Inorganic Silicon Compound, E.g., Diatomaceous Earth, Soil, Glass, Sand, Etc., Or Material Derived Therefrom Patents (Class 106/482)
  • Patent number: 5858906
    Abstract: Compacts produced from a pyrogenically produced oxide, magnesium stearate, methyl cellulose and urea are mixed together in the presence of water, compacted, dried, comminuted to a powder, and the powder is pressed with an isostatic press to compacts and the compacts tempered. The resulting compacts have an outside diameter of 16 to 100 mm.
    Type: Grant
    Filed: August 1, 1995
    Date of Patent: January 12, 1999
    Assignee: Degussa Aktiengesellschaft
    Inventors: Klaus Deller, Helmfried Krause, Roland Burmeister
  • Patent number: 5846310
    Abstract: Spherical SiO.sub.2 particles with a size of from 5 to 500 nm coated at individual points with TiO.sub.2, Fe.sub.2 O.sub.3 or ZrO.sub.2 particles with a size of less than 60 nm. The coated SiO.sub.2 particles can be aftercoated with silanes or further metal oxides. The products obtained are used for pigmenting paints, printing inks, plastics and coatings or as sunscreen agents.
    Type: Grant
    Filed: April 21, 1997
    Date of Patent: December 8, 1998
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Tamio Noguchi, Kazhisa Iwasa, Ralf Anselmann, Martin Knapp, Manuela Loch
  • Patent number: 5833746
    Abstract: A silica filler containing from 30 to 90 wt % of particles having a particle size of at least 30 .mu.m, wherein the roundness of the particles having a particle size of at least 30 .mu.m, is from 0.83 to 0.94.
    Type: Grant
    Filed: September 15, 1997
    Date of Patent: November 10, 1998
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Mitsuyoshi Iwasa, Yukio Sakaguchi, Hirofumi Simazoe
  • Patent number: 5827363
    Abstract: A method for preparing precipitated silicates and silicas having good high shear rheology in high solids aqueous slurries. Destructuring of aluminum silicate and silica via dry milling results in decreasing DBP oil absorption. The destructured materials are useful for ink jet coating formulations.
    Type: Grant
    Filed: December 17, 1996
    Date of Patent: October 27, 1998
    Assignee: Degussa Corporation
    Inventors: Michael S. Darsillo, Sturgis Gregg Allen
  • Patent number: 5800608
    Abstract: The invention relates to a new process for the preparation of precipitated silica which has an excellent dispersibility and very satisfactory reinforcing properties. It also relates to new precipitated silicas which are in the form of powder, of substantially spherical beads or of granules, these silicas being characterized by the fact that they have a CTAB specific surface of between 140 and 200 m.sup.2 /g, a BET specific surface of between 140 and 200 m.sup.2 /g, a DOP oil uptake lower than 300 ml/100 g, a median diameter, after disintegration with ultrasound, smaller than 3 .mu.m, an ultrasonic disintegration factor higher than 10 ml and an aluminium content of at least 0.35% by weight. The invention also relates to the use of the said silicas as reinforcing fillers for elastomers.
    Type: Grant
    Filed: March 3, 1997
    Date of Patent: September 1, 1998
    Assignee: Rhone-Poulenc Chimie
    Inventors: Yves Bomal, Yvonick Chevallier, Philippe Cochet
  • Patent number: 5776240
    Abstract: Granules based on silicon dioxide and having the properties:Average particle size: 10 to 120 .mu.mBET surface area: 40 to 400 m.sup.2 /gPore volume: 0.5 to 2.5 ml/gPore size distribution: less than 5% of the total pore volume exists of pores with a diameter<5 nm, remainder are meso- and macroporespH value: 3.6 to 8.5Tapped density: 220 to 700 g/lThey are prepared by dispersing silicon dioxide in water, spray drying, and optionally heating and/or silanizing. The granules can be used as catalyst supports.
