APPARATUS, SYSTEM AND TECHNIQUES FOR MASS ANALYZED ION BEAM
An apparatus may include a housing including an entrance aperture, to receive an ion beam. The apparatus may include an exit aperture, disposed in the housing, downstream to the entrance aperture, the entrance aperture and the exit aperture defining a beam axis, extending therebetween. The apparatus may include an electrodynamic mass analysis assembly disposed in the housing and comprising an upper electrode assembly, disposed above the beam axis, and a lower electrode assembly, disposed below the beam axis. The apparatus may include an AC voltage assembly, electrically coupled to the upper electrode assembly and the lower electrode assembly, wherein the upper electrode assembly is arranged to receive an AC signal from the AC voltage assembly at a first phase angle, and wherein the lower electrode assembly is arranged to receive the AC signal at a second phase angle, the second phase angle 180 degrees shifted from the first phase angle.
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The disclosure relates generally to ion beam apparatus and more particularly to ion implanters having mass analysis.
BACKGROUND OF THE DISCLOSUREIon implantation is a process of introducing dopants or impurities into a substrate via bombardment. Ion implantation systems (“ion implanters”) may comprise an ion source and a substrate stage or process chamber, housing a substrate to be implanted. The ion source may comprise a chamber where ions are generated. Beamline ion implanters may include a series of beam-line components, for example, a mass analyzer, a collimator, and various components to accelerate or decelerate the ion beam.
A useful function of an ion implanter beamline is to separate ions of different masses so that an ion beam may be formed having the desired ions for treating the work piece or substrate, while undesirable ions are intercepted in a beamline component and do not reach the substrate. In known systems, this mass analysis function is provided by an analyzing magnet, which component bends a beam of ions that all have the same energy in a curve whose radius depends on the ion mass, thus achieving the required separation. Magnets of this kind, however, are large, expensive and heavy and represent a significant fraction of the cost and power consumption of an ion implanter.
For relatively lower energy ion implantation, such as energy below approximately 50 keV, compact ion beam systems have been developed. These ion beam systems may include a plasma chamber acting as ion source, and placed adjacent a process chamber, housing the substrate to be implanted. An ion beam may be extracted from the plasma chamber using an extraction grid or other extraction optics to provide an ion beam to the substrate, with a desired beam shape, such as a ribbon beam. In these latter systems, mass analysis may be omitted because of size/space considerations for installing a magnetic analyzer, as discussed above, as well as cost. Thus, the use of such compact ion beam systems may be limited to applications where purity of implanting species is not a strict requirement.
With respect to these and other considerations, the present disclosure is provided.
BRIEF SUMMARYIn one embodiment, an apparatus may include a housing including an entrance aperture, to receive an ion beam, and an exit aperture, disposed in the housing, downstream to the entrance aperture, where the entrance aperture and the exit aperture define a beam axis, extending therebetween. The apparatus may include an electrodynamic mass analysis assembly disposed in the housing and comprising an upper electrode assembly, disposed above the beam axis, as well as a lower electrode assembly, disposed below the beam axis. The apparatus may include an AC voltage assembly, electrically coupled to the upper electrode assembly and the lower electrode assembly. The upper electrode assembly may be arranged to receive an AC signal from the AC voltage assembly at a first phase angle, and the lower electrode assembly may be arranged to receive the AC signal at a second phase angle, the second phase angle being 180 degrees shifted from the first phase angle.
In another embodiment, a system may include an ion source, disposed to generate an ion beam and an electrodynamic mass analysis device. The electrodynamic mass analysis device may include an entrance aperture, disposed to receive the ion beam and an exit aperture, disposed downstream to the entrance aperture, where the entrance aperture and the exit aperture define a beam axis, extending therebetween. The electrodynamic mass analysis device may further include an upper electrode assembly, disposed above the first axis; and a lower electrode assembly, disposed below the first axis. The system may also include a process chamber, disposed downstream of the exit aperture, the process chamber comprising a substrate stage, and an AC voltage assembly, electrically coupled to the upper electrode assembly and the lower electrode assembly.
