With Feeding And/or Withdrawal Means Patents (Class 204/263)
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Patent number: 9809470Abstract: According to one embodiment, an electrolytic membrane separation (EMS) subsystem is configured to remove one or more impurities from a contaminated reject solution and to recycle the reusable reject solution for subsequent use in regenerating ion exchange resins. According to another embodiment of the invention, the EMS subsystem is configured to concentrate the impurities recovered from the contaminated brine solution for subsequent disposal or treatment.Type: GrantFiled: April 23, 2015Date of Patent: November 7, 2017Assignee: Exergy Technologies CorporationInventor: Fred P. Reinhard
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Patent number: 9804090Abstract: An energy store system, including at least one cell element situated in a cell region having an anode, a cathode and an electrolyte system that is situated between the anode and the cathode and that is particularly at least partially liquid, the anode, the cathode and/or the electrolyte system being configured so that, as a function of a charging or discharging process of the cell element, functioning material is situated in the electrolyte system, and the functional material situated in the electrolyte system being ascertainable qualitatively and/or quantitatively. Because of such an energy store system, operating states of an energy store or a cell may be ascertained particularly simply and accurately. Also described is a related state detection system.Type: GrantFiled: July 17, 2012Date of Patent: October 31, 2017Assignee: ROBERT BOSCH GMBHInventors: Marcus Wegner, Jens Grimminger, Martin Tenzer, Jean Fanous
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Patent number: 9803058Abstract: An ion exchange membrane (52) for a fuel cell comprises a polymer having an acid functional group normally including protons, and having alkali metal ions partially ion-exchanged with the protons of the acid functional group of the membrane. The partial ion exchange of alkali metal ions into the membrane relates either to patterning of the exchanged ion make-up of the membrane, with some being ion exchanged and some not, or to the extent or concentration of the ion exchange in any particular location, or to both.Type: GrantFiled: June 24, 2008Date of Patent: October 31, 2017Assignee: Audi AGInventors: Vishal Onkarmal Mittal, Lesia V. Protsailo, Sathya Motupally
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Patent number: 9764335Abstract: A system for extracting metals (e.g. precious metals or dangerous metals) from a substrate material such as sludge from a lake bed or sewage treatment facility includes processing the substrate material and metals by exposing the substrate material and metals to the plasma of an electric arc. Then, the exposed substrate material and metals are passed through an electrically charged collection grid in which the metals, now electrically charged, are attracted to the collection grid and hold to the collection grid and the substrate material exits the collection grid with less concentrations (or none) of the metals. In some embodiments, in addition to recovering the metals (e.g. precious metals, dangerous metals, etc.), a flammable gas is produced.Type: GrantFiled: May 4, 2015Date of Patent: September 19, 2017Assignee: MAGNEGAS CORPORATIONInventor: Ermanno Santilli
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Patent number: 9719178Abstract: An electrochemical cell for the continuous acidification of alkaline water sources and recovery of carbon dioxide with simultaneous continuous hydrogen gas production having a center compartment, an electrolyte-free anode compartment having a mesh anode in direct contact with an ion permeable membrane, an endblock in direct contact with the anode where the endblock provides a gas escape route behind the anode, an electrolyte-free cathode compartment having a mesh cathode in direct contact with an ion permeable membrane, and an endblock in direct contact with the cathode where the endblock provides a gas escape route behind the cathode. Current applied to the electrochemical cell for generating hydrogen gas also lowers the pH of the alkaline water to produce carbon dioxide with no additional current or power. Also disclosed is the related method for continuously acidifying alkaline water sources and recovering carbon dioxide with continuous hydrogen gas production.Type: GrantFiled: February 28, 2014Date of Patent: August 1, 2017Assignee: The United States of America, as represented by the Secretary of the NavyInventors: Felice DiMascio, Heather D. Willauer, Dennis R. Hardy, Frederick Williams, M. Kathleen Lewis
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Patent number: 9718711Abstract: Various aspects of the present disclosure are directed toward apparatus and methods method for filtering water fluid by screening ionic minerals including sodium chloride from the water fluid. In one embodiment, the water fluid is passed into a work zone defined at least in part by oppositely-arranged first and second porous structures, each of which have a plurality of gated channels. The water fluid is processed in the work zone by applying respective electric voltages to electrically bias the first porous structure and the second porous structure. The respective electric voltages deplete sodium chloride ions in the water fluid in the work zone due to ion-flux continuity. In response to processing of the water fluid, ion-filtered water is collected from the work zone.Type: GrantFiled: October 1, 2013Date of Patent: August 1, 2017Assignee: The Board of Trustees of the Leland Stanford Junior UniversityInventors: Kee-Hyun Paik, Yang Liu, Robert W. Dutton, Qiushi Ran
