Organic Material Is Resin Or Resinous Patents (Class 166/295)
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Patent number: 12252957Abstract: A method for clearing an obstruction in a wellbore may include opening a first choke that is in fluid communication with the wellbore. This may create a first pressure in the wellbore. The first choke may then be closed. If the choke is adjustable, the choke size may be adjusted to a second size and opened. If the choke is fixed, a second choke of a different size is then opened. When the second choke is opened, a second pressure may be created in the wellbore that is different from the first pressure. The second choke may then be closed. For an adjustable choke, the size is changed to either the first size or a third size. For a fixed choke, either the first choke or a third choke that has a different size may be opened. These steps may be repeated until the obstruction in the wellbore is cleared.Type: GrantFiled: January 27, 2022Date of Patent: March 18, 2025Assignee: SAUDI ARABIAN OIL COMPANYInventors: Rayan A. AlRabaei, Abdulhamid N. AlSousy, Akram R. AlBarghouti, Mohammed H. AlKhaldi
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Patent number: 12134950Abstract: A deployment system for deploying a polymer grout system includes a first conduit line for conveying an isocyanate component, a second conduit line for conveying an organic polyol component, and a mixer for mixing the isocyanate component and the organic polyol component to form an expandable polymer grout system that is deployed to a target location associated with a wellbore. The deployment system can include a tailpipe and/or bridge plug for directing the expandable polymer grout system to the target location. The disclosure also includes methods of using the foregoing deployment system.Type: GrantFiled: December 9, 2021Date of Patent: November 5, 2024Assignees: CHEVRON U.S.A. INC., CHEVRON AUSTRALIA PTY LTDInventors: Paul Michael Benet, Michael James Fuller, Douglas Cory Arceneaux, Eduardo Martinez, George Nabil Farag
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Patent number: 12122958Abstract: A method for mitigating loss circulation zones in a wellbore is provided. The method includes synthesizing a carbamate from an amine-curing agent, and the carbamate is mixed with an epoxy resin from the loss control composition. The loss control composition is pumped into a wellbore with a loss circulation zone, wherein the loss control composition flows into the loss circulation zone. The carbamate of the loss control composition is allowed to decompose at wellbore temperatures, wherein the carbamate releases CO2 gas and the amine-curing agent. The CO2 gas foams the epoxy resin, expanding the epoxy resin to fill voids in the loss circulation zone, and the amine-curing agent cures the foamed epoxy resin, forming a loss control material that seals the loss circulation zone.Type: GrantFiled: February 27, 2023Date of Patent: October 22, 2024Assignee: Saudi Arabian Oil CompanyInventors: Vikrant Wagle, Noktan Mohammed AlYami, Abdullah Saleh Hussain Al-Yami, Khawlah Alanqari
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Patent number: 12116525Abstract: In accordance with one or more embodiments of the present disclosure, a low-density treatment fluid includes a base water-control system and at least one light-weight filler material. The base water-control system may include an inorganic material system comprising an aqueous colloidal silica and a water-soluble chemical activator for gelling the colloidal silica, or the base water-control system may include an organic material system comprising of polymeric material. The low-density treatment fluid may have a density of from 0.1 g/cm3 to 0.75 g/cm3. Also described are methods of recovering a target fluid from a subterranean cavity using such a low-density treatment fluid.Type: GrantFiled: June 28, 2021Date of Patent: October 15, 2024Assignee: Saudi Arabian Oil CompanyInventors: Weishu Zhao, Jin Huang, Feng Liang, Wengang Li
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Patent number: 12098613Abstract: A resin plug for wellbore abandonment includes: an amount of a heavier resin and an amount of a light weight resin, the heavier resin configured to have a faster setting rate than the light weight resin. The resin plug creates a seal for wellbore abandonment by the heavier resin setting first followed by setting of the light weight resin thereafter. Any void formed during setting of the heavier resin is filled by the light weight resin before the light weight resin sets.Type: GrantFiled: June 18, 2021Date of Patent: September 24, 2024Assignee: Nautonnier Holding Corp.Inventors: Bernie Cabot, Mark Schumlick
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Patent number: 12098322Abstract: A solids-control fluid for controlling flow of solids in a subterranean formation is disclosed herein. The solids-control fluid can include a diluent and a curable resin. The diluent can include a glycol ether. The curable resin can be dispersed within the diluent for controlling flow of solids in the subterranean formation.Type: GrantFiled: January 23, 2023Date of Patent: September 24, 2024Assignee: Halliburton Energy Services, Inc.Inventors: Antonio Recio, Jay Deville, Michael Wayne Sanders, Philip D. Nguyen
