With Group Iii Metal, Rare Earth Metal, Or Metal Oxide (i.e., Sc, Y, Al, Ga, In, Tl, Metal Of Atomic Number 57-71 Or Oxide Thereof) Patents (Class 208/120.01)
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Patent number: 11498054Abstract: A metal trap for an FCC catalyst include pre-formed microspheres impregnated with an organic acid salt of a rare earth element.Type: GrantFiled: November 8, 2018Date of Patent: November 15, 2022Assignee: BASF CORPORATIONInventors: Gary M. Smith, Bilge Yilmaz
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Patent number: 11473022Abstract: In accordance with one or more embodiments of the present disclosure, process for reforming a diesel feedstock to convert diesel to a gasoline blending component includes hydrodesulfurizing and hydrodenitrogenizing the diesel feedstock to reduce a sulfur content of the diesel feedstock and a nitrogen content of the diesel feedstock; hydrocracking the hydrodesulfurized and hydrodenitrogenized diesel feedstock over a metal-containing diesel hydrocracking catalyst comprising at least one zeolite to produce an isomerate fraction; and separating the isomerate fraction into a first stream enriched in n-paraffins and a second stream enriched in iso-paraffins and naphthenes.Type: GrantFiled: January 7, 2021Date of Patent: October 18, 2022Assignee: Saudi Arabian Oil CompanyInventors: Omer Refa Koseoglu, Ashok Kumar Punetha
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Patent number: 11279885Abstract: A catalyst regenerator according to an embodiment of the present invention, as a catalyst regenerator that regenerates a coked catalyst separated from a product produced in an endothermic catalytic reaction of a fluidized bed reactor, includes: a reaction chamber that includes a regeneration space, receives the coked catalyst from a standpipe connected to the regeneration space, and discharges a regenerated catalyst to an outlet; a fuel supplier that is connected to the reaction chamber to inject a fuel for combustion into the regeneration space; and a fuel supplier that is connected to the reaction chamber to inject an air for combustion into the regeneration space, wherein the fuel injected from the fuel supplier is a reformed fuel containing hydrogen and carbon monoxide.Type: GrantFiled: May 10, 2019Date of Patent: March 22, 2022Assignees: KOREA INSTITUTE OF MACHINERY & MATERIALS, KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGYInventors: Sungkwon Jo, Seongil Choi, Donghyun Cho, Dae-hoon Lee, Kwan-Tae Kim, Younghoon Song, Yong-Ki Park, Na Young Kang
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Patent number: 11225612Abstract: Embodiments of the disclosure provide a method for producing light olefins from a hydrocarbon feed. The hydrocarbon feed and a water feed are introduced to a reactor to produce an effluent stream. The reactor is operated at a temperature and pressure such that cracking reactions occur in the reactor. The reactor includes a catalyst bed including a nanoscale zeolite catalyst having a crystal size ranging between 10 nm and 300 nm. The effluent stream includes the light olefins. The effluent stream is introduced to a first separator to produce a gas phase fraction and a liquid phase fraction. The gas phase fraction includes the light olefins. The liquid phase fraction is introduced to a second separator to produce a liquid hydrocarbon stream and a spent water stream.Type: GrantFiled: March 27, 2020Date of Patent: January 18, 2022Assignee: SAUDI ARABIAN OIL COMPANYInventors: Emad Naji Al-Shafei, Mohammed Z. Al-Bahar, Ali Nader Al-Jishi, Ki-Hyouk Choi, Mohammad F. Al-Jishi, Ali S. Al-Nasir
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Patent number: 11198115Abstract: Methods are provided for forming noble metal catalysts comprising both platinum and a second Group VIII metal, such as palladium, with improved aromatic saturation activity. Instead of impregnating a catalyst with both platinum and another Group VIII metal at the same time, a sequential impregnation can be used, with the Group VIII metal being impregnated prior to platinum. It has been discovered that by forming a Group VIII metal-impregnated catalyst first, and then impregnating with platinum, the distribution of platinum throughout the catalyst can be improved. The improved distribution of platinum can result in a catalyst with enhanced aromatic saturation activity relative to a catalyst with a similar composition formed by simultaneous impregnation.Type: GrantFiled: December 9, 2019Date of Patent: December 14, 2021Assignee: ExxonMobil Research and Engineering CompanyInventors: Matthew S. Ide, Stephen J. McCarthy, Gary P. Schleicher
