BOTTOM TUNNEL JUNCTION LIGHT-EMITTING FIELD-EFFECT TRANSISTORS
A method for achieving voltage-controlled gate-modulated light emission using monolithic integration of fin- and nanowire-n-i-n vertical FETs with bottom-tunnel junction planar InGaN LEDs is described. This method takes advantage of the improved performance of bottom-tunnel junction LEDs over their top-tunnel junction counterparts, while allowing for strong gate control on a low-cross-sectional area fin or wire without sacrificing LED active area as in lateral integration designs. Electrical modulation of 5 orders, and an order of magnitude of optical modulation are achieved in the device.
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This application claims the benefit of priority to U.S. Provisional Patent Application No. 63/052,180, filed on Jul. 15, 2020, and entitled “BOTTOM TUNNEL JUNCTION LIGHT-EMITTING FIELD-EFFECT TRANSISTORS,” which application is incorporated herein by reference.
STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH OR DEVELOPMENTThis invention was made [partially] with U.S. Government support from the National Science Foundation under Awards No. 1534303, 1710298, 1719875, 1839196 and from NSF National Nanotechnology Coordinated Infrastructure under Awards No. ECCS-1542081, DMR-1719875, MRI DMR-1338010. The U.S. Government has certain rights to the invention.
BACKGROUNDVisible light-emitting diodes (LEDs) based on the Indium Gallium Nitride (InGaN) material system have emerged as fundamental components in micro-LED display technology, car headlamps, and cell phone backlighting, amongst other lighting applications. More recently, interest in InGaN LEDs has spread beyond lighting applications towards a different area—light fidelity (Li-Fi) communications—due to promises of faster and more secure data transmission compared to conventional Wi-Fi. InGaN LEDs are attractive for such applications due to their preponderance in lighting, and also due to their high external quantum efficiencies (EQEs) in the visible spectral range—a range which is >2000× larger in bandwidth than the entire RF spectral range, and one which is currently underutilized.
In order to use LEDs for Li-Fi communications, high speed modulation of the LED light output is desirable. This modulation is achieved with the use of a current or voltage driver. In the GaAs semiconductor family, heterojunction bipolar transistors (HBTs) have been redesigned epitaxially into LEDs and even laser diodes (LDs) for current driven operation. Though the Nitride semiconductor family allows for visible to UV emission wavelengths and higher power operation, to realize HBT-LEDs or HBT-LDs similar to GaAs requires the quantum well active region to be placed inside p-type base-layers, which are rather resistive and problematic for contact formation. Voltage-driven control methods involve simpler control schemes and offer more flexibility than current-driven methods. Using GaN FETs directly integrated on the LED for voltage driving can take advantage of a single epitaxial step, and the excellent performance demonstrated by vertical GaN FETs. Towards this end, integration of GaN-based FETs and LEDs on the same epi-wafer can enable high power and high efficiency voltage-controlled modulated visible light emission while eliminating interconnects and reducing the overall device footprint. Prior demonstrations integrating III-Nitride FETs and LED structures on the same epi-wafer for these applications involve lateral integration of High Electron Mobility Transistors (HEMTs) with the LED, or vertical integration through a top-down full nanowire platform. However, both strategies limit the LED active area on the wafer: the former strategy requires removing the LED epi from certain regions of the wafer (and in certain processes, an additional regrowth step to define the LED structure). The latter constrains LED active volume down to the size of a gate-controllable nanowire, severely limiting the optical output power.
BRIEF SUMMARYThe strategy demonstrated in these teachings offers a solution to both problems by integrating nanowire and fin vertical n-FETs on large-area planar LEDs through top-down fabrication on a heterostructure that is realized in one epitaxial stack. This approach allows for strong all-around gate control on the relatively low cross sectional area FETs, while allowing large area LEDs that take advantage of the on-wafer area for high output power.
For a better understanding of the present teachings, together with other and further needs thereof, reference is made to the accompanying drawings and detailed description.
The following detailed description presents the currently contemplated modes of carrying out the invention. The description is not to be taken in a limiting sense but is made merely for the purpose of illustrating the general principles of the invention.
Group III, as used herein, refers to CAS Group IIIA (Triels or the Boron group) in the periodic table.
Group V, as used herein, refers to the Nitrogen group.
III-nitride semiconductor materials, as used herein, refers to (Al, In, Ga and their alloys) N.
A “tunnel junction,” as used herein, refers to one or more highly doped n-type layers followed by one or more highly doped p-type layers.
The strategy demonstrated in these teachings offers a solution to both problems by integrating nanowire and fin vertical n-FETs on large-area planar LEDs through top-down fabrication on a heterostructure that is realized in one epitaxial stack. This approach allows for strong all-around gate control on the relatively low cross-sectional area FETs, while allowing large area LEDs that take advantage of the on-wafer area for high output power.
