Abstract: A process is disclosed for separating cuprous chloride from a solution comprising cuprous chloride and one or more of a number of metal impurities, the process comprising crystallizing the cuprous chloride from the solution in the presence of copper as cupric chloride in a concentration of at least about 20 grams per liter.

Abstract: Apparatus suitable for oxidizing a metal halide in the vapor phase wherein at least part of the wall of the reaction zone is formed from crimped annular plates separated by uncrimped annular plates to form orifices through which at least one of the reactants can be introduced into the reaction zone.

Abstract: A pyroscrubber for combustion of large carbon particles in a stream of waste gas, particularly the waste gas from a coke calcination furnace comprises a generally U-shaped combustion chamber having a first passage arranged parallel with (preferably above) a second passage, so that there is a reversal in gas flow direction between the two passages. The combustion chamber has an exhaust gas inlet and an array of air inlets at the inlet end of the first passage. A gas outlet preferably leads laterally out of the side of the structure at the outlet end of the second passage to secure an abrupt change in the direction of gas flow.

Abstract: Apparatus for continuously, controllably passing and mixing carbon black and water together, controllably jetting a plurality of fluid stream against the inner walls of the mixing apparatus, and moving the streams along the inner walls.

Abstract: An apparatus for arresting the generation of dust from a coke dry quenching station comprising a dust collecting hood mounted on a traveling crane for transferring to the coke dry quenching station a coke bucket loaded with coke discharged from a coke oven so that the upper surface and the outer side wall of the bucket are enclosed by the dust collecting hood when the bucket is suspended from the crane, a fixed hood permanently arranged above the coke charging hole in the top of the quenching station in such a manner that the upper edge portion of the fixed hood is located adjacent to the lower edge portion of the dust collecting hood to form a practically continued hood, a suction duct attached to the fixed hood at its one end and connected to a dust collector at its other end, a movable chute disposed below the fixed hood so that it alternately changes positions with a lid which closes the coke charging hole of the quenching station, and a flange portion formed on the lower edge portion of the chute and ada

Abstract: An apparatus for catalytically combining hydrogen and oxygen which includes two concentric catalyst chambers arranged so that the outer chamber surrounds the inner chamber and the gas stream passes radially through the outer catalyst chamber.

Abstract: A low sulfur coke product is obtained in an integrated fluid coking and gasification process in which an oxygen-containing gas is introduced into the upper portion of the gasification zone and steam is introduced into the lower portion of the gasification zone. The desired degree of coke desulfurization is controlled by controlling the thickness of the gasifier coke layer on the gaseous reactor leaving solids per pass.

Abstract: The apparatus comprises an outermost, an intermediate, and an innermost compartment, the outermost compartment being provided with burners, activated carbon being supplied into, treated in, and removed from the intermediate compartment, and there being communication for gas between the three compartments. In revivification by the direct heating process, reactor gas is supplied into the outermost compartment, heated by the burners, passed into the intermediate compartment to contact the activated carbon being treated, and is then passed into the innermost compartment and exhausted therefrom. In revivification by the indirect heating process, reactor gas is supplied into the innermost compartment, passed into the intermediate compartment for treatment of activated carbon, and then passed into the outermost compartment and is exhausted therefrom, the innermost and intermediate compartments and elements therein being indirectly heated by the burners of the outermost compartment.

Abstract: A method and an improved platinum-tin promoted zinc aluminate catalyst reactor for dehydrogenation of a paraffinic hydrocarbon feed stream as first and second layers of silica-free particles, each positioned in contact with and on opposed surfaces of the catalyst across the direction of feed stream flow through the reactor for preventing the poisoning of said catalyst.

Abstract: The control system includes a controller and a clocking circuit along with a computer for each one of the coke oven chambers. A first control signal is responsive to the occurrence of charging coal into a given oven chamber and starts the clock. A second control signal is responsive to the pushing of coke from the oven chamber and stops the clock. When the duration of the coking time for a given oven chamber exceeds a predetermined coking time, the controller provides a signal for operating valves to terminate the flow of combustion gases into heating flues at the sides of that coke oven chamber. In the system, the computer updates coking time and establishes from time-to-time from data fed to it, the thermal state of each heating flue in the battery.

Abstract: A tunnel autoclave having guillotine doors at opposite ends has sections of rail fixed to the said doors so as to be aligned with guide rails extending through the said autoclave when the doors are in the open position.

