COSMETIC DEFECT REDUCTION IN ANODIZED PARTS
A system and process for reducing cosmetic defects such as black lines, and otherwise improving the final cosmetic appearance of anodized parts is disclosed. The process can include degreasing an aluminum or other metal part in a neutral to low alkaline solution having a mild detergent, chemically polishing the metal part with a specialized solution having one or more additives at an increased temperature for a reduced amount of time, and anodizing the metal part at a reduced voltage and for a reduced amount of time. An activating step can also be performed as part of the overall process. Tap water rinse, deionized water rinse, desmut, seal and bake procedures can also be performed on the metal part.
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This application is a National Stage application which claims priority under 35 U.S.C. §371 to International Application No. PCT/CN2011/076264, filed Jun. 24, 2011, and entitled “COSMETIC DEFECT REDUCTION IN ANODIZED PARTS,” which is incorporated herein by reference in its entirety and for all purposes.
TECHNICAL FIELDThe present invention relates generally to manufacturing and part formation. More particularly, the present embodiments relate to improving the final cosmetic appearance of anodized metal parts.
BACKGROUNDThe outward appearance of a computing system or device is important to many consumers. In particular, an aesthetically pleasing and cosmetically clean device that is free of any seams, burrs, marks or other irregularities can be perceived as being nicer and more desirable that devices that are not so cosmetically clean. Creating an outward appearance that is aesthetically pleasing and durable for computing systems and other devices that include metal parts can sometimes include the use of anodized metal parts.
It is generally well known that anodizing metal parts can improve the outer surfaces of such parts by hardening and strengthening the surfaces, increasing resistance to corrosion and wear, and providing better adhesion for paint primers and adhesives, among other advantages. In addition, the outward appearance of an anodized surface tends to be uniform and aesthetically pleasing, particularly with respect to aluminum. It is also generally well known that anodization tends to change the crystal structure or other microscopic texture of the metal material. This is generally not a problem though, as the advantages of anodizing aluminum and other metals can outweigh any expenses or drawbacks in many cases.
Unfortunately, the outward cosmetic appearance of an anodized metal part or system of parts may not be pristine or seamless where the microscopic structure of the part or parts contains defects, irregularities, or foreign materials, such as trace amounts of Ti, B, Cu, Fe, Si and the like. The existence of such defects or irregularities, which can occur at weld regions, seams or cracks, for example, can become manifested upon anodization. This can result in the outward cosmetic appearance of the anodized metal part or parts having black lines, white lines, pits or other flaws that are revealed or magnified as a result of the anodization process. While some amount of minor “black line” flaws such as these may be tolerable in some cases, such outcomes have a lowered aesthetic value and can often result in an increased amount of part rejection or recycling in the manufacturing process.
While many designs and techniques used with respect to anodizing metal parts and components have generally worked well in the past, there is always a desire to provide further designs and techniques for metal part anodization that result in a higher incidence of acceptable and cosmetically pleasing finished parts. In particular, what is desired are improved designs and techniques that enable the anodization of metal parts having inherent internal defects or flaws that still result in a final anodizing finish that is cosmetically pleasing and less likely to result in part rejection or recycling for cosmetic reasons.
SUMMARYThe present application describes various embodiments regarding systems and methods for the anodization of metal parts having inherent internal defects or flaws that still result in a final anodizing finish that is cosmetically pleasing and less likely to result in part rejection or recycling for cosmetic reasons. This can be accomplished at least in part through the use of manufacturing systems and methods that utilize specialized degreasing, chemical polishing and anodizing processes for the treatment of metal parts.
In various embodiments, a system adapted for the manufacture of anodized metal parts can include at least a degreasing station, a chemical polishing station, and an anodizing station. The degreasing station can be adapted to degrease a separate metal part using an alkaline solution with a mild detergent, wherein the alkaline solution has a pH that ranges from about 8 to 9. The chemical polishing station can be adapted to chemically polish the degreased metal part at a temperature that ranges from about 105 to 115 degrees C. and for a period of about 15 to 30 seconds, by using a chemical polishing solution with one or more specialized additives. The anodizing station can be adapted to anodize the chemically polished part for about 15 to 20 minutes and at a voltage that ranges from about 12.5 to 14.5 volts. More particularly, the chemical polishing can take place for about 15 seconds, while the anodizing can take place for about 15 minutes.
