With Feeding And/or Withdrawal Means Patents (Class 204/263)
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Patent number: 11584666Abstract: An apparatus for manufacturing hydrogen-containing water is disclosed. In one aspect, the apparatus includes a container part formed with a upper space and a lower space positioned vertically from each other around a connecting passage therein. The apparatus also includes an ion exchange membrane configured to close the connecting passage and an electrolytic part comprising a cathode disposed on the upper space and a cathode an anode disposed on the lower space. The apparatus further includes a handle part configured to couple to the container part and to provide a supply passage for water to be supplied to the lower space and a discharge passage to discharge oxygen and ozone generated from the lower space.Type: GrantFiled: May 16, 2017Date of Patent: February 21, 2023Assignee: Welltech Korea Co., Ltd.Inventors: Seung Yeol Park, Nam Suck Lee, Pil Jong Kim
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Patent number: 11585005Abstract: A semiconductor apparatus and methods of processing a semiconductor workpiece are provided. The semiconductor apparatus for pre-wetting a semiconductor workpiece includes a process chamber, a workpiece holder disposed within the process chamber to hold the semiconductor workpiece, a pre-wetting fluid tank disposed outside the process chamber and containing a pre-wetting fluid, and a conduit coupled to the pre-wetting fluid tank and extending into the process chamber. The conduit delivers the pre-wetting fluid from the pre-wetting fluid tank out through an outlet of the conduit to wet a major surface of the semiconductor workpiece comprising a plurality of recess portions.Type: GrantFiled: January 13, 2021Date of Patent: February 21, 2023Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.Inventors: Chen-Yu Tsai, Ku-Feng Yang, Wen-Chih Chiou
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Patent number: 11545672Abstract: An electrical energy generating device includes an electrical energy generating element, a first container, a second container, and a liquid having positive and negative ions. The electrical energy generating element includes a first porous electrode, an eggshell membrane, and a second porous electrode stacked on each other in that order. The first container is located on a side of the first porous electrode away from the eggshell membrane. The second container is located on a side of the second porous electrode away from the eggshell membrane. The liquid is located in at least one of the first container and the second container, and the liquid is configured to penetrate from one of the first container and the second container to another through the electrical energy generating element.Type: GrantFiled: June 28, 2019Date of Patent: January 3, 2023Assignees: Tsinghua University, HON HAI PRECISION INDUSTRY CO., LTD.Inventors: Dan Gao, Chang-Hong Liu, Shou-Shan Fan
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Patent number: 11535535Abstract: An apparatus for manufacturing hydrogen containing water is disclosed. An aspect of the present disclosure may provide an apparatus for manufacturing hydrogen containing water, comprising: housing having first receiving space formed therein; cylinder coupled to the housing to form second receiving space; connecting passage penetrating the housing to interconnect the first receiving space and the second receiving space; ion exchange membrane closing the connecting passage; electrolysis part comprising an anode and a cathode, the anode being disposed in the first receiving space and the cathode being disposed in the second receiving space; exhaust pipe penetrating the housing to interconnect the first receiving space and an external space; and first waterproof membrane closing the exhaust pipe and inhibiting water from being discharged while allowing gas to be discharged.Type: GrantFiled: March 22, 2019Date of Patent: December 27, 2022Inventors: Guan Duk Lim, Ye Dam Kim
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Patent number: 11519082Abstract: An organic hydride production apparatus includes: an electrolyte membrane having proton conductivity; a cathode that includes a cathode catalyst layer used to hydrogenate a hydrogenation target substance using protons to produce an organic hydride and also includes a cathode chamber; an anode that includes an anode catalyst layer used to oxidize water to produce protons and also includes an anode chamber; and a gas introduction unit that introduces, into the anolyte at a certain position, a certain gas used to remove at least one of the hydrogenation target substance and the organic hydride that have passed through the electrolyte membrane and been mixed into the anolyte.Type: GrantFiled: May 15, 2019Date of Patent: December 6, 2022Assignees: NATIONAL UNIVERSITY CORPORATION YOKOHAMA NATIONAL UNIVERSITY, DE NORA PERMELEC LTD.Inventors: Shigenori Mitsushima, Kensaku Nagasawa, Yoshinori Nishiki, Akihiro Kato, Setsuro Ogata, Awaludin Zaenal, Akiyoshi Manabe, Koji Matsuoka, Yasushi Sato
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Patent number: 11431012Abstract: Provided herein are electrochemical cell and/or electrolyzer configurations with membrane-electrode gap and optionally one or more spacers; and methods to use and manufacture the same.Type: GrantFiled: December 23, 2021Date of Patent: August 30, 2022Assignee: Verdagy, Inc.Inventors: Ryan J Gilliam, Thomas H McWaid