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Patent number: 9605352Abstract: Provided is a cation exchange membrane having excellent mechanical strength against folding and the like and capable of delivering stable electrolytic performance for a long time, an electrolysis vessel using the cation exchange membrane and a method for producing the cation exchange membrane. A cation exchange membrane 1 at least includes: a membrane body containing a fluorine-based polymer having an ion-exchange group; and two or more reinforcing core materials arranged approximately in parallel within the membrane body. The membrane body is provided with two or more elution holes 12 formed between the reinforcing core materials 10 adjacent to each other.Type: GrantFiled: September 3, 2014Date of Patent: March 28, 2017Assignee: ASAHI KASEI KABUSHIKI KAISHAInventors: Hiroyuki Kameyama, Manabu Sugimoto, Yoshifumi Kado
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Patent number: 9599373Abstract: A hydrogen storage heat pump, including: a hydrogen storage unit in which hydrogen gas is stored in a compressed state; a hydrogen flow tube through which the hydrogen gas, which is supplied from the hydrogen storage unit, flows; plural hydrogen absorbing materials that are provided at the hydrogen flow tube, that each have a different absorption pressure at which hydrogen is absorbed, and that are arranged in an order such that the absorption pressure decreases in a hydrogen gas flow direction from the hydrogen storage unit; and a switching valve that is disposed between the hydrogen absorbing materials in the hydrogen flow tube and that switches a flow rate of the hydrogen gas.Type: GrantFiled: March 13, 2015Date of Patent: March 21, 2017Assignee: KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHOInventors: Takafumi Yamauchi, Yasuki Hirota, Masakazu Aoki, Takashi Shimazu
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Patent number: 9551076Abstract: The electrochemical reactors disclosed herein provide novel oxidation and reduction chemistries and employ increased mass transport rates of materials to and from the surfaces of electrodes therein.Type: GrantFiled: May 31, 2012Date of Patent: January 24, 2017Assignee: Clean Chemistry, Inc.Inventor: Wayne Buschmann
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Patent number: 9493368Abstract: A method of precipitating scale from water includes providing an electrochemical cell. The electrochemical cell includes a primary cathode chamber including a first electrode therein, a primary anode chamber including a second electrode therein, and a cation exchange membrane separating the primary cathode chamber from the primary anode chamber. A flow of feed water is split into separate input flows to each of the primary cathode chamber and the primary anode chamber. The pH of the water in the primary anode chamber is reduced by electrolysis. The pH of water in the primary cathode chamber is increased by electrolysis, and cations are removed from the water in the primary cathode chamber by forming scale on the first electrode in the primary cathode chamber. Separate treated water output flows, from each of the primary cathode chamber and primary anode chamber, are combined into a combined conditioned water flow.Type: GrantFiled: May 2, 2013Date of Patent: November 15, 2016Assignee: TANGENT COMPANY LLCInventor: Lyle E. Kirman
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Patent number: 9404191Abstract: It is an object of the present invention to provide an anode for a zero-gap brine electrolyzer which through employment of a highly roughened surface at a catalyst layer at an anode for a zero-gap brine electrolyzer makes it possible to achieve sufficient liquid permeability and further reduction in electrolyzing voltage and a brine electrolysis method employing same. The present invention relates to an anode for a zero-gap brine electrolyzer equipped with a liquid-permeable conductive substrate 21, and with a catalyst layer 22 which is provided on the conductive substrate 21 and which is such that the maximum difference in height of surface irregularities is 55 ?m to 70 ?m; a zero-gap brine electrolyzer equipped with the anode 20, a cathode 30, and an ion-exchange membrane I disposed between and in contact with the anode 20 and the cathode 30; and a brine electrolysis method employing same.Type: GrantFiled: October 25, 2013Date of Patent: August 2, 2016Assignee: OSAKA SODA CO., LTD.Inventors: Kanefusa Hara, Satoshi Hatano
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Patent number: 9206517Abstract: The present invention concerns an anodic compartment for metal electrowinning cells delimited by a frame-shaped skeleton comprising an envelope including a permeable separator secured to said frame-shaped skeleton by means of a frame-shaped flange, at least one anode obtained starting from a valve metal substrate coated with at least one corrosion-resistant catalytic layer, said anode being inserted inside said envelope, and a demister located above said anode and delimited by said separator and said skeleton. The invention also concerns an electrochemical cell for metal electrowinning comprising at least one such anodic compartment.Type: GrantFiled: October 25, 2012Date of Patent: December 8, 2015Assignee: INDUSTRIE DE NORA S.P.A.Inventor: Giuseppe Faita
