Organic Material Is Resin Or Resinous Patents (Class 166/295)
  • Patent number: 11661815
    Abstract: The present disclosure may relate to a method of remediating a wellbore. The method may comprise pumping a resin treatment fluid from a surface location to an annular space bounded by an outer diameter of a production tubular, wherein the resin treatment fluid comprises a liquid hardenable resin, a hardening agent, and a particulate bridging agent. The resin treatment fluid may gravity settle in the annular space to contact production equipment in the annular space such that at least a portion of the particulate bridging agent bridges across one or more damaged sections of the production equipment, wherein at least a portion of the liquid hardenable resin sets to form a hardened mass to seal the one or more damaged sections.
    Type: Grant
    Filed: June 6, 2022
    Date of Patent: May 30, 2023
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Philippe Quero, Philip D. Nguyen
  • Patent number: 11655378
    Abstract: A composition for forming an electroactive coating includes an acid as a polymerization catalyst, at least one functional component, and at least one compound of formula (1) as a monomer: wherein X is selected from S, O, Se, Te, PR2 and NR2, Y is hydrogen (H) or a precursor of a good leaving group Y? whose conjugate acid (HY) has a pKa of less than 45, Z is hydrogen (H), silyl, or a good leaving group whose conjugate acid (HY) has a pKa of less than 45, b is 0, 1 or 2, each R1 is a substituent, and the at least one compound of formula (1) includes at least one compound of formula (1) with Z?H and Y?H.
    Type: Grant
    Filed: November 3, 2019
    Date of Patent: May 23, 2023
    Assignee: PolyM technology corporation
    Inventors: Chien-Chung Han, Ting-Chia Ku, Jo-Wen Chiang
  • Patent number: 11624021
    Abstract: A method for controlling the permeability of an oil well includes the steps of preparing a polymerizable bicomponent system having at least a fluid with at least an olefinically unsaturated first polymerizable compound; optionally, at least one radical polymerization initiator IA, the initiator IA being activated thermally or in the presence of an accelerating compound and a fluid with a radical polymerization activator, the activator being selected from: a radical polymerization initiator IB for polymerizing the polymerizable compound, the initiator IB having an activation temperature equal to or lower than the temperature of the thief zone, an accelerator of the initiator IA, The method further includes injecting one of the fluids into the well annulus until the thief zone is reached, and injecting the remainder into the tubular element, until it comes into contact with the fluid injected through the annulus to form a blocking polymer at the thief zone.
    Type: Grant
    Filed: December 28, 2018
    Date of Patent: April 11, 2023
    Assignee: ENI S.P.A.
    Inventors: Elisa Di Biase, Matia Minelli, Davide Moscatelli, Azzurra Agostini
  • Patent number: 11584695
    Abstract: A method of designing a cement slurry may include: (a) selecting at least a cement and concentration thereof, a water and concentration thereof, and one or more chemical additives and a concentration thereof such that a cement slurry formed from the cement, water, and the one or more chemical additives meet a density requirement; (b) calculating a thickening time of the cement slurry using a thickening time model; (c) comparing the thickening time of the cement slurry to a thickening time requirement, wherein steps (a)-(c) are repeated if the thickening time of the cement slurry does not meet or exceed the thickening time requirement, wherein the step of selecting comprises selecting concentrations and/or different chemical identities for the one or more chemical additives, cement, or water, or step (d) is performed if the thickening time of the cement slurry meets or exceeds the thickening time requirement; and (d) preparing the cement slurry.
    Type: Grant
    Filed: July 8, 2020
    Date of Patent: February 21, 2023
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Siva Rama Krishna Jandhyala, John Paul Bir Singh
  • Patent number: 11566163
    Abstract: A polymerizable chemical system for consolidating particulates in a subterranean formation including a liquid resin, a curing agent, and a permeability enhancing additive. The chemical system is a homogenous composition that polymerizes to forms a solid upon heating at a temperature greater than 60° C. Consolidating particulates in a subterranean formation includes providing a polymerizable chemical system comprising a liquid resin, a curing agent, and a permeability enhancing additive to a subterranean formation, and polymerizing the polymerizable chemical system to consolidate particulates in the formation to yield a porous consolidated particulates pack.
    Type: Grant
    Filed: August 20, 2020
    Date of Patent: January 31, 2023
    Assignee: Saudi Arabian Oil Company
    Inventors: Fakuen Frank Chang, Xiaoyu Tan
  • Patent number: 11548962
    Abstract: A self-healing polymer network containing a physical crosslinking agent, a composition therefor, and an optical element comprising the same is provided. The self-healing polymer network comprises a polymer derived from monomers including self-healing monomers each having a first polymerizable functional group and at least one of urethane, urea, or amide group chemically linked to the first polymerizable functional group, wherein the polymer has a backbone formed by polymerizing the first polymerizable functional groups of the self-healing monomers and a plurality of side groups each having at least one of urethane, urea, or amide group chemically linked to the backbone. In addition, the self-healing polymer network comprises a physical crosslinking agent which is an alcohol mixture having at least two of monool, diol, triol, and tetraol or the higher polyol and crosslinking the polymer by physically crosslinking the urethane, urea, or amide group of the side groups.