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Patent number: 11214879Abstract: An electrochemical apparatus for the production of a disinfectant from sodium chloride solution.Type: GrantFiled: May 8, 2017Date of Patent: January 4, 2022Assignee: H2ENVIRO LLCInventors: Joseph A. Edgar, Andrew Krefta
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Patent number: 11208728Abstract: The invention relates to an electrochemical cell partitioned by a cation-exchange membrane suitable for production of high purity hydrogen and oxygen by electrolysis of alkaline solutions comprising a cathode in form of porous web including a platinum or palladium catalyst. The cell can be used as an element of a modular filter-press electrolyzer.Type: GrantFiled: July 15, 2014Date of Patent: December 28, 2021Assignee: INDUSTRIE DE NORA S.P.AInventor: Julia Lynne Krasovic
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Patent number: 11199493Abstract: A functional water concentration sensor includes: a light source which emits ultraviolet light; a container capable of holding functional water having a pH between 6 and 9, inclusive, and containing hypochlorous acid and hypochlorite dissociated from the hypochlorous acid; a light-receiving element; and a signal processor. The signal processor calculates the concentration of the hypochlorite in the functional water on the basis of the output signal, calculates the percentages of the hypochlorous acid and the hypochlorite in the functional water on the basis of the pH of the functional water and the dissociation constant of the hypochlorous acid, and calculates the concentration of the hypochlorous acid in the functional water on the basis of the calculated hypochlorite concentration and the calculated percentages.Type: GrantFiled: July 20, 2018Date of Patent: December 14, 2021Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.Inventors: Yoshifumi Watabe, Ryo Arakawa, Toru Baba
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Patent number: 11174564Abstract: An electroforming system and method for electroforming a component includes an electroforming reservoir with a housing with at least one inlet and at least one outlet, and at least one anode chamber within the housing and fluidly coupled to the at least one inlet. An anode can be located within the at least one anode chamber.Type: GrantFiled: October 31, 2018Date of Patent: November 16, 2021Assignee: Unison Industries, LLCInventors: Dattu GV Jonnalagadda, Karthick Vilapakkam Gourishankar, Merin Sebastian, Sandeep Kumar, Gordon Tajiri
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Patent number: 11162178Abstract: An electrode of an electrolysis cell for gas-producing electrochemical processes, which includes a plurality of horizontal lamella elements which in the manner of a flat C-profile consist of a flat central part and one or more flank parts, where one or more transition regions of any shape are arranged between the flat central part and the one or more flank parts, where the lamella elements have a plurality of through-openings, where the lamella elements have a flat surface without structural raised regions and depressions and the flat central part has a plurality of through-openings which are arranged in rows and arranged diagonally to one another.Type: GrantFiled: November 28, 2012Date of Patent: November 2, 2021Assignee: UHDENORA S.P.A.Inventors: Karl-Heinz Dulle, Frank Funck, Dirk Hoormann, Stefan Oelmann, Peter Woltering, Carsten Schmitt, Philipp Hofmann
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Patent number: 11111589Abstract: An electrolytic cell for carbon dioxide of an embodiment includes: an anode part including an anode to oxidize water or a hydroxide ion and thus produce oxygen and an anode solution flow path to supply an anode solution to the anode; a cathode part including a cathode to reduce carbon dioxide and thus produce a carbon compound, a cathode solution flow path to supply a cathode solution to the cathode, a gas flow path to supply the carbon dioxide to the cathode, and a hydrophobic porous body disposed between the cathode and the gas flow path; and a separator to separate the anode part and the cathode part from each other.Type: GrantFiled: September 4, 2019Date of Patent: September 7, 2021Assignee: KABUSHIKI KAISHA TOSHIBAInventors: Yuki Kudo, Akihiko Ono, Masakazu Yamagiwa, Ryota Kitagawa, Jun Tamura, Yoshitsune Sugano, Takayuki Tsukagoshi, Asahi Motoshige, Satoshi Mikoshiba
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Patent number: 10968526Abstract: The invention relates to an electrolysis cell of alkali solutions partitioned by an ion-exchange membrane into an anodic compartment in which an alkaline electrolyte is circulated and a cathodic compartment consisting of a gas chamber; the cathodic compartment contains a gas-diffusion cathode in whose interior an electrolyte film coming from the anodic compartment percolates.Type: GrantFiled: October 15, 2013Date of Patent: April 6, 2021Assignee: INDUSTRIE DE NORA S.P.A.Inventors: Luciano Iacopetti, Antonio Lorenzo Antozzi
