Phosphorus, Boron Or Nitrogen Containing Catalyst Patents (Class 208/114)
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Patent number: 11306263Abstract: A process for upgrading a heavy oil includes passing heavy oil and disulfide oil to a thermal cracking system that includes a thermal cracking unit and a cracker effluent separation system downstream of the thermal cracking unit and thermally cracking at least a portion of the heavy oil in the presence of the disulfide oil in the thermal cracking unit to produce solid coke and a cracking effluent comprising reaction products. The reaction products include one or more liquid reaction products, one or more gaseous reaction products, or both. The presence of the disulfide oil in the thermal cracking unit promotes conversion of hydrocarbons from the heavy oil to the liquid reaction products, the gaseous reaction products, or both relative to the production of the solid coke.Type: GrantFiled: February 4, 2021Date of Patent: April 19, 2022Assignee: Saudi Arabian Oil CompanyInventors: Ki-Hyouk Choi, Mazin M. Fathi, Maddala Venkata Bhanumurthy, Abdullah M. Salma, Faisal M. Almulla, Ali M. Alsomali, Young-Kyoung Ahn
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Patent number: 11299680Abstract: A process is provided for the catalytic cracking of a glyceride oil feedstock with a catalyst composition containing a phosphorus-containing ZSM-5 light olefins additive.Type: GrantFiled: June 24, 2021Date of Patent: April 12, 2022Assignee: CHEVRON U.S.A. INC.Inventors: Mingting Xu, Tengfei Liu, Richard L. Grove, Michael K. Maholland
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Patent number: 10927314Abstract: An integrated process to convert crude oil into petrochemical products includes distilling crude oil to produce gases fraction, naphtha, kerosene, gasoil and resid; subjecting resid to resid upgrading to produce LPG, light-distillate and middle-distillate; subjecting at least a portion of one or more of the group consisting of middle-distillate produced by resid upgrading, kerosene and gasoil to middle-distillate hydrocracking to produce LPG, light-distillate and hydrowax; and subjecting at least a portion of one or more of the group consisting of light-distillate produced by resid upgrading, light-distillate produced by middle-distillate hydrocracking and hydrowax to steam cracking. A process installation for performing the process is also provided.Type: GrantFiled: January 27, 2017Date of Patent: February 23, 2021Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Andrew Mark Ward, Arno Johannes Maria Oprins, Egidius Jacoba Maria Schaerlaeckens, Raul Velasco Pelaez
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Patent number: 10799855Abstract: A catalytic additive comprising an intermediate pore zeolite, such as ZSM-5 is treated so as to improve propylene yields when the additive is included in a FCC catalytic inventory by first treating the zeolite with a phosphorus compound to incorporate the phosphorus in the zeolite, and mixing the P-treated zeolite with a matrix component comprising kaolin and another phosphorus-containing compound.Type: GrantFiled: January 23, 2014Date of Patent: October 13, 2020Assignee: BASF CorporationInventors: Xingtao Gao, David Hamilton Harris
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Patent number: 10744200Abstract: The present invention relates to an improved process for production of Aluminium phosphate (AlPhos) gel wherein the solutions of aluminium salt and alkaline phosphate salt are added to water by maintaining the pH under stirring to obtain the precipitate, followed by sterilization of the said precipitate and finally obtaining the Aluminum phosphate gel.Type: GrantFiled: June 13, 2016Date of Patent: August 18, 2020Assignee: BIOLOGICAL E LIMITEDInventors: Ravi Ganapathy, Nagireddy Gade, Manish Manohar, Vikram Madhusadan Paradkar, Mahima Datla
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Patent number: 10676369Abstract: Provided is a production method by which an AEI zeolite is obtained without inducing a structural transformation in a crystalline aluminosilicate having a Y-structure and without using fluorine or phosphorus, the method including a crystallization step of crystallizing a composition containing an alumina source, a silica source, a structure directing aunt, a sodium source, and water, a weight proportion of crystalline aluminosilicate relative to a total weight of the alumina source and the silica source being from 0 wt. % to 10 wt. %, and the crystallization step satisfying at least one of the following conditions: a molar ratio of hydroxide ion to silica in the composition is 0.45 or greater, the composition contains a cation represented by (CH3)3RN+ (R represents an alkyl group having from 1 to 4 carbons, and the alkyl group may contain at least one substituent), and the crystallization time is 80 hours or longer.Type: GrantFiled: July 12, 2019Date of Patent: June 9, 2020Assignee: TOSOH CORPORATIONInventors: Tomoya Ishikawa, Hidekazu Aoyama, Takayoshi Mishima
