Abstract: A mechanically activated pozzolan prepared from granitic quarry fines. Quarry fines are milled by a high-energy milling process to convert the essentially inert raw granitic fines into a chemically reactive state. When added to a portland cement mortar mixture, mechanically activated fines combined with calcium hydroxide to improve the strength of the cured mortar compared to a similar mixture prepared with raw fines. Mortars prepared with mechanically activated granitic fines typically show strength values comparable to or exceeding similar mortars made using fly ash as a pozzolan. In some instances, the strength of a mortar prepared with mechanically activated granitic quarry fines exceeded a mortar prepared using 100% portland cement as the cementitious component.
Abstract: The present invention relates to pigment mixtures consisting of at least two components, component A being SiO2 flakes coated with one or more metal oxides and/or metals and component B being special-effect pigments, and to their use in varnishes, paints, printing inks, masterbatches, plastics and cosmetic formulations.
Type:
Application
Filed:
March 24, 2003
Publication date:
September 25, 2003
Applicant:
Merck Patent Gesellschaft mit beschrankter Haftung
Inventors:
Sabine Schoen, Reiner Vogt, Norbert Schul, Karl Osterried, Johann Munz
Abstract: Methods and apparatus are provided for uniformly depositing a coating material from a vaporization source onto a powdered substrate material to form a thin coalescence film of the coating material that smoothly replicates the surface microstructure of the substrate material. The coating material is uniformly deposited on the substrate material to form optical interference pigment particles. The thin film enhances the hiding power and color gamut of the substrate material. Physical vapor deposition process are used for depositing the film on the substrate material. The apparatus and systems employed in forming the coated particles utilize vibrating bed coaters, vibrating conveyor coaters, or coating towers. These allow the powdered substrate material to be uniformly exposed to the coating material vapor during the coating process.
Abstract: Described are hydrophobic particulate inorganic oxides useful for reinforcing polymeric composition, e.g., rubber. The materials are characterized by: (a) the substantial absence of functional groups capable of chemical reaction with rubber; (b) a BET surface area of in the range of from 40 to 350 m2/g; (c) a hydroxyl content in the range of 2 to 15 OH/nm2; (d) a carbon content in the range of from 0.1 to 6 percent by weight that is substantially non-extractable; (e) a pH in the range of from 3 to 10; (f) an M1 Standard White Area less than 0.4 percent and (g) a methanol wettability of from 15 to 45 percent. Compositions such as polymers, cured organic rubber articles, master batches and slurries containing the hydrophobic fillers are also described.
Type:
Application
Filed:
December 20, 2002
Publication date:
September 18, 2003
Inventors:
Jo-Ann E. Bice, Stuart D. Hellring, Timothy A. Okel
Abstract: A manufactured granular substrate composition suitable for use as a carrier for active chemical agents. The composition includes one or more mineral components having a bulk density greater than about 70 pounds per cubic foot. The composition also contains about one or more light weight additives and one or more water soluble binders. The resulting manufactured granular substrate has a bulk density of less than about 55 pounds per cubic foot with a size guide number of about 75 to about 300.
Type:
Grant
Filed:
May 14, 2001
Date of Patent:
September 2, 2003
Assignees:
The National Lime and Stone Co., The Andersons Agriservices, Inc.
Inventors:
James W. Welshimer, Nadine C. Dunn, Timothy D. Birthisel
Abstract: The present invention relates to coating compositions, preferably printing inks for security applications comprising at least one organic resin, at least one pigment and optionally at least one organic solvent. Said pigment comprises glass ceramic composite particles, containing at least one crystalline particle embedded in a glass matrix. Said glass ceramic particles have a particle size in the range of between 0.1 &mgr;m to 50 &mgr;m. Preferably active ions selected from the group of the rare-earth elements are incorporated into the crystalline phase of the composite to provide the glass ceramics with luminescent up- and down-converting characteristics. Glass ceramic luminescent have excellent physical and chemical stability. The glass matrix permits as well the stabilization of the photophysically interesting halide host crystals which have low phonon energies. Such materials provide unusual excitation and emission properties.
