Organic Material Is Resin Or Resinous Patents (Class 166/295)
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Patent number: 9862872Abstract: Methods including introducing a treatment fluid into a wellbore in a subterranean formation, wherein the subterranean formation includes a coal seam gas reservoir, a freshwater reservoir, and formation laminae interposed therebetween, and the wellbore penetrating each, and wherein the treatment fluid comprises an aqueous base fluid and an aqueous curable resin; penetrating at least a portion of the formation laminae with the aqueous curable resin while maintaining the treatment fluid in the wellbore at a pressure sufficient to prevent the flow of freshwater from the freshwater reservoir into the wellbore; curing the aqueous curable resin, thereby stabilizing the formation laminae; creating permeability pathways in the coal seam gas reservoir itself; removing the treatment fluid from the wellbore; recovering gas from the coal seam gas reservoir.Type: GrantFiled: May 9, 2014Date of Patent: January 9, 2018Assignee: Halliburton Energy Services, Inc.Inventors: Philip D. Nguyen, Douglas Magill, Jessica Lynn Heeter, Billy Smith
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Patent number: 9840655Abstract: A method of treating a subterranean formation including providing a treatment fluid comprising a hardenable acid curable resin and a hydrolysable dimer acid ester. The treatment fluid is combined with a carrier fluid and is introduced into a subterranean formation. Upon the hydrolyzing of the ester in the formation and the contacting of unconsolidated proppants, the treatment method produces consolidated proppants.Type: GrantFiled: September 20, 2013Date of Patent: December 12, 2017Assignee: Halliburton Energy Services, Inc.Inventors: Philip D. Nguyen, Loan K. Vo, James William Ogle
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Patent number: 9840656Abstract: A method of treating a subterranean formation including providing a treatment fluid comprising a hardenable acid curable resin and a hydrolysable strong acid ester. The treatment fluid is combined with a diluent fluid and is introduced into a subterranean formation. Upon the hydrolyzing of the ester in the formation and the contacting of unconsolidated proppants, the treatment method produces consolidated proppants.Type: GrantFiled: September 20, 2013Date of Patent: December 12, 2017Assignee: Halliburton Energy Services, Inc.Inventors: Jim D. Weaver, Philip D. Nguyen, Dipti Singh
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Patent number: 9796909Abstract: The instant application relates to nanogels or compositions that hold multivalent metal ions until some level of nanogel degradation has occurred, then slowly release the multivalent metal ions for gelation with carboxylate containing polymers. Compositions comprising such nanogels, together with polymers that can be crosslinked with multivalent metal ions, allow the deployment of such mixtures in various applications, and greatly increased gelation times.Type: GrantFiled: December 30, 2013Date of Patent: October 24, 2017Assignees: ConocoPhillips Company, University of KansasInventors: Huili Guan, Cory Berkland, Ahmad Moradi-Araghi, Jenn-Tai Liang, Terry M. Christian, Riley B. Needham, Min Cheng, Faye Lynn Scully, James H. Hedges
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Patent number: 9790419Abstract: A composition for treating a subterranean formation is formed from water, a water-soluble polymer and a crosslinking system. The crosslinking system utilizes 1) primary crosslinking agent of at least one of a dialdehyde benzene source, a dioxane, and a trioxane, 2) a secondary low temperature organic crosslinking agent that generates aldehyde, and 3) a phenol source. The crosslinking system provides the composition a delayed gel time of about 2 to about 20 hours at temperatures of about 250° F. (121° C.) or higher. A method of treating a subterranean formation penetrated by a wellbore is also accomplished by forming a treatment fluid from the composition and introducing the treatment fluid into the formation through the wellbore.Type: GrantFiled: June 10, 2011Date of Patent: October 17, 2017Assignee: SCHLUMBERGER TECHNOLOGY CORPORATIONInventors: Richard D. Hutchins, Syed A. Ali, Maria Sarita Simon
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Patent number: 9758713Abstract: A hydraulic cementing composition and a method of making the same is disclosed. The composition is useful to form a sheath of hardened cement in the annular space between a well pipe disposed in a well bore and the walls of the well bore. The cementing composition is a mixture of dry ingredients comprising hydraulic cement and an additive to control the loss of fluid from an aqueous slurry containing the cementing composition. The fluid loss additive and a method of making the same is disclosed. The fluid loss additive is the reaction product of three chemical compounds each having an ethylene backbone and functional groups selected from carboxylates, hydrogen, anhydrides and combinations thereof.Type: GrantFiled: March 21, 2016Date of Patent: September 12, 2017Assignee: FRITZ INDUSTRIES, INC.Inventors: James C. Ferrell, Jr., Kurt O. Lindstrom, Luis M. Perales, Hongfeng Ren