In order to vertically integrate nanowire- or fin-n-FETs with planar LEDs, the wires or fins must sit on top of the planar LED. This requires the top layer of the LED to be n-GaN rather than p-GaN. A tunnel junction (TJ) LED is required if conventional n-GaN substrates are used. This particular embodiment uses bottom-TJ homojunction LEDs, which have been shown to outperform standard top-TJ LEDs in terms of wall-plug efficiency with n-i-n vertical n-FETs on top, (see, International Publication No, WO2019/152611A1, entitled PLATFORMS ENABLED BY BURIED TUNNEL JUNCTION FOR INTEGRATED PHOTONIC AND ELECTRONIC SYSTEMS, published on Aug. 8, 2019, Shyam Bharadwaj et al., Enhanced injection efficiency and light output in bottom tunnel junction light-emitting diodes, Opt. Express, Vol. 28, No. 4, Feb. 17, 2020, Henryk Turski et al., Polarization control in nitride quantum well light emitters enabled by bottom tunnel-junctions, J. Appl. Phys. 125, 203104 (2019), all of which are incorporated by reference herein in their entirety and for all purposes) as shown in
In the embodiment shown in
Referring to
In some embodiments, the one or more nanopillars or nanowires are at least two one or more nanopillars or nanowires. The two or more nanopillars or nanowires include two groups of nanopillars or nanowires. In one instance, each one of the groups of nanopillars or nanowires surrounds a portion of a perimeter of an opening 185. The opening avoids reflection and absorption of the light generated by the LED quantum wells. The large electron conductivity of the n+GaN 20 allows the current to spread laterally and allows for uniform emission. In another instance, the third ohmic contact 120 has another opening, an area of the other opening, in the third ohmic contact 120, substantially includes an area of the opening 185. The opening in the third ohmic contact 120 allows better collection of light from the backside of the device.
The diameter of the nanowire or width of the fin FET 90 range from about 400 nm to about 2 μm to allow for significant modulation of the drain-source current by field-effect whilst simultaneously allowing large electron current for high output power from the LED.
The deposition of one embodiment of the device of these teachings is described hereinbelow. It should be noted that these teachings are not limited only to this embodiment.
The light-emitting FET (LEFET) structure was grown by plasma-assisted molecular beam epitaxy (PAMBE) in a single growth on a free standing Lumilog bulk n-type GaN substrate with a dislocation density of 107 cm−2. The growth was performed using a Nitrogen RF plasma power of 400 W, corresponding to a growth rate of 420 nm/hr. During growth, reflection high-energy electron diffraction (RHEED) was used to confirm a metal-rich growth condition, which promotes 2D growth in PAMBE.
One embodiment of the epitaxial layer structure for the sample is shown in
Optical microscope images after the MBE growth showed Ga metal droplets on the surface, confirming the metal rich growth condition. After removing the droplets with HCl, structural characterization was then performed through x-ray diffraction (XRD) and atomic force microscopy (AFM), with the results shown in
After device processing, electrical and optical measurements were performed, with results for a 500 nm×50 μm single-fin depletion-mode device shown in
The measured electroluminescence (EL) spectra are shown in
For the embodiment shown in
For visible light communications, switching speed is an important parameter that dictates data transmission rates. The optical switching speed of the device was measured by switching VG with VDS fixed at 10 V, and tracking the output signal from a photodiode placed directly underneath the device using an oscilloscope. A square voltage pulse with a duty cycle of 50% was used as the input signal on the gate, with the frequency varied between 1 kHz and 100 kHz. The input electrical signal (square wave-black) and output photodiode voltage signal (thinner) are shown in
It should be noted that the device geometry need not change for different wavelengths—the same design should work fine for extracting light at any wavelength in the IR, visible, or UV range. For different wavelength emitters, the material compositions in the structure would have to change, but the fabrication method would stay very similar. Visible wavelengths between ˜400 nm and 600 nm can be achieved by simply changing the indium composition in the quantum wells, while leaving the processing substantially the same. One exception is that for some materials (i.e., deep UV emitter materials), conducting substrates are not available. Because of that, the drain contact, which in the above design is on the backside of the substrate, would have to be on the etched n-GaN epi-surface (where the gate pad is, but not separated from the n+GaN by oxide). This would simply require doing the drain metal deposition earlier in the process. For deep UV emitters, the GaN would be replaced by AlGaN, but the metallizations and etch chemistry are substantially identical for AlGaN, InGaN, and GaN.