    Type: Grant
    Filed: May 11, 2018
    Date of Patent: January 10, 2023
    Assignee: INDUSTRY-UNIVERSITY COOPERATION FOUNDATION HANYANG UNIVERSITY
    Inventors: Dong Hack Suh, Kyoung Hwan Choi, Jeong Seop Oh
  • Patent number: 11512574
    Abstract: Techniques of the present disclosure relate to proppant flowback control using a plug and perf completion. A method comprises disposing a resin in at least one cluster of fractures of a stage; disposing an activator for the resin in the stage; displacing the activator from the wellbore and into the at least one cluster of the stage with a plug attached to a perforating apparatus; setting the plug such that the resin and the activator are contained in the stage; and perforating a subsequent stage.
    Type: Grant
    Filed: December 31, 2021
    Date of Patent: November 29, 2022
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Philippe Quero
  • Patent number: 11472998
    Abstract: A cement composition is disclosed that includes a cement slurry and an epoxy resin system that includes at least one epoxy resin and a curing agent. The cement slurry has a density in a range of from 65 pcf to 180 pcf and includes a cement precursor material, silica sand, silica flour, a weighting agent, and manganese tetraoxide. The epoxy resin system includes at least one of 2,3-epoxypropyl o-tolyl ether, alkyl glycidyl ethers having from 12 to 14 carbon atoms, bisphenol-A-epichlorohydrin epoxy resin, or a compound having formula (I): (OC2H3)—CH2—O—R1—O—CH2—(C2H3O) where R1 is a linear or branched hydrocarbyl having from 4 to 24 carbon atoms; and a curing agent.
    Type: Grant
    Filed: July 18, 2019
    Date of Patent: October 18, 2022
    Assignee: Saudi Arabian Oil Company
    Inventors: Abdullah Al-Yami, Vikrant Wagle, Zainab Alsaihati, Tushar Mukherjee, Ali BinAli, Ali Alqahtani
  • Patent number: 11441063
    Abstract: A method for the removal of well bore damage, the method including performing an acid cleaning of one or more of a coiled tubing and the well bore using a hydrochloric acid mixture of 7 to 15 wt % hydrochloric acid and displacing the hydrochloric acid mixture with a first fresh water stream. After acid cleaning, a composition comprising at least 10 wt % acetic acid into the wellbore is injected into the wellbore. After injecting acetic acid, gel jetting of the well is performed with a gel mixture, and the gel mixture is subsequently displaced with a second fresh water stream. After gel jetting, an organic solvent mixture is injected into the well bore and allowing the organic solvent mixture to soak for 2 to 6 hours. Finally, a thermochemical mixture is injected into the well bore, thereby increasing temperature and pressure and cleaning build up from the well bore.
    Type: Grant
    Filed: April 7, 2021
    Date of Patent: September 13, 2022
    Assignee: SAUDI ARABIAN OIL COMPANY
    Inventors: Ayman R. Al-Nakhli, Rayed M. Zayer, Ahmad S. Busaleh
  • Patent number: 11401455
    Abstract: The invention is directed to polymers that self-crosslink at acidic pH or can be crosslinked by phenolic agents in brine. Such polymers have lower viscosity and can be pumped deep into reservoirs, where they will cross link in situ, thus increasing their viscosity and/or form a gel and blocking thief zones. Methods of making and using such polymers are also provided.
    Type: Grant
    Filed: September 12, 2021
    Date of Patent: August 2, 2022
    Assignees: CONOCOPHILLIPS COMPANY, UNIVERSITY OF KANSAS
    Inventors: Huili Guan, Cory Berkland, Ahmad Moradi-Araghi, Jenn-Tai Liang, Terry M. Christian, Riley B. Needham, James H. Hedges, Min Cheng, Faye L. Scully
  • Patent number: 11370955
    Abstract: A method to control a heat transfer profile in a defined space, the method comprising the steps of introducing a thermally insulating packer fluid into the defined space such that the thermally insulating packer fluid forms a gelled solid and reduces a rate of heat transfer through the defined space as compared to a prior rate of heat transfer through the defined space before introducing the thermally insulating packer fluid, where the thermally insulating packer fluid comprises an acidic nanosilica dispersion and a polyamine.
    Type: Grant
    Filed: May 5, 2020
    Date of Patent: June 28, 2022
    Inventors: Vikrant Wagle, Abdullah Al-Yami, Zainab Alsaihati, Abdulaziz Alhelal
  • Patent number: 11352551
    Abstract: Proppants are used in oil and gas extraction, particularly in fracking operations. The invention relates to resin coated proppants. The coatings on proppants have antimicrobial materials incorporated within these coatings. The antimicrobially active agents are incorporated in a concentration less than 70% by weight of the coatings or the active agent from these coatings can be released from these coatings in the environment of the proppants.