In various detailed embodiments, the system can be specially adapted to be used on aluminum parts, although other types of metal parts can also be processed. Additional system stations can include an activating station adapted to neutralize or activate the metal part between the degreasing and chemically polishing steps, one or more rinsing stations adapted to rinse the metal part with tap water after the part has been processed through the degreasing station, and one or more deionized rinsing stations adapted to rinse the metal part with deionized water after the part has been processed through the chemical polishing station. Still further system stations can include a de-smutting station adapted to de-smut the anodized metal part in a nitric acid solution at a temperature of about 25 degrees C. and for a period of about 30 seconds, a sealing station adapted to seal the anodized metal part using an acetate solution that is applied at a temperature that ranges from about 92 to 96 degrees C. and for a period of about 15 minutes, and a baking station adapted to bake the sealed metal part at a temperature that ranges from about 85-90 degrees C. and for a period of about 10 to 15 minutes. In one particular embodiment, the chemical polishing solution comprises by weight about 76-82% phosphoric acid, 18-20% sulfuric acid, 1-5% nitric acid, 1-1.5% corrosion inhibiting additive, 1-1.5% buffering agent, and a trace amount of fatty alcohol ehyoxyl compound.
In further embodiments, various methods of manufacturing metal parts having aesthetically pleasing surface finishes are provided. Method steps can include degreasing the metal part, chemically polishing the degreased metal part, and anodizing the chemically polished part. In particular, degreasing can be performed using an alkaline solution having a mild detergent and a pH of about 8 to 9. Also, chemical polishing can be performed at a temperature that ranges from about 105 to 115 degrees C. and for a period of about 15 to 30 seconds using a solution having one or more specialized additives. Further, anodizing can be performed for about 15 to 20 minutes and at a voltage that ranges from about 12.5 to 14.5 volts. More particularly, the chemical polishing can take place for about 15 seconds, while the anodizing can take place for about 15 minutes. Again, the subject metal parts can be aluminum, for example, and can be designed to be used for a computing device. Other metals and types of devices are also possible.
Additional process steps can include activating the degreased metal part between the degreasing and chemically polishing steps, rinsing the degreased metal part with tap water after the degreasing step, rinsing the chemically polished metal part with deionized water after the chemically polishing step, de-smutting the anodized metal part in a nitric acid solution at a temperature of about 25 degrees C. and for a period of about 30 seconds, sealing the anodized metal part using an acetate solution that is applied at a temperature that ranges from about 92 to 96 degrees C. and for a period of about 15 minutes, and baking the sealed metal part at a temperature that ranges from about 85-90 degrees C. and for a period of about 10 to 15 minutes.
In still further embodiments, a computing device can include a processor, one or more input components coupled to the processor, one or more output components coupled to the processor, and an outer housing including at least one anodized metal component. In particular, the anodized metal component or components can have been degreased in an alkaline solution having mild detergent and a pH that ranges from about 8 to 9, chemically polished at a temperature that ranges from about 105 to 115 degrees C. and for a period of about 15 to 30 seconds using a solution having one or more specialized additives, and anodized for about 15 to 20 minutes and at a voltage that ranges from about 12.5 to 14.5 volts. More particularly, the chemical polishing can take place for about 15 seconds, while the anodizing can take place for about 15 minutes. The anodized metal component or components can include anodized aluminum. Also, the outer housing can include one or more microstructure defects that are not made readily apparent as a result of the anodization process.
Other apparatuses, methods, features and advantages of the invention will be or will become apparent to one with skill in the art upon examination of the following figures and detailed description. It is intended that all such additional systems, methods, features and advantages be included within this description, be within the scope of the invention, and be protected by the accompanying claims.
The included drawings are for illustrative purposes and serve only to provide examples of possible structures and arrangements for the disclosed inventive systems and methods for the anodization of metal parts. These drawings in no way limit any changes in form and detail that may be made to the invention by one skilled in the art without departing from the spirit and scope of the invention.
Exemplary applications of apparatuses and methods according to the present invention are described in this section. These examples are being provided solely to add context and aid in the understanding of the invention. It will thus be apparent to one skilled in the art that the present invention may be practiced without some or all of these specific details. In other instances, well known process steps have not been described in detail in order to avoid unnecessarily obscuring the present invention. Other applications are possible, such that the following examples should not be taken as limiting.
In the following detailed description, references are made to the accompanying drawings, which form a part of the description and in which are shown, by way of illustration, specific embodiments of the present invention. Although these embodiments are described in sufficient detail to enable one skilled in the art to practice the invention, it is understood that these examples are not limiting; such that other embodiments may be used, and changes may be made without departing from the spirit and scope of the invention.
