Publication number: 20240166533
Abstract: A high-nickel ternary core-shell precursor for a lithium battery, a positive electrode material and a preparation method therefor. The chemical structural formula of the precursor is zNi(C4H7N2O2)2—Nix-zM1yM21-x-y(OH)2, wherein M1 and M2 are two of cobalt, aluminum, and manganese. The preparation method comprises: pumping a prepared metal salt solution, a dimethylglyoxime-ammonia water composite solution, and an ammonia water solution into a reaction kettle, maintaining the pH of a reaction system, and controlling the reaction time to obtain a sphere-like precursor inner core with a structural formula of Ni(C4H7N2O2)2; pumping the metal salt solution and the ammonia water solution, stopping pumping the dimethylglyoxime-ammonia water composite solution, pumping a sodium hydroxide solution to obtain a sphere-like core-shell precursor, washing, drying, sieving and deironing the precursor, mixing with a lithium source, and calcining to prepare the positive electrode material.
Type:
Application
Filed:
August 18, 2022
Publication date:
May 23, 2024
Applicant:
JINGMEN GEM CO., LTD.
Inventors:
Kaihua XU, Kun ZHANG, Dongming JIA, Cong LI, Xing YANG, Xiaofei XUE, Liangjiao FAN, Xiaofei CHEN, Xueqian LI, Xiaoshuai ZHU, Hao LV, Wenfang YUAN, Ding WANG, Xianjin YUE
Patent number: 11981616
Abstract: A method for preparing 3,3?-diaminobenzidine, the method comprising the following steps: subjecting 4,4?-biphenol and N,N-dimethylsulfamoyl chloride to an esterification reaction in a specified solvent at 40-70° C. to obtain 4,4?-biphenyl bis(N,N-dimethylaminosulfonate) as a first intermediate; subjecting the 4,4?-biphenyl bis(N,N-dimethylaminosulfonate) to a chlorination reaction with a chlorinating reagent under acidic conditions to obtain 3,3?-dichloro-4,4?-biphenyl bis(N,N-dimethylaminosulfonate) as a second intermediate; subjecting the second intermediate 3,3?-dichloro-4,4?-biphenyl bis(N,N-dimethylaminosulfonate) to an ammonolysis reaction with anammoniation reagent in the presence of a combined catalyst to obtain a crude product of 3,3?,4,4?-tetraaminobiphenyl, wherein the combined catalyst is a mixture of proline, a cuprous salt and a phase transfer catalyst; and subjecting the crude product of 3,3?,4,4?-tetraaminobiphenyl to a post-treatment to obtain a purified 3,3?,4,4?-tetraaminobiphenyl product.
Type:
Grant
Filed:
January 12, 2022
Date of Patent:
May 14, 2024
Assignees:
Hubei Huida High-Tech Co., Ltd, Borun High-Tech Co., Ltd.
Inventors:
Yun Ling, Yongfang Li, Kun Wang, Lizhu Chen, Wei Yin, Jinying Zhang