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Patent number: 9067087Abstract: An air revitalization apparatus and method simultaneously removes carbon dioxide, water vapor, and heat from air and produces oxygen gas, hydrogen gas, and concentrated carbon dioxide gas, does not require an explosion proof enclosure, and includes a fan configured to blow air into a first gas-liquid contactor, an electrochemical cell including first through fourth passages configured to emit hydrogen gas, permit a flow of a carbonate-hydroxide solution, permit a flow of carbonate-bicarbonate solution, and emit oxygen gas, respectively, the first and fourth passages separated by at least three gas-impermeable membranes, and a second gas-liquid contactor, where the first gas-liquid contactor, second passage, and a first pump are configured to circulate the carbonate-hydroxide solution therethrough, where the second gas-liquid contactor, third passage, and a second pump are configured to circulate the carbonate-bicarbonate solution therethrough, and where the output of the first passage is operationally coupledType: GrantFiled: August 30, 2013Date of Patent: June 30, 2015Assignee: OCEANEERING INTERNATIONAL, INC.Inventor: Gary Patrick Noyes
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Patent number: 9028764Abstract: An electro-catalytic honeycomb for controlling exhaust emissions, which adopts to purify a lean-burn exhaust, comprises a honeycomb structural body, a solid-oxide layer and a cathode layer. The honeycomb structural body includes an anode, a plurality of gas channels, and a shell. The anode is formed as a backbone, the gas channels are formed inside the backbone for passing the exhaust, and the shell covers an outer surface of the anode. The solid-oxide layer is adhered to an inner surface of the anode and connects the shell so as to encapsulate the anode. The cathode layer is adhered to a tube wall of the solid-oxide layer and has an oxidizing environment. The anode has a reducing environment. The reducing and the oxidizing environment facilitate an electromotive force to occur between the anode and the cathode layer to promote a decomposition of nitrogen oxides of the exhaust into nitrogen and oxygen.Type: GrantFiled: November 1, 2012Date of Patent: May 12, 2015Inventor: Ta-Jen Huang
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Publication number: 20150122668Abstract: A water conditioner that utilizes ionic flow and selective ionic filtering to control water hardness and/or pH. In some embodiments, the water conditioner includes one or more conditioning cells each having electrodes and a cathode side and an anode side separated by an ion-selective filter. The ion-selective filter is design/configured/selected to pass alkaline earth metal cations and block corresponding carbonate anions. When the electrodes are energized and water is present on the cathode and anode sides of the filter membrane, the alkaline earth metal cations pass from the anode side to the cathode side through the membrane, while the membrane blocks carbonate ions on the cathode side from passing to the anode side. In this manner, alkaline earth metal cations, and water hardness, can be reduced in the anode flow.Type: ApplicationFiled: October 30, 2014Publication date: May 7, 2015Inventor: Tadeusz Karabin
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Publication number: 20150122638Abstract: Apparatuses and methods are provided for depositing a metal layer on a wafer. A secondary weir is positioned at a region below the primary weir such that overflowed plating solution over the primary weir during electroplating flows in a substantially azimuthally uniform manner. Methods are provided for electroplating wafers by increasing flow rate between wafer processes while plating solution flows over a primary weir, remains in contact with the overflowing plating solution, and flows onto the secondary weir such that overflow is substantially azimuthally uniform.Type: ApplicationFiled: November 6, 2013Publication date: May 7, 2015Applicant: Lam Research CorporationInventors: Daniel Mark Dinneen, Jingbin Feng
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Patent number: 9017538Abstract: According to one embodiment, an electrolytic membrane separation (EMS) subsystem is configured to remove one or more impurities from a contaminated reject solution and to recycle the reusable reject solution for subsequent use in regenerating ion exchange resins. According to another embodiment of the invention, the EMS subsystem is configured to concentrate the impurities recovered from the contaminated brine solution for subsequent disposal or treatment.Type: GrantFiled: October 15, 2012Date of Patent: April 28, 2015Assignee: Exergy Technologies CorporationInventor: Fred P. Reinhard
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Patent number: 9011650Abstract: An electrochemical cell having a cation-conductive ceramic membrane and an acidic anolyte. Generally, the cell includes a catholyte compartment and an anolyte compartment that are separated by a cation-conductive membrane. While the catholyte compartment houses a primary cathode, the anolyte compartment houses an anode and a secondary cathode. In some cases, a current is passed through the electrodes to cause the secondary cathode to evolve hydrogen gas. In other cases, a current is passed between the electrodes to cause the secondary cathode to evolve hydroxyl ions and hydrogen gas. In still other cases, hydrogen peroxide is channeled between the secondary cathode and the membrane to form hydroxyl ions. In yet other cases, the cell includes a diffusion membrane disposed between the secondary cathode and the anode. In each of the aforementioned cases, the cell functions to maintain the pH of a fluid contacting the membrane at an acceptably high level.Type: GrantFiled: October 7, 2011Date of Patent: April 21, 2015Assignee: Ceramatec, IncInventors: Sai Bhavaraju, Ashok V. Joshi
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Publication number: 20150101935Abstract: An electroplating apparatus includes a container containing plural portions and an ionic liquid plating solution that is capable of flowing therebetween. The plural portions include at least a first portion containing a counter electrode that includes coating donor material and a second portion that includes a workpiece. A porous scrubber separating the first and second portions has a plurality of metallic outer surfaces in contact with the ionic liquid plating solution. Coating, repair, and regeneration methods using an ionic liquid plating solution are also described.Type: ApplicationFiled: October 9, 2014Publication date: April 16, 2015Inventor: Lei Chen
