With Group Ii Metal Or Metal Oxide (i.e., Alkaline Earth Metal, Be, Mg, Zn, Cd, Hg, Or Oxide Thereof) Patents (Class 208/120.25)
  • Patent number: 11805937
    Abstract: The present invention relates to a heating cooker using a ceramic heating element and a manufacturing method thereof, the method comprising: a cooker body preparation step; a heating element material preparation step of preparing any one or more selected from among mill scale, steelmaking slag and magnetite (Fe3O4); an inorganic binder preparation step of preparing, as an inorganic binder, a colloidal silica sol having a colloidal silica content of 8 to 30 wt %; a mixing step of mixing 20 to 40 parts by weight of the colloidal silica sol as the inorganic binder with 100 parts by weight of the heating element material, thereby making a heating material paste; an application step of applying the heating element paste to the bottom of the cooker body; and a drying and curing step of drying and curing the heating element paste, thereby forming a solid heating element.
    Type: Grant
    Filed: April 25, 2017
    Date of Patent: November 7, 2023
    Assignee: PELLYTECH CO., LTD.
    Inventor: Jong Hyun Kim
  • Patent number: 11666895
    Abstract: The invention includes an additive for maximizing production of olefins. The additive comprises a ZSM-5 molecular sieve, at least one inorganic oxide, and phosphorus oxide. The ZSM-5 molecular sieve has iron in the framework, and the additive comprises at least 0.5 weight percent iron, as measured as iron oxide, in the molecular sieve framework. The additive is useful for maximizing production of olefins in a FCC process.
    Type: Grant
    Filed: September 22, 2021
    Date of Patent: June 6, 2023
    Assignee: Johnson Matthey Process Technologies, Inc.
    Inventors: Mehdi Allahverdi, Paul Diddams, Charles Kanyi
  • Patent number: 11524926
    Abstract: The invention includes a fluid catalytic cracking process that comprises reacting a hydrocarbon feedstock under catalytic cracking conditions in the presence of a FCC catalyst and an additive, wherein the additive comprises a ZSM-5 molecular sieve having iron in the framework, wherein the process increases production of propylene compared to a process without using the additive. The invention also includes an additive for maximizing production of olefins, which comprises a ZSM-5 molecular sieve having iron in the framework.
    Type: Grant
    Filed: September 22, 2021
    Date of Patent: December 13, 2022
    Assignee: Johnson Matthey Process Technologies, Inc.
    Inventors: Mehdi Allahverdi, Paul Diddams, Charles Kanyi
  • Patent number: 11332675
    Abstract: A bottoms cracking catalyst composition, comprising: about 30 to about 60 wt % alumina; greater than 0 to about 10 wt % of a dopant, measured as the oxide; about 2 to about 20 wt % reactive silica; about 3 to about 20 wt % of a component comprising peptizable boehmite, colloidal silica, aluminum chlorohydrol, or a combination of any two or more thereof; and about 10 to about 50 wt % of kaolin.
    Type: Grant
    Filed: December 10, 2018
    Date of Patent: May 17, 2022
    Assignee: BASF Corporation
    Inventors: David M. Stockwell, Junmei Wei, Xingtao Gao, David H. Harris
  • Patent number: 9839904
    Abstract: The present invention provides a method for producing a hydroprocessing catalyst including a supporting step of allowing a catalyst support having a content of a carbonaceous substance containing carbon atoms of 0.5% by mass or less in terms of carbon atoms to support an active metal component containing at least one active metal element selected from metals belonging to Group 6, Group 8, Group 9 and Group 10 in the periodic table, to obtain a catalyst precursor, and a calcining step of calcining the catalyst precursor obtained in the supporting step to obtain the hydroprocessing catalyst.
    Type: Grant
    Filed: March 26, 2012
    Date of Patent: December 12, 2017
    Assignees: JAPAN OIL, GAS AND METALS NATIONAL CORPORATION, INPEX CORPORATION, JX NIPPON OIL & ENERGY CORPORATION, JAPAN PETROLEUM EXPLORATION CO., LTD., COSMO OIL CO., LTD., NIPPON STEEL & SUMIKIN ENGINEERING CO., LTD.
    Inventor: Marie Iwama
  • Patent number: 9539543
    Abstract: Described are catalyst composites containing mechanically fused components, methods of making the catalyst composites, and methods of using the catalyst composites such as in pollution abatement applications. The catalyst composites contain a core and a shell at least substantially covering the core, the shell mechanically fused to the core and comprising particles mechanically fused to each other, wherein a size ratio of the core to particles of the shell is at least about 10:1.
    Type: Grant
    Filed: January 29, 2009
    Date of Patent: January 10, 2017
    Assignee: BASF Corporation
    Inventor: Gary Gramiccioni
  • Patent number: 9446364
    Abstract: Systems and methods for storing and handling slurries are provided. The surge drum system for storing a slurry can include a storage vessel having a first end, a second end, and at least one wall surrounding an internal volume between the first and second ends. The system can also include a slurry inlet and a slurry outlet, both in fluid communication with the internal volume. A recirculation inlet can be in fluid communication with the internal volume at the first end of the storage vessel. The system can also include a pump having a suction line in fluid communication with the outlet. A discharge line of the pump can be in fluid communication with an outlet valve and a recirculation valve that can be in fluid communication with the recirculation inlet.