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Patent number: 10619109Abstract: A process that catalytically converts olefinic (Alkenes, typically liquid at standard temperature and pressure) material in thermally cracked streams to meet olefin content specifications for crude oil transport pipelines. A thermally cracked stream or portion of a thermally cracked stream is selectively reacted to reduce the olefin content within a reactor operating at specific, controlled conditions in the presence of a catalyst and the absence of supplemental hydrogen. The process catalyst is comprised of a blend of select catalyzing metals supported on an alumina, silica or shape selective zeolite substrate together with appropriate pore acidic components.Type: GrantFiled: May 16, 2017Date of Patent: April 14, 2020Inventors: Tom Corscadden, Darius Remesat, Frank David Guffey, Shunlan Liu, Greg Diduch
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Patent number: 10577545Abstract: A process and catalyst is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products using multifunctional catalysts. Multifunctional catalysts enable use of less expensive metal by substituting expensive metals for less expensive metals with no loss or superior performance in slurry hydrocracking. Less available and expensive ISM can be replaced effectively.Type: GrantFiled: October 27, 2017Date of Patent: March 3, 2020Assignee: UOP LLCInventors: Phuong T. M. Do, Alakananda Bhattacharyya, Beckay J. Mezza, Stephen C. Houdek
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Patent number: 10519078Abstract: Methods of producing propylene and/or ethylene. The methods can include contacting a mixture of C4+ compounds with a catalyst, such as a fixed bed catalyst, that includes a phosphorus treated zeolite. The mixture of C4+ compounds can include a plurality of C4 olefins, a plurality of C5 olefins, and/or a plurality of C6+ olefins.Type: GrantFiled: October 19, 2018Date of Patent: December 31, 2019Assignee: Lyondell Chemical Technology, L.P.Inventor: Linn Fang
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Patent number: 10486109Abstract: A separation membrane structure comprises a porous support, a first separation membrane formed on the porous support, and a second separation membrane formed on the first separation membrane. The first separation membrane has an average pore diameter of greater than or equal to 0.32 nm and less than or equal to 0.44 nm. The second separation membrane includes addition of at least one of a metal cation or a metal complex that tends to adsorb nitrogen in comparison to methane.Type: GrantFiled: June 30, 2017Date of Patent: November 26, 2019Assignee: NGK Insulators, Ltd.Inventor: Kenichi Noda
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Patent number: 10478783Abstract: A separation membrane structure comprises a porous support, and a separation membrane formed on the porous support. The separation membrane has an average pore diameter of greater than or equal to 0.32 nm and less than or equal to 0.44 nm. The separation membrane includes addition of at least one of a metal cation or a metal complex that tends to adsorb nitrogen in comparison to methane.Type: GrantFiled: June 30, 2017Date of Patent: November 19, 2019Assignee: NGK Insulators, Ltd.Inventor: Kenichi Noda
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Patent number: 10258973Abstract: A catalyst washcoat is provided having a molecular sieve with a CHA crystal structure; about 0.5 to about 5.0 mol % phosphorus; and SiO2 and Al2O3 in a mole ratio of about 5 to about 40. The washcoat includes one or more promoters or stabilizers, and may be applied to a monolith substrate to produce a catalytically active article.Type: GrantFiled: January 29, 2018Date of Patent: April 16, 2019Assignee: Johnson Matthey Public Limited CompanyInventors: John L. Casci, Hai-Ying Chen, Joseph Michael Fedeyko, Jillian Elaine Collier, Raj Rao Rajaram, David Thompsett, Robert P. Hodgkins
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Patent number: 10252249Abstract: The present invention relates to a composition of attrition resistant attrition resistant catalyst particularly for FCC catalyst additives such as ZSM-5, bottom cracking additive/residue upgradation additive and GSR additive comprising aluminum phosphate binder wherein said binder comprising of 1.5 to 2.9 moles equivalent of monobasic acid for each mole of mono-aluminum phosphate (MAP). Further, the aluminum phosphate binder is added to the catalyst additive to ensure effective binding of catalyst as well as preserving catalyst activity with high selectivity towards light olefins including LPG.Type: GrantFiled: August 15, 2016Date of Patent: April 9, 2019Assignee: INDIAN OIL CORPORATION LIMITEDInventors: Mohan Prabhu Kuvettu, Mahesh Kadgaonkar, Biswanath Sarkar, Arumugam Velayutham Karthikeyani, Balaiah Swamy, Mani Karthikeyan, Jayaraj Christopher, Brijesh Kumar
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Patent number: 10179741Abstract: A process for the post-treatment of a zeolitic material having a BEA framework structure, the process comprising (i) providing a zeolitic material having a BEA framework structure, wherein the framework structure of the zeolitic material comprises X2O3 and YO2, wherein Y is a tetravalent element and X is a trivalent element and wherein the molar ratio X2O3:YO2 is greater than 0.02:1; (ii) treating the zeolitic material provided in (i) with a liquid solvent system thereby obtaining a zeolitic material having a molar ratio X2O3:YO2 of at most 0.02:1, and at least partially separating the zeolitic material from the liquid solvent system; (iii) treating the zeolitic material obtained from (ii) with a liquid aqueous system having a pH in the range of 5.5 to 8 and a temperature of at least 75° C.Type: GrantFiled: October 9, 2013Date of Patent: January 15, 2019Assignee: BASF SEInventors: Andrei-Nicolae Parvulescu, Jeff Yang, Stefan Maurer, Manuela Gaab, Karsten Seidel, Olga Gerlach, Ulrich Mueller