    Type: Grant
    Filed: February 5, 1996
    Date of Patent: July 7, 1998
    Assignee: Degussa Aktiengesellschaft
    Inventors: Klaus Deller, Helmfried Krause, Juergen Meyer, Dieter Kerner, Hans Lansink-Rotgerink, Werner Hartmann
  • Patent number: 5766336
    Abstract: Colored pigments are provided from the green-yellow to red spectrum based on oxide-nitrides with two or three different cations Q, R and S in the crystal lattice, wherein the nitrogen to oxygen atomic ratio is determinative for the color. These pigments crystallise in the pyrochlore, spinel or elpasolite structure. Pigments in the perovskite are as provided with increased color brilliance. The color of the pigments can be adjusted in a wide range of the color spectrum during their preparation within a substance class with the cations Q, R and S and while retaining the crystal structure, by increasing or lowering the atomic ratio N to O in the oxide-nitride and bringing about the required charge balancing by replacing an equivalent quantity of the cation Q with the valency q by a cation R with the valency q+1.
    Type: Grant
    Filed: August 21, 1995
    Date of Patent: June 16, 1998
    Assignee: Cerdec Aktiengesellschaft Keramische Farben
    Inventors: Martin Jansen, Hans-Peter Letschert
  • Patent number: 5753371
    Abstract: A pearlescent pigment consists essentially of C glass flakes having a layer comprising rutile titanium dioxide or iron oxide thereon. A hydrous layer of the rutile forming titanium dioxide or iron oxide is formed on the glass flakes and the resulting coated flakes are calcined.
    Type: Grant
    Filed: June 3, 1996
    Date of Patent: May 19, 1998
    Assignee: The Mearl Corporation
    Inventors: William J. Sullivan, Patricia Elliot, Dana Fleming
  • Patent number: 5753026
    Abstract: Reaction spray process for preparing inclusion pigments by suspending the pigment to be encapsulated in an aqueous solution or suspension of a precursor of the inclusion material, spraying the suspension, with or without the addition of nitric acid and fuel, in a tubular reactor heated at from 850.degree. to 1100.degree. C., separating the inclusion pigment from the product stream and, if desired post-calcining the pigment at a temperature of at least 816.degree. C.
    Type: Grant
    Filed: October 21, 1996
    Date of Patent: May 19, 1998
    Assignee: Merck Patent Gesellschaft mit Beschrankter Haftung
    Inventors: Mathias Kuntz, Hubert Linne, Joachim Weitzel, Dieter Heinz, Rodney Riddle
  • Patent number: 5747003
    Abstract: A statistically large population of particles of amorphous precipitated silica comprising pigmentary phase particles and glassy phase particles and having a glassy phase fraction in the range of from 0.3 to 30 area percent is useful as an abrasive for dentifrice compositions, especially toothpaste.
    Type: Grant
    Filed: March 22, 1995
    Date of Patent: May 5, 1998
    Assignee: PPG Industries, Inc.
    Inventors: Shantilal M. Mohnot, Harold E. Swift, Thomas G. Krivak, Robert H. Fear, Laura M. Randall, Laurence E. Jones
  • Patent number: 5720806
    Abstract: The invention provides a filler for ink jet recording paper which is composed of an amorphous silica containing 0.3-1.0% by weight of Al.sub.2 O.sub.3 and having a BET specific surface area of 250-400 m.sup.2 /g, a mean particle size of 3.6-10.0 .mu.m and a peak position of pore radius as measured by mercury injection method of 37.5-75 angstrom. A coat layer of ink jet recording paper formed of this filler excels not only in true circle property of dots and ink absorbing property when printed by ink jet recording system, but also in surface strength and writing quality. Furthermore, the coating liquid containing this filler has a low viscosity and hence exhibits good coating workability.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: February 24, 1998
    Assignee: Tokuyama Corporation
    Inventors: Tsuneo Fujii, Hiroshi Tonoike, Daisaku Isomura
  • Patent number: 5707440
    Abstract: A finely divided inorganic filler material is a sintered composite which consists of larger macro-filler particles of glass and of smaller micro-filler particles of glass or ceramics partially covering the macro-filler particle and firmly connected to it by sintering. Plastic materials reinforced with the filler are distinguished by improved abrasion resistance.
    Type: Grant
    Filed: October 7, 1994
    Date of Patent: January 13, 1998
    Assignee: Heraeus Kulzer GmbH
    Inventors: Xu Hengchang, Joachim Nagel
  • Patent number: 5707439
    Abstract: Novel silicate minerals that have undergone a cation exhange with at least one heteroaromatic cation comprising a positively charged organo-substituted heteroatom and/or at least one positively charged heteroatom not part of an aromatic ring with at least one bond having a bond order greater than one and compositions comprising the same are described.