    Type: Grant
    Filed: December 11, 2018
    Date of Patent: June 7, 2022
    Assignee: Agienic, Inc.
    Inventors: Anoop Agrawal, Donald R. Uhlmann, Nicholas R. Krasnow
  • Patent number: 11352541
    Abstract: A sealing composition for sealing an annulus of a wellbore includes from 20 weight percent to 97 weight percent epoxy resin based on the total weight of the composition. The epoxy resin comprising at least one of 2,3-epoxypropyl o-tolyl ether, alkyl glycidyl ethers having from 12 to 14 carbon atoms, or a compound having formula (OC2H3)—CH2—O—R1—O—CH2—(C2H3O), where R1 is a linear or branched hydrocarbyl having from 4 to 24 carbon atoms. The sealing composition also includes from 1 weight percent to 20 weight percent curing agent based on the total weight of the composition. Methods for sealing a wellbore annulus or casing-casing annulus includes introducing a spacer fluid to the wellbore, introducing the sealing composition to the wellbore, displacing the sealing composition into the annulus, and curing the sealing composition.
    Type: Grant
    Filed: August 30, 2018
    Date of Patent: June 7, 2022
    Assignee: Saudi Arabian Oil Company
    Inventors: Abdullah Al-Yami, Ali Alsafran, Vikrant Wagle, Hussain Albahrani, Zainab Alsaihati
  • Patent number: 11312892
    Abstract: The present disclosure relates to subterranean formation operations and, more particularly, to embedded treatment fluid additives for use in subterranean formation operations. The embedded treatment additives may comprise an aqueous-soluble downhole reactive material embedded in a crosslinked polymeric solution to delay the reactivity of the aqueous-soluble downhole reactive material, thereby forming the embedded treatment additive, wherein the aqueous-soluble downhole reactive material is a solid.
    Type: Grant
    Filed: December 7, 2016
    Date of Patent: April 26, 2022
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Dipti Singh, Aaron Michael Beuterbaugh, Enrique Antonio Reyes
  • Patent number: 11306240
    Abstract: Aqueous well treatment fluids especially suited for use in far field diversion in low viscosity carrier fluids comprise water, a friction reducer, and a diverter. The diverter comprises dissolvable particulates and proppants. The dissolvable particulates have a specific gravity of from about 0.9 to about 1.6 and a particle size of about 50 mesh or less. The proppants have a specific gravity of from about 0.9 to about 1.4 and a particle size of from about 20 to about 100 mesh. The dissolvable particulates have a higher specific gravity and a smaller particle size than the proppant.
    Type: Grant
    Filed: August 25, 2020
    Date of Patent: April 19, 2022
    Assignee: BJ Energy Solutions, LLC
    Inventors: Leonid Vigderman, Lingjuan Shen, Diankui Fu
  • Patent number: 11286726
    Abstract: Methods and systems are directed to the uniform distribution of a fluid through an annulus between a pipe and a wellbore wall, primarily when there is a preferential flow in one side of the annulus relative to another side of the annulus. Generally, the methods and systems involve introducing a first agent into the annulus, wherein the first agent is configured to cause swelling of a cladding on the exterior of the section of the pipe. The swelling reduces flow in the annulus on the side of the pipe with preferential flow so as to reduce the preferential flow on that side of the pipe.
    Type: Grant
    Filed: January 7, 2019
    Date of Patent: March 29, 2022
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Siva Rama Krishna Jandhyala, Sunita Kadam, Rahul Chandrakant Patil, Wiliam W. Shumway
  • Patent number: 11230660
    Abstract: Lightweight micro-proppant suitable to prop open not only near-wellbore microfractures but also far-field microfractures. Some methods of fracturing and propping may comprise first introducing a pad fluid comprising a lightweight micro-proppant into a wellbore penetrating a subterranean formation at a rate and pressure sufficient to create or extend a fracture network in the subterranean formation, wherein the fracture network comprises microfractures. The lightweight micro-proppant comprises a thermoset nanocomposite having a specific gravity of about 0.9 to about 1.4 and having an average diameter of about 0.1 microns to about 50 microns. Then introducing a proppant slurry comprising a macro-proppant into the wellbore penetrating the subterranean formation after introducing the pad fluid forming a proppant pack in the fracture network wherein at least some of the lightweight micro-proppant is located in the microfractures.
    Type: Grant
    Filed: July 8, 2016
    Date of Patent: January 25, 2022
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Philip D. Nguyen, Mallikarjuna Shroff Rama, Prashant D. Chopade
  • Patent number: 11220581
    Abstract: An aqueous dispersion includes polyacrylamide, a crosslinker, and a filler. The crosslinker includes at least one of hydroquinone or hexamethylenetetramine. The filler includes at least one of a metal oxide or a nanomaterial. The metal oxide includes at least one of zirconium oxide, zirconium hydroxide, or titanium oxide. The nanomaterial includes at least one of graphene, graphene oxide, or boron nitride. In some cases, the filler is a nanocomposite of the metal oxide and the nanomaterial.
