Diaphragm Type Patents (Class 204/252)
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Patent number: 12195866Abstract: A plating membrane includes a support structure extending radially outward from a nozzle that is to direct a flow of a plating solution toward a wafer. The plating membrane also includes a frame, supported by the support structure, having an inner wall that is angled outward from the nozzle. The outward angle of the inner wall relative to the nozzle directs a flow of plating solution from the nozzle in a manner that increases uniformity of the flow of the plating solution toward the wafer, reduces the amount of plating solution that is redirected inward toward the center of the plating membrane, reduces plating material voids in trenches of the wafer (e.g., high aspect ratio trenches), and/or the like.Type: GrantFiled: July 28, 2023Date of Patent: January 14, 2025Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.Inventors: Yung-Hsiang Chen, Hung-San Lu, Ting-Ying Wu, Chuang Chihchous, Yu-Lung Yeh
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Patent number: 12176588Abstract: A reflective laminate for use in fuel cell manufacture. The reflective laminate includes a polymer sheet and a reflective substrate having a reflectivity greater than 6% at each wavelength from 400 nm to 1000 nm removably adhered to the polymer sheet. The polymer sheet can include a polymer electrolyte membrane such as a perfluorosulfonic acid resin reinforced with expanded porous polytetrafluoroethylene. The reflective substrate can include a metal substrate (e.g., aluminum). The reflective substrate can reflect a portion of electromagnetic radiation traversing the polymer sheet. The portion of electromagnetic radiation reflected by the reflective substrate can be used to determine a characteristic or property of the polymer sheet (e.g., a size of the polymer sheet, a thickness of the polymer sheet, or a defect of the polymer sheet). A catalyst electrode can be applied to opposite sides of the polymer sheet to form a membrane electrode assembly (“MEA”).Type: GrantFiled: March 9, 2017Date of Patent: December 24, 2024Inventor: Alexander Agapov
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Patent number: 12172909Abstract: A method of moderating concentration of at least highly fluorinated alkyl materials from a contaminated aqueous feed liquid containing an original composition of between 60 parts per trillion and 300 parts per billion of the at least highly fluorinated materials per liter of water into an aqueous electronic separator having at least three chambers including a feed chamber having a liquid exit port from which a mediated aqueous contaminated feed liquid exits and a liquid input port into which the contaminated aqueous feed liquid enters the feed chamber; an anodic electrode chamber filled with an aqueous anodic liquid; and a cathodic electrode chamber filled with an aqueous cathodic liquid; wherein the feed chamber is between and adjacent to the anodic electrode chamber and the cathodic electrode chamber and the feed chamber is separated from each of the anodic electrode chamber and the cathodic electrode chamber by at least one semipermeable membrane.Type: GrantFiled: November 3, 2020Date of Patent: December 24, 2024Inventors: Randall P. Moore, Kevin B. Jackson
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Patent number: 12166252Abstract: Disclosed are: a polymer electrolyte membrane which can guarantee the production of a membrane-electrode assembly having excellent mechanical properties without a decrease in performance, such as in ionic conductivity, and thus having a high enough durability to achieve at least 30,000 wet/dry cycles as measured according to the NEDO protocol; a membrane-electrode assembly including the polymer electrolyte membrane; and a method for measuring the durability of the membrane-electrode assembly. The polymer electrolyte membrane according to the present invention comprises a composite layer including: a porous support having multiple pores; and ionomers filling the pores, and has an MD internal tearing strength of 150 N/mm or greater, a TD internal tearing strength of 150 N/mm or greater, a stab initial strain of 8% or less, and a stab final strain of 10% or less.Type: GrantFiled: December 23, 2020Date of Patent: December 10, 2024Assignee: KOLON INDUSTRIES, INC.Inventors: Eunsu Lee, Donghoon Lee, Nayoung Kim, Junghwa Park, Hyesong Lee
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Patent number: 12134826Abstract: The present disclosure relates to an electrode for CO2 electroreduction in an acidic electrolyte comprising cation species, the electrode comprising: a substrate, a metal-based catalyst material, and a cation-augmenting material; wherein the cation-augmenting material comprises an acidic group exchanging protons with the cation species of the acidic electrolyte so as to increase a concentration of the cation species at a surface of the electrode.Type: GrantFiled: March 4, 2022Date of Patent: November 5, 2024Assignees: TOTALENERGIES ONETECH, THE GOVERNING COUNCIL OF THE UNIVERSITY OF TORONTOInventors: Jianan Erick Huang, Fengwang Li, Adnan Ozden, David Sinton, Edward Sargent
