Abstract: Combined removal of both ammonia from an ammonia-containing waste gas and nitrogen oxides from a nitrogen oxide-containing waste gas in a combined ammonia/urea synthesis plant is accomplished by mixing the gases and employing one or both of selective non-catalytic reduction at a temperature of 850° C. to 1100° C. or selective catalytic reduction at a temperature of 150° C. to 550° C., in which the ammonia and the nitrogen oxides react with one another to give nitrogen and water, the ammonia-containing waste gas derived from a low-pressure and/or atmospheric absorber of the urea synthesis plant, and the nitrogen oxide-containing waste gas derived from a flue gas duct of a primary reformer of the ammonia synthesis plant, both the ammonia and the nitrogen oxides of the mixed waste gas flows being depleted simultaneously during the same process step.

Abstract: Dosed proportioning and cutoff of combustion air into the primary heating space of a horizontal coke oven is provided by apertures in the ceiling of the coke oven chamber, the apertures covered with a withdrawable cover device which controls the amount of air admitted, manually or in an automatic mode. By way of this device, ventilation of a coke oven chamber with primary air can be so controlled that primary air is introduced in an exactly dosed manner and, depending on its place of installation, exactly distributed into the primary heating space of a coke oven chamber.

Abstract: Coal compacts which are suitable for coking in coke oven chambers are prepared by pressing and compacting coal in a pressing device having a design which shapes the surface of the coal compacts to provide higher surface area. Already compacted coal blocks can be pressed to generate the surface shape. The resulting coal compacts exhibit significantly improved properties during the coking process, resulting in improved gas and heat exchange. A device for compacting coal preferably contains a plate provided with shaping elements on the pressing surface.

Abstract: A catalyst for the dehydrogenation of alkanes or alkyl substituents of hydrocarbons, is a shaped body having at least one oxide from the elements of the main or secondary group II to IV of the periodic table or of a mixed oxide thereof serving as base material of the shaped body. The catalyst further contains an additional constituent which is an oxide of an element of the main group IV of the periodic table, added during the shaping process. A platinum compound and a compound of an element of the main group IV of the periodic table is used as a surface constituent of the catalyst. The invention further relates to the production of the catalyst and to a method for the dehydrogenation of alkanes using the catalyst.

Abstract: With a device for removal of fine-grained or dust-like solids from a container that is to be pressurized or is pressurized, whereby the container is equipped with a double-walled discharge cone or funnel, a solution is supposed to be created with which the use of porous materials, such as sintered metals or the like, in particular, is avoided, while making available good conveyance properties in the transfer funnel, without restricting the grain sizes of the material, in each instance, whereby even particle-charged gas can be used for conveyance. This is achieved in that the gas exit openings are larger than the largest particles of the solid to be removed, and that the gas exit openings (4) are provided with a pipe connector or gas feed channel (4a) that projects into the interior of the ring chamber (6) and has at least one angle with an imaginary horizontal plane, and that the gas feed channel (4a) is part of a retention device (12) for preventing solid from trickling into the ring chamber (6).

Abstract: A device is disclosed for removing slag from a coal gasification reactor and to a slag water bath enclosed by the reaction vessel. The slag is discharged by means of a lock-type transfer vessel arranged downstream of the slag bath. The lock-type transfer vessel comprises one upper and one lower cylindrical section, the upper cylindrical section having a diameter larger than that of the lower cylindrical section and both sections being connected with each other via a tapered section which preferably is conical and the angle of the cone being similar to that of the angle of repose of the slag. Also disclosed is a process for removing slag from a coal gasification reactor and a slag water bath housed by the reaction vessel. The device permits a discharge of slag in a lock-type transfer vessel and precludes formation of slag incrustations in the lock-type transfer vessel.

