With Feeding And/or Withdrawal Means Patents (Class 204/263)
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Patent number: 8778148Abstract: Apparatus for hydrogen chloride electrolysis, comprising a cathode that has a layer of nitrogen-doped carbon nanotubes having functional groups containing nitrogen.Type: GrantFiled: March 25, 2009Date of Patent: July 15, 2014Assignee: Bayer Intellectual Property GmbHInventors: Aurel Wolf, Leslaw Mleczko, Volker Michele, Jens Assmann, Jürgen Kintrup, Rainer Weber
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Publication number: 20140158527Abstract: The present invention relates to a method for manufacturing an electrode module for recovery of metal ions, an electrode module for recovery of metal ions, and an apparatus for recovery of metal ions including the same. the present invention provides a method for manufacturing an electrode module for recovery of metal ions, the method including the steps of: a) preparing a first electrode part and a second electrode part for electrically adsorbing or desorbing metal ions contained in a liquid; and b) interposing an insulating layer, through which the liquid passes, between the first electrode part and the second electrode part, an electrode module for recovery of metal ions manufactured by the method, and an apparatus for recovery of metal ions including the same.Type: ApplicationFiled: April 13, 2012Publication date: June 12, 2014Inventors: Kang-Sup Chung, Tae Gong Ryu, Jae Chun Ryu
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Publication number: 20140138255Abstract: The invention relates to the sphere of meeting vital requirements of people in the area of disinfection methods and equipment, involving electrolyzer and electrolysis in the sphere of chemistry. It can be used both to obtain disinfectant and to manufacture new equipment, used to obtain disinfectants. Electrolytes are made subject to electrochemical processes of different intensity in electrode chambers of one and the same electrolyzer; relatively low in cathode chamber and relatively strong in anode chamber. In addition, the construction of electrolyzer involves elements that improve sealing properties of connection, protect materials from electrochemical influences, simplify servicing equipment, supplied with electrolyzers. Technical results involve decreasing the fraction of electrolyte that is discharged to enhance the pH value of disinfectant obtained to 5.8-6.5 with the purpose of improving its efficiency and extend the useful lifetime of the electrolyzer and diversify its scope of application.Type: ApplicationFiled: December 27, 2012Publication date: May 22, 2014Inventors: Valeri Iltshenko, Nikolay Nayda
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Patent number: 8728295Abstract: A cell having an anode compartment and a cathode compartment is used to electrolyze an alkali metal polysulfide into an alkali metal. The cell includes an anode, wherein at least part of the anode is housed in the anode compartment. The cell also includes a quantity of anolyte housed within the anode compartment, the anolyte comprising an alkali metal polysulfide and a solvent. The cell includes a cathode, wherein at least part of the cathode is housed in the cathode compartment. A quantity of catholyte is housed within the cathode compartment. The cell operates at a temperature below the melting temperature of the alkali metal.Type: GrantFiled: October 9, 2009Date of Patent: May 20, 2014Assignee: Ceramatec, Inc.Inventors: John Howard Gordon, Ashok V. Joshi
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Patent number: 8679304Abstract: A biocide solution containing hypochlorous acid, hydrochlorous acid, hydrochloric acid, percholoric acid, chlorine gas, hydrogen peroxide and ozone provides broad spectrum biocidal properties as well as an apparatus for producing the solution.Type: GrantFiled: August 26, 2009Date of Patent: March 25, 2014Inventor: Firdose Irani
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Publication number: 20140076724Abstract: A cell module includes an anode, a cathode and a proton exchange membrane. The anode adheres to one side of the proton exchange membrane while the cathode adheres to the opposite side thereof. The anode comprises a substrate and at least one diamond-like carbon layer covering the substrate. The present disclosure further provides an ozone generator and a method using the same.Type: ApplicationFiled: September 14, 2012Publication date: March 20, 2014Applicant: CASHIDO CORPORATIONInventors: LIANG-CHIEN CHENG, TAI-FANG HUNG, I-CHIAO LIN, CHUN-LUNG CHIU, XIN-YING HAN, RU-SHI LIU, SHIH-CHANG CHEN, CHIEN-MIN SUNG
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Patent number: 8669296Abstract: A process for preparing a polyazole with an inherent viscosity, measured in at least 96% sulfuric acid at 25° C., greater than 2.9 dl/g, comprising the steps of i) mixing one or more aromatic tetraamino compounds with one or more aromatic carboxylic acids or esters thereof which comprise at least two acid groups per carboxylic acid monomer, or mixing one or more aromatic and/or heteroaromatic diaminocarboxylic acids, in polyphosphoric acid to form a solution and/or dispersion ii) heating the mixture from step i) under inert gas to temperatures in the range from 120° C. to 350° C. to form the polyazole, wherein in step ii), a mixture having a concentration of polyphosphoric acid, calculated as P2O5 (by acidimetric means), based on the total amount of H3PO4, polyphosphoric acid and water in the mixture, greater than 78.Type: GrantFiled: June 17, 2010Date of Patent: March 11, 2014Assignee: BASF SEInventors: Jörg Belack, Klaus Leitner, Hansjoachim Scupin, Oemer Uensal
