horizontal plane, and that the gas feed channel (4a) is part of a retention device (12) for preventing solid from trickling into the ring chamber (6).

Abstract: A catalyst for the dehydrogenation of alkanes or alkyl substituents of hydrocarbons, is a shaped body having at least one oxide from the elements of the main or secondary group II to IV of the periodic table or of a mixed oxide thereof serving as base material of the shaped body. The catalyst further contains an additional constituent which is an oxide of an element of the main group IV of the periodic table, added during the shaping process. A platinum compound and a compound of an element of the main group IV of the periodic table is used as a surface constituent of the catalyst. The invention further relates to the production of the catalyst and to a method for the dehydrogenation of alkanes using the catalyst.

Abstract: A device is disclosed for removing slag from a coal gasification reactor and to a slag water bath enclosed by the reaction vessel. The slag is discharged by means of a lock-type transfer vessel arranged downstream of the slag bath. The lock-type transfer vessel comprises one upper and one lower cylindrical section, the upper cylindrical section having a diameter larger than that of the lower cylindrical section and both sections being connected with each other via a tapered section which preferably is conical and the angle of the cone being similar to that of the angle of repose of the slag. Also disclosed is a process for removing slag from a coal gasification reactor and a slag water bath housed by the reaction vessel. The device permits a discharge of slag in a lock-type transfer vessel and precludes formation of slag incrustations in the lock-type transfer vessel.