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Patent number: 12065610Abstract: A method may include: introducing a resin modified cement slurry into a wellbore penetrating a subterranean formation, the subterranean formation comprising a caprock and a carbon dioxide injection zone, the resin modified cement slurry comprising: a resin; a hardener; a hydraulic cement; and water; and setting the resin modified cement slurry to form a set cement wherein the set cement forms a carbonation-resistant barrier in the carbon dioxide injection zone in the subterranean formation.Type: GrantFiled: August 30, 2022Date of Patent: August 20, 2024Assignee: Halliburton Energy Services, Inc.Inventors: Samuel J. Lewis, Paul J. Jones
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Patent number: 12043792Abstract: A treatment fluid and method for water shut-off applications containing an amine-functionalized solid support, an epoxy resin, a second curing agent, and a carrier fluid. Prior to use of the treatment fluid, the amine-functionalized solid support has reacted with carbon dioxide to produce a carbamate-functionalized solid support. The treatment fluid is introduced into a geological formation with high-permeability pathways, curing the epoxy resin, and sealing these pathways.Type: GrantFiled: January 27, 2023Date of Patent: July 23, 2024Assignee: SAUDI ARABIAN OIL COMPANYInventors: Wenwen Li, Fakuen Frank Chang, Feng Liang
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Patent number: 12043790Abstract: A method includes deploying a solid epoxy material into a target region of a pipe and delivering a liquid epoxy formulation into the target region of the pipe so that the liquid epoxy formulation fills voids around the solid epoxy material and inside the pipe within the target region, wherein the liquid epoxy formulation cures within the voids to form a solid epoxy plug with the solid epoxy material within the target region of the pipe.Type: GrantFiled: October 12, 2022Date of Patent: July 23, 2024Inventor: Philip Martial Burguieres
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Patent number: 12043798Abstract: Compositions and methods for treating a well with a treatment fluid. An example method prepares a treatment fluid by combining a furan-based polymer, a Bronsted acid, at least one of an anhydride and/or dibasic ester, a wetting agent, and a docking agent. The treatment fluid is introduced into a wellbore and a wellbore operation is performed with the treatment fluid.Type: GrantFiled: April 18, 2023Date of Patent: July 23, 2024Assignee: HALLIBURTON ENERGY SERVICES, INCInventors: Antonio Recio, Nicole Mast, I Wayan Rakananda Saputra, Philip D. Nguyen
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Patent number: 12037444Abstract: Benzyl ether-type phenolic resins are useful in either a phenolic resin polyurethane cold-box (PUCB) process or a phenolic resin polyurethane no-bake (PUNB) process. The benzyl ether-type phenolic resins contain at least one formaldehyde scavenger in the form of a beta-dicarbonyl compound, and an alpha-carbonyl-carboxyl compound, particularly glyoxylic acid, binders based on these phenolic resins, and isocyanate compounds having at least two isocyanate groups. The resins having the inventive concept exhibit low free formaldehyde content. The inventive concept extends to molding material blends containing the binder, and a method for producing cores, molds or risers.Type: GrantFiled: January 11, 2019Date of Patent: July 16, 2024Assignee: ASK Chemicals GmbHInventor: Christian Priebe
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Patent number: 11994637Abstract: The present disclosure provides a device for full-wave field seismic source based on a gas explosion technology and a method for acquiring seismic data. The device includes a cylindrical explosion-proof metal outer barrel, and four sides of the explosion-proof metal outer barrel are fixedly connected to four high-strength steel plates. The device also includes a cylindrical explosion-proof metal gas explosion inner barrel and pipelines for injecting high-pressure air and high-pressure gas into the gas explosion inner barrel. A center of the gas explosion inner barrel is installed with an electronic ignition gun, which is connected to a GPS timing module connected to the electronic ignition gun. The device further includes a controller configured to control a seismic source of a gas explosion full-wave field.Type: GrantFiled: November 6, 2023Date of Patent: May 28, 2024Assignees: BGP INC., CHINA NATIONAL PETROLEUM CORPORATION, OPTICAL SCIENCE AND TECHNOLOGY (CHENGDU) LTD.Inventors: Liang Gou, Gang Yu, Maojun Yang, Ximing Wang
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Patent number: 11965129Abstract: A method includes conveying a straddle packer assembly into a wellbore that provides a water production zone and first and second oil production zones, the water production zone interposing the first and second oil production zones, deploying the straddle packer assembly and thereby isolating the water production zone from the first and second oil production zones, injecting an injection fluid into the water production zone from the straddle packer assembly, and preventing the influx of water from the water production zone into the wellbore with the injection fluid.Type: GrantFiled: November 28, 2022Date of Patent: April 23, 2024Assignee: SAUDI ARABIAN OIL COMPANYInventors: Haitham Aljuaydi, Khalid Alhamed, Abdulrahman Alyoubi, Sajid Mehmood
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Patent number: 11932805Abstract: A bulk dry cement may comprise a cement; a solid particle; and a liquid resin accelerator, wherein the liquid resin accelerator is disposed on a surface of the solid particle.Type: GrantFiled: September 24, 2021Date of Patent: March 19, 2024Assignee: Halliburton Energy Services, Inc.Inventors: Paul Joseph Jones, William Cecil Pearl, Jr., Samuel Jason Lewis, Thomas Jason Pisklak