Abstract: Process for heat utilization in steam reforming, having a high-temperature conversion unit, a first heat exchanger, boiler feed water preheater, product condensate heat exchanger, and low-pressure evaporator, a cooling section, in which the process gas is further cooled and a condensate stream is generated and the resultant process gas is passed through at least one unit for further processing. Wherein a first part of the boiler feed water stream is passed into the low-pressure evaporator, and the low-pressure steam generated is divided and a first substream of the low-pressure steam is conducted into the water treatment unit for heat transfer and a second substream of the low-pressure steam is passed to at least one consumer. A second part of the boiler feed water stream is passed via a heat exchanger and one or more boiler feed water preheaters and finally passed for steam generation.

Abstract: A method and a system for uniformization and regulation of the solid fuels pneumatically conveyed using dense-stream conveying, into a gasifier for the production of synthesis gas, is supposed to be configured in such a manner that clearly homogenized feed of the coal to the burner is made possible, whereby the short-term fluctuations are minimized and thus the gasification quality is improved, and regulation of the amounts of coal to the burner is structured to be more effective. This is achieved in that the fine-grain to dust-type fuel is first conveyed out of a feed container positioned below the burner level, to a level above the burner level, and subsequently homogenized in a line that is directed downward toward the burner.

Abstract: Process for scrubbing out ammonia nitrogen and/or ammonium nitrogen and/or urea nitrogen from exhaust gases enriched with these nitrogen compounds in plants for producing ammonia or urea, wherein the nitrogen compounds first form with a hypochlorite-containing solution in a scrubber an intermediate which under acidic or neutral reaction conditions is reacted to form elemental nitrogen and salt, and the reaction of the nitrogen compounds to form elemental nitrogen and salt proceeds in a pH range of 4 to 6.

Abstract: A method for discharging the dust that occurs from pressurized gasification, using a dust precipitator having at least one discharge container assigned to it, is supposed to be configured in such a manner that nitrogen introduction into the raw gas is minimized or completely avoided, in order to free subsequent chemical syntheses from introduction of nitrogen, if at all possible, right from the start. This is achieved in that filter elements are positioned in the dust precipitator, which elements are back-flushed by means of a gas that contains carbon dioxide or pure CO2 gas.

Abstract: The invention relates to a method for producing electrically conducting nickel oxide surfaces made of nickel-containing material. According to the method, the nickel surface is first degreased and is then roughened for approximately ten minutes in a solution containing about one percent of hydrochloric acid, the process being accelerated by adding hydrogen peroxide solution, resulting in the electrolyte turning green. The nickel surface is briefly wetted, the nickel material is introduced into a solution of 3.5 molar lye to which about ten percent of hydrogen peroxide is added and is kept therein for ten minutes, and the resulting nickel hydroxide surface is dehydrated in a subsequent thermal process and is then further oxidized to obtain nickel oxide. The invention further relates to a conductive boundary layer that is produced according to the method, the electrodes therefrom, and the use thereof in chlorine-alkali electrolysis processes, in fuel cells and storage batteries.

Abstract: With the help of a method and device for nozzle-jetting oxygen into a synthesis reactor, e.g. for oxy-dehydration, with largely axial flow of the gas mixture through a catalyst bed, it is intended to vastly improve the mixing-in and mixing-through of oxygen above the catalyst especially for oxy-dehydration process. This is achieved by feeding the oxygen to a ring distributor system arranged above the catalyst bed in pure form, as air or mixed with inert gas or water vapor and jetting the oxygen onto the catalyst surface through several exit openings in the ring distributor at an inclined angle deviating from the vertical.

Abstract: A method for cyclical operation of a coke oven facility which includes an even number of coke oven banks which in turn include an even number of coke oven chambers is shown. Located downstream of the coke oven banks are boiler facilities which drive turbines with the hot waste gases from the coke oven banks. Energy is recovered in this manner. The coke oven chambers are pushed and charged in an exactly determined cycle so that the production of hot waste gas over the temporal mean can be homogenized.

Abstract: A synthesis gas (H2+CO) that comes from a gasifier is supposed to be used in more efficient and optimal manner, particularly for generating electricity, whereby then, CO2 that occurs at the same time is supposed to be passed to storage. This is achieved in that—the synthesis gas (H2+CO) and oxygen (O2) from an air separation system are combusted in a burner, and relaxed by way of a gas turbine (driving a generator),—CO2 is separated in the waste gas stream and passed to a compressor driven by the gas turbine, and—passed to CO2 storage as compressed CO2.

