Incorporation Procedures Patents (Class 162/183)
  • Patent number: 5830320
    Abstract: The invention is a method of enhancing the strength of paper products, particularly the dry strength, without adversely affecting repulpability. It is also directed to the resulting products. It is particularly applicable but not limited to products with significant amounts of secondary fiber in the furnish. Preferably, about 10-30% of the fiber is separated from the furnish at some point prior to sheeting. This is treated with a cationic wet strength resin which is allowed to bond to the fiber. Cationic polyamide-epichlorohydrin resins are particularly useful. The treated fiber is them mixed with the untreated balance of the fiber at some point before the paper machine. Screnning fines on repulping do not normally exceed 2-3%.
    Type: Grant
    Filed: September 18, 1996
    Date of Patent: November 3, 1998
    Assignee: Weyerhaeuser Company
    Inventors: David W. Park, Frank R. Hunter
  • Patent number: 5827398
    Abstract: Filled paper is made by adding a cationising amount of cationic polymer to a slurry of precipitated calcium carbonate, mixing this slurry into a cellulosic suspension and forming a thin stock, adding anionic particulate material to the suspension before or after the slurry, mixing a polymeric retention aid into the thin stock which includes the precipitated calcium carbonate and the anionic particulate material, draining the thin stock on a screen to form a sheet and drying the sheet. A suitable slurry for this purpose is a slurry of 5 to 70% by weight precipitated calcium carbonate and cationic polymer selected from 0.1 to 1% cationic starch and 0.01 to 0.3% of a high charge density, relatively low molecular weight, cationic polymer.
    Type: Grant
    Filed: February 13, 1996
    Date of Patent: October 27, 1998
    Assignees: Allied Colloids Limited, Mineral Technologies, Inc.
    Inventors: David Depasquale, Bruce Evans
  • Patent number: 5824192
    Abstract: Disclosed is a method for the production of paper and an adjuvant composition comprising the following ingredients: 30 to 80% by weight of phenolic resin or modified phenolic resin; 10 to 50% by weight of melamine resin; and 5 to 35% by weight of at least one naphthalene sulphonate salt. The ingredients are under granulated form or dissolved in an aqueous solution. The method comprises the step of admixing the adjuvant composition with a solution of one or several polyethylene oxide having a molecular weight varying from 1.times.10.sup.6 to 13.times.10.sup.6 and with an aqueous mixture comprising lignocellulosic particles and an aqueous medium to significantly improve the retention of particles such as fines and fibers, on a wire screen and the drainage of the aqueous medium.
    Type: Grant
    Filed: May 24, 1996
    Date of Patent: October 20, 1998
    Assignee: E. QU. I. P. International Inc.
    Inventor: Georges Radu
  • Patent number: 5810971
    Abstract: A liquid slurry of bentonite which comprises bentonite, water, a polyacrylate, and a sodium salt of silicic acid. Optionally, a sulfonate is present in an amount of between about 10 to about 30% by weight.
    Type: Grant
    Filed: October 4, 1996
    Date of Patent: September 22, 1998
    Assignee: Nalco Canada, Inc.
    Inventor: Daniel K. Chung
  • Patent number: 5810970
    Abstract: A method for making a collagen strengthened cellulosic sheet by providing a cellulosic pulp slurry; adding solubilized collagen to the pulp slurry, and mixing for a time effective for interaction of the cellulosic pulp slurry and solubilized collagen; forming the interacted cellulosic pulp slurry and solubilized collagen into a sheet; and drying the sheet; also, a method for using solubilized collagen for strengthening paper by mixing the solubilized collagen with a cellulosic pulp slurry; and making a cellulosic pulp product from the mixture and drying.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: September 22, 1998
    Assignee: Ranpak Corporation
    Inventors: Kenneth E. Hughes, David C. Masterson, David J. Fink, Barbara A. Metz, Gordon E. Pickett, Paul M. Gemmer
  • Patent number: 5798023
    Abstract: A method for minimizing pitch, ink, and stickies particle deposits in the paper making process by causing the retention of such particles onto fiber, comprising the steps of adding an effective pitch, ink, and stickies controlling amount of talc to a suspension of fiber in contact with the paper machine and associated parts and adding an effective pitch, ink, and stickies controlling amount of bentonite to the suspension, thereby increasing retention of pitch, ink, and stickies onto the fiber and minimizing the deposition of pitch, ink, and stickies particles on the paper machine and associated parts.