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Patent number: 11130917Abstract: A modified Y-type molecular sieve has a rare earth content of about 4-11% by weight on the basis of rare earth oxide, a sodium content of no more than about 0.7% by weight on the basis of sodium oxide, a zinc content of about 0.5-5% by weight on the basis of zinc oxide, a phosphorus content of about 0.05-10% by weight on the basis of phosphorus pentoxide, a framework silica-alumina ratio of about 7-14 calculated on the basis of SiO2/Al2O3 molar ratio, a percentage of non-framework aluminum content to the total aluminum content of no more than about 20%, and a percentage of the pore volume of secondary pores having a pore size of 2-100 nm to the total pore volume of about 15-30%. The modified Y-type molecular sieve has a high crystallinity, a structure comprising secondary pores, and a high thermal and hydrothermal stability.Type: GrantFiled: August 20, 2019Date of Patent: September 28, 2021Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPECInventors: Hao Sha, Lingping Zhou, Shuai Yuan, Weilin Zhang, Zhenyu Chen, Mingde Xu, Huiping Tian
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Patent number: 11111443Abstract: The present invention deals with a process for catalytic cracking of hydrocarbons comprising vacuum gas oil, hydrotreated vacuum gas oil, unconventional light crude oil, preferably unconventional light crude oil type shale/tight oil and its blends with conventional vacuum gas oil, in order to generate products of major commercial value in the field of fuels, getting improved gasoline and coke yield, as well as the procedure for the preparation of a catalyst with essential physical properties of density and particle size to uphold it in a fluidized bed under the operation conditions in the catalyst evaluation unit at micro level, wherein the catalyst particles achieve a catalytic performance similar to fluidized microspheres in a reactor, without appreciable generation of fine particles.Type: GrantFiled: August 22, 2018Date of Patent: September 7, 2021Assignee: INSTITUTO MEXICANO DEL PETROLEOInventors: Blanca Lucia Medellin Rivera, Maria del Rosario Socorro Luna Ramirez, Edith Meneses Ruiz, Rogelio Hernandez Suarez, Agapito Alberto Neri Gomez, Guadalupe Hayde Moreno Vasquez, Gonzalo Hernandez Tapia, Roberto Garcia De Leon
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Patent number: 10953391Abstract: Provided is a Fluid Catalytic Cracking catalyst composition having increased propylene production with respect to other Fluid Catalytic Cracking catalysts (measured at constant conversion). The catalyst composition comprises a particulate which comprises (a) non-rare earth metal exchanged Y-zeolite in an amount in the range of about 5 to about 50 wt %, based upon the weight of the particulate; and (b) ZSM-5 zeolite in an amount in the range of about 2 to about 50 wt %, based upon the weight of the particulate.Type: GrantFiled: November 27, 2018Date of Patent: March 23, 2021Assignee: ALBEMARLE EUROPE SPRLInventors: Maria Margaret Ludvig, Erja Paivi Helena Rautiainen, Albert Carel Pouwels
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Patent number: 10894721Abstract: Methods and processes are provided to make clinoptilolite into a water-soluble solvolyzed form with electrolytes suitable for various administration routes for use in the detoxification and rejuvenation in environment arena, nutraceutical arena, and pharmaceutical arena This process includes oral, topical, tablet, pill formulas, biotech delivery and intravenous. Absorption of water-soluble solvolyzed clinoptilolite fragments can aid in detoxification by binding to heavy metals, viruses and environmental toxins and can reduce reactive oxygen species and inflammation related to metals. The process and method described can provide an increase in energy, increase in growth factors that aid in hair, skin, and nail growth, and can provide an increase in focus, concentration, and memory.Type: GrantFiled: October 15, 2015Date of Patent: January 19, 2021Assignee: Entox Solutions LLCInventor: Christina Rahm Cook
