Abstract: With a method and a system for interruption-free fuel supply to a gasification system for the production of crude synthesis gas, whereby the fuel is passed from a fuel reservoir to a grinding/drying system, subsequently the resulting fuel dust is passed to a fuel storage container, from there to a dust feed container, and finally, to the gasifier, by way of transport means, the system availability is supposed to be increased, and, at the same time, the storage capacities are supposed to be minimized, in order to thereby particularly achieve a cost reduction. This is achieved in that the fuel in the form of dust is passed to the storage container from at least two grinding/drying systems, by way of transport means, whereby at least one of the transport means, as a dust transport device, is acted on by at least two grinding/drying systems.

Abstract: A device for directed introduction of primary combustion air into the primary heating space of a coke oven chamber is shown. Primary air is admitted through entry ports in the top of a coke oven chamber or in the frontal coke oven chamber walls above the coke oven chamber door or in the coke oven chamber door or in several or all of the mentioned positions These entry ports have inserts that are equipped with oven-inwardly directed spouts, with the spouts having an opening-outwardly directed angle through which primary air is conducted at a chamfered angle onto the coke cake so that the primary air from the opening ports in the coke oven chamber top streams to the coke oven at an angle of less than 90° and primary air from the opening ports in the coke oven chamber wall above the coke oven chamber door or in the coke oven chamber door streams to the coke oven at an angle of greater than 0°. Also shown is a method for a directed introduction of primary air with the described device.

Abstract: In the case of a device for gasification of carbonaceous fuels, having a discharge for slags into a slag bath, a solution is supposed to be created with which the gasifier discharge opening is reliably kept at a temperature that guarantees that the slag will flow out. This is achieved in that the gasifier discharge opening (6) is equipped with a ceramic drip edge (7) that can be electrically heated.

Abstract: With a method and a device for igniting and operating burners when gasifying a carbon-containing fuel using at least two gasification burners, start of the pressure gasification with short start times is made possible, at high pressures, without prior inertization of the gas space, while avoiding continuous fuel gas consumption in the pilot burner or ignition burner and also protecting stationary ignition burners against contamination by configuring one gasification burner as a start-up burner, which is ignited by at least one pilot burner using an electrical ignition device. A combustible gas mixture including a fuel gas and oxygen-containing gas is ignited by the pilot burner, in the start-up burner. After ignition of the start-up burner, at least one further gasification burner is ignited by this burner. The start-up burner is operated further as one of the gasification burners of the carbon-containing fuel via a change in medium.

Abstract: An apparatus for the degassing of a dust from a synthesis gas produced by a gasification process, is disclosed. The apparatus comprises a main dust separator, a multi-purpose vessel, fluid for degassing and cooling and a storage facility for dust. The synthesis gas produced is conducted via a connecting pipe to a main dust separator, from which a de-dusted raw synthesis gas stream and a dust-like solid which also contains raw synthesis gas in the voids between the dust particles can be removed. The dust-like solid is directed into a multi-purpose vessel equipped with devices for reducing the pressure level so that a tail gas is obtained and a solid containing lower gas quantities in the void fraction remains. There is a device for transporting a solid into a gas exchange apparatus, the latter comprising a gas exchange tank, a dust separator and a feed device for exchange gas. It is possible to reduce the gas exchange tank to atmospheric pressure.

Abstract: With a method and a system for treatment of a hot crude gas generated by an entrained flow gasification system, removal of the compounds that contain sulfur and carbon is supposed to be undertaken in such a manner that hot gas is made available for further use. This is achieved in that a desulfurization (7) follows the gasifier (2), in series, in the flow path of the hot gas, followed by a solid separation (8, 9), whereby behind the solid separation (8, 9), a partial stream (13) of the gas is provided downstream by way of a water quench (14), a Venturi scrubber (15), a crude gas cooler (16), as well as an H2O separation (17) and a compressor (18), the flow path (19) of which is passed back, cooled, into the circuit, behind the gasification (2) and ahead of the desulfurization system.