    Type: Grant
    Filed: May 14, 1996
    Date of Patent: August 25, 1998
    Assignee: Nalco Chemical Company
    Inventors: Przemyslaw Pruszynski, John R. Armstrong
  • Patent number: 5795439
    Abstract: The instant invention is directed to a process for making a non-woven, wet-laid, superabsorbent polymer-impregnated structure. The process generally comprises the steps of: mixing; deliquifying; and drying. Specifically, fibers, superabsorbent polymers, and a liquid are mixed to form a furnish. The liquid is treated with a means for inhibiting the swelling of the superabsorbent polymer. Then, the furnish is deliquified to form a preformed structure. The preformed structure is dried to form the non-woven, wet-laid, superabsorbent polymer-impregnated structure.
    Type: Grant
    Filed: January 31, 1997
    Date of Patent: August 18, 1998
    Assignee: Celanese Acetate LLC
    Inventors: Joanne M. Euripides, Lessie C. Phillips, Steven F. Nielsen
  • Patent number: 5792317
    Abstract: A method of applying a starch sizing to a forming web on a paper machine, such as in the form of a curtain on a fourdrinier machine, employs a suspension of uncooked particulate starch and water which is applied, as a suspension, to the inlet of a downwardly opening die positioned over the forming web and applied at a consistency of between about 2 to 10% onto the surface of the web as a free falling curtain, the impact velocity of which is controlled to a rate sufficiently low to prevent distortion of the web on impact. Improved drainage is achieved by heating the suspension to a temperature less than about 150.degree., to prevent the cooking of the starched particles. The curtain may be applied to the web at fourdrinier table consistencies as low as about 2% and still obtain starch retention rates of about 80%.
    Type: Grant
    Filed: February 7, 1996
    Date of Patent: August 11, 1998
    Assignees: GL&V-Paper Machine Group, Inc., Jefferson Smurfit Corporation
    Inventors: John Andrew Taylor, Marcus Francis Foulger, Joseph Edgar Parisian, III, Hanuman Prasad Didwania
  • Patent number: 5785813
    Abstract: An efficient and effective method for treating tissue making stock to make soft tissues involves adding a softening agent to a first papermaking furnish of short fibers, such as eucalyptus fibers. A second papermaking furnish of long fibers, such as softwood fibers, is blended with the short fiber furnish. Thereafter, wet strength agents and/or dry strength agents are added to the blended furnish. The treated furnish is then fed to a headbox and processed into soft tissue in any suitable manner.
    Type: Grant
    Filed: February 24, 1997
    Date of Patent: July 28, 1998
    Assignee: Kimberly-Clark Worldwide Inc.
    Inventors: Michael John Smith, Vinay Kumar Rao, Gary Lee Shanklin
  • Patent number: 5783041
    Abstract: A method for imparting dry strength to paper by adding to a pulp slurry during a paper-making process a mixed resin solution containing (i) an aminopolyamide-epichlorohydrin resin and (ii) a glyoxylated acrylamide-dimethyl diallyl ammonium chloride resin, in combination with (iii) a high charge density cationic polymer.
    Type: Grant
    Filed: April 18, 1996
    Date of Patent: July 21, 1998
    Assignee: Callaway Corporation
    Inventor: Richard T. Underwood
  • Patent number: 5779859
    Abstract: A method for improving retention of filler in papermaking systems includes a split stream feed to either the head box or fan pump of a papermaking system. The split stream divides the pulp flow into two streams, one stream having a retention aid and filler added thereto. The retention aid and filler-containing stream is then added back to the other stream upstream of the fan pump or head box. Treating only a portion of the overall pulp flow with the filler/retention aid lowers retention aid consumption, improves paper product appearance and maintains or increases filler retention during papermaking.
    Type: Grant
    Filed: December 13, 1996
    Date of Patent: July 14, 1998
    Assignee: J.M. Huber Corporation
    Inventors: Richard Douglas Carter, Britt Ciccrchi
  • Patent number: 5759349
    Abstract: This invention relates to the application of an optically active dye or fluorecent whitening agent within a paper fiber such that the dye or whitening agent does not migrate out of the fiber at a level of toxicological concern. Such processes of this type, generally, allow the dye or whitening agent to be used in hygienic end use applications.
    Type: Grant
    Filed: July 25, 1997
    Date of Patent: June 2, 1998
    Assignee: Westvaco Corporation
    Inventors: James Joseph Foster, Roger Wayne Ogden
  • Patent number: 5755930
    Abstract: Filled paper is made by adding a cationising amount of cationic polymer to precipitated calcium carbonate or other filler either as a slurry or in a thick stock component, producing a thin stock containing the cationised filler and then treating the thin stock with a formaldehyde resin and polyethylene oxide as a retention system prior to drainage and drying.
    Type: Grant
    Filed: February 13, 1996
    Date of Patent: May 26, 1998
    Assignees: Allied Colloids Limited, Minerals Technologies Inc.