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Patent number: 9759052Abstract: A method of treating a producing well that includes the introduction of a treatment fluid to the producing well from a surface above the subterranean formation, the treatment fluid comprised of at least PPG particles to enhance the oil rate and reduce the water rate of the producing well.Type: GrantFiled: December 2, 2014Date of Patent: September 12, 2017Assignee: SCHLUMBERGER TECHNOLOGY CORPORATIONInventors: Richard Hutchins, Syed A. Ali, Yenny Christanti, Manuel Jose Lastre Buelvas
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Patent number: 9751900Abstract: Special hydroxysilanes, which can be obtained by reacting ?-(3,4-epoxycyclohexyl)alkyltrialkoxysilanes with secondary amines, and adducts of the hydroxysilanes in the form of polymers containing silane groups. The hydroxysilanes can be produced having high purity in a simple process and are very stable in storage after production. The polymers containing silane groups that can be obtained by means of the hydroxysilanes have advantageous properties. The polymers enable moisture-curing compositions, which contain no isocyanate groups and which are suitable as elastic adhesives and sealants.Type: GrantFiled: May 21, 2014Date of Patent: September 5, 2017Assignee: SIKA TECHNOLOGY AGInventors: Andreas Kramer, Urs Burckhardt, Ursula Stadelmann
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Patent number: 9688000Abstract: The present invention provides a producing method of concrete capable of appropriately controlling setting and hardening, and having excellent flexibility of production and handling of concrete. The producing method of concrete includes a cement paste mixing step and a concrete mixing step. In the cement paste mixing step, cement, mixing water and retarder are mixed together to obtain cement paste. According to this, setting and hardening of the cement paste are suppressed, and it is possible to store the cement paste for predetermined time. In the concrete mixing step, aggregate is input into the cement paste, and they are mixed together to obtain concrete. By the mixing operation, a setting-delaying effect is canceled.Type: GrantFiled: July 19, 2012Date of Patent: June 27, 2017Assignee: AIZAWA CONCRETE CORPORATIONInventors: Seiji Nakamura, Toru Sakai, Ryo Aoki
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Patent number: 9657214Abstract: A drilling fluid system using retarded acid systems such as gelled acid (VES or polymer) and/or emulsified acid to drill carbonate formations (calcite and dolomite). Foamed acid may be used in low abnormal pressure carbonate reservoirs. The drilling fluid system permits drilling a target hydrocarbon-producing formation with zero-invasion of the drilling fluid system. A method for using the drilling fluid system for fluid loss control during drilling operations.Type: GrantFiled: July 22, 2014Date of Patent: May 23, 2017Assignee: King Fahd University of Petroleum and MineralsInventors: Badr Salem Ba geri, Mohamed Ahmed Mahmoud
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Patent number: 9657213Abstract: The invention relates to a curable sealant composition broadly comprising a resealable, swellable, reactive sealant and free radical initiator; said resealable, swellable reactive sealant comprises monofunctional monomer(s), multifunctional monomer(s), reactive polymer such as unsaturated styrenic block copolymer, swellable additive, and optional components. The monofunctional monomer is a vinyl ester derivative of versatic acid with C9-C12 carbon atoms, or monoacrylate, monomethacrylate, monoacrylamide, or monomethacrylamide. The multifunctional monomer are di-, tri-, tetra-, and/or penta-functional monomers with vinyl, acrylate, methacrylate, acrylamide, or methacrylamide functionality, such as tricyclodecane dimethanol diacrylate, trimethylolpropane trimethacrylate, 1,3-butylene glycol dimethacrylate or a mixture thereof. The reactive unsaturated polymer is a styrenic block copolymer such as SBS, SIS, S-I/B-S, I-SEBS-I, and mixtures of two or more of these.Type: GrantFiled: October 20, 2014Date of Patent: May 23, 2017Assignee: Kraton Polymers U.S. LLCInventors: Erin B. Murphy, Duc V. Nguyen, Robert C. Bening
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Patent number: 9644134Abstract: A method for recovering oil from a subterranean, hydrocarbon-bearing formation includes at least one injection well and injecting a carrier fluid including a diverting agent into a high permeability pathway within the formation. An activating fluid is injected into the high permeability pathway within the formation, resulting in the precipitation or swelling of the diverting agent. The permeability of the high permeability pathway is decreased within the formation containing the diverting agent to a permeability less than the permeability of the adjacent areas of the formation. A mineralization fluid may be injected that is oversaturated or becomes oversaturated upon interacting with the acid gas that causes mineral precipitation to seal off high-permeability pathways.Type: GrantFiled: January 29, 2014Date of Patent: May 9, 2017Assignee: ExxonMobil Upstream Research CompanyInventors: Gary F. Teletzke, Jasper L. Dickson, Preeti Kamakoti, Stuart R. Keller, William B. Maze, Peter G. Smith, Jr., Yitian Xiao