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Patent number: 10875799Abstract: Systems and methods for generating reactive oxygen species formulations useful in various oxidation applications. Exemplary formulations include singlet oxygen or superoxide and can also contain hydroxyl radicals or hydroperoxy radicals, among others. Formulations can contain other reactive species, including other radicals. Exemplary formulations containing peracids are activated to generate singlet oxygen. Exemplary formulations include those containing a mixture of superoxide and hydrogen peroxide. Exemplary formulations include those in which one or more components of the formulation are generated electrochemically. Formulations of the invention containing reactive oxygen species can be further activated to generate reactive oxygen species using activation chosen from a Fenton or Fenton-like catalyst, ultrasound, ultraviolet radiation or thermal activation.Type: GrantFiled: November 12, 2019Date of Patent: December 29, 2020Assignee: Clean Chemistry, Inc.Inventor: Wayne Buschmann
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Patent number: 10879539Abstract: A metal oxide compound of formula (I): MnxMyRu1-(x+y)O2??(I) is a single phase rutile-type structure, where M is Co, Ni, or Fe, or a combination thereof, x>0, y?0, and 0.02?(x+y)?0.30. Related electro-catalysts, devices, and processes are also provided.Type: GrantFiled: June 7, 2017Date of Patent: December 29, 2020Assignee: CORNELL UNIVERSITYInventors: Marc Murphy, Ryo H. Wakabayashi, R. Bruce Van Dover, Héctor D. Abruña, Francis J. Disalvo
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Patent number: 10822708Abstract: A differential pressure type high pressure water electrolysis apparatus has a flow passage forming member for supplying water to an anode. In the flow passage forming member, there are formed a water receiving section for receiving water supplied from the exterior, a distributing path for distributing the water that has flowed into the water receiving section, a converging path into which a surplus supplied amount of water flows, and a water discharging section for receiving the water inside the converging path and discharging it to the exterior. The positions of the distributing path and the converging path are offset from an opposing position where a seal member faces toward a pressure resistant member that surrounds the seal member from the exterior.Type: GrantFiled: January 15, 2019Date of Patent: November 3, 2020Assignee: Honda Motor Co., Ltd.Inventors: Kazuhiro Yamamoto, Mikiya Kobayashi
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Patent number: 10640878Abstract: An electrolytic ozone generator for use with a faucet and methods for assembling and using the same.Type: GrantFiled: October 27, 2016Date of Patent: May 5, 2020Assignee: Delta Faucet CompanyInventors: Patrick B. Jonte, Michael Scot Rosko, Todd Andrew Huffington, Kurt Judson Thomas, Derek Allen Brown
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Patent number: 10626026Abstract: A multifunctional membraneless boiled water electrolysis machine comprises a container (21) for containing raw water, and a water electrolysis apparatus. The water electrolysis apparatus is mounted outside the container (21) for containing raw water and comprises an electrolysis power supply (9), an electrolysis water tank (10) and an electrolysis electrode assembly (18) located in the electrolysis water tank. A water outlet at a bottom of the container for containing the raw water is connected with a water pump (24) through a pipeline. The water pump (24) is connected with a water inlet (15) of the electrolysis water tank (10) through the pipeline. The raw water in the container can flow into the electrolysis electrode assembly (18) from the water inlet (15) of the electrolysis water tank (10) after being heated or boiled by a heater (16). The water is electrolyzed through the gaps between the electrodes of different polarities in the electrolysis electrode assembly (18).Type: GrantFiled: August 25, 2017Date of Patent: April 21, 2020Inventors: Minxiong Luo, Ming Li
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Patent number: 10590545Abstract: An electrochemical cell has a membrane located between two flow field plates. On a first side of the membrane, there is a porous support surrounded by a seal between the membrane and the flow field plate. There is a gap between the porous support and the seal at the surface of the membrane. On a second side of the membrane, there is a seal between the membrane and the flow field plate located inside of the gap in plan view. The electrochemical cell is useful, for example, in high pressure or differential pressure electrolysis in which the second side of the membrane will be consistently exposed to a higher pressure than the first side of the membrane.Type: GrantFiled: September 26, 2016Date of Patent: March 17, 2020Assignee: HYDROGENICS CORPORATIONInventors: Rami Michel Abouatallah, Rainey Yu Wang, Nathaniel Ian Joos
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Patent number: 10501346Abstract: Systems and methods for generating reactive oxygen species formulations useful in various oxidation applications. Exemplary formulations include singlet oxygen or superoxide and can also contain hydroxyl radicals or hydroperoxy radicals, among others. Formulations can contain other reactive species, including other radicals. Exemplary formulations containing peracids are activated to generate singlet oxygen. Exemplary formulations include those containing a mixture of superoxide and hydrogen peroxide. Exemplary formulations include those in which one or more components of the formulation are generated electrochemically. Formulations of the invention containing reactive oxygen species can be further activated to generate reactive oxygen species using activation chosen from a Fenton or Fenton-like catalyst, ultrasound, ultraviolet radiation or thermal activation.Type: GrantFiled: November 4, 2016Date of Patent: December 10, 2019Assignee: Clean Chemistry, Inc.Inventor: Wayne Buschmann
