Abstract: A fluxing composition for soldering metals together, contains a carrier solvent, an oxide removing agent, and a nitrogen liberating compound. The oxide removing agent sublimes at or below the temperature at which the metals are soldered together. The nitrogen liberating compound sublimes or decomposes at below the temperature at which the metals are soldered together in order to provide a blanket of inert gas over the metals being soldered. The oxide removing agent is 2-amino-isophthalic acid, 5-amino-isophthalic acid, isophthalic acid, ammonium fluoborate, or ammonium salicylate. The compound that liberates nitrogen upon heating is 1,2-benz-3,4-anthraquinone, 1,2-benz-9,10-anthraquinone, 5,6-chrysoquinone, 6,12-chrysoquinone, 2,3-benzanthraquinone, 2-amino-isophthalic acid, 5-amino-isophthalic acid, or 5-isoquinoline carboxylonitrile. Electronic components are soldered to a circuit board by applying the fluxing composition to the circuit board.

Abstract: A flux for use in a dry process for the flux treatment of the material to be coated with molten metal contains at least one chloride selected from the group consisting of zinc chloride, stannous chloride, an alkali metal chloride and an alkaline earth metal chloride and at least one aliphatic nitrogen derivative with alkyl group having 1 to 18 carbons. The treatment of steel with this flux enables the formation of a coating having a good finish from, among others, a molten alloy of zinc and aluminum, which may further contain other elements, or molten aluminum, by a single dipping operation in an atmospheric environment which has hitherto been difficult. A process for manufacturing steel coated with molten metal, including its treatment with the flux, is also disclosed.

Abstract: A no-clean, low-residue, rosin-free soldering flux is described which comprises a solvent consisting essentially of demineralized water present in amount of at least about 95% by weight based on total weight of the soldering flux; from about 1% to about 4% by weight based on total weight of the soldering flux of a fluxing agent consisting essentially of at least two carboxylic acids selected from the group consisting of C.sub.2 -C.sub.10 dicarboxylic acids, monocarboxylic acids and hydroxy acids, said fluxing agent being present as solute in said deionized water solvent; and nonionic surfactant present in an amount of less than about 1% by weight based on total weight of soldering flux.

Abstract: A coating composition comprises a slurry consisting essentially of an aluminum neutralized phosphate bonding solution and aluminum powder. The bonding solution advantageously contains a relatively small but essential amount of vanadium pentoxide and, preferably, magnesium. A process for forming the bonding solution component of the coating slurry includes equilibrating an aqueous phosphate solution with a small but controlled and necessary amount of solute aluminum prior to adding aluminum powder to form the slurry. The present invention overcomes the problem of bonding solutions which require environmentally disadvantageous chromates or molybdates.

Abstract: A seal coat composition comprises a slurry consisting essentially of an aluminum neutralized phosphate bonding solution and iron oxide (Fe.sub.2 O.sub.3) powder. The bonding solution advantageously contains a relatively small but essential amount of vanadium pentoxide and, preferably, magnesium. A process for forming the bonding solution component of the coating slurry includes equilibrating an aqueous phosphate solution with a small but controlled and necessary amount of solute aluminum prior to adding iron oxide powder to form the slurry. The present invention overcomes the problem of bonding solutions which require environmentally disadvantageous chromates or molybdates to neutralize the bonding solution prior to formation of the slurry.

Abstract: A braze paste is disclosed for brazing superalloys together which includes an organic binding system, a major amount of a nickel, cobalt, gold, silver, copper or palladium based braze alloy and ground polytetrafluoroethylene. The braze paste can be used to braze superalloys together without prior nickel treatment. In the brazing step, the polytetrafluoroethylene decomposes and forms fluoride ions which in turn acts on any oxide that may form during the brazing step to remove the oxide and permit a good braze between the metal objects.

Abstract: A soldering paste for light beam-heating soldering containing a flux which contains 2 to 8 % by weight of a thixotropic agent having a melting point of 140.degree. to 150.degree. C., 1.8 to 3.0 % by weight of an activator containing cyclohexylamine hydrobromide, 40 to 50 % by weight of a rosin component and 40 to 50 % by weight of a solvent; and spherical solder particles having a particle size of 250 to 400 mesh and an oxygen content of not larger than 200 ppm, in which a content of the flux in the soldering paste is from 9 to 13 % by weight and the soldering paste has a thixotropy index of 7 to 8.