    Inventors: Brian Frederic Satterfield, Bruce Evans, Thomas Adrian Cauley
  • Patent number: 5753077
    Abstract: In a web printing paper the base paper comprises of more than 50% wt. de-inked recycled fibers, 10-35% wt. mineral filler and the remainder being wood-pulp and/or cellulose and has a weight of 30 to less than 60 g/m.sup.2. The base paper is coated with a coating having a weight of 2 to 8 g per m.sup.2 and side and the binder proportion is no more than 15% wt. in relation to the coating pigment.
    Type: Grant
    Filed: September 21, 1995
    Date of Patent: May 19, 1998
    Assignee: Stora Feldmuhle AG
    Inventors: Dieter Horand, Adam Gurtler, Paul Heinz Dahling, Bernd Pelech
  • Patent number: 5744002
    Abstract: A method for making a collagen strengthened cellulosic sheet by providing a cellulosic pulp slurry; adding solubilized collagen to the pulp slurry, and mixing for a time effective for interaction of the cellulosic pulp slurry and solubilized collagen; forming the interacted cellulosic pulp slurry and solubilized collagen into a sheet; and drying the sheet; also, a method for using solubilized collagen for strengthening paper by mixing the solubilized collagen with a cellulosic pulp slurry; and making a cellulosic pulp product from the mixture and drying.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: April 28, 1998
    Assignee: Ranpak Corp.
    Inventors: Kenneth E. Hughes, David C. Masterson, David J. Fink, Barbara A. Metz, Gordon E. Pickett, Paul M. Gemmer, Richard S. Brody
  • Patent number: 5744001
    Abstract: Aqueous pigment slurries which contain up to 80% by weight of a finely divided pigment in dispersed form and from 0.1 to 5% by weight of dispersants which are obtainable by reacting(a) polyalkylenepolyamines, polyamidoamines, polyamidoamines grafted with ethyleneimine, polyetheramines and mixtures of the stated compounds and(b) monoethylenically unsaturated carboxylic acids, salts, esters, amides or nitriles of monoethylenically unsaturated carboxylic acids, chlorocarboxylic acids and/or glycidyl compounds and, if required,(c) bifunctional or polyfunctional crosslinking agents which have a halohydrin, glycidyl, aziridine or isocyanate unit or a halogen atom as a functional group,to give water-soluble condensates which, in 20% strength by weight aqueous solution at 20.degree. C., have a viscosity of at least 100 mPa.s are prepared by milling or dispersing pigments in the presence of the dispersants and water and are used as additives to paper stock in the production of filler-containing paper.
    Type: Grant
    Filed: August 23, 1995
    Date of Patent: April 28, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Friedrich Linhart, Dietmar Moench, Guenter Scherr, Wolfgang Reuther, Primoz Lorencak
  • Patent number: 5738759
    Abstract: A recording material including paper containing cellulose fibers as the main component, with the elongation percentage of the paper in the cross direction thereof when immersed in water at 20.degree. C. for 1 minute being 1.8 % or less, is produced and recycled. In addition, paper containing cellulose fibers, with the same elongation percentage as mentioned above in the machine direction thereof is also provided.
    Type: Grant
    Filed: October 2, 1995
    Date of Patent: April 14, 1998
    Assignee: Ricoh Company, Ltd.
    Inventors: Hiroshi Kitazawa, Shigeaki Kimura, Eiichi Kawamura, Toshiyuki Kawanishi, Masato Igarashi
  • Patent number: 5736010
    Abstract: A method for making a collagen strengthened cellulosic sheet by providing a cellulosic pulp slurry; adding solubilized collagen to the pulp slurry, and mixing for a time effective for interaction of the cellulosic pulp slurry and solubilized collagen; forming the interacted cellulosic pulp slurry and solubilized collagen into a sheet; and drying the sheet; also, a method for using solubilized collagen for strengthening paper by mixing the solubilized collagen with a cellulosic pulp slurry; and making a cellulosic pulp product from the mixture and drying.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: April 7, 1998
    Assignee: Ranpak Corporation
    Inventors: Kenneth E. Hughes, David C. Masterson, David J. Fink, Barbara A. Metz, Gordon E. Pickett, Paul M. Gemmer, Richard S. Brody
  • Patent number: 5733414
    Abstract: During the manufacture of paper from a cellulosic suspension, retention is improved by adding to the suspension a water soluble cationic polymer containing 0.1 to 15 mole % cationic monomer groups and having an intrinsic viscosity of at least 4 dl/g and then adding a substantially water soluble formaldehyde condensate resin. This resin is preferably a phenol sulphone formaldehyde resin. Preferred phenol sulphone formaldehyde resins are materials wherein at last 70 mole % of the recurring groups are dihydroxyl phenyl sulphone groups free of sulphonic acid groups.