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Patent number: 11891565Abstract: In accordance with one or more embodiments of the present disclosure, a host-guest lost circulation material (LCM) composition for sealing lost circulation zones in wellbores includes an aqueous solution; one or more linear polymer chains, the linear polymer chains comprising polyethylene glycols (PEG) with molecular weights greater than 2500 g/mol, polypropylene glycols (PPG), polydimethylsiloxanes (PDMS), or combinations thereof; and one or more cyclic molecules comprising alpha cyclodextrin, beta cyclodextrin, gamma cyclodextrin, or combinations thereof, and wherein the one or more cyclic molecules form a host-guest structure around the one or more linear polymer chains utilizing van der Waals forces.Type: GrantFiled: August 12, 2022Date of Patent: February 6, 2024Assignee: Saudi Arabian Oil CompanyInventors: Hasmukh A. Patel, Younane Abousleiman, Ashok Santra
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Patent number: 11884878Abstract: Methods and fluids for consolidating unconsolidated particulates. An example method introduces a furfuryl alcohol-based resin treatment fluid into a wellbore; wherein the furfuryl alcohol-based resin treatment fluid is a furfuryl alcohol-based resin and a diluent. The method contacts the unconsolidated particulates within the wellbore with the furfuryl alcohol-based resin treatment fluid to produce resin-contacted unconsolidated particulates. The method further introduces a substituted amine acid treatment fluid into the wellbore after the introduction of the furfuryl alcohol-based resin treatment fluid into the wellbore; wherein the substituted amine acid treatment fluid is a substituted amine acid salt and a solvent. The method further contacts the resin-contacted unconsolidated particulates with the substituted amine acid treatment fluid.Type: GrantFiled: July 22, 2022Date of Patent: January 30, 2024Assignee: Halliburton Energy Services, Inc.Inventors: Antonio Recio, III, Aaron M. Beuterbaugh, Josselyne Chano, Philip D. Nguyen, Michael Wayne Sanders
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Patent number: 11879304Abstract: Methods and systems for cementing in a wellbore. An example method includes introducing a conduit into a wellbore. The conduit comprises a reactive metal element disposed on an exterior of the conduit. The reactive metal element comprises a reactive metal having a first volume. The method further includes circulating a cement over the exterior of the conduit and the reactive metal element, contacting the reactive metal element with a fluid that reacts with the reactive metal to produce a reaction product having a second volume greater than the first volume, and contacting a surface of the cement adjacent to the reactive metal element with the reaction product.Type: GrantFiled: May 17, 2021Date of Patent: January 23, 2024Assignee: Halliburton Energy Services, Inc.Inventors: Abdel-Hamid Rawhi Abeidoh, Bryon D Mullen, Michael Linley Fripp
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Patent number: 11866644Abstract: A composition for a fracturing fluid may include a chelating agent, a polymeric gelling agent, and a base fluid. The base fluid in the fracturing fluid composition may be a produced fluid having a hardness content of at least 7,000 ppm. Method for treating a hydrocarbon-bearing formation may include introducing a fracturing fluid in the hydrocarbon-bearing formation. The fracturing fluid contains a chelating agent, a polymeric gelling agent, and a base fluid. The base fluid may be a produced fluid that has a hardness content of at least 7,000 ppm. The fracturing fluid may have a viscosity of at least 200 cp at 150° F., 100 1/s shear rate, and 300 psia when tested using model 5550 HPHT rheometer. After contacting the hydrocarbon-bearing formation, the viscosity of the fracturing fluid may drop near a range of 1 cP to 5 cP.Type: GrantFiled: August 3, 2022Date of Patent: January 9, 2024Assignees: SAUDI ARABIAN OIL COMPANY, KING FAHD UNIVERSITY OF PETROLEUM & MINERALSInventors: Mustafa Alkhowaildi, Mohamed Ahmed Nasr El Din Mahmoud, Mohammed Abudullah Bataweel, Rajendra Arunkumar Kalgaonkar
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Patent number: 11851608Abstract: A method may include: introducing a treatment fluid into a subterranean formation, the treatment fluid comprising: an aqueous brine; and a hydrolysable resin precursor; allowing the hydrolysable resin precursor to hydrolyze in the subterranean formation to form at least a polymerizable resin precursor monomer; and allowing the polymerizable resin precursor monomer to polymerize to form a polymerized resin in the subterranean formation.Type: GrantFiled: December 13, 2021Date of Patent: December 26, 2023Assignee: Halliburton Energy Services, Inc.Inventors: Philip D. Nguyen, Michael Wayne Sanders, Josselyne Chano, Philippe Quero, Julio Estuardo Vasquez Estrada
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Patent number: 11840664Abstract: Methods and compositions comprising one or more degraded in situ gelable polymers are provided. Use of such compositions and methods comprising one or more degraded in situ gelable polymers during enhanced oil recovery may result in an increase in oil production relative to methods and/or compositions which do not comprise one or more degraded in situ gelable polymers.Type: GrantFiled: October 31, 2019Date of Patent: December 12, 2023Assignee: KEMIRA OYJInventors: Yuping Luo, Pengpeng Qi