Abstract: The invention pertains to an amorphous silica particle comprising 0.1 to 105 ppm boron atoms, and optionally 0.05 to 15 wt. % aluminum atoms wherein the boron and aluminum atoms are covalently bonded to the oxygen atoms of the silica network. The amorphous silica particles arc used as a reinforcing filler for rubber articles, particularly for tires, more particularly for tire treads.
Type:
Application
Filed:
March 14, 2003
Publication date:
August 28, 2003
Inventors:
Paulus Johannes Kunkeler, Willem Hendrik Dokter
Abstract: A curable film-forming composition is provided comprising (i) 10 to 90 percent by weight based on the total weight of resin solids in the film-forming composition of a crosslinking agent; (ii) 10 to 90 percent by weight of a polymer containing a plurality of functional groups reactive with the crosslinking agent; and (iii) 5 to 85 percent by volume of particles having a mean particle size less than 100 nm. The particles comprise 1 to 99 percent by weight of at least one metal oxide wherein the metal is selected from zinc, titanium, cerium, manganese, bismuth, copper, zirconium and iron.
Abstract: Silica having a large pore volume and specific surface area, controlled pore properties and also excellent hydrothermal resistance is provided. The silica has the following properties: (a) a pore volume of the silica is larger than 1.6 ml/g and is 3.0 ml/g or less; (b) a specific surface area of the silica is between 100 and 1000 m2/g; (c) a mode pore diameter (Dmax) of the silica is 5 nm or more; (d) a value of Q4/Q3 in a solid-state Si nuclear magnetic resonance (hereinafter called solid-state Si NMR) spectrum of the silica is 1.2 or more; and (e) the silica is amorphous; and (f) a total content of metal impurities in the silica is 100 ppm or less.
Abstract: A composition for improving grip between the hands and a tool or implement is provided, which comprises a chlorinated paraffin, a dispersing agent, and a solvent in an amount up to and including about 3.0% by weight relative to the total weight of the composition. A method of making the composition in the form of a dry powder, as well as a method of using the dry powder to improve friction or grip on the hands, are also provided.
Abstract: This invention provides a multicolor coating composition comprising a vehicle and a metal oxide-coated silica flake pigment wherein a coating film resulting from baking of said coating composition and a coating film resulting from reheating of the former coating film under the same conditions as in said baking, followed by 10 minutes of standing at room temperature show a color difference of less than 0.5.
Abstract: Inorganic anti-corrosive pigments consist of surface-coated solids having a grain size of 0.1 to 75 &mgr;m. In order to improve the resistance of the paints and coatings containing such pigments, firstly Mn3(PO4)2 and secondly aluminium oxides and/or aluminium hydroxides are precipitated onto the solids.
Abstract: A mechanically activated pozzolan prepared from granitic quarry fines. Quarry fines are milled by a high-energy milling process to convert the essentially inert raw granitic fines into a chemically reactive state. When added to a portland cement mortar mixture, mechanically activated fines combined with calcium hydroxide to improve the strength of the cured mortar compared to a similar mixture prepared with raw fines. Mortars prepared with mechanically activated granitic fines typically show strength values comparable to or exceeding similar mortars made using fly ash as a pozzolan. In some instances, the strength of a mortar prepared with mechanically activated granitic quarry fines exceeded a mortar prepared using 100% portland cement as the cementitious component.
Abstract: The invention relates to particles with an opalescent effect, which have a particle size in the range from 5 &mgr;m to 5000 &mgr;m, comprising monodisperse spheres having a diameter of 50 nm to 2 &mgr;m with a standard deviation of less than 5% in a packed and regularly ordered structure which is three-dimensional -in terms of domains and is mechanically stabilized by physical or chemical modification.
Type:
Application
Filed:
November 14, 2002
Publication date:
June 26, 2003
Inventors:
Ralf Anselmann, Thomas Albrecht, Sara Rodriguez-Mozaz
Abstract: Dispersions of pyrogenic oxides, doped using an aerosol, are prepared by mixing the oxide with a suspending agent and milling. The dispersions can be used to prepare inkjet paper.
Type:
Application
Filed:
November 18, 2002
Publication date:
June 26, 2003
Applicant:
Degussa AG
Inventors:
Thomas Scharfe, Rainer Golchert, Helmut Mangold
Abstract: A method for sealing an annular space between a bore hole and a casing includes the steps of: providing a fluid sealing system comprising a particulate material and a bonding agent; positioning the fluid sealing system in the annular space whereby the particulate material adheres to walls of the bore hole and the casing; and curing the fluid sealing system so as to form a solid seal in the annular space.