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Publication number: 20140061037Abstract: The present disclosure relates to a sterilized water creating cartridge having an inlet and an outlet in one direction for producing sterilized water by underwater-discharging water supplied from an inlet and discharging the sterilizes water to an outlet, the cartridge including a sterilized water producing unit including a negative electrode plate having an electrode connector for underwater-discharging the water, and a positive electrode plate, and a case accommodating the sterilized water producing unit thereinside, formed with an electrode connector through hole passing the electrode connector, and having an inlet and an outlet on a surface of one direction toward both sides of the sterilized water producing unit.Type: ApplicationFiled: September 28, 2012Publication date: March 6, 2014Inventor: Man-Geun Kim
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Publication number: 20140057003Abstract: Device, system and method for electrochemical generation of a liquid soap by electrolyzing a surfactant in an aqueous carrier in a cathode compartment of an electrolytic cell and electrolyzing an antimicrobial agent in an aqueous carrier in an anode compartment of the electrolytic cell with the compartments separated by a semipermeable membrane. Portions of the electrolyzed surfactant solution and portions of the electrolyzed antimicrobial solution are withdrawn from the cathode compartment and the anode compartment and combined to form the liquid soap. Skin benefiting agents such as vitamins may be added to the liquid soap with the surfactant and/or antimicrobial agent.Type: ApplicationFiled: August 23, 2013Publication date: February 27, 2014Inventor: Raymond C. Johnson
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Patent number: 8647497Abstract: A system for hydrogen sulfide removal from a sour gas mixture including hydrogen sulfide. The sour gas mixture is reacted with a transition metal compound in a scrubber. Sulfide from the hydrogen sulfide is oxidized to form elemental sulfur and the transition metal is reduced to form a reduced state transition metal compound. An electrochemical redox reaction is performed including the reduced state transition metal compound to regenerate the transition metal compound in an electrolyzer including a power source. During the electrochemical redox reaction a voltage from the power source applied to the electrolyzer is controlled to regenerate the transition metal compound at a rate sufficient to match a flow rate of hydrogen sulfide into the scrubber or maintain a predetermined maximum hydrogen sulfide level out from the scrubber. The transition metal compound regenerated is returned to the scrubber for the reacting.Type: GrantFiled: January 17, 2012Date of Patent: February 11, 2014Assignee: University of Central Florida Research Foundation, Inc.Inventors: Cunping Huang, Franklyn Smith, Clovis A. Linkous, Karthikeyan Ramasamy, Ali T. Raissi, Nazim Muradov
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Publication number: 20140034506Abstract: Methods and systems for electrochemically generating an oxidation product and a reduction product may include one or more operations including, but not limited to: receiving a feed of at least one organic compound into an anolyte region of an electrochemical cell including an anode; at least partially oxidizing the at least one organic compound at the anode to generate at least carbon dioxide; receiving a feed including carbon dioxide into a catholyte region of the electrochemical cell including a cathode; and at least partially reducing carbon dioxide to generate a reduction product at the cathode.Type: ApplicationFiled: September 25, 2013Publication date: February 6, 2014Applicant: Liquid Light, Inc.Inventors: Kyle Teamey, Jerry J. Kaczur, Narayanappa Sivasankar, Paul Majsztrik, Emily Barton Cole, Andrew B. Bocarsly
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Publication number: 20140034511Abstract: An electrolytic cell, a method for manufacturing the cell, and a method of operating same. The electrolytic cell has at least two bipolar plates, at least one fluid inflow and outflow, as well as at least one laminated core arranged between the at least two bipolar plates. The laminated core is constructed from laminations which are stacked one on top of the other. At least two laminations have recesses which are designed to extend through the entire thickness of the respective lamination. The at least two laminations are arranged one on top of the other in such a way that recesses in adjacent laminations overlap partially, but not completely, as a result of which ducts, which are continuous in the direction of the plane of the lamination, are formed.Type: ApplicationFiled: March 27, 2012Publication date: February 6, 2014Inventors: Ralf Cordes, Klaus Dennerlein, Alexander Hahn, Hagen Hertsch, Norbert Huber, Carola Kuehn
