Abstract: Cement compositions containing a hydraulic cement, a synthetic phyllosilicate (e.g. Laponite®), and silica flour. The cement compositions may optionally include other additives such as an expandable agent, a defoamer, and a fluid loss controller. Cement slurries and wellbore cements made therefrom are also specified. The inclusion of the synthetic phyllosilicate has enhanced the mechanical strength, improved the density homogeneity, as well as decreased the permeability of the wellbore cement, making it suitable for cementing oil and gas wells under high pressure and high temperature (HPHT) conditions.

Abstract: A fracturing fluid can include: a base fluid, wherein the base fluid comprises water; proppant; a friction reducer; and a friction reducer enhancer, wherein the friction reducer enhancer is a surfactant. The friction reducer enhancer can be in a concentration greater than or equal to a critical micelle concentration. Methods of fracturing a subterranean formation can include introducing the fracturing fluid into the subterranean formation. The friction reducer enhancer can increase the hydration rate of the friction reducer, whereby friction reduction of the fracturing fluid can occur much faster than without the friction reducer enhancer.

Abstract: Methods, compositions, and tools for use in creating rapidly forming plugs in situ in subterranean formations. In one instance, the disclosure provides a method that includes: placing a first pill comprising a calcium-aluminate-based cement composition at a plug location within the wellbore with the tubing; and placing a second pill comprising an alkaline fluid composition into the wellbore adjacent to the first pill with the tubing. In some cases there is a spacer fluid or spacer device between the first pill and the second pill. In some cases tubing having a mixing device is located at the bottom of the tubing in the wellbore to aid I mixing the first pill and the second pill to facilitate a chemical in situ reaction of the first pill and the second pill. The reaction between the first pill and the second pill forms a set plug at the plug location.

Abstract: A surfactant foam for enhanced oil recovery (EOR) gas injection that includes a surfactant and Aloe vera gel. The surfactant may be a methanol surface active agent foamer. The surfactant foam may be generated in-situ from an injected gas (such as air or nitrogen), water (such as seawater), a surfactant, and Aloe vera gel. A process for enhancing oil recovery in a hydrocarbon reservoir using the surfactant foam and for manufacturing the foam are also provided.

Abstract: A method and a system for a water shut off material in a wellbore are provided. In an exemplary embodiment the water shutoff material includes a precipitate formed from a solution of asphaltene and an aqueous precipitant.

Abstract: Described herein are plugging materials with polysaccharides that can be used in wellbore operations. A plugging material can include hydraulic cement, amorphous silica, polysaccharides, a retarder, clay, and an aqueous base, where the material is injectable into a wellbore. The polysaccharides can be cross-linked with borate. The retarder can be at least one of an organo phosphoric acid, a modified sulfonated styrene-maleic anhydride polymer, lignosulfonate, or a polyacrylic acid.

Abstract: A viscosified aqueous solution, optionally for use in a subterranean wellbore, is made by reacting in aqueous solution (i) an initial polymer with either carboxylic acid or amino groups on its polymer chain, (ii) a second compound with an amino group or carboxylic acid group, and (iii) a coupling agent, so that molecules of the second compound join to the polymer chain through amide groups, thereby forming an aqueous solution of a modified polymer which, without separation from the aqueous solution, participates in cross-linking thereby enhancing viscosity of the solution. The second compound may include hydrophobic groups so that the modified polymer contains hydrophobic groups and is able to cross-link with itself or a viscoelastic surfactant through association of hydrophobic groups (without covalent bond formation) in aqueous solution. Such cross-links can reform after the fluid has been subjected to shear.

Abstract: Methods and systems for removing a gel from wellbore equipment. An example method includes introducing a cleaning fluid into the wellbore equipment comprising the gel disposed therein or thereon. The cleaning fluid includes a brine having a total dissolved solids concentration of between about 30K ppm to about 300K ppm. The method further includes contacting the gel with the cleaning fluid in the wellbore equipment, and removing the gel and the cleaning fluid from the wellbore equipment.