    Type: Grant
    Filed: November 5, 2019
    Date of Patent: January 11, 2022
    Assignee: Saudi Arabian Oil Company
    Inventors: Ayman Mohammed Almohsin, Edreese Alsharaeh
  • Patent number: 11220882
    Abstract: A method for recompleting a well is applied to a well such that the recompleted well can thermally transfer geothermal energy to surface. The recompleting method can comprise steps to enhance the thermal conductivity of a wellbore of a hydrocarbon well, by inserting a thermal material into the wellbore that displaces a reservoir fluid having a lower thermal conductivity than the thermal material. The recompleting method can also comprise steps to enhance the thermal conductivity of a reservoir in which the wellbore is located by inserting a thermal material into the reservoir that displaces a reservoir fluid having a lower thermal conductivity than the thermal material, or in which the reservoir is fractured, and a thermal material is inserted into created fractures.
    Type: Grant
    Filed: December 18, 2017
    Date of Patent: January 11, 2022
    Assignee: Element Coil Services Inc.
    Inventors: Grant Nevison, Josh Thompson
  • Patent number: 11149181
    Abstract: A convertible composition comprising a nanosilica drilling fluid, the nanosilica drilling fluid comprising an aqueous based drilling mud, where the aqueous based drilling mud comprises water, and an alkaline nanosilica dispersion, where the alkaline nanosilica dispersion comprises nanosilica; and a chemical activator, the chemical activator operable to hydrolyze in the presence of water to produce an acid, where a weight ratio of the alkaline nanosilica dispersion to the chemical activator is between 1 to 0.001 and 1 to 0.25.
    Type: Grant
    Filed: September 15, 2020
    Date of Patent: October 19, 2021
    Assignee: SAUDI ARABIAN OIL COMPANY
    Inventors: Vikrant Wagle, Abdullah Al-Yami, Rajendra A. Kalgaonkar, Zainab Alsaihati
  • Patent number: 11136494
    Abstract: A polymer composition may include one or more monomeric units, with an internal crosslinker, internal breaker, scale control additive or a combination thereof.
    Type: Grant
    Filed: June 1, 2017
    Date of Patent: October 5, 2021
    Assignee: ROCKWATER ENERGY SOLUTIONS, LLC
    Inventors: Jack Maberry, Yifan Li, Rupa Venugopal, Mark Kinsey, Paul Pistono, Fati Malekahmadi
  • Patent number: 11124689
    Abstract: Systems and methods for forming a permanent plug in a subterranean formation include providing a solution of colloidal silica and pumping the colloidal silica into a bore of a subterranean well so that the colloidal silica penetrates pores of the subterranean formation. The colloidal silica within the pores of the subterranean formation is dehydrated to form a glass-like material within the pores of the subterranean formation.
    Type: Grant
    Filed: October 18, 2019
    Date of Patent: September 21, 2021
    Assignee: SAUDI ARABIAN OIL COMPANY
    Inventors: Mohammed Bataweel, Prasad Baburao Karadkar, Ayman Al-Mohsin, Haitham A. Othman
  • Patent number: 11034882
    Abstract: The present invention relates to a method for inhibiting water permeation in an extraction well of a hydrocarbon oil from an underground reservoir which comprises injecting into said reservoir at least one polymerizable composition comprising: at least one hydrophilic monomer, -at least one hydrophilic initiator of radical polymerization with thermal activation (hydrophilic initiator), at least one lipophilic initiator of radical polymerization with thermal activation (lipophilic initiator). The present invention also relates to the polymerizable compositions that can be used in said method.
    Type: Grant
    Filed: August 22, 2017
    Date of Patent: June 15, 2021
    Assignee: ENI S.P.A.
    Inventors: Lucilla Del Gaudio, Davide Moscatelli, Paola Albonico
  • Patent number: 11035195
    Abstract: Methods of mitigating lost circulation while drilling a wellbore. The methods include circulating a drilling mud to a downhole end of the wellbore via a drill string and, during the circulating, drilling the wellbore with a drill bit of the drill string. The methods also include detecting lost circulation within the wellbore while drilling the wellbore and include providing a monomer solution to the wellbore. The methods further include providing a catalyst to the wellbore responsive to detecting the lost circulation event and combining the monomer solution and the catalyst to polymerize a monomer from the monomer solution, within the wellbore, and forming a viscous plug within the wellbore. Subsequent to the combining, the methods include flowing at least a portion of the viscous plug within the wellbore and into a zone of lost circulation that extends within a subsurface region.