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Patent number: 10052610Abstract: Na+-SAPO-34 sorbents were ion-exchanged with several individual metal cations for CO2 absorption at different temperatures (273-348 K) and pressures (<1 atm). In general, the overall adsorption performance of the exchanged materials increased as follows: Ce3+<Ti3+<Mg2+<Ca2+<Ag+<Na+<Sr2+. The strontium exchanged materials excelled at low-pressure ranges, exhibiting very sharp isotherms slopes at all temperatures. The Sr2+ species were responsible for the surface strong interaction and the cations were occupying exposed sites (SII?) in the materials Chabazite cages. All the sorbent materials exhibited higher affinity for CO2 over the other gases tested (i.e., CH4, H2, N2 and O2) due to strong ion-quadrupole interactions. Sr2+-SAPO-34 sorbents are by far the best option for CO2 removal from CH4 mixtures, especially at low concentrations.Type: GrantFiled: December 15, 2008Date of Patent: August 21, 2018Assignee: University of Puerto RicoInventors: Arturo J Hernandez-Maldonado, Milton E Rivera-Ramos, Ana G Arevalo-Hidalgo
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Patent number: 9840625Abstract: Anticorrosive coating compositions as disclosed comprise a binding polymer and an aluminum phosphate corrosion inhibiting pigment dispersed therein. The coating composition comprises up to 25 percent by weight aluminum phosphate. The binding polymer can include solvent-borne polymers, water-borne polymers, solventless polymers, and combinations thereof. The aluminum phosphate is made by sol gel process of combining an aluminum salt with phosphoric acid and a base material. Aluminum phosphate colloidal particles are nanometer sized, and aggregate to form substantially spherical particles. The coating composition provides a controlled delivery of phosphate anions of 100 to 1,500 ppm, depending on post-formation treatment of the aluminum phosphate, and has a total solubles content of less than 1500 ppm, The amorphous aluminum phosphate is free of alkali metals and alkaline earth metals, and has a water adsorption potential of up to about 25 percent by weight water when present in a cured film.Type: GrantFiled: April 14, 2015Date of Patent: December 12, 2017Assignee: Bunge Amorphic Solutions LLCInventor: Raymond E. Foscante
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Patent number: 9744526Abstract: A SAPO-34 molecular sieve and method for preparing the same, whose chemical composition in the anhydrous state is expressed as: mSDA.(SixAlyPz)O2, wherein m is 0.08-0.3, x is 0.01-0.60, y is 0.2-0.60, z is 0.2-0.60, and x+y+z=1. The template agent SDA is in micropores of the molecular sieve. SDA is an organic amine with the structural formula (CH3)2NRN(CH3)2, wherein R is a saturated straight-chain or branched-chain alkylene group with having from 2-5 carbon atoms. There is a slight Si enrichment phenomenon on the crystal surface of the molecular sieve crystal, and the ratio of the surface Si content to the bulk Si content of the crystal ranges from 1.50-1.01. Said SAPO-34 molecular sieve, after being calcined at a temperature range from 400-700° C. in air, can be used as a gas adsorbent and catalyst for an acid-catalyzed reaction or oxygenate to olefin reaction.Type: GrantFiled: September 26, 2012Date of Patent: August 29, 2017Assignee: DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCESInventors: Peng Tian, Zhongmin Liu, Dong Fan, Xiong Su, Ying Zhang, Yue Yang
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Patent number: 9623364Abstract: Na+-SAPO-34 sorbents were ion-exchanged with several individual metal cations for CO2 absorption at different temperatures (273-348 K) and pressures (<1 atm). In general, the overall adsorption performance of the exchanged materials increased as follows: Ce3+<Ti3+<Mg2+<Ca2+<Ag+<Na+<Sr2+. The strontium exchanged materials excelled at low-pressure ranges, exhibiting very sharp isotherms slopes at all temperatures. The Sr2+ species were responsible for the surface strong interaction and the cations were occupying exposed sites (SII?) in the materials Chabazite cages. All the sorbent materials exhibited higher affinity for CO2 over the other gases tested (i.e., CH4, H2, N2 and O2) due to strong ion-quadrupole interactions. Sr2+-SAPO-34 sorbents are by far the best option for CO2 removal from CH4 mixtures, especially at low concentrations.Type: GrantFiled: August 24, 2016Date of Patent: April 18, 2017Assignee: University of Puerto RicoInventors: Arturo J Hernandez-Maldonado, Milton E Rivera-Ramos, Ana G Arevalo-Hidalgo