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Patent number: 10800978Abstract: The present disclosure relates to an additive and a catalyst composition for a catalytic cracking process of vacuum gas oil for preparing cracked run naphtha having reduced liquid olefin content, and increased propylene and butylene yields in the LPG fraction. The process makes use of a catalyst composition which is a mixture of an FCC equilibrated catalyst and an additive comprising a zeolite, phosphorus and a combination of metal promoters. The process is successful in achieving high propylene and butylene yields in the LPG fraction along with a lower liquid olefin content and increased aromatic content with increase in RON unit in the resultant cracked run naphtha, as compared to that achieved using an FCC equilibrated catalyst alone.Type: GrantFiled: June 1, 2016Date of Patent: October 13, 2020Assignee: Hindustan Petroleum Corporation LimitedInventors: Raman Ravishankar, Somnath Kukade, Peddy Venkata Chalapathi Rao, Nettem Venkateswarlu Choudary
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Patent number: 10786809Abstract: The present disclosure relates to an additive and a catalyst composition for a catalytic cracking process of vacuum gas oil for preparing cracked run naphtha having reduced liquid olefin content, and increased propylene and butylene yields in the LPG fraction. The process makes use of a catalyst composition which is a mixture of an FCC equilibrated catalyst and an additive comprising a zeolite, phosphorus and a combination of metal promoters. The process is successful in achieving high propylene and butylene yields in the LPG fraction along with a lower liquid olefin content and increased aromatic content with increase in RON unit in the resultant cracked run naphtha, as compared to that achieved using an FCC equilibrated catalyst alone.Type: GrantFiled: June 1, 2016Date of Patent: September 29, 2020Assignee: HINDUSTAN PETROLEUM CORPORATION LIMITEDInventors: Raman Ravishankar, Peddy Venkata Chalapathi Rao, Nettem Venkateswarlu Choudary
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Method and reactor containing perovskite for cracking hydrocarbon and method for coating the reactor
Patent number: 10696903Abstract: A reactor has an inner surface accessible to the hydrocarbon and comprising a sintered product of at least one of cerium oxide, zinc oxide, tin oxide, zirconium oxide, boehmite and silicon dioxide, and a perovskite material of formula: AaBbCcDdO3-?. 0<a<1.2, G?b?1.2, 0.9<a+b?1.2, O<c<1.2, 0?d?1.2, 0.9<c+d?1.2, ?0.5<?<0.5. A is selected from calcium, strontium, barium, and any combination thereof. B is selected from lithium, sodium, potassium, rubidium, and any combination thereof. C is selected from cerium, zirconium, antimony, praseodymium, titanium, chromium, manganese, ferrum, cobalt, nickel, gallium, tin, terbium and any combination thereof.Type: GrantFiled: February 6, 2019Date of Patent: June 30, 2020Assignee: General Electric CompanyInventors: Yanfei Gu, Wenqing Peng, Shizhong Wang, Chuan Lin, Lawrence Bernard Kool, Zhaoping Wu, Qijia Fu, Zhigang Deng -
Patent number: 10633596Abstract: A zeolite fluid catalytic cracking catalyst is provided that passivates nickel and vanadium during catalytic cracking. The zeolite fluid catalytic cracking catalyst includes Y-faujasite crystallized in-situ from a metakaolin-containing calcined microsphere. The zeolite fluid catalytic cracking catalyst further includes an alumina-containing matrix obtained by calcination of a dispersible crystalline boehmite and a kaolin contained in the metakaolin-containing calcined microsphere, where the dispersible crystalline boehmite has a crystallite size of less than 500 ?. Also provided are a method of reducing contaminant coke and hydrogen yields and a method of catalytic cracking of heavy hydrocarbon feed stocks.Type: GrantFiled: September 13, 2016Date of Patent: April 28, 2020Assignee: BASF CorporationInventors: Robert McGuire, Gary M. Smith, Bilge Yilmaz, Sven Serneels