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Patent number: 9005411Abstract: An electrochemical compressor includes one or more electrochemical cells through which a working fluid flows, and an external electrical energy source electrically connected to the electrochemical cell. Each electrochemical cell includes an anode connected to the electrical energy source; a cathode connected to the electrical energy source; an ion exchange membrane disposed between and in electrical contact with the cathode and the anode to pass an electrochemically motive material of the working fluid from the anode to the cathode, the ion exchange membrane comprising polar ionic groups attached to nonpolar chains; and a non-aqueous solvent comprising polar molecules, the polar molecules of the non-aqueous solvent being associated with and electrostatically attracted to the polar ionic groups of the ion exchange membrane.Type: GrantFiled: January 11, 2013Date of Patent: April 14, 2015Assignee: Xergy IncInventors: Bamdad Bahar, Walther Grot, William Parmelee
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Patent number: 9005409Abstract: An electrochemical deposition apparatus adapted to deposit metal onto a surface of a substrate, the apparatus has a frame configured for holding a process electrolyte. A substrate holder is removably coupled to the frame, the substrate holder supporting the substrate in the process electrolyte. An anode fluid compartment is removably coupled to the frame and containing an anolyte and having an anode facing the surface of the substrate, the anode fluid compartment further having a ion exchange membrane disposed between the anode and the surface of the substrate, the anode fluid compartment removable from the frame as a unit with the ion exchange membrane and the anode. The holder, the anode and the membrane are arranged in the frame so that ions from the anode pass through the ion exchange membrane into and primarily replenish ions in the process electrolyte depleted by ion deposition onto the surface of the substrate.Type: GrantFiled: April 12, 2012Date of Patent: April 14, 2015Assignee: Tel Nexx, Inc.Inventors: David Guarnaccia, Arthur Keigler, Demetrius Papapanayiotou, Johannes Chiu
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Patent number: 9005410Abstract: A continuous electrolyzed oxidizing/reduction water generator device includes an electrically insulative housing which is an acid, alkali and pressure resistant box with a water inlet and multiple water outlets on opposing sides, positive and negative electrodes are mounted in the electrically insulative housing in parallel and equally spaced by a cation exchange membrane, and an electric control box to provide high voltage DC across the positive and negative electrodes to oxidize intake water into electrolyzed oxidizing/reduction water. Multiple generator units may be connected in series.Type: GrantFiled: August 21, 2012Date of Patent: April 14, 2015Inventor: Yun-Chi Hung
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Patent number: 8999120Abstract: An energy-saving ionized water production device and a production method are provided that are capable of producing strongly alkaline ionized in a short period of time.Type: GrantFiled: November 10, 2011Date of Patent: April 7, 2015Assignee: Kabushiki Kaisha Alone WorldInventors: Kazunori Osamura, Takao Kawajiri, Yutaka Nakamura, Noboru Kudo, Masae Shimizu
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Patent number: 8986518Abstract: The present aspects of an embodiment make more efficient use of hydrogen on-demand (hereinafter “HoD”) systems, thereby improving fossil-fuel-powered systems on the market. One main aspect uses a disposable cartridge in which the electrolytic process takes place to separate gas molecules from a solution that uses a substantially dry-cell design. Generally, the aspects include a replaceable and reusable cartridge for the flow of electrolyte solution using a pump, which may include a variety of safety features. A HoD cartridge generator has a plurality of staggered conductive material members that require electrolyte solution to flow between them, from one or more inlets to one or more outlets, using one or more specified paths. A conventional or specially-formulated electrolyte solution may be used. One or more sensors allow the generator to have a steady flow of solution in and a steady flow of liquid-gas mixture out of the system.Type: GrantFiled: January 18, 2012Date of Patent: March 24, 2015Assignee: Cleanworld Fuels, LLCInventor: Marc Daniel Moncion
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Publication number: 20150075999Abstract: Process and station for stabilizing an aqueous solution of an iron salt of an organic acid with a ferric component and a ferrous component of less solubility than the ferric component, such as the aqueous solution based on the Fe3+ salt of meso-tartaric acid. To stabilize the content of the dissolved ferric salt, the solution is at least partly subjected to electrolytic oxidation.Type: ApplicationFiled: March 27, 2013Publication date: March 19, 2015Inventors: Hans Lammers, Johannes Albertus Maria Meijer