Abstract: A low temperature-wetting solder paste for forming a tin-base solder connection comprises a mixture of compositionally distinct first and second solder powders. The first solder is formed predominantly of tin, preferably at least 90 weight percent. The second powder is formed of a tin alloy containing indium or bismuth and having a melting temperature less than the first powder. During soldering, the second powder melts during the early stages of the heating cycle to initiate wetting of the faying surfaces and promote dissolution of the first powder, thereby reducing the time and temperature required to form the solder connection.

Abstract: In a paste for use in the electronics industry which comprises:i) a non aqueous vehicle; andii) a particulate filler material, the improvement which comprises the vehicle being a stable emulsion of at least two immiscible organic liquids of at least 50% by volume disperse phase, one of which liquids is selected from the group consisting of a polar solvent and a mixture of polar solvents, and the other of which liquids is selected from the group consisting of an aliphatic hydrocarbon and a mixture of aliphatic hydrocarbons and the paste, when heated to remove the vehicle therefrom yields less than 3.0% by weight of organic residues based on the weight of the paste.

Abstract: Disclosed is a water-soluble solder flux and a method of fabricating circuit boards which does not adversely affect the insulation resistance of the boards. The flux applied to the board comprises a vehicle including at least two random copolymers of polyalkylene glycol with various amounts of ethylene oxide and propylene oxide. The flux also exhibits a low viscosity for improved copper coverage.

Abstract: A solder paste that is useful in applications such as surface mounting of components on printed circuit boards has been found. After soldering, the residue requires no cleaning. The achievement of these desirable properties is accomplished by employing a solder flux vehicle including a three component residue modifier.

Abstract: A soldering flux composition comprising, as a flux base resin, a modified amine compound obtained by reacting (i) at least one member selected from the group consisting of vinyl group-containing compounds, carboxyl group-containing compounds and epoxy group-containing compounds (ii) with an amine compound having an active hydrogen.

Abstract: A non-toxic, non-corrosive foaming soldering flux (14) comprises citric acid and water, together with at least one foaming agent. The foam is fast-breaking, dissipating almost immediately. Such a fast-breaking foam is novel in an aqueous-based flux. The unique flux of the invention produces solder joints of high metallic luster and excellent quality. Disposal presents no health hazards, and clean-up of flux residues is accomplished using only water and, optionally, a surfactant.

Abstract: A water soluble, thermally stable, solder flux for use in forming a water soluble, thermally stable, solder paste is provided. The water soluble, thermally stable, solder flux contains an acidic ester component having about 50% to about 60% monoesters by weight based on total weight, about 40% to about 50% diesters by weight based on total weight, and about 0% to about 1.5% phosphoric acid by weight based on total weight. This ester component is combined with triethanolamine to form a flux vehicle having a molar ratio of triethanolamine to the ester component of about 0.6 to about 1.2. This vehicle is present in the solder flux in an amount from about 68% to about 79% by weight based on total weight of solder flux. The flux also contains rheology adjusting components in an amount ranging from about 17% to about 26% by weight based on total weight of solder flux. Citric acid included in the flux in an amount ranging from about 4% to about 6% by weight based on total weight of solder flux.

Abstract: A paste solder with minimized flux residue remaining after soldering comprises a powdered solder and a flux in admixture. The flux comprises from about 5% to about 40% by weight of carrier components which comprise a rosin or a rosin derivative, an activating agent, and a thixotropic agent and from about 60% to about 95% by weight of a solvent which predominantly comprises a 2-alkyl-1,3-hexanediol having 1 to 4 carbon atoms in the alkyl group.

Abstract: Discloses an aluminium brazing paste which not only has excellent preservability and coating performance but also reveals excellent brazing characteristics; said aluminium brazing paste according to this invention comprises, per 100 parts by weight of aluminum-containing metal powder with 10 to 500 .mu.m of mean particle size for aluminium brazing, of 0.5 to 15 parts by weight of flux and 30 to 80 parts by weight of a liquid polyisobutylene with 300 to 1500 of average molecular weight and/or its hydrogenated product.