Abstract: Aqueous fluids containing hydrophobic particles are effective media for cleaning water-base drilling fluids and drilling fluid solids from the interior surface of a casing string. Hydrophobic fibers may be added to a drilling fluid, a spacer fluid, a sacrificial spacer fluid, a chemical wash, or combinations thereof. The disclosed fluids may be employed during primary cementing operations where it is not possible to use a bottom plug.

Abstract: Systems and methods include using a fracture fluid downhole for fracturing a formation. The method includes providing an aqueous solution comprising dissolved solids at a certain ionic strength, and adding a proppant to create a fracture fluid. The method continues by adding a polymeric additive and a surfactant to the fracture fluid, wherein the polymeric additive comprises friction reducing capabilities that can be decreased by the ionic strength present in the fracture fluid (i.e., ionic strength originally found in the water). The addition of the polymeric additive and the surfactant to the fracture fluid creates an enhanced fracture fluid, wherein the surfactant increases the performance of the friction reducing capabilities of the polymeric additive in the enhanced fracture fluid, which provides a more efficient fracturing operation. The method concludes by pumping the enhanced fracture fluid downhole for a more efficient fracture of the formation.

Abstract: An example method includes pumping fluid into a wellbore to fill, at least partly, a region in a lost circulation zone, with the fluid having a first density; and after pumping the fluid, pumping cement slurry into the wellbore. The cement slurry has a second density. The first density is greater than, or equal to, the second density, which causes the fluid to prevent, at least partly, the cement slurry from mixing with other fluid in the lost circulation zone for at least a period of time.

Abstract: A method of cementing a wellbore comprises combining an alginate suspension additive with a cement slurry to form a cementing composition, the cement slurry comprising an aqueous carrier and a cementitious component; injecting the cementing composition into the wellbore; and allowing the cement composition to set.

Abstract: Methods for using treatment fluids comprising synthetic silicates in subterranean formations are provided. In some embodiments, the methods may comprise introducing a treatment fluid comprising an aqueous base fluid and a synthetic silicate into a wellbore penetrating at least a portion of a subterranean formation comprising a loss zone; allowing the treatment fluid to displace at least a portion of a first fluid present in the wellbore; and allowing the treatment fluid to at least partially plug the loss zone.

Abstract: Lost circulation compositions, systems, and methods of using the same are described. A lost circulation composition comprises a water-swellable starch graft copolymer; and a carrier fluid. A method for bridging a lost circulation zone comprises providing a lost circulation composition comprising a water-swellable starch graft copolymer and a carrier fluid. Then introducing the lost circulation composition into a wellbore within a subterranean formation, wherein the subterranean formation comprises a lost circulation zone. Finally the lost circulation composition is placed into the lost circulation zone.

Abstract: Various embodiments disclosed relate to cement activator compositions for treatment of subterranean formations. In various embodiments, the present invention provides a method of treating a subterranean formation including placing in the subterranean formation a liquid cement activator composition including water, an alkali sulfate salt, a polyphosphate salt, and a stabilizer polymer.

Abstract: A combination of three polymers including a crosslinked acrylamide-TBAS copolymers in inverse emulsion form, N-vinyl pyrrolidone-acrylamide-TBAS terpolymer, and crosslinked N-vinyl pyrrolidone-acrylamide-TBAS acts as high temperature, high pressure fluid loss control additives for water-based drilling fluids systems. The combination is particularly useful for high salt, high density drilling fluids, and high temperature applications.

Abstract: Invert emulsion drilling fluids having a combination of fatty acids derived from waste vegetable oil (WVO) and a fatty amine as a rheology modifier are provided. An invert emulsion drilling fluid may include a water in oil emulsion, an invert emulsifier, a fatty amine having six to thirty carbon atoms, and a fatty acid having six to eighteen carbon atoms. The fatty acid is provided by esterifying a waste vegetable oil to produce a methyl ester of the waste vegetable oil and cleaving an ester group from the methyl ester of the waste vegetable oil. The invert emulsion drilling fluid may be formulated free of organoclay. Methods of drilling a wellbore using an invert emulsion drilling fluid are also provided.

Abstract: A method for isolating a first region and a proximate second region of a subterranean formation is disclosed that includes introducing an asphaltene composition into the first region of the subterranean formation, the asphaltene composition including asphaltene dissolved in a solvent, and after introducing the asphaltene composition, introducing an aqueous composition to the first region to precipitate the asphaltene in the first region. The precipitated asphaltene forms a barrier that isolates the second region from at least a portion of the first region.