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Patent number: 10449503Abstract: A temporary addition or injection system installed without the need for civil work comprising: one or more silos mounted on a trailer; optionally one or more transfer pots; and one or more control systems, wherein the one or more transfer pots and the one or more control systems are either (a) directly or indirectly connected to the one or more silos mounted on the trailer or (b) mounted adjacent to the one or more silos mounted on the trailer.Type: GrantFiled: February 28, 2015Date of Patent: October 22, 2019Inventors: Jason K. Smith, Emanuele Fratto, Fabio Novelli, Stefano C. Riva, Erik Wayne Johnson
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Patent number: 10407620Abstract: A reactor having an inner surface accessible to the hydrocarbon and providing a sintered product of at least one of cerium oxide, zinc oxide, tin oxide, zirconium oxide, boehmite and silicon dioxide, and a perovskite material of formula AaBbCcDdO3??. 0<a<1.2, 0?b?1.2, 0.9<a+b?1.2, 0<c<1.2, 0?d?1.2, 0.9<c+d?1.2, ?0.5<?<0.Type: GrantFiled: November 7, 2017Date of Patent: September 10, 2019Assignee: General Electric CompanyInventors: Yanfei Gu, Wenqing Peng, Shizong Wang, Chuan Lin, Lawrence Bernard Kool, Zhaoping Wu, Qijia Fu, Zhigang Deng
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Patent number: 10385280Abstract: The presently disclosed subject matter relates to systems and methods for catalyst regeneration. In particular, the presently disclosed subject matter provides for an integrated fluidized bed reactor and catalyst regeneration system to minimize hydrocarbon accumulation. In one embodiment, the presently disclosed subject matter provides for a fluidized bed reactor unit including a catalyst riser having a partially perforated surface in close proximity to a reactor stripper.Type: GrantFiled: February 23, 2016Date of Patent: August 20, 2019Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventor: Mustapha N. Karime
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Patent number: 10369556Abstract: An integrated process for gasoline production is described. The process includes introducing a feed comprising n-C5 hydrocarbons into a disproportionation reaction zone in the presence of a disproportionation catalyst to form a disproportionation mixture comprising iso-C4 and C6+ disproportionation products and unreacted n-C5 hydrocarbons. An iso-C4 hydrocarbon stream and an olefin feed are introduced into an alkylation reaction zone in the presence of an alkylation catalyst to produce an alkylation mixture comprising alkylate and unreacted iso-C4 paraffins. The disproportionation mixture and the alkylation mixture are combined, and the combined mixture is separated into at least a stream comprising the alkylate product, an iso-C4 stream, and an unreacted n-C5 hydrocarbon stream. The iso-C4 stream is recycled to the alkylation reaction zone, and the unreacted n-C5 hydrocarbon stream is recycled to the disproportionation reaction zone. The stream comprising the alkylate product is recovered.Type: GrantFiled: December 11, 2014Date of Patent: August 6, 2019Assignee: UOP LLCInventors: Tom N. Kalnes, Stuart Smith, Douglas A. Nafis, Alakananda Bhattacharyya, Bryan K. Glover, Susie C. Martins
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Patent number: 10323196Abstract: Methods and systems producing gasoline boiling range hydrocarbons from light paraffins are disclosed. Such methods may include exposing a paraffin-containing stream to a catalyst in a side riser of a fluid catalytic cracking reactor under effective conditions for dehydrogenating at least a portion of paraffins in the stream into olefins and thereby producing an olefin-containing stream, wherein the paraffin-containing stream comprises greater than 50 wt % isobutane; and alkylating olefins in the olefin-containing stream to produce a product stream comprising an alkylate fraction comprising hydrocarbons boiling between 100° F. and 400° F.Type: GrantFiled: March 5, 2018Date of Patent: June 18, 2019Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: William R. Gunther, Christopher G. Smalley, Brian A. Cunningham, James R. Bielenberg