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Patent number: 12076691Abstract: In an embodiment, a method of concentrating a hydrogen isotope, comprises delivering a fluid comprising the hydrogen isotope to be concentrated and an additional gas other than then hydrogen isotope to an anode of an electrochemical cell comprising a hydron exchange membrane comprising hydrons of the hydrogen isotope, and also comprising said anode on a first side of the hydron exchange membrane, a cathode on a second side of the hydron exchange membrane, and an electrical circuit connection between the anode and the cathode; removing a first stream in fluid communication with the cathode, the first stream comprising concentrated hydrogen isotope; and removing a second stream in fluid communication with the anode, comprising the additional gas delivered to the anode depleted of the hydrogen isotope.Type: GrantFiled: January 6, 2023Date of Patent: September 3, 2024Assignee: SKYRE INC.Inventors: Daryl Ludlow, Gregory P. Hesler, Trent M. Molter
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Patent number: 12006578Abstract: An electrochemical oxygen pump moves or pumps oxygen molecules with a unique anion conducting layer comprising an anion conducting polymer. These pumps can either be used as high precision oxygen flow meters or as oxygen filters. The system can be plumbed to have air as the inlet and the pump will selectively pump oxygen out, offering another way to remove oxygen from the air, along with distillation or pressure swing absorption.Type: GrantFiled: March 12, 2018Date of Patent: June 11, 2024Assignee: FFI Ionix IP, Inc.Inventors: Bamdad Bahar, Zhefei Li, Richard Sherrer, Jacob Zerby
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Patent number: 11878279Abstract: Disclosed herein is a method for selectively reducing, using electrical energy, CO2 to formic acid, a catalyst for use in the method, and an electrochemical reduction system.Type: GrantFiled: June 8, 2022Date of Patent: January 23, 2024Assignee: JAPAN SCIENCE AND TECHNOLOGY AGENCYInventor: Osamu Ishitani
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Patent number: 11879178Abstract: An electrochemical device of an embodiment includes: an electrochemical cell including a first electrode having a first flow path, a second electrode having a second flow path, and a separating membrane sandwiched between the first electrode and the second electrode; a gas-liquid separation tank which is connected to the first flow path of the first electrode and to which a product produced at the first electrode and water permeating from the second electrode to the first electrode are sent at an operation time; and a water sealing pipe which is connected to a liquid portion of the gas-liquid separation tank, and to send water in the gas-liquid separation tank to the first flow path of the first electrode at a stop time.Type: GrantFiled: August 19, 2021Date of Patent: January 23, 2024Assignees: KABUSHIKI KAISHA TOSHIBA, TOSHIBA ENERGY SYSTEMS & SOLUTIONS CORPORATIONInventors: Norihiro Yoshinaga, Ryota Kitagawa, Shinichi Sekiguchi
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Patent number: 11757112Abstract: A humidifier has a plurality of humidifier modules that are clamped between end plates by tie rods and have a membrane that is permeable to water vapor, in which on both sides of the membrane there is respectively arranged a flow field frame having a multiplicity of webs defining a flow field. The tie rods are configured as hollow rods forming coolant tubes for a coolant to be led through. A fuel cell device and a motor vehicle having such a humidifier are also provided.Type: GrantFiled: June 28, 2019Date of Patent: September 12, 2023Assignees: Volkswagen AG, Audi AGInventors: Oliver Berger, Rune Staeck, Christian Lucas
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Patent number: 11733507Abstract: An optical device, wherein the optical device includes a dielectric layer over a mirror layer. The optical device further includes a plurality of plasmonic nanoparticles over the dielectric layer. Additionally, the optical device includes a protective layer over the plurality of plasmonic nanoparticles.Type: GrantFiled: February 19, 2020Date of Patent: August 22, 2023Assignee: Purdue Research FoundationInventors: Piotr Nyga, Alexander V. Kildishev, Sarah Nahar Chowdhury, Alexandra Boltasseva, Zhaxylyk Kudyshev, Vladimir M. Shalaev
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Patent number: 11725291Abstract: An environment control system utilizes oxygen and humidity control devices that are coupled with an enclosure to independently control the oxygen concentration and the humidity level within the enclosure. An oxygen depletion device may be an oxygen depletion electrolyzer cell that reacts with oxygen within the cell and produces water through electrochemical reactions. A desiccating device may be g, a dehumidification electrolyzer cell, a desiccator, a membrane desiccator or a condenser. A controller may control the amount of voltage and/or current provided to the oxygen depletion electrolyzer cell and therefore the rate of oxygen reduction and may control the amount of voltage and/or current provided to the dehumidification electrolyzer cell and therefore the rate of humidity reduction. The oxygen level may be determined by the measurement of voltage and a limiting current of the oxygen depletion electrolyzer cell. The enclosure may be a food or artifact enclosure.Type: GrantFiled: April 17, 2019Date of Patent: August 15, 2023Assignee: FFI IONIX IP, INC.Inventors: Bamdad Bahar, Jacob Zerby
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Patent number: 11715863Abstract: The present disclosure provides methods of preparing a solid-state polymer matrix electrolyte (PME) and methods for preparing a PME precursor solution for forming the PME for use in battery technologies.Type: GrantFiled: October 6, 2020Date of Patent: August 1, 2023Assignee: BRIGHTVOLT, INC.Inventors: Anaba Anani, Chananate Uthaisar, Joshua Wolfe, Han Wu, Huikang Wu, Wenbin Yin