    Type: Grant
    Filed: December 18, 1995
    Date of Patent: January 13, 1998
    Assignee: General Electric Company
    Inventors: Tohru Takekoshi, Farid Fouad Khouri, John Robert Campbell, Therese Coste Jordan, Kevin Hsingtao Dai
  • Patent number: 5647903
    Abstract: Precipitated silicas having wet cake moisture values in excess of 85%, BET surface areas of 600-700 m.sup.2 /g, oil absorption values of 50 to 60 cc/100 g, total intruded volume of about 1.2 to 0.8 cc/g, and a median pore radius of 50 .ANG. to 20 .ANG. are produced by a low temperature silica precipitation process. The silicas have unique flatting characteristics and are additionally useful as conditioning agents for food and salt and in dentifrice compositions.
    Type: Grant
    Filed: October 3, 1995
    Date of Patent: July 15, 1997
    Inventors: Patrick D. McGill, William Fultz
  • Patent number: 5637284
    Abstract: A rotating cylindrical quartz glass tube is partitioned into at least 3 chambers comprising a pre-heating chamber, a reaction chamber, and a gas desorption chamber. The process comprises pre-heating the starting quartz powder by continuously supplying it into the pre-heating chamber, refining the powder by transferring it into the reaction chamber in which the powder is brought into contact with a chlorine-containing gas atmosphere, and transferring the powder into the gas desorption chamber; the chambers may be partitioned using a sectioning plate having an opening. Alkali metal elements such as sodium and potassium, as well as transition metal elements such as iron, copper, chromium, and nickel are removed from a powder of naturally occurring quartz. The process also removes alkaline earth metal elements such as magnesium and calcium. Furthermore, it is of high productivity because it can be operated continuously to yield high purity quartz powder at a low cost.
    Type: Grant
    Filed: March 22, 1996
    Date of Patent: June 10, 1997
    Assignees: Heraeus Quarzglas GmbH, Shin-Etsu Quartz Products, Co., Ltd.
    Inventors: Tatsuhiro Sato, Hiroyuki Watanabe, Werner Ponto
  • Patent number: 5628932
    Abstract: An electroconductive composition comprising a two-dimensional network of antimony-containing tin oxide crystallites in association with amorphous silica, the composition according to one aspect of the invention comprising a powder of submicron to tens of micron size particles capable of forming a conductive network within a carrier matrix, such as a thin film matrix, and a process for preparing the composition.
    Type: Grant
    Filed: June 15, 1994
    Date of Patent: May 13, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Howard R. Linton
  • Patent number: 5605569
    Abstract: Particles comprising particulate amorphous precipitated silica in association with from 5 to 10 percent by weight sodium sulfate and less than 10 percent by weight water, wherein the percentages are based on the weight of the silica, the sodium sulfate, and the water, which particles have a BET surface area of from 100 to 300 m.sup.2 /g, a total intruded volume from 1.8 to 3.6 cm.sup.3 /g, and a DBP oil absorption of from 180 to 320 cm.sup.3 /100 g, may be employed in microporous battery separators to introduce all or a portion of the desired sodium sulfate to the battery electrolyte. Moreover the enhanced amount of sodium sulfate enhances silica characteristics and battery separator production.
    Type: Grant
    Filed: November 8, 1995
    Date of Patent: February 25, 1997
    Assignee: PPG Industries, Inc.
    Inventors: James L. Boyer, Thomas G. Krivak, Harold E. Swift, Robert C. Wang
  • Patent number: 5591797
    Abstract: The transition metal-containing hydrophobic silica has a BET specific surface area of 40 to 450 m.sup.2 /g, a carbon content, obtained by the imparting of hydrophobic properties, of at least 0.5% by weight and a transition metal content of 10 to 10,000 ppm by weight. The hydrophobic silica is used as a heat stabilizer in addition-crosslinking 2-component silicone rubber materials.