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Publication number: 20150075976Abstract: An electroplating processor includes an electrode plate having a continuous flow path formed in a channel. The flow path may optionally be a coiled flow path. One or more electrodes are positioned in the channel. A membrane plate is attached to the electrode plate with a membrane in between them. Electrolyte moves through the flow path at a high velocity, preventing bubbles from sticking to the bottom surface of membrane. Any bubbles in the flow path are entrained in the fast moving electrolyte and carried away from the membrane. The electroplating processor may alternatively have a wire electrode extending through a tubular membrane formed into a coil or other shape, optionally including shapes having straight segments.Type: ApplicationFiled: November 25, 2014Publication date: March 19, 2015Inventors: Randy A. Harris, Daniel J. Woodruff, Jeffrey I. Turner, Gregory J. Wilson, Paul R. McHugh
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Publication number: 20150068911Abstract: A copper plating apparatus according to an embodiment includes a plating tank configured to have a copper member and a plating member being disposed in an interior of the plating tank, a blocking film configured to partition the interior of the plating tank into an anode chamber where the copper member is to be disposed and a cathode chamber where the plating member is to be disposed, the blocking film being configured to transmit copper ions and not transmit an additive agent, a supply unit configured to supply the additive agent to the anode chamber, and a power supply configured to apply a voltage between the copper member and the plating member.Type: ApplicationFiled: December 6, 2013Publication date: March 12, 2015Applicant: Kabushiki Kaisha ToshibaInventors: Fumitoshi IKEGAYA, Toshiyuki MORITA
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Patent number: 8968533Abstract: An electroplating processor includes an electrode plate having a continuous flow path formed in a channel. The flow path may optionally be a coiled flow path. One or more electrodes are positioned in the channel. A membrane plate is attached to the electrode plate with a membrane in between them. Electrolyte moves through the flow path at a high velocity, preventing bubbles from sticking to the bottom surface of membrane. Any bubbles in the flow path are entrained in the fast moving electrolyte and carried away from the membrane. The electroplating processor may alternatively have a wire electrode extending through a tubular membrane formed into a coil or other shape, optionally including shapes having straight segments.Type: GrantFiled: May 10, 2012Date of Patent: March 3, 2015Assignee: APPLIED Materials, IncInventors: Randy A. Harris, Daniel J. Woodruff, Jeffrey I. Turner, Gregory J. Wilson, Paul R. McHugh
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Publication number: 20150053571Abstract: Alkali metals and sulfur may be recovered from an oil desulfurization process which utilized alkali metal in an electrolytic process that utilizes an electrolytic cell having an alkali ion conductive membrane. An anolyte solution includes an alkali monosulfide, an alkali polysulfide, or a mixture thereof and a solvent that dissolves elemental sulfur. A catholyte includes molten alkali metal. Applying an electric current oxidizes sulfide and polysulfide in the anolyte compartment, causes alkali metal ions to pass through the alkali ion conductive membrane to the catholyte compartment, and reduces the alkali metal ions in the catholyte compartment. Liquid sulfur separates from the anolyte solution and may be recovered. The electrolytic cell is operated at a temperature where the formed alkali metal and sulfur are molten.Type: ApplicationFiled: November 5, 2014Publication date: February 26, 2015Inventors: John Howard Gordon, Javier Alvare
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Publication number: 20150021171Abstract: An electrolytic bath for manufacturing acidic water capable of ensuring sufficient conductivity through wide surfaces of electrodes and stability of the surfaces of the electrodes to electrolyze tap water as well as RO water or DI water, especially, by coupling electrodes having the same polarity as one to apply a power source to the electrodes having the same polarity at the same time without using an additional catalytic agent or ion exchange resin, and use of the acidic water are provided. In particular, an electrolytic bath for manufacturing acidic water capable of obtaining a high concentration of acidic water by further forming mesh electrodes having a polarity different from the plurality of electrodes on a surface of an ion exchange membrane to widen an area of the electrodes and minimize a distance between the electrodes, thereby further facilitating a redox reaction, and use of the acidic water are provided.Type: ApplicationFiled: August 19, 2013Publication date: January 22, 2015Applicant: SEEMS BIONICS INC.Inventors: Shin Gyo Yim, Jae Yong Lee
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Publication number: 20150014178Abstract: Provided are a film formation device and a film formation method for forming a metal film, with which metal films with a desired thickness can be continuously formed on surfaces of a plurality of substrates. A film formation device 1A includes at least a positive electrode 11, a negative electrode 12, a solid electrolyte membrane 13 arranged on a surface of the positive electrode 12, between. the positive electrode and a substrate to serve as the negative electrode, and a power supply unit E adapted to apply a voltage across the positive electrode 11 and the substrate B. A voltage is applied across the positive electrode 11 and the substrate B to deposit metal on a surface of the substrate from metal ions contained in the solid electrolyte membrane 13, whereby a metal film F made of metal is formed, The positive electrode 11 is made of a porous body that allows a solution L containing metal ions to pass therethrough and supplies the metal ions to the solid electrolyte membrane 13.Type: ApplicationFiled: February 21, 2013Publication date: January 15, 2015Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Motoki Hiraoka, Hiroshi Yanagimoto, Yuki Sato, Takayasu Yoshioka