    Type: Grant
    Filed: February 23, 2012
    Date of Patent: September 20, 2016
    Assignee: KELLOGG BROWN & ROOT LLC
    Inventor: Gary L. Mason
  • Patent number: 8901026
    Abstract: A catalytic cracking catalyst composition is disclosed that is suitable for reducing the sulfur content of catalytically cracking liquid products, in particularly gasoline products, produced during a catalytic cracking process. Preferably, the catalytic cracking process is a fluidized catalytic cracking (FCC) process. The composition comprises zeolite, zinc and at least one rare earth element having an ionic radius of less than 0.95 ? at a coordination number of 6. Preferably, zinc and the rare earth element are present as cations that have been exchanged on the zeolite. The zeolite is preferably a Y-type zeolite.
    Type: Grant
    Filed: January 28, 2008
    Date of Patent: December 2, 2014
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Richard Franklin Wormsbecher, Ruizhong Hu
  • Publication number: 20140116923
    Abstract: The present invention relates to a catalyst for Fluid Catalytic Cracking (FCC) which contains a combination of a FCC catalyst component and an additive component with certain physical properties attributed therein. The present invention is also directed to provide methods for the preparation of the catalyst for FCC. The admixture of the FCC catalyst component and additive component is used in cracking of hydrocarbon feedstock containing hydrocarbons of higher molecular weight and higher boiling point and/or olefin gasoline naphtha feedstock for producing lower yield of fuel gas with out affecting the conversion and yield of general cracking products such as gasoline, propylene and C4 olefins.
    Type: Application
    Filed: January 6, 2014
    Publication date: May 1, 2014
    Applicant: RELIANCE INDUSTRIES LIMITED
    Inventors: Srikanta DINDA, Praveen Kumar CHINTHALA, Amit GOHEL, Ashwani YADAV, Sukumar MANDAL, Gopal RAVICHANDRAN, Asit Kumar DAS
  • Publication number: 20140021098
    Abstract: Particulate catalytic cracking catalysts which comprise a zeolite having catalytic cracking ability under catalytic cracking conditions, added silica, a magnesium salt, an alumina containing binder, clay and optionally, a matrix material. The catalytic cracking catalyst has a high matrix surface area and is useful in a catalytic cracking process, in particularly, a fluid catalytic cracking process, to provide increased catalytic activity and improved coke and hydrogen selectivity without the need to incorporate rare earth metals.
    Type: Application
    Filed: July 23, 2013
    Publication date: January 23, 2014
    Applicant: W. R. GRACE & CO.-CONN.
    Inventors: Ranjit KUMAR, Wu-Cheng Cheng, Kevin J. Sutovich, Michael S. Ziebarth, Yuying Shu
  • Publication number: 20140021097
    Abstract: A rare earth free particulate catalytic cracking catalyst which comprises a zeolite having catalytic cracking ability under catalytic cracking conditions, an acidified silica sol binder, magnesium salt, clay and a matrix material. The catalytic cracking catalyst has a high matrix surface area and is useful in a catalytic cracking process, in particularly, a fluid catalytic cracking process, to provide increased catalytic activity and improved hydrogen and coke selectivity without the need to incorporate rare earth metals.
    Type: Application
    Filed: July 23, 2013
    Publication date: January 23, 2014
    Applicant: W. R. GRACE & CO.-CONN.
    Inventors: Kevin J. SUTOVICH, Wu-Cheng CHENG, Ranjit KUMAR, Michael S. ZIEBARTH, Yuying SHU
  • Publication number: 20130081980
    Abstract: The present invention relates to sulphur reduction catalyst additive composition comprising an inorganic porous support incorporated with metals; an alumino silicate or zeolite component; an alumina component and clay. More particularly the present invention relates to sulphur reduction catalyst additive composition comprising refinery spent catalyst as support. The primary sulphur reduction catalyst additive component of the catalyst composition contains metals of Period III or IV of the Periodic Table, preferably Zinc or Magnesium or combination thereof or one of the transition metals along with other metals.
    Type: Application
    Filed: October 1, 2012
    Publication date: April 4, 2013
    Applicant: BHARAT PETROLEUM CORPORATION LIMITED
    Inventors: Dattatraya Tammannashastri GOKAK, Chiranjeevi THOTA, Pragya RAI, N. JOSE, P.S. VISWANATHAN
  • Publication number: 20130029832
    Abstract: This invention relates to stabilized aggregates of small primary crystallites of zeolite Y that are clustered into larger secondary particles. At least 80% of the secondary particles may comprise at least 5 primary crystallites. The size of the primary crystallites may be at most about 0.5 micron, or at most about 0.3 micron, and the size of the secondary particles may be at least about 0.8 micron, or at least about 1.0 ?m. The silica to alumina ratio of the resulting stabilized aggregated Y zeolite may be 4:1 or more.
