Abstract: A method of treating a subterranean formation penetrated by a wellbore by contacting an energized fluid with the subterranean formation; and reducing a partial pressure of the energized fluid by an amount sufficient to form polymeric foam structure within the subterranean formation.

Abstract: In an embodiment, the cement compositions comprise: (i) hydraulic cement, wherein the hydraulic cement has a ratio of CaO to SiO2 in the range of 2.0 to 4.0; and (ii) a water-soluble metaphosphate in a concentration of at least 2.5% bwoc. In another embodiment, the cement compositions comprise: (i) hydraulic cement, wherein the hydraulic cement has a ratio of CaO to SiO2 of less than 2.0; and (ii) a water-soluble metaphosphate; wherein any alkali nitrate is in a concentration of less than 2% bwoc; and wherein any alkali hydroxide, alkali carbonate, or alkali citrate is in a concentration of less than 0.2% bwoc. Methods of cementing in a well comprising forming either of such cement compositions and introducing it into the well are provided.

Abstract: A wellbore cement composition includes substantially unhydrated cement powder and additive powder for cement. The additive powder is formulated from ingredients including a liquid additive for cement and solid carrier particles. The liquid additive is absorbed by the solid carrier particles. A wellbore cementing method includes using a dry cement composition, adding water to the dry cement composition, forming a cement slurry, placing the slurry in a wellbore, and setting the placed slurry. The dry cement composition contains substantially unhydrated cement powder and retarder powder for cement. The retarder powder contains a retarder absorbed by solid carrier particles.

Abstract: Spacer fluids that are stable at temperatures up to at least 300° C. comprise water, polystyrene sulfonate and a mixture of particulate materials. The particulate materials may be chosen such that the mixture has at least a trimodal particle-size distribution. The fluids may further comprise inorganic clays, mutual solvents and surfactants.

Abstract: A cross-linkable composition with controlled cross-linking as a material is used for fixing and thermally insulating tubes used for casing in drill holes, especially oil drill holes, during exploitation operations, such as oil extraction, in the drill hole. The cross-linkable composition includes at least one diene polyol, at least one polyisocyanate, and at least one heat insulating liquid filler.

Abstract: The present disclosure is directed to compositions and methods that may be used for enhanced oil recovery, for modifying the permeability of subterranean formations and for increasing the mobilization and/or recovery rate of hydrocarbon fluids present in the formations. The compositions may include, for example, expandable cross linked polymeric microparticles having an unexpanded volume average particle size diameter of from about 0.05 to about 5,000 microns and a cross linking agent content of from about 100 to about 200,000 ppm of hydrolytically labile silyl ester or silyl ether crosslinkers and from 0 to about 300 ppm of non-labile crosslinkers.

Abstract: Methods of treating a subterranean formation are disclosed that include placing a treatment fluid into a subterranean formation, the treatment fluid containing a solid agent and one or more polymers capable of consolidating to form a composite polymeric structure at a downhole location.

Abstract: A method of wellbore strengthening may include providing a wellbore strengthening fluid comprising a drilling fluid, a particulate, and a fiber; introducing the wellbore strengthening fluid into a wellbore penetrating a subterranean formation; and forming a plug comprising the particulate and the fiber in a void near the wellbore, the plug being capable of maintaining integrity at about 1000 psi or greater overbalance pressure.

Abstract: Methods of making a degradable ball composition comprising a carboxylic acid, a fatty alcohol, a fatty acid salt, a fatty ester, or a combination thereof comprising the steps of: forming a thermoplastic mass, and allowing the thermoplastic mass to cool as to form a degradable ball that is introduced in subterranean treatments by a carrier fluid.

Abstract: Disclosed is a composition and a method for cementing a casing in a borehole of a well using an aqueous cementing composition comprising (a) water, (b) a cementing composition comprising (i) a hydraulic cement, (ii) an anionically- and hydrophobically-modified polymer, (iii) a dispersant, and optionally (iv) one or more other additives conventionally added to aqueous cementing compositions useful in cementing casings in the borehole of wells. Preferably the anionically- and hydrophobically-modified hydroxyethyl cellulose has an ethylene oxide molar substitution of from 0.5 to 3.5, a hydrophobe degree of substitution of from 0.001 to 0.025, an anionic degree of substitution of from 0.001 to 1, and a weight-average molecular weight of from 100,000 to 4,000,000 Daltons and the dispersant is sulfonated polymer, melamine formaldehyde condensate, a naphthalene formaldehyde condensate, a branched or non-branched polycarboxylate polymer.