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Patent number: 11697883Abstract: An electrolysis cell includes an anode chamber and a cathode chamber separated by an ion-exchange membrane. The electrolysis cell includes an anode, a cathode, and a cathode current distributor. The anode, the ion-exchange membrane, the cathode, and the cathode current distributor are in direct touching contact in the mentioned order. Flexibly resilient holding elements are arranged on the other side of the anode and/or on the other side of the cathode current distributor. The flexibly resilient holding elements exert a contact pressure on the anode and/or on the cathode current distributor. The flexibly resilient holding elements have annular elements, the axis of which is oriented in the height direction of the electrolysis cell. By means of the flexibly resilient and in part also plastically deforming annular elements, effective mechanical contact pressure of the ion-exchange membrane against the oxygen-depolarized cathode is achieved.Type: GrantFiled: June 29, 2022Date of Patent: July 11, 2023Assignee: THYSSENKRUPP NUCERA AG & CO. KGAAInventor: Sebastian Austenfeld
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Patent number: 11649551Abstract: The present disclosure discloses an asymmetric electrolyte membrane, a membrane electrode assembly including the same, a water electrolysis apparatus including the same and a method for manufacturing the same. More particularly, it discloses an asymmetric electrolyte membrane having a porous layer and a dense layer at the same time, a membrane electrode assembly including the same, a water electrolysis apparatus including the same and a method for manufacturing the same.Type: GrantFiled: September 30, 2020Date of Patent: May 16, 2023Assignee: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGYInventors: So Young Lee, Hyoung-Juhn Kim, Sae Yane Baek, Taekyung Lee, Sung Jong Yoo, Jong Hyun Jang, Hee-Young Park, Jin Young Kim, Hyun S. Park
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Patent number: 11592417Abstract: Flexible fuel cell sensors and methods of making and using the same are provided. A fuel cell sensor can be used for the detection of, for example, isopropyl alcohol (IPA), and the working mechanism of the fuel cell sensor can rely on redox reactions. The fuel cell sensor can include a proton exchange membrane (PEM), an anode disposed on a first surface of the PEM, a cathode disposed on a second surface of the PEM opposite from the first surface, and a reference electrode disposed on the first surface of the PEM and spaced apart from the anode.Type: GrantFiled: April 27, 2022Date of Patent: February 28, 2023Assignee: THE FLORIDA INTERNATIONAL UNIVERSITY BOARD OF TRUSTEESInventors: Ahmed Hasnain Jalal, Arif I. Sarwat
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Patent number: 11560632Abstract: A water electrolyzer comprises a membrane, a cathode and an anode. The membrane comprises a first membrane layer comprising a first ion-conductive polymer, a second membrane layer comprising a second ion-conductive polymer, and a platinized nanostructured layer disposed between the first layer and the second layer. The platinized nanostructured layer comprises close-packed whiskers having at least one of platinum or platinum oxide disposed thereon. The cathode is disposed on the membrane and comprises a first catalyst consisting essentially of both metallic Pt and Pt oxide. The anode is disposed on the opposite surface of the membrane and comprises a second catalyst comprising at least 95 percent by weight of collectively metallic Ir and Ir oxide, calculated as elemental Ir, based on the total weight of the second catalyst, wherein at least one of metallic Ir or Ir oxide is present. Membranes and methods of making them are also disclosed.Type: GrantFiled: September 27, 2019Date of Patent: January 24, 2023Assignee: 3M Innovative Properties CompanyInventors: Jiyoung Park, Krzysztof A. Lewinski, Sean M. Luopa, Andrew J. L. Steinbach
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Patent number: 11552296Abstract: There is provided an improved electrochemical energy storage device. The storage device includes using functionalized boron nitride nanoparticles as electroactive materials in the electrodes.Type: GrantFiled: March 13, 2020Date of Patent: January 10, 2023Assignee: BORON NITRIDE POWER LLCInventor: Karoly Nemeth
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Patent number: 11450857Abstract: A current collector for a lithium ion battery of reduced sensitivity to shocks and jars includes an insulating substrate, a first conductive layer; and at least one extended conductive layer extending from the first conductive layer. The insulating substrate has a main region and at least one tab region extending therefrom. The main region includes first and second surfaces opposing each other. The tab region includes a first extended surface extending from the first surface, and a second extended surface extending from the second surface. The first conductive layer covers the first surface, and the at least one extended conductive layer covers the first extended surface. Each tab region and extended conductive layer form a tab. The disclosure also provides an electrode plate and an electrode assembly.Type: GrantFiled: July 31, 2019Date of Patent: September 20, 2022Assignee: NINGDE AMPEREX TECHNOLOGY LIMITEDInventors: Hongmei Wei, Bin Wang, Li Xiang, Yi-Bo Zhang