Type:
Grant
Filed:
March 16, 2001
Date of Patent:
April 29, 2003
Assignee:
Intevep, S.A.
Inventors:
Luis Carlos Genolet, Juan Carlos Chavez, Douglas Espin, Marie Alejandra Jimenez
Abstract: In a method for the manufacture of a nacreous pigment, in which a multilayer film is produced by vacuum evaporation coating on a substrate and, after release from the substrate, the particles thus produced are comminuted to pigment particles of a desired size, vapor deposition of a plurality of layers taking place at separate locations within an evacuable container and the substrate being passed along the sources of evaporation, it is provided that at least a backing (A), in particular a silicon oxide layer, and at least a metal oxide layer (B), in particular a titanium oxide layer, are vapor-deposited on the substrate, in particular a circulating metal belt.
Abstract: The invention relates to a non-dusting, homogeneous pigment preparation, comprising
≧40% by weight of one or more effect pigments,
0.5-60% by weight of a polyalkylene glycol and/or one or more polyalkylene glycol derivatives,
0-10% by weight of a redispersing auxiliary,
0-40% by weight of water or an organic solvent or solvent mixture,
0-40% by weight of at least one further hydroxyl-rich resin,
and to its use as a precursor for printing inks.
Type:
Grant
Filed:
December 13, 2000
Date of Patent:
April 15, 2003
Assignee:
Merck Patent Gesellschaft mit beschränkter
Haftung
Abstract: The object of this invention is to provide a UV protective powder, and a cosmetic preparation in which the dispersibility of metal oxide is kept at a high level, and the UV protection activity and transparency of the preparation are satisfactorily maintained.
Abstract: The present invention describes the reaction product of an alkanolamine and a hydrocarbyl succinic anhydride compound useful in assisting the dispersion of pigments in aqueous and/or non-aqueous media.
Abstract: A colorant for ink-jet printing ink of the present invention, has an average particle diameter of 0.001 to 0.15 &mgr;m, and comprises: extender pigments as core particles; a gluing agent coating layer formed on at least a part of surface of said core particle; and an organic pigment coat uniformly formed on at least a part of said gluing agent coating layer. The colorant for ink-jet printing ink exhibits not only a high tinting strength and a clear hue, but also excellent dispersibility and light resistance in spite of fine particles.
Abstract: A silica comprising at least two silica fractions, wherein said at least two silica fractions differ by at least 10% in at least one value for BET surface area, CTAB surface area and DBP absorption, the ranges of these three physicochemical properties being as follows: 1 BET surface area 100-900 m2/g, CTAB surface area 100-500 m2/g, DBP absorption 150-350 g/100 g.
Type:
Application
Filed:
March 18, 2002
Publication date:
March 27, 2003
Applicant:
DE GUSSA AG
Inventors:
Stefan Uhrlandt, Ralf Schmoll, Claus-Peter Drexel
Abstract: A silica having a high degree of dispersibility and a low dust concentration contains at least two silica fractions that differ by at least 10% in at least one value of BET or CTAB surface area or DBP absorption.
Type:
Application
Filed:
January 18, 2002
Publication date:
February 27, 2003
Applicant:
DE GUSSA AG
Inventors:
Stefan Uhrlandt, Ralf Schmoll, Anke Blume, Detlef Luginsland
Abstract: Methods and apparatus are provided for uniformly depositing a coating material from a vaporization source onto a powdered substrate material to form a thin coalescence film of the coating material that smoothly replicates the surface microstructure of the substrate material. The coating material is uniformly deposited on the substrate material to form optical interference pigment particles. The thin film enhances the hiding power and color gamut of the substrate material. Physical vapor deposition processes are used for depositing the film on the substrate material. The apparatus and systems employed in forming the coated particles utilize vibrating bed coaters, vibrating conveyor coaters, or coating towers. These allow the powdered substrate material to be uniformly exposed to the coating material vapor during the coating process.