    Type: Grant
    Filed: October 4, 1995
    Date of Patent: March 31, 1998
    Assignee: Allied Colloids Limited
    Inventor: John Oliver Stockwell
  • Patent number: 5723023
    Abstract: The method of making paper wherein the use of a selected ether or ester modified, cationic starch as an additive in the papermaking wet end provides significantly improves retention and drainage properties particularly in alkaline microparticle containing systems.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: March 3, 1998
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: John Tsai, Walter Maliczyszyn, Teresa Capitani, Christopher Kulp
  • Patent number: 5714042
    Abstract: A method for making a collagen strengthened cellulosic sheet by providing a cellulosic pulp slurry; adding solubilized collagen to the pulp slurry, and mixing for a time effective for interaction of the cellulosic pulp slurry and solubilized collagen; forming the interacted cellulosic pulp slurry and solubilized collagen into a sheet; and drying the sheet; also, a method for using solubilized collagen for strengthening paper by mixing the solubilized collagen with a cellulosic pulp slurry; and making a cellulosic pulp product from the mixture and drying.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: February 3, 1998
    Assignee: Ranpak Corporation
    Inventors: Kenneth E. Hughes, David C. Masterson, David J. Fink, Barbara A. Metz, Gordon E. Pickett, Paul M. Gemmer, Richard S. Brody
  • Patent number: 5711799
    Abstract: An improved form of calcium carbonate which is acid tolerant to enable its use as a filler material in the making of neutral to weakly acid paper, and a process for producing this acid tolerant calcium carbonate are provided. This acid tolerant calcium carbonate comprises a mixture of calcium carbonate with at least about 0.1 percent, based on the dry weight of the calcium carbonate, of sodium aluminate together with at least about 0.1 percent, based on the dry weight of the calcium carbonate, of one or more weak acids.
    Type: Grant
    Filed: March 13, 1996
    Date of Patent: January 27, 1998
    Assignee: ECC International Inc.
    Inventors: Kevin Snowden, Jose M. Rodriguez, Kuan-Ting Wu
  • Patent number: 5711853
    Abstract: A method for making a collagen strengthened cellulosic sheet by providing a cellulosic pulp slurry; adding solubilized collagen to the pulp slurry, and mixing for a time effective for interaction of the cellulosic pulp slurry and solubilized collagen; forming the interacted cellulosic pulp slurry and solubilized collagen into a sheet; and drying the sheet; also, a method for using solubilized collagen for strengthening paper by mixing the solubilized collagen with a cellulosic pulp slurry; and making a cellulosic pulp product from the mixture and drying.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: January 27, 1998
    Assignee: Ranpak Corp.
    Inventors: Kevin M. Virnelson, Kenneth E. Hughes, David C. Masterson, David J. Fink, Barbara A. Metz, Gordon E. Pickett, Paul M. Gemmer, Richard S. Brody
  • Patent number: 5707491
    Abstract: A method for making a collagen strengthened cellulosic sheet by providing a cellulosic pulp slurry; adding solubilized collagen to the pulp slurry, and mixing for a time effective for interaction of the cellulosic pulp slurry and solubilized collagen; forming the interacted cellulosic pulp slurry and solubilized collagen into a sheet; and drying the sheet; also, a method for using solubilized collagen for strengthening paper by mixing the solubilized collagen with a cellulosic pulp slurry; and making a cellulosic pulp product from the mixture and drying.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: January 13, 1998
    Assignee: Ranpak Corporation
    Inventors: Kenneth E. Hughes, David C. Masterson, David J. Fink, Barbara A. Metz, Gordon E. Pickett, Paul M. Gemmer, Richard S. Brody
  • Patent number: 5707493
    Abstract: A temperature-activated polysilicic acid is prepared by heating an acidified aqueous alkali metal silicate. The temperature-activated polysilicic acid is used in the production of paper for improvement of retention and water removal.
    Type: Grant
    Filed: January 29, 1996
    Date of Patent: January 13, 1998
    Assignee: J.M. Huber Corporation
    Inventor: Sakari Saastamoinen
  • Patent number: 5707494
    Abstract: An improved method for the production of water soluble polyaluminosilicate microgels, formed by the reaction of solutions of alkali metal silicates with solutions of acids containing dissolved aluminum compounds, is provided.