A technique for achieving monolithic integration of n-FETs and LEDs, using vertical fin- and nanowire-FETs and bottom tunnel junction planar LEDs has been demonstrated in these teachings. This platform allows for strong gate control (about 5 orders of magnitude on/off for ID) without limiting the on-wafer LED active area and does not require regrowth. Optical switching behavior up to 30 kHz was demonstrated in the initial embodiments, with improvement possible through use of InGaN heterojunction TJs. The LEFET device geometry can be easily modified for light extraction from the surface without sacrificing significant wafer area by patterning the top source contact. Such devices are promising for use in Li-Fi communications and in micro-LED displays, in which gate voltage controllability along with utility of space are important parameters.
For the purpose of better describing and defining the present teachings, it is noted that terms of degree (e.g., “substantially,” “about,” and the like) may be used in the specification and/or in the claims. Such terms of degree are utilized herein to represent the inherent degree of uncertainty that may be attributed to any quantitative comparison, value, measurement, and/or other representation. The terms of degree may also be utilized herein to represent the degree by which a quantitative representation may vary (e.g., ±10%) from a stated reference without resulting in a change in the basic function of the subject matter at issue.
International application WO 2020/096838, published on May 14, 2020, is incorporated by reference herein in its entirety and for all purposes.
Although the teachings have been described with respect to various embodiments, it should be realized these teachings are also capable of a wide variety of further and other embodiments within the spirit and scope of the appended claims.
Claims
1. A light emitting FET structure comprising:
- a substrate having a first surface opposite a second surface;
- one or more layers of n doped III-nitride material disposed on the first surface of the substrate
- a sub-structure comprising: a tunnel junction disposed on at least a portion of the one or more layers of n doped III-nitride material; a p-type III-nitride layer formed directly on the tunnel junction; an active layer comprising one or more III-nitride quantum wells disposed on the p-type III-nitride layer; and one or more other layers of n-doped III-nitride material disposed on the active layer;
- a layer of unintentionally doped III-nitride material disposed on the one or more other layers of n-doped III-nitride material of the sub-structure; the layer of unintentionally doped III-nitride material being patterned into one or more nanopillars or nanowires;
- a further layer of n-doped III-nitride material disposed on the one or more nanopillars or nanowires;
- an insulating layer disposed on at least one of (a) surfaces of the nanopillars or nanowires extending from below the further layer of n-doped III-nitride material to said one or more other layers of n-doped III-nitride material not covered by the unintentionally doped III-nitride material, also on a surface of the one or more other layers of n-doped III-nitride material not covered by the unintentionally doped III-nitride material or (b) disposed along the sub-structure from the one or more other layers of n-doped III-nitride material to said at least one portion of the one or more layers of n doped III-nitride material;
- a metal layer disposed over the insulating layer on at least one of (i) along the one or more nanopillars or nanowires, (ii) on a portion of a surface of the one or more other layers of n-doped III-nitride material, the layer of unintentionally dope III-nitride material being disposed on said surface, the portion being the portion on which the layer of unintentionally dope III-nitride material is not disposed, or (iii) disposed along the insulator layer that is disposed along the sub-structure from the one or more other layers of n-doped III-nitride material to said at least one portion of the one or more layers of n doped III-nitride material;
- a first ohmic contact layer disposed on a portion of said metal layer; and
- a second ohmic contact layer disposed on said further layer of n-doped III-nitride material.
2. The light emitting FET structure of claim 1 wherein the active layer including at least one quantum well.
3. The light emitting FET structure of claim 1 wherein the active layer is a light emitting layer.
4. The light emitting FET structure of claim 1 wherein the substrate is conducting; the light emitting FET structure further comprising a third ohmic contact disposed on the second surface of the substrate.
5. The light emitting FET structure of claim 1 comprising another portion of the one or more layers of n-doped III-nitride material, the tunnel junction not being disposed on said another portion of the one or more layers of n-doped III-nitride material;
- the insulating layer being also disposed on said another portion of the one or more layers of n doped III-nitride material;
- the metal layer being disposed along the insulator layer that is disposed along the sub-structure from the one or more other layers of n-doped III-nitride material to said at least one portion of the one or more layers of n doped III-nitride material;
- the metal layer also being disposed on the insulating layer that is disposed on at least part of said another portion of the one or more layers of n doped III-nitride material.
6. The light emitting FET structure of claim 5 wherein in the substrate is a metal (Ill)-polar Ill-nitride substrate.
7. The light emitting FET structure of claim 5 wherein the first ohmic contact layer is disposed on the portion of said metal layer that is disposed on a portion of the insulating layer, the portion of the insulating layer being disposed on said another portion of the one or more layers of n doped III-nitride material.