Abstract: Methods and systems for cementing casing in a wellbore are described. The methods include introducing a modified biopolymer into an inner diameter of the casing, reverse-circulating a cement composition in the wellbore, permitting the modified biopolymer to contact the cement composition, and terminating the reverse-circulation upon detection of an increase in pressure in pumping the cement composition. The modified biopolymer includes a reaction product of a biopolymer and an organic carbonate, and the cement composition has a pH greater than 11.

Abstract: A method and system for inhibiting corrosion of a surface in a well including introducing a composition into the well, the composition comprising an acidic medium and Dihydrogen (ethyl) [4-[4-[ethyl(3-sulphonatobenzyl)amino] (4-hydroxy-2-sulphonatobenzhydrylidene]cyclohexa-2,5-dien-1-ylidene](3-sulphonatobenzyl)ammonium), contacting the metal surface with the composition, and inhibiting corrosion of the metal surface with the Dihydrogen (ethyl)[4-[4-[ethyl(3-sulphonatobenzyl)amino](4-hydroxy-2-sulphonatobenzhydrylidene]cyclohexa-2,5-dien-1-ylidene] (3-sulphonatobenzyl)ammonium).

Abstract: Swellable packer assemblies for providing a physical barrier inside a wellbore are provided. In one embodiment, the swellable packer comprises at least one seal element disposed on an outer surface of a tubular body portion which swells when contacted with one or more gases, the seal element comprising a polymer derived from a perfluoro vinyl monomer.

Abstract: Disclosed herein are polymer compositions useful in high temperature enhanced oil recovery applications. The polymer compositions include at least 20 mol % of an N,N-dialkyl-N,N-diallylammonium salt and further have a net negative charge. The polymer compositions provide polymer dispersions in water or brine having stable viscosity when maintained at temperatures of 100° C. and above for at least 2 days.

Abstract: A method of modifying an alteration zone of a formation near a wellbore using a non-Newtonian polymeric composition created from a reaction of a non-Newtonian combination comprises the steps of mixing an anhydrous tetraborate and a fluid to create a crosslinker solution, mixing a crosslinkable polyvinyl alcohol and water to create a polymer solution, where the crosslinker solution and the polymer solution form the non-Newtonian combination, pumping the non-Newtonian combination to a reaction zone in the wellbore, where pumping the non-Newtonian combination is configured to induce mixing of the polymer solution and the crosslinker solution, allowing the non-Newtonian combination to react to form the non-Newtonian polymeric composition, allowing the non-Newtonian polymeric composition to migrate to the alteration zone, where the non-Newtonian polymeric composition migrates due to gravity, and allowing the non-Newtonian polymeric composition to interact with the alteration zone to modify the alteration zone.

Abstract: A method of treating lost circulation issues stemming from loss zones during the drilling and cementing process through the utilization of a thixotropic cement. The method comprises the steps of encountering a loss zone in a bore hole during drilling or running casing and pumping a treatment fluid into the loss zone, wherein the treatment fluid is a gel capable of gelling, breaking when sheared, and building back shear strength after shearing is removed.

Abstract: A breaker composition for use in a fracturing fluid comprises water, at least one peroxide (e.g., tert-butyl hydroperoxide), and optionally at least one alcohol (e.g., propylene glycol and/or a butyl alcohol). The peroxide(s) and optional alcohol(s) are present in amounts effective to reduce the viscosity of a fracturing fluid at a temperature of 90-300 F. (the “breaking temperature”), and to prevent rehealing of the fracturing fluid, i.e., to maintain the reduced viscosity for a period of time after the temperature is reduced from the breaking temperature to a temperature below the breaking temperature (e.g., after the temperature is reduced from the breaking temperature to room temperature).

Abstract: A combination of three polymers including a crosslinked acrylamide-TBAS copolymers in inverse emulsion form, N-vinyl pyrrolidone-acrylamide-TBAS terpolymer, and crosslinked N-vinyl pyrrolidone-acrylamide-TBAS acts as high temperature, high pressure fluid loss control additives for water-based drilling fluids systems. The combination is particularly useful for high salt, high density drilling fluids, and high temperature applications.