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Publication number: 20140038074Abstract: A method and an apparatus of reacting reaction components. The method comprises electro-chemically reacting reaction components on opposite sides of at least one membrane with at least one catalyst encompassing a respective volume. In another embodiment, the method includes conducting electrolysis, such as electrolysis of water. The apparatus includes at least one membrane with first and second sides encompassing a respective volume. The apparatus further includes at least one catalyst coupled to the first and second sides to electro-chemically react reaction components on the first and second sides in gaseous communication with the at least one catalyst, and a cover coupled to the at least one membrane to separate flow paths on the first and second sides.Type: ApplicationFiled: October 11, 2013Publication date: February 6, 2014Applicant: Encite, LLCInventor: Stephen A. Marsh
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Publication number: 20140027301Abstract: A method and electrochemical cell for recovery of metals is provided, where the electrochemical cell includes an anode disposed in an anodic chamber, a cathode disposed in a cathodic chamber, an ion-conducting separator disposed between the anode and the cathode to physically separate the anodic and cathodic chambers, a basic pH anolyte containing a sacrificial reductant disposed within the anodic chamber, an acidic pH catholyte containing metal ions disposed within the cathodic chamber, and an electrical connection between the anode and the cathode. The method includes applying a voltage or an electrical current to an electrolytic cell across the cathode and the anode and is sufficient to reduce the metal ions to form an elemental metal species at the cathode, and to oxidize the sacrificial reductant at the anode.Type: ApplicationFiled: March 14, 2013Publication date: January 30, 2014Applicant: OHIO UNIVERSITYInventor: Gerardine G. Botte
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Patent number: 8636880Abstract: The present invention provides an electrochemical cell for producing hydrogen gas and cupric chloride, comprising an anode compartment including an anode disposed in an anolyte, wherein the anolyte is cuprous chloride in hydrochloric acid, a cathode compartment including a cathode, wherein the cathode comprises an electrocatalyst, and a cation exchange membrane disposed between the anode compartment and the cathode compartment.Type: GrantFiled: August 26, 2009Date of Patent: January 28, 2014Assignee: Atomic Energy of Canada LimitedInventor: Lorne Stolberg
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Patent number: 8632663Abstract: There is provided a hydrogen production device high in light use efficiency and capable of producing hydrogen with high efficiency. The hydrogen production device according to the present invention includes a photoelectric conversion part having a light acceptance surface and a back surface, a first gas generation part provided on the back surface, and a second gas generation part provided on the back surface, in which one of the first gas generation part and the second gas generation part is a hydrogen generation part to generate H2 from an electrolytic solution, another one thereof is an oxygen generation part to generate O2 from the electrolytic solution, the first gas generation part is electrically connected to the back surface, and the second gas generation part is electrically connected to the light acceptance surface via a first conductive part.Type: GrantFiled: June 25, 2010Date of Patent: January 21, 2014Assignee: Sharp Kabushiki KaishaInventors: Akihito Yoshida, Shunsuke Sata, Masaki Kaga
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Publication number: 20140001053Abstract: A system and method for generating hypochlorous acid, the system comprising an electrolysis cell, a first fluid line configured to direct a first salt solution to a cathode chamber of the electrolysis cell, and a second fluid line configured to direct a second salt solution to an anode chamber of the electrolysis cell, where the second salt solution has a greater salt concentration than the first salt solution.Type: ApplicationFiled: June 27, 2013Publication date: January 2, 2014Inventors: Daniel P. Longhenry, Daniel L. Joynt
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Publication number: 20130341204Abstract: Electrode devices and systems for use in liquid environments, including associated methods are provided. In one aspect, for example, an electrode device for use in a liquid environment can include a proton exchange membrane having a first side and a second side, a first electrode including a carbon material, where the first electrode is positioned at the first side of the proton exchange membrane, and a second electrode including a carbon material, where the second electrode positioned at the second side of the proton exchange membrane opposite the first electrode. The proton exchange membrane spaces the first electrode and the second electrode at a distance of less than or equal to about 100 microns apart.Type: ApplicationFiled: April 23, 2013Publication date: December 26, 2013Applicant: RiteDia CorporationInventor: RiteDia Corporation
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Publication number: 20130337366Abstract: The design and method of fabrication of a three-dimensional, porous flow structure for use in a high differential pressure electrochemical cell is described. The flow structure is formed by compacting a highly porous metallic substrate and laminating at least one micro-porous material layer onto the compacted substrate. The flow structure provides void volume greater than about 55% and yield strength greater than about 12,000 psi. In one embodiment, the flow structure comprises a porosity gradient towards the electrolyte membrane, which helps in redistributing mechanical load from the electrolyte membrane throughout the structural elements of the open, porous flow structure, while simultaneously maintaining sufficient fluid permeability and electrical conductivity through the flow structure.Type: ApplicationFiled: June 12, 2013Publication date: December 19, 2013Inventors: Scott Blanchet, Roger Van Boeyen