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Patent number: 10307735Abstract: The present invention relates to an anti-coking catalyst having a physical property of reducing coke formation, which comprises a solid acid catalyst containing gadolinium (Gd) on the surface, a preparation method thereof, and a use thereof. The preparation method includes a first step of determining the amount of gadolinium (Gd) or a Gd-providing precursor to be used relative to the total weight of the solid acid catalyst, which reducing the coking of a specific solid acid catalyst below a specific level under a specific reaction condition; and a second step of preparing a Gd-containing solid acid catalyst using the amount determined in the first step. The catalyst according to the present invention is a catalyst in which an appropriate weight ratio of gadolinium is supported on the surface of a pure solid acid substance or solid acid substance on which a specific metal is supported.Type: GrantFiled: July 13, 2017Date of Patent: June 4, 2019Assignee: KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGYInventors: Sung Tak Kim, Geun Jae Kwak, Ki Won Jun, Ahron Hwang, Seok Chang Kang
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Patent number: 10280372Abstract: The present invention relates to a novel catalyst composition for catalytic cracking of hydrocarbon streams to enhance the yield of light olefins. The catalyst composition for the cracking of hydrocarbon feed streams to light olefins, comprises a USY zeolite with silica/alumina ratio of more than 40, pentasil zeolite, a phosphate compound and alumina silica binder. The yield of olefins is further increased when the catalyst composition is impregnated with a cerium oxide. The present invention also provides a process of increasing the yield of light olefins from hydrocarbon feed streams comprising contacting the hydrocarbon streams with catalyst compositions of the present invention.Type: GrantFiled: January 7, 2014Date of Patent: May 7, 2019Assignee: INDIAN OIL CORPORATION LIMITEDInventors: Biswanath Sarkar, Satyen Kumar Das, Somnath Kukade, Ganga Shankar Mishra, Eswar Prasad Dalai, Velusamy Chidambaram, Sudhir Kumar Pandey, Ram Mohan Thakur, Debasis Bhattacharyya, Santanam Rajagopal
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Patent number: 10272414Abstract: Na+-SAPO-34 sorbents were ion-exchanged with several individual metal cations for CO2 absorption at different temperatures (273-348 K) and pressures (<1 atm). In general, the overall adsorption performance of the exchanged materials increased as follows: Ce3+<Ti3+<Mg2+<Ca2+<Ag+<Na+<Sr2+. The strontium exchanged materials excelled at low-pressure ranges, exhibiting very sharp isotherms slopes at all temperatures. The Sr2+ species were responsible for the surface strong interaction and the cations were occupying exposed sites (SII?) in the materials Chabazite cages. All the sorbent materials exhibited higher affinity for CO2 over the other gases tested (i.e., CH4, H2, N2 and O2) due to strong ion-quadrupole interactions. Sr2+-SAPO-34 sorbents are by far the best option for CO2 removal from CH4 mixtures, especially at low concentrations.Type: GrantFiled: August 24, 2016Date of Patent: April 30, 2019Assignee: University of Puerto RicoInventors: Arturo J Hernandez-Maldonado, Milton E Rivera-Ramos, Ana G Arevalo-Hidalgo
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Patent number: 10093866Abstract: An improved hydrocarbon conversion catalyst is obtained through removal and modification by various means, of detrimental large and/or small particle fractions. Such modified fractions may be reused in the same or similar processes. The improved catalyst is advantageous to a wide range of hydrocarbon conversion processes.Type: GrantFiled: July 14, 2016Date of Patent: October 9, 2018Assignee: Quanta Technologies, LLCInventor: Augusto Rodolfo Quinones
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Patent number: 9850432Abstract: A reactor has an inner surface accessible to the hydrocarbon and comprising a sintered product of at least one of cerium oxide, zinc oxide, tin oxide, zirconium oxide, boehmite and silicon dioxide, and a perovskite material of formula AaBbCcDdO3-?. 0<a<1.2, 0?b?1.2, 0.9<a+b?1.2, 0<c<1.2, 0?d?1.2, 0.9<c+d?1.2, ?0.5<?<0.5. A is selected from calcium, strontium, barium, and any combination thereof. B is selected from lithium, sodium, potassium, rubidium, and any combination thereof. C is selected from cerium, zirconium, antimony, praseodymium, titanium, chromium, manganese, ferrum, cobalt, nickel, gallium, tin, terbium and any combination thereof.Type: GrantFiled: December 5, 2011Date of Patent: December 26, 2017Assignee: General Electric CompanyInventors: Yanfei Gu, Wenqing Peng, Shizhong Wang, Chuan Lin, Lawrence Bernard Kool, Zhaoping Wu, Qijia Fu, Zhigang Deng