    Type: Grant
    Filed: January 6, 1997
    Date of Patent: January 13, 1998
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: John Derek Rushmere, Robert Harvey Moffett
  • Patent number: 5705033
    Abstract: Unique titanium dioxide (TiO.sub.2) particulates have an especially high physicochemical affinity for cellulosic fibers and, thus, are well suited as opacifying pigments for paper and paper laminates, and include a zeta potential-adjusting amount of at least one cationic polymer, e.g., a polymer of a quaternary ammonium, sulfonium or phosphonium salt or a copolymer of acrylamide with a cationic comonomer, fixed to the face surfaces thereof.
    Type: Grant
    Filed: December 30, 1992
    Date of Patent: January 6, 1998
    Assignee: Rhone-Poulenc Chimie
    Inventors: Bernard Gerard, Remy Lorang, Anny Mazzacavallo
  • Patent number: 5700352
    Abstract: A process for incorporating a fine particulate filler such as kaolin clay into tissue paper is disclosed. The process results in strong, soft, and low dusting tissue paper webs useful in the manufacture of soft, absorbent sanitary products such as bath tissue, facial tissue, and absorbent towels.
    Type: Grant
    Filed: April 3, 1996
    Date of Patent: December 23, 1997
    Assignee: The Procter & Gamble Company
    Inventors: Kenneth Douglas Vinson, Howard Thomas Deason
  • Patent number: 5700354
    Abstract: A method for making a collagen strengthened cellulosic sheet by providing a cellulosic pulp slurry; adding solubilized collagen to the pulp slurry, and mixing for a time effective for interaction of the cellulosic pulp slurry and solubilized collagen; forming the interacted cellulosic pulp slurry and solubilized collagen into a sheet; and drying the sheet; also, a method for using solubilized collagen for strengthening paper by mixing the solubilized collagen with a cellulosic pulp slurry; and making a cellulosic pulp product from the mixture and drying.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: December 23, 1997
    Assignee: Ranpak Corp.
    Inventors: Kevin M. Virnelson, Kenneth E. Hughes, David C. Masterson, David J. Fink, Barbara A. Metz, Gordon E. Pickett, Paul M. Gemmer, Richard S. Brody
  • Patent number: 5700353
    Abstract: A method for making a collagen strengthened cellulosic sheet by providing a cellulosic pulp slurry; adding solubilized collagen to the pulp slurry, and mixing for a time effective for interaction of the cellulosic pulp slurry and solubilized collagen; forming the interacted cellulosic pulp slurry and solubilized collagen into a sheet; and drying the sheet; also, a method for using solubilized collagen for strengthening paper by mixing the solubilized collagen with a cellulosic pulp slurry; and making a cellulosic pulp product from the mixture and drying.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: December 23, 1997
    Assignee: Ranpak Corporation
    Inventors: Kenneth E. Hughes, David C. Masterson, David J. Fink, Barbara A. Metz, Gordon E. Pickett, Paul M. Gemmer, Richard S. Brody
  • Patent number: 5695609
    Abstract: The invention relates to a process for the production of paper by adding to an aqueous fiber suspension, which possibly contains a filler, auxiliary agents for improving retention and/or dewatering, the auxiliary agents being a cationic long-chain polyacrylamide and an aluminum salt, and by dewatering the obtained fiber suspension during the sheet-forming stage. According to the invention, the said aqueous fiber suspension, possibly containing a filler, to which the cationic long-chain polyacrylamide has first been added, is subjected to shearing forces, whereafter there is added to it, directly before sheet forming, a polymeric aluminum salt or an aluminum salt, in which case a base or an acid is added, when necessary, to the said fiber suspension so that the pH be within the range 7-9 before the sheet forming, in which case aluminum hydroxy particles having anionic surface charges will be formed in situ.
    Type: Grant
    Filed: January 19, 1996
    Date of Patent: December 9, 1997
    Assignee: Kemira Oy
    Inventors: Lars Harald Petander, Tore Anders Duvnas
  • Patent number: 5690789
    Abstract: Speckle-patterned paper is produced on the paper machine without the use of printing techniques by first preparing speckle-forming material and then introducing this into a contrasting color papermaking furnish. Paper is then made from the speckle-containing furnish in the normal way. The speckle-forming material is produced either by agglomerating a mixture of papermaking fiber, particulate pigment and, preferably, a latex or other binder or by dry comminution of cellulose fiber aggregates in the form of paper or entangled fiber clumps.