Abstract: Biomimetic adhesive compositions can be used in various aspects of subterranean treatment operations. Methods for treating a subterranean formation can comprise: providing an adhesive composition that comprises a first polymer comprising a plurality of monomers that comprise a phenolic moiety, a biopolymer that is crosslinkable with the first polymer, a crosslinking agent, and an oxidizing agent; introducing the adhesive composition into a subterranean formation; and forming a coacervate-bound surface in the subterranean formation by crosslinking the first polymer.

Abstract: The present invention relates to processes for consolidating an underground formation with a consolidating mineral. The consolidating material is a carbonate and is produced from an alkaline treatment fluid containing, in at least some embodiments, environmentally friendly and inexpensive components. In one embodiment, the process can be applied to consolidation of an underground formation during or following drilling. The present invention also provides a treatment fluid suitable for use in such processes.

Abstract: A variety of methods and compositions are disclosed, including, in one embodiment, a method of cementing in a subterranean formation, comprising: providing a set-delayed cement composition comprising water, pumice, hydrated lime, and a set retarder; activating the set-delayed cement composition; introducing the set-delayed cement composition into a subterranean formation; and allowing the set-delayed cement composition to set in the subterranean formation.

Abstract: A self-adaptive cement formulation includes cement, water and asphaltite-mineral particles. The set cement demonstrates self-healing properties when exposed to methane, and is particularly suited for well-cementing applications. After placement and curing, the self-healing properties help maintain zonal isolation should bonding be disrupted between the set cement and the formation or a casing string, should cracks or defects appear in the set-cement matrix, or both.

Abstract: A method for removing water from a wellbore fluid may include the steps of contacting a wellbore fluid with a water absorbing polymer, where the wellbore fluid includes an aqueous fluid, allowing the water absorbing polymer to interact with the wellbore fluid for a sufficient period of time so that the water absorbing polymer absorbs at least a portion of water in the aqueous fluid, and separating the water absorbing polymer containing the absorbed water from the wellbore fluid.

Abstract: Methods of providing fluid loss control in a portion of a subterranean formation comprising: providing a treatment fluid comprising a base fluid and a plurality of seeds; introducing the treatment fluid into a portion of a subterranean formation penetrated by a well bore such that the seeds block openings in the subterranean formation to provide fluid loss control; and degrading the seeds over time within the subterranean formation. In some methods, the seeds are present in the treatment fluid in an amount of at least about 5 pounds per barrel. In addition, in some methods the seeds are preferably degradable.

Abstract: A method for blocking the permeability of a portion of a subterranean formation including the steps of: (a) selecting the portion of the subterranean formation to be treated, wherein the bottomhole temperature of the portion of the subterranean formation is equal to or greater than 250° F. (121° C.

Abstract: Disclosed herein are cement compositions and methods of using set-delayed cement compositions in subterranean formations. In one embodiment a method of plugging a wellbore is described. The method comprises providing a set-delayed cement composition comprising pumice, hydrated lime, a cement set retarder, and water; activating the set-delayed cement composition to produce an activated set-delayed cement composition; introducing the activated set-delayed cement composition into the wellbore; and allowing the activated set-delayed cement composition to form a plug in the wellbore that has a permeability of less than 0.1 millidarcy.

Abstract: This invention relates to oil and gas production, more specifically, to the methods of producing polymer emulsion for downhole operations and mixing degradable (hydrolysable) polymer emulsion with the treatment fluid.

Abstract: Compositions and methods for improving wellbores stability of a hydrocarbon bearing shale formation using nanoparticles to decrease swelling and plug pore throats.

Abstract: Mixtures of fibers and solid particles are effective for curing fluid losses and lost circulation in a subterranean well. Stiff fibers are more effective than flexible ones; however, mixtures of stiff and flexible fibers have a synergistic effect. The quantity and particle-size distribution of the solids are optimized according to the stiffness, dimensions and concentrations of fibers.

Abstract: A method for isolating a portion of a wellbore including preparing a sealant composition includes an emulsion of an internal phase and an external phase. The sealant composition is placed into the wellbore where one phase sets upon subjecting the sealant composition to a thermal source followed by the setting of the other phase.

Abstract: Methods and compositions that include a method of treating a subterranean formation comprising the steps of providing a carrier fluid comprising degradable balls that comprise a carboxylic acid, a fatty alcohol, a fatty acid salt, a fatty ester, a fatty acid salt, or a combination thereof, and introducing the carrier fluid to the subterranean formation during a treatment.

