Patent number: 10526471
Abstract: The invention relates to the process for preparing ethylenedialkylphosphinic acids, esters and salts, wherein a) a phosphonic acid source (I) is reacted with olefins (IV) in the presence of a catalyst A to give an alkylphosphonous acid (II), or salt or ester thereof, b) the alkylphosphonous acid (II), or the salt or ester thereof, is reacted with an acetylenic compound (V) in the presence of a catalyst B to give the ethylenedialkylphosphinic acid derivative (III) where R1, R2, R3, R4, R5, R6, R11, R12, R13, R14 are the same or different and are each independently H, C1-C18-alkyl, C6-C18-aryl, C6-C18-aralkyl, C6-C18-alkylaryl, where the C6-C18-aryl, C6-C18-aralkyl, C6-C18-alkylaryl groups may be substituted by —C(O)CH3, OH, CH2OH, NH2, NO2, OCH3, SH and/or OC(O)CH3, and X is Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K, H and/or a protonated nitrogen base, and/or is H, C1-C18-alkyl, C6-C18-aryl, C6-C18-aralkyl, C6-C18-alkylaryl, (CH2)kOH, CH2—CHOH—CH2OH, (CH2)kO(CH2)lH, (CH2
Type:
Grant
Filed:
September 10, 2015
Date of Patent:
January 7, 2020
Assignee:
Clariant Plastics & Coatings Ltd
Inventors:
Martin Sicken, Fabian Schneider