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Patent number: 11434337Abstract: To provide an ion exchange membrane for alkali chloride electrolysis which has a low membrane resistance and which is capable of reducing the electrolysis voltage during the alkali chloride electrolysis, while increasing the membrane strength. An ion exchange membrane 1 for alkali chloride electrolysis wherein a reinforcing material 20 obtained by weaving with reinforcing yarns 22 and sacrificial yarns 24 is embedded in a fluoropolymer having ion exchange groups, the ion exchange membrane 1 comprises elution holes (28) formed by eluting at least a portion of a material of the sacrificial yarns 24, and in a cross section perpendicular to the length direction of the yarns, the total area (S) obtained by adding the cross-sectional area of an elution hole 28 and the cross-sectional area of a sacrificial yarn 24 remaining in the elution hole 28 is from 500 to 1,200 ?m2, and the number (n) of elution holes 28 between adjacent reinforcing yarns 22 is at least 10.Type: GrantFiled: July 19, 2017Date of Patent: September 6, 2022Assignee: AGC Inc.Inventors: Takayuki Kaneko, Hiromitsu Kusano, Yasushi Yamaki, Takuo Nishio
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Patent number: 11377510Abstract: The copolymer includes divalent units represented by formula —[CF2—CF2]—, divalent units represented by formula: (I), and one or more divalent units independently represented by formula: (II) When Z is hydrogen, the copolymer has an alpha transition temperature of up to 100 ?C. The copolymer has an —SO3Z equivalent weight in a range from 300 to 1400, and a variation of the copolymer in which —SO3Z is replaced with —SO2F has a melt flow index of up to 80 grams per ten minutes measured at a temperature of 265° C. and at a support weight of 5 kg. A catalyst ink or polymer electrolyte membrane including the copolymer are also provided.Type: GrantFiled: September 14, 2018Date of Patent: July 5, 2022Assignee: 3M Innovative Properties CompanyInventors: Lisa P. Chen, Gregg D. Dahlke, Denis Duchesne, Steven J. Hamrock, Klaus Hintzer, Markus E. Hirschberg, Arne Thaler, Tilman C. Zipplies
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Patent number: 11362382Abstract: A micro-battery is provided in which a metallic sealing layer is used to provide a hermetic seal between an anode side of the micro-battery and the cathode side of the micro-battery. In accordance with the present application, the metallic sealing layer is formed around a perimeter of each metallic anode structure located on the anode side and then the metallic sealing layer is bonded to a solderable metal layer of a wall structure present on the cathode side. The wall structure contains a cavity that exposes a metallic current collector structure, the cavity is filled with battery materials.Type: GrantFiled: January 26, 2017Date of Patent: June 14, 2022Assignee: International Business Machines CorporationInventors: Paul S. Andry, Bing Dang, John U. Knickerbocker, Yang Liu, Jae-Woong Nah, Adinath Narasgond, Bucknell C. Webb
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Patent number: 11286572Abstract: The preferred embodiment of the invention provides a gas generator comprising an ion membrane electrolytic cell and an atomized/volatile gas mixing tank. The ion membrane electrolytic cell comprises an ion exchange membrane, a cathode chamber and an anode chamber. An anode electrode is set in the anode chamber, and a cathode electrode is set in the cathode chamber. The ion exchange membrane is set between the anode chamber and the anode chamber. When water is electrolyzed by the ion membrane electrolytic cell, oxygen is generated by the anode electrode and hydrogen is generated by the cathode electrode. The atomized/volatile gas mixing tank coupled to the ion membrane electrolytic cell accepts the hydrogen generated from the ion membrane electrolytic cell and generates an atomized gas to mix with the hydrogen for generating a healthy gas.Type: GrantFiled: December 22, 2016Date of Patent: March 29, 2022Inventor: Hsin Yung Lin
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Patent number: 11283085Abstract: A fuel cell system component ink includes a fuel cell system component powder, a solvent including propylene carbonate (PC), and a binder including polypropylene carbonate (PPC).Type: GrantFiled: March 6, 2020Date of Patent: March 22, 2022Assignee: BLOOM ENERGY CORPORATIONInventors: Andres Leming, Olexa Stavila, Perry Scheetz, Lisa Adams
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Patent number: 11274376Abstract: A method of electroplating a metal foam includes placing a metal foam to be plated into an electroplating chamber with a plating material source, circulating an electrolyte through the chamber to carry metal ions from the plating material source, the circulating being selected and controlled to produce an even coating of plating material on surfaces of the metal foam.Type: GrantFiled: December 4, 2020Date of Patent: March 15, 2022Assignee: APOLLO ENERGY SYSTEMS, INC.Inventors: Robert R. Aronsson, Barry S. Iseard, Peter Kalal
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Patent number: 11276863Abstract: Disclosed is a gas diffusion layer for a fuel cell that may be made thinner by integrally forming a base and a fine pore layer, and a method for manufacturing the same. A gas diffusion layer for a fuel cell which constitutes a unit cell of the fuel cell includes: a base layer formed by impregnating a first slurry, in which carbon powder and polytetrafluoroethylene (PTFE) are mixed, in the interior of a carbon fiber base; and a fine pore layer formed by coating a second slurry, in which carbon powder and polytetrafluoroethylene (PTFE) are mixed and which has a viscosity that is higher than the viscosity of the first slurry, on a surface of the base layer.Type: GrantFiled: May 27, 2020Date of Patent: March 15, 2022Assignees: HYUNDAI MOTOR COMPANY, KIA MOTORS CORPORATIONInventors: Jae Man Park, Seung Tak Noh, Ji Han Lee