In a further embodiment, a method of processing an ion beam may include generating the ion beam as a continuous ion beam and directing the continuous ion beam along a beam axis into an electrodynamic mass analysis (EDMA) device. The EDMA device may include an upper electrode assembly, disposed above the beam axis, and a lower electrode assembly, disposed below the beam axis. The method may include conducting the continuous ion beam through the EDMA device while applying an AC voltage signal at a target frequency and a target voltage amplitude to the upper electrode assembly and to the lower electrode assembly. As such, a target ion species having a first mass may exit the EDMA device along the first axis, wherein an impurity ion species having a second mass, different from the first mass does not exit the EDMA device along the first axis, and wherein a mass analyzed ion beam exits the EDMA device.
The drawings are not necessarily to scale. The drawings are merely representations, not intended to portray specific parameters of the disclosure. The drawings are intended to depict exemplary embodiments of the disclosure, and therefore are not be considered as limiting in scope. In the drawings, like numbering represents like elements.
DETAILED DESCRIPTIONAn apparatus, system and method in accordance with the present disclosure will now be described more fully hereinafter with reference to the accompanying drawings, where embodiments of the system and method are shown. The system and method may be embodied in many different forms and are not be construed as being limited to the embodiments set forth herein. Instead, these embodiments are provided so this disclosure will be thorough and complete, and will fully convey the scope of the system and method to those skilled in the art.
As used herein, an element or operation recited in the singular and proceeded with the word “a” or “an” are understood as potentially including plural elements or operations as well. Furthermore, references to “one embodiment” of the present disclosure are not intended to be interpreted as precluding the existence of additional embodiments also incorporating the recited features.
Provided herein are approaches for mass analyzed ion implantation systems, using a novel mass analysis device. In various embodiments the mass analysis device may be implemented in beamline ion implanters or in compact ion beam systems.
As shown in
To perform mass analysis, the apparatus 100 may include an electrodynamic mass analysis assembly, including an upper electrode assembly 102, disposed above the beam axis 101, and a lower electrode assembly 104, disposed below the beam axis 101.
In some embodiments, the upper electrode assembly 102 and the lower electrode assembly 104 may include a plurality of electrodes, where the plurality of electrodes are elongated along an electrode axis (represented by the X-axis) where the electrode axis extends perpendicularly to the beam axis. This configuration may be especially suitable for treating ribbon beams, where the ribbon beam is characterized by a long axis in cross-section extending along the X-axis. However, in other embodiments the electrodes of the apparatus 100 may treat a spot or pencil beam having a more equiaxed shape in cross-section.
The upper electrode assembly 102 may include an upper entrance electrode 112, disposed in an entrance chamber 110, a main upper electrode assembly 122, disposed in a main chamber 120, downstream to the upper entrance electrode 112, and an upper exit electrode 132, disposed downstream to the main upper electrode assembly 122.
The lower electrode assembly 104 may include a lower entrance electrode 114, disposed in the entrance chamber 110, a main lower electrode assembly 124, disposed in the main chamber 120, and a lower exit electrode 134, disposed downstream to the main lower electrode assembly 124.
According to various embodiments, the main upper electrode assembly 122 and the main lower electrode assembly 124 may define a flared relationship, wherein a separation between the main upper electrode assembly and the main lower electrode assembly increases between an upstream position of the main chamber and a downstream position of the main chamber. This flared relationship may aid in reducing ion impacts from an ion beam traveling through the enclosure 103.
As shown in
The apparatus 100 may include a ground tunnel in the entrance chamber 110, disposed downstream of the upper entrance electrode 112 and the lower entrance electrode 114. As shown in
The apparatus 100 may include an AC voltage assembly 160, electrically coupled to the upper electrode assembly 102 and the lower electrode assembly 104. As described in more detail below, the upper electrode assembly 102 may be arranged to receive an AC signal from the AC voltage assembly 160 at a first phase angle, while the lower electrode assembly 104 is arranged to receive the AC signal at a second phase angle, the second phase angle being 180 degrees shifted from the first phase angle.