    Type: Grant
    Filed: October 21, 1994
    Date of Patent: January 7, 1997
    Assignee: Wacker-Chemie GmbH
    Inventors: Herbert Barthel, Frank Achenbach
  • Patent number: 5585037
    Abstract: An electroconductive composition comprising a two-dimensional network of antimony-containing tin oxide crystallites in association with amorphous silica, the composition according to one aspect of the invention comprising a powder of submicron to tens of micron size particles capable of forming a conductive network within a carrier matrix, such as a thin film matrix, and a process for preparing the composition.
    Type: Grant
    Filed: August 2, 1989
    Date of Patent: December 17, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Howard R. Linton
  • Patent number: 5578120
    Abstract: A laser beam absorbing resin composition is disclosed which includes 100 parts by weight of a resin, and 1-100 parts by weight of composite particles having an average particle diameter of 0.1-50 .mu.m and each including a particulate, laser beam absorbing inorganic substance, and a colorant physically bonded directly to the inorganic substance and capable of discoloring upon being heated at a temperature of 250.degree. C. or more, the weight ratio of the colorant to the inorganic substance being in the range of 1:99 to 50:50. By irradiating a shaped, hardened body of the above composition with a laser beam, the colorant is thermally decomposed, so that the color of the irradiated surface is changed and becomes discriminative from that of non-irradiated surface.
    Type: Grant
    Filed: February 15, 1996
    Date of Patent: November 26, 1996
    Assignee: Somar Corporation
    Inventors: Jun Takahashi, Masaaki Toyoda, Akira Yasuda, Hideo Ochi
  • Patent number: 5575957
    Abstract: The invention provides acicular electroconductive tin oxide fine particles which has a mean diameter of 0.005-1 .mu.m and a mean length of 0.05-10 .mu.m and an aspect ratio of 3 or higher. The invention further provides a process for producing the acicular electroconductive tin oxide fine particles, which comprises firing a starting material containing tin, silicon and an alkali metal halide at 700.degree.-1200.degree. C. and removing soluble salts from the resulting fired product.
    Type: Grant
    Filed: December 22, 1995
    Date of Patent: November 19, 1996
    Assignee: Ishihara Sangyo Kaisha, Ltd.
    Inventors: Haruo Okuda, Hideo Futamata, Hideo Takahashi, Norihiko Sanefuji
  • Patent number: 5532063
    Abstract: A silicon oxide depositing source is a mixture of a metallic silicon powder and a silicon dioxide powder. Both the powders are finely divided to a mean particle size of up to 20 .mu.m. They are mixed to give an oxygen to silicon atom ratio between 1.2:1 and 1.7:1. The source is adapted to be evaporated by an electron beam heating technique, allows the power of an electron beam to be increased without a splash phenomenon, and eventually deposits a silicon oxide thin film having transparency and improved barrier properties.
    Type: Grant
    Filed: July 15, 1994
    Date of Patent: July 2, 1996
    Assignees: Shin-Etsu Chemical Co., Ltd., Nihon Shinku Gijutsu Kabushiki Kaisha
    Inventors: Toshihiko Shindoh, Takeshi Kakegawa, Kazuhiko Urano, Toshimasa Okamura, Tetsuo Suzuki, Masatoshi Sato
  • Patent number: 5484454
    Abstract: Particulate adsorbents composed of inorganic oxides impregnated with an indicator dye selected from the group consisting of phenolphthalein, cresol red and thymol blue; a method for the production thereof, and a method for adsorptive drying of neutral gases using the aforementioned particulate adsorbents, whereby the degree of water absorption by the adsorbent particles is indicated by a reversible color change.
    Type: Grant
    Filed: October 5, 1994
    Date of Patent: January 16, 1996
    Assignee: Engelhard Process Chemicals GmbH
    Inventors: Kirsten Furhmann, Alf-Eric Wischnat, Thomas Schulz, Michael Hoffmeister
  • Patent number: 5480480
    Abstract: An improved polyurethane-based water-in-water multicolor paint composition is provided having a disperse phase and a continuous phase which is characterized by disperse phase bodies of improved durability. The disperse phase preferably is comprised of a water dispersible, inert film-forming, crosslinkable polymer system; hydroxy (lower alkyl) cellulose; alkali metal carboxy (lower alkyl) cellulose; quaternized water soluble cellulose ether; peptized clay; inorganic salt of heavy or trivalent metal; and water. The continuous phase preferably is comprised of such a crosslinkable polymer system, a peptized clay and water. Methods for preparing the paint are also provided.