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Patent number: 11827845Abstract: Aqueous well treatment fluids especially suited for use in far field diversion in low viscosity carrier fluids comprise water, a friction reducer, and a diverter. The diverter comprises dissolvable particulates and proppants. The dissolvable particulates have a specific gravity of from about 0.9 to about 1.6 and a particle size of about 50 mesh or less. The proppants have a specific gravity of from about 0.9 to about 1.4 and a particle size of from about 20 to about 100 mesh. The dissolvable particulates have a higher specific gravity and a smaller particle size than the proppant.Type: GrantFiled: December 27, 2022Date of Patent: November 28, 2023Assignee: BJ Energy Solutions, LLCInventors: Leonid Vigderman, Lingjuan Shen, Diankui Fu
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Patent number: 11827841Abstract: A method of treating a lost circulation zone may include positioning a cured lost circulation material composition in the lost circulation zone of a subterranean natural resource well to produce a barrier operable to mitigate wellbore fluids from passing into the lost circulation zone. The cured lost circulation material composition may be a foam comprising a gas phase and a liquid phase. The cured lost circulation material composition may include a cured bisphenol epoxy resin, one or more surfactants positioned at the interface of the liquid phase and the gas phase of the foam and carbon dioxide in the gas phase of the foam. The cured bisphenol epoxy resin may be a reaction product of a bisphenol epoxy resin system including uncured bisphenol epoxy resin, one or more curing agents, and optionally, a diluent. The carbon dioxide may be a reaction product of one or more carbon dioxide gas-generating compounds.Type: GrantFiled: December 23, 2021Date of Patent: November 28, 2023Assignee: Saudi Arabian Oil CompanyInventors: Vikrant Wagle, Abdullah Al-Yami, Ali Al Safran, Mohammad Alharthi
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Patent number: 11807802Abstract: A nano-organosilicon film-forming and hydrophobic shale surface hydration inhibitor is obtained by performing hydrophobic modification for nano-particles through long-chain organosilicon together with a surface-active agent. A preparation method of the said hydrophobic shale surface hydration inhibitor comprises steps as follows: nano-particles are added to the solvent under stirring conditions, and then an ultrasonic dispersion is performed; upon the end of the ultrasonic dispersion, the reaction system is adjusted to a pH of 9-11 to obtain mixed solution A; a long-chain organosilicon solution is then dropwise added to the mixed solution A for reaction under stirring conditions to obtain mixed solution B; a surface-active agent is added to the mixed solution B for reaction under stirring conditions; upon the reaction is finished, part of the solvent is removed to obtain the inhibitor.Type: GrantFiled: March 1, 2022Date of Patent: November 7, 2023Assignee: CHINA UNIVERSITY OF PETROLEUM (EAST CHINA)Inventors: Xianbin Huang, Jinsheng Sun, He Li, Kaihe Lv, Jingping Liu, Jiafeng Jin, Jintang Wang, Yingrui Bai
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Patent number: 11773693Abstract: A method for providing a mixture downhole at or about a location in an open or cased wellbore. The method includes extending a retrievable delivery sub-system downhole through the wellbore, delivering two or more chemical components downhole through the retrievable delivery sub-system, and mixing the two or more chemical components to provide the mixture at or about the location. The delivery sub-system has a tubing assembly having at least two fluidly separated delivery channels, and each delivery channel is for delivering at least one of the two or more chemical components.Type: GrantFiled: October 28, 2020Date of Patent: October 3, 2023Inventor: Colton Garrett Hoffman
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Patent number: 11767748Abstract: A system for stimulating oil or gas production from a wellbore includes a hydraulic fracturing pump unit having one or more hydraulic fracturing pumps driven by one or more electrical fracturing motors, a variable frequency drive (VFD) controlling the electrical fracturing motors, a fracturing pump blower unit driven by a blower motor, and a fracturing pump lubrication unit having a lubrication pump driven by a lubrication motor and a cooling fan driven by a cooling motor. The system may further include a blender unit and a hydration unit. A system control unit may control the operational parameters of the system.Type: GrantFiled: July 8, 2022Date of Patent: September 26, 2023Assignee: STEWART & STEVENSON LLCInventors: Mark Payne, Haomin Lin, Tom Robertson
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Patent number: 11718777Abstract: Compositions and methods involving polyvalent cation reactive polymers for use as lost circulation materials in subterranean treatment operations are provided. In some embodiments, the methods include forming a treatment fluid including a base fluid, a source of a polyvalent cation, a polyvalent cation reactive polymer, and an acid precursor; introducing the treatment fluid into a wellbore penetrating at least a portion of a subterranean formation; and allowing the treatment fluid to at least partially set.Type: GrantFiled: April 11, 2022Date of Patent: August 8, 2023Assignee: Halliburton Energy Services, Inc.Inventors: Preston Andrew May, Hui Zhou, Jay Deville