Abstract: The invention is directed to polymer-enhanced proppant transport fluids, comprising a suspension fluid comprising a crosslinked synthetic polymer gel formulation, and a plurality of proppant particles. The invention also encompasses methods for improving production from an oil or gas well, methods of water blocking or water shutoff in an oil or gas well, methods of enhancing oil recovery from an oil source, methods of treating a petroleum-containing formation to reduce sand production, and methods of displacing fluid from a wellbore by viscous plug flow.

Abstract: A lost circulation material and method for well treatment employing the material that is effective at sealing or plugging fractured zones and has utility over a wide range of temperatures, including high temperatures. The lost circulation material includes particulate material to quickly de-fluidize the fluid formulation, fibrous material to suspend particles in the slurrified form of the composition and increase the shear strength of the resultant seal, and non-Portland cement material for increasing the compressive strength.

Abstract: A cement composition for use in an oil or gas well, the cement composition comprises: a calcium aluminate cement; water; an organic acid; and a polymeric mixture comprising: (A) water; (B) citric acid; (C) a first polymer, wherein the first polymer: (i) comprises a cellulose backbone and carboxymethyl functional groups; and (ii) has a molecular weight of less than 100,000; and (D) a second polymer, wherein the second polymer: (i) comprises a lignosulfonate; and (ii) has a molecular weight of less than 100,000, wherein a test composition consisting essentially of: the cement; the water; the organic acid; and the polymeric mixture, and in the same proportions as in the cement composition has a thickening time of at least 5 hours at a temperature of 300° F. (148.9° C.) and a pressure of 10,000 psi (68.9 MPa).

Abstract: Fracturing operations can be problematic in completed wellbores containing at least one existing fracture, since it can be difficult to seal an existing fracture and initiate a new fracture within a reasonable timeframe due to the presence of particulate materials in the wellbore. Methods for fracturing a completed wellbore can comprise introducing a treatment fluid comprising a plurality of degradable sealing particulates into a completed wellbore penetrating a subterranean formation having an existing fracture therein; sealing the existing fracture with at least a portion of the degradable sealing particulates, thereby forming a degradable particulate seal; after sealing, allowing any degradable sealing particulates remaining in the treatment fluid to degrade, such that the treatment fluid becomes substantially particulate free; and after the treatment fluid becomes substantially particulate free, fracturing the subterranean formation so as to introduce at least one new fracture therein.

Abstract: Additives are used in treatment fluids in subterranean operations to prevent fluid loss within a subterranean formation. A method includes providing a treatment fluid that includes a viscosifying polymer and a solid-liquid phase transition temperature modifier and placing the treatment fluid in a subterranean formation penetrated by a wellbore, wherein the solid-liquid phase temperature modifier is added in an amount to modulate the gelling temperature of the viscosifying polymer to a target temperature.

Abstract: Methylhydroxyethyl cellulose may be used as an additive in cement slurries in the treatment of wells to prevent or reduce the occurrence of gas channeling. In addition to acting as a gas control additive, methylhydroxyethyl cellulose controls fluid loss, minimizes free fluid and stabilizes foam during cementing of the well.

Abstract: The current application discloses compositions and methods for treating a subterranean formation. CO2 swellable elastomers can be used in a treatment fluid to at least partially block a high permeability region, therefore improving the performance of an operation such as matrix stimulation, acidizing, and acid fracturing.

Abstract: The present invention includes methods relating to the setting of fluids or slurries in a wellbore. In one embodiment, a method of isolating a portion a wellbore by preparing a sealant composition comprising a fluid component and a polymeric additive component, placing the sealant composition into a wellbore and subjecting the sealant composition to ionizing radiation. The ionizing radiation can cause bonding between polymeric additive components and create a polymer matrix within the sealant composition that increases the mechanical strength of the sealant composition.

Abstract: The present invention includes methods and compositions relating to the setting of fluids or slurries in a wellbore. In one embodiment, a method of isolating a portion a wellbore includes preparing a sealant composition having a fluid component, a polymeric additive constituent, and a set modifier component. The sealant composition is placed into a wellbore and subjected to ionizing radiation. The ionizing radiation can cause bonding between polymeric additive constituents and create a polymer matrix within the sealant composition that increases the mechanical strength of the sealant composition. The ionizing radiation also alters the set modifier component, triggering the thickening of the sealant composition.