Abstract: A number of stable mixtures are disclosed containing specific combinations and levels of extender pigments and thickeners. These stable mixtures may be employed, inter alia, as a mixture in a method of making paints using prepaints or as a conventional component in a coating, such as a paint, or other end-use where opacifying pigments are employed.
Type:
Application
Filed:
August 8, 2002
Publication date:
February 20, 2003
Inventors:
Edwin Hugh Nungesser, Jerry William Washel, John Michael Friel
Abstract: The present invention relates to pigment mixtures comprising at least two components, component A being multilayer pigments based on mica, SiO2 flakes, glass flakes, Al2O3 flakes or polymer flakes and component B being platelet-shaped, acicular or spherical colorants and/or fillers, and to the use thereof expecially in varnishes, paints, printing inks, powder coatings, plastics, ceramic glazes, polymer films and cosmetic formulations.
Type:
Grant
Filed:
April 17, 2000
Date of Patent:
February 11, 2003
Assignee:
Merck Patent GmbH
Inventors:
Gerhard Pfaff, Ralf Anselmann, Sabine Schoen
Abstract: A pigment, especially a yellow to red emitting luminescent material, with a host lattice of the nitridosilicate type MxSiyNz:Eu, wherein M is at least one of an alkaline earth metal chosen from the group Ca, Sr, Ba and wherein z=⅔x+{fraction (4/3)}y.
Type:
Application
Filed:
November 28, 2001
Publication date:
February 6, 2003
Inventors:
Ir G. Botty, Hubertus T. Hintzen, Jost W. H. van Krevel
Abstract: Systems and methods of making and using fine particle materials in pigment blends and for using the aforementioned pigment blends in paint, coating, or coloring compositions are provided. This invention further provides systems and methods of enhancing the visual appearance of a variety of substrates by introducing a paint, coating, or coloring composition to the substrate. The fine particle materials of the present invention have a substantially random geometric shape, a particle size less than about 100 microns, and help provide both functional and visual enhancing properties to compositions and substrates containing these fine particle materials.
Type:
Application
Filed:
July 16, 2002
Publication date:
January 2, 2003
Applicant:
Ameritech Holding Corporation, a corporation of New York
Inventors:
Guido Greco, Vincent Pernice, Barry E. Scheetz
Abstract: The present invention relates to pigment mixtures consisting of at least two components, component A being SiO2 flakes coated with one or more metal oxides and/or metals and component B being platelet-shaped, acicular or spherical colorants or fillers, and to their use in particular in varnishes, paints, printing inks, powder coating materials, plastics and cosmetic formulations.
Abstract: A stable aquasol containing colloidal silica having a surface area of from about 700 m2/g to about 1100 m2/g, and an S-value of from about 20 to about 50; wherein the colloidal silica is not surface treated; wherein the molar ratio of SiO2/Na2O in the colloidal silica is greater than about 13.0:1 and is less than about 17.0:1; and wherein the aquasols have a percent by weight SiO2 solids level of from about 7.00 percent to about 16.80 percent is described and claimed.
Type:
Grant
Filed:
June 27, 2000
Date of Patent:
November 26, 2002
Assignee:
Ondeo Nalco Company
Inventors:
Bruce A. Keiser, Maureen B. Nunn, Cheng-Sung Huang, Dennis L. MacDonald
Abstract: A sodium-based dechlorinating agent g is added to a flue gas G6; hydrogen chloride contained in this flue gas is removed as residue of dechlorination; the thus removed residue of dechlorination is dissolved by adding water i; water-insoluble constituents k are separated from the resulting aqueous solution j; and after adjusting pH of the aqueous solution 1 remaining after separation of the water-insoluble constituents k, mercury, dioxin and the like are removed and discharged. The sodium-based dechlorinating agent g is mixed with a hydrophilic anti-caking agent, with an angle of repose of 40° or more, a dispersibility of less than 50, and a floodability index value of less than 90. A mean particle diameter of sodium hydrogencarbonate is set within a range of from 2 &mgr;m to 30 &mgr;m. The hydrophilic anti-caking agent comprises silica, and is contained in an amount of 0.1 mass % or more in the sodium-based dechlorinating agent.