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Patent number: 11708521Abstract: A method for zonal isolation in a subterranean formation includes identifying a zone of interest within the subterranean formation, determining a static temperature of the zone of interest, determining a time duration for gelation of a treatment fluid, determining a concentration of a cross-linker in the treatment fluid, determining a volume of the treatment fluid to be delivered to the zone of interest, determining a correlation between cooling of a wellbore near the zone of interest and a delivery rate of the treatment fluid, determining a target wellbore temperature, delivering a cooling stage until the target wellbore temperature is reached, and delivering a treatment stage. Delivering the cooling stage and the treatment stage results in forming, within the zone of interest, a gel that is impermeable to fluid flow.Type: GrantFiled: December 14, 2021Date of Patent: July 25, 2023Assignee: Saudi Arabian Oil CompanyInventors: Mohamed Hassan Sherief, Ayman Mohammed Almohsin, Haider J. Abdulal, Mohammed I. Alabdrabalnabi
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Patent number: 11661815Abstract: The present disclosure may relate to a method of remediating a wellbore. The method may comprise pumping a resin treatment fluid from a surface location to an annular space bounded by an outer diameter of a production tubular, wherein the resin treatment fluid comprises a liquid hardenable resin, a hardening agent, and a particulate bridging agent. The resin treatment fluid may gravity settle in the annular space to contact production equipment in the annular space such that at least a portion of the particulate bridging agent bridges across one or more damaged sections of the production equipment, wherein at least a portion of the liquid hardenable resin sets to form a hardened mass to seal the one or more damaged sections.Type: GrantFiled: June 6, 2022Date of Patent: May 30, 2023Assignee: Halliburton Energy Services, Inc.Inventors: Philippe Quero, Philip D. Nguyen
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Patent number: 11655378Abstract: A composition for forming an electroactive coating includes an acid as a polymerization catalyst, at least one functional component, and at least one compound of formula (1) as a monomer: wherein X is selected from S, O, Se, Te, PR2 and NR2, Y is hydrogen (H) or a precursor of a good leaving group Y? whose conjugate acid (HY) has a pKa of less than 45, Z is hydrogen (H), silyl, or a good leaving group whose conjugate acid (HY) has a pKa of less than 45, b is 0, 1 or 2, each R1 is a substituent, and the at least one compound of formula (1) includes at least one compound of formula (1) with Z?H and Y?H.Type: GrantFiled: November 3, 2019Date of Patent: May 23, 2023Assignee: PolyM technology corporationInventors: Chien-Chung Han, Ting-Chia Ku, Jo-Wen Chiang
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Patent number: 11624021Abstract: A method for controlling the permeability of an oil well includes the steps of preparing a polymerizable bicomponent system having at least a fluid with at least an olefinically unsaturated first polymerizable compound; optionally, at least one radical polymerization initiator IA, the initiator IA being activated thermally or in the presence of an accelerating compound and a fluid with a radical polymerization activator, the activator being selected from: a radical polymerization initiator IB for polymerizing the polymerizable compound, the initiator IB having an activation temperature equal to or lower than the temperature of the thief zone, an accelerator of the initiator IA, The method further includes injecting one of the fluids into the well annulus until the thief zone is reached, and injecting the remainder into the tubular element, until it comes into contact with the fluid injected through the annulus to form a blocking polymer at the thief zone.Type: GrantFiled: December 28, 2018Date of Patent: April 11, 2023Assignee: ENI S.P.A.Inventors: Elisa Di Biase, Matia Minelli, Davide Moscatelli, Azzurra Agostini
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Patent number: 11584695Abstract: A method of designing a cement slurry may include: (a) selecting at least a cement and concentration thereof, a water and concentration thereof, and one or more chemical additives and a concentration thereof such that a cement slurry formed from the cement, water, and the one or more chemical additives meet a density requirement; (b) calculating a thickening time of the cement slurry using a thickening time model; (c) comparing the thickening time of the cement slurry to a thickening time requirement, wherein steps (a)-(c) are repeated if the thickening time of the cement slurry does not meet or exceed the thickening time requirement, wherein the step of selecting comprises selecting concentrations and/or different chemical identities for the one or more chemical additives, cement, or water, or step (d) is performed if the thickening time of the cement slurry meets or exceeds the thickening time requirement; and (d) preparing the cement slurry.Type: GrantFiled: July 8, 2020Date of Patent: February 21, 2023Assignee: Halliburton Energy Services, Inc.Inventors: Siva Rama Krishna Jandhyala, John Paul Bir Singh