    Type: Application
    Filed: March 6, 2012
    Publication date: January 31, 2013
    Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Wenyih Frank Lai, Robert E. Kay, Jason Wu, Kun Wang, Robert C. Lemon
  • Patent number: 8337803
    Abstract: Compositions and methods suitable for removing poisonous metals from hydrocarbons are provided. The compositions comprise hydrotalcite having one or more trapping metals dispersed on the outer surface thereof.
    Type: Grant
    Filed: November 1, 2010
    Date of Patent: December 25, 2012
    Assignee: Albemarle Netherlands B.V.
    Inventors: Julie Ann Francis, Charles Vadovic
  • Patent number: 8221615
    Abstract: The invention is a composition that is suitable for reducing sulfur species from products produced by petroleum refining processes, especially gasoline products produced by fluidized catalytic cracking (FCC) processes. The composition comprises zeolite, yttrium, and at least one element selected from the group consisting of zinc, magnesium and manganese, wherein the yttrium and element are present as cations. The yttrium and zinc are preferably present as cations that have been exchanged onto the zeolite. The zeolite is preferably a zeolite Y.
    Type: Grant
    Filed: February 1, 2011
    Date of Patent: July 17, 2012
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Ruizhong Hu, Richard Franklin Wormsbecher
  • Patent number: 8137535
    Abstract: Systems and methods for producing and using one or more doped catalysts are provided. One or more coked-catalyst particles can be fluidized in the presence of one or more oxidants to provide a fluidized mixture. The coke from the one or more coked-catalyst particles can be removed to provide regenerated catalyst particles within the fluidized mixture. One or more doping agents can be distributed to the fluidized mixture, and the one or more doping agents can be deposited onto the surface of the regenerated catalyst particles to provide a regenerated, doped catalyst particle.
    Type: Grant
    Filed: January 29, 2008
    Date of Patent: March 20, 2012
    Assignee: Kellogg Brown & Root LLC
    Inventor: Pritham Ramamurthy
  • Patent number: 8084383
    Abstract: The present invention is directed to certain catalyst compositions and processes that are capable of reducing sulfur compounds normally found as part of the gasoline fraction streams of fluid catalytic cracking processes. The present invention is a cracking catalyst composition comprising a zeolite in combination with a Lewis Acid containing component, wherein the cracking catalyst composition comprises 0.2% Na2O or less. It has been found that sulfur compounds in hydrocarbon feeds to fluid catalytic cracking processes can be reduced by at least 15% compared to the same composition, which does not comprise the aforementioned Lewis Acid containing component.
    Type: Grant
    Filed: March 16, 2004
    Date of Patent: December 27, 2011
    Assignee: W.R. Grace & Co.-Conn.
    Inventors: Ruizhong Hu, Xinjin Zhao, Richard Franklin Wormsbecher, Michael Scott Ziebarth
  • Publication number: 20110230697
    Abstract: Catalytic cracking processes such as fluidized catalytic cracking, naphtha cracking, and olefin cracking are catalyzed by the UZM-35 family of crystalline aluminosilicate zeolites represented by the empirical formula: Mmn+Rr+Al(1-x)ExSiyOz where M represents a combination of potassium and sodium exchangeable cations, R is a singly charged organoammonium cation such as the dimethyldipropylammonium cation and E is a framework element such as gallium. These UZM-35 zeolites are active and selective in the catalytic cracking of hydrocarbons.
    Type: Application
    Filed: June 2, 2011
    Publication date: September 22, 2011
    Applicant: UOP LLC
    Inventors: Christopher P. Nicholas, Deng-Yang Jan, Jaime G. Moscoso
  • Patent number: 8022003
    Abstract: A porous crystalline composition having a molar composition as follows: YO2:m X2O3:n ZO, wherein Y is a tetravalent element selected from the group consisting of silicon, germanium, tin, titanium and combinations thereof, X is a trivalent element selected from the group consisting of aluminum, gallium, boron, iron and combinations thereof, Z is a divalent element selected from the group consisting of magnesium, zinc, cobalt, manganese, nickel and combinations thereof, m is between about 0 and about 0.5, n is between about 0 and about 0.5; and the composition has an x-ray diffraction pattern which distinguishes it from the materials. A process for making the composition, and a process using the composition to treat an organic compound are also provided.
    Type: Grant
    Filed: August 6, 2010
    Date of Patent: September 20, 2011
    Assignee: Intevep, S.A.
    Inventors: Andres Quesada Perez, Gerardo Vitale Rojas
  • Patent number: 8021642
    Abstract: A porous crystalline composition having a molar composition as follows: YO2:m X2O3:n ZO, wherein Y is a tetravalent element selected from the group consisting of silicon, germanium, tin, titanium and combinations thereof, X is a trivalent element selected from the group consisting of aluminum, gallium, boron, iron and combinations thereof, Z is a divalent element selected from the group consisting of magnesium, zinc, cobalt, manganese, nickel and combinations thereof, m is between about 0 and about 0.5, n is between about 0 and about 0.5; and the composition has an x-ray diffraction pattern which distinguishes it from the materials. A process for making the composition, and a process using the composition to treat an organic compound are also provided.
    Type: Grant
    Filed: June 13, 2007
    Date of Patent: September 20, 2011
    Assignee: Intevep, S.A.