Abstract: There are disclosed a frost-coating composition, which comprises (i) a hydrophobic silica particle or further comprises (ii) a polymer particle, in addition to a photocurable compound; and a frosted glass container coated with such a composition. The frosted glass container coated with such a composition is excellent in alkali resistance, or excellent both in alkali resistance and in impact resistance.
Abstract: To provide an ultraviolet absorbent having high UV shieldability, especially UV-A shieldability, high transparency and good dispersibility.
An ultraviolet absorbent, which comprises a flaky substrate coated with ultra-fin zinc oxide particles having a mean particle size of not larger than 100 nm, and which is optionally treated with an organic silicone compound; and a method for producing the ultraviolet absorbent, which comprises calcining particles as coated with basic zinc carbonate in the presence of a complex-forming agent.
Abstract: A color effect material is composed of a plurality of encapsulated substrate platelets in which each platelet is encapsulated with copper, zinc, an alloy of copper, or an alloy of zinc first layer which acts as a reflector to light directed thereon, a second layer encapsulating the first layer in which the second layer provides an optically variable reflection of light impinging thereon and a third layer encapsulating the second layer and being selectively transparent to light directed thereon.
Type:
Grant
Filed:
November 6, 2000
Date of Patent:
August 27, 2002
Assignee:
Engelhard Corporation
Inventors:
James D. Christie, Daniel S. Fuller, Curtis J. Zimmermann
Abstract: Foreign-atom-doped precipitated silicas having a BET surface area of more than 300 m2/g and a maximum surface concentration of the foreign atoms of 0.05 mmol/m2, to a process for preparing them and to the use of the resulting precipitated silicas in papermaking.
Abstract: The invention relates to a non-dusting, homogeneous pigment preparation which is distinguished by the fact that it comprises at least 40% by weight of one or more effect pigments and 0.5-59.5% by weight of a modified colophony resin, based on the pigment preparation, and the use thereof, in particular for the production of dry preparations. The pigment preparation according to the invention and the dry preparations produced therefrom are particularly suitable for the pigmenting of paints, coatings, powder coatings, printing inks and plastics.
Type:
Grant
Filed:
May 14, 2001
Date of Patent:
August 13, 2002
Assignees:
Merck Patent Gesellschaft mit beschraenkter Haftung, Lackharzwerke Robert Kraemer GmbH & Co.
Inventors:
Thomas Rathschlag, Carsten Griessmann, Sabine Schoen, Werner Sarfert
Abstract: Polymer coating composition for a plastics substrate including a polymeric binder and an inert filler. The composition also includes polyamide epichlorohydrin and an ionic insolubilizing agent that is capable of reacting with the binder to render the binder insoluble in water.
Abstract: The present invention relates to rare earth metal sulfide or oxysulfide pigments and yttrium sulfide or oxysulfide pigments based on platelet-shaped substrates.
Type:
Grant
Filed:
November 13, 2000
Date of Patent:
July 16, 2002
Assignee:
Merck Patent Gesellschaft mit beschrankter Haftung
Abstract: An initial solids mixture for a later organic coating, such as pigmented coatings, films, priming coats, etc., e.g., for a coil coating method in which an initial solids mixture is applied to a substrate, e.g., broad strip, and this is thereby pre-coated, wherein the initial solids mixture includes, as additive particles, boron carbide and/or silicon carbide and/or compounds of transition elements or lanthanides, the electrical conductivity of which is selected to be in the metallic range (&sgr;>102 1/&OHgr;cm and &sgr;<107 1/&OHgr;cm), during the later coating, the additive particles have a continuous physical connection in at least one spatial direction.
Abstract: Disclosed is a rigid fine-celled light-weight foam composition and a method of producing it which has improved retention of liquids by absorption/adsorption which improves the thermal insulation and fire retardant properties of the fine-celled foam particularly suited for use in double walled tanks and hollow canopies, building panels, profiles, and the like.
Abstract: A low-viscosity dental material contains a non-settling nanoscale filler. Improvements of the mechanical properties of the dental materials, including the abrasive resistance and the compressive strength are provided. Furthermore, the dental materials have increased resistance to microleakage and have increased bond strengths. The filler forms a stable sol with low-viscosity dental materials and the filler may be prepared by surface treatment of fillers having a primary particle size of from about 1 to about 100 nanometers.