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Patent number: 9579637Abstract: The present invention relates to a SAPO-34 molecular sieve having both micropores and mesopores and synthesis method thereof. The mesopore diameter in the molecular sieve is in a range of 2-10 nm and the mesopore volume thereof is 0.03-0.3 cm3/g. Triethylamine is used as a template agent and the pore size modifiers are added to the synthesis gel at the same time in the synthesis process, thereby the prepared molecular sieve crystals have mesopore distribution besides micropores. The SAPO-34 molecular sieve synthesized in the present invention can be used as catalysts for conversion of oxygen-containing compounds to lower olefins.Type: GrantFiled: June 21, 2013Date of Patent: February 28, 2017Assignee: Dalian Institute of Chemical Physics, Chinese Academy of SciencesInventors: Lei Xu, Peng Tian, Zhongmin Liu, Lixin Yang, Shuanghe Meng, Changqing He, Cuiyu Yuan, Yue Qi
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Patent number: 9562203Abstract: The disclosure provides a gasification process for the production of a methane-rich syngas at temperatures exceeding 400° C. through the use of an alkali hydroxide MOH, using a gasification mixture comprised of at least 0.25 moles and less than 2 moles of water for each mole of carbon, and at least 0.15 moles and less than 2 moles of alkali hydroxide MOH for each mole of carbon. These relative amounts allow the production of a methane-rich syngas at temperatures exceeding 400° C. by enabling a series of reactions which generate H2 and CH4, and mitigate the reforming of methane. The process provides a methane-rich syngas comprised of roughly 20% (dry molar percentage) CH4 at temperatures above 400° C., and may effectively operate within an IGFC cycle at reactor temperatures between 400-900° C. and pressures in excess of 10 atmospheres.Type: GrantFiled: November 26, 2014Date of Patent: February 7, 2017Assignee: U.S. Department of EnergyInventors: Nicholas S. Siefert, Dushyant Shekhawat, David A. Berry, Wayne A. Surdoval
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Patent number: 9534177Abstract: Process for the preparation of a catalyst comprising the steps of (a) preparing a slurry comprising clay, zeolite, and quasi-crystalline boehmite, provided that the slurry does not comprise peptized quasi-crystalline boehmite, (b) adding a monovalent acid to the slurry, (c) adding a silicon source to the slurry, and (d) shaping the slurry to form particles. This process leads to a catalyst with high accessibility and high attrition resistance.Type: GrantFiled: June 29, 2011Date of Patent: January 3, 2017Assignee: Albemarle Netherlands, B.V.Inventor: Scott Michael Babitz
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Patent number: 9492817Abstract: The physical and chemical properties of Faujasite Y-type zeolites (FAU), mainly used as a base material of catalyst used in the Fluid Catalytic Cracking (FCC) process, are modified by contact with a short-chain polyol and mixture with an ammonium salt followed by thermal treatment to produce a modified Faujasite Y-type zeolite with sodium content as low as 75% below that of the starting Faujasite Y-type zeolite. The modified Faujasite Y-type zeolite is dispersed in a mesoporous material having an average pore size ranging from 2 to 100 nm.Type: GrantFiled: May 13, 2011Date of Patent: November 15, 2016Assignee: INSTITUTO MEXICANO DEL PETROLEOInventors: Héctor Armendáriz Herrera, María de Lourdes Alejandra Guzmán Castillo, Francisco Javier Hernández Beltrán, Patricia Pérez Romo, Jaime Sánchez Valente, José Marie Maurice Julien Fripiat
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Patent number: 9067196Abstract: The present invention relates to a Fluid Catalytic Cracking (FCC) additive preparation process and composition, which has high efficiency in the production of light olefins C2, C3 and C4 hydrocarbons, specifically propylene. The present invention discloses the stabilization of medium pore zeolite specifically ZSM-5 using optimum phosphate salts at a pH in the range 7-9 with synergetic combination of silica rich binder to produce FCC additive having excellent stability under severe hydrothermal conditions.Type: GrantFiled: September 13, 2011Date of Patent: June 30, 2015Assignee: RELIANCE INDUSTRIES LIMITEDInventors: Gopal Ravichandran, Praveen Kumar Chinthala, Tejas Doshi, Arun Kumar, Amit Gohel, Sukumar Mandal, Asit Kumar Das, Srikanta Dinda, Amit Kumar Parekh
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Patent number: 8911614Abstract: A new family of crystalline microporous metallophosphates designated AlPO-59 has been synthesized. These metallophosphates are represented by the empirical formula R+rMm2+EPxSiyOz where R is an organoammonium cation such as the ETMA+, M is a framework metal alkaline earth or transition metal of valence 2+, and E is a trivalent framework element such as aluminum or gallium. The AlPO-59 compositions are characterized by a new unique ABC-6 net structure and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes, and separation properties for separating at least one component.Type: GrantFiled: June 29, 2012Date of Patent: December 16, 2014Assignee: UOP LLCInventors: Gregory J. Lewis, Lisa M. Knight, Paulina Jakubczak, Justin E. Stanczyk