    Inventors: Andres Quesada Perez, Gerardo Vitale Rojas
  • Patent number: 7993623
    Abstract: Compositions and methods suitable for removing poisonous metals from hydrocarbons are provided. The compositions comprise hydrotalcite having one or more trapping metals dispersed on the outer surface thereof.
    Type: Grant
    Filed: June 29, 2007
    Date of Patent: August 9, 2011
    Assignee: Albemarle Netherlands B.V.
    Inventors: Julie Ann Francis, Charles Vadovic
  • Patent number: 7976697
    Abstract: A NOx reduction composition and process of using the composition to reduce the content of NOx emissions and gas phase reduced nitrogen species released from the regeneration zone during fluid catalytic cracking of a hydrocarbon feedstock into lower molecular weight components is disclosed. The process comprises contacting a hydrocarbon feedstock during a fluid catalytic cracking (FCC) process wherein a regeneration zone of an fluid catalytic cracking unit (FCCU) is operated in a partial or incomplete combustion mode under FCC conditions, with a circulating inventory of an FCC cracking catalyst and a particulate NOx reduction composition. The NOx reduction composition has a mean particle size of greater than 45 ?m and comprises (1) a zeolite component having (i) a pore size of form 2-7 A Angstroms and (ii) a SiO2 to Al2O3 molar ratio of less than 500, and (2) at least one noble metal selected from the group consisting of platinum, palladium, rhodium, iridium, osmium, ruthenium, rhenium and mixtures thereof.
    Type: Grant
    Filed: March 24, 2006
    Date of Patent: July 12, 2011
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: M. Sundaram Krishnamoorthy, Michael Scott Ziebarth, George Yaluris, Roger Jean Lussier, John Allen Rudesill
  • Publication number: 20110163006
    Abstract: The present invention concerns a new cracking process, preferably a fluid catalytic process, characterized in that it is carried out in the presence of a catalyst containing ERS-10 zeolite. The invention also relates to a new catalytic composition containing said ERS-10 zeolite, which can be used as catalyst in catalytic cracking processes, in particular in fluid catalytic cracking processes (FCC).
    Type: Application
    Filed: May 28, 2009
    Publication date: July 7, 2011
    Applicant: ENI S.P.A
    Inventors: Giuseppe Bellussi, Roberto Millini, Caterina Rizzo, Daniele Colombo
  • Publication number: 20110127193
    Abstract: The present invention relates to a catalyst for catalytic cracking fluidized-bed, and the technical problems to be primarily solved by the present invention are high reaction temperature, low cryogenic activity of catalysts and worse selectivity during the preparation of ethylene-propylene by catalytically cracking naphtha. The present invention uses the composition having the chemical formula (on the basis of the atom ratio): AaBbPcOx, so as to magnificently solve said problems. The present invention therefore can be industrially used to produce ethylene and propylene by catalytically cracking naphtha.
    Type: Application
    Filed: December 23, 2010
    Publication date: June 2, 2011
    Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY SINOPEC
    Inventors: Zaiku Xie, Guangwei Ma, Weimin Yang, Hui Yao, Liang Chen
  • Publication number: 20110120911
    Abstract: The invention is a composition that is suitable for reducing sulfur species from products produced by petroleum refining processes, especially gasoline products produced by fluidized catalytic cracking (FCC) processes. The composition comprises zeolite, yttrium, and at least one element selected from the group consisting of zinc, magnesium and manganese, wherein the yttrium and element are present as cations. The yttrium and zinc are preferably present as cations that have been exchanged onto the zeolite. The zeolite is preferably a zeolite Y.
    Type: Application
    Filed: February 1, 2011
    Publication date: May 26, 2011
    Inventors: Ruizhong Hu, Richard Franklin Wormsbecher
  • Patent number: 7943038
    Abstract: Processes for producing one or more olefins are provided. In one or more embodiments, a doped catalyst can be prepared by fluidizing one or more coked-catalyst particles in the presence of one or more oxidants to provide a fluidized mixture. At least a portion of the coke can be removed from the coked-catalyst particles to provide regenerated catalyst particles. One or more doping agents can be distributed throughout the fluidized mixture, depositing on the surface of the regenerated catalyst particles to provide doped catalyst particles. One or more hydrocarbon feeds can be fluidized with the doped catalyst particles to provide a reaction mixture which can be cracked to provide a first product containing propylene, ethylene, and butane.
    Type: Grant
    Filed: January 29, 2008
    Date of Patent: May 17, 2011
    Assignee: Kellogg Brown & Root LLC
    Inventor: Pritham Ramamurthy
  • Patent number: 7918991
    Abstract: Compositions for reduction of NOx generated during a catalytic cracking process, preferably, a fluid catalytic cracking process, are disclosed. The compositions comprise a fluid catalytic cracking catalyst composition, preferably containing a Y-type zeolite, and a NOx reducing zeolite having a pore size ranging from about 2 to about 7.2 Angstroms and a SiO2 to Al2O3 molar ratio of less than about 500 and being stabilized with a metal or metal ion selected from the group consisting of zinc, iron and mixtures thereof. Preferably, the NOx reducing zeolite particles are bound with an inorganic binder to form a particulate composition. In the alternative, the NOx reducing zeolite particles are incorporated into the cracking catalyst as an integral component of the catalyst.