Abstract: The invention provides a method and means of producing weld metal for use in joining two or more aluminum containing pieces. The method includes the steps of providing a novel mixture of reactants comprising silicon, a reducing agent, a metallic compound which is exothermically reduced by the reducing agent, and a filler metal that does not react with the metallic compound. The mixture of reactants is then exothermically reacted so as to form the weld metal for joining the metallic pieces. At least about 90 percent by weight of the weld metal is produced by the silicon and the filler metal and at least about 90 percent by weight of the weld metal has a chemical composition substantially similar to that of at least one of the metallic pieces being joined.

Abstract: Disclosed is a soldering flux which prevents a release of an active ion contained in an activator when exposed to a high-temperature atmosphere maintaining at a temperature higher than 80.degree. C., for example, an atmosphere of an engine room of an automobile, and thus makes washing unnecessary. This soldering flux comprises, together with an activator, (1) a thermoplastic resin having a softening point not lower than 80.degree. C., and/or (2) an epoxy group-containing compound, a radical-polymerizable unsaturated double bond-containing compound or a blocked isocyanate group-containing compound, or (3) a thermosetting resin composed of a carboxyl group-containing resin and an epoxy resin and/or a thermosetting resin containing carboxy and epoxy groups.

Abstract: A method for making multilayer electronic circuits comprising the sequential steps of(1) applying to a substrate comprising a plurality of alternating dielectric and conductive layers a thick film dielectric paste containing a low-melting silicate glass;(2) applying to the dielectric paste layer a pattern of thick film conductor paste comprising finely divided particles of silver, an inorganic binder and a ruthenium- or rhodium-based sintering inhibitor, all dispersed in an organic medium; and(3) air cofiring the applied layers of thick film dielectric and conductive pastes.

Abstract: A solder flux that is useful in applications such as surface mounting of components on printed circuit boards has been found. After soldering, the residue from the flux is either removable by water cleaning or requires no cleaning at all. The achievement of these desirable properties is accomplished by employing a solder flux vehicle including a removing agent, a low vapor pressure component, a high temperature component, and a rheological properties promoter.

Abstract: A low temperature solder and method for soldering an oxide layer-building metal such as aluminum, titanium, tantalum or stainless steel. The comosition comprises tin and zinc; germanium as a wetting agent; preferably small amounts of copper and antimony; and a grit, such as silicon carbide. The grit abrades any oxide layer formed on the surface of the metal as the germanium penetrates beneath and loosens the oxide layer to provide good metal-to-metal contact. The germanium comprises less than aproximatley 10% by weight of the solder composition so that it provides sufficient wetting action but does not result in a melting temperature above approximately 300.degree. C. The method comprises the steps rubbing the solder against the metal surface so the grit in the solder abrades the surface while heating the surface until the solder begins to melt and the germanium penetrates the oxide layer, then brushing aside any oxide layer loosened by the solder.

Abstract: A solder precipitating composition comprises a powder of a metal having the highest ionization level among metals constituting a solder alloy to be prepared, and a salt between a carboxylic acid and a remaining metal of the solder alloy. The composition is applied to a surface on which the solder is to be precipitated, and the solder is precipitated, thereby performing soldering.

Abstract: A non-toxic, non-corrosive water-soluble soldering paste comprises at least about 80 wt % of particulate solder and the balance a thixotropic flux base. The flux base has a viscosity of at least about 200,000 cp and comprises (a) a botanical oil, (b) an aqueous emulsion of a thickening agent, such as corn starch or an ethoxylated linear alcohol in water, and (c) an organic acid having at least two carboxylic acid groups, such as citric acid. The paste of the invention produces solder joints of high metallic luster and excellent quality. Clean-up of paste residues is ac complished using only water.

Abstract: An electronic circuit device comprising an electronic part having a gold-plated connecting terminal arranged thereon connected through a solder to a circuit substrate on the predetermined connecting element thereof, in which the connecting terminal of the electronic part and the solder-connected portion of the circuit substrate are constituted by an alloy composition consisting of 1.0 to 8.0 wt. % of Ag, 0.1 to 6.0 wt % of Au and the balance of Sn, is provided. The device is made by using a solder for use in connecting a gold-plated connecting terminal which consists of 1.0 to 8.