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Patent number: 9587473Abstract: A method for treating a zone of a subterranean formation penetrated by a wellbore, the method including the steps of: (A) introducing a treatment fluid through the wellbore into the zone of the subterranean formation, wherein the treatment fluid comprises an alkoxysilane having at least two alkoxy groups; (B) shutting in the zone to allow the alkoxysilane to hydrolyze in the formation under the design conditions; and (C) before or after introducing the treatment fluid into the zone, installing a mechanical sand control device in the wellbore of the zone.Type: GrantFiled: April 17, 2013Date of Patent: March 7, 2017Assignee: Halliburton Energy Services, Inc.Inventors: Prajakta Ratnakar Patil, Shoy Chittattukara George, Prasanta Das
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Patent number: 9587460Abstract: Disclosed are systems and methods for deploying a casing patch in a wellbore. One casing patch assembly includes a setting kit arranged at an uphole end, an upper wedge portion operatively coupled to the setting kit and defining an upper ramp portion, a lower wedge portion arranged at a downhole end and defining a lower ramp portion, and a casing patch axially interposing the upper and lower wedge portions and having a proximal end configured to radially expand upon slidably engaging the upper ramp portion and a distal end configured to radially expand upon slidably engaging the lower ramp portion.Type: GrantFiled: May 16, 2013Date of Patent: March 7, 2017Assignee: Halliburton Energy Services, Inc.Inventor: Jack Gammill Clemens
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Patent number: 9562425Abstract: Methods of treating subterranean formations comprising providing a wellbore in a subterranean formation having at least one fracture therein; providing a first treatment fluid comprising a base fluid and an acid generating inert agent; providing a second treatment fluid comprising a base fluid, and an acid generating activator; introducing the first treatment fluid into the at least one fracture; and introducing the second treatment fluid into the at least one fracture, wherein the acid generating inert agent in the first treatment fluid reacts with the acid generating activator in the second treatment fluid so as to generate an acid in the at least one fracture and create or enhance at least one microfracture therein.Type: GrantFiled: December 18, 2012Date of Patent: February 7, 2017Assignee: Halliburton Energy Services, Inc.Inventors: Philip D. Nguyen, Feng Liang, Thomas D. Welton, Christopher Parton
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Patent number: 9540561Abstract: Methods of propping subterranean fractures using swellable particulates. Some methods alternate the placement into a fracture of proppant and swellable particulates. Other methods alternate the placement into a fracture of proppant-free fluid and swellable particulates. Still other methods combine proppant and swellable particulates into a single fluid and place that fluid into a subterranean fracture. The methods are useful for treatment of low closure stress formations.Type: GrantFiled: August 29, 2012Date of Patent: January 10, 2017Assignee: Halliburton Energy Services, Inc.Inventor: Philip D. Nguyen
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Patent number: 9513119Abstract: A tiltmeter-integrated two element optical relative alignment monitor provides relative alignment and contact sensing and can provide precise information regarding the nature of physical contact experienced by objects being monitored. A computer monitor can display the information in real time, in an intuitive manner. This system can provide all the information with good resolution in a low-cost, easily installable package for a wide variety of research, high energy physics applications, and industrial uses. A projector unit is mounted on one component containing a diffuse light source, a coded mask, and a lens. The projector is aligned with a camera to receive the focused image. Shifts in the image of the mask indicate relative motion between the camera and the projector unit. A tiltmeter is affixed to either the camera or projector, to distinguish between image shifts due to translational movement and image shifts due to rotation or tilting.Type: GrantFiled: October 21, 2013Date of Patent: December 6, 2016Assignee: The United States of America, as represented by the Secretary of the NavyInventor: David J. Goldstein
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Patent number: 9487692Abstract: Methods of treating a wellbore in a subterranean formation including providing a treatment fluid comprising a consolidating agent, wherein the consolidating agent comprises the reaction product of a furfuryl alcohol or a furfuryl alcohol derivative and a silicon derivative compound selected from the group consisting of a siloxane; a silane; a silanol; a silsesquioxane; any derivative thereof; and any combination thereof; introducing the treatment fluid into the wellbore in the subterranean formation; contacting the consolidating agent with a surface of the wellbore in the subterranean formation; and setting the consolidating agent.Type: GrantFiled: March 19, 2013Date of Patent: November 8, 2016Assignee: Halliburton Energy Services, Inc.Inventors: Philip D. Nguyen, Thomas D. Welton