    Type: Grant
    Filed: March 24, 2006
    Date of Patent: April 5, 2011
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Michael Scott Ziebarth, M. Sundaram Krishnamoorthy, Roger Jean Lussier
  • Patent number: 7863494
    Abstract: Provided are a catalyst for hydrocarbon steam cracking for light olefin production and a method for preparing the same. The catalyst is a simple KMgPO4 catalyst, a supported KMgPO4 catalyst, or a KMgPO4-sintered catalyst. The supported KMgPO4 catalyst is prepared by impregnating a carrier with an aqueous solution of a KMgPO4 precursor and the KMgPO4-sintered catalyst is prepared by mixing a KMgPO4 powder or a KMgPO4 precursor powder with metal oxide followed by sintering. Provided is also a method for producing light olefins such as ethylene and propylene by steam cracking in the presence of the catalyst. When the catalyst comprising KMgSO4 as a catalytic component is used in olefin production, the yield of olefins is increased and the amount of cokes deposited on the catalyst is reduced.
    Type: Grant
    Filed: May 7, 2004
    Date of Patent: January 4, 2011
    Assignees: LG Chem, Ltd., LG Petrochemical Co., Ltd.
    Inventors: Jun-han Kang, Won-ho Lee, Sang-mun Jeong, Sang-ku Park, Jong-hyun Chae
  • Patent number: 7803267
    Abstract: The sulfur content of liquid cracking products, especially the cracked gasoline, of the catalytic cracking process is reduced by the use of a sulfur reduction catalyst composition comprising a porous molecular sieve which contains a metal in an oxidation state above zero within the interior of the pore structure of the sieve as well as a cerium component which enhances the stability and sulfur reduction activity of the catalyst. The molecular sieve is normally a faujasite such as USY. The primary sulfur reduction component is normally a metal of Period 3 of the Periodic Table, preferably vanadium. The sulfur reduction catalyst may be used in the form of a separate particle additive or as a component of an integrated cracking/sulfur reduction catalyst.
    Type: Grant
    Filed: April 29, 2005
    Date of Patent: September 28, 2010
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Arthur W. Chester, Terry G. Roberie, Hye Kyung C. Timken, Michael S. Ziebarth
  • Publication number: 20100133145
    Abstract: A catalytic cracking catalyst composition is disclosed that is suitable for reducing the sulfur content of catalytically cracking liquid products, in particularly gasoline products, produced during a catalytic cracking process. Preferably, the catalytic cracking process is a fluidized catalytic cracking (FCC) process. The composition comprises zeolite, zinc and at least one rare earth element having an ionic radii of less than 0.95 ? at a coordination number of 6. Preferably, zinc and the rare earth element are present as cations that have been exchanged on the zeolite. The zeolite is preferably a Y-type zeolite.
    Type: Application
    Filed: January 28, 2008
    Publication date: June 3, 2010
    Applicant: W. R. GRACE & CO.-CONN.
    Inventors: Richard Franklin Wormsbecher, Ruizhong Hu
  • Patent number: 7718840
    Abstract: Disclosed is a process for producing light olefins from hydrocarbon feedstock. The process is characterized in that a porous molecular sieve catalyst consisting of a product obtained by evaporating water from a raw material mixture comprising a molecular sieve with a framework of Si—OH—Al— groups, a water-insoluble metal salt, and a phosphate compound, is used to produce light olefins, particularly ethylene and propylene, from hydrocarbon, while maintaining excellent selectivity to light olefins. According to the process, by the use of a specific catalyst with hydrothermal stability, light olefins can be selectively produced in high yield with high selectivity from hydrocarbon feedstock, particularly full-range naphtha. In particular, the process can maintain higher cracking activity than the reaction temperature required in the prior thermal cracking process for the production of light olefins, and thus, can produce light olefins with high selectivity and conversion from hydrocarbon feedstock.
    Type: Grant
    Filed: June 27, 2006
    Date of Patent: May 18, 2010
    Assignees: SK Energy Co., Ltd., Korea Research Institute of Chemical Technology
    Inventors: Sun Choi, Yong Seung Kim, Deuk Soo Park, Suk Joon Kim, Il Mo Yang, Hee Young Kim, Yong Ki Park, Chul Wee Lee, Won Choon Choi, Kwang An Ko, Na Young Kang
  • Patent number: 7641787
    Abstract: Compositions for reduction of NOx generated during a catalytic cracking process, preferably, a fluid catalytic cracking process, are disclosed. The compositions comprise a fluid catalytic cracking catalyst composition, preferably containing a Y-type zeolite, and a particulate NOx composition containing particles of a zeolite having a pore size ranging from about 3 to about 7.2 Angstroms and a SiO2 to Al2O3 molar ratio of less than about 500. Preferably, the NOx reduction composition contains NOx reduction zeolite particles bound with an inorganic binder. In the alternative, the NOx reduction zeolite particles are incorporated into the cracking catalyst as an integral component of the catalyst. Compositions in accordance with the invention are very effective for the reduction of NOx emissions released from the regenerator of a fluid catalytic cracking unit operating under FCC process conditions without a substantial change in conversion or yield of cracked products.