Abstract: An adhesive material 220 including a fluxing agent and metal particles 240 is applied to either a substrate 200 having a metallization pattern 210 or an electrical component 230. The component 230 is positioned on the substrate 210 and heated. During the heating step, the fluxing agent promotes adhesion of the metal particles 240 to the substrate metallization pattern 210 and the component, and the adhesive material 220 is cured, to mechanically interconnect and encapsulate the substrate 210 and the component 230.

Abstract: A chemical solder is described that includes an organometallic which thermally degrades within a predetermined temperature range to a metal and volatile compounds. The solder also includes a polymeric matrix that decomposes within the same temperature range to volatile fractions, thereby leaving only the metal.A method for bonding first and second bodies is disclosed wherein a chemical solder, as above-described, is disposed between the first and second bodies and heat is applied to elevate the solder to the predetermined temperature range to thermally degrade the organometallic compound and to decompose the polymeric matrix. The remaining metal bonds the first and second bodies.

Abstract: A soldering flux includes at least one acid component and at least one ester component. The acid component is selected from among dibasic carboxylic acid, hydroxycarboxylic acid and keto carboxylic acid. The ester component is selected from among phosphoric ester, phosphorous ester and hypophosphite ester.

Abstract: A no-clean, thermally dissipated soldering flux is shown which includes hydroabietal alcohol as a flux base, an organic activator and an organic diluent. The hydroabietal alcohol provides a tacky medium which holds a precisely aligned chip in place both during placement and reflow. The nature of the formula renders a reducing atmosphere unnecessary. The composition is thermally dissipated during soldering and leaves no undesirable residue which would require a post-cleaning step.

Abstract: An additive contains a deactivation agent functioning at soldering temperature. This novel additive is used for fluxes and soldering pastes. In the course of soldering, the deactivation agent in the additive deactivates an activator such as organic acids contained in the flux and the soldering paste in order for removal of an oxide film from a metallic base used for electric circuit. By use of the additive, corrosion of the metallic base with the activator is prevented even though the activator remains on the base. The additive enables one to omit an unnecessary washing step from a preparation of electric circuit.

Abstract: The composition of the present invention includes a water-soluble soldering flux requiring no thermal energy to place the water-soluble flux in an active state. The water-soluble soldering flux contains (1) from about 1 percent to about 5 percent by weight, based on the weight of the water-soluble soldering flux, of an inorganic acid which, in solution, forms anions of the acid having a low propensity for forming metal complexes; (2) from about 30 percent to about 70 percent by weight, based on the total weight of the water-soluble soldering flux, of an anionic surfactant; and (3) from about 30 percent to about 70 percent by weight, based on the total weight of the water-soluble soldering flux, of a diluent. The composition of the present invention may contain a fourth component, a viscosity modifier from about 5 percent to about 40 percent by weight, based on total weight of the water-soluble soldering flux.

Abstract: Solder pastes having vehicles including formic acid-soluble organic acids as fluxing agents are described. Fluxing agents may be compounds of the formula: ##STR1## where R is an electron withdrawing group. In one embodiment, R is selected from the group consisting of fluorine, chlorine, bromine, iodine, sulfur, hydroxyl, nitrile, and benzyl. Other suitable formic-acid fluxing agents include, but are not limited to, adipic acid, acrylic acid, polyacrylic acid, methacrylic acid and polymethacrylic acid. The compounds clean oxides from the printed circuit boards (PCBs) under assembly and then volatilize leaving a residue to be cleaned away. The cleaning step involves rinsing with formic acid. No undesired residue remains indicating that the organic acids of the invention are effective in cleaning boards.

Abstract: A brazing paste gel has a composition of 1-4 wt. % hydroxypropylcellulose, 40-80 wt. % 1,2-propanediol, 18-58 wt. % 2-propanol. Alternatively, the composition may be 1-4 wt. % hydroxypropylcellulose, 20-70 wt. % 1,2-propanediol, 26-76 wt. % water.

Abstract: The present invention relates to solder flux and solder paste compositions which do not require cleaning after the soldering operation.