Abstract: With a method for utilization of the reaction heat that occurs in the production of 1,2-dichloroethane from ethylene, by reaction with oxygen and hydrochloride (oxychlorination), in a fluidized bed reactor, with dissipation of this reaction heat through cooling pipe bundles situated within the reactor, positioned in the fluidized bed, utilization of the heat is supposed to be improved, while simultaneously reducing the size of the corresponding system elements. This is achieved in that part of the reaction heat is dissipated by heating boiler feed water, whereby the heated boiler feed water is used to heat heat sinks in the production process.

Abstract: Supports having a catalytic coating comprising at least one porous and cavity-containing catalyst layer are described, cavities being irregular spaces having dimensions greater than 5 ?m in at least two dimensions or having cross-sectional areas of at least 10 ?m2. The catalytic coatings are distinguished by a high adhesive strength and can preferably be used in microreactors.

Abstract: A process for the discharge of slag and ash from a gasification reactor is disclosed. These solids are directed from the gasification reactor into a water bath housed with the gasification reactor in a pressure vessel. There are at least two lock hoppers underneath the water bath which are fed with a stream of water/solids via a pipe and a flow divider element, it being possible to supply the lock hoppers individually and in a controlled manner with a stream of water/solids via shut-off devices. The filling is performed in a manner that encourages the sett-ling process by withdrawing a stream of liquid from the lock hopper being filled, the filling time being controlled so as to prevent the solids settling above the valves and lock hoppers. Also disclosed is an apparatus with at least two lock hoppers underneath the water bath of a gasification reactor, there being, in an advantageous embodiment, a flow divider element and shut-off devices between the water bath and the lock hoppers.

Abstract: With a system for synthesis gas production, having a reactor as well as a gas cooler/purifier connected with it in terms of flow, a solution is supposed to be created, with which the most compact possible connection between reactor, on the one hand, and the gas cooler or purifier, on the other hand, is made possible, whereby heat expansions that occur due to different temperatures are absorbed. This is accomplished in that the connection between reactor (1) and gas cooler/purifier (7) is formed by a horizontal connection piece (5) having a throttle element (6) configured as a Venturi element.

Abstract: With a method for discharging slag from a water bath of a reactor for synthesis gas production, whereby the slag is brought to a lower pressure level by means of a transfer container, a solution is supposed to be created, with which the components connected with transferring the slag out are subject to a low temperature, whereby immediate slag transfer without water exchange is supposed to be made possible, with a minimal required cooling power. This is accomplished in that a cooling water stream is passed to the slag stream in the outlet region of the slag from the water bath of the gas generator or the pressurized container that surrounds it, in a region having a greater cross-section than the cross-section of the entry connector of another system part, such as, for example, the transfer container, in such a manner that temperature stratification in the outlet region is made possible.

Abstract: The invention relates to a material which is suited as a carrier for catalysts in the dehydrogenation of alkanes and in the oxidative dehydrogenation of alkanes and which is made of an oxide ceramic foam and may contain combinations of the substances aluminium oxide, calcium oxide, silicon dioxide, tin oxide, zirconium dioxide, calcium aluminate, zinc aluminate, silicon carbide, and which is impregnated with one or several suitable catalytically active materials, by which the flow resistance of the catalyst decreases to a considerable degree and the accessibility of the catalytically active material improves significantly and the thermal and mechanical stability of the material increases. The invention also relates to a process for the manufacture of the material and a process for the dehydrogenation of alkanes by using the material according to the invention.

Abstract: The invention relates to a falling film evaporator, which is fitted with a liquid distributor which is divided into segments, such that it is possible to charge only a limited number of evaporator tubes with liquid and the evaporator can be operated in an optimum manner even with a partial load. The invention also relates to a method for operating said falling film evaporator, the aim of which is to transfer heat, which is released when a gas-vapor mixture is condensed, to a liquid which is to be evaporated at least partially. It would be useful to use said falling film evaporator thus fitted in heat recuperation systems such as those used in the production of 1,2 dichloroethane.

Abstract: With a slag runner on burners or burner niches for protection against dripping slag, which occurs during the gasification of fine-particle fuels that contain ash, within a gasifier, reliable protection of the burner exits or the burner niches to prevent them from becoming clogged with slag is supposed to be made available. This is achieved in that the slag runner (8) is formed by a plurality of pipe elbows (9) through which cooling medium flows, which elbows, in the installed position, form a runner surface that faces into the interior of the gasifier, stands at a slant relative to the gasifier wall (1), and shields the burner (2) or the burner niche (7) at the upper region, in the direction of gravity, which surface configures an essentially acute angle (?) relative to the burner wall (1).