8. The light emitting FET structure of claim 5 further comprising another ohmic contact disposed on an outer area of the one or more other layers of n-doped III-nitride material not covered by the unintentionally doped III-nitride material; the insulating layer being also disposed over said another ohmic contact.
9. The light emitting FET structure of claim 8 wherein the one or more nanopillars or nanowires comprise at least two one or more nanopillars or nanowires; the two or more nanopillars or nanowires comprising two groups of nanopillars or nanowires; each one of the groups of nanopillars or nanowires surrounding a portion of a perimeter of an opening.
10. The light emitting FET structure of claim 8 further comprising a third ohmic contact disposed on the second surface of the substrate.
11. The light emitting FET structure of claim 10 wherein the third ohmic contact comprises another opening, an area of said another opening substantially comprising an area of said opening.
12. A method for forming an LE FET, the method comprising:
- epitaxially depositing one or more layers of n doped III-nitride material on a first surface of a substrate;
- epitaxially forming a substructure on the one or more layers of the n doped III-nitride material; the substructure comprising: a tunnel junction disposed on at least a portion of the one or more layers of n doped III-nitride material; a p-type III-nitride layer formed directly on the tunnel junction; an active layer comprising one or more III-nitride quantum wells disposed on the p-type III-nitride layer; and one or more other layers of n-doped III-nitride material disposed on the active layer;
- epitaxially depositing a layer of unintentionally doped III-nitride material on the substructure;
- epitaxially depositing a further layer of n doped III-nitride material on the layer of unintentionally doped III-nitride material;
- patterning the further layer of n doped III-nitride material and the layer of unintentionally doped III-nitride material into one or more nano-pillars or nano-wires;
- depositing, after patterning, an ohmic contact on the further layer of n doped III-nitride material;
- patterning the substructure into a mesa on a portion of the one or more layers of the n doped III-nitride material;
- depositing an insulating layer on surfaces of the one or more nano-pillars or nano-wires extending from below the further layer of n-doped III-nitride material to said one or more other layers of n-doped III-nitride material not covered by the unintentionally doped III-nitride material, also on a surface of the one or more other layers of n-doped III-nitride material not covered by the unintentionally doped III-nitride material, along the substructure from the one or more other layers of n-doped III-nitride material to said at least one portion of the one or more layers of n doped III-nitride material, and another portion of the one or more layers of n doped III-nitride material on which the mesa is not disposed;
- depositing a metal layer along the insulator layer that is disposed along the substructure from the one or more other layers of n-doped III-nitride material to said at least one portion of the one or more layers of n doped III-nitride material and on the insulating layer that is disposed on said another portion of the one or more layers of n doped III-nitride material; and
- depositing another ohmic contact on the metal layer.
13. The method of claim 12 wherein the substrate is conducting; the method further comprising:
- depositing a third ohmic contact on a second surface of the substrate; and
- patterning an aperture on the third ohmic contact in order to facilitate collection of light.
14. The method of claim 12 further comprising:
- depositing, after depositing said another ohmic contact on the metal layer, another insulating material in order to isolate components.
15. The method of claim 12 further comprising:
- depositing an ohmic contact pad on the ohmic contact on the further layer of n doped III-nitride material.
16. The method of claim 12 further comprising depositing, before the depositing of the insulating layer, a further other ohmic contact on an outer area of the one or more other layers of n-doped III-nitride material not covered by the unintentionally doped III-nitride material; the insulating layer being also disposed over said further other ohmic contact.
17. The method of claim 16 wherein the metal layer is also deposited on the insulating material on surfaces of the one or more nano-pillars or nano-wires extending from below the further layer of n-doped III-nitride material to said one or more other layers of n-doped III-nitride material not covered by the unintentionally doped III-nitride material and on the insulating material over said further other ohmic contact.
18. The method of claim 17 further comprising:
- depositing, after depositing said another ohmic contact on the metal layer, another insulating material in order to isolate components.
19. The method of claim 18 further comprising:
- depositing an ohmic contact pad on the ohmic contact on the further layer of n doped III-nitride material.
20. The light emitting FET structure of claim 1 wherein the substrate is non-conducting;
- the light emitting FET structure further comprising a third ohmic contact disposed on the one or more layers of n doped III-nitride material.
Type: Application
Filed: Jul 13, 2021
Publication Date: Jun 22, 2023
Applicant: Cornell University (Ithaca, NY)
Inventors: Shyam Bharadwaj (Ithaca, NY), Kevin Lee (Ithaca, NY), Kazuki Nomoto (Ithaca, NY), Austin Hickman (Hickman, NY), Len van Deurzen (Ithaca, NY), Huili Grace Xing (Ithaca, NY), Debdeep Jena (Ithaca, NY), Vladimir Protasenko (Ithaca, NY)
Application Number: 18/016,334