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Patent number: 9816037Abstract: A method is provided for increasing production of middle distillate hydrocarbons from conversion of a heavy hydrocarbon feed in a fluid catalytic cracking system having a primary riser and a secondary riser, wherein the method comprises providing regenerated catalyst to the primary riser and operating the primary riser under severe conditions and providing spent catalyst to the secondary riser and operating the secondary riser under moderate conditions.Type: GrantFiled: September 22, 2014Date of Patent: November 14, 2017Assignee: UOP LLCInventor: Fariha Avais
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Patent number: 9782760Abstract: Disclosed herein is a method of making activated EU-2 zeolite, including: pores having a diameter of 30 to 40 ? while maintaining the crystal structure of the EU-2 zeolite; and pores having a diameter of 40 to 200 ?, wherein the volume of the pores having a diameter of 30 to 40 ? is 0.01 to 0.06 cc/g, and the volume of the pores having a diameter of 40 to 200 ? is 0.07 to 0.4 cc/g.Type: GrantFiled: May 25, 2017Date of Patent: October 10, 2017Assignees: SK INNOVATION CO., LTD., SK LUBRICANTS CO., LTD.Inventors: Yoon Kyung Lee, Seung Woo Lee, Jae Suk Choi, Tae Jin Kim, Do Woan Kim, Seon Ju Lim
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Patent number: 9777228Abstract: A process and apparatus is for recycling HCO and/or naphtha from a first FCC unit to a second FCC unit to recover additional distillate and/or light olefins. A first catalyst stream for the first FCC unit may be isolated from a second catalyst stream for the second FCC unit. Fractionation of second cracked products from the second FCC unit may be separate from fractionation of first cracked products from the first FCC unit.Type: GrantFiled: May 3, 2016Date of Patent: October 3, 2017Assignee: UOP LLCInventor: Lev Davydov
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Patent number: 9637688Abstract: The present invention provides a metal passivator/trap comprising a rare earth oxide dispersed on a matrix containing a calcined hydrous kaolin.Type: GrantFiled: March 3, 2015Date of Patent: May 2, 2017Assignee: BASF CorporationInventors: Qi Fu, Walter Babbitt, Mark Schmalfeld, Chandrashekhar Pandurang Kelkar
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Patent number: 9580664Abstract: The present invention relates to a catalytic conversion process for improving the product distribution, characterized in that a feedstock oil of good quality is contacted with a hot regenerated catalyst having a lower activity in a reactor to carry out a cracking reaction, the reaction product is separated from the spent catalyst to be regenerated, then the reaction product is fed into a separation system, and the spent catalyst to be regenerated is stripped, regenerated and recycled in the process. The isobutene content in the liquefied petroleum gas (LPG) produced by the process is increased by a factor of more than 30%, and the olefin content in the gasoline composition may be increased to more than 30 wt. %. The product distribution is optimized, and the yields of dry gas and coke are decreased, so as to sufficiently utilize the petroleum resources.Type: GrantFiled: September 23, 2011Date of Patent: February 28, 2017Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPECInventors: Youhao Xu, Shouye Cui, Siwei Liu, Nan Jiang, Yinliang Liu
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Patent number: 9573859Abstract: The present invention relates to a process to make light olefins and aromatics, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising: a0) providing a first portion and a second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock, a) providing a catalyst comprising zeolitic molecular sieves containing at least 10 membered ring pore openings or larger in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting the first portion of said oxygen-containing, halogenide-containing or sulphur-contType: GrantFiled: December 4, 2014Date of Patent: February 21, 2017Assignee: TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Nikolai Nesterenko, Walter Vermeiren, Giacomo Grasso, Sander Van Donk, Wolfgang Garcia