    Type: Grant
    Filed: November 7, 2008
    Date of Patent: January 5, 2010
    Assignee: W.R. Grace & Co.-Conn.
    Inventors: George Yaluris, Michael Scott Ziebarth, Xinjin Zhao
  • Publication number: 20090288990
    Abstract: The present invention relates to a catalyst for catalytic cracking fluidized-bed, and the technical problems to be primarily solved by the present invention are high reaction temperature, low cryogenic activity of catalysts and worse selectivity during the preparation of ethylene-propylene by catalytically cracking naphtha. The present invention uses the composition having the chemical formula (on the basis of the atom ratio): AaBbPcOx, so as to magnificently solve said problems. The present invention therefore can be industrially used to produce ethylene and propylene by catalytically cracking naphtha.
    Type: Application
    Filed: August 15, 2006
    Publication date: November 26, 2009
    Applicants: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology Sinopec
    Inventors: Zaiku Xie, Guangwei Ma, Weimin Yang, Hui Yao, Jingxian Xiao, Liang Chen
  • Patent number: 7598202
    Abstract: Novel compositions of matter comprising a cationic layered material and a second compound. The second compound has a reflection in its XRD pattern at 18.5 degrees two-theta, and s second reflection at 29 degrees two-theta. The composition of matter may be used in hydrocarbon conversion, purification, and synthesis processes, such as fluid catalytic cracking and hydroprocessing. The materials are especially suitable for the reduction of SOx and NOx emissions and the reduction of the sulfur and nitrogen content in fuels like gasoline and diesel.
    Type: Grant
    Filed: December 20, 2005
    Date of Patent: October 6, 2009
    Assignee: Albemarle Netherlands B.V.
    Inventors: Paul O'Connor, William Jones, Dennis Stamires
  • Patent number: 7582202
    Abstract: A Composition comprising one or more metal hydroxy salts and a matrix, binder or carrier material, wherein the metal hydroxy salt is a compound comprising (a) as metal either (i) one or more divalent metals, at least one of them being selected from the group consisting of Ni, Co, Ca, Zn, Mg, Fe, and Mn, or (ii) one or more trivalent metal(s), (b) framework hydroxide, and (c) a replaceable anion. This composition has various catalytic applications.
    Type: Grant
    Filed: February 10, 2004
    Date of Patent: September 1, 2009
    Assignees: Akzo Nobel N.V., Albemarle Netherlands B.V.
    Inventors: William Jones, Paul O'Connor, Dennis Stamires
  • Patent number: 7576025
    Abstract: A composition comprising FCC catalyst particles and additive particles suitable for the reduction of NOx emissions from a FCC regenerator, said additive particles comprising a Mg and Al-containing anionic clay or solid solution, a rare earth metal oxide, alumina and/or silica-alumina, and Y-type zeolite. The invention further relates to a process for preparing such a composition and its use for reducing NOx emissions.
    Type: Grant
    Filed: October 12, 2004
    Date of Patent: August 18, 2009
    Assignee: Albemarle Netherlands B.V.
    Inventors: Christopher W. Kuehler, Paul O'Connor, Dennis Stamires
  • Patent number: 7473348
    Abstract: Production of diesel oil from hydrocarbon-containing residues in an oil circuit with solids separation and product distillation for the diesel product with energy input by means of pumps and counterrotating agitators and by the use of fully crystallized catalysts of potassium, sodium, calcium, and magnesium-aluminum silicates, where all surfaces are cleaned continuously by the agitator mechanisms.
    Type: Grant
    Filed: July 15, 2004
    Date of Patent: January 6, 2009
    Assignee: Alphakat GmbH
    Inventor: Christian Koch
  • Patent number: 7435332
    Abstract: This invention relates to a process for cracking hydrocarbon oils. The process comprises contacting a hydrocarbon oil with a catalyst that has been contacted with an atmosphere containing a reducing gas, separating cracked products and the catalyst, and regenerating the catalyst. The catalyst is a cracking catalyst containing a metal component, or a catalyst mixture of a cracking catalyst containing a metal component and a cracking catalyst free of metal component. The catalyst is contacted with the atmosphere containing a reducing gas at a temperature of 100 to 900° C. for at least 1 second, and the amount of the atmosphere containing a reducing gas is not less than 0.03 cubic meters of reducing gas per ton of the cracking catalyst containing a metal component per minute, at a pressure of 0.1-0.5 MPa in the reduction reactor. The process has enhanced capability for desulfurizing and cracking heavy oils.