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Patent number: 9475974Abstract: This invention relates to compositions and methods of treating a surface in contact with a wellbore and/or a subterranean formation penetrated by a well bore, comprising forming a treatment composition comprising a rheological polymer, a partitioning agent, and a liquid medium; and injecting the treatment fluid into the well bore, wherein the treatment composition forms a heterogeneous mixture comprising a dispersed rheological polymer-rich phase and a partitioning agent-rich phase, and wherein the stability of the heterogeneous mixture is controlled by introducing a stability control agent. This invention relates to compositions and methods for forming a water in water emulsion, comprising a rheological polymer, a partitioning agent, a liquid medium; and a stability control agent, wherein the emulsion is a heterogeneous mixture comprising a dispersed rheological polymer-rich phase and a partitioning agent-rich phase.Type: GrantFiled: August 26, 2010Date of Patent: October 25, 2016Assignee: SCHLUMBERGER TECHNOLOGY CORPORATIONInventor: Philip F. Sullivan
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Patent number: 9388670Abstract: A containment system for recovering hydrocarbon fluid from a leaking device comprises a dome situated above the leaking device and forming a cavity for accumulating hydrocarbon fluid from the leaking device, and an injection system that inputs an injection fluid into the cavity. The injection system comprises a plurality of first injectors near the domes inner surface.Type: GrantFiled: July 19, 2013Date of Patent: July 12, 2016Assignee: Total SAInventors: Van-Khoi Vu, Jean-Claude Bourguignon
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Patent number: 9376608Abstract: According to an embodiment, an invert emulsion drilling fluid comprises: an external phase, wherein the external phase of the drilling fluid comprises a hydrocarbon liquid; an internal phase, wherein the internal phase of the drilling fluid comprises a hygroscopic liquid; and a suspending agent, wherein the suspending agent is a polymer comprising urea linkages or urea and urethane linkages. According to certain embodiments, the hygroscopic liquid comprises a salt and a suitable solvent. According to other embodiments, the hygroscopic liquid comprises an alcohol. In certain embodiments, the drilling fluid does not contain an organophilic clay or organophilic lignite. According to another embodiment, a method of using the invert emulsion drilling fluid comprises: introducing the drilling fluid into at least a portion of a subterranean formation.Type: GrantFiled: July 20, 2011Date of Patent: June 28, 2016Assignee: Halliburton Energy Services, Inc.Inventors: Vikrant Wagle, Shadaab Maghrabi
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Patent number: 9371478Abstract: Described are methods and compositions for plugging in a subterranean formation. An example comprises providing a composition comprising a cementitious material, water, and a swellable glass additive, wherein the swellable glass additive comprises a plurality of interconnected organosilica nanoparticles; and introducing the composition into a subterranean formation.Type: GrantFiled: July 29, 2015Date of Patent: June 21, 2016Assignee: Halliburton Energy Services, Inc.Inventors: Jiten Chatterji, Craig Wayne Roddy, Darrell Chad Brenneis, Gregory Robert Hundt
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Patent number: 9321953Abstract: A hydraulic cementing composition and a method of making the same is disclosed. The composition is useful to form a sheath of hardened cement in the annular space between a well pipe disposed in a well bore and the walls of the well bore. The cementing composition is a mixture of dry ingredients comprising hydraulic cement and an additive to control the loss of fluid from an aqueous slurry containing the cementing composition. The fluid loss additive and a method of making the same is disclosed. The fluid loss additive is the reaction product of three chemical compounds each having an ethylene backbone and functional groups selected from carboxylates, hydrogen, anhydrides and combinations thereof.Type: GrantFiled: November 22, 2013Date of Patent: April 26, 2016Assignee: FRITZ INDUSTRIES, INC.Inventors: James C. Ferrell, Jr., Kurt O. Lindstrom, Luis M. Perales, Hongfeng Ren
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Patent number: 9284478Abstract: According to one embodiment, a treatment fluid for a well includes: (a) a water-soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non-acidic ethylenically unsaturated polar monomer; (b) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (c) a salt of a weak Bronsted base and a Bronsted acid; and (d) water; wherein the treatment fluid is a crosslinkable polymer composition.Type: GrantFiled: March 3, 2010Date of Patent: March 15, 2016Assignee: Halliburton Energy Services, Inc.Inventors: B. Raghava Reddy, Larry S. Eoff, Julio Estuardo Vasquez, Eldon Dwyann Dalrymple