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Patent number: 10450661Abstract: A method for using an electrochemical cell to continuously acidify alkaline water sources and recover carbon dioxide with simultaneous continuous hydrogen gas production. The electrochemical cell has a center compartment, an electrolyte-free anode compartment having a mesh anode in direct contact with an ion permeable membrane, an endblock in direct contact with the anode where the endblock provides a gas escape route behind the anode, an electrolyte-free cathode compartment having a mesh cathode in direct contact with an ion permeable membrane, and an endblock in direct contact with the cathode where the endblock provides a gas escape route behind the cathode. Current applied to the electrochemical cell for generating hydrogen gas also lowers the pH of the alkaline water to produce carbon dioxide with no additional current or power.Type: GrantFiled: June 6, 2017Date of Patent: October 22, 2019Assignee: The Government of the United States of America, as represented by the Secretary of the NavyInventors: Felice DiMascio, Heather D. Willauer, Dennis R. Hardy, Frederick Williams, M. Kathleen Lewis
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Patent number: 10443136Abstract: An electrochemical reaction device comprises: an electrolytic solution tank including a first region, a second region, and a path; a reduction electrode disposed in the first region; an oxidation electrode disposed in the second region; and a power source connected to the reduction electrode and oxidation electrode; and a plurality of ion exchange membranes separating the first region and the second region.Type: GrantFiled: January 23, 2017Date of Patent: October 15, 2019Assignee: KABUSHIKI KAISHA TOSHIBAInventors: Akihiko Ono, Satoshi Mikoshiba, Jun Tamura, Norihiro Yoshinaga, Yoshitsune Sugano
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Patent number: 10407782Abstract: This invention includes an electrolysis chamber and method for producing controlled flow acid electrolyzed water and controlled flow alkaline electrolyzed water with independent flows from aqueous solutions. Its objective is to produce controlled flow acid water with an oxide reduction potential (ORP) between +1100 and +1200 mV and a pH between 1.5 and 2.9 with a stability and shelf life of over a year, and controlled flow alkaline electrolyzed water with a pH between 9.0-11.0 and an ORP between ?700 mV to ?800 mV with a shelf life of more than a year.Type: GrantFiled: June 1, 2017Date of Patent: September 10, 2019Inventor: Juan Manuel Nuñez Montalvo
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Patent number: 10280526Abstract: A system that produces a sterilizing solution, has an electrolytic cell containing an anode compartment and a cathode compartment separated by a porous ion-exchange membrane. The system further has an ion-exchange water softener arranged to supply the electrolytic cell with deionized water and a brine tank arranged to supply the electrolytic cell with a sodium chloride brine solution. The system is arranged for conducting a regeneration of the water softener by use of a sodium chloride brine solution from the brine tank. The system has a positive displacement pump controlled by a control unit of the system to selectively supply a sodium chloride brine solution from the brine tank to the electrolytic cell and to the water softener for regeneration thereof.Type: GrantFiled: June 2, 2016Date of Patent: May 7, 2019Assignee: DANISH CLEAN WATER A/SInventor: Hardy Peter Jepsen
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Patent number: 10241035Abstract: Spectrophotometric sensors for measuring the concentration of various solutions are disclosed. Methods for controlling the introduction of disinfectants using such sensors for water treatment are also disclosed. Hypochlorite strength is monitored in at least some embodiments.Type: GrantFiled: December 9, 2014Date of Patent: March 26, 2019Assignee: Evoqua Water Technologies LLCInventors: David Macdonald Bonnick, Michael Brooks
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Patent number: 10227245Abstract: A system and method for applying an advanced oxidation process to a UV fluid reactor. An L-shaped electrode is connected to a UV reactor hatch and inserted into the reactor upstream from a UV radiation source.Type: GrantFiled: February 2, 2017Date of Patent: March 12, 2019Assignee: Neptune Benson Inc.Inventor: Jonathan Charles McClean