In brief, the provision of an AC voltage signal (see AC voltage assembly 160 of
The ions 152 have a different mass than the mass of process ions 154. Again, by appropriate selection of various parameters, the ions 152 may be deflected along trajectories that cause the ions 152 to be captured within the enclosure 103, or may be caused to exit through exit aperture 108 along trajectories that are not parallel to the beam axis 101, and thus to not strike a substrate to be processed. These various parameters may include frequency of the applied AC voltage, voltage amplitude, as well as the geometrical arrangement of various components within the enclosure 103.
As the ions enter the enclosure 103, the electric field appears on for approximately 65° adjacent the upper entrance electrode 112 and lower entrance electrode 114. The electric field appears off for approximately 65°, adjacent the ground tunnel, on for approximately 175°, in the left portion of the main chamber 120, off for approximately 65° and then on for approximately 65°, toward the right of the main chamber 120 and left of the exit chamber 130. This arrangement causes the trajectory of any given ion to be bent initially in the entrance chamber 110, to drift in a straight line adjacent the ground tunnel, to be bent again in the initial portion of the main chamber 120, to drift in a straight line while exiting the main chamber 120, and to again be bent in the exit chamber 130.
In accordance with various embodiments of the disclosure, the dimensions and the operation of the apparatus 100 may be engineered to accommodate a wide variety of ion beam sizes, ion energies, ion masses and AC frequencies. These parameters are related by the simple equation
where L is the length from the entrance to the exit of the enclosure 103, n is the number of cycles of the AC voltage of frequency f, E is the ion energy and m is the ion mass. The parameter n depends on the detailed trajectory chosen, and may in general be an integer or non-integer value. In the arrangement of
Notably, in other embodiments, a given EDMA device having a given length of enclosure 103 (along the Z-axis), may be used to transmit different ion species by changing the frequency applied to the electrodes or the energy of the incoming beam, as appropriate. Table II provides a set of ion energies corresponding to a length L (see Eq. 1) of 0.3 m for enclosure 103, as a function of AC voltage frequency for hydrogen (amu=1), boron (amu=11), phosphorous (amu=31), and arsenic (amu=75).
As shown in table II., for a given ion energy (e.g. 22 keV+/−1 eV), the frequency of the AC voltage decreases with increasing mass (showing a square root dependence), but well within the range of commercially available RF supplies. Thus, different AC voltage (RF voltage in this case) supplies may be used as appropriate to drive the same enclosure having a given length L, in order to transmit ions of different masses for a given ion energy.
More generally, the dimensions of drift regions, deflection regions, and number of different regions may be tailored to optimize EDMA device performance.
In
In
As noted, an EDMA device arranged according to the present embodiments may be used to replace a magnetic mass analyzer, such as a known magnetic mass analyzer, used in beamline ion implanters. Moreover, the EDMA devices of the present embodiments may be used to construct a novel compact ion implantation apparatus having mass analysis capabilities.
The apparatus 100, including enclosure 103, having an electrode assembly disposed therein, and generally configured as described above with respect to
The system 400 further includes a process chamber 410, disposed downstream of the enclosure 103, to receive a mass analyzed ion beam and expose a substrate 412 to the mass analyzed ion beam. In some embodiments, a substrate stage 414 may be provided in the process chamber 410, to scan the substrate 412, for example, along the Y direction, where the mass analyzed ion beam may be elongated along the X-direction. In this manner, the entirety of the substrate 412 may be exposed to the mass analyzed ion beam 430B. As suggested in
Thus, a mass analyzed, energy filtered ion beam 430C may be provided to the substrate 412. Notably, in embodiments where the enclosure 103 has the dimensions on the order of several tenths of one meter, the entire distance between ion source 402 and process chamber 410 may be on the order of 1 meter or less.
At block 504, the continuous ion beam is directed along a beam axis into an electrodynamic mass analysis (EDMA) device. The EDMA device may include an upper electrode assembly and lower electrode assembly, where the upper electrode assembly is disposed above the beam axis and lower electrode assembly is disposed below the beam axis.