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Patent number: 9222014Abstract: Method of treating a subterranean formation comprising providing a consolidation fluid, introducing the resin consolidation fluid into a subterranean formation comprising unconsolidated particulates; and, curing the resin to at least partially consolidate the unconsolidated particulates. The consolidation fluid comprises a resin in emulsified form with an aqueous external phase and an organic internal phase wherein the emulsified resin does not comprise a hardening agent and an aqueous base fluid that further comprises a hardening agent. The consolidation fluid may further comprise an emulsifying agent.Type: GrantFiled: April 27, 2012Date of Patent: December 29, 2015Assignee: Halliburton Energy Services, Inc.Inventors: Richard D. Rickman, Ronald G. Dusterhoft, Philip D. Nguyen, Thomas D. Welton, Jimmie D. Weaver, Mike W. Sanders, Harvey J. Fitzpatrick
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Patent number: 9206345Abstract: A method of servicing a wellbore in a subterranean formation comprising tethering a relative permeability modifier to one or more surfaces of the formation via a coupling agent. A method of servicing a wellbore in a subterranean formation comprising introducing into the wellbore a first wellbore servicing fluid comprising a coupling agent; allowing the coupling agent to associate with the surface of the formation; introducing into the wellbore a second wellbore servicing fluid comprising a relative permeability modifier; and allowing the relative permeability modifier to associate with the coupling agent. A method of servicing a wellbore in a subterranean formation comprising placing into the formation a wellbore servicing fluid comprising a coupling agent and a relative permeability modifier; and allowing the relative permeability modifier to associate with the formation.Type: GrantFiled: February 12, 2013Date of Patent: December 8, 2015Assignee: Halliburton Energy Services, Inc.Inventors: Jimmie D. Weaver, Philip D. Nguyen
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Patent number: 9133386Abstract: A method of treating a well the method including the steps of: (A) forming a fluid including: (i) a shear-thinning aqueous liquid phase; and (ii) an inorganic setting material; wherein the fluid is shear-thinning, pumpable, and settable; and (B) introducing the fluid into the well.Type: GrantFiled: December 12, 2012Date of Patent: September 15, 2015Assignee: Hallburton Energy Services, Inc.Inventors: Arunesh Kumar, Sharath Savari, Jason T. Scorsone, Rajendra A. Kalgaonkar
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Patent number: 9127193Abstract: A treatment fluid for a well including: (a) a water-soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non-acidic ethylenically unsaturated polar monomer; (b) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (c) a Lewis acid; and (d) water; wherein the treatment fluid is a crosslinkable polymer composition. According to an embodiment, a method for blocking the permeability of a portion of a subterranean formation penetrated by a wellbore is provided, the method including the steps of: (a) selecting the portion of the subterranean formation to be treated; (b) selecting estimated treatment conditions, wherein the estimated treatment conditions comprise temperature over a treatment time; (c) forming the treatment fluid; and (d) injecting the treatment fluid through the wellbore into the portion of the subterranean formation.Type: GrantFiled: October 31, 2012Date of Patent: September 8, 2015Assignee: Halliburton Energy Services, Inc.Inventors: B. Raghava Reddy, Larry S. Eoff, Julio Estuardo Vasquez, Eldon Dwyann Dalrymple
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Patent number: 9097105Abstract: Screen assemblies capable of being disposed in a wellbore for hydrocarbon fluid production are described. The screen assemblies can support tubes for receiving hydrocarbon fluid and reduce or eliminate plugging of the tubes by swellable material. A screen assembly may include a support material between a tube and swellable material located exterior to a base pipe. The tube may include perforations and can receive and direct hydrocarbon fluids from the formation. The swellable material can expand after contact with an activating fluid and can displace the tube toward a surface of the bore. The swellable material can expand more than the support material and the support material can reduce or prevent plugging of the perforations by the swellable material expanding.Type: GrantFiled: October 3, 2012Date of Patent: August 4, 2015Assignee: Halliburton Energy Services, Inc.Inventors: Luke W. Holderman, Alf Kolbjorn Sevre
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Patent number: 9090812Abstract: A downhole sealant includes a composition that includes a polymer; an absorbent material; a primary crosslink network including primary bonds between chains of the polymer; and a secondary crosslink network which is transient. A method of regulating the swell rate of the downhole sealant includes disposing a downhole sealant comprising a polymer and an absorbent material in a borehole; maintaining a primary crosslink network of the polymer; and decomposing a secondary crosslink network of the absorbent material in response to a condition to regulate the swell rate of the downhole sealant.Type: GrantFiled: December 9, 2011Date of Patent: July 28, 2015Assignee: Baker Hughes IncorporatedInventors: David P. Gerrard, James E. Goodson, John C. Welch, Anil K. Sadana