    Type: Grant
    Filed: May 4, 1995
    Date of Patent: November 25, 1997
    Assignee: The Wiggins Teape Group Limited
    Inventors: Edward Charles Small, Brian Edward Evans
  • Patent number: 5690790
    Abstract: The present invention relates to paper products having temporary wet strength. The paper products contain cellulosic fibers that are treated with a polyaldehyde polymer having free aldehyde groups and a water soluble polyhydroxy polymer. The initial wet strength obtained with the combined use of these materials is significantly greater than that obtained by use of either the polyaldehyde or pelyhydroxy polymer alone. At the same time, the wet strength decays at a rate that is rapid enough to enable the paper product to be flushed under conditions of normal use.
    Type: Grant
    Filed: March 28, 1996
    Date of Patent: November 25, 1997
    Assignee: The Procter & Gamble Company
    Inventors: Michael Martyn Headlam, David Jay Smith
  • Patent number: 5688371
    Abstract: Process for fixing anionic interfering substances in papermaking process by the addition of cationic polycondensation products obtained by reactinga) a monofunctional or polyfunctional amine having one or more primary and/or secondary and/or tertiary amino groups withb) cyanamide, dicyandiamide, guanidine or biguanidine, wherein up to 50 mol. % of cyanamide, dicyandiamide or biguanidine may be replaced with a dicarboxylic acid or a mono- or diester thereof, with elimination of ammonia, optionally in the presence of a catalyst,optionally together with other auxiliaries.
    Type: Grant
    Filed: June 18, 1996
    Date of Patent: November 18, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Joachim Konig, Jurgen Kopp, Udo-Winfried Hendricks, Jurgen Reiners, Peter Nowak
  • Patent number: 5686262
    Abstract: The invention includes a method that provides a low cost aqueous solution of solubilized collagen by the steps of: (a) providing an aqueous ground slurry of insoluble collagen and adjusting the pH of said slurry to obtain activity for a proteolytic enzyme added in Step b; (b) adding said proteolytic enzyme to said pH adjusted slurry; (c) reacting the slurry and enzyme of Step b and/or recycled insoluble collagen and enzyme from Step e at a temperature, T, and for a time, t, effective for forming a solution increased in solubilized collagen; (d) adding additional water and insoluble collagen to said solution of Step c and mixing; (e) separating at least some of the solution of Step d containing solubilized collagen from insoluble collagen, whereby at least a portion of said insoluble collagen and proteolytic enzyme is recycled to Step c, and the separated solution containing solubilized collagen is withdrawn as product; an alternative embodiment provides for the direct production of solubilized collagen withou
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: November 11, 1997
    Assignee: Ranpak Corporation
    Inventors: David J. Fink, Richard S. Brody
  • Patent number: 5679308
    Abstract: A porous material such as paper made of cellulose fiber prepared by a preservation method of the present invention can retain excellent folding endurance after being subjected to accelerated aging treatment performed at a high temperature with high humidity. The method for preserving the porous material includes the steps of placing a porous material made of mainly cellulose fiber in an airtight chamber, evacuating the airtight chamber to reduce the pressure, supplying an ammonia gas into the airtight chamber to thereby neutralize an acidic substance present in the porous material, simultaneously permitting the porous material to absorb the ammonia gas, and supplying an ethylene-oxide-containing gas into the airtight chamber to thereby react with an ammonia present on the surface of and inside the porous material, thus producing an alkaline substance principally consisting of triethanolamine and allowing the alkaline substance to attach to the porous material.
    Type: Grant
    Filed: October 24, 1995
    Date of Patent: October 21, 1997
    Assignee: Nippon Filing Co., Ltd.
    Inventors: Raysabro Oye, Takayuki Okayama, Masaaki Akagi
  • Patent number: 5679220
    Abstract: A method for enhancing the deposition and retention of particulate filler on papermaking fibers. In a first vessel, there is formed a slurry of papermaking fibers and in a second vessel there is formed a slurry of lime or its equivalent. The fiber slurry is at a consistency of not greater than about 5%. These separately formed slurries are thereafter combined with a gaseous precipitant in a flow reactor and under conditions whereby the gaseous precipitant is subjected to rapid shear and calcium carbonate is deposited in situ on the fibers. Unexpectedly, the reaction time for the formation and deposition of the calcium carbonate filler is very rapid. Control over the pH of the reactants in the reactor is achieved through the sequence of introduction of the reactants to the reactor. Also, through selection of the molar ratio of the gaseous precipitant and lime, the morphology of the calcium carbonate crystals may be controlled.
    Type: Grant
    Filed: January 19, 1995
    Date of Patent: October 21, 1997
    Assignee: International Paper Company
    Inventors: M. C. Matthew, Sanjay Patnaik, Paul Hart, Thomas Amidon
  • Patent number: 5676796
    Abstract: Paper is made by forming a thick stock cellulosic suspension, flocculating the thick stock by adding a relatively high molecular weight and relatively low cationic charge density polymer, diluting the flocculated thick stock to form a thin stock and then draining the thin stock to form a sheet. Usually coagulant is added to the thin stock before drainage and best results are achieved by adding coagulant followed by anionic colloidal material such as bentonite. The process can be operated to give good retention and good formation and, if the thick stock is dirty, to minimise pitch problems.