Abstract: Systems and methods for creating a hydraulic barrier at an interface between high and low permeability regions that may exist in high permeability-contrast subterranean formations. These systems and methods may include providing injection and/or production wells that are completed within the high and/or low permeability regions, supplying a pore throat blocking agent to an interface between the high and low permeability regions, and forming the hydraulic barrier at the interface. The pore throat blocking agent may be sized to substantially flow through the high permeability region while being substantially blocked, or occluded, from the low permeability region. In some embodiments, the hydraulic barrier may be greater than one acre (0.4 hectare) in area. In some embodiments, the subterranean formation may include an oil reservoir. In some embodiments, the high and/or low permeability formations may be swept concurrently and/or independently to remove oil from the oil reservoir.

Abstract: The invention provides concentrates for reducing the fluid loss on an oil base well drilling or servicing fluid, the concentrates comprising an oleagineous liquid and (1) a polymer which is solublized in the oleagineous liquid, or (2) a polymer which is solublized in the oleaginous liquid together with an organophilic polyphenolic material which is solublized and/or dispersed in the oleagineous liquid. The method of preparing the concentrate and the method of reducing the fluid loss of an oil base well drilling or servicing fluid utilizing the concentrates is also disclosed. The preferred oil soluble polymer is a styrene-butadiene rubber crumb. The preferred oleagineous liquid is an aromatic-free hydrogenated oil essentially containing only saturated hydrocarbons. The preferred polyphenolic material is a source of humic acid, such as mined lignite.

Abstract: The present invention relates to methods useful for isolating a portion of a wellbore. In one embodiment, a method includes preparing a sealant composition containing a set modifier component. The sealant composition is placed into the wellbore and is subjected to ionizing radiation that alters the set modifier component, triggering the thickening of the sealant composition.

Abstract: The uncontrolled flow of fluid from an oil or gas well may be reduced or stopped by injecting a composition including 2-cyanoacrylate ester monomer into the fluid stream. Injection of the monomer results in a rapid, perhaps instantaneous, polymerization of the monomer within the flow stream of the fluid. This polymerization results in formation of a solid plug that reduces or stops the flow of additional fluid from the well.

Abstract: Systems and methods for maximizing energy recovery from a subterranean formation are herein disclosed. According to one embodiment, a selected subterranean open-hole interval is isolated and at least one fracture is stimulated in the isolated subterranean open-hole interval.

Abstract: A method of servicing a wellbore in contact with a subterranean formation comprising placing a wellbore servicing fluid comprising a polyuronide polymer within the wellbore, contacting the wellbore servicing fluid with a divalent ion source, and allowing the wellbore servicing fluid to form a gel within the wellbore wherein the divalent ion source is located within the wellbore. A method of servicing a wellbore in contact with a subterranean formation comprising (a) placing a wellbore servicing fluid comprising a polyuronide polymer into the wellbore wherein the wellbore servicing fluid contacts a calcium ion source, (b) shutting the wellbore and allowing the servicing fluid to set into place for a period of time, and (c) repeating steps (a) and (b) until the permeability of a structure within the wellbore is reduced by about 50%.

Abstract: The flow of a fluid may be diverted from a high permeability zone to a low permeability portion of a subterranean formation by use of a diverter having the structural formula (I): wherein: R1 is —COO—(R5O)y—R4; R2 and R3 are selected from the group consisting of —H and —COO—(R5O)y—R4; provided that at least one of R2 or R3 is —COO—(R5O)y—R4 and further provided that both R2 or R3 are not —COO—(R5O)y—R4; R4 is —H or a C1-C6 alkyl group; R5 is a C1-C6 alkylene group; and each y is 0 to 5. Anhydrides of formula (I) are also acceptable as the diverter.

Abstract: In some embodiments, methods of disposing of produced water recovered during hydrocarbon drilling, production, transportation or storage operations include collecting produced water, mixing Type I Portland cement with produced water to form a cementitious slurry, introducing the cementitious slurry into an underground void and allowing the cementitious slurry to set and form cement.

Abstract: A variety of methods and compositions are disclosed, including, in one embodiment, a method of cementing in a subterranean formation, comprising: introducing a cement composition into a subterranean formation, wherein the cement composition comprises cement, water, and a saponin; and allowing the cement composition to set in the subterranean formation.