    Type: Grant
    Filed: June 7, 1994
    Date of Patent: January 2, 1996
    Assignee: Multicolor Specialties, Inc.
    Inventors: James F. Lynch, John Predkelis
  • Patent number: 5472493
    Abstract: A novel and improved surfactant modified silica and method for making the same. The surfactant modified silica is characterized as a fumed silica having a surfactant material treated therewith. Also disclosed is process of thickening aqueous systems which includes the addition of an effective amount of a fumed silica having a surfactant material treated therewith.
    Type: Grant
    Filed: January 9, 1995
    Date of Patent: December 5, 1995
    Assignee: Cabot Corporation
    Inventor: David M. Regan
  • Patent number: 5472640
    Abstract: The application relates to conductive lamellar pigments in which lamellar substrate is coated with an electrically conductive layer, characterized in that a lamellar metal oxide or a lamellar material coated with one or more metal oxides is present as the lamellar substrate and that an optionally hydrated silicon dioxide layer or a layer of another insoluble silicate is arranged between the metal oxide layer and the conductive layer.
    Type: Grant
    Filed: April 22, 1994
    Date of Patent: December 5, 1995
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Hans D. Bruckner, Reiner Esselborn
  • Patent number: 5453212
    Abstract: The invention concerns a powdery, hydrophobic filler for bituminized traffic surfaces, including at least one substance that lowers the freezing point of water.
    Type: Grant
    Filed: May 4, 1994
    Date of Patent: September 26, 1995
    Assignees: ChemischeFabrik Gruenau GmbH, Mannesmann Aktiengesellschaft
    Inventors: Dieter Annemaier, Stefan Keipl, Wilhelm Kaemereit, Oskar Schmitt
  • Patent number: 5447604
    Abstract: Silica sols which have a large alkali excess, i.e. a low molar ratio SiO.sub.2 to M.sub.2 O, and which contain silica particles with a high specific surface area. The silica sols can be prepared through acidification of a water glass solution and subsequent alkalization of the acid sol to the molar ratio in question. The sols are particularly suitable for use as additives, in combination with cationic polymers, in papermaking.
    Type: Grant
    Filed: May 8, 1992
    Date of Patent: September 5, 1995
    Assignee: Eka Nobel AB
    Inventors: Hans E. Johansson, Bo V. Larsson
  • Patent number: 5441564
    Abstract: The invention relates to a pigment mixture containing a component A composed of at least one platelet-shaped interference pigment and a pigment B composed of at least one platelet-shaped color pigment.
    Type: Grant
    Filed: December 2, 1993
    Date of Patent: August 15, 1995
    Assignee: Merck Patent Gesellschaft mit Beschrankter Haftung
    Inventor: Reiner Vogt
  • Patent number: 5437719
    Abstract: An improved polyurethane-based water-in-water multicolor paint composition is provided having a disperse phase and a continuous phase which is characterized by an accelerated capacity to transfer from an applicator surface to a substrate surface during paint application. The disperse phase preferably is comprised of a water dispersible, inert film-forming, crosslinkable, polyurethane polymer system; hydroxy (lower alkyl) cellulose; quaternized water soluble cellulose ether; peptized clay and water. The continuous phase preferably is comprised of such a polyurethane polymer system, a water soluble, film-forming, crosslinkable, pressure-responsive contact adhesive, a peptized clay and water. Methods for preparing the paint are also provided.
    Type: Grant
    Filed: June 7, 1994
    Date of Patent: August 1, 1995
    Assignee: Multicolor Specialties, Inc.
    Inventors: James F. Lynch, John Predkelis
  • Patent number: 5401309
    Abstract: Novel colorant/pigment compositions, prepared via precipitation technique and well suited for the coloration of a wide variety of materials and substrates, e.g., plastics, paints and inks, ceramics, cosmetics, etc., comprise composite core/sheath particulates, the cores of which comprising particles of at least one crystalline rare earth metal sesquisulfide having the formula M.sub.2 S.sub.3 in which M is at least one lanthanide element having an atomic number of from 57 to 71, or yttrium, and such core particles having at least one alkali and/or alkaline earth metal dopant at least in part incorporated within the crystal lattice of the at least one crystalline rare earth metal sesquisulfide, and each sheath comprising a coating layer of at least one transparent oxide deposited onto the external face surfaces of the doped core particles.