The present disclosure generally relates to the manufacture of various metallic housings and other computer components, as well as a manufacturing system and process adapted to treat and anodize such metal components. Although the following specific embodiments have been described with respect to a computer or computing device, it will be readily appreciated that other metal parts and components may be similarly treated without departing from the inventive features described herein and claimed below. For example, such parts can be used for the exteriors of refrigerators, valves, toys, or any other item having anodized parts that may be suitable. Further alternatives will be readily appreciated by those skilled in the art.
Referring first to
As seen in
Although a desktop computing device 10 has been shown for purposes of illustration, it will be readily appreciated that many other forms of computing devices can similarly have outer metal components that are suitable for the finishing systems and methods provided herein. Such other devices can include, for example, media playback devices, cellular telephones, tablet computing devices and the like. Furthermore, numerous other metal parts and components that are used for items other than computing devices may also be treated and finished using the various systems and methods disclosed herein.
Moving next to
An alkaline etch station 220 can then be set up to provide an alkaline etch for degreased metal parts. The alkaline etchant can involve a sodium hydroxide based solution having a relatively high alkaline pH of about 13-18. Another tap water rinse station 222 can be provided after the alkaline etch station 220. A de-smut station 224 can also be provided, which can involve a nitric acid de-smut solution. Another tap water rinse station 226 can then follow the de-smut station 224. As will be readily appreciated, rinsing may be performed at the same station in some arrangements, such that stations 212, 222 and 226 can actually be the same station.
A chemical polish station 230 can be used to facilitate the chemical polishing of the metal parts. The chemical polishing solution can be, for example, sulfuric acid at 250 g/l and phosphoric acid at 750 g/l. Polishing can be performed at a temperature of about 78-86 degrees C. for about 20-70 seconds. A deionized water rinse station 232 can then be provided after the chemical polish station 230, as will be readily understood.
An anodize station 240 can then be used to anodize the chemically polished parts. Anodizing can be conducted, for example, using 220 g/l sulfuric acid for about 23-26 minutes, and at a voltage of about 14.5 to 15.5 volts. Subsequent to the metal part anodizing, seal station 250 and bake station 260 can also be provided, with the functions, temperatures and times used for these final stations being generally well known by those skilled in the art.
Continuing now with
Starting with degrease station 310, a preferable degreasing formula for station can be composed of, for example, a mild detergent contained within a mild alkaline solution having a pH of about 8 to 9. This can result in an effect degreasing of the metal parts without exposing the parts to the harsher nature of a highly alkaline solution such as that which is used in the previous example. In one particular example, the mild detergent can be the Upland 102 model industrial detergent provided by the HangZhou Ylang Chemical Company of China. A tap water rinse station 312 can then be used after the metal parts have been degreased in degrease station 310. Tap water rinse station 312 can involve the use of three separate cleaning tanks for an efficient and effective rinsing of the metal parts. In addition, ultrasonic vibrations can be provided for the fluids in station 312, as well as for any of stations 310-340, as may be desired for a given manufacturing system.
An activation station 314 can then be provided to activate the surface of the metal parts after the degreasing and rinsing stations. As a particular example, a 150 g/l nitric acid solution can be applied at about 25 degrees C. for about 30 seconds to result in an effective activation of the degreased metal parts. Another tap water rinse station 316 can then be provided. In some instances, tap water rinse stations 312 and 316 can actually be the same station if desired.
A chemical polish station 320 can then be provided for the chemical polishing of the metal parts. The chemical polishing solution used can contain one or more specialized additives. In one particular example, the additives can be found in the 2022 product model metal working liquid provided by the HangZhou PShang Chemical Company of China. By using these particular additives, the resulting specialized chemical polishing solution can then comprise by weight about 76-82% phosphoric acid, 18-20% sulfuric acid, 1-5% nitric acid, 1-1.5% corrosion inhibiting additive, 1-1.5% buffering agent, and a trace amount of fatty alcohol ehyoxyl compound. The actual polishing using this specialized solution can be conducted at a temperature that ranges from about 105 to 115 degrees C., and for a period of about 15 to 30 seconds, which is generally hotter and shorter than the previous example. More particularly, the chemical polishing can take place for about 15 seconds. A deionized water rinse station 322 can then be provided after the chemical polish station 320, as will be readily appreciated. A de-smut station 324 can then be used to de-smut the metal parts. Such a de-smut can involve a nitric acid solution of a concentration less than about 100 g/l, and can be conducted at about 25 degrees C. for about 30 seconds, for example. Other de-smut details or variations are also possible.