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Patent number: 10207936Abstract: Various ultraviolet (UV) reactors and their methods of fabrication are disclosed. One exemplary process comprises forming a set of parallel channels in a slab of ultraviolet transparent material. The process also comprises providing a reactor substrate with an input manifold and an output manifold. The process also comprises joining the slab of ultraviolet transparent material and the reactor substrate. The input manifold, output manifold, and set of parallel channels are in fluid communication after the joining step. The process also comprises providing a planar ultraviolet light source isolated from the set of parallel channels by the shaped slab of ultraviolet-transparent material. The set of parallel channels and a defining plane of the planar ultraviolet light source are parallel in the assembled ultraviolet reactor.Type: GrantFiled: February 14, 2017Date of Patent: February 19, 2019Assignee: Silanna UV Technologies Pte LtdInventors: Steven Duvall, Norbert Krause, Christopher Flynn, Mark Hiscocks, Matthew Stewart
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Patent number: 10189727Abstract: A fluid purification system has cells whose purifying capability can be regenerated. Some of the cells are arranged in series to reach a high level of purification. An automatic valve network is controlled to cycle the cells in a way that levels the loads on each, thereby maximizing the service interval for replacing expired cells, enabling all of the cells to be replaced at the same time after having each contributing approximately equally to the purification load, and operated such that at any one time, at least one cell is regenerated so as to enable continuous up-time.Type: GrantFiled: June 20, 2016Date of Patent: January 29, 2019Assignee: NxStage Medical, Inc.Inventors: William K Weigel, Goetz Friederichs, Joseph E Turk, Jefferey B Hover, Sr.
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Patent number: 10177388Abstract: Provided are a cathode substrate, a high capacity all-solid-state battery, and a method for manufacturing the same. The cathode substrate includes a base in a mesh form and a cathode formed on the base, wherein the cathode is configured to overlap the base. The present invention may resolve a conventional problem of deterioration in battery efficiency, which has been caused by a long distance between an electrode and a cathode, and may produce a high capacity all-solid-state battery while suppressing or preventing an increase in the thickness of the cathode.Type: GrantFiled: April 16, 2014Date of Patent: January 8, 2019Assignee: GACHON UNIVERSITY OF INDUSTRY—ACADEMIC COOPERATION FOUNDATIONInventors: Young Soo Yoon, Seung Hyun Jee, Seok Hee Lee
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Patent number: 10038201Abstract: An exemplary fuel cell component includes a plate comprising an electrically conductive material. An electrical connector includes a first portion embedded in the plate. A second portion of the electrical connector extends from the plate. The second portion is configured to make an electrically conductive connection with another device.Type: GrantFiled: June 13, 2012Date of Patent: July 31, 2018Assignee: AUDI AGInventors: David Melo Ferreira, Christopher John Carnevale, Glenn Michael Allen
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Patent number: 10006130Abstract: The invention relates to a photoelectrochemical cell 100 for light-driven production of hydrogen and oxygen, especially from water or another electrolyte based on aqueous solution, having a photoelectric layer structure 1 and an electrochemical layer structure 2 in a layer construction 40, where—the photoelectric layer structure 1 for absorption of light 3 uninfluenced by the electrolyte 10 forms a front side 41 of the layer structure 40, and—the electrochemical layer structure 2, for accommodation of the electrolyte 10, forms a reverse side 42 of the layer construction 40, and—a conductive and corrosion-inhibiting coupling layer 13 forms electrical contact between the photoelectric layer structure 1 and the electrochemical layer structure 2 in the layer construction 40, where—the electrochemical layer structure 2 has an electrode structure of a front electrode 21 and an electrode structure of a rear electrode 22, between which is arranged an ion exchange layer 61 such that an integrated layer construction 40Type: GrantFiled: March 15, 2013Date of Patent: June 26, 2018Assignee: Evonik Degussa GmbHInventors: Sascha Hoch, Matthias Blug, Jens Busse, Wolfram Calvet, Bernhard Kaiser, Wolfram Jaegermann, Hanna Hahn, Horst-Werner Zanthoff
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Patent number: 9915136Abstract: A method of extracting hydrocarbons from a hydrocarbon well includes receiving an aqueous solution including dissolved inorganic carbon, and extracting the dissolved inorganic carbon from the aqueous solution to create CO2 by changing a pH of the aqueous solution. The method also includes pumping the CO2 into the hydrocarbon well and, in response to pumping the CO2 into the hydrocarbon well, extracting the hydrocarbons from the hydrocarbon well.Type: GrantFiled: May 26, 2016Date of Patent: March 13, 2018Assignee: X Development LLCInventors: Matthew D. Eisaman, Kathleen E. Cooper
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Patent number: 9903030Abstract: According to an aspect, a hydrogen-containing water generating electrode includes: a positive electrode that is a tubular conductor and includes a plurality of openings in a side portion; an insulator that is provided on an outer peripheral portion of the positive electrode and is in contact with the positive electrode; and a negative electrode that is provided on an outer peripheral portion of the insulator, is a tubular conductor in contact with the insulator, and includes a plurality of openings in a side portion.Type: GrantFiled: January 31, 2014Date of Patent: February 27, 2018Assignee: THE CHUGOKU ELECTRIC POWER CO., INC.Inventors: Keisou Iwai, Masayuki Shimokatu, Suehiro Sakai