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Patent number: 8906225Abstract: A new family of crystalline microporous metallophosphates designated AlPO-57 has been synthesized. These metallophosphates are represented by the empirical formula R+rMmn+EPxSiyOz where R is an organoammonium cation such as the DEDMA+, M is a divalent framework metal such as an alkaline earth or transition metal, and E is a framework element such as aluminum or gallium. The microporous AlPO-57 compositions are characterized by a new unique ABC-6 net structure and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.Type: GrantFiled: June 29, 2012Date of Patent: December 9, 2014Assignee: UOP LLCInventors: Gregory J. Lewis, Lisa M. Knight, Paulina Jakubczak, Justin E. Stanczyk
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Patent number: 8900445Abstract: A process for the catalytic conversion of hydrocarbons to convert petroleum hydrocarbons in a higher yield for light olefins, particularly propylene is disclosed, the process involving a hydrocarbon-converting catalyst comprising zeolite, phosphorous and a transition metal, as defined herein.Type: GrantFiled: September 28, 2006Date of Patent: December 2, 2014Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, SinopecInventors: Chaogang Xie, Genquan Zhu, Yihua Yang, Yibin Luo, Jun Long, Xingtian Shu, Jiushun Zhang
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Patent number: 8895796Abstract: Described herein are processes and related devices and systems for the conversion of higher hydrocarbons, such as in the form of waste plastics, petroleum sludge, slope oil, vegetable oil, and so forth, into lower hydrocarbons, which can be used as fuels or raw materials for a variety of industrial and domestic uses.Type: GrantFiled: June 18, 2010Date of Patent: November 25, 2014Assignee: Innovative Energy Solutions, Inc.Inventors: Atul G. Kelkar, Prasad V. Bhat
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Publication number: 20140299511Abstract: The present invention provides a modified Y-type molecular sieve, characterized by having a unit cell size of 2.420-2.440 nm; as percent by weight of the modified Y-type molecular sieve, a phosphorus content of 0.05-6%, a RE2O3 content of 0.03-10%, and an alumina content of less than 22%; and a specific hydroxyl nest concentration of less than 0.35 mmol/g and more than 0.05 mmol/g, said ? ? specific ? ? hydroxyl ? ? nest ? ? concentration = [ ( M 500 ? ° ? ? C . - M 200 ? ° ? ? C . ) - ( 17 / 9 ) × ( M 800 ? ° ? ? C . - M 500 ? ° ? ? C . ) ] × 1000 36 × ( 1 - M 200 ? ° ? ? C . ) × C ? ( Unit ? : ? mmol ? / ? g ) wherein M200° C., M500° C. and M800° C. respectively represent the weight loss percents of a sample measured at 200° C., 500° C. and 800° C., and C is the crystallinity of the sample. The modified Y-type molecular sieve has few defect in the crystal lattice.Type: ApplicationFiled: October 26, 2012Publication date: October 9, 2014Applicant: CHINA PETROLEUM & CHEMICAL CORPORATIONInventors: Yibin Luo, Li Zhuang, Minggang Li, Ying Ouyang, Xingtian Shu
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Publication number: 20140206919Abstract: A new family of crystalline microporous metallophosphates designated AlPO-67 has been synthesized. These metallophosphates are represented by the empirical formula R+rMm2+EPxSiyOz where R is an organoammonium cation such as the ETMA+ or DEDMA+, M is a framework metal alkaline earth or transition metal of valence 2+, and E is a trivalent framework element such as aluminum or gallium. The AlPO-67 compositions have the LEV topology and have catalytic properties for carrying out various hydrocarbon conversion processes, and separation properties for separating at least one component.Type: ApplicationFiled: March 25, 2014Publication date: July 24, 2014Applicant: UOP LLCInventors: Gregory J. Lewis, Lisa M. Knight, Paulina Jakubczak, Justin E. Stanczyk
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Publication number: 20140206918Abstract: A new family of crystalline microporous silicometallophosphates designated MAPSO-64 and modified forms thereof have been synthesized. These silicometallophosphates are represented by the empirical formula R+rMm2+EPxSiyOz where R is an organoammonium cation such as ETMA+ or DEDMA+, M is an alkaline earth or transition metal cation of valence 2+, and E is a trivalent framework element such as aluminum or gallium. The MAPSO-64 compositions are characterized by a BPH framework topology and have catalytic properties for carrying out various hydrocarbon conversion processes, and separation properties for separating at least one component.Type: ApplicationFiled: March 25, 2014Publication date: July 24, 2014Applicant: UOP LLCInventors: Gregory J. Lewis, Lisa M. Knight, Paulina Jakubczak, Justin E. Stanczyk
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Patent number: 8658024Abstract: The invention discloses a catalyst and a method for cracking hydrocarbons. The catalyst comprises, calculated by dry basis, 10˜65 wt % ZSM-5 zeolite, 0˜60 wt % clay, 15˜60 wt % inorganic oxide binder, 0.5˜15 wt % one or more metal additives selected from the metals of Group VIIIB and 2˜25 wt % P additive, in which the metal additive is calculated by metal oxide and the P additive is calculated by P2O5. The method for cracking hydrocarbons using this catalyst increases the yield of FCC liquefied petroleum gas (LPG) and the octane number of FCC gasoline, as well as it increases the concentration of propylene in LPG dramatically.Type: GrantFiled: August 2, 2012Date of Patent: February 25, 2014Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, SinopecInventors: Jun Long, Wenbin Jiang, Mingde Xu, Huiping Tian, Yibin Luo, Xingtian Shu, Jiushun Zhang, Beiyan Chen, Haitao Song