At block 506, the continuous ion beam is conducted through the EDMA device while applying an AC voltage at a target frequency and target amplitude. The target frequency may be tuned according to the energy of the continuous ion beam and the target ion species to be transmitted through the EDMA device. As such, the target ion species having a first mass and a target energy exits the EDMA device along the beam axis, while ion species having a second mass, different from the target mass does not exit the EDMA device along the beam axis. In this manner, the impurity ion species may be filtered from continuing to propagate along the beam axis toward a substrate to be implanted.
In view of the foregoing, at least the following advantages are achieved by the embodiments disclosed herein. A first advantage is realized by providing a more compact mass analysis component for mass analyzing an ion beam. A second advantage is expense saved in providing an EDMA type system for mass analysis. A third advantage is provided in that high frequency AC fields used to perform mass analysis according to the present embodiments will probably not transport particles, and thus reduce particle contamination. A further advantage is the relatively higher throughput of the mass analyzer according to the present embodiments, simulated to be above 50% and in some cases as high as 70%.
While certain embodiments of the disclosure have been described herein, the disclosure is not limited thereto, as the disclosure is as broad in scope as the art will allow and the specification may be read likewise. Therefore, the above description are not to be construed as limiting. Those skilled in the art will envision other modifications within the scope and spirit of the claims appended hereto.
Claims
1. An apparatus, comprising:
- a housing including an entrance aperture, to receive an ion beam;
- an exit aperture, disposed in the housing, downstream to the entrance aperture, the entrance aperture and the exit aperture defining a beam axis, extending therebetween;
- an electrodynamic mass analysis assembly disposed in the housing and comprising: an upper electrode assembly, disposed above the beam axis; and a lower electrode assembly, disposed below the beam axis; and
- an AC voltage assembly, electrically coupled to the upper electrode assembly and the lower electrode assembly, wherein the upper electrode assembly is arranged to receive an AC signal from the AC voltage assembly at a first phase angle, and wherein the lower electrode assembly is arranged to receive the AC signal at a second phase angle, the second phase angle being 180 degrees shifted from the first phase angle.
2. The apparatus of claim 1, wherein the upper electrode assembly comprises:
- an upper entrance electrode, disposed in an entrance chamber of the housing;
- a main upper electrode assembly, disposed in a main chamber of the housing, downstream to the upper entrance electrode; and
- an upper exit electrode, disposed in the main chamber of the housing, downstream to the main upper electrode assembly; and
- wherein the lower electrode assembly comprises:
- a lower entrance electrode, disposed in the entrance chamber;
- a main lower electrode assembly, disposed in the main chamber, downstream to the lower entrance electrode; and
- a lower exit electrode, disposed downstream to the main lower electrode assembly.
3. The apparatus of claim 2, wherein the main upper electrode assembly and the main lower electrode assembly define a flared relationship, wherein a separation between the main upper electrode assembly and the main lower electrode assembly increases between an upstream position of the main chamber and a downstream position of the main chamber.
4. The apparatus of claim 2, further comprising a beam blocker, the beam blocker being disposed in the main chamber and extending across the beam axis, the beam blocker being set at ground potential.
5. The apparatus of claim 2, wherein the entrance chamber further comprises a ground tunnel, disposed downstream of the upper entrance electrode and the lower entrance electrode, the ground tunnel having an upper portion disposed above the beam axis and a lower portion, disposed below the beam axis.
6. The apparatus of claim 1, wherein the AC signal comprises a frequency of 200 kHz to 100 MHz.
7. The apparatus of claim 1, wherein the electrodynamic mass analysis assembly comprises a plurality of electrodes, the plurality of electrodes being elongated along an electrode axis, the electrode axis extending perpendicularly to the beam axis.