Abstract: An axial thin-film reactor for carrying out catalytic reactions in the gas phase, comprising a cylindrical pressure casing, a device for letting in a gaseous reactant stream, a device for letting out a gaseous product stream, a device for receiving a catalyst bed arranged vertically in the reaction chamber and isolated from the reactor wall at the sides and at the ends so as to produce two separate chambers for the gaseous reactant stream and the gaseous product stream that are sealed with respect to one another and have two gas-permeable bounding walls arranged plane-parallel to one another. The device is designed in such a way that it has a height-to-thickness ratio greater than 1 and the catalyst bed has a height-to-thickness ratio greater than 1.

Abstract: A process for the production, treatment and combustion of synthesis gas for the purpose of generating electric power is disclosed. The synthesis gas is produced from a solid, carbon-containing fuel with the aid of an oxygen-containing gas and treated by a slag-separating device and a device separating alkalis. Subsequently, the synthesis gas produced is fed to an expansion turbine where the pressure energy is used for generating power. On account of the treatment and separation of alkalis the expansion turbine is protected from corrosion and mechanical impact. The expanded synthesis gas is then burnt under pressure and the combustion is used in a combined-cycle process using a gas turbine, steam generator and steam turbine for generating power. The process thus has an increased efficiency. Apparatus for use of the process is also described.

Abstract: A process for utilizing synthesis gas heat for the generation of supercritical steam in a low energy ammonia or methanol plant is disclosed. The process involves a reforming or partial oxidation stage, at least one supercritical steam generator having a shell side and a tube side, at least one superheater, at least one back pressure turbine, at least one extraction and condensing turbine, and at least one boiler feedwater pump. The synthesized synthesis gas is sent to the shell side of the supercritical steam generator, and the supercritical steam generator is fed with pressurized feedwater. The feedwater flow is adjusted to maintain the steam temperature at the exit of the supercritical steam generator in the range of 375-500° C. The supercritical steam is generated in the supercritical steam generator at a pressure of 225-450 bar, the supercritical steam is further heated in a superheater to a temperature of 500-750° C.

Abstract: With a method for cooling units subjected to stress at high temperatures, in cooled reactors for gasification of fuels that contain carbon, using gasification media that contain oxygen, whereby the reactor walls are cooled by way of a coolant circuit, penetration of substances from the reactor into the cooling circuit in the event of possible leaks is supposed to be reliably prevented. This is achieved in that the units to be cooled, such as, for example, gasification burners, burner muffles, or the like, are equipped with an independent cooling circuit, whereby this cooling circuit is directly connected with the main cooling circuit.

Abstract: A process for removing silicon compounds from aqueous NaCl brine includes, first, adjusting a weak brine to a pH value of less than 3 with hydrochloric acid. Iron(III) chloride or other trivalent iron ions are added to the acidified weak brine, the obtained weak brine is then continuously fed to a stirred dissolution vessel which contains undissolved salt in addition to brine. Fresh salt is charged batchwise and intermittently to the dissolution vessel to produce strong brine. The obtained strong brine is fed to a stirred buffer vessel, the pH value in this buffer vessel being maintained at a level ranging from 5 to 8. A strong-brine flow is continuously withdrawn from the buffer vessel and filtered, and the filtrate containing the added iron and silicon is discharged.

Abstract: A process is described for purifying synthesis gas by means of a pressure swing adsorption unit which is desorbed by a vacuum produced by a so-called ejector, which is driven by steam generated by a heat exchanger which uses the heat in the flue gas duct or in the useful-gas duct for the generation of steam. The pressure swing adsorption unit is operated advantageously in cyclic turns of adsorption under excess pressure, depressurization desorption and vacuum desorption and the gas desorbed by the ejector being cooled in a cooler so that the contained steam can be condensed and discharged or is advantageously returned to the feed gas for the synthesis gas production. The foreign gas desorbed by the pressure swing adsorption unit, which contains at least partly not yet consumed fuel gas, is recycled to the fuel gas. In an advantageous embodiment, the vacuum from the ejector is stored in an intermediate tank and applied to the pressure swing adsorption unit according to the vacuum desorption cycle.