Abstract: Diverter compositions including an invert emulsion. A method of treating a subterranean formation. The method can include placing in a subterranean formation a diverter composition including an invert emulsion. The invert emulsion includes a continuous oil phase that includes at least one rheological modifier. The invert emulsion also includes an internal aqueous phase.

Abstract: A method of modifying an alteration zone of a formation near a wellbore using a non-Newtonian polymeric composition created from a reaction of a non-Newtonian combination comprises the steps of mixing an anhydrous tetraborate and a fluid to create a crosslinker solution, mixing a crosslinkable polyvinyl alcohol and water to create a polymer solution, where the crosslinker solution and the polymer solution form the non-Newtonian combination, pumping the non-Newtonian combination to a reaction zone in the wellbore, where pumping the non-Newtonian combination is configured to induce mixing of the polymer solution and the crosslinker solution, allowing the non-Newtonian combination to react to form the non-Newtonian polymeric composition, allowing the non-Newtonian polymeric composition to migrate to the alteration zone, where the non-Newtonian polymeric composition migrates due to gravity, and allowing the non-Newtonian polymeric composition to interact with the alteration zone to modify the alteration zone.

Abstract: A method of servicing a wellbore in a subterranean formation having one or more lost circulation zones comprising placing a wellbore servicing fluid comprising a sealing composition into the wellbore, wherein the sealing composition comprises a latex and an accelerator and wherein the latex, the accelerator or both are encapsulated with an encapsulation material. A wellbore servicing fluid comprising a latex and an accelerator wherein the latex, the accelerator, or both are encapsulated.

Abstract: A method for reducing lost circulation in a subterranean formation. The method includes providing a treatment fluid comprising a base fluid and a lost circulation material comprising cane ash. The treatment fluid is introduced into a wellbore within the subterranean formation such that at least a portion of the cane ash bridges openings in the subterranean formation to reduce loss of fluid circulation into the subterranean formation.

Abstract: The disclosure is directed to polyelectrolyte complex nanoparticles that can be used to deliver agents deep into hydrocarbon reservoirs. Methods of making and using said polyelectrolyte complex nanoparticles are also provided.

Abstract: A method of modifying an alteration zone of a formation near a wellbore using a non-Newtonian polymeric composition created from a reaction of a non-Newtonian combination comprises the steps of mixing an anhydrous tetraborate and a fluid to create a crosslinker solution, mixing a crosslinkable polyvinyl alcohol and water to create a polymer solution, where the crosslinker solution and the polymer solution form the non-Newtonian combination, pumping the non-Newtonian combination to a reaction zone in the wellbore, where pumping the non-Newtonian combination is configured to induce mixing of the polymer solution and the crosslinker solution, allowing the non-Newtonian combination to react to form the non-Newtonian polymeric composition, allowing the non-Newtonian polymeric composition to migrate to the alteration zone, where the non-Newtonian polymeric composition migrates due to gravity, and allowing the non-Newtonian polymeric composition to interact with the alteration zone to modify the alteration zone.

Abstract: A system is described for evaluating coagulation of particles in a downhole fluid-particle mixture based on dielectric measurements. An example downhole treatment is one in which flocs are used to plug a high-permeability subterranean formation zone as part of a stimulation procedure. An injection tube is positioned within the wellbore to the high-permeability zone. An instrumented section of tubing includes one or more dielectric probes that are positioned and configured to make dielectric measurements of the particle-fluid mixture flowing in the tubing or in the annulus. The downhole dielectric measurements are used to indicate whether or not the particle-fluid mixture has the desired structural properties. An operator on the surface can make adjustments in real-time according to the received dielectric measurements.

Abstract: A drilling mud composition including Aloe vera particles with a largest dimension of 75-600 ?m, an aqueous base fluid, and a viscosifier, where the Aloe vera particles are present in the drilling mud composition at a concentration of less than 150 ppm, relative to the total weight of the drilling mud composition. A process for fracking a geological formation, whereby the drilling mud composition is injected into the geological formation through a well bore at a pressure of at least 5,000 psi to fracture the geological formation.