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Patent number: 8603305Abstract: An electrolyte, and particularly anolyte, may be circulated via an open loop having a pressure regulator, so that the pressure in the plating chamber is maintained at a constant (or substantially constant) value with respect to atmospheric pressure. In these embodiments, a pressure regulator is in fluid communication with the anode chamber.Type: GrantFiled: March 18, 2011Date of Patent: December 10, 2013Assignee: Novellus Systems, Inc.Inventors: Robert Rash, Richard Abraham, David W. Porter, Steven T. Mayer
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Patent number: 8597476Abstract: Electrolytic equipment in the form of radiation mode that is provided with pluralities of baffles (13) in the form of radiation mode on the top surface of the seat (10) and acidic water passage (131) is formed between the baffles (13). The top surface of the seat (10) has through holes (14) used to make anode conduction portions (33) of anode plate (30) through. In the center of the seat (10), there is a socket joint portion (11) that is provided with an inlet and outlet interval tube (15) in the center of it. There are plurality of equidistributed baffles (151, 157) on the inside wall and the outside wall of the inlet and outlet interval tube (15) to form raw water inlet passage (152) and acidic water outlet passage (153).Type: GrantFiled: November 15, 2007Date of Patent: December 3, 2013Inventor: Wen-Shing Shyu
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Publication number: 20130313126Abstract: An electrolysis method for electrolytic cells having an electrode-membrane-electrode assembly includes two porous electrode having a porous membrane located therebetween and filled with electrolyte or having an ion exchange membrane located therebetween, one or more liquids being led directly into the membrane of the electrode-membrane-electrode assembly. The one or more liquids are guided in a channel structure arranged in the membrane. An electrolytic cell includes porous electrode, between which a porous membrane is arranged. A liquid electrolyte is fixed in the pore of electrodes and membrane, a product gas chamber adjoining the cathode, a further product gas chamber adjoining the anode, and an arrangement for feeding a liquid to the electrode. A channel structure, in which distribution of the liquid is provided, is arranged in the membrane.Type: ApplicationFiled: December 6, 2011Publication date: November 28, 2013Applicant: ASTRIUM GMBHInventors: Willigert Raatschen, Joachim Lucas, Walter Jehle, Helmut Funke
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Patent number: 8591719Abstract: An electrolytic cell for the production of hydrogen peroxide with faradic efficiency and a method for the production of highly pure hydrogen peroxide with high faradic efficiency are disclosed. The cell is provided with a separator of high hydraulic permeability and is equipped with an oxygen-fed gas-diffusion cathode and with an anode activated with a catalyst for oxygen evolution. The high faradic efficiency of hydrogen peroxide generation is allowed by the dilution of product hydrogen peroxide by the anolyte crossing the permeable separator, and by keeping the operating temperature at values below 50° C.Type: GrantFiled: March 20, 2009Date of Patent: November 26, 2013Assignee: Industrie de Nora S.p.A.Inventor: Giuseppe Faita
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Publication number: 20130299343Abstract: An electroplating processor includes an electrode plate having a continuous flow path formed in a channel. The flow path may optionally be a coiled flow path. One or more electrodes are positioned in the channel. A membrane plate is attached to the electrode plate with a membrane in between them. Electrolyte moves through the flow path at a high velocity, preventing bubbles from sticking to the bottom surface of membrane. Any bubbles in the flow path are entrained in the fast moving electrolyte and carried away from the membrane. The electroplating processor may alternatively have a wire electrode extending through a tubular membrane formed into a coil or other shape, optionally including shapes having straight segments.Type: ApplicationFiled: May 10, 2012Publication date: November 14, 2013Applicant: APPLIED MATERIALS, INC.Inventors: Randy A. Harris, Daniel J. Woodruff, Jeffrey I. Turner, Gregory J. Wilson, Paul R. McHugh
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Publication number: 20130277210Abstract: The present invention relates to an electrolytic cell for an FT-CDI including: an injection port into which a bead and a concentrate are injected and a discharge port through which the bead and the concentrate are discharged to circulate the bead, thereby preventing the concentration of the bead from being degraded and disposes a mesh at a place in which the concentrate and the bead are received to disperse the concentrate and the bead well.Type: ApplicationFiled: October 16, 2012Publication date: October 24, 2013Inventors: Teak Sung Hwang, Sung-Gyu Park, Hui-Man Park, Noh-Seok Kwak, Chi Won Hwang