An anodize station 330 can then be used to anodize the chemically polished parts. Anodizing can be conducted, for example, using 200 g/l sulfuric acid for about 15 to 20 minutes, and at a voltage of about 12.5 to 14.5 volts. More particularly, the anodizing can take place for about 15 minutes. In comparison with the foregoing example, this is a less concentrated solution that is being used at a lower voltage for a shorter period of time. Another de-smut station 332 can then be used to de-smut the metal parts after anodization. Again, such a de-smut can involve a nitric acid solution of a concentration less than about 100 g/l, and can be conducted at about 25 degrees C. for about 30 seconds, for example.
A seal station 340 can then be used to provide a sealing function. Sealing can be performed, for example, using an acetate solution at about 95 degrees C. and for about 10 minutes. A bake station can then be used to provide a baking function. Baking can be performed, for example, at about 85-90 degrees C. and for about 10 minutes as well.
As a result of the different details in metal part finishing system 300 with respect to the foregoing example, such as those regarding degrease station 310, chemical polish station 320 and anodize station 330, among others, improved results in the final cosmetic appearance of the metal parts can be realized. In particular, many black lines, white lines, pits and other cosmetic imperfections are not so readily apparent, despite the presence of underlying microscopic flaws or issues that ordinarily result in the manifestation of such cosmetic issues. It has thus been determined that use of system 300 in
At subsequent process step 406, a de-smut can be conducted on the metal part, with such a de-smut utilizing a 30-40% by weight nitric acid solution. This can be done at room temperature for about 30-60 seconds, for example. Again, a tap water rinse can be performed after this de-smut step 406. A chemical polish can then be conducted on the metal part at process step 408. Such a chemical polish can be done using a solution containing sulfuric acid at 250 g/l and phosphoric acid at 750 g/l at a temperature of about 78-86 degrees C. and for about 20-70 seconds. A water rinse can also be performed after this chemical polish step 408, and this may involve the use of deionized water.
At the following process step 410, the metal part can then be anodized using sulfuric acid at a concentration of 220 g/l for about 23-26 minutes, and at a voltage of about 15 (+/−0.5) volts. Subsequent process step 412 can involve sealing the anodized metal part in a nickel acetate and water solution at a temperature of about 92-96 degrees C. for about 15 minutes. Process step 414 can then involve baking the sealed part at about 80-100 degrees C. for about 10-15 minutes. The method then ends at end step 416.
Finishing now with
After a start step 500, a suitable metal part can be degreased at process step 502. Again, this can be an aluminum part, although other types of metal can also be used. As in the foregoing embodiment of
At subsequent process step 506, the metal part can then be activated in a nitric acid solution. In one example, a 150 g/l nitric acid solution can be applied at about 25 degrees C. for about 30 seconds. Another optional tap water rinse can then be performed at process step 508. Again, such a tap water rinse can take place in a three tank process. A chemical polishing of the metal part can then be conducted at process step 510. Again, as in the foregoing embodiment of
A deionized water rinse can then take place at process step 512. This deionized water rinse can similarly take place in a three tank process. A de-smut can then be performed on the metal part at process step 514. Such a de-smut can involve a nitric acid solution of a concentration less than about 100 g/l, and can be conducted at about 25 degrees C. for about 30 seconds. At subsequent process step 516, the metal part can be anodized. In particular, anodization can be performed using sulfuric acid at 200 g/l for about 15 to 20 minutes, and at a voltage that ranges from about 12.5 to 14.5 volts. More particularly, a voltage of about 13.5 volts can be used. Another de-smut can then be performed on the metal part at process step 518, with such a de-smut being the same or similar to the de-smut of step 514.
A sealing function can then take place at process step 520. Sealing can be performed using an acetate solution at about 95 degrees C. and for about 10 minutes. Baking can then take place at process step 522, with such baking being performed at about 85-90 degrees C. and for about 10 minutes as well. The method then ends at end step 524. In addition to the foregoing details, it will be readily appreciated that one or more of the solution based steps or rinses can optionally be conducted using ultrasonically vibrating tanks or baths.
Although the foregoing invention has been described in detail by way of illustration and example for purposes of clarity and understanding, it will be recognized that the above described invention may be embodied in numerous other specific variations and embodiments without departing from the spirit or essential characteristics of the invention. Certain changes and modifications may be practiced, and it is understood that the invention is not to be limited by the foregoing details, but rather is to be defined by the scope of the appended claims.