    Type: Grant
    Filed: February 1, 1996
    Date of Patent: October 14, 1997
    Assignee: Allied Colloids Limited
    Inventor: Paul Kenneth Cutts
  • Patent number: 5672249
    Abstract: A process for incorporating a fine particulate filler such as kaolin clay into tissue paper is disclosed. The process results in strong, soft, and low dusting tissue paper webs useful in the manufacture of soft, absorbent sanitary products such as bath tissue, facial tissue, and absorbent towels.
    Type: Grant
    Filed: April 3, 1996
    Date of Patent: September 30, 1997
    Assignee: The Procter & Gamble Company
    Inventors: Kenneth Douglas Vinson, John Paul Erspamer, Charles William Neal, Jonathan Andrew Ficke, Jeffress Paul Halter
  • Patent number: 5670021
    Abstract: A process for the production of paper by forming and dewatering a suspension of cellulose containing fibers and optional fillers and cationic starch on a wire or fabric, characterized in that the forming and dewatering takes place in the presence of an alkali metal silicate and a phenolic resin added at the same point into the suspension, and polyethylene oxide added at a subsequent point into the suspension. The amount of alkali metal silicate is 0.1 kg per ton to 50 kg/ton based on silica content per ton of dry fibers. The amount of phenolic resin is 0.01 kg/ton to 5 kg/ton based on weight of resin in the as-supplied material per ton of dry fibers. The amount of polyethylene oxide is 0.01 to 2.0 kg/ton based on weight of polyethylene oxide per ton of dry fibers.
    Type: Grant
    Filed: October 31, 1994
    Date of Patent: September 23, 1997
    Assignee: Kemira Kemi Aktiebolag
    Inventor: Michael Owens
  • Patent number: 5665205
    Abstract: A high level of calcium carbonate filler is added to secondary fiber pulp by in situ attachment to the secondary fibers. The secondary fiber pulp is mixed with an alkaline salt such as calcium oxide or calcium hydroxide and contacted with a reaction gas such as carbon dioxide in a gas-liquid contactor apparatus through efficient mixing in order to precipitate filler material such as calcium carbonate crystal complexes on the secondary fibers. The resulting pulp products have comparable or, in some cases, better brightness, cleanliness, and other sheet properties as compared to filler addition by conventional methods.
    Type: Grant
    Filed: January 19, 1995
    Date of Patent: September 9, 1997
    Assignee: International Paper Company
    Inventors: Narendra R. Srivatsa, Sanjay Patnaik, Paul Hart, Thomas E. Amidon, Jean J. Renard
  • Patent number: 5653795
    Abstract: A method is disclosed for producing bulking and opacifying pigments for filling paper by the selective aggregation of fine particles in an anionically or cationically dispersed slurry, such that an aggregated structure is formed which contains within it a labyrinth of internal voids or pores. The aqueous slurry is formed at one to thirty percent solids. A low molecular weight agent of opposite ionic charge is then added to the slurry to selectively aggregate the fine particles present. The resultant aggregates are of larger mean particle size than the feed material and contain little or no fine and colloidal particles. The net charge present on the aggregated particles is lower than that of the feed material.
    Type: Grant
    Filed: November 16, 1995
    Date of Patent: August 5, 1997
    Assignee: Columbia River Carbonates
    Inventor: Alan J. Brown
  • Patent number: 5651862
    Abstract: Described is a wet-formed composite. The wet-formed composite is formed from a combination of fibers and absorbent material. Specifically, the wet-formed composite is formed from absorbent material and a fiber slurry wherein the absorbent material is swellable in the dispersion medium of the slurry. Also disclosed is a method of forming the wet-formed composite. The method involves forming a fiber slurry, combining an absorbent material with the fiber slurry prior to forming the composite and then forming and drying the composite. The absorbent material is swellable in the dispersion medium of the fiber slurry.
    Type: Grant
    Filed: August 13, 1991
    Date of Patent: July 29, 1997
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Richard Allen Anderson, Richard John Schmidt
  • Patent number: 5647956
    Abstract: A composition comprising aqueous cellulosic furnish, a high molecular weight cationic polymer, and a modified lignin wherein the ratio of the cationic polymer to the modified lignin is from about 10:1 to 1:10 on an active basis is disclosed. A process employing this composition for making paper or paperboard having improved drainage, retention and formation properties is also provided.