Abstract: Water and gas flow into a subterranean reservoir may be reduced by pumping into the reservoir a multi-aldehyde crosslinking agent and a low molecular weight polyacrylamide capable of crosslinking with the crosslinking agent. The reaction product forms a gel plug impermeable to water and gas.

Abstract: A well treatment fluid contains a surface modifying treatment agent having an anchor and a hydrophobic tail. The surface modifying treatment agent is an organophosphorus acid derivative. After the well treatment fluid is pumped into a well penetrating the subterranean formation, the anchor binds to the surface of the formation. The subterranean formation is a siliceous formation or a metal oxide-containing subterranean formation. The anchor bonds to a Si atom when the formation is a siliceous formation and to the metal of the metal oxide when the formation is a metal oxide-containing formation. After being bound to the surface of the formation, frictional drag within the well is reduced. This allows for faster recovery of formation fluids. The bonding of the surface modifying treatment agent onto the formation may further be enhanced by first pre-treating the formation with a non-aqueous fluid.

Abstract: A low-polymer-load fracturing fluid may include an aqueous carrier fluid, proppant, and polymer-treated degradable fibers. The polymer-treated degradable fibers may include degradable fibers that have been at least partially treated with a crosslinkable, hydratable polymer. In some instances, a method may involve placing a low-polymer-load fracturing fluid having an initial viscosity into a subterranean formation penetrated by a wellbore at a rate to generate pressure above fracture gradient to form or enhance at least one fracture in the formation matrix surrounding a designated portion of the wellbore; placing the low-polymer-load fracturing fluid into the fracture and allowing the polymer to crosslink and increase the initial viscosity to a gelled viscosity; and allowing the polymer-treated degradable fibers to degrade and reduce the gelled viscosity to a broken viscosity.

Abstract: Methods for mitigating precipitation during matrix acidizing of a subterranean formation. The methods generally comprise introducing a treatment fluid into a subterranean formation. The treatment fluid comprises a chelating agent; a hydrofluoric acid source; and a stabilizing compound. The stabilizing compound has two or more quaternized amine groups. In some cases the treatment fluid further comprises alkali metal ions.

Abstract: A process for producing mineral oil from mineral oil deposits, in which the mineral oil yield is increased by blocking high-permeability regions of the mineral oil formation by injecting at least one formulation into the deposit, the formulation not being brought to a temperature at which the viscosity increases significantly until within the deposit, by injection of steam. The process can be used especially in the final stage of deposit development between water flooding and steam flooding of the deposits.

Abstract: Corrosion inhibitor blends including one or more ether compounds, one or more quaternary ammonium compounds, and one or more fatty acid amine condensates are disclosed. The corrosion inhibitor blends can be used in methods of inhibiting corrosion of a metallic surface in a geothermal process. In one method, an effective amount of a corrosion inhibitor blend may be added to a production well in a geothermal process. In another method, an effective amount of a corrosion inhibitor blend may be added to a geothermal medium, which could be, for example, steam or liquid brine.

Abstract: The invention is directed to polymers that self-crosslink at acidic pH or can be crosslinked by phenolic agents in brine. Such polymers have lower viscosity and can be pumped deep into reservoirs, where they will cross link in situ, thus increasing their viscosity and/or form a gel and blocking thief zones. Methods of making and using such polymers are also provided.

Abstract: The present invention provides compositions including poly(alkenylamide)-polysaccharide hydrogels for treating a subterranean formation and methods of using the same. In various embodiments, the present invention provides a method of treating a subterranean formation, including obtaining or providing a composition including a poly(alkenylamide)-polysaccharide hydrogel. The method also includes placing the composition in a subterranean formation. In some embodiments, the poly(alkenylamide)-polysaccharide hydrogel is a polyacrylamide-alginate hydrogel.