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Patent number: 11262313Abstract: A sulfur chemiluminescence detector 200 includes: a heating furnace including a gas passage having first and second supply ports, and a heater configured to heat the gas passage; an oxidation-reduction gas supply unit configured to supply, to the gas passage, an oxidizing-agent gas through the first supply port and a reducing-agent gas through the second supply port; a reaction cell configured to make a sample gas that has passed through the gas passage react with ozone; an ozone supply unit configured to supply the ozone into the reaction cell; a vacuum pump connected to the reaction cell; a photodetector configured to detect light generated inside the reaction cell; a signal receiving unit configured to receive a shutdown signal; and a shutdown functioning unit configured to control each unit to automatically stop supplying the reducing-agent gas and the oxidizing-agent gas by the oxidation-reduction gas supply unit, heating the gas passage by the heater, supplying the ozone by the ozone supply unit, and evType: GrantFiled: November 22, 2019Date of Patent: March 1, 2022Assignee: Shimadzu CorporationInventors: Masashi Yamane, Shigenobu Nakano
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Patent number: 11231374Abstract: A sulfur chemiluminescence detector 200 includes: a heating furnace including a gas passage having first and second supply ports, and a heater configured to heat the gas passage; an oxidation-reduction gas supply unit configured to supply, to the gas passage, an oxidizing-agent gas through the first supply port and a reducing-agent gas through the second supply port; a reaction cell configured to make a sample gas that has passed through the gas passage react with ozone; an ozone supply unit configured to supply the ozone into the reaction cell; a vacuum pump connected to the reaction cell; a photodetector configured to detect light generated inside the reaction cell; a signal receiving unit configured to receive a shutdown signal; and a shutdown functioning unit configured to control each unit to automatically stop supplying the reducing-agent gas and the oxidizing-agent gas by the oxidation-reduction gas supply unit, heating the gas passage by the heater, supplying the ozone by the ozone supply unit, and evType: GrantFiled: November 22, 2019Date of Patent: January 25, 2022Assignee: Shimadzu CorporationInventors: Masashi Yamane, Shigenobu Nakano
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Patent number: 11211671Abstract: Provided herein are a porous film, a separator including the same, an electrochemical device including the separator, and a method of preparing the porous film. The porous film includes first cellulose nanofibers which is impregnated with a carbonate-based solvent-containing electrolyte solution and has a reaction heat of 150 J/g or less at a temperature ranging from about 30° C. to about 300° C., as measured by differential scanning calorimetry (DSC).Type: GrantFiled: November 20, 2018Date of Patent: December 28, 2021Assignee: SAMSUNG ELECTRONICS CO., LTD.Inventors: Hyunchul Lee, Junhwan Ku, Hyeokjo Gwon, Nagjong Kim, Chilhee Chung, Sangmin Ji, Jinkyu Kang, Changduk Kang, Ryounghee Kim, Minsang Kim, Euncheol Do, Kitae Park, Sunghaeng Lee
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Patent number: 11201344Abstract: A method for manufacturing a membrane assembly for a fuel cell. To overcome a problem of chemical degradation at an edge of the membrane, the method comprises the following steps: positioning a first decal layer, which is made of the same material as a first catalyst layer, on a first side of the membrane, positioning a second decal layer, which is made of the same material as a second catalyst layer, on a second side of the membrane, pressing a compression pad, which is positioned on the first decal layer with the first decal layer and the second decal layer fully overlapping the compression pad, and the second decal layer against each other with the first decal layer and the membrane positioned in-between, whereby pressure on the first and the second decal layer is applied only in an area covered by the compression pad.Type: GrantFiled: March 9, 2020Date of Patent: December 14, 2021Assignees: Daimler AG, Ford Motor CompanyInventors: Sebastian Prass, Manpal Ghuman, Andrew Leow, Jennie Eastcott, Owen Thomas
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Patent number: 11135551Abstract: The present disclosure provides an ion-exchange membrane that includes a supporting substrate impregnated with an ion-exchange material. The supporting substrate includes an imprinted non-woven layer, and the imprinting includes a plurality of deformations at a surface density of at least 16 per cm2. The supporting substrate may lack a reinforcing layer. In some examples, the supporting substrate may include only a single layer of the imprinted non-woven fabric.Type: GrantFiled: March 20, 2017Date of Patent: October 5, 2021Assignee: BL TECHNOLOGIES, INC.Inventors: Yonghong Zhao, John H. Barber