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Publication number: 20150122496Abstract: A method of cementing a well is disclosed. The method comprising pumping into the well a cement slurry comprising a solid blend including cement, water, and a fluid loss control agent, and allowing the cement slurry to set. The fluid loss control agent comprises a styrene-butadiene latex and a high molecular-weight water-soluble polymer such as a copolymer AMPS-Am. The addition of the water-soluble polymer allows drastic reduction of the quantity of latex required to achieve fluid loss control performance and even gas migration control.Type: ApplicationFiled: January 14, 2015Publication date: May 7, 2015Inventors: Michel Michaux, Bruno Drochon, Sylwia Komocki
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Patent number: 9004163Abstract: The equipment for drilling and reinforcing a borehole of a well comprises a drill pipe string carrying a drill tool at its lowermost end and a downhole treatment device held on the drill pipe string for applying a liner of polymer material at the surface of the borehole. The polymer material is a fusible and/or curable material dissolved and/or emulsified and/or dispersed in drilling fluid or mud circulated through the drill pipe string and an annulus between the drill pipe string and the wall of the borehole. The treatment device is adapted to concentrate energy for fusing and/or curing the polymer material contained in the drilling fluid in a limited space at the vicinity of the wall of the borehole. The treatment device thus focuses its energy in the vicinity of the wall and allows a continuous reinforcing of the borehole simultaneously while drilling.Type: GrantFiled: April 3, 2009Date of Patent: April 14, 2015Assignee: Statoil Petroleum ASInventor: Steinar Wasa Tverlid
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Patent number: 8975217Abstract: Methods are provided for treating a portion of a well. The method according to this aspect comprises the steps of: (A) forming a treatment fluid, the treatment fluid comprising: (i) water; (ii) a water-soluble polymer; (iii) a complexed metal cation that: (a) has a valence state of at least three; and (b) is capable of cross-linking the water-soluble polymer; and (iv) an aromatic compound that is capable of dissolving, melting, or chemically decomposing, dissociating, or reacting, to form a chelating agent, wherein the chelating agent comprising vicinal substituents containing donor heteroatoms, and wherein the chelating agent is capable of chelating the metal cation; and (B) introducing the treatment fluid into the well.Type: GrantFiled: June 23, 2009Date of Patent: March 10, 2015Assignee: Halliburton Energy Services, Inc.Inventors: B. Raghava Reddy, Rajesh K. Saini, Sherry G. Gaskins
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Publication number: 20150047843Abstract: A method of inerting pipelines, or buried tanks or wellbores consisting of preparing a composition including at least one superabsorbent (co)polymer partially or fully swollen in the presence of water, then injecting the composition directly into the pipelines or buried tank or well.Type: ApplicationFiled: December 18, 2012Publication date: February 19, 2015Applicant: S.P.C.M. SAInventors: Stéphane Delheur, Pierre Lyot
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Publication number: 20150021028Abstract: A method and a sealing fluid for setting a packer in an annulus between a well bore and a well tubular is provided, which by adjusting i.a. the density, viscosity and setting time of the sealing fluid is able to provide among other things a full radial seal with an acceptable axial dispersion, in particular in highly deviated wells and/or in wells having eccentric annuli.Type: ApplicationFiled: January 17, 2013Publication date: January 22, 2015Inventors: Edo Boekholtz, Hans Van Dongen
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Patent number: 8936087Abstract: Methods including the steps of providing an injection well having unconsolidated particulates in one or more formation intervals along the wellbore that accept injection fluid; providing a consolidating treatment fluid comprising a base fluid and a consolidating agent; introducing the consolidating treatment fluid through the injection well, while the well is under injection, such that the consolidating treatment fluid enters into a portion of a formation interval along the wellbore that accepts injection fluid; and, allowing the consolidating fluid to consolidate formation particulates therein. The methods may be performed such that the percentage of consolidating agent varies over the course of the treatment or the rate of injection varies over the course of the treatment.Type: GrantFiled: October 27, 2011Date of Patent: January 20, 2015Assignee: Halliburton Energy Services, Inc.Inventors: Philip D. Nguyen, Richard D. Rickman, Ronald G. Dusterhoft, Jimmie D. Weaver, Dave Tiffin, Gary Hurst