8. The apparatus of claim 1, wherein the AC signal comprises a maximum voltage amplitude of 1 kV to 100 kV.
9. A system, comprising:
- an ion source, disposed to generate an ion beam;
- an electrodynamic mass analysis device, comprising: an entrance aperture, disposed to receive the ion beam; an exit aperture, disposed downstream to the entrance aperture, the entrance aperture and the exit aperture defining a beam axis, extending therebetween; an upper electrode assembly, disposed above the beam axis; and a lower electrode assembly, disposed below the beam axis; and
- a process chamber, disposed downstream of the exit aperture, the process chamber comprising a substrate stage; and
- an AC voltage assembly, electrically coupled to the upper electrode assembly and the lower electrode assembly.
10. The system of claim 9, wherein the upper electrode assembly is arranged to receive an AC signal from the AC voltage assembly at a first phase angle, and wherein the lower electrode assembly is arranged to receive the AC signal at a second phase angle, the second phase angle being 180 degrees shifted from the first phase angle.
11. The system of claim 9, further comprising an electrostatic energy filter, disposed between the exit aperture and the process chamber, wherein the electrostatic energy filter is arranged to deflect the ion beam from the beam axis to a process axis, over an angular range of 10 degrees to 60 degrees.
12. The system of claim 10, wherein the upper electrode assembly comprises:
- an upper entrance electrode, disposed in an entrance chamber of the housing;
- a main upper electrode assembly, disposed in a main chamber of the housing, downstream to the upper entrance electrode; and
- an upper exit electrode, disposed in the main chamber of the housing, downstream to the main upper electrode assembly; and
- wherein the lower electrode assembly comprises:
- a lower entrance electrode, disposed in the entrance chamber;
- a main lower electrode assembly, disposed in the main chamber, downstream to the lower entrance electrode; and
- a lower exit electrode, disposed downstream to the main lower electrode assembly.
13. The system of claim 12, wherein the main upper electrode assembly and the main lower electrode assembly define a flared relationship, wherein a separation between the main upper electrode assembly and the main lower electrode assembly increases between an upstream position of the main chamber and a downstream position of the main chamber.
14. The system of claim 12, further comprising a beam blocker, the beam blocker being disposed in the main chamber and extending across the beam axis, the beam blocker being set at ground potential.
15. The system of claim 12, wherein the entrance chamber further comprises a ground tunnel, disposed downstream of the upper entrance electrode and the lower entrance electrode, the ground tunnel having an upper portion disposed above the beam axis and a lower portion, disposed below the beam axis.
16. The system of claim 12, wherein the AC signal comprises a frequency of 200 kHz to 100 MHz and a maximum voltage amplitude of 1 kV to 100 kV.
17. The system of claim 9, wherein the electrodynamic mass analysis device comprises a plurality of electrodes, the plurality of electrodes being elongated along an electrode axis, the electrode axis extending perpendicularly to the beam axis.
18. A method of processing an ion beam, comprising:
- generating the ion beam as a continuous ion beam;
- directing the continuous ion beam along a beam axis into an electrodynamic mass analysis (EDMA) device, the EDMA device comprising an upper electrode assembly, disposed above the beam axis, and a lower electrode assembly, disposed below the beam axis; and
- conducting the continuous ion beam through the EDMA device while applying an AC voltage signal at a target frequency and a target voltage amplitude to the upper electrode assembly and to the lower electrode assembly,
- wherein a target ion species having a first mass exits the EDMA device along the beam axis, wherein an impurity ion species having a second mass, different from the first mass does not exit the EDMA device along the beam axis, and wherein a mass analyzed ion beam exits the EDMA device.
19. The method of processing an ion beam of claim 18, further comprising:
- directing the mass analyzed ion beam through an energy filter, wherein a mass analyzed energy filtered ion beam is generated; and
- directing the mass analyzed energy filtered ion beam to a substrate.
Type: Application
Filed: Mar 15, 2019
Publication Date: Sep 17, 2020
Applicant: APPLIED Materials, Inc. (Santa Clara, CA)
Inventors: Frank Sinclair (Boston, MA), Costel Biloiu (Rockport, MA), Joseph C. Olson (Beverly, MA), Alexandre Likhanskii (Malden, MA)
Application Number: 16/354,638