Abstract: A process for isolating carboxylic acids from residues of the oxo reaction which are obtained as residues, on hydroformylation of ethylene or propylene, optionally after removing a part of the aldehydes produced, subsequent hydrogenation, treatment with aqueous alkali metal hydroxide solutions and subsequent distillation, wherein the residues are acidified with strong mineral acids to a pH of from 2-4, the acidified mixture not containing more than 5 parts by weight of water per part by weight of the carboxylic acids contained in the mixture, the organic phase is then separated off and the carboxylic acids are isolated therefrom by distillation at pressures below 150 mbar. The carboxylic acids obtained can be used as solvents or for the manufacture of esters.

Abstract: A float valve arrangement is disposed in a mixing condenser that is arranged intermediate the first and second stage of a two-stage evaporation installation suitable for purifying radio-active liquids. In normal operation, vapor evaporated in the first stage extends via a first conduit into the mixing condenser where such vapor is condensed by contact with a portion of the liquid in the second stage that is circulated back to the mixing condenser via a pump. The normal vapor pressure generated in the first stage keeps the float valve open and permits the steam to displace, into the second stage, liquid present in the mixing condenser. During start-up and shutdown of the installation wherein vapor from the first stage is no longer present, the resulting rise in liquid level in the mixing condenser causes the float valve to close and to prevent any backflow of liquid into the first stage via the first conduit.

Abstract: A vapor-liquid separator is provided which is adapted to be connected directly to the exit of a fixed reactor bed, and includes a vertically disposed housing, an upper portion of which is connected to vapor-liquid inlet means which may be provided by the fixed bed reactor so that a vapor-liquid mixture may be introduced downwardly into the housing.

Abstract: An improved method and apparatus for by-product coke oven operation wherein the problems of pollution caused by gases leaking out of the oven during the coking cycle are eliminated by providing an improved coke oven door using the metal-to-metal contact principle. Because of thermal conditions the distortion of the jambs and the distortion of the doors themselves takes place thus making the sealing of coke oven doors very difficult; this in particular is very serious with respect to high ovens. This distortion being of such form that the distortion of the jamb occurs in the opposite direction of the distortion of the oven door. This invention compensates for such distortion and makes possible the proper fit up of the door to a particular jamb irrespective of the degree of distortion.

Abstract: An apparatus for thermally recombining gases comprising a first (heating) chamber in which the gases to be combined are initially heated to a temperature above the threshold for thermal combination or recombination, a second (reaction) chamber is formed to provide for mixing of previously reacted gases with the gases delivered from the first chamber, and a temperature control means responsive to the temperature in the second chamber for controlling the temperature to which the gases are initially heated in the first chamber.

Abstract: The invention relates to a method and apparatus for the heat treatment of materials on a traveling hearth mounted on a horizontal plane and rotated on a vertical axis within a substantially air-tight enclosure. The materials on the hearth are deposited thereon in separate and distinct rows and retained in separate rows while undergoing heat treatment within the enclosure. The material in one of said rows is capable of evolving volatiles when the materials are subjected to a heat treatment and the evolved volatiles rise and are dispersed in the upper portion of the enclosure where the same will combine with an oxidant such as air and/or oxygen which is admitted into this portion of the enclosure. The mixture of evolved volatiles and oxidants such as air and/or oxygen will combust in the upper portion of the enclosure.

Abstract: An apparatus to allow manufacture of fine particle PETN (penetaerythritol tetranitrate) having a sensitivity to propagate in thin layers in slurry and having a particle size which presents advantages in safety of handling and ability to obtain higher solids loading in slurries and flexible explosive binder systems due to a lower surface area, and a wider particle size distribution, compared to previous PETN of similar sensitivity to propagation in thin layers, i.e., as the major explosive ingredient in flexible sheet explosive formulations, and to propagation as a high velocity detonation in small core loads, i.e., 1 grain/ft., in mild detonating fuse, confined detonating fuse, and the like.

Abstract: Gas-liquid contact reaction efficiency in a two stage heavy black liquor oxidation process is improved by co-current contact in the first stage and countercurrent contact in the second stage or vice versa. Such improved efficiency is sustained by preventing the obstruction of gas discharge nozzles.

Abstract: A low pressure loss, two stage burner is provided wherein a portion of the effluent gases are admitted to a primary burner defining a primary combustion zone, recirculated within the primary combustion zone, mixed with a combustible fuel in the primary combustion zone and ignited by means of an ignition system. The remainder of the effluent gases bypass the primary burner and flow into a secondary burner defining a secondary combustion zone. Gases entering this zone are mixed with a combustible fuel and ignited by means of the combustion occurring in the primary combustion zone. The effluent gases admitted to the secondary combustion zone have turbulent recirculation vortices generated therein in order that the gases will remain closely spaced to the secondary burner sidewall as they travel generally axially through the secondary combustion zone.