Abstract: A solder paste is formulated by combining a solder paste vehicle, a resin, and solder alloy particles. The solder paste vehicle is made by combining mono and polyfunctional alcoholic solvents with a fluxing agent. The solder particles are first reacted with a formate ion produced by formic acid, formaldehyde, paraformaldehyde, or mixtures thereof, in order to create a metal-formate complex that functions as an oxygen scavenger on the surface of the solder alloy particles.

Abstract: A soft soldering flux based on organic carboxylic acids is particularly suitable for the production of electronic and electrical components. Its reduced solids content (e.g. 6%) makes it specially suited to SMT manufacturing and in-circuit tests. To this end, alkylfluorinated alcohols of formula Rf--CH.sub.2 --CH.sub.2 --OH, alicyclic and aromatic mono-, di-, or polycarboxylic acids with at least one carbon ring or their derivatives are introduced, using aliphatic mono-, di, poly-, keto- or hydroxy carboxylic acids and quaternary ammonium salts.

Abstract: A novel method is described for joining aluminum surfaces by brazing. The method comprises (a) applying as a coating to at least one of the aluminum surfaces to be joined a mixture of a metal and a brazing flux, the metal of the mixture being adapted to form a brazable eutectic with the aluminum, (b) heating the surfaces and the coating in juxtaposed relation to a temperature above the brazing alloy melting point to thereby dissolve oxide film on the surface to be joined, cause the metal of the coating to dissolve into the oxide-free aluminum surface and form therewith a brazing alloy layer and form a brazed assembly and (c) cooling the brazed assembly to form a solidified joint between the surfaces. This has the advantage of providing for the joining of aluminum surfaces by brazing without the prior formation of a brazing alloy cladding on the surfaces to be brazed.

Abstract: Metal filler compositions and methods of employing the same are disclosed, in which the compositions are copper base with the addition thereto of tin and silicon. For thermal spraying applications, aluminum is included in the formulation. By practice of the invention, substantial improvements in bond strength and quality of the surface finish are achieved.

Abstract: This invention is a residue-free cleaning process for removing metal-containing contaminants from a surface of a substrate of the type used in manufacturing semi-conductor devices. The process comprises contacting the substrate with an effective amount of a cleaning agent comprising a .beta.-diketone or .beta.-ketoimine dispersed in an atmosphere capable of oxidizing the metal-contaminants at a temperature sufficient to form volatile metal-ligand complexes on the surface of the substrate. The volatile metal-ligand complexes are sublimed from the surface of the substrate leaving essentially no residue.

Abstract: Solder pastes having vehicles including blends of low boiling point alcohols and relatively high boiling point alcohols are described which leave residues which may be cleaned using only water are described. The low boiling point alcohols have a boiling point range of between about 65.degree. and about 150.degree. C. whereas the high boiling point alcohols have a boiling point in rhe range of about 150.degree. to about 270.degree. C. The solder pastes also use water-soluble organic acids as fluxing agents such as compounds of the formula: ##STR1## where R is an electron withdrawing group such as fluorine, chlorine, bromine, iodine, sulfur, hydroxyl, nitrile, and benzyl. Other suitable formic-acid fluxing agents include, but are not limited to, adipic acid, polyacrylic acid, methacrylic acid and polymethacrylic acid. The compounds clean oxides from the printed circuit boards (PCBs) under assembly and then volatilze leaving a residue to be cleaned away. The cleaning step involves rinsing with water.

Abstract: A method of joining components to a substrate by reflow soldering with non-rosin-based flux containing solder is disclosed comprising heating the solder in the presence of the components in a low oxidizing atmosphere.

Abstract: A water-soluble soldering flux having good solderability, removability with water, and insulation resistance comprises, as activators, a combination of tartaric acid and a hydrohalide salt of mono-, di-, or tri-ethanolamine.

Abstract: A water soluble solder paste, which does not adversely impact the surface insulation resistance (SIR) of a circuit board, is comprised of powdered solder, a water soluble flux (containing an activator within a water soluble vehicle), a hydrophobic surfactant preferentially absorbed over the water soluble vehicle, and a solvent within which the surfactant and flux are dissolved. The hydrophobic surfactant is chosen to be preferentially absorbed by the circuit board surface over the water soluble flux vehicle to prevent the vehicle, which is hydrophilic from becoming trapped in the board surface, thereby adversely affecting the board SIR.