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Patent number: 8633128Abstract: The invention describes a heteropolycompound constituted by a nickel salt of a lacunary Keggin type heteropolyanion comprising tungsten in its structure, with formula: Nix+y/2AW11-yO39-5/2y, zH2O wherein Ni is nickel, A is selected from phosphorus, silicon and boron, W is tungsten, O is oxygen, y=0 or 2, x=3.5 if A is phosphorus, x=4 if A is silicon, x=4.5 if A is boron, and x=m/2+2 for the rest, and z is a number in the range 0 to 36, in which said heteropolycompound has no nickel atom in substitution for a tungsten atom in its structure, said nickel atoms being placed in the counter-ion position in the structure of said compound.Type: GrantFiled: July 29, 2009Date of Patent: January 21, 2014Assignee: IFP Energies NouvellesInventors: Audrey Bonduelle, Fabrice Bertoncini, Karima Ben Tayeb, Carole Lamonier, Michel Fournier, Edmond Payen
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Publication number: 20140005452Abstract: A new family of crystalline microporous metallophosphates designated AlPO-59 has been synthesized. These metallophosphates are represented by the empirical formula R+rMm2+EPxSiyOz where R is an organoammonium cation such as the ETMA+, M is a framework metal alkaline earth or transition metal of valence 2+, and E is a trivalent framework element such as aluminum or gallium. The AlPO-59 compositions are characterized by a new unique ABC-6 net structure and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes, and separation properties for separating at least one component.Type: ApplicationFiled: June 29, 2012Publication date: January 2, 2014Applicant: UOP LLCInventors: Gregory J. Lewis, Lisa M. Knight, Paulina Jakubczak, Justin E. Stanczyk
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Patent number: 8617513Abstract: One aspect of the present invention relates to mesostructured zeolites. The invention also relates to a method of preparing mesostructured zeolites, as well as using them as cracking catalysts for organic compounds and degradation catalysts for polymers.Type: GrantFiled: July 20, 2009Date of Patent: December 31, 2013Assignee: Massachusetts Institute of TechnologyInventors: Jackie Y. Ying, Javier García-Martínez
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Publication number: 20120292230Abstract: The invention discloses a catalyst and a method for cracking hydrocarbons. The catalyst comprises, calculated by dry basis, 10˜65 wt % ZSM-5 zeolite, 0˜60 wt % clay, 15˜60 wt % inorganic oxide binder, 0.5˜15 wt % one or more metal additives selected from the metals of Group VIIIB and 2˜25 wt % P additive, in which the metal additive is calculated by metal oxide and the P additive is calculated by P2O5. The method for cracking hydrocarbons using this catalyst increases the yield of FCC liquefied petroleum gas (LPG) and the octane number of FCC gasoline, as well as it increases the concentration of propylene in LPG dramatically.Type: ApplicationFiled: August 2, 2012Publication date: November 22, 2012Applicants: Research Institute of Petroleum Processing, Sinopec, CHINA PETROLEUM & CHEMICAL CORPORATIONInventors: Jun Long, Wenbin Jiang, Mingde Xu, Huiping Tian, Yibin Luo, Xingtian Shu, Jishun Zhang, Beiyan Chen, Haitao Song
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Publication number: 20120222991Abstract: Novel catalytic compositions for cracking of crude oil fractions are disclosed. The catalytic compositions comprise a basic material. When used in a cracking process, preferably a FCC process, the resulting LCO and HCO fractions have desirably low aromatics levels. Further disclosed is a one-stage FCC process using the catalytic composition of the invention. Also disclosed is a two-stage FCC process for maximizing the LCO yield.Type: ApplicationFiled: April 2, 2012Publication date: September 6, 2012Applicant: ALBEMARLE NETHERLANDS B.V.Inventors: PAUL O'CONNOR, KING YEN YUNG, AVELINO CORMA CANOS, ELBERT ARJAN DE GRAAF, ERJA PÄIVI HELENA RAUTIAINEN
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Publication number: 20120132563Abstract: Solid acid nanoparticles are added to crude oil before initial distillation in order to increase the yield of light hydrocarbons obtained during initial distillation. According to one aspect, nanoparticles of a solid acid of a characteristic particle size are added to crude oil before initial distillation in order to increase the yield of light hydrocarbons obtained during initial distillation. According to another aspect, nanoparticles of a solid acid are added to crude oil in a characteristic concentration before initial distillation in order to increase the yield of light hydrocarbons obtained during initial distillation. According to another aspect, nanoparticles of two or more solid acids are mixed and added to crude oil before initial distillation in order to increase the yield of light hydrocarbons obtained during initial distillation.Type: ApplicationFiled: November 29, 2010Publication date: May 31, 2012Inventors: Oleksander S. Tov, Petro E. Stryzhak