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Publication number: 20130256151Abstract: Electrolyser comprising at least one single electrolyser element which comprises at least one anode compartment with an anode, one cathode compartment with a cathode and one ion exchange membrane arranged between the anode and the cathode compartments, with the anode and/or cathode being a gas diffusion electrode. A gap is provided between the gas diffusion electrode and the ion exchange membrane, with an electrolyte inlet arranged at the upper end of the gap and an electrolyte outlet at the lower end of the gap and a gas inlet and a gas outlet. The electrolyte outlet extending into a discharge header, and the electrolyte inlet connected to an electrolyte feed tank and having an overflow, the overflow connected to the discharge header, with a coiled hose connecting the electrolyte feed tank with the electrolyte inlet and with a coiled hose connecting the overflow with the discharge header.Type: ApplicationFiled: November 15, 2011Publication date: October 3, 2013Applicant: UHDENORA, S.P.A.Inventors: Peter Woltering, Randolf Kiefer, Rainer Weber, Andreas Bulan
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Patent number: 8540857Abstract: An apparatus for electroplating a layer of metal onto a work piece surface includes a membrane separating the chamber of the apparatus into a catholyte chamber and an anolyte chamber. In the catholyte chamber is a catholyte manifold region that includes a catholyte manifold and at least one flow distribution tube. The catholyte manifold and at least one flow distribution tube serve to mix and direct catholyte flow in the catholyte chamber. The provided configuration effectively reduces failure and improves the operational ranges of the apparatus.Type: GrantFiled: August 9, 2012Date of Patent: September 24, 2013Assignee: Novellus Systems, Inc.Inventors: Steven Mayer, Shantinath Ghongadi, Kousik Ganesan, Zhian He, Jingbin Feng
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Publication number: 20130245540Abstract: A producing method for a living organism-applicable hydrogen-contained fluid, which includes hydrogen molecules in living organism-applicable fluid enclosed in a container (2i) with hydrogen molecule permeability, is provided. This method includes a hydrogen exposing step of exposing hydrogen molecules to the container (2i) in which the living organism-applicable fluid is enclosed from the outside of the container without opening the container. The container with hydrogen molecule permeability is one that allows a dissolved hydrogen concentration of a normal saline solution to be 1 ppb or greater when the container filled with the normal saline solution is immersed for 5 hours in a volume of hydrogen water, which stably maintains an approximately saturated state (1.6 ppm at 20 C degrees under 1 barometric pressure) and is 20 times the content volume of the container.Type: ApplicationFiled: March 15, 2013Publication date: September 19, 2013Applicant: MIZ CO. LTD.Inventors: Bunpei SATOH, Kazuyoshi ARAI, Fumitake SATOH
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Publication number: 20130220830Abstract: Apparatuses and methods for controlling ionic strength and/or pH of a solution are provided.Type: ApplicationFiled: February 15, 2013Publication date: August 29, 2013Applicants: Technion Research & Development Foundation Ltd., Bio-Rad Laboratories, Inc.Inventors: Aran Paulus, Camille Diges, Roumen Bogoev, Sricharan Bandhakavi, Annett Hahn-Windgassen, Anton Posch, Elad Brod, Uri Sivan
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Patent number: 8518225Abstract: An apparatus for producing in the home hydrogen-dissolved drinking water that is suitable for drinking, has a high dissolved hydrogen concentration, and a long dissolved hydrogen life. A hydrogen-dissolved drinking water production apparatus includes an electrolytic cell through which water can pass for producing drinking water having a pH in a range of 2.5 to 8.5, and in particular, in a range of 5.8 to 8.5, and a dissolved hydrogen concentration of 0.1 ppm or more by supplying high-purity water having a conductivity of 50 ?S/cm or less.Type: GrantFiled: October 16, 2009Date of Patent: August 27, 2013Assignee: Spring Co., Ltd.Inventors: Osao Sumita, Shin Gyo Yim
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Patent number: 8496789Abstract: An electrochemical processor may include a head having a rotor configured to hold a workpiece, with the head moveable to position the rotor in a vessel. Inner and outer anodes are in inner and outer anolyte chambers within the vessel. An upper cup in the vessel, has a curved upper surface and inner and outer catholyte chambers. A current thief is located adjacent to the curved upper surface. Annular slots in the curved upper curved surface connect into passageways, such as tubes, leading into the outer catholyte chamber. Membranes may separate the inner and outer anolyte chambers from the inner and outer catholyte chambers, respectively.Type: GrantFiled: May 18, 2011Date of Patent: July 30, 2013Assignee: APPLIED Materials, Inc.Inventors: Paul R. McHugh, Gregory J. Wilson, Kyle M. Hanson
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Patent number: 8496790Abstract: An electrochemical processor may include a head having a rotor configured to hold a workpiece, with the head moveable to position the rotor in a vessel. Inner and outer anodes are in inner and outer anolyte chambers within the vessel. An upper cup in the vessel, has a curved upper surface and inner and outer catholyte chambers. A current thief is located adjacent to the curved upper surface. Annular slots in the curved upper curved surface connect into passageways, such as tubes, leading into the outer catholyte chamber. Membranes may separate the inner and outer anolyte chambers from the inner and outer catholyte chambers, respectively.Type: GrantFiled: November 3, 2011Date of Patent: July 30, 2013Assignee: APPLIED Materials, Inc.Inventors: Gregory J. Wilson, Paul R. McHugh