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Patent number: 11566163Abstract: A polymerizable chemical system for consolidating particulates in a subterranean formation including a liquid resin, a curing agent, and a permeability enhancing additive. The chemical system is a homogenous composition that polymerizes to forms a solid upon heating at a temperature greater than 60° C. Consolidating particulates in a subterranean formation includes providing a polymerizable chemical system comprising a liquid resin, a curing agent, and a permeability enhancing additive to a subterranean formation, and polymerizing the polymerizable chemical system to consolidate particulates in the formation to yield a porous consolidated particulates pack.Type: GrantFiled: August 20, 2020Date of Patent: January 31, 2023Assignee: Saudi Arabian Oil CompanyInventors: Fakuen Frank Chang, Xiaoyu Tan
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Patent number: 11548962Abstract: A self-healing polymer network containing a physical crosslinking agent, a composition therefor, and an optical element comprising the same is provided. The self-healing polymer network comprises a polymer derived from monomers including self-healing monomers each having a first polymerizable functional group and at least one of urethane, urea, or amide group chemically linked to the first polymerizable functional group, wherein the polymer has a backbone formed by polymerizing the first polymerizable functional groups of the self-healing monomers and a plurality of side groups each having at least one of urethane, urea, or amide group chemically linked to the backbone. In addition, the self-healing polymer network comprises a physical crosslinking agent which is an alcohol mixture having at least two of monool, diol, triol, and tetraol or the higher polyol and crosslinking the polymer by physically crosslinking the urethane, urea, or amide group of the side groups.Type: GrantFiled: May 11, 2018Date of Patent: January 10, 2023Assignee: INDUSTRY-UNIVERSITY COOPERATION FOUNDATION HANYANG UNIVERSITYInventors: Dong Hack Suh, Kyoung Hwan Choi, Jeong Seop Oh
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Patent number: 11512574Abstract: Techniques of the present disclosure relate to proppant flowback control using a plug and perf completion. A method comprises disposing a resin in at least one cluster of fractures of a stage; disposing an activator for the resin in the stage; displacing the activator from the wellbore and into the at least one cluster of the stage with a plug attached to a perforating apparatus; setting the plug such that the resin and the activator are contained in the stage; and perforating a subsequent stage.Type: GrantFiled: December 31, 2021Date of Patent: November 29, 2022Assignee: Halliburton Energy Services, Inc.Inventor: Philippe Quero
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Patent number: 11472998Abstract: A cement composition is disclosed that includes a cement slurry and an epoxy resin system that includes at least one epoxy resin and a curing agent. The cement slurry has a density in a range of from 65 pcf to 180 pcf and includes a cement precursor material, silica sand, silica flour, a weighting agent, and manganese tetraoxide. The epoxy resin system includes at least one of 2,3-epoxypropyl o-tolyl ether, alkyl glycidyl ethers having from 12 to 14 carbon atoms, bisphenol-A-epichlorohydrin epoxy resin, or a compound having formula (I): (OC2H3)—CH2—O—R1—O—CH2—(C2H3O) where R1 is a linear or branched hydrocarbyl having from 4 to 24 carbon atoms; and a curing agent.Type: GrantFiled: July 18, 2019Date of Patent: October 18, 2022Assignee: Saudi Arabian Oil CompanyInventors: Abdullah Al-Yami, Vikrant Wagle, Zainab Alsaihati, Tushar Mukherjee, Ali BinAli, Ali Alqahtani
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Patent number: 11441063Abstract: A method for the removal of well bore damage, the method including performing an acid cleaning of one or more of a coiled tubing and the well bore using a hydrochloric acid mixture of 7 to 15 wt % hydrochloric acid and displacing the hydrochloric acid mixture with a first fresh water stream. After acid cleaning, a composition comprising at least 10 wt % acetic acid into the wellbore is injected into the wellbore. After injecting acetic acid, gel jetting of the well is performed with a gel mixture, and the gel mixture is subsequently displaced with a second fresh water stream. After gel jetting, an organic solvent mixture is injected into the well bore and allowing the organic solvent mixture to soak for 2 to 6 hours. Finally, a thermochemical mixture is injected into the well bore, thereby increasing temperature and pressure and cleaning build up from the well bore.Type: GrantFiled: April 7, 2021Date of Patent: September 13, 2022Assignee: SAUDI ARABIAN OIL COMPANYInventors: Ayman R. Al-Nakhli, Rayed M. Zayer, Ahmad S. Busaleh
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Patent number: 11401455Abstract: The invention is directed to polymers that self-crosslink at acidic pH or can be crosslinked by phenolic agents in brine. Such polymers have lower viscosity and can be pumped deep into reservoirs, where they will cross link in situ, thus increasing their viscosity and/or form a gel and blocking thief zones. Methods of making and using such polymers are also provided.Type: GrantFiled: September 12, 2021Date of Patent: August 2, 2022Assignees: CONOCOPHILLIPS COMPANY, UNIVERSITY OF KANSASInventors: Huili Guan, Cory Berkland, Ahmad Moradi-Araghi, Jenn-Tai Liang, Terry M. Christian, Riley B. Needham, James H. Hedges, Min Cheng, Faye L. Scully