    Type: Grant
    Filed: November 13, 2018
    Date of Patent: June 15, 2021
    Assignee: ExxonMobil Upstream Research Company
    Inventors: Bill R. Meeks, Timothy J. Nedwed, Douglas A. Mitchell, Rachna Jain, Kaustubh S. Kulkarni
  • Patent number: 11015109
    Abstract: A particulate profile control agent self-adaptive to a size of formation pore throat and a preparation method thereof include: raw materials and mass fraction for preparing a system including a main agent of 0.04˜0.2%, a nucleating agent of 0.005˜0.01%, a crosslinking agent of 0.002˜0.04%, an additive of 0.005˜0.01% and water. The preparation method includes: adding the main agent in proportion to the water and evenly mixing the mixture of the main agent and the water, and then adding the additive, the crosslinking agent and the nucleating agent in turn so as to form the profile control agent; pumping the profile control agent into the formation to be reacted at a reservoir temperature for a period of time to form colloidal particles on the spot for sealing off a high-permeability layer. The present disclosure is of easy operation and low cost, low initial viscosity and good injectivity.
    Type: Grant
    Filed: October 15, 2020
    Date of Patent: May 25, 2021
    Assignee: Southwest Petroleum University
    Inventors: Fayang Jin, Daijun Du, Wanfen Pu, Xiang Li, Ye Ju, Kexing Li, Lin Sun, Rui Liu, Shuyu Song, Mian Wang, Wei Liao, Desheng Qian
  • Patent number: 10974289
    Abstract: Embodiments relate to solid nano-particles applied to the surface of well equipment to treat bituminous material adhesion. An embodiment provides a method of treating the surface of well equipment. The method may comprise applying a solid nanoparticle film to the surface of the well equipment with a treatment fluid comprising solid nanoparticles. The method may further comprise allowing the solid nanoparticles to interact with the surface of the well equipment and/or bituminous materials adhered to the surface of the well equipment to remove at least a portion of the bituminous materials from the surface of the well equipment.
    Type: Grant
    Filed: August 8, 2018
    Date of Patent: April 13, 2021
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Lee J. Hall, Philip W. Livanec
  • Patent number: 10927247
    Abstract: A method for inhibiting the permeation of water in an extraction well of a hydrocarbon fluid from an underground reservoir is described. The method includes the injection of at least one treatment fluid into the underground reservoir. The treatment fluid contains at least one emulsion or dispersion in an organic solvent of at least one copolymer of a first monomer of an acrylic monomer or a methacrylic monomer, and a second monomer having at least one ethylene unsaturation and at least one polyoxyethylene chain. The emulsion or dispersion of the copolymer used in the method is also described.
    Type: Grant
    Filed: April 13, 2016
    Date of Patent: February 23, 2021
    Assignee: ENI S.p.A.
    Inventors: Lucilla Del Gaudio, Roberto Lorefice, Massimo Silvio Morbidelli, Davide Moscatelli
  • Patent number: 10889746
    Abstract: Provided is a glass bead suspension. The glass bead suspension comprises water, a synthetic hectorite having an empirical formula of Si8Mg5.45Li0.4H4O24Na0.7, and glass beads.
    Type: Grant
    Filed: January 29, 2020
    Date of Patent: January 12, 2021
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Peter James Boul, Gregory Robert Hundt, Joseph Kleber Maxson, Simone Elizabeth Ashley Lumsden, Darrell Chad Brenneis, Ronnie Glen Morgan
  • Patent number: 10883033
    Abstract: A date palm seed-based lost circulation material (LCM) is provided. A date palm seed LCM may be manufactured by drying date palm seeds and grinding the dried date palm seeds to create a plurality of particles. The particles may have sizes less than 4 mm, from 1 mm to 2 mm, or from 2 mm to 4 mm. The date palm seed LCM may have a volumetric swelling greater than an LCM formed from tree nuts and may have a volumetric swelling of at least 0.3 cubic centimeters per gram. The date palm seed LCM may have a D50 shift factor less than an LCM formed from calcium carbonate and may have a D50 shift factor of at least 0.38%. The date palm seed LCM may have a stability index of at least 0.95. Methods of lost circulation control and manufacture of a date palm seed LCM are also provided.
    Type: Grant
    Filed: May 17, 2019
    Date of Patent: January 5, 2021
    Assignee: Saudi Arabian Oil Company
    Inventor: Md Amanullah
  • Patent number: 10876037
    Abstract: A polymerizable chemical system for consolidating particulates in a subterranean formation including a liquid resin, a curing agent, and a permeability enhancing additive. The chemical system is a homogenous composition that polymerizes to forms a solid upon heating at a temperature greater than 60° C. Consolidating particulates in a subterranean formation includes providing a polymerizable chemical system comprising a liquid resin, a curing agent, and a permeability enhancing additive to a subterranean formation, and polymerizing the polymerizable chemical system to consolidate particulates in the formation to yield a porous consolidated particulates pack.