Abstract: A method includes providing a treatment fluid that is a viscous fluid. The viscous fluid may be greater than 0.01 Pa-s, greater than 0.1 Pa-s, and/or a cross-linked polymer based fluid. The method further includes determining a fines migration composition soluble in an aqueous phase of the treatment fluid that is compatible with the treatment fluid, and that interacts to secure fines in an earth formation intersecting a wellbore within a fines reaction time. The method further includes adding an amount of the fines migration composition to the treatment fluid, and treating the earth formation with the treatment fluid. The method includes leaking off a portion of the treatment fluid into the earth formation, and providing a residence time of the leaked off portion of the treatment fluid in the earth formation, where the residence time meets or exceeds the fines reaction time.

Abstract: Methods and systems relating to in situ decomposition of carbonyls at high temperature for fixing incomplete and failed well seals, are described. According to one embodiment, a method, comprises injecting a sealing agent into a subterranean well having sealing channels or voids in well casings. An alkaline-earth carbonate precipitate is formed from the decomposition of a carbonyl compound. The sealing agent includes the carbonyl compound and an alkaline-earth halide salt.

Abstract: Single-phase microemulsions, comprising a solvent, a surfactant blend and a carrier fluid, are effective spacer fluids for use during cementing operations. The solvent may be selected from the group consisting of monoterpenes, diterpenes, and alkyl or aryl esters of short-chain alcohols. The surfactant blend comprises a water-wetting surfactant or nonionic surfactant, a co-surfactant and an oil-solubilizing surfactant. The carrier fluid is aqueous. The solvent and surfactant blend are combined with the carrier fluid to produce the well-treatment microemulsion.

Abstract: A well treatment composition comprises: an aqueous liquid; a fluid loss additive, wherein the fluid loss additive comprises a high molecular weight, water-swellable polymer; and an amphiphilic dispersant, wherein the well treatment composition has an activity of at least 10%. A method of cementing in a subterranean formation comprises: introducing a cement composition into the subterranean formation, the cement composition comprising: (i) cement; (ii) water; and (iii) the well treatment composition; and allowing the cement composition to set.

Abstract: A foamed cement composition is disclosed for utilization in performing a variety of well cementing operations, and to methods for making and using same. The foamed cement composition basically includes a cement, water sufficient to form a pumpable slurry, a gas sufficient to foam the slurry, a foaming agent and optionally a foam stabilizing agent.

Abstract: A method of servicing a wellbore in a subterranean formation comprising preparing a wellbore servicing fluid comprising cement, an aqueous fluid, and a cyclodextrin, a cyclodextrin derivative, or combination thereof; placing the wellbore servicing fluid in the wellbore and allowing the fluid to set. A wellbore servicing fluid comprising cement, aqueous fluid, and a cyclodextrin, cyclodextrin derivative, or combination thereof.

Abstract: Methods of isolating a portion of a wellbore comprising placing a sealant composition into a subterranean formation after drilling of the wellbore therein and subjecting the sealant composition to ionizing radiation wherein subjecting the sealant composition to the ionizing radiation alters the set modifier. The sealant composition comprises a set modifier selected from the group consisting of an accelerator, an oxidizing agent, a set retarder, and combinations thereof. And the sealant composition comprises a polymeric component.

Abstract: A well treatment composition comprises a surfactant comprising a substituted ethoxylated phenol having at least one substituent, 1 to 14 moles of ethylene oxide, and the substituent being an alkyl, alkene, or alkyne with a carbon chain length in the range of 4 to 25, wherein the substituted ethoxylated phenol is selected from the group consisting of: ortho-, para-, or meta-substituted ethoxylated phenol; cardanol ethoxylate; derivatives thereof; and combinations of any of the foregoing. Preferably, the surfactant comprises cardanol ethoxylate, a substituted cardanol ethoxylate, and derivatives thereof. A method of cementing in a subterranean formation comprises: introducing a cement composition into the subterranean formation, wherein the cement composition comprises: (A) cement; (B) water; and (C) the surfactant; and allowing the cement composition to set.

Abstract: Methods are provided that include a method comprising providing a consolidating agent emulsion composition comprising an aqueous fluid, an emulsifying agent, and a consolidating agent; and introducing the consolidating agent emulsion composition into at least a portion of a subterranean formation. In some embodiments, the consolidating agent emulsion composition may be introduced into at least a portion of a propped fracture that comprises proppant particulates and allowed to at least partially consolidate at least a portion of the propped fracture. In some embodiments, the consolidating agent emulsion composition comprises a resin composition. Additional methods are also provided.