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Publication number: 20130180849Abstract: The present aspects of an embodiment make more efficient use of hydrogen on-demand (hereinafter “HoD”) systems, thereby improving fossil-fuel-powered systems on the market. One main aspect uses a disposable cartridge in which the electrolytic process takes place to separate gas molecules from a solution that uses a substantially dry-cell design. Generally, the aspects include a replaceable and reusable cartridge for the flow of electrolyte solution using a pump, which may include a variety of safety features. A HoD cartridge generator has a plurality of staggered conductive material members that require electrolyte solution to flow between them, from one or more inlets to one or more outlets, using one or more specified paths. A conventional or specially-formulated electrolyte solution may be used. One or more sensors allow the generator to have a steady flow of solution in and a steady flow of liquid-gas mixture out of the system.Type: ApplicationFiled: January 18, 2012Publication date: July 18, 2013Inventor: Marc Daniel Moncion
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Patent number: 8486254Abstract: A washing apparatus and a method of deodorizing washing water that can prevent the unpleasant smell of washing water are provided. An electrolytic water producing means 2 produces strong acidic water and strong alkaline water by electrolysis of an electrolytic solution. The produced strong acidic water and strong alkaline water are stored in an acid container 3 and alkali container 4, respectively. A mist container 5 connected to the alkali container 4 produces a deodorant mist upon receiving a part of the strong alkaline water in the alkali container 4. A discharge port 6a is selectively connected to the acid container 3, alkali container 4, or water pipe 8 so as to discharge the strong acidic water, strong alkaline water, or tap water. A mist ejection portion 7 is formed to spray the deodorant mist of the strong alkaline water in the mist container 5 around the strong acidic water or tap water discharged from the discharge port 6a so that the mist surrounds the strong acidic water or tap water.Type: GrantFiled: January 13, 2010Date of Patent: July 16, 2013Inventor: Minoru Kanno
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Publication number: 20130168260Abstract: An electrolytic device for the generation of hypohalous acid in aqueous solutions includes at least a single liquid chamber for receiving an aqueous solution containing halide ions therein, the single liquid chamber having an exterior wall and a solid anode contained within to provide for the oxidation of the halide ions, which, in turn, provides for the formation of hypohalous acid in aqueous solution, and a gas permeable cathode forming a portion of the exterior wall of the single liquid chamber, the cathode providing for the reduction of oxygen to provide hydroxyl ions in solution within the single liquid chamber to mix with the products generated at the anode. An embodiment of the electrolytic device including an anolyte chamber and a catholyte chamber separated by an ionomeric membrane is also described, whereby the anolyte chamber further includes an outlet including a pH control for determining and regulating the pH of the exiting anolyte effluent to between about 4 and 9.Type: ApplicationFiled: February 27, 2013Publication date: July 4, 2013Applicant: GOJO INDUSTRIES, INC.Inventors: Daniel A. Scherson, Jackson W. Weglin, Wilfred J. Hemker
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Publication number: 20130161200Abstract: In the magnesium recovery method and magnesium recovery apparatus, anode electrolyzed water (7a) and cathode electrolyzed water (7b) produced by electrolysis of seawater are separated, alkaline material is inputted into the anode electrolyzed water to adjust pH, magnesium is precipitated as magnesium hydroxide in the cathode electrolyzed water, and recovered, and the anode electrolyzed water after pH adjustment and cathode electrolyzed water after carbonate fixation are intermixed, and discharged in a state where a pH of the intermixed water is identical to a pH of the seawater. As a result, magnesium can be recovered from seawater while minimizing impact on the environment.Type: ApplicationFiled: September 6, 2011Publication date: June 27, 2013Inventors: Tatsushi Iwamoto, Kenichi Akamine, Junichi Okuyama
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Patent number: 8470143Abstract: A chlorine-generating apparatus is herein disclosed which uses softened household water and salt. The apparatus includes a freestanding brine tank to hold salt and softened household water. The brine tank includes a submerged chlorine-generating cell, an improved chlorine-generating cell container, and a cell-cleaning reservoir. The brine tank also includes a precipitation tank to help remove minerals from the incoming household water. The chlorine-generating apparatus generates sodium hypochlorite, sodium hydroxide, as well as other sanitizing chemicals. The chlorine-generating apparatus also incorporates an improved method for controlling pH. A water-cooled power supply independently delivers power to the chlorine-generating cell.Type: GrantFiled: January 26, 2010Date of Patent: June 25, 2013Inventor: Daniel Moroni Tucker