Abstract: A paste vehicle for use in a metal bearing solder paste composition having a heat-polymerizable binder is provided. This vehicle can be non-aqueous, inorganic salt-free and dispersed in a non-aqueous, organic liquid, and may be incorporated with a flux into a solder paste composition capable of utilizing an average particle size finer than 100 mesh. This paste has excellent anti-slump properties, requires no cleanup to remove residual solder reflow, and permits smaller more controlled joints to be formed.

Abstract: Fluxing compositions are described containing as fluxing agents compounds of the formula: ##STR1## where R is an electron withdrawing group. In one embodiment, R is selected from the group consisting of fluorine, chlorine, bromine, iodine, sulfur, hydroxyl, nitrile, and benzyl. The compound cleans oxides from the printed circuit boards (PCBs) under assembly and then volatilize with little or no need for a cleaning step, or cleaning only with water or formic acid. Very little or no undesired residue remains. Such acid fluxing agents can be used mixed with typical solder formulations, such as lead/tin solder pastes, or applied topically to solders, such as solder balls; both techniques permit the assembly of PCBs more easily with high quality bonds, and with little or no residue. Malic acid is a preferred organic acid fluxing agent.

Abstract: Improved soldering paste for surface mounting of electronic components comprises a novel fluxing agent selected from formylated polyhydric compounds. The paste enables circuit boards to be washed with water to remove flux residues.

Abstract: The invention provides a method and means of producing weld metal for use in joining two or more metallic pieces. The method includes the steps of providing a novel mixture of reactants comprising a reducing agent, a metallic compound which is exothermically reduced by the reducing agent, and a filler metal that does not react with the metallic compound. The mixture of reactants is then exothermically reacted so as to form the weld metal for joining the metallic pieces. At least about 90 percent by weight of the weld metal is produced by the filler metal and at least about 90 percent by weight of the weld metal has a chemical composition substantially similar to that of at least one of the metallic pieces being joined.

Abstract: A residue-free fluxing process wherein the active fluxing agent comprises a .beta.-diketone or .beta.-ketoimine ligand. Such ligands react with surface metal oxides on workpieces to be soldered to form volatile metal-ligand complexes as reaction products which are sublimed from the surface leaving essentially no residue on the workpieces. The fluxing agents can be utilized in gas-phase processes wherein the workpieces are contacted with an effective amount of one or more ligands which are dispersed in a carrier gas or solvent or by incorporating the ligands into an alloy-vehicle mixture for use as conventional creams or pastes. The invention eliminates the need for post-reflow cleaning using solvents since no flux residue remains on the workpieces to be soldered following volitilization of the metal-ligand complex.

Abstract: An improved solder/polymer fluxless composite paste interconnection material having a low reflow temperature to form electrical contacts having good bonding strength and low contact resistance. The present pastes comprise a major proportion of a meltable metal alloy powder filler, free of noble metals and preferably free of lead, a minor proportion of a solution of a temperature-stable thermoplastic polymer having a softening temperature above the melting temperature of the metal powder filler in a volatile solvent which evaporates during reflow, and a minor proportion of a fluxing agent having a boiling point lower than the reflow temperature of the composition and higher than the melting point of the eutectic alloy powder filler. An oxide-free, partially coalesced metal alloy connection is obtained, which is polymer strengthened and reworkable at a low reflow temperature, per se, or in the presence of polymer solvent.

Abstract: Improved soldering paste for the surface mounting of electronic components comprises a novel fluxing agent selected from quaternary ammonium hydroxides and mixtures thereof. Use of these agents as fluxes eliminates the problem of ionic residues on circuit boards and permits the boards to be washed with water to remove any non-ionic residues.

Abstract: According to the present invention, there is provided an electronic component part comprising (i) a high thermal conductivity ceramic circuit board, (ii) terminal pins located over said circuit board, and (iii) a metal brazing material having metal brazing powder, at least one element selected from the Group IVa elements and a metal having a melting point higher than that of the metal brazing powder, the metal brazing material bonding said board and said pins. According to the present invention, metal, such as input/output terminal pins can very firmly be bonded to ceramic, such as a circuit board, within an atmosphere of, for example, N.sub.2 gas without the scattering of any brazing material in which case, unlike the prior art method, any vacuum furnace is not employed.