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Patent number: 11370955Abstract: A method to control a heat transfer profile in a defined space, the method comprising the steps of introducing a thermally insulating packer fluid into the defined space such that the thermally insulating packer fluid forms a gelled solid and reduces a rate of heat transfer through the defined space as compared to a prior rate of heat transfer through the defined space before introducing the thermally insulating packer fluid, where the thermally insulating packer fluid comprises an acidic nanosilica dispersion and a polyamine.Type: GrantFiled: May 5, 2020Date of Patent: June 28, 2022Inventors: Vikrant Wagle, Abdullah Al-Yami, Zainab Alsaihati, Abdulaziz Alhelal
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Patent number: 11352541Abstract: A sealing composition for sealing an annulus of a wellbore includes from 20 weight percent to 97 weight percent epoxy resin based on the total weight of the composition. The epoxy resin comprising at least one of 2,3-epoxypropyl o-tolyl ether, alkyl glycidyl ethers having from 12 to 14 carbon atoms, or a compound having formula (OC2H3)—CH2—O—R1—O—CH2—(C2H3O), where R1 is a linear or branched hydrocarbyl having from 4 to 24 carbon atoms. The sealing composition also includes from 1 weight percent to 20 weight percent curing agent based on the total weight of the composition. Methods for sealing a wellbore annulus or casing-casing annulus includes introducing a spacer fluid to the wellbore, introducing the sealing composition to the wellbore, displacing the sealing composition into the annulus, and curing the sealing composition.Type: GrantFiled: August 30, 2018Date of Patent: June 7, 2022Assignee: Saudi Arabian Oil CompanyInventors: Abdullah Al-Yami, Ali Alsafran, Vikrant Wagle, Hussain Albahrani, Zainab Alsaihati
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Patent number: 11352551Abstract: Proppants are used in oil and gas extraction, particularly in fracking operations. The invention relates to resin coated proppants. The coatings on proppants have antimicrobial materials incorporated within these coatings. The antimicrobially active agents are incorporated in a concentration less than 70% by weight of the coatings or the active agent from these coatings can be released from these coatings in the environment of the proppants.Type: GrantFiled: December 11, 2018Date of Patent: June 7, 2022Assignee: Agienic, Inc.Inventors: Anoop Agrawal, Donald R. Uhlmann, Nicholas R. Krasnow
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Patent number: 11312892Abstract: The present disclosure relates to subterranean formation operations and, more particularly, to embedded treatment fluid additives for use in subterranean formation operations. The embedded treatment additives may comprise an aqueous-soluble downhole reactive material embedded in a crosslinked polymeric solution to delay the reactivity of the aqueous-soluble downhole reactive material, thereby forming the embedded treatment additive, wherein the aqueous-soluble downhole reactive material is a solid.Type: GrantFiled: December 7, 2016Date of Patent: April 26, 2022Assignee: Halliburton Energy Services, Inc.Inventors: Dipti Singh, Aaron Michael Beuterbaugh, Enrique Antonio Reyes
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Patent number: 11306240Abstract: Aqueous well treatment fluids especially suited for use in far field diversion in low viscosity carrier fluids comprise water, a friction reducer, and a diverter. The diverter comprises dissolvable particulates and proppants. The dissolvable particulates have a specific gravity of from about 0.9 to about 1.6 and a particle size of about 50 mesh or less. The proppants have a specific gravity of from about 0.9 to about 1.4 and a particle size of from about 20 to about 100 mesh. The dissolvable particulates have a higher specific gravity and a smaller particle size than the proppant.Type: GrantFiled: August 25, 2020Date of Patent: April 19, 2022Assignee: BJ Energy Solutions, LLCInventors: Leonid Vigderman, Lingjuan Shen, Diankui Fu
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Patent number: 11286726Abstract: Methods and systems are directed to the uniform distribution of a fluid through an annulus between a pipe and a wellbore wall, primarily when there is a preferential flow in one side of the annulus relative to another side of the annulus. Generally, the methods and systems involve introducing a first agent into the annulus, wherein the first agent is configured to cause swelling of a cladding on the exterior of the section of the pipe. The swelling reduces flow in the annulus on the side of the pipe with preferential flow so as to reduce the preferential flow on that side of the pipe.Type: GrantFiled: January 7, 2019Date of Patent: March 29, 2022Assignee: Halliburton Energy Services, Inc.Inventors: Siva Rama Krishna Jandhyala, Sunita Kadam, Rahul Chandrakant Patil, Wiliam W. Shumway