    Type: Grant
    Filed: April 18, 1994
    Date of Patent: March 28, 1995
    Assignee: Rhone-Poulenc Chimie
    Inventors: Thierry Chopin, Dominique Dupuis
  • Patent number: 5393716
    Abstract: There is disclosed a process for preparing a filler composition suitable for incorporation in a polyester film-forming material, which process comprises the following steps:(a) calcining a crude kaolin clay under conditions such that the calcined product comprises particles consisting of aggregates of fine kaolin platelets;(b) suspending the calcined clay product from step (a) in water containing a dispersing agent for the calcined clay, so as to form a suspension containing from 40% to 70% by weight of dry calcined clay;(c) subjecting the suspension formed in step (b) to comminution by attrition grinding with a particulate grinding medium for a time sufficient to reduce the average diameter of the aggregate particles to within the range from 0.3 .mu.m to 0.9 .mu.m, and to ensure that the calcined clay is substantially free of particles having an equivalent spherical diameter larger than 5 .mu.
    Type: Grant
    Filed: September 24, 1993
    Date of Patent: February 28, 1995
    Assignee: ECC International Limited
    Inventors: David L. Light, Christopher D. Paynter
  • Patent number: 5380359
    Abstract: A melanin-coated pigment obtained by coating a carrier with a readily alkali-soluble natural melanin, and a cosmetic containing the pigment are provided. The melanin-coated pigment is highly safe and has high coloring and high saturation tone, and a cosmetic which contains it is also expected to have ultraviolet-ray-absorbing and anti-oxidizing effects.
    Type: Grant
    Filed: November 24, 1993
    Date of Patent: January 10, 1995
    Assignee: Kyowa Hakko Kogyo Co., Ltd.
    Inventors: Shinkichi Honda, Yoichiro Takekoshi, Yoichiro Arai
  • Patent number: 5362322
    Abstract: A multi-component settable epoxy blend for setting and grouting of ceramic tiles, pavers and quarry tiles, the first component comprising an epoxy resin and the second component comprising an epoxy hardener wherein one of the first or second components has a plurality of subcomponents, at least two of the subcomponents further comprising a color pigment additive which defines the same or different colors so that when the subcomponents are combined they produce a grout having a specific color shade selected by the user.
    Type: Grant
    Filed: December 17, 1990
    Date of Patent: November 8, 1994
    Assignee: C-Cure Chemical Company, Inc.
    Inventors: Charles J. Johansen, Jr., Robert L. Vecchio, Ernest D. Hollas
  • Patent number: 5358560
    Abstract: Solid form additive systems which are dispersible in aqueous media are disclosed, as are methods for preparing such additive systems. The additive systems are dry, free-flowing particulate materials that contain at least one additive component, at least one tackifying agent, and at least one surfactant.
    Type: Grant
    Filed: October 4, 1991
    Date of Patent: October 25, 1994
    Assignee: Eastman Chemical Company
    Inventors: Brenda J. Hitch, Mahendra K. Sharma, Leo P. Voetgli
  • Patent number: 5350448
    Abstract: A process for the preparation of light-colored, electrically conductive pigments based on substrates having an expansion of not more than 500 .mu.m, which pigments consist of one or more metals, metal oxides or materials containing metal oxide, silicon oxide or silicate materials and contain, if desired above one or more other metal oxide and/or silicon oxide layers, an outer layer based on halogen-doped tin oxide and/or titanium oxide.
    Type: Grant
    Filed: April 22, 1993
    Date of Patent: September 27, 1994
    Assignee: Merck Patent Gesellschaft Mit Beschrankter Haftung
    Inventors: Johann Dietz, Klaus Franz, Gerhard Pfaff, Reiner Vogt, Katsuhisa Nitta
  • Patent number: 5344489
    Abstract: A method of making synthetic color pigments comprises synthesizing monodispersed colloidal core particles by precipitation from a solution and applying dye material to the core particles either by adsorption directly into the core particles or by adsorption or incorporation into alumina fixation shells at the surfaces of the core particles. Additional functional shells may be applied to the dyed core particles for various reasons. The pigments are useful for the coloration of various media such as printing inks and paint compositions.