Abstract: The precipitated silica has the following physico-chemical parameters:
BET surface area (DIN 66131) in m2/g
400-600
DBP index (DIN 53601) in g/100 g
300-360
Compacted density (DIN 53194) in g/l
70-140
Grindometer value (ISO 1524) in &mgr;m
15-50
Size distribution index I
<1.0
measured with a Malvern instrument
Size distribution index
I
=
d
90
-
d
10
2
⁢
d
50
This precipitated silica is prepared by milling a precipitated silica in accordance with DE-A 31 44 299 in a classifier mill or a fluidized bed counter-flow mill. A polyethylene wax emulsion may be added before the milling procedure.
Abstract: A flake-based pigment is provided having improved specular reflectance characteristics in the visible wavelength range. The flake-based pigment has a plurality of core flake sections each formed of a central reflector layer and dielectric support layers on opposing sides of the reflector layer. The resulting core flake section is a very thin three-layered structure that exhibits a uniaxial compressive strength much greater than a corresponding uniaxial tensile strength. This structure provides the benefits of rigidity and brittle fracture during manufacturing and application processes, which ultimately provides favorable planar and specular reflectance characteristics for the pigment in the visible wavelength range. A variety of outer coating layers can be formed around the core flake sections, such as various dielectric and absorber layers having thicknesses dependent upon the desired optical characteristics of the pigment.
Type:
Grant
Filed:
April 7, 2000
Date of Patent:
May 14, 2002
Assignee:
Flex Products, Inc.
Inventors:
Kent E. Coulter, Thomas Mayer, Roger W. Phillips, John S. Matteucci
Abstract: A flake-based pigment is provided having improved specular reflectance characteristics in the visible wavelength range. The flake-based pigment has a plurality of core flake sections each formed of a central reflector layer and dielectric support layers on opposing sides of the reflector layer. The resulting core flake section is a very thin three-layered structure that exhibits a uniaxial compressive strength much greater than a corresponding uniaxial tensile strength. This structure provides the benefits of rigidity and brittle fracture during manufacturing and application processes, which ultimately provides favorable planar and specular reflectance characteristics for the pigment in the visible wavelength range. A variety of outer coating layers can be formed around the core flake sections, such as various dielectric and absorber layers having thicknesses dependent upon the desired optical characteristics of the pigment.
Type:
Grant
Filed:
October 13, 2000
Date of Patent:
May 7, 2002
Assignee:
Flex Products, Inc.
Inventors:
Kent E. Coulter, Thomas Mayer, Roger W. Phillips, John S. Matteucci
Abstract: The precipitated silica has the following physico-chemical parameters:
BET surface area (DIN 66131) in m2/g
400-600
DBP index (DIN 53601) in g/100 g
300-360
Compacted density (DIN 53194) in g/l
70-140
Grindometer value (ISO 1524) in &mgr;m
15-50
Size distribution index I
<1.0
measured with a Malvern instrument
Size
⁢
⁢
distribution
⁢
⁢
index
⁢
⁢
I
=
d
90
-
d
10
2
⁢
d
50
This precipitated silica is prepared by milling a precipitated silica in accordance with DE-A 31 44 299 in a classifier mill or a fluidized bed counter-flow mill.
Abstract: Disclosed are amorphous precipitated silicas, silica gels, and amorphous carbons derived from biomass and methods of producing them with and without adhered or deposited amorphous carbons produced by acidifying a caustic silicate solution produced by caustic digestion of biomass ash containing silica with and without activated carbon, the ash being obtained from thermal pyrolysis of the biomass, the acidifying effective to produce a slurry of the precipitated silica and silica gels with and without adhered or deposited amorphous carbon, and separated from the slurry the precipitated silicas and silica gels with and without the adhered or deposited amorphous carbons. The properties of the precipitated silica with adhered or deposited carbon being within the range as utilized in rubber compositions thereby avoiding the blending of silica and carbon components for such use.
Type:
Grant
Filed:
March 31, 2000
Date of Patent:
April 23, 2002
Assignees:
Agritec, Inc., Occidental Chemical Corporation
Inventors:
Douglas K. Stephens, Clyde W. Wellen, Jeffrey B. Smith, Kenneth F. Kubiak