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Publication number: 20150014175Abstract: An electroplating apparatus for plating a metal onto a surface of a wafer is disclosed. The apparatus comprises a wafer support configured to support a wafer and a processing base. The processing base has a scroll pump oriented to pump a plating solution in a substantially perpendicular direction with respect to the surface of the wafer. Further, the scroll pump includes a first scroll and a second scroll, at least one of which is configured as an anode. In one embodiment, the processing base includes an anolyte chamber including the scroll pump, a catholyte chamber, and a membrane separating the anolyte chamber from the catholyte chamber.Type: ApplicationFiled: July 9, 2013Publication date: January 15, 2015Inventor: Raymon F. Thompson
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Publication number: 20150008119Abstract: An electrochemical deposition system is described. The electrochemical deposition system includes one or more electrochemical deposition modules arranged on a common platform for depositing one or more metals on a substrate, and a chemical management system coupled to the one or more electrochemical deposition modules. The chemical management system is configured to supply at least one of the one or more electrochemical deposition modules with one or more metal constituents for depositing the one or more metals. The chemical management system can include at least one metal enrichment cell and at least one metal-concentrate generator cell.Type: ApplicationFiled: July 1, 2014Publication date: January 8, 2015Inventors: Demetrius Papapanayiotou, Arthur Keigler, Jonathan Hander, Johannes Chiu, David G. Guarnaccia, Daniel L. Goodman
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Publication number: 20140367248Abstract: Spacers arranged on opposite sides of an article to be processed into an EUV pellicle support the article. Plates on opposite ends of the spacer-article combination include respective electrodes. The plates, article, and spacers can be held together with a vacuum retention system. A center hole of each spacer forms a chamber with surfaces engaged by the spacer. A fluid entry extending from an outer surface of each spacer to its center hole allows delivery of fluid to each chamber. Additional spacers can be used to support additional articles. Additional plates and electrodes can also be used.Type: ApplicationFiled: June 13, 2013Publication date: December 18, 2014Inventor: Dario L. Goldfarb
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Publication number: 20140353164Abstract: Disclosed are a device for electrowinning europium and a method thereof. The device for electrowinning europium using a channeled cell including a cathode cell includes a channel having an inlet and an outlet; an anode cell including a channel having an inlet and an outlet; and an ion-exchange membrane tightly interposed between the cathode and anode cells, wherein reduced europium is exhausted from the outlet of the cathode cell.Type: ApplicationFiled: December 16, 2013Publication date: December 4, 2014Applicant: Korea Institute of Geoscience and Mineral ResourcesInventors: Kyeong-Woo Chung, Jin-Young Lee, Sung-Don Kim
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Patent number: 8894829Abstract: A water electrolysis apparatus is formed by stacking a plurality of unit cells. Each unit cell includes a membrane electrode assembly, and an anode separator and a cathode separator which sandwich the membrane electrode assembly therebetween. The anode separator has a plurality of inlet joint channels in fluid communication with a water supply passage, and a plurality of outlet joint channels in fluid communication with a discharge passage. The water supply passage has an inner wall surface at which the inlet joint channels are open, and an outer wall surface which faces the inner wall surface, the inner wall surface and the outer wall surface jointly forming an opening of an oblong cross-sectional shape.Type: GrantFiled: December 21, 2010Date of Patent: November 25, 2014Assignee: Honda Motor Co., Ltd.Inventors: Eiji Haryu, Masanori Okabe, Koji Nakazawa, Kenji Taruya
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Patent number: 8894830Abstract: A low-voltage, low-energy electrochemical system and method of removing protons and/or producing a base solution comprising hydroxide and carbonate/bicarbonate ions, utilizing carbon dioxide in a cathode compartment that is partitioned into a first cathode electrolyte compartment and a second cathode electrolyte compartment such that liquid flow between the cathode electrolyte compartments is possible, but wherein gaseous communication between the cathode electrolyte compartments is restricted. Carbon dioxide gas in one cathode electrolyte compartment is utilized with the cathode electrolyte in both compartments to produce the base solution with less that 3V applied across the electrodes.Type: GrantFiled: July 3, 2012Date of Patent: November 25, 2014Assignee: Celera CorporationInventors: Ryan J. Gilliam, Thomas A. Albrecht, Nikhil Jalani, Nigel Antony Knott, Valentin Decker, Michael Kostowskyj, Bryan Boggs, Alexander Gorer, Kasra Farsad
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Publication number: 20140311897Abstract: The present invention relates to a highly efficient sodium hypochlorite generation apparatus capable of decreasing disinfection by-products, which is a chlorine disinfection device for on-site generation and produces sodium hypochlorite solution by electrolyzing sodium chloride aqueous solution on site, thereby requiring no additional liquefied chlorine storage equipment or disaster prevention equipment and securing flexibility of installation and operation while not being regulated by a high-pressure gas safety control act.Type: ApplicationFiled: November 28, 2012Publication date: October 23, 2014Inventors: Boong Ik Jung, Jung Sik Kim, Hyun Su Shin, Sang Seek Bae, Kyung Lee, Young Jae Lee