Abstract: Using a method for supplying a reactor (32) for generating crude synthesis gas with fuel (3), the fuel supply of a pressurized gasification system according to the line is to be configured in such a manner that the introduction of nitrogen into the crude gas is minimized or completely avoided. This is achieved in that—for inertization and loosening of the fuel in the storage container (2), —for loosening and fluidization of the content of the lock containers (5), —as the lock gas from the lock containers (5), —for loosening and fluidization in the feed container (29), as well as—for feed of the fuel between the system parts and out of the feed container (29) to the gasification reactor (32), a gas consisting predominantly of CO2 (more than 95 vol.-% CO2 with admixtures such as H2, CO, N2, hydrocarbons or the like) is used.

Abstract: The invention relates to a process using a solvent combination for the gas scrubbing of industrial gases in order to separate acid gases, particularly including carbon dioxide and hydrogen sulphide. The inventive solvent combination consists of a solution of amines in water, said solution containing ammonia for improving the absorption of CO2. The group of primary and secondary amines includes all types of amines with one or two substituents. Particularly suitable as constituent of the inventive solvent combination is piperazine and piperazine derivatives.

Abstract: The invention relates to a method for isolating hydrogen sulphide from coke-oven gas with the subsequent recovery of elemental sulphur in a Claus plant. The hydrogen sulphide is eliminated from the coke-oven gas by gas washing using an absorption liquid. During the regeneration of the loaded absorption liquid, hydrogen sulphide is accumulated in concentrated form and is fed to the Claus plant. Said Claus plant comprises a Claus boiler, a waste-heat boiler, in addition to a reactor, which forms an additional catalyst stage. According to the invention, the Claus plant is operated with a single reactor, which operates at a working temperature of below 250° C. The process gas that exits the reactor is returned after the deposition of elemental sulphur with a non-reacted residual concentration of hydrogen sulphide to the coke-oven gas that is to be cleaned, prior to the gas washing stage.

Abstract: The invention relates to a method for removing hydrogen sulphide and other acidic gas components from pressurized technical gases by means of a physical detergent and for obtaining sulphur from hydrogen sulphide by using a Claus system. The hydrogen sulphide and the other acidic gas components are removed in an absorbent manner from the physical detergent, the physical detergent undergoes multi-step regeneration, said multi-step regeneration comprising at least one device for CO enrichment, a device for H2S enrichment, a device for CO2 stripping and a device for thermal regeneration. The various regeneration steps consist of various pressure steps and have a lower pressure than that of the absorption. A hydrogen sulphide rich Claus gas is withdrawn from one of the regeneration steps and is guided to a Claus system where sulphur is produced. The residual gas exiting from the Claus system is hydrated and is condensed under pressure, corresponding to one of the regeneration steps.

Abstract: A device for proportioning of secondary combustion air into the secondary air soles of coke oven chamber ovens is shown. The device is formed by a slide gate or a parallelepiped device or by plates moved by means of a thrust bar, the thrust bar being moved longitudinally in parallel to the coke oven chamber wall so that the plates move away from the secondary air apertures and open or close these. The thrust bar is moved by means of a positioning motor, with the power transmission being effected hydraulically or pneumatically. Via suitable measuring parameters, it is thus possible to optimize secondary heating so that heating is provided evenly from all sides, thus achieving an improvement in coke quality.

Abstract: The invention relates to a desulfurization process, wherein a gas mixture is subjected to a separation process to separate the acidic components of the gas, an acid gas containing carbon dioxide and sulfur compounds, in particular hydrogen sulfide, being formed in this process, the acid gas being sent to a Claus plant for separation of elemental sulfur, and the residual gas leaving the Claus plant being subjected to a further separation, in which the water formed in the Claus process is at least partially removed, only technically pure oxygen being supplied as the oxygen-containing reaction gas to the Claus plant, and carbon dioxide in a purity which allows direct sequestration or industrial utilization being removed downstream from the Claus plant.