    Type: Grant
    Filed: November 15, 1991
    Date of Patent: September 6, 1994
    Assignee: Manfred R. Kuehnle
    Inventors: Egon Matijevic, Wan P. Hsu, Manfred R. Kuehnle
  • Patent number: 5326395
    Abstract: A silica matting agent has a wax coating comprising a mixture of three waxes, i.e. hard microcrystalline, plasticising monocrystalline and synthetic polyethylene. The use of this ternary mixture gives the matting agent improved interaction with lacquers and improved sedimentation.
    Type: Grant
    Filed: November 6, 1992
    Date of Patent: July 5, 1994
    Assignee: Unilever Patent Holdings B.V.
    Inventors: Derek Aldcroft, Ian P. McKeown, Bryan Rogers, Peter W. Stanier
  • Patent number: 5318619
    Abstract: An improved polyurethane-based water-in-water multicolor paint composition is provided having a disperse phase and a continuous phase which is characterized by an accelerated capacity to transfer from an applicator surface to a substrate surface during paint application. The disperse phase preferably is comprised of a water dispersible, inert film-forming, crosslinkable, polyurethane polymer system; hydroxy (lower alkyl) cellulose; quaternized water soluble cellulose ether; peptized clay and water. The continuous phase preferably is comprised of such a polyurethane polymer system, a water soluble, film-forming, crosslinkable, pressure-responsive contact adhesive, a peptized clay and water. Methods for preparing the paint are also provided.
    Type: Grant
    Filed: April 6, 1993
    Date of Patent: June 7, 1994
    Assignee: Multicolor Specialties, Inc.
    Inventors: James F. Lynch, John Predkelis
  • Patent number: 5314535
    Abstract: A polyurethane-based water-in-water multicolor paint composition is provided having a disperse phase and a continuous phase. The disperse phase contains a water dispersible, film-forming, crosslinkable, polymer system selected from among a polyurethane polymer system, a carboxylated polymer system, and mixtures thereof; as well as hydroxy (lower alkyl) cellulose, quaternized water soluble cellulose ether, peptized clay, and water. The continuous phase preferably is comprised of a polyurethane polymer system, a peptized clay and water. Methods for preparing the paint are also provided.
    Type: Grant
    Filed: April 6, 1993
    Date of Patent: May 24, 1994
    Assignee: Multicolor Specialties, Inc.
    Inventors: James F. Lynch, John Predkelis
  • Patent number: 5304242
    Abstract: A colour developing composition for use in pressure-sensitive (carbonless) copying paper sets comprises an inorganic pigment extender (e.g. kaolin, talc or calcined kaolin) and a hydrated silica/hydrated alumina composite. The composition is produced by precipitating the hydrated silica/hydrated alumina composite in the presence of the extender by the following steps:a) gradually adding a metal silicate solution to a solution of an aluminium salt which is initially at a pH below 4 until the pH of the resulting mixture is approximately 4, thereby to induce some precipitation and to form a sol;b) gradually adding alkali to said sol to raise the pH to approximately 7, thereby to induce further precipitation and gel the sol or further gel the sol, said gelled sol being a hydrated silica/hydrated alumina composite;c) separating the resulting product from the aqueous medium and washing to remove dissolved salts; andd) drying the washed product and reducing it in particle size.
    Type: Grant
    Filed: May 13, 1992
    Date of Patent: April 19, 1994
    Assignee: The Wiggins Teape Group Limited
    Inventor: David J. Taylor
  • Patent number: 5304241
    Abstract: A filler to be dispersed, as an inorganic material, in a thermosetting resin to produce an electronic component sealing agent, is composed of crystalline silicon dioxide particles. Not less than 70 wt-% of the crystalline silicon dioxide particles have the major-to-minor-axis ratio in the range of 1.20-1.40 and the circularity in the range of 0.75-0.90.
    Type: Grant
    Filed: June 12, 1992
    Date of Patent: April 19, 1994
    Assignee: Toshiba Ceramics Co., Ltd.
    Inventors: Yoji Nagano, Takashi Ueno, Toshiaki Maeda
  • Patent number: 5302200
    Abstract: An admixture for a dense and durable concrete mix consisting essentially of diatomaceous earth and silica fume in the ratio of from 1 to 1 up to 1 to 8. Optionally, fly ash and lignosulfonate dispersant may be added to the admixture.