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Patent number: 8936084Abstract: Methods of making a degradable ball composition comprising a carboxylic acid, a fatty alcohol, a fatty acid salt, a fatty ester, or a combination thereof comprising the steps of: forming a thermoplastic mass, and allowing the thermoplastic mass to cool as to form a degradable ball that is introduced in subterranean treatments by a carrier fluid.Type: GrantFiled: April 27, 2012Date of Patent: January 20, 2015Assignee: Halliburton Energy Services, Inc.Inventors: Hongyu Luo, Dwight D. Fulton
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Publication number: 20140374099Abstract: A treatment fluid and method for simultaneously swelling an oil-swellable elastomer and breaking a filtercake in a well. The treatment fluid includes an emulsion comprising: (i) a continuous oil phase, wherein the oil phase comprises: (a) an oil; and (b) an emulsifier; and (ii) an internal aqueous phase, wherein the aqueous phase comprises: (a) water; and (b) a water-soluble hydrolyzable ester of a carboxylic acid; wherein the emulsion is stable to hydrolysis of the water-soluble hydrolyzable ester of the carboxylic acid. A method of treating a well includes the steps of: (A) forming the treatment fluid; and (B) introducing the treatment fluid into the portion of the wellbore, wherein: (i) a filtercake has been previously formed in the portion of the wellbore, wherein the filtercake comprises an acid-soluble or an acid-degradable material; and (ii) an oil-swellable elastomer has been previously deposited or positioned in the portion of the wellbore.Type: ApplicationFiled: June 22, 2013Publication date: December 25, 2014Inventors: Vikrant Bhavanishankar Wagle, Kushabhau Dagadu Teke, Dhanashree Gajanan Kulkarni
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Publication number: 20140367105Abstract: Filler particles having an average diameter of about 3 nm to about 20 microns may have enhanced suspendability and be useful in hardenable resin compositions and methods relating thereto. In some instances, a method may include providing a hardenable resin composition that comprises a liquid hardenable resin, a hardening agent, and a plurality of filler particles having an average diameter of about 3 nm to about 20 microns; introducing the hardenable resin composition into a wellbore penetrating a subterranean formation; and allowing the hardenable resin composition to harden to form a resin-based sealant composition in at least a portion of the wellbore, in at least a portion of the subterranean formation, or both.Type: ApplicationFiled: June 14, 2013Publication date: December 18, 2014Inventors: Jeffery Dwane Karcher, Paul Joseph Jones, Misty Dawn Rowe, Greg Robert Hundt
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Patent number: 8910712Abstract: Clathrate reservoirs of Class II are modified in order to improve the ability to produce hydrocarbons from them. Specifically a method for improving producibility of subsurface clathrate formation underlain by a mobile aquifer includes drilling a borehole to a depth providing access to the mobile aquifer and injecting a material into the mobile aquifer such that the material passes through pore spaces and forms a barrier underlying the clathrate formation and substantially impeding fluid flow from the mobile aquifer into contact with the clathrate formation.Type: GrantFiled: October 31, 2011Date of Patent: December 16, 2014Assignee: Chevron U.S.A. Inc.Inventor: John T. Balczewski
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Patent number: 8899328Abstract: Epoxy-based zonal isolation compositions are capable of being adjusted by varying the epoxy-based compositions for isolating zones in borehole of oil and gas wells under high-temperature, mid-temperature and low-temperature conditions.Type: GrantFiled: May 20, 2010Date of Patent: December 2, 2014Assignee: Clearwater International LLCInventors: Frank Zamora, Sarkis R. Kakadjian, Tina Garza
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Patent number: 8893790Abstract: Biomimetic adhesive compositions can be used in various aspects of subterranean treatment operations. Methods for treating a subterranean formation can comprise: providing an adhesive composition that comprises a first polymer comprising a plurality of monomers that comprise a phenolic moiety, a biopolymer that is crosslinkable with the first polymer, a crosslinking agent, and an oxidizing agent; introducing the adhesive composition into a subterranean formation; and forming a coacervate-bound surface in the subterranean formation by crosslinking the first polymer.Type: GrantFiled: May 23, 2012Date of Patent: November 25, 2014Assignee: Halliburton Energy Services, Inc.Inventors: Enrique A. Reyes, Pinmanee Boontheung, Narongsak Tonmukayakul
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Publication number: 20140311743Abstract: Methods of treating a wellbore in a subterranean formation including providing an aqueous treatment fluid comprising a liquid resin agent, wherein the liquid resin agent comprises the reaction product of a multifunctional electrophilic compound and at least one nucleophilic compound selected from the group consisting of a dimer acid; a dimer amine; any derivative thereof; and any combination thereof, and wherein the multifunctional electrophilic compound comprises least two electrophilic reactive groups; introducing the aqueous treatment fluid into the wellbore in the subterranean formation; and, curing the liquid resin agent.Type: ApplicationFiled: April 22, 2013Publication date: October 23, 2014Inventors: Loan Vo, Feng Liang, Philip D. Nguyen, Tingji Tang