    Type: Grant
    Filed: September 27, 2004
    Date of Patent: October 14, 2008
    Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing Sinopec
    Inventors: Jun Long, Huiping Tian, Yujian Liu, Yuxia Zhu, Zhenyu Chen, Yaoqing Guo, Zhijian Da, Jiushun Zhang, Mingyuan He
  • Publication number: 20080202984
    Abstract: The present invention is directed to methods for mitigating the deleterious effect of at least one metal on an FCC catalyst. This objective is achieved by using a mixed metal oxide compound comprising magnesium and aluminum, that has not been derived from a hydrotalcite compound, and having an X-ray diffraction pattern displaying at least a reflection at a two theta peak position at about 43 degrees and about 62 degrees, wherein the ratio of magnesium to aluminum in the compound is from about 0.6:1 to about 10:1. In one embodiment, the ratio of magnesium to aluminum in the compound is from about 1:1 to about 6:1. In one embodiment, the ratio of magnesium to aluminum in the compound is from about 1.5:1 to about 10:1. In another embodiment, the invention is directed to methods wherein the ratio of magnesium to aluminum in the compound is from about 1.5:1 to about 6:1.
    Type: Application
    Filed: January 28, 2008
    Publication date: August 28, 2008
    Inventor: Albert A. Vierheilig
  • Publication number: 20080156698
    Abstract: The invention is a composition that is suitable for reducing sulfur species from products produced by petroleum refining processes, especially gasoline products produced by fluidized catalytic cracking (FCC) processes. The composition comprises zeolite, yttrium, and at least one element selected from the group consisting of zinc, magnesium and manganese, wherein the yttrium and element are present as cations. The yttrium and zinc are preferably present as cations that have been exchanged onto the zeolite. The zeolite is preferably a zeolite Y.
    Type: Application
    Filed: February 24, 2006
    Publication date: July 3, 2008
    Inventors: Ruizhong Hu, Richard Franklin Wormsbecher
  • Patent number: 7361264
    Abstract: The present invention is directed to methods for mitigating the deleterious effect of at least one metal on an FCC catalyst. This objective is achieved by using a mixed metal oxide compound comprising magnesium and aluminum, that has not been derived from a hydrotalcite compound, and having an X-ray diffraction pattern displaying at least a reflection at a two theta peak position at about 43 degrees and about 62 degrees, wherein the ratio of magnesium to aluminum in the compound is from about 0.6:1 to about 10:1. In one embodiment, the ratio of magnesium to aluminum in the compound is from about 1:1 to about 6:1. In one embodiment, the ratio of magnesium to aluminum in the compound is from about 1.5:1 to about 10:1. In another embodiment, the invention is directed to methods wherein the ratio of magnesium to aluminum in the compound is from about 1.5:1 to about 6:1.
    Type: Grant
    Filed: May 25, 2005
    Date of Patent: April 22, 2008
    Assignee: Intercat, Inc.
    Inventor: Albert A. Vierheilig
  • Patent number: 7347930
    Abstract: A novel process for cracking olefins including contacting a hydrocarbon oil with a catalyst in a riser reactor having multiple reaction zones under cracking reaction conditions; separating reaction products and the catalyst; regenerating at least a part of spent catalyst obtained, contacting a part of the regenerated catalyst with the hydrocarbon in the first reaction zone; contacting the other part of the spent catalyst and/or regenerated catalyst in at least one reaction zone after the first reaction zone with the products obtained in previous reaction zones.
    Type: Grant
    Filed: October 15, 2004
    Date of Patent: March 25, 2008
    Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, Sinopec
    Inventors: Jun Long, Yuxia Zhu, Huiping Tian, Yujian Liu, Zhenyu Chen, Yaoqing Guo, Zhijian Da, Jiushun Zhang, Mingyuan He
  • Patent number: 7291259
    Abstract: Processes are disclosed for removing sulfur, including cyclic and polycyclic organic sulfur components such as thiophenes and benzothiophenes, from a hydrocarbon feedstock including fuels and fuel components. The feedstock is contacted with a regenerable sorbent material capable of selectively adsorbing the sulfur compounds present in the hydrocarbon feedstock in the absence of a hydrodesulfurization catalyst. In one embodiment, the sorbent can be an active metal oxide sulfur sorbent in combination with a refractory inorganic oxide cracking catalyst support. In another embodiment, the sorbent can be a metal-substituted refractory inorganic oxide cracking catalyst wherein the metal is a metal which is capable in its oxide form, of adsorption of reduced sulfur compounds by conversion of the metal oxide to a metal sulfide. The processes are preferably carried out in a transport bed reactor.
    Type: Grant
    Filed: September 12, 2001
    Date of Patent: November 6, 2007
    Assignee: Research Triangle Institute
    Inventors: Raghubir P. Gupta, Brian S. Turk
  • Patent number: 7125817
    Abstract: A catalyst system and process for combined cracking and selective hydrogen combustion of hydrocarbons are disclosed. The catalyst comprises (1) at least one solid acid component, (2) at least one metal-based component comprised of one or more elements from Group 3 and one or more elements from Groups 4–15 of the Periodic Table of the Elements; and at least one of oxygen and sulfur, wherein the elements from Groups 3, Groups 4–15 and the at least one of oxygen and sulfur are chemically bound both within and between the groups and (3) at least one of at least one support, at least one filler and at least one binder. The process is such that the yield of hydrogen is less than the yield of hydrogen when contacting the hydrocarbons with the solid acid component alone.
