Abstract: A process for converting hydrocarbon oils into products of lower average molecular weight and lower boiling point comprising contacting a hydrocarbon oil containing less than 200 ppm N at elevated temperature and pressure in the presence of hydrogen with a catalyst A comprising a wide pore zeolite, a binder and at least one hydrogenation component of a Group VI and/or Group VIII metal, wherein the hydrocarbon oil is subsequently, without intermediate separation or liquid recycle, contacted with an amorphous silica-alumina containing catalyst B comprising at least one hydrogenation component of a Group VI and/or Group VIII metal.

Abstract: The present invention provides a process for decreasing the energy consumption of a catalytic cracking process product recovery section while improving gasoline yield by integrating multistage vapor compression and product recovery with deacidification and conversion of C.sub.2 -C.sub.4 aliphatics to C.sub.5 + normally liquid hydrocarbons.

Abstract: The invention involves visbreaking heavy oil under mild conditions in a vertical vessel containing a vertical elongate ring spaced inwardly from the vessel wall to form an outer open-ended annular chamber and an inner open-ended soak chamber. Heavy oil at 220.degree.-600.degree. F. is fed to top of annular chamber. A mixture of visbroken residuum and heavy oil at 730.degree.-800.degree. F. is fed to top of soak chamber. There is heat transfer through the ring from the soak liquid to the annulus liquid to assist in maintaining mild temperature in the soak chamber. The two streams mix in the base of the vessel whereby the visbreaking reaction is quenched. Part of the product is recycled and heated to provide the feed to the soak chamber.

Abstract: A process is disclosed for sludge addition to a coking zone in which the sludge is contacted with oxygen. The sludge is then contacted with feed, liquid derived from the feed, or vapor derived from the feed. Oxygen also contacts the feed, liquid derived from the feed, or vapor derived from the feed to help maintain reaction temperature in the coking zone.

Abstract: Hydrocarbon lubricants having a high viscosity index (V.I.) and low pour point are produced by hydroisomerizing a waxy lube feed such as slack wax or a waxy gas oil over zeolite beta after which aromatic components are removed by extraction, e.g. with furfural. The raffinate is then dewaxed, preferably by solvent dewaxing to target pour point with a final hydrofinishing step. The hydroisomerization coupled with the aromatics extraction and dewaxing increases the range of crudes that can be processed into high V.I. lubes while maintaining equivalent product qualities. Hydrogen consumption in the process is relatively low.

Abstract: A process for the production of alkylaromatic hydrocarbons uses a working fluid to reduce the costs of separating an unreacted aromatic feed substrate from aromatic hydrocarbon products. Unreacted aromatic substrate is combined with a light hydrocarbon, such as propane, to form a combined effluent stream. The combined effluent stream enters a flash separator where unreacted aromatic substrate is lifted overhead with the light hydrocarbon while heavier aromatic products are recovered below. The aromatic substrate and light hydrocarbon are easily separated in a simple separation zone. Lifting the aromatic substrate with the working fluid reduces the volume of aromatic substrate that remains with the aromatic product so that the more energy intensive separation of the aromatic substrate and aromatic product is performed on a reduced volume of material.

Abstract: Cracking catalysts which yield higher octane gasoline than conventional cracking catalysts are made with large pore size zeolites such as zeolite Beta and zeolite ZSM-20 in the low sodium, H.sup.+ form. These zeolites are mixed with a matrix which contains at least a binder and formed into catalyst particles. These catalysts are especially suitable to be used in fluid catalytic cracking.

Abstract: The catalytic cracking of a hydrocarbon oil to provide a product of increased octane number and increased light olefin content is carried out employing a cracking catalyst composition containing both a large pore crystalline zeolite component and a ZSM-57 zeolite component.

Abstract: A method for the solvent dewaxing of wax-containing petroleum products with at least one solvent suitable for dewaxing and a polymeric dewaxing aid comprising polyacrylates, by mixing the products to be dewaxed with the solvent and the polymeric dewaxing aid, chilling the mixture so obtained, and separating the precipitated wax, the dewaxing aid used being a mixture of(I) a polymer of esters of acrylic acid with C.sub.10 -C.sub.40 alkanols and(II) a polymer of esters of methacrylic acid with alkanols comprising more than 10 weight percent of branched alkanols,the weight ratio between components (I) and (II) ranging from 1:20 to 20:1.

Abstract: A process for upgrading heavy hydrocarbons in an emulsion through dense phase processing. The process involves subjecting a feed of oil in an immiscible solvent emulsion to supercritical conditions to facilitate separation of the heavy hydrocarbons into light hydrocarbons with greater value and more uses.

Abstract: A zeolite-containing catalytic cracking catalyst having been passivated by treatment with an aqueous solution which has been prepared by mixing an antimony oxide, ammonium bifluoride and water, at an atomic ratio of F:Sb in excess of about 6:1, is used in a process for catalytically cracking a hydrocarbon-containing feed, in particular one which contains metal impurities. In one embodiment, the above-described aqueous solution is injected into the feed. In other embodiments, the solution is injected into the cracking zone or into a catalyst regeneration zone.