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Publication number: 20140246328Abstract: An electrolyzer device comprises a container configured to receive liquid to be electrolyzed; a separator arranged in the container so as to define a first chamber and a second chamber positioned lower in a vertical direction than the first chamber; a cathode arranged in the first chamber and operatively connected to a power supply; and an anode arranged in the second chamber and operatively connected to the power supply.Type: ApplicationFiled: March 1, 2013Publication date: September 4, 2014Applicant: Osaka Electro-Communication UniversityInventors: Koichi Umimoto, Shunji Nagata
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Publication number: 20140246308Abstract: A three-compartment-cell one-port type electrolysis apparatus having a three-compartment-cell one-port structure which solves the problems of a one-compartment-cell type electrolytic bath and a two-compartment-cell type electrolytic bath, can generate high-purity electrolytic water having strong functionality by consuming only minute amounts of electrolyte, can generate various kinds of electrolyzed water using various electrolytes in a salt state, particularly provides oxidized water or reduced water having an optimized pH according to the various uses by selectively combining the oxidized water and the reduced water, and minimizes the consumption of water.Type: ApplicationFiled: October 11, 2012Publication date: September 4, 2014Inventor: Dong Won Lim
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Patent number: 8815075Abstract: A water electrolysis system includes a water electrolysis apparatus for electrically decomposing water to generate oxygen and high-pressure hydrogen having a pressure higher than the oxygen, a gas-liquid separator connected to a hydrogen pipe which discharges the high-pressure hydrogen from the water electrolysis apparatus, for separating water contained in the high-pressure hydrogen, a high-pressure hydrogen outlet pipe for delivering the high-pressure hydrogen separated from water from the gas-liquid separator, a water drainage line for discharging the water from the gas-liquid separator, and a gas depressurizing line connected to the gas-liquid separator, for degassing the gas-liquid separator before the water is discharged from the water drainage line into the water drainage line.Type: GrantFiled: April 3, 2012Date of Patent: August 26, 2014Assignee: Honda Motor Co., Ltd.Inventors: Jun Takeuchi, Koji Nakazawa, Hisashi Nagaoka, Tetsuya Yoshida, Masanori Okabe, Daisuke Kurashina, Aoi Miyake
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Patent number: 8808512Abstract: An apparatus for the electrolytic splitting of water into hydrogen and oxygen gases is disclosed. The apparatus comprises: (i) a first hemi-enclosure; (ii) a second hemi-enclosure; (iii) a diaphragm electrode array positioned between the first hemi-enclosure and the second hemi-enclosure comprising: (a) a diaphragm, that passes ions and impedes the passage of gases, comprising a first side and a second opposed side; (b) a first plurality of electrodes in a first vicinity of the first side of the diaphragm; and (c) a second plurality of electrodes in a second vicinity of the second opposed side of the diaphragm; (iv) a fastener, for leak-tight fastening of the first hemi-enclosure, the diaphragm electrode array, and the second hemi-enclosure, whereby a leak-tight enclosure is formed; (v) contacts, for electrically powering the first and second pluralities of electrodes, and; (vi) pathways, configured to remove hydrogen and oxygen gases from the enclosure.Type: GrantFiled: January 22, 2013Date of Patent: August 19, 2014Assignee: GTA, Inc.Inventor: Elias Greenbaum
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Publication number: 20140224668Abstract: A method for operating an electrolytic cell for electrolytic water splitting in which at least one membrane is supplied with water in a passive manner.Type: ApplicationFiled: January 23, 2014Publication date: August 14, 2014Applicant: Astrium GmbHInventors: Walter JEHLE, Joachim LUCAS, Willigert RAATSCHEN
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Patent number: 8801912Abstract: Disclosed is a method for a repeated electroplating of a workpiece to be plated as a cathode by using an insoluble anode in a plating vessel accommodating a copper sulfate plating bath, wherein a copper dissolution vessel different from the plating vessel is provided, the plating bath is transferred to the copper dissolution vessel and is returned from the copper dissolution vessel to the plating vessel for circulating the plating bath between the plating vessel and the copper dissolution vessel, copper ion supplying salt is charged into the copper dissolution vessel and dissolved in the plating bath so that copper ions consumed by the plating can be replenished, and the workpiece to be plated is continuously electroplated, characterized in that the plating bath is permitted to transfer between the anode side and the cathode side, and the plating bath is returned to vicinity of the anode in the return of the plating bath from the copper dissolution vessel to the plating vessel.Type: GrantFiled: March 10, 2009Date of Patent: August 12, 2014Assignee: C. Uyemura & Co., Ltd.Inventors: Naoyuki Omura, Toshihisa Isono, Koji Shimizu, Shinji Tachibana, Tomohiro Kawase, Shunsaku Hoshi