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Patent number: 11125714Abstract: A potentiometric sensor having a measuring half cell with a conductor element, a reference half cell with a reference element, a measuring circuit connected with the conductor element of the measuring half cell and the reference element of the reference half cell and designed to create a measuring signal that is dependent on a potential difference between the conductor element and the reference element. The measuring half cell further includes a housing having a housing chamber closed off by a first ion-selective membrane and contacted by the conductor element, a first inner electrolyte contained within the housing chamber and contacting the ion-selective membrane. The conductor element includes an inner conductor, especially an inner conductor comprising a metallic conductor, connected with the measuring circuit and a gas-tight barrier separating the inner conductor from the first inner electrolyte.Type: GrantFiled: January 27, 2016Date of Patent: September 21, 2021Assignee: Endress+Hauser Conducta GmbH+Co. KGInventors: Stefan Wilke, Jens Vettermann, Jens Voigtlander, Magdalena Losik, Michael Hanko
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Patent number: 11114684Abstract: A membrane-electrode assembly for a fuel cell is provided. The membrane-electrode assembly includes a cathode electrode and an anode electrode which are positioned oppositely to each other; and a polymer electrolyte membrane positioned between the cathode electrode and the anode electrode. The cathode electrode and the anode electrode each includes an electrode substrate; a micropore layer which is positioned on the electrode substrate; and a first catalyst layer positioned on the micropore layer, at least one of a second catalyst layer is positioned between the first catalyst layer and the polymer electrolyte membrane, and the second catalyst layer includes a reaction inducing material which is a metal or alloy.Type: GrantFiled: April 28, 2017Date of Patent: September 7, 2021Inventor: Myoung-Ki Min
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Patent number: 11108071Abstract: The present invention relates to a method for producing a polymer electrolyte molded article, which comprises forming a polymer electrolyte precursor having a protective group and an ionic group, and deprotecting at least a portion of protective groups contained in the resulting molded article to obtain a polymer electrolyte molded article. According to the present invention, it is possible to obtain a polymer electrolyte material and a polymer electrolyte molded article, which are excellent in proton conductivity and are also excellent in fuel barrier properties, mechanical strength, physical durability, resistance to hot water, resistance to hot methanol, processability and chemical stability. A polymer electrolyte fuel cell using a polymer electrolyte membrane, polymer electrolyte parts or a membrane electrode assembly can achieve high output, high energy density and long-term durability.Type: GrantFiled: January 11, 2019Date of Patent: August 31, 2021Assignee: TORAY INDUSTRIES, INC.Inventors: Daisuke Izuhara, Hiroshi Taiko, Yuriko Okada, Shinya Adachi, Masataka Nakamura
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Patent number: 11105009Abstract: The present invention relates to a graphene material inlaid with single metal atoms, the preparation method thereof and its application of being used as the catalyst for the electroreduction of carbon dioxide. The graphene material inlaid with single metal atoms comprises single metal atoms and graphene; the single metal atoms are dispersed in the framework of the graphene; and the graphene is at least one selected from N doped graphene and N and S co-doped graphene. The material is used for the electrochemical reduction reaction of carbon dioxide, which significantly improves the utilization efficiency of the metal atoms and enhances the catalytic activity for the electroreduction of carbon dioxide, improves the catalytic stability, inhibits effectively the hydrogen evolution reaction, improves the selectivity for CO product, and broadens the electric potential window of reducing carbon dioxide to generate CO.Type: GrantFiled: December 20, 2017Date of Patent: August 31, 2021Assignee: DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCESInventors: Bin Liu, Hongbin Yang, Yanqiang Huang, Song Liu, Tao Zhang
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Patent number: 11028199Abstract: The invention provides a powder that is easily redispersible in a liquid medium such as water. The powder contains a fluoropolymer. The fluoropolymer contains at least one group A selected from the group consisting of —SO2Y, —COOR, —SO3X, —SO2NR12, and —COOX, wherein Y is a halogen atom; R is a C1-C4 alkyl group; X is M1/L or NR14, where M is a hydrogen atom or an L-valent metal, the L-valent metal being a metal in group 1, group 2, group 4, group 8, group 11, group 12, or group 13 of the periodic table; and R1s are each individually a hydrogen atom or a C1-C4 alkyl group. The powder exhibits a dispersion of 50% or higher. The dispersion is calculated by filtering a composition obtainable by mixing the powder with water through a mesh having an opening of 20 ?m.Type: GrantFiled: October 11, 2017Date of Patent: June 8, 2021Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Yuki Yotsumoto, Tadashi Ino, Kazuhiro Ohtsuka, Noriyuki Shinoki, Masaharu Nakazawa, Takashi Yoshimura, Masahiro Kondo