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Patent number: 9863047Abstract: An electrolysis device of an embodiment includes: an anode, a cathode having a nitrogen-containing carbon alloy catalyst, and an electrolysis cell having a membrane electrode assembly composed of an electrolyte present between the anode and the cathode so that voltage is applied to the anode and the cathode, wherein the electrolyte is any one of acidic, neutral, or alkali, water is produced by the electrolysis device at the cathode, when the electrolyte is acidic, and hydroxide ion is produced by the electrolysis device at the anode, when the electrolyte is neutral or alkali.Type: GrantFiled: August 7, 2014Date of Patent: January 9, 2018Assignee: Toshiba Lifestyle Products & Services CorporationInventors: Norihiro Yoshinaga, Yoshihiko Nakano, Norihiro Tomimatsu, Yoshihiro Akasaka
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Patent number: 9819041Abstract: A mixed oxide of Si and at least one metal M comprising inorganic groups —SO3H. The addition of the mixed oxide to fluorinated polymers containing sulfonic acid functional groups increases their stability towards radical degradation when used in fuel cell applications.Type: GrantFiled: July 9, 2013Date of Patent: November 14, 2017Assignee: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.Inventors: Claudio Oldani, Luca Merlo, Antonio Salvatore Arico, Claudia D'Urso, Vincenzo Baglio
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Patent number: 9809470Abstract: According to one embodiment, an electrolytic membrane separation (EMS) subsystem is configured to remove one or more impurities from a contaminated reject solution and to recycle the reusable reject solution for subsequent use in regenerating ion exchange resins. According to another embodiment of the invention, the EMS subsystem is configured to concentrate the impurities recovered from the contaminated brine solution for subsequent disposal or treatment.Type: GrantFiled: April 23, 2015Date of Patent: November 7, 2017Assignee: Exergy Technologies CorporationInventor: Fred P. Reinhard
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Patent number: 9803058Abstract: An ion exchange membrane (52) for a fuel cell comprises a polymer having an acid functional group normally including protons, and having alkali metal ions partially ion-exchanged with the protons of the acid functional group of the membrane. The partial ion exchange of alkali metal ions into the membrane relates either to patterning of the exchanged ion make-up of the membrane, with some being ion exchanged and some not, or to the extent or concentration of the ion exchange in any particular location, or to both.Type: GrantFiled: June 24, 2008Date of Patent: October 31, 2017Assignee: Audi AGInventors: Vishal Onkarmal Mittal, Lesia V. Protsailo, Sathya Motupally
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Patent number: 9804090Abstract: An energy store system, including at least one cell element situated in a cell region having an anode, a cathode and an electrolyte system that is situated between the anode and the cathode and that is particularly at least partially liquid, the anode, the cathode and/or the electrolyte system being configured so that, as a function of a charging or discharging process of the cell element, functioning material is situated in the electrolyte system, and the functional material situated in the electrolyte system being ascertainable qualitatively and/or quantitatively. Because of such an energy store system, operating states of an energy store or a cell may be ascertained particularly simply and accurately. Also described is a related state detection system.Type: GrantFiled: July 17, 2012Date of Patent: October 31, 2017Assignee: ROBERT BOSCH GMBHInventors: Marcus Wegner, Jens Grimminger, Martin Tenzer, Jean Fanous
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Patent number: 9764335Abstract: A system for extracting metals (e.g. precious metals or dangerous metals) from a substrate material such as sludge from a lake bed or sewage treatment facility includes processing the substrate material and metals by exposing the substrate material and metals to the plasma of an electric arc. Then, the exposed substrate material and metals are passed through an electrically charged collection grid in which the metals, now electrically charged, are attracted to the collection grid and hold to the collection grid and the substrate material exits the collection grid with less concentrations (or none) of the metals. In some embodiments, in addition to recovering the metals (e.g. precious metals, dangerous metals, etc.), a flammable gas is produced.Type: GrantFiled: May 4, 2015Date of Patent: September 19, 2017Assignee: MAGNEGAS CORPORATIONInventor: Ermanno Santilli