Abstract: A kerogen-agglomerated oil shale is contacted with an acid-containing solution prior to economically upgrade the oil shale prior to retorting. The kerogen is agglomerated by contacting the oil shale with a two phase mixture of an organic liquid and water to form kerogen-rich agglomerates and mineral-rich particles. Acids suitable for use in this invention include any acid capable of forming a soluble metallic salt, preferably sulfurous acid.

Abstract: Commercially attractive continuous processes for the preparation of mesophase pitches for manufacturing high-performance carbon fibers are disclosed. One feature resides in that conversion of a pitch into a mesophase pitch is conducted continuously by using a unique continuous dispersion-heat-treating apparatus.

Abstract: A process for the reforming of hydrocarbons is improved by the use of an enhanced nucleate boiling surface in a selected portion of the feed effluent heat exchanger. In a vertical type heat exchanger where the reforming feedstream enters at a lower end of the heat exchanger and is at least partially vaporized in the heat exchanger by contact with a reforming effluent stream that enters an upper end of the heat exchanger and is at least partially condensed therein, an enhanced nucleate boiling surface is formed on the heat exchange surface that is in contact with the entering liquid phase portion of the stream feed. The enhanced nucleate boiling surface increases the amount of condensing that takes place on the opposite side of the heat exchange surface in a boiling-condensing zone.

Abstract: The pour point and/or cloud point of the lube fractions comprising a waxy hydrocarbon feedstock containing straight and branched chain paraffins is reduced by contacting the feedstock in a dewaxing zone, preferably in the presence of added hydrogen, with a dewaxing catalyst comprising (1) an intermediate pore crystalline molecular sieve having a pore size between about 5.0 Angstroms and about 7.0 Angstroms and (2) a large pore crystalline molecular sieve having a pore size above about 7.0 Angstroms and typically selected from the group consisting of silicoaluminophosphates, ferrosilicates, aluminophosphates and Y zeolites. A hydrocarbon fraction of reduced paraffin content is recovered from the effluent of the dewaxing zone. Preferred intermediate pore crystalline molecular sieves are silicalite and a ZSM-5 type zeolite. Preferred large pore crystalline molecular sieves are silicoaluminophosphates such as SAPO-5 and ammonium exchanged and steamed Y zeolites.

Abstract: A process for reducing the benzene content of a reformate stream in a conventional catalytic cracking reactor wherein a heavy hydrocarbon feed is cracked to lighter products by contact with a supply of hot regenerated cracking catalyst is disclosed. The reformate can be mixed with the heavy feed to the cracking reactor, but preferably reformate contacts hot regenerated cracking catalyst before the heavy feed is added. Benzene content is reduced by alkylation with reactive fragments created in the cracking reactor, or by transalkylation with alkyl aromatics. Benzene removal can be enhanced by adding a light reactive gas such as ethylene to the cracking reactor, by adding heavier aromatics, such as a light cycle oil, or both. The reaction is preferably conducted in an FCC riser reactor, but may be conducted in a moving bed cracking reactor.

Abstract: Methods of diminishing the content of soluble and insoluble forms of iron from crude are disclosed. Crude and water soluble chelant are mixed prior to addition of wash water. After wash water addition, an emulsion is formed. After resolution of the emulsion, iron laden water phase is separated resulting in decreased iron content in the crude. In a two-step desalting process, water soluble chelant is mixed with crude separated from the resolved emulsion emanating from the first, upstream, desalter. After such mixing, fresh wash water is added, with the so-formed crude/chelant/wash water mixture being fed to the second, downstream, desalter, for resolution. Crude separated from the second desalter has substantially diminished iron content compared to crude fed to the first desalter.

Abstract: Methods of extracting iron species, such as iron naphthenate, and iron sulfides, from a liquid hydrocarbon, such as crude oil are disclosed. A chelant selected from oxalic or citric acid is added directly to the liquid hydrocarbon and mixed therewith. Then, wash water is added to form a water in oil emulsion. The emulsion is resolved, with iron laden aqueous phase being separated.

Abstract: A midbarrel hydrocracking catalyst for use in producing middle distillate products from hydrocarbon feedstocks via hydrocracking comprises at least one hydrogenation component, preferably one containing a metal selected from Group VIB and/or Group VIII of the Periodic Table of Elements, a layered magnesium silicate such as sepiolite, an intercalated clay such as pillared clay, and, optionally, a crystalline molecular sieve, preferably a zeolitic molecular sieve such as the modified Y zeolite known as LZ-10 zeolite.

Abstract: This invention relates to a process for the separation of fine catalyst particles from a hydrocarbon feedstock coming from a catalytic cracking unit by filtration through mineral barriers and a filtration loop.The process consists of filtering the feedstock through mineral barriers that are resistant to heat and have a porosity adapted to the minimum diameter of the particles to be retained. The porosity is generally between 0.1 and 100 microns.