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Patent number: 10988559Abstract: The invention provides a powder that is easily redispersible in a liquid medium such as water. The powder contains a fluoropolymer. The fluoropolymer contains at least one group A selected from the group consisting of —SO2Y, —COOR, —SO3X, —SO2NR12, and —COOX, wherein Y is a halogen atom; R is a C1-C4 alkyl group; X is M1/L or NR14, where M is a hydrogen atom or an L-valent metal, the L-valent metal being a metal in group 1, group 2, group 4, group 8, group 11, group 12, or group 13 of the periodic table; and R1s are each individually a hydrogen atom or a C1-C4 alkyl group. The powder exhibits a dispersion of 50% or higher. The dispersion is calculated by filtering a composition obtainable by mixing the powder with water through a mesh having an opening of 20 ?m.Type: GrantFiled: October 11, 2017Date of Patent: April 27, 2021Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Yuki Yotsumoto, Tadashi Ino, Kazuhiro Ohtsuka, Noriyuki Shinoki, Masaharu Nakazawa, Takashi Yoshimura, Masahiro Kondo
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Patent number: 10988848Abstract: An electrolytic cell that prevents, or at least minimizes, damage to a membrane and reduces electrolytic voltage may include an elastic member attached to an electrolytic partition wall within an anode chamber and/or a cathode chamber. The elastic member comprises a spring retaining part and a bonding part that is bonded to the electrolytic partition wall, parallel first support parts extending from the bonding part away from the electrolytic partition wall, a second support part connecting the first support parts, and two parallel spring rows. Each spring row may include first flat spring-like bodies, which originate from the first support part and extend toward the opposite direction of the electrolytic partition wall, and second flat spring-like bodies, which originate from the second support part and extend toward the opposite direction of the electrolytic partition wall.Type: GrantFiled: June 13, 2017Date of Patent: April 27, 2021Assignee: THYSSENKRUPP UHDE CHLORINE ENGINEERS GMBHInventors: Koji Kawanishi, Takehiro Oiwa, Shinichiro Yamamoto, Masaki Watanabe
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Patent number: 10975483Abstract: The diaphragm for alkaline water electrolysis according to the present invention comprises a porous polymer membrane, the porous polymer membrane comprising a polymer resin and hydrophilic inorganic particles. A porosity of the porous polymer membrane is 30% or more and 60% or less, average pore sizes at both surfaces of the porous polymer membrane is 0.5 ?m or more and 2.0 ?m or less, and a ratio of a mode particle size of the hydrophilic inorganic particles to the average pore size of the porous polymer membrane (mode particle size/average pore size) is 2.0 or more.Type: GrantFiled: March 18, 2016Date of Patent: April 13, 2021Assignee: ASAHI KASEI KABUSHIKI KAISHAInventors: Yusuke Suzuki, Kenji Nakagawa, Hidefumi Takami, Norikazu Fujimoto
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Patent number: 10968124Abstract: A method for changing filler pollutant accumulation of a constructed wetland belongs to the field of environmental protection engineering. A coupling device of a microbial fuel cell and a constructed wetland is constructed by using active carbon as a constructed wetland filler, and pond sewage enters into the constructed wetland from the top of the device in an intermittent mode. A titanium mesh is taken as an electron collector for packaging a cathode of the active carbon filler by using the characteristic that electrons are collected by the titanium mesh in a concentrated mode, after stable operation for a period of time, active carbon close to a water surface and active carbon close to the bottom of the titanium mesh are taken out for carrying out specific surface area and biomass measurement, and the accumulation distribution condition of filler pollutants inside the constructed wetland is analyzed.Type: GrantFiled: November 11, 2019Date of Patent: April 6, 2021Assignee: Dalian University of TechnologyInventors: Qiao Yang, Minhui Liu, Chao Gao, Shengna Liang
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Patent number: 10961635Abstract: A light-weight composite material with enhanced structural characteristics includes, in one embodiment, a compositionally modulated nanolaminate coating electrically deposited into an open, accessible void structure of a porous substrate. As a result of including a nanolaminate within the void structure, the composite can include a greater amount of nanolaminate material per unit volume than can be achieved by depositing a nanolaminate material solely on a two-dimensional surface. In addition, the nanolaminate material as well as other material electrodeposited to form the composite is compositionally modulated so that discontinuities between layers are minimized and potentially eliminated. The light-weight but structurally enhanced composite material can be used in a number of different applications including, but not limited to, ballistic applications (e.g., armor panels or tank panels), automotive protection applications (e.g., car door panels, racing shells) and sporting equipment applications (e.g.Type: GrantFiled: July 15, 2015Date of Patent: March 30, 2021Assignee: MODUMETAL, INC.Inventor: John D. Whitaker
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Patent number: 10961134Abstract: The present disclosure is directed to a method of removing pesticides from water. An electrolysis cell oxidizes pesticides and/or other organic components, optionally in conjunction with one or more filtration steps. Hydrogen peroxide may be added to the electrolysis process to aid oxidation.Type: GrantFiled: March 15, 2019Date of Patent: March 30, 2021Assignee: INNOVATIVE WATER CARE, LLCInventors: Maurice Paul Tax, Jerome Logie