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Patent number: 8795482Abstract: Methods and apparatus are provided for planar metal plating on a workpiece having a surface with recessed regions and exposed surface regions; comprising the steps of: causing a plating accelerator to become attached to said surface including the recessed and exposed surface regions; selectively removing the plating accelerator from the exposed surface regions without performing substantial metal plating on the surface; and after removal of plating accelerator is at least partially complete, plating metal onto the surface, whereby the plating accelerator remaining attached to the surface increases the rate of metal plating in the recessed regions relative to the rate of metal plating in the exposed surface regions.Type: GrantFiled: August 10, 2012Date of Patent: August 5, 2014Assignee: Novellus Systems, Inc.Inventors: Steven T. Mayer, Marshall R. Stowell, John S. Drewery, Richard S. Hill, Timothy M. Archer, Avishai Kepten
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Publication number: 20140202849Abstract: An electrolyzed water processor chamber with an anodic chamber having an anode plate held in an anode tray, and a cathodic chamber having a cathode plate held within a cathode tray. The plates are charged by an electrical current, to separate an incoming water stream into its electromagnetically ionized alkaline and acidic components, across an ion exchange membrane sandwiched between the anode and cathode plate trays. The trays can include sets of ducts and cavities, so that when the trays are stacked together, with the cavities aligning to form plenums for the routing of water between the trays. The trays stack as modular units, so that any multiple of the anodic and cathodic tray pairs, with their plates and sandwiched membrane, can be stacked together and function as a combined processor chamber, with end caps mounted on the top-most and bottom-most plate trays.Type: ApplicationFiled: January 23, 2013Publication date: July 24, 2014Inventor: Carl Halterman
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Publication number: 20140202871Abstract: A system (10) for generating a chlorine-containing compound includes an anodic chamber (12), a cathodic chamber (20), and a brine chamber (30). The anodic chamber (12) includes an anodic electrode (14) and the cathodic chamber (20) includes a cathodic electrode (22). A membrane (28) separates the anodic and cathodic chambers (12), (20). The brine chamber (30) includes an anodic electrode (32) and a cathodic electrode (34). Concentration and type of the chlorine-containing compound can be selectively and consistently controlled by the system (10) in real time.Type: ApplicationFiled: June 8, 2012Publication date: July 24, 2014Inventor: Michael Lumetta
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Patent number: 8784619Abstract: A portable, on-demand hydrogen generation system is provided for producing hydrogen and injecting the hydrogen as a fuel supplement into the air intake of internal combustion engines, more particularly to vehicles. Hydrogen and oxygen is produced with a fuel cell at low temperatures and pressure from water in a supply tank. The hydrogen and oxygen is passed back thru the supply tank for distribution and water preservation. The gases are kept separate by a divider in the tank and the water level in the tank. In the case of gasoline engines, the hydrogen is directed to the air intake of the engine while the oxygen is vented to the atmosphere. The device is optionally powered by the vehicle battery, a stand alone battery, waste heat of the internal combustion engine or solar energy. The system utilizes a vacuum switch or other engine sensor that permits power to the device and therefore hydrogen production only when the engine is in operation.Type: GrantFiled: March 15, 2013Date of Patent: July 22, 2014Assignee: HNO Green Fuels, Inc.Inventor: Donald W Owens
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Patent number: 8784620Abstract: Described is a method for improving the operation of an electrolytic cell having an anolyte compartment, a catholyte compartment and a synthetic diaphragm separating the compartments, wherein liquid anolyte is introduced into the anolyte compartment and flows through the diaphragm into the catholyte compartment, which method involves introducing particulate material comprising halocarbon polymer short fiber, e.g., fluorocarbon polymer short fiber, into the anolyte compartment in amounts sufficient to lower the flow of liquid anolyte through the diaphragm into the catholyte compartment. In the case of an electrolytic cell wherein aqueous alkali metal chloride, e.g.Type: GrantFiled: May 10, 2011Date of Patent: July 22, 2014Assignee: Axiall Ohio, Inc.Inventors: Henry W. Schussler, David R. Bush, Craig R. Long
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Publication number: 20140197040Abstract: Alkali metals and sulfur may be recovered from alkali monosulfide and polysulfides in an electrolytic process that utilizes an electrolytic cell having an alkali ion conductive membrane. An anolyte solution includes an alkali monosulfide, an alkali polysulfide, or a mixture thereof and a solvent that dissolves elemental sulfur. A catholyte includes molten alkali metal. Applying an electric current oxidizes sulfide and polysulfide in the anolyte compartment, causes alkali metal ions to pass through the alkali ion conductive membrane to the catholyte compartment, and reduces the alkali metal ions in the catholyte compartment. Liquid sulfur separates from the anolyte solution and may be recovered. The electrolytic cell is operated at a temperature where the formed alkali metal and sulfur are molten.Type: ApplicationFiled: March 14, 2014Publication date: July 17, 2014Applicant: Ceramatec, Inc.Inventors: John Howard Gordon, Javier Alvare