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Patent number: 9718711Abstract: Various aspects of the present disclosure are directed toward apparatus and methods method for filtering water fluid by screening ionic minerals including sodium chloride from the water fluid. In one embodiment, the water fluid is passed into a work zone defined at least in part by oppositely-arranged first and second porous structures, each of which have a plurality of gated channels. The water fluid is processed in the work zone by applying respective electric voltages to electrically bias the first porous structure and the second porous structure. The respective electric voltages deplete sodium chloride ions in the water fluid in the work zone due to ion-flux continuity. In response to processing of the water fluid, ion-filtered water is collected from the work zone.Type: GrantFiled: October 1, 2013Date of Patent: August 1, 2017Assignee: The Board of Trustees of the Leland Stanford Junior UniversityInventors: Kee-Hyun Paik, Yang Liu, Robert W. Dutton, Qiushi Ran
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Patent number: 9719178Abstract: An electrochemical cell for the continuous acidification of alkaline water sources and recovery of carbon dioxide with simultaneous continuous hydrogen gas production having a center compartment, an electrolyte-free anode compartment having a mesh anode in direct contact with an ion permeable membrane, an endblock in direct contact with the anode where the endblock provides a gas escape route behind the anode, an electrolyte-free cathode compartment having a mesh cathode in direct contact with an ion permeable membrane, and an endblock in direct contact with the cathode where the endblock provides a gas escape route behind the cathode. Current applied to the electrochemical cell for generating hydrogen gas also lowers the pH of the alkaline water to produce carbon dioxide with no additional current or power. Also disclosed is the related method for continuously acidifying alkaline water sources and recovering carbon dioxide with continuous hydrogen gas production.Type: GrantFiled: February 28, 2014Date of Patent: August 1, 2017Assignee: The United States of America, as represented by the Secretary of the NavyInventors: Felice DiMascio, Heather D. Willauer, Dennis R. Hardy, Frederick Williams, M. Kathleen Lewis
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Patent number: 9605352Abstract: Provided is a cation exchange membrane having excellent mechanical strength against folding and the like and capable of delivering stable electrolytic performance for a long time, an electrolysis vessel using the cation exchange membrane and a method for producing the cation exchange membrane. A cation exchange membrane 1 at least includes: a membrane body containing a fluorine-based polymer having an ion-exchange group; and two or more reinforcing core materials arranged approximately in parallel within the membrane body. The membrane body is provided with two or more elution holes 12 formed between the reinforcing core materials 10 adjacent to each other.Type: GrantFiled: September 3, 2014Date of Patent: March 28, 2017Assignee: ASAHI KASEI KABUSHIKI KAISHAInventors: Hiroyuki Kameyama, Manabu Sugimoto, Yoshifumi Kado
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Patent number: 9599373Abstract: A hydrogen storage heat pump, including: a hydrogen storage unit in which hydrogen gas is stored in a compressed state; a hydrogen flow tube through which the hydrogen gas, which is supplied from the hydrogen storage unit, flows; plural hydrogen absorbing materials that are provided at the hydrogen flow tube, that each have a different absorption pressure at which hydrogen is absorbed, and that are arranged in an order such that the absorption pressure decreases in a hydrogen gas flow direction from the hydrogen storage unit; and a switching valve that is disposed between the hydrogen absorbing materials in the hydrogen flow tube and that switches a flow rate of the hydrogen gas.Type: GrantFiled: March 13, 2015Date of Patent: March 21, 2017Assignee: KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHOInventors: Takafumi Yamauchi, Yasuki Hirota, Masakazu Aoki, Takashi Shimazu
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Patent number: 9551076Abstract: The electrochemical reactors disclosed herein provide novel oxidation and reduction chemistries and employ increased mass transport rates of materials to and from the surfaces of electrodes therein.Type: GrantFiled: May 31, 2012Date of Patent: January 24, 2017Assignee: Clean Chemistry, Inc.Inventor: Wayne Buschmann
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Patent number: 9493368Abstract: A method of precipitating scale from water includes providing an electrochemical cell. The electrochemical cell includes a primary cathode chamber including a first electrode therein, a primary anode chamber including a second electrode therein, and a cation exchange membrane separating the primary cathode chamber from the primary anode chamber. A flow of feed water is split into separate input flows to each of the primary cathode chamber and the primary anode chamber. The pH of the water in the primary anode chamber is reduced by electrolysis. The pH of water in the primary cathode chamber is increased by electrolysis, and cations are removed from the water in the primary cathode chamber by forming scale on the first electrode in the primary cathode chamber. Separate treated water output flows, from each of the primary cathode chamber and primary anode chamber, are combined into a combined conditioned water flow.Type: GrantFiled: May 2, 2013Date of Patent: November 15, 2016Assignee: TANGENT COMPANY LLCInventor: Lyle E. Kirman