    Type: Grant
    Filed: May 2, 2018
    Date of Patent: December 29, 2020
    Assignee: Saudi Arabian Oil Company
    Inventors: Fakuen Frank Chang, Xiaoyu Tan
  • Patent number: 10876032
    Abstract: Disclosed is a composition and use thereof for the recovery of hydrocarbon fluids from a subterranean reservoir. More particularly, this invention concerns ?-glycol containing sulfonated epoxy resin composition and method for preparing said composition. The ?-glycol containing sulfonated epoxy resin composition is made by forming a reaction product comprising an epoxide-containing compound, a primary amino sulfonate, and optionally one or more of a primary monoamine alkylene oxide oligomer, followed by converting any unreacted epoxide groups in the reaction product to ?-glycol groups by hydrolysis. Said ?-glycol containing sulfonated epoxy resin compositions demonstrate good solubility in aqueous solutions and are useful for modifying the permeability of subterranean formations and increasing the mobilization and/or recovery rate of hydrocarbon fluids present in the formations.
    Type: Grant
    Filed: June 26, 2017
    Date of Patent: December 29, 2020
    Assignee: Dow Global Technologies LLC
    Inventors: Stephen M. Hoyles, Robert E. Hefner, Jr.
  • Patent number: 10870787
    Abstract: A date tree trunk-based lost circulation material (LCM) is provided. The date tree trunk LCM includes date tree trunk fibers produced from date tree trunks. The date tree trunks may be obtained from the date tree waste produced by the processing of date trees in the production of date fruits. The date tree trunk LCM may include fibers having lengths less than 8 millimeters (5 mm) and having an aspect ratio range of 10 to 15. Methods of lost circulation control using a date tree trunk LCM and manufacture of a date tree trunk LCM are also provided.
    Type: Grant
    Filed: April 9, 2019
    Date of Patent: December 22, 2020
    Assignee: Saudi Arabian Oil Company
    Inventors: Md Amanullah, Jothibasu Ramasamy
  • Patent number: 10851620
    Abstract: An injection and downhole-mixing system and method mix two or more components downhole in a wellbore. The system delivers two or more components via fluidly separated delivery channels from the surface into a downhole injection point of the wellbore wherein they are mixed and injected into the wellbore to form a solidifying isolation mixture therein at or about the downhole injection point. After set, the isolation mixture forms a solid, impermeable barrier in the wellbore. The components for forming such barriers may be epoxies, polymers, resins, resin-based gypsum cements, and the like.
    Type: Grant
    Filed: April 5, 2017
    Date of Patent: December 1, 2020
    Inventor: Colton Garrett Hoffman
  • Patent number: 10844274
    Abstract: In an embodiment, a hydrocarbon recovery material includes an organic acid and a water material, the organic acid including a naphthenic acid, L-prolific, or a combination thereof. In another embodiment, an oil recovery method includes injecting a treatment fluid into a reservoir under reservoir conditions, the reservoir containing hydrocarbons, and the treatment fluid includes an organic acid and a water material. In another embodiment, an oil recovery method includes injecting a treatment fluid into a reservoir containing hydrocarbons, the treatment fluid comprising an organic acid in one or more of an oil-in-water emulsion, a resin dispersion, or a polymer capsule.
    Type: Grant
    Filed: April 16, 2019
    Date of Patent: November 24, 2020
    Assignee: UNIVERSITY OF WYOMING
    Inventors: Vladimir Alvarado, Teresa Reilly, Kelly Meyers
  • Patent number: 10844269
    Abstract: A method and a sealing fluid for setting a packer in an annulus between a well bore and a well tubular is provided, which by adjusting i.a. the density, viscosity and setting time of the sealing fluid is able to provide among other things a full radial seal with an acceptable axial dispersion, in particular in highly deviated wells and/or in wells having eccentric annuli.
    Type: Grant
    Filed: February 19, 2018
    Date of Patent: November 24, 2020
    Assignee: TOTAL E&P DANMARK A/S
    Inventors: Edo Boekholtz, Hans Van Dongen
  • Patent number: 10830021
    Abstract: A subsurface system includes a tubular having an opening. A filtration media is mounted about the tubular over the opening. The filtration media includes a selectively expandable outer surface positioned over the opening. The selectively expandable outer surface includes one or more selectively expandable openings. The one or more selectively expandable openings transition from a first dimension to a second dimension upon expansion of the selectively expandable outer surface.
    Type: Grant
    Filed: July 5, 2018
    Date of Patent: November 10, 2020
    Assignee: BAKER HUGHES, A GE COMPANY, LLC
    Inventors: Jason E. Fuxa, Christophe Malbrel, Michael Johnson, Elmer Peterson
  • Patent number: 10774255
    Abstract: A viscosity-retaining formulation for use in high-temperature hydrocarbon-bearing reservoir applications. The formulation includes a brine composition and a viscosity enhancing composition, the viscosity enhancing composition operable to enhance viscosity retention of the viscosity-retaining formulation at least, in part, through micellization, the viscosity enhancing composition including a polycation composition and an anionic surfactant composition.