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Patent number: 8128806Abstract: The present invention relates to a process and equipment for fluid catalytic cracking for the production of middle distillates of low aromaticity that comprises cracking a mixed feed consisting of heavy fractions of hydrocarbons, in the absence of added hydrogen and employing a catalyst of low activity and low acidity, in a dense-bed FCC reactor to produce an effluent constituted of fractions of middle distillates and naphtha of low aromaticity.Type: GrantFiled: January 23, 2009Date of Patent: March 6, 2012Assignee: Petroleo Brasileiro S.A.—PetrobrasInventors: Claudia Maria de Lacerda Alvarenga Baptista, Edisson Morgado Junior, William Richard Gilbert
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Patent number: 8110092Abstract: Disclosed is a process for recovery power from an FCC product. Gaseous hydrocarbon product from an FCC reactor is heat exchanged with a heat exchange media which is delivered to an expander to generate power. Cycle oil from product fractionation may be added to the gaseous FCC product to wash away coke precursors.Type: GrantFiled: August 23, 2010Date of Patent: February 7, 2012Assignee: UOP LLCInventor: John A. Petri
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Publication number: 20110230691Abstract: The invention describes a heteropolycompound constituted by a nickel salt of a lacunary Keggin type heteropolyanion comprising tungsten in its structure, with formula: Nix+y/2AW11-yO39-5/2y,zH2O wherein Ni is nickel, A is selected from phosphorus, silicon and boron, W is tungsten, O is oxygen, y=0 or 2, x=3.5 if A is phosphorus, x=4 if A is silicon, x=4.5 if A is boron, and x=m/2+2 for the rest, and z is a number in the range 0 to 36, in which said heteropolycompound has no nickel atom in substitution for a tungsten atom in its structure, said nickel atoms being placed in the counter-ion position in the structure of said compound.Type: ApplicationFiled: July 29, 2009Publication date: September 22, 2011Inventors: Audrey Bonduelle, Fabrice Bertoncini, Karima Ben Tayeb, Carole Lamonier, Michel Fournier, Edmond Payen
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Patent number: 7973209Abstract: Processing schemes and arrangements for the catalytic cracking of a heavy hydrocarbon feedstock and obtaining light olefins substantially free of carbon dioxide via amine treatment and employing fractionation processing are provided.Type: GrantFiled: September 28, 2006Date of Patent: July 5, 2011Assignee: UOP LLCInventors: Gavin P. Towler, John P. Brady, William J. Lechnick, Michael A. Schultz
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Patent number: 7973208Abstract: A catalyst for converting methanol to light olefins and the process for making and using the catalyst are disclosed and claimed. SAPO-34 is a specific catalyst that benefits from its preparation in accordance with this invention. A seed material is used in making the catalyst that has a higher content of the EL metal than is found in the principal part of the catalyst. The molecular sieve has predominantly a roughly rectangular parallelepiped morphology crystal structure with a lower fault density and a better selectivity for light olefins.Type: GrantFiled: April 28, 2009Date of Patent: July 5, 2011Assignee: UOP LLCInventors: Wharton Sinkler, Robert W. Broach, Natasha Erdman, Thomas M. Reynolds, John Q. Chen, Stephen T. Wilson, Paul T. Barger
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Patent number: 7879224Abstract: The present invention concerns doped catalysts on an alumino-silicate support with an adapted macropore content and hydrocracking/hydroconversion and hydrotreatment processes employing them. The catalyst comprises at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table, a controlled quantity of phosphorus (optionally in combination with boron and/or silicon) as a doping element, and a non-zeolitic support based on alumina-silica containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2).Type: GrantFiled: September 20, 2005Date of Patent: February 1, 2011Assignee: IFP Energies NouvellesInventors: Patrick Euzen, Alexandra Chaumonnot, Magalie Roy-Auberger, Patrick Bourges, Tivadar Cseri, Maryline Delage, Nathalie Lett
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Patent number: 7863494Abstract: Provided are a catalyst for hydrocarbon steam cracking for light olefin production and a method for preparing the same. The catalyst is a simple KMgPO4 catalyst, a supported KMgPO4 catalyst, or a KMgPO4-sintered catalyst. The supported KMgPO4 catalyst is prepared by impregnating a carrier with an aqueous solution of a KMgPO4 precursor and the KMgPO4-sintered catalyst is prepared by mixing a KMgPO4 powder or a KMgPO4 precursor powder with metal oxide followed by sintering. Provided is also a method for producing light olefins such as ethylene and propylene by steam cracking in the presence of the catalyst. When the catalyst comprising KMgSO4 as a catalytic component is used in olefin production, the yield of olefins is increased and the amount of cokes deposited on the catalyst is reduced.Type: GrantFiled: May 7, 2004Date of Patent: January 4, 2011Assignees: LG Chem, Ltd., LG Petrochemical Co., Ltd.Inventors: Jun-han Kang, Won-ho Lee, Sang-mun Jeong, Sang-ku Park, Jong-hyun Chae