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Patent number: 10944099Abstract: A fluoride ion conductor contains potassium, at least one alkaline earth metal selected from the group consisting of calcium, barium, and strontium, and fluorine. The fluoride ion conductor includes a phase of a compound containing potassium, at least one alkaline earth metal, and fluorine.Type: GrantFiled: December 11, 2018Date of Patent: March 9, 2021Assignee: PANASONIC CORPORATIONInventor: Tomoyuki Komori
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Patent number: 10928354Abstract: Disclosed is an ammonia sensor element having a measured gas chamber, a reference gas chamber and a solid electrolyte body arranged therebetween. The solid electrolyte body has a first main surface facing the measured gas chamber and a second main surface facing the reference gas chamber. A detection electrode is formed on the first main surface. A reference electrode is formed on the second main surface. The solid electrolyte body contains a first proton conducting solid electrolyte. The detection electrode contains a second proton conducting solid electrolyte. The second proton conducting solid electrolyte has an acid strength greater than that of the first proton conducting solid electrolyte.Type: GrantFiled: December 22, 2017Date of Patent: February 23, 2021Assignee: DENSO CORPORATIONInventors: Toshihiko Harada, Shinya Teranishi, Satoshi Nakamura, Hiroaki Yoto
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Patent number: 10926253Abstract: To provide a process for producing an ion exchange membrane for electrolysis which has a low membrane resistance and which is capable of reducing the electrolysis voltage during the electrolysis, even if the membrane strength is increased, an ion exchange membrane for electrolysis, a precursor membrane of an ion exchange membrane for electrolysis, and an electrolysis apparatus.Type: GrantFiled: October 10, 2017Date of Patent: February 23, 2021Assignee: AGC Inc.Inventors: Takayuki Kaneko, Hiromitsu Kusano, Yasushi Yamaki, Takuo Nishio
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Patent number: 10889497Abstract: Provided is a sheet-shaped nitrogen-phosphorus co-doped porous carbon material, prepared and obtained according to the following method: mixing aniline and hexachlorocyclotriphosphazene, undergoing a closed reaction for 2-24 h at a pressure of 1-10 MPa and a temperature of 140-260° C., then pressure is released to atmospheric pressure and steam drying is performed to obtain a solid substance; under inert gas protection, the obtained solid substance is treated for 1-6 h at a high temperature of 400-1000° C., and the finished product is obtained; the sheet-shaped nitrogen-phosphorus co-doped porous carbon material thus provided has excellent electrical properties and may be used for fabricating capacitor electrodes and especially supercapacitor electrodes; thus it may be used in capacitors and especially supercapacitors, and has great application potential and industrial value in the field of energy storage.Type: GrantFiled: August 30, 2017Date of Patent: January 12, 2021Inventors: Huile Jin, Shun Wang, Meng Liu, Xiaochun Yu, Jichang Wang, Xiaomei Dong, Chao Yang, Cheng Feng
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Patent number: 10868324Abstract: The invention relates to flow batteries having improved crossover resistance to electroactive species, excellent coulombic and voltage efficiency and durability, which batteries comprise a separator membrane comprising an ionomer having a high equivalent weight, EW, to achieve these performance benefits. The ionomer has an EW of 1150 to 2000. Preferably, the ionomer is a perfluorosulfonic acid ionomer which has substantially all of the functional groups being represented by the formula —SO3X wherein X is H, Li, Na, K or N(R1)(R2)(R3)(R4) and R1, R2, R3, and R4 are the same or different and are H, CH3 or C2H5. Preferably, substantially all of the functional groups are represented by the formula —SO3X wherein X is H.Type: GrantFiled: December 17, 2013Date of Patent: December 15, 2020Assignee: THE CHEMOURS COMPANY FC, LLCInventors: Ralph Birchard Lloyd, Murat Unlu
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Patent number: 10865489Abstract: To provide an ion exchange membrane for alkali chloride electrolysis, which has low membrane resistance and which reduces the electrolysis voltage during alkali chloride electrolysis, even if the spacing between reinforcing yarns is made narrow to increase the membrane strength.Type: GrantFiled: January 26, 2017Date of Patent: December 15, 2020Assignee: AGC Inc.Inventors: Takayuki Kaneko, Hiromitsu Kusano, Yasushi Yamaki, Takuo Nishio
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Patent number: 10829605Abstract: Disclosed is a method for making a material having supported micro- and/or nanostructures, the method includes (a) obtaining a substrate comprising a precursor material and an electrically conductive layer of micro- or nanostructures embedded into at least a portion of a first surface of the substrate, and (b) applying a voltage across the electrically conductive layer to heat the micro- or nanostructures, wherein the heat converts the precursor material into micro- and/or nanostructures.Type: GrantFiled: June 28, 2016Date of Patent: November 10, 2020Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Ihab N. Odeh, Nitin Chopra, Saad Al-Hussain
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Patent number: RE49701Abstract: Synthetic materials that are useful as heterogeneous catalysts or electrocatalysts. The materials can be used to catalyze oxidation and/or reduction reactions and/or oxygen/hydrogen evolution/oxydation reactions.Type: GrantFiled: May 14, 2020Date of Patent: October 17, 2023Assignee: UNM Rainforest InnovationsInventors: Alexey Serov, Plamen Atanassov