Claims
1. A system adapted for the manufacture of anodized metal parts, the system comprising:
- a degreasing station adapted to degrease a separate metal part, said degreasing station having an alkaline solution with a mild detergent, wherein the alkaline solution has a pH that ranges from about 8 to 9;
- a chemical polishing station adapted to chemically polish the degreased metal part at a temperature that ranges from about 105 to 115 degrees C. and for a period of about 15 to 30 seconds, said chemical polishing station having a chemical polishing solution with one or more specialized additives; and
- an anodizing station adapted to anodize the chemically polished part for about 15 to 20 minutes and at a voltage that ranges from about 12.5 to 14.5 volts.
2. The system of claim 1, wherein said system is adapted to be used on aluminum parts.
3. The system of claim 1, further including:
- an activation station adapted to activate the metal part between the degreasing and chemically polishing steps.
4. The system of claim 1, further including:
- one or more rinsing stations adapted to rinse the metal part with tap water after the part has been processed through the degreasing station.
5. The system of claim 1, further including:
- one or more deionized rinsing stations adapted to rinse the metal part with deionized water after the part has been processed through the chemical polishing station.
6. The system of claim 1, further including:
- a de-smutting station adapted to de-smut the anodized metal part in a nitric acid solution at a temperature of about 25 degrees C. and for a period of about 30 seconds.
7. The system of claim 1, further including:
- a sealing station adapted to seal the anodized metal part using an acetate solution that is applied at a temperature that ranges from about 92 to 96 degrees C. and for a period of about 15 minutes.
8. The system of claim 1, further including:
- a baking station adapted to bake the sealed metal part at a temperature that ranges from about 85-90 degrees C. and for a period of about 10 to 15 minutes.
9. The system of claim 1, wherein the chemical polishing solution comprises by weight about 76-82% phosphoric acid, 18-20% sulfuric acid, 1-5% nitric acid, 1-1.5% corrosion inhibiting additive, 1-1.5% buffering agent, and a trace amount of fatty alcohol ehyoxyl compound.
10. A method of manufacturing a metal part having an aesthetically pleasing surface finish, comprising:
- degreasing the metal part in an alkaline solution having a mild detergent, wherein the alkaline solution has a pH that ranges from about 8 to 9;
- chemically polishing the degreased metal part at a temperature that ranges from about 105 to 115 degrees C. and for a period of about 15 to 30 seconds, wherein said chemical polishing is accomplished using a solution having one or more specialized additives; and
- anodizing the chemically polished part for about 15 to 20 minutes and at a voltage that ranges from about 12.5 to 14.5 volts.
11. The method of claim 10, wherein the metal part is aluminum.
12. The method of claim 10, wherein the metal part is designed to be used for a computing device.
13. The method of claim 10, further including the step of:
- activating the degreased metal part between the degreasing and chemically polishing steps.
14. The method of claim 10, further including the step of:
- rinsing the degreased metal part with tap water after the degreasing step.
15. The method of claim 10, further including the step of:
- rinsing the degreased metal part with deionized water after the chemically polishing step.
16. The method of claim 10, further including the step of:
- de-smutting the anodized metal part in a nitric acid solution at a temperature of about 25 degrees C. and for a period of about 30 seconds.
17. The method of claim 10, further including the steps of:
- sealing the anodized metal part using an acetate solution that is applied at a temperature that ranges from about 92 to 96 degrees C. and for a period of about 15 minutes; and
- baking the sealed metal part at a temperature that ranges from about 85-90 degrees C. and for a period of about 10 to 15 minutes.
18. A computing device, comprising:
- a processor;
- one or more input components coupled to the processor;
- one or more output components coupled to the processor; and
- an outer housing including at least one anodized metal component, wherein said at least one anodized metal component has been degreased in an alkaline solution having mild detergent and a pH that ranges from about 8 to 9, chemically polished at a temperature that ranges from about 105 to 115 degrees C. and for a period of about 15 to 30 seconds using a solution having one or more specialized additives, and anodized for about 15 to 20 minutes and at a voltage that ranges from about 12.5 to 14.5 volts.
19. The computing device of claim 18, wherein said at least one anodized metal component comprises anodized aluminum.
20. The computing device of claim 18, wherein said outer housing includes one or more microstructure defects that are not made readily apparent as a result of the anodization process.
Type: Application
Filed: Jun 24, 2011
Publication Date: Oct 17, 2013
Applicant: Apple Inc. (Cupertino, CA)
Inventors: Zhicong Yao (Rochester Hills, MI), Chi-Hsiang Chang (Taibei)
Application Number: 13/995,146
International Classification: C25D 11/16 (20060101);