    Type: Grant
    Filed: January 11, 2018
    Date of Patent: September 15, 2020
    Assignee: SAUDI ARABIAN OIL COMPANY
    Inventor: Peter Boul
  • Patent number: 10767101
    Abstract: A method of treating a subterranean formation penetrated by a wellbore comprises: introducing into the subterranean formation a treatment fluid comprising coated polymeric particles having a polymeric core and a curable thermoset coating disposed on the polymeric core; allowing the curable thermoset coating to cure under downhole conditions; and forming a fluid-permeable pack from the coated polymeric particles, the fluid-permeable pack reducing or substantially preventing the passage of formation particles from the subterranean formation into the wellbore while allowing passage of formation fluids from the subterranean formation into the wellbore.
    Type: Grant
    Filed: June 28, 2018
    Date of Patent: September 8, 2020
    Assignee: BAKER HUGHES, A GE COMPANY, LLC
    Inventors: Anton Kovalchuk, Ramon Garza
  • Patent number: 10689559
    Abstract: According to at least one embodiment of the present description, a cement slurry includes 50% to 90% BWOC of a cement precursor material based on a total weight of the cement slurry; and from 10% to 50% BWOC of a flexible additive based on the total weight of the cement slurry. The flexible additive includes hydrophilic polyolefin fibers or 2,6-di-tert-butyl-p-cresol.
    Type: Grant
    Filed: March 19, 2018
    Date of Patent: June 23, 2020
    Assignee: Saudi Arabian Oil Company
    Inventors: Abdullah Al-Yami, Vikrant Wagle, Hussain Albahrani, Zainab Alsaihati, Antonio Santagati, Mohammad Al-Alqam, Ali Alsafran, Abdulaziz Alhelal, Nasser Alalhareth, Abdullah Al-Awadh
  • Patent number: 10663448
    Abstract: Methods of ranking formation stabilizer performance are described. The methods include obtaining drill cuttings from a subterranean formation, grinding and sieving the drill cuttings to a particle size larger than 200 mesh, adding a formation stabilizer solution to the ground and sieved drill cuttings to form a mixture, agitating the mixture, and measuring turbidity of the agitated mixture.
    Type: Grant
    Filed: November 6, 2014
    Date of Patent: May 26, 2020
    Assignee: HALLIBURTON ENERGY SERVICES, INC.
    Inventors: Venkata Satya Srikalyan Bhamidipati, Ajish Potty, Syed Muhammad Farrukh Hamza
  • Patent number: 10655043
    Abstract: Aqueous fluids containing hydrophobic particles are effective media for cleaning water-base drilling fluids and drilling fluid solids from the interior surface of a casing string. Hydrophobic fibers may be added to a drilling fluid, a spacer fluid, a chemical wash, or combinations thereof. The disclosed fluids may be employed during primary cementing operations where it is not possible to use a bottom plug.
    Type: Grant
    Filed: August 11, 2015
    Date of Patent: May 19, 2020
    Assignee: Schlumberger Technology Corporation
    Inventors: Diankui Fu, Bipin Jain
  • Patent number: 10648279
    Abstract: A method for creating access to annular spacing during P&A operations is described. Specifically, helical coils are cut into one or more casings before the plugging material is set. The plugging material is able to exit the helical coils, forming multiple, small rock-to-rock seals.
    Type: Grant
    Filed: March 12, 2018
    Date of Patent: May 12, 2020
    Assignee: ConocoPhillips Company
    Inventor: Randall S. Shafer
  • Patent number: 10611944
    Abstract: A rapidly dehydrating lost circulation material (LCM) composition that forms an acid-soluble plug is provided. The LCM composition may include a carrier fluid, an acid-soluble-particulate material, a viscosifier, and date tree rachis fibers. The carrier fluid may be water and the viscosifier may be a cellulosic microfiber. The LCM composition may alter a lost circulation zone by forming an acid-soluble plug in a fracture of the lost circulation zone. The acid-soluble plug may be removed via an acid solution, such as a hydrochloric acid solution. Methods of lost circulation control and manufacture of a rapidly dehydrating LCM are also provided.
    Type: Grant
    Filed: February 18, 2019
    Date of Patent: April 7, 2020
    Assignee: Saudi Arabian Oil Company
    Inventor: Md Amanullah
  • Patent number: 10611945
    Abstract: A rapidly dehydrating lost circulation material (LCM) composition that forms an acid-soluble plug is provided. The LCM composition may include a carrier fluid, an acid-soluble-particulate material, a viscosifier, and date tree rachis fibers. The carrier fluid may be water and the viscosifier may be a cellulosic microfiber. The LCM composition may alter a lost circulation zone by forming an acid-soluble plug in a fracture of the lost circulation zone. The acid-soluble plug may be removed via an acid solution, such as a hydrochloric acid solution. Methods of lost circulation control and manufacture of a rapidly dehydrating LCM are also provided.