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Patent number: 7737317Abstract: Processing schemes and arrangements are provided for the processing a heavy hydrocarbon feedstock via hydrocarbon cracking processing with selected hydrocarbon fractions being obtained via fractionation-based product recovery.Type: GrantFiled: September 28, 2006Date of Patent: June 15, 2010Assignee: UOP LLC.Inventors: Michael A. Schultz, Jason T. Corradi
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Patent number: 7718840Abstract: Disclosed is a process for producing light olefins from hydrocarbon feedstock. The process is characterized in that a porous molecular sieve catalyst consisting of a product obtained by evaporating water from a raw material mixture comprising a molecular sieve with a framework of Si—OH—Al— groups, a water-insoluble metal salt, and a phosphate compound, is used to produce light olefins, particularly ethylene and propylene, from hydrocarbon, while maintaining excellent selectivity to light olefins. According to the process, by the use of a specific catalyst with hydrothermal stability, light olefins can be selectively produced in high yield with high selectivity from hydrocarbon feedstock, particularly full-range naphtha. In particular, the process can maintain higher cracking activity than the reaction temperature required in the prior thermal cracking process for the production of light olefins, and thus, can produce light olefins with high selectivity and conversion from hydrocarbon feedstock.Type: GrantFiled: June 27, 2006Date of Patent: May 18, 2010Assignees: SK Energy Co., Ltd., Korea Research Institute of Chemical TechnologyInventors: Sun Choi, Yong Seung Kim, Deuk Soo Park, Suk Joon Kim, Il Mo Yang, Hee Young Kim, Yong Ki Park, Chul Wee Lee, Won Choon Choi, Kwang An Ko, Na Young Kang
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Patent number: 7691767Abstract: Provided are a catalyst which inhibits light paraffins form being produced in catalytic cracking of heavy hydrocarbons and which effectively produces olefins and a process in which the above catalyst is used to produce olefins from heavy hydrocarbons at a high yield. The catalyst is a catalytic cracking catalyst for catalytically cracking a hydrocarbon raw material, comprising (A) pentasil type zeolite modified with a rare earth element and zirconium and (B) faujasite type zeolite, and the process is a production process for olefin and a fuel oil, comprising bringing a heavy oil containing 50 mass % or more of a hydrocarbon fraction having a boiling point of 180° C. or higher into contact with the catalyst described above to crack it.Type: GrantFiled: January 17, 2007Date of Patent: April 6, 2010Assignees: Research Association of Refinery Integration for Group-Operation, Idemitsu Kosan Co., Ltd.Inventors: Kenichi Wakui, Kinsho Furusawa, Akio Suwa, Toshio Itoh, Hisao Nagashima
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Patent number: 7686945Abstract: Process to prepare a water-white lubricating base oil having a saturates content of more than 90 wt %, a sulphur content of less than 0.03 wt % and a viscosity index of between 80-120 by subjecting a non-water-white hydrocarbon feed having a lower saturates content than the desired saturates content to a hydrogenation step, the hydrogenation step comprising contacting the feed with hydrogen in the presence of a hydrogenation catalyst, wherein the contacting is performed in two steps: (a) contacting the hydrocarbon feed with hydrogen in the presence of a hydrogenation catalyst at a temperature of above 300° C. and at a WSHV of between 0.3 and 2 kg of oil per litre of catalyst per hour, and (b) contacting the intermediate product obtained in step (a) with hydrogen in the presence of a hydrogenation catalyst at a temperature of below 280° C.Type: GrantFiled: July 10, 2001Date of Patent: March 30, 2010Assignee: Shell Oil CompanyInventors: Gerard Benard, Patrick Moureaux
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Patent number: 7663013Abstract: A porous solid acid catalyst for producing light olefins is prepared through pillaring and a solid state reaction of a raw material mixture. The catalyst is made of a porous material having a crystalline structure that is different from that of the raw material mixture. The catalyst exhibits excellent catalytic activity (i.e., conversion and selectivity) in the production of light olefins from hydrocarbon feeds such as full range naphthas.Type: GrantFiled: November 5, 2008Date of Patent: February 16, 2010Assignee: SK Energy Co., Ltd.Inventors: Sun Choi, Deuk Soo Park, Suk Joon Kim, Ahn Seop Choi, Hee Young Kim, Yong Ki Park, Chul Wee Lee, Won Choon Choi, Sang Yun Han, Jeong Ri Kim
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Patent number: 7655136Abstract: The invention concerns a process for producing middle distillates from a paraffinic feed produced by Fischer-Tropsch synthesis, using a hydrocracking/hydroisomerization catalyst which comprises: at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table; 0.01% to 6% of phosphorus as a doping element; and a non-zeolitic support based on mesoporous alumina-silica.Type: GrantFiled: June 27, 2006Date of Patent: February 2, 2010Assignee: Institut Francais du PetroleInventors: Patrick Euzen, Christophe Gueret, Vincenzo Calemma