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Patent number: 8465630Abstract: An electrically driven oxygen separation assembly and method for applying an electrical potential in which the assembly has one or more tubular membrane elements. The potential is applied at two central spaced locations of a tubular membrane element and at least at opposite end locations thereof. As a result the electric current flow through the tubular membrane element is divided into two parts flowing between the two central spaced locations and the opposite end locations. Additionally, the present invention also provides an end seal to be used in connection with tubular membrane elements.Type: GrantFiled: October 28, 2009Date of Patent: June 18, 2013Assignee: Praxair Technology, Inc.Inventors: David M. Reed, David Frisbee Suggs, Michael J. Collins, Richard Martin Kelly, Gervase Maxwell Christie
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Patent number: 8465856Abstract: A polymer electrolyte-containing solution is obtained by preparing a first solution, preparing a second solution and mixing the first and second solutions. The first solution is prepared by dissolving a perfluorocarbonsulfonic acid resin (component A) having an ion-exchange capacity of 0.5 to 3.0 meq/g in a protic solvent. The second solution is prepared separate from the first solution, by dissolving a polyazole-based compound (component B) and an alkali metal hydroxide in a protic solvent. The first and second solutions are mixed to prepare a polymer electrolyte-containing solution in which a weight ratio of the component A to component B, (A/B) , is from 2:3 to 199 and a total weight of the component A and the component B is from 0.5 to 30% by weight on the basis of the solution including the protic solvent. The protic solvent is an aliphatic alcohol.Type: GrantFiled: August 26, 2010Date of Patent: June 18, 2013Assignee: Asahi Kasei Chemicals CorporationInventors: Yoshinori Yanagita, Kohei Kita, Naoki Sakamoto, Takehiro Koga
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Patent number: 8454808Abstract: A hydrogen generation system for producing hydrogen and injecting the hydrogen as a fuel supplement into the air intake of internal combustion engines. Hydrogen and oxygen is produced with a fuel cell at low temperatures and pressure from water in a supply tank. The hydrogen is directed to the air intake of the engine while the oxygen is vented to the atmosphere. The device is powered by the vehicle battery. The system utilizes an engine sensor that permits power to the system only when the engine is in operation.Type: GrantFiled: September 2, 2011Date of Patent: June 4, 2013Assignee: HNO Greenfuels, Inc.Inventor: Donald Owens
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Publication number: 20130134045Abstract: Methods, systems, and apparatus for plating a metal onto a work piece are described. In one aspect, an apparatus includes a plating chamber, a substrate holder, an anode chamber housing an anode, and an ionically resistive ionically permeable element positioned between a substrate and the anode chamber during electroplating. The anode chamber may be movable with respect to the ionically resistive ionically permeable element to vary a distance between the anode chamber and the ionically resistive ionically permeable element during electroplating. The anode chamber may include an insulating shield oriented between the anode and the ionically resistive ionically permeable element, with opening in a central region of the insulating shield.Type: ApplicationFiled: November 29, 2011Publication date: May 30, 2013Inventors: David W. PORTER, Jonathan D. REID, Frederick D. WILMOT
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Patent number: 8449733Abstract: A hydrogen generation system for producing hydrogen and injecting the hydrogen as a fuel supplement into the air intake of internal combustion engines. Hydrogen and oxygen is produced with a fuel cell at low temperatures and pressure from water in a supply tank. The hydrogen is directed to the air intake of the engine while the oxygen is vented to the atmosphere. The device is powered by the vehicle battery. The system utilizes an engine sensor that permits power to the system only when the engine is in operation.Type: GrantFiled: September 2, 2011Date of Patent: May 28, 2013Assignee: HNO Greenfuels, Inc.Inventor: Donald Wade Owens
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Patent number: 8449736Abstract: A hydrogen generation system for producing hydrogen and injecting the hydrogen as a fuel supplement into the air intake of internal combustion engines. Hydrogen and oxygen is produced with a fuel cell at low temperatures and pressure from water in a supply tank. The hydrogen is directed to the air intake of the engine while the oxygen is vented to the atmosphere. The device is powered by the vehicle battery. The system utilizes an engine sensor that permits power to the system only when the engine is in operation.Type: GrantFiled: September 2, 2011Date of Patent: May 28, 2013Assignee: HNO Greenfuels, Inc.Inventor: Donald Wade Owens