    Type: Grant
    Filed: February 18, 2019
    Date of Patent: April 7, 2020
    Assignee: Saudi Arabian Oil Company
    Inventor: Md Amanullah
  • Patent number: 10611946
    Abstract: A rapidly dehydrating lost circulation material (LCM) composition that forms an acid-soluble plug is provided. The LCM composition may include a carrier fluid, an acid-soluble-particulate material, a viscosifier, and date tree rachis fibers. The carrier fluid may be water and the viscosifier may be a cellulosic microfiber. The LCM composition may alter a lost circulation zone by forming an acid-soluble plug in a fracture of the lost circulation zone. The acid-soluble plug may be removed via an acid solution, such as a hydrochloric acid solution. Methods of lost circulation control and manufacture of a rapidly dehydrating LCM are also provided.
    Type: Grant
    Filed: February 18, 2019
    Date of Patent: April 7, 2020
    Assignee: Saudi Arabian Oil Company
    Inventor: Md Amanullah
  • Patent number: 10570700
    Abstract: A method of fracturing a subterranean formation penetrated by a well comprises: forming a fracturing composition comprising a carrier fluid; and a superabsorbent polymer component comprising one or more of the following: a first composite of a proppant and a first superabsorbent polymer in an unhydrated form, the first superabsorbent polymer being at least partially embedded in a void area of the proppant; a coated superabsorbent polymer; a superabsorbent material having a three-dimensional network; or a second composite of a second superabsorbent polymer and a slow-release breaker; and pumping the hydraulic fracturing composition into the subterranean formation to create or enlarge a fracture.
    Type: Grant
    Filed: July 24, 2018
    Date of Patent: February 25, 2020
    Assignee: BAKER HUGHES, A GE COMPANY, LLC
    Inventors: Scott Gregory Nelson, Hong Sun, Jia Zhou, Leiming Li, Xiaolan Wang, Qi Qu
  • Patent number: 10570709
    Abstract: A variety of systems, methods and compositions are disclosed, including, in one method, a method may comprise pumping a solids containing fluid through a wellbore and into a previously fractured subterranean formation at an injection rate and pressure that is at or above a fracture gradient of the previously fractured subterranean formation, wherein the solids containing fluid comprises a curable resin coated proppant; lowering the injection rate of the solids containing fluid to allow a portion of the curable resin coated proppant to, at least partially, pack and fill one or more voids surrounding a casing disposed in the wellbore; and allowing the portion of the curable resin coated proppant disposed in the one or more voids to cure and form an in situ mechanical screen.
    Type: Grant
    Filed: March 24, 2016
    Date of Patent: February 25, 2020
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Philip D. Nguyen
  • Patent number: 10550307
    Abstract: Methods for treating a zone of a subterranean formation penetrated by a wellbore comprising: (A) forming a treatment fluid comprising: (i) an aqueous continuous phase; (ii) a first chemical having: (a) a single epoxy group; and (b) at least one alkoxy group on a silicon atom, wherein the first chemical is water soluble or dissolves with hydrolysis in the aqueous continuous phase; (iii) a second chemical having an amine group, wherein the second chemical is water soluble or dissolves with hydrolysis in the aqueous continuous phase; and (B) introducing the treatment fluid through the wellbore into the zone of the subterranean formation.
    Type: Grant
    Filed: February 14, 2014
    Date of Patent: February 4, 2020
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Prajakta Ratnakar Patil, Shoy George Chittattukara, Philip D. Nguyen
  • Patent number: 10519357
    Abstract: A lost circulation material (LCM) having date fruit caps is provided. The date fruit cap LCM includes date fruit caps from a date tree. The date fruit caps have multiple flakes (for example, three flakes) attached at one end to an end cap and free at the other end. The date fruit caps may be obtained from the waste product of date tree and date fruit processing. The date fruit cap LCM may be added to a drilling fluid (for example, a drilling mud) to mitigate or prevent such lost circulation in a well. Methods of lost circulation control with the date fruit cap LCM are also provided.
    Type: Grant
    Filed: March 1, 2018
    Date of Patent: December 31, 2019
    Assignee: Saudi Arabian Oil Company
    Inventor: Md Amanullah
  • Patent number: 10513647
    Abstract: A lost circulation material (LCM) having date fruit caps is provided. The date fruit cap LCM includes date fruit caps from a date tree. The date fruit caps have multiple flakes (for example, three flakes) attached at one end to an end cap and free at the other end. The date fruit caps may be obtained from the waste product of date tree and date fruit processing. The date fruit cap LCM may be added to a drilling fluid (for example, a drilling mud) to mitigate or prevent such lost circulation in a well. Methods of lost circulation control with the date fruit cap LCM are also provided.
    Type: Grant
    Filed: March 1, 2018
    Date of Patent: December 24, 2019
    Assignee: Saudi Arabian Oil Company
    Inventor: Md Amanullah