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Patent number: 8851174Abstract: Foamable epoxy-based zonal isolation sealing compositions include epoxy resin and a blowing agent and methods for isolating zones in borehole of oil and gas wells using the compositions, where the foam nature of the cured seals provide sufficient compressibility and resiliency to be used with expandable tubing without substantial loss in sealant integrity and in squeeze operations.Type: GrantFiled: March 22, 2011Date of Patent: October 7, 2014Assignee: Clearwater International LLCInventors: Frank Zamora, Sarkis R. Kakadjian, Tina Garza
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Patent number: 8844628Abstract: A self-adaptive cement formulation includes cement, water and asphaltite-mineral particles. The set cement demonstrates self-healing properties when exposed to methane, and is particularly suited for well-cementing applications. After placement and curing, the self-healing properties help maintain zonal isolation should bonding be disrupted between the set cement and the formation or a casing string, should cracks or defects appear in the set-cement matrix, or both.Type: GrantFiled: January 24, 2012Date of Patent: September 30, 2014Assignee: Schlumberger Technology CorporationInventors: Sylvaine Le Roy-Delage, Laure Martin
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Publication number: 20140284054Abstract: Methods of treating a wellbore in a subterranean formation including providing a treatment fluid comprising a consolidating agent, wherein the consolidating agent comprises the reaction product of a furfuryl alcohol or a furfuryl alcohol derivative and a silicon derivative compound selected from the group consisting of a siloxane; a silane; a silanol; a silsesquioxane; any derivative thereof; and any combination thereof; introducing the treatment fluid into the wellbore in the subterranean formation; contacting the consolidating agent with a surface of the wellbore in the subterranean formation; and setting the consolidating agent.Type: ApplicationFiled: March 19, 2013Publication date: September 25, 2014Applicant: Halliburton Energy Services, Inc.Inventors: Philip D. Nguyen, Thomas D. Welton
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Patent number: 8839862Abstract: A method of stabilizing a blasthole prior to detonation which comprises the step of coating the inner wall of the blasthole with a stabilizing composition. In one embodiment, the invention comprises coating the blast hole with a movable spraying application. The invention further relates to the use of a silicate-containing resin but is also suitable for use with a thermoset resin system. The method can be used to apply the stabilizing composition to both dry and wet blastholes.Type: GrantFiled: September 24, 2009Date of Patent: September 23, 2014Assignee: Minova International LimitedInventor: Robert Hawker
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Patent number: 8839859Abstract: A method for removing water from a wellbore fluid may include the steps of contacting a wellbore fluid with a water absorbing polymer, where the wellbore fluid includes an aqueous fluid, allowing the water absorbing polymer to interact with the wellbore fluid for a sufficient period of time so that the water absorbing polymer absorbs at least a portion of water in the aqueous fluid, and separating the water absorbing polymer containing the absorbed water from the wellbore fluid.Type: GrantFiled: January 9, 2007Date of Patent: September 23, 2014Assignee: M-I L.L.C.Inventors: Catalin Ivan, Karen McCosh
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Patent number: 8815785Abstract: Methods for creating a fluid diverting barrier in a zone of a subterranean formation are provided. Certain methods comprise providing a treatment fluid that comprises an aqueous base fluid, a viscoelastic surfactant, and a soap component; placing the treatment fluid in a subterranean formation penetrated by a well bore; and allowing the soap component of the treatment fluid to interact with a metal ion present in the subterranean formation to form a precipitate.Type: GrantFiled: January 28, 2009Date of Patent: August 26, 2014Assignee: Halliburton Energy Services, Inc.Inventors: Thomas D. Welton, Bobby J. Burns
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Patent number: 8813842Abstract: A plurality of solid particles including a thermoplastic composition having a softening temperature in a range from 50° C. to 180° C. and a blocked isocyanate resin; optionally at least some of the particles in the plurality of solid particles comprise both the thermoplastic composition and the blocked isocyanate resin. A composition comprising the plurality of particles dispersed in a fluid is also disclosed. A method of modifying a wellbore within a geological formation is also disclosed. The method includes introducing the fluid composition into the wellbore. A method of making a plurality of particles, for example, to use in the fluid composition, is also disclosed.Type: GrantFiled: December 21, 2009Date of Patent: August 26, 2014Assignee: 3M Innovative Properties CompanyInventors: Michael D. Crandall, Ignatius A. Kadoma, Clara E. Mata, Yong K. Wu