    Type: Grant
    Filed: November 27, 1991
    Date of Patent: April 12, 1994
    Assignee: Specrete - IP Incorporated
    Inventors: David A. Smetana, Alfonzo L. Wilson, Richard J. Lenczewski
  • Patent number: 5286682
    Abstract: A pavement marking that has yellow-tinted, retroreflective beads partially embedded in a bead-carrier medium. The bead-carrier medium contains 0.5 to 15 volume percent of a light-scattering agent that scatters white light. The pavement marking is able to retroreflect a distinct yellow color at nighttime without using yellow pigments that contain the potentially-toxic metals, cadmium, chromium, and lead.
    Type: Grant
    Filed: February 19, 1992
    Date of Patent: February 15, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Gregory F. Jacobs, James E. Lasch, Thomas P. Hedblom, Larry K. Stump
  • Patent number: 5275652
    Abstract: A multicomponent aqueous flowable admixture is formed with silica fume and stabilized with one or more high-range concrete water-reducing agents or one or more ordinary concrete water-reducing agents alone or in combination. The admixture is of particular advantage when added to fresh concrete or mortar to enhance plasticity and workability as compared to conventional concrete or mortar.
    Type: Grant
    Filed: May 27, 1993
    Date of Patent: January 4, 1994
    Assignee: Elkem Materials Inc.
    Inventor: Magne Dastol
  • Patent number: 5273578
    Abstract: A light-modifying composition comprising a color pigment component and a pigment spacer component characterized by being a transducing material having the ability to absorb light and reflect at least part of the light absorbed, thereby modifying the light in the coating resulting from the application of the composition. Such pigment spacing component includes any material having the ability to partially absorb light. Preferred are neutral grey pigments in the form of grey powders having a minimal color producing effect. The pigments can be in the form of ground grey powders such as powders taken from granite, feldspar, quartz or limestone or in the form of spherical metallic particles such as metallic zinc.
    Type: Grant
    Filed: April 2, 1993
    Date of Patent: December 28, 1993
    Inventor: Michael Towe
  • Patent number: 5262239
    Abstract: A composite pigment product useful as a paper filler pigment comprises a mineral nucleus coated with a substantially continuous substantially uniform coating of an active paper pigment. The active paper pigment coating is preferably formed in situ under alkaline conditions.
    Type: Grant
    Filed: February 12, 1992
    Date of Patent: November 16, 1993
    Assignee: J. M. Huber Corporation
    Inventors: Satish K. Wason, Michael C. Withiam
  • Patent number: 5256196
    Abstract: A precipitated silica paste is produced by dispersing precipitated silica in silicon oil. During the hydrophobing of precipitated silicas, the precipitated silica paste is added as a hydrophobing agent in the suspension phase. The product is spray-dried, tempered and ground.
    Type: Grant
    Filed: December 18, 1991
    Date of Patent: October 26, 1993
    Assignee: Degussa Aktiengesellschaft
    Inventors: Marian Chjonowski, Werner Nagel, Karl Meier, Wolfgang Leonhardt, Heinz Esch
  • Patent number: 5248556
    Abstract: Whitener pigment particles that offer good hiding power consist of particles having a uniform shape (preferably spherical) and varying only slightly in dimension. The particles consist of an inexpensive, readily manufacturable core material which is surrounded by one or more thin, concentric layers or shells, one of which is titania. The core provides the central mechanical support for the shells. In addition to the titania shell, layers can be added to provide compatibility with the carrier in which the particles are dispersed and promote phase transformation. Also described is a production method and apparatus for generating large quantities of the particles.
    Type: Grant
    Filed: November 15, 1991
    Date of Patent: September 28, 1993
    Assignee: Manfred R. Kuehnle
    Inventors: Egon Matijevic, Peter Hsu, Manfred R. Kuehnle
  • Patent number: 5219660
    Abstract: A composite pigment product useful as a paper filler pigment comprises a substantially inert mineral nucleus coated with a substantially continuous uniform coating of an active paper pigment. The active paper pigment coating is preferably formed in situ under alkaline conditions.
    Type: Grant
    Filed: September 16, 1991
    Date of Patent: June 15, 1993
    Inventors: Satish K. Wason, Michael C. Withiam