Abstract: A method for building a plug in a horizontal wellbore using a fluid pill containing a suspended well treatment composite. The well treatment composite contains a core comprising at least one deformable particulate and at least one dissolvable diverter. At least a portion of the surface of the core is coated with at least one viscosifying polymer and at least one crosslinking agent. The fluid pill is pumped into the wellbore at the end of a fracturing treatment and the fluid pill may be displaced by a displacement fluid. The fluid pill may be diverted to an area of lower permeability by disassociating the dissolvable diverter from the core. The disassociated diverter blocks an area of higher permeability. The sized particle distribution of the diverter is sufficient to at least partially block the penetration of fluid into the high permeability zone. In the lower permeability zone, a thickened gel is formed by the in-situ reaction of the viscosifying polymer and crosslinking.

Abstract: The invention relates to the use of at least one mixed mineral organoclay rheology additive, which comprises or consists of a quaternary alkyl-ammonium salt treated mineral clay mixture prepared by forming an aqueous hormite clay slurry (a), forming an aqueous smectite clay slurry (b), combining the aqueous hormite clay slurry (a) with the aqueous smectite clay slurry (b) to form a combined clay slurry (c), treating the combined clay slurry (c) with one or more quaternary alkyl-ammonium salts, separating the thus produced quaternary alkyl-ammonium salt treated mineral clay mixture from the aqueous medium, in which the aqueous hormite clay slurry (a) being formed by (i.1) dispersing a fraction of one or more hormite clays selected from the group of sepiolites and palygorskites in an aqueous medium to form a dispersion, and the aqueous smectite clay slurry (b) being formed by (ii.

Abstract: The invention relates to the use of at least one mixed mineral organoclay rheology additive, which comprises or consists of a quaternary alkyl-ammonium salt treated mineral clay mixture prepared by forming an aqueous hormite clay slurry (a), forming an aqueous smectite clay slurry (b), combining the aqueous hormite clay slurry (a) with the aqueous smectite clay slurry (b) to form a combined clay slurry (c), treating the combined clay slurry (c) with one or more quaternary alkyl-ammonium salts, in which the aqueous hormite clay slurry (a) being formed by dispersing a fraction of one or more hormite clays selected from the group of sepiolites and palygorskites in an aqueous medium to form a dispersion, and whereby the hormite clay fraction employed contains less than 3.0% by weight of Al2O3, less than 1.0% by weight of Fe2O3, and less than 3.

Abstract: The present disclosure generally relates to various composite slurries for use in seamless surface coverings and various methods for making the same. In particular, the present disclosure teaches various composite slurry compositions comprising, for example, a clear hardening material, a plurality of particles, a stabilizing filler, and an aggregate. Additionally, the present disclosure teaches various methods of forming composite slurry compositions for use in seamless surface coverings.

Abstract: Chelating agents used in conjunction with stimulation operations in a subterranean formation can often be limited by the pH range over which they may effectively complex metal ions. Perfluorinated chelating agents may have a broader effective pH range for metal ion complexation than do other types of chelating agents, particularly at highly acidic pH values. Methods for treating a subterranean formation can comprise: providing a treatment fluid comprising a perfluorinated chelating agent having at least two carboxylic acid groups; introducing the treatment fluid into a subterranean formation; and complexing metal ions in the subterranean formation with the perfluorinated chelating agent.

Abstract: The hydration of clays and shale in drilling operations may be inhibited by employing an aqueous based drilling fluid comprising a shale hydration inhibition agent having the formula wherein R is an alkyl group having 1 to 6 carbons, R1 is an alkyl group having 1 to 18 carbons, and X is an anion. The shale hydration inhibition agent should be present in the aqueous based drilling fluid in sufficient concentration to reduce the reactivity, such as swelling, of clays and shale when exposed to water-based drilling fluids.

Abstract: A method of drilling into a geological region including a subsurface clathrate reservoir includes drilling a borehole into the geological region including the subsurface clathrate reservoir and dissociating at least a portion of the clathrate in a region near the borehole. After the dissociating, material within at least a portion of the region near the borehole in which the clathrate has been dissociated is compacted to form a compacted region at least partially surrounding the borehole within the clathrate reservoir. After the compacting, well casing is placed into the borehole within the compacted region and the well casing is cemented into the borehole in the compacted area.

Abstract: A method of treating a subterranean formation penetrated by a wellbore by contacting an energized fluid with the subterranean formation; and reducing a partial pressure of the energized fluid by an amount sufficient to form polymeric foam structure within the subterranean formation.