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Patent number: 8449735Abstract: A hydrogen generation system for producing hydrogen and injecting the hydrogen as a fuel supplement into the air intake of internal combustion engines. Hydrogen and oxygen is produced with a fuel cell at low temperatures and pressure from water in a supply tank. The hydrogen is directed to the air intake of the engine while the oxygen is vented to the atmosphere. The device is powered by the vehicle battery. The system utilizes an engine sensor that permits power to the system only when the engine is in operation.Type: GrantFiled: September 2, 2011Date of Patent: May 28, 2013Assignee: HNO Greenfuels, Inc.Inventor: Donald Wade Owens
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Patent number: 8449734Abstract: A hydrogen generation system for producing hydrogen and injecting the hydrogen as a fuel supplement into the air intake of internal combustion engines. Hydrogen and oxygen is produced with a fuel cell at low temperatures and pressure from water in a supply tank. The hydrogen is directed to the air intake of the engine while the oxygen is vented to the atmosphere. The device is powered by the vehicle battery. The system utilizes an engine sensor that permits power to the system only when the engine is in operation.Type: GrantFiled: September 2, 2011Date of Patent: May 28, 2013Assignee: HNO GreenFuels, Inc.Inventor: Donald Wade Owens
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Publication number: 20130126338Abstract: An electrolyte electrolyzer adapted to create hydrogen and oxygen from electrolyte fluid at or near atmospheric pressure. The electrolyzer is comprised in a preferred form of a plurality of cells which collectively create oxygen and hydrogen chambers separated by an ion permeable membrane. The electrolyzer is further defined by a passive electrode that is electrically interposed between a charged anode and cathode. The chambers defined by the cells are in communication with oxygen and hydrogen supply lines to transfer the hydrogen gas from the unit.Type: ApplicationFiled: November 27, 2012Publication date: May 23, 2013Applicant: WOOD STONE CORPORATIONInventor: Wood Stone Corporation
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Patent number: 8444846Abstract: A method of producing hydrogen from sodium hydroxide and water is disclosed. The method comprises separating sodium from a first aqueous sodium hydroxide stream in a sodium ion separator, feeding the sodium produced in the sodium ion separator to a sodium reactor, reacting the sodium in the sodium reactor with water, and producing a second aqueous sodium hydroxide stream and hydrogen. The method may also comprise reusing the second aqueous sodium hydroxide stream by combining the second aqueous sodium hydroxide stream with the first aqueous sodium hydroxide stream. A system of producing hydrogen is also disclosed.Type: GrantFiled: December 7, 2009Date of Patent: May 21, 2013Assignee: Battelle Energy Alliance, LLCInventors: Dennis N. Bingham, Kerry M. Klingler, Terry D. Turner, Bruce M. Wilding, Lyman Frost
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Patent number: 8444833Abstract: The invention relates to an electrolysis device for cleaning acidic waters which comprises a cathode, an anode, and an ion exchange membrane, wherein the membrane is arranged between the cathode and the anode and is attached at least along the entire circumference of its rim, wherein many inlets and outlets are arranged along the upper and lower rim of the electrolysis device which are linked to the cathode space or to the anode space, in such a way that a plug flow, ideally with a laminar profile, is created in the cathode space and in the anode space.Type: GrantFiled: May 16, 2007Date of Patent: May 21, 2013Assignee: Uhde GmbHInventors: Randolf Kiefer, Karl-Heinz Dulle, Peter Woltering, Stefan Oelmann, Ulf-Steffen Baeumer, Wolfram Stolp
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Publication number: 20130118911Abstract: Disclosed is a system and method for reducing carbon dioxide into a carbon based product. The system includes an electrochemical cell having a cathode region which includes a cathode and a non-aqueous catholyte; an anode region having an anode and an aqueous or gaseous anolyte; and an ion permeable zone disposed between the anode region and the cathode region. The ion permeable zone is at least one of (i) the interface between the anolyte and the catholyte, (ii) an ion selective membrane; (iii) at least one liquid layer formed of an emulsion or (iv) a hydrophobic or glass fiber separator. The system and method includes a source of energy, whereby applying the source of energy across the anode and cathode reduces the carbon dioxide and produces an oxidation product.Type: ApplicationFiled: December 21, 2012Publication date: May 16, 2013Applicant: Liquid Light, Inc.Inventor: Liquid Light, Inc.
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Publication number: 20130112550Abstract: Among other things, a device for use in electrolyzing water is described. The device comprises an electrolysis unit that includes a chamber, an ion exchange structure in the chamber, a cathode, an anode, a high pressure chamber, and a reservoir. The chamber is separated by the ion exchange structure into a first compartment and a second compartment. The cathode is in the first compartment and the anode in the second compartment. The reservoir is disposed in the high pressure chamber for storing water to be supplied to the chamber of the electrolysis unit. In some implementations, the ion exchange structure is a proton exchange membrane.Type: ApplicationFiled: September 20, 2012Publication date: May 9, 2013Applicant: ENCITE LLCInventors: Stephen Alan Marsh, Donald Merrill Parker