    Type: Grant
    Filed: February 20, 2003
    Date of Patent: October 24, 2006
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: John D. Y. Ou, Neeraj Sangar
  • Patent number: 7122492
    Abstract: A catalyst system and process for combined cracking and selective hydrogen combustion of hydrocarbons are disclosed. The catalyst comprises (1) at least one solid acid component, (2) at least one metal-based component comprised of one or more elements from Groups 1 and 2; one or more elements from Group 3; one or more elements from Groups 4–15 of the Periodic Table of the Elements; and at least one of oxygen and sulfur and (3) at least one of at least one support, at least one filler and at least one binder. The process is such that the yield of hydrogen is less than the yield of hydrogen when contacting the hydrocarbons with the solid acid component alone.
    Type: Grant
    Filed: February 5, 2003
    Date of Patent: October 17, 2006
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: John D. Y. Ou, Neeraj Sangar
  • Patent number: 7025873
    Abstract: Cationic layered materials, a process for their preparation and their use in hydrocarbon conversion, purification, and synthesis processes, such as fluid catalytic cracking. Cationic layered materials are especially suitable for the reduction of SOx and NOx emissions and the reduction of the sulfur and nitrogen content in fuels like gasoline and diesel. The new preparation process avoids the use of metal salts and does not require the formation of anionic clay as an intermediate.
    Type: Grant
    Filed: June 24, 2003
    Date of Patent: April 11, 2006
    Assignees: Albemarle Netherlands BV., Akzo Nobel NV.
    Inventors: Paul O'Connor, William Jones, Dennis Stamires
  • Patent number: 6923903
    Abstract: The sulfur content of liquid cracking products, especially the cracked gasoline, of the catalytic cracking process is reduced by the use of a sulfur reduction catalyst composition comprising a porous molecular sieve which contains a metal in an oxidation state above zero within the interior of the pore structure of the sieve as well as a cerium component which enhances the stability and sulfur reduction activity of the catalyst. The molecular sieve is normally a faujasite such as USY. The primary sulfur reduction component is normally a metal of Period 3 of the Periodic Table, preferably vanadium. The sulfur reduction catalyst may be used in the form of a separate particle additive or as a component of an integrated cracking/sulfur reduction catalyst.
    Type: Grant
    Filed: December 3, 2002
    Date of Patent: August 2, 2005
    Assignees: ExxonMobil Oil Corporation, W.R. Grace & Co.-Conn.
    Inventors: Arthur W. Chester, Hye Kyung Cho Timken, Terry G. Roberie, Michael S. Ziebarth
  • Patent number: 6902665
    Abstract: Compositions comprising a component containing (i) an acidic oxide support, (ii) an alkali metal and/or alkaline earth metal or mixtures thereof, (iii) a transition metal oxide having oxygen storage capability, and (iv) palladium promote CO combustion in FCC processes while minimizing the formation of NOx. The acidic oxide support preferably contains silica alumina. Ceria is the preferred oxygen storage oxide.
    Type: Grant
    Filed: December 18, 2001
    Date of Patent: June 7, 2005
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Alan W. Peters, Edward F. Rakiewicz, Gordon Dean Weatherbee, Xinjin Zhao
  • Patent number: 6852214
    Abstract: The sulfur content of liquid cracking products, especially the cracked gasoline, of the catalytic cracking process is reduced by the use of a sulfur reduction additive comprising a porous molecular sieve which contains a metal in an oxidation state above zero within the interior of the pore structure of the sieve. The molecular sieve is normally a large pore size zeolite such as USY or zeolite beta or an intermediate pore size zeolite such as ZSM-5. The metal is normally a metal of Period 4 of the Periodic Table, preferably zinc or vanadium. The sulfur reduction catalyst may be used in the form of a separate particle additive or as a component of an integrated cracking/sulfur reduction catalyst.
    Type: Grant
    Filed: August 31, 1998
    Date of Patent: February 8, 2005
    Assignees: Mobil Oil Corporation, W. R. Grace & Co.-Conn.
    Inventors: Arthur W. Chester, Hye Kyung Cho Timken, Michael S. Ziebarth, Terry G. Roberie
  • Patent number: 6846403
    Abstract: The sulfur content of liquid cracking products, especially the cracked gasoline, of the catalytic cracking process is reduced by the use of a sulfur reduction catalyst composition comprising a porous molecular sieve which contains a metal in an oxidation state above zero within the interior of the pore structure of the sieve as well as a rare earth component which enhances the cracking activity of the cracking catalyst. The molecular sieve is normally a faujasite such as USY. The primary sulfur reduction component is normally a metal of Period 4 of the Periodic Table, preferably vanadium. The rare earth component preferably includes cerium which enhances the sulfur reduction activity of the catalyst. The sulfur reduction catalyst may be used in the form of a separate particle additive or as a component of an integrated cracking/sulfur reduction catalyst.
    Type: Grant
    Filed: December 28, 1998
    Date of Patent: January 25, 2005
    Assignees: Mobil Oil Corporation, W.R. Grace & Co.-Conn.
    Inventors: Wu-Cheng Cheng, Scott Kevin Purnell, Terry G. Roberie, Hye Kyung Cho Timken, Xinjin Zhao