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Patent number: 9404191Abstract: It is an object of the present invention to provide an anode for a zero-gap brine electrolyzer which through employment of a highly roughened surface at a catalyst layer at an anode for a zero-gap brine electrolyzer makes it possible to achieve sufficient liquid permeability and further reduction in electrolyzing voltage and a brine electrolysis method employing same. The present invention relates to an anode for a zero-gap brine electrolyzer equipped with a liquid-permeable conductive substrate 21, and with a catalyst layer 22 which is provided on the conductive substrate 21 and which is such that the maximum difference in height of surface irregularities is 55 ?m to 70 ?m; a zero-gap brine electrolyzer equipped with the anode 20, a cathode 30, and an ion-exchange membrane I disposed between and in contact with the anode 20 and the cathode 30; and a brine electrolysis method employing same.Type: GrantFiled: October 25, 2013Date of Patent: August 2, 2016Assignee: OSAKA SODA CO., LTD.Inventors: Kanefusa Hara, Satoshi Hatano
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Patent number: 9206517Abstract: The present invention concerns an anodic compartment for metal electrowinning cells delimited by a frame-shaped skeleton comprising an envelope including a permeable separator secured to said frame-shaped skeleton by means of a frame-shaped flange, at least one anode obtained starting from a valve metal substrate coated with at least one corrosion-resistant catalytic layer, said anode being inserted inside said envelope, and a demister located above said anode and delimited by said separator and said skeleton. The invention also concerns an electrochemical cell for metal electrowinning comprising at least one such anodic compartment.Type: GrantFiled: October 25, 2012Date of Patent: December 8, 2015Assignee: INDUSTRIE DE NORA S.P.A.Inventor: Giuseppe Faita
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Patent number: 9067087Abstract: An air revitalization apparatus and method simultaneously removes carbon dioxide, water vapor, and heat from air and produces oxygen gas, hydrogen gas, and concentrated carbon dioxide gas, does not require an explosion proof enclosure, and includes a fan configured to blow air into a first gas-liquid contactor, an electrochemical cell including first through fourth passages configured to emit hydrogen gas, permit a flow of a carbonate-hydroxide solution, permit a flow of carbonate-bicarbonate solution, and emit oxygen gas, respectively, the first and fourth passages separated by at least three gas-impermeable membranes, and a second gas-liquid contactor, where the first gas-liquid contactor, second passage, and a first pump are configured to circulate the carbonate-hydroxide solution therethrough, where the second gas-liquid contactor, third passage, and a second pump are configured to circulate the carbonate-bicarbonate solution therethrough, and where the output of the first passage is operationally coupledType: GrantFiled: August 30, 2013Date of Patent: June 30, 2015Assignee: OCEANEERING INTERNATIONAL, INC.Inventor: Gary Patrick Noyes
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Patent number: 9028764Abstract: An electro-catalytic honeycomb for controlling exhaust emissions, which adopts to purify a lean-burn exhaust, comprises a honeycomb structural body, a solid-oxide layer and a cathode layer. The honeycomb structural body includes an anode, a plurality of gas channels, and a shell. The anode is formed as a backbone, the gas channels are formed inside the backbone for passing the exhaust, and the shell covers an outer surface of the anode. The solid-oxide layer is adhered to an inner surface of the anode and connects the shell so as to encapsulate the anode. The cathode layer is adhered to a tube wall of the solid-oxide layer and has an oxidizing environment. The anode has a reducing environment. The reducing and the oxidizing environment facilitate an electromotive force to occur between the anode and the cathode layer to promote a decomposition of nitrogen oxides of the exhaust into nitrogen and oxygen.Type: GrantFiled: November 1, 2012Date of Patent: May 12, 2015Inventor: Ta-Jen Huang
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Publication number: 20150122668Abstract: A water conditioner that utilizes ionic flow and selective ionic filtering to control water hardness and/or pH. In some embodiments, the water conditioner includes one or more conditioning cells each having electrodes and a cathode side and an anode side separated by an ion-selective filter. The ion-selective filter is design/configured/selected to pass alkaline earth metal cations and block corresponding carbonate anions. When the electrodes are energized and water is present on the cathode and anode sides of the filter membrane, the alkaline earth metal cations pass from the anode side to the cathode side through the membrane, while the membrane blocks carbonate ions on the cathode side from passing to the anode side. In this manner, alkaline earth metal cations, and water hardness, can be reduced in the anode flow.Type: ApplicationFiled: October 30, 2014Publication date: May 7, 2015Inventor: Tadeusz Karabin