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Patent number: 11230660Abstract: Lightweight micro-proppant suitable to prop open not only near-wellbore microfractures but also far-field microfractures. Some methods of fracturing and propping may comprise first introducing a pad fluid comprising a lightweight micro-proppant into a wellbore penetrating a subterranean formation at a rate and pressure sufficient to create or extend a fracture network in the subterranean formation, wherein the fracture network comprises microfractures. The lightweight micro-proppant comprises a thermoset nanocomposite having a specific gravity of about 0.9 to about 1.4 and having an average diameter of about 0.1 microns to about 50 microns. Then introducing a proppant slurry comprising a macro-proppant into the wellbore penetrating the subterranean formation after introducing the pad fluid forming a proppant pack in the fracture network wherein at least some of the lightweight micro-proppant is located in the microfractures.Type: GrantFiled: July 8, 2016Date of Patent: January 25, 2022Assignee: Halliburton Energy Services, Inc.Inventors: Philip D. Nguyen, Mallikarjuna Shroff Rama, Prashant D. Chopade
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Patent number: 11220882Abstract: A method for recompleting a well is applied to a well such that the recompleted well can thermally transfer geothermal energy to surface. The recompleting method can comprise steps to enhance the thermal conductivity of a wellbore of a hydrocarbon well, by inserting a thermal material into the wellbore that displaces a reservoir fluid having a lower thermal conductivity than the thermal material. The recompleting method can also comprise steps to enhance the thermal conductivity of a reservoir in which the wellbore is located by inserting a thermal material into the reservoir that displaces a reservoir fluid having a lower thermal conductivity than the thermal material, or in which the reservoir is fractured, and a thermal material is inserted into created fractures.Type: GrantFiled: December 18, 2017Date of Patent: January 11, 2022Assignee: Element Coil Services Inc.Inventors: Grant Nevison, Josh Thompson
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Patent number: 11220581Abstract: An aqueous dispersion includes polyacrylamide, a crosslinker, and a filler. The crosslinker includes at least one of hydroquinone or hexamethylenetetramine. The filler includes at least one of a metal oxide or a nanomaterial. The metal oxide includes at least one of zirconium oxide, zirconium hydroxide, or titanium oxide. The nanomaterial includes at least one of graphene, graphene oxide, or boron nitride. In some cases, the filler is a nanocomposite of the metal oxide and the nanomaterial.Type: GrantFiled: November 5, 2019Date of Patent: January 11, 2022Assignee: Saudi Arabian Oil CompanyInventors: Ayman Mohammed Almohsin, Edreese Alsharaeh
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Patent number: 11149181Abstract: A convertible composition comprising a nanosilica drilling fluid, the nanosilica drilling fluid comprising an aqueous based drilling mud, where the aqueous based drilling mud comprises water, and an alkaline nanosilica dispersion, where the alkaline nanosilica dispersion comprises nanosilica; and a chemical activator, the chemical activator operable to hydrolyze in the presence of water to produce an acid, where a weight ratio of the alkaline nanosilica dispersion to the chemical activator is between 1 to 0.001 and 1 to 0.25.Type: GrantFiled: September 15, 2020Date of Patent: October 19, 2021Assignee: SAUDI ARABIAN OIL COMPANYInventors: Vikrant Wagle, Abdullah Al-Yami, Rajendra A. Kalgaonkar, Zainab Alsaihati
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Patent number: 11136494Abstract: A polymer composition may include one or more monomeric units, with an internal crosslinker, internal breaker, scale control additive or a combination thereof.Type: GrantFiled: June 1, 2017Date of Patent: October 5, 2021Assignee: ROCKWATER ENERGY SOLUTIONS, LLCInventors: Jack Maberry, Yifan Li, Rupa Venugopal, Mark Kinsey, Paul Pistono, Fati Malekahmadi
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Patent number: 11124689Abstract: Systems and methods for forming a permanent plug in a subterranean formation include providing a solution of colloidal silica and pumping the colloidal silica into a bore of a subterranean well so that the colloidal silica penetrates pores of the subterranean formation. The colloidal silica within the pores of the subterranean formation is dehydrated to form a glass-like material within the pores of the subterranean formation.Type: GrantFiled: October 18, 2019Date of Patent: September 21, 2021Assignee: SAUDI ARABIAN OIL COMPANYInventors: Mohammed Bataweel, Prasad Baburao Karadkar, Ayman Al-Mohsin, Haitham A. Othman
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Patent number: 11035195Abstract: Methods of mitigating lost circulation while drilling a wellbore. The methods include circulating a drilling mud to a downhole end of the wellbore via a drill string and, during the circulating, drilling the wellbore with a drill bit of the drill string. The methods also include detecting lost circulation within the wellbore while drilling the wellbore and include providing a monomer solution to the wellbore. The methods further include providing a catalyst to the wellbore responsive to detecting the lost circulation event and combining the monomer solution and the catalyst to polymerize a monomer from the monomer solution, within the wellbore, and forming a viscous plug within the wellbore. Subsequent to the combining, the methods include flowing at least a portion of the viscous plug within the wellbore and into a zone of lost circulation that extends within a subsurface region.Type: GrantFiled: November 13, 2018Date of Patent: June 15, 2021Assignee: ExxonMobil Upstream Research CompanyInventors: Bill R. Meeks, Timothy J. Nedwed, Douglas A. Mitchell, Rachna Jain, Kaustubh S. Kulkarni