    Type: Grant
    Filed: December 4, 1995
    Date of Patent: July 15, 1997
    Assignee: Calgon Corporation
    Inventors: David L. Elliott, Wood E. Hunter, Ronald J. Falcione
  • Patent number: 5647957
    Abstract: A method for making a collagen strengthened cellulosic sheet by providing a cellulosic pulp slurry; adding solubilized collagen to the pulp slurry, and mixing for a time effective for interaction of the cellulosic pulp slurry and solubilized collagen; forming the interacted cellulosic pulp slurry and solubilized collagen into a sheet; and drying the sheet; also, a method for using solubilized collagen for strengthening paper by mixing the solubilized collagen with a cellulosic pulp slurry; and making a cellulosic pulp product from the mixture and drying.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: July 15, 1997
    Assignee: Ranpak Corporation
    Inventors: Kenneth E. Hughes, David C. Masterson, David J. Fink, Barbara A. Metz, Gordon E. Pickett, Paul M. Gemmer, Richard S. Brody
  • Patent number: 5643414
    Abstract: Silica sols having a high content of microgel and aluminum modified particles with high specific surface area. The sols can be prepared by a process comprising acidification of a water glass solution, alkalization at a certain dry substance content, particle growth and aluminum modification. The sols are particularly suitable for use as additives, in combination with cationic polymers, in papermaking.
    Type: Grant
    Filed: June 27, 1994
    Date of Patent: July 1, 1997
    Assignee: EKA Nobel AB
    Inventors: Hans Erik Johansson, Bo Valdemar Larsson
  • Patent number: 5633300
    Abstract: A process for making paper to enhance the dry strength of the paper produced without substantially reducing its softness comprising adding to a bleached pulp furnish, separately or together, (1) an anionic polymer selected from the group consisting of carboxymethyl guar, carboxymethyl bean gum, carboxymethyl hydroxyethyl guar, and a carboxymethyl hydroxypropyl guar, with (2) a cationic polymer selected from the group consisting of a cationic guar, a cationic acrylamide copolymer, a cationic bean gum, a cationic amineepichlorohydrin wet strength resin, and both a cationic wet strength resin and at least one of the other said cationic polymers, a composition for adding to a paper-making pulp slurry comprising the said polymers, a method for making the said composition, and a paper product containing the said composition, are disclosed.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: May 27, 1997
    Assignee: Hercules Incorporated
    Inventor: Sunil P. Dasgupta
  • Patent number: 5626721
    Abstract: An improved method for the production of water soluble polyaluminosilicate microgels, formed by the reaction of solutions of alkali metal silicates with solutions of acids containing dissolved aluminum compounds, is provided.
    Type: Grant
    Filed: December 6, 1995
    Date of Patent: May 6, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: John D. Rushmere, Robert H. Moffett
  • Patent number: 5620565
    Abstract: Paper products such as bathroom tissue, facial tissue, napkins and paper towels are made from high coarseness fibers such as recycled newsprint fibers, CTMP, TMP, and groundwood. These products exhibit premium level qualities in terms of softness, bulk, and flexibility. The novel process selectively treats these high coarseness fibers in a way that makes the fibers feel softer and enhances papermachine operation with this type of furnish, thereby permitting higher product quality levels than previously possible with high coarseness fibers.
    Type: Grant
    Filed: October 26, 1995
    Date of Patent: April 15, 1997
    Assignee: Kimberly-Clark Corporation
    Inventors: Nicholas W. Lazorisak, John F. Schmitt, Reginald Smith
  • Patent number: RE35460
    Abstract: The present invention relates to a method for loading a chemical compound within the fibers of a fibrous material and to the fibrous materials produced by the method. In the method, a fibrous cellulose material is provided which consists of a plurality of elongated fibers having a fiber wall surrounding a hollow interior. The fibrous material has a moisture content such that the level of water ranges from 40-95% of the weight of the fibrous material and the water is positioned substantially within the hollow interior of the fibers and within the fiber walls of the fibers. A chemical is added to the fibrous material in a manner such that the chemical is disposed in the water present in the fibrous material. The fibrous material is then contacted with a gas which is reactive with the chemical to form a water insoluble chemical compound. The method provides a fibrous material having a chemical compound loaded within the hollow interiors and within the fiber walls of the plurality of fibers.
    Type: Grant
    Filed: October 21, 1993
    Date of Patent: February 25, 1997
    Assignee: The United States of America as represented by the Secretary of Agriculture
    Inventors: John H. Klungness, Daniel F. Caulfield, Irving B. Sachs, Marguerite S. Sykes, Freya Tan, Richard W. Shilts