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Patent number: 9573860Abstract: The present invention relates to a process to make light olefins, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising: a) providing a catalyst comprising zeolitic molecular sieves containing 10 member and larger channels in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the XTO reactor with the catalyst at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a hType: GrantFiled: December 10, 2014Date of Patent: February 21, 2017Assignee: TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Nikolai Nesterenko, Walter Vermeiren, Giacomo Grasso, Sander Van Donk, Wolfgang Garcia
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Patent number: 9561990Abstract: The present invention relates to a process to make light olefins, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising: a0) providing a first portion and a second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock, a) providing a catalyst comprising zeolitic molecular sieves containing at least 10 membered ring pore openings or larger in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting the first portion of said oxygen-containing, halogenide-containing or sulphur-containing organicType: GrantFiled: December 4, 2014Date of Patent: February 7, 2017Assignee: Total Research Technology FeluyInventors: Nikolai Nesterenko, Walter Vermeiren, Giacomo Grasso, Sander Van Donk, Wolfgang Garcia
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Patent number: 9556082Abstract: The present invention relates to a process to make light olefins, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising: a0) providing a first portion and a second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock, a) providing a catalyst comprising zeolitic molecular sieves containing at least 10 membered ring pore openings or larger in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, optionally at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting the first portion of said oxygen-containing, halogenide-containing or sulphur-containType: GrantFiled: December 4, 2014Date of Patent: January 31, 2017Assignee: TOTAL RESEARCH TECHNOLOGY FELUYInventors: Nikolai Nesterenko, Walter Vermeiren, Giacomo Grasso, Sander Van Donk, Wolfgang Garcia
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Patent number: 9468918Abstract: An aluminum phosphate-modified metal-supported crystalline silicoaluminophosphate NOx-reducing catalyst includes metal-supported crystalline silicoaluminophosphate particles having a surface modified with aluminum phosphate.Type: GrantFiled: May 1, 2015Date of Patent: October 18, 2016Assignee: JGC CATALYSTS AND CHEMICALS LTD.Inventors: Tomohiro Mitsui, Yuka Seto, Takaki Mizuno, Tsuguo Koyanagi
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Patent number: 9440222Abstract: Provided is a production method for a porous alumina material, comprising the steps of: mixing an alkoxysilane solution that comprises an alkoxysilane, a mixed solvent comprising water and an alcohol, and an inorganic acid, with an aluminum solution comprising an aluminum compound and water, to prepare a mixed solution in which the aluminum compound and the alkoxysilane are dissolved in the mixed solvent; co-precipitating aluminum hydroxide with a silicon compound in the mixed solution, to form a precipitate; and baking the precipitate to form a porous alumina material comprising aluminum oxide and silicon oxide.Type: GrantFiled: January 13, 2012Date of Patent: September 13, 2016Assignees: Renaissance Energy Research Corporation, Institute of National Colleges of Technology, JapanInventors: Akira Hasegawa, Osamu Okada, Chihiro Ito
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Patent number: 9433912Abstract: The invention provides for a process and apparatus for simultaneous conversion of lighter and heavier hydrocarbon feedstocks into improved yields of light olefins in the range of C2 to C4, liquid aromatics in the range C6 to C8 mainly benzene, toluene, xylene and ethyl benzene and other useful products employing at least two different reactors operated in series with respect to catalyst flow and parallel with respect to feed flow under different regimes and process conditions with same catalyst system.Type: GrantFiled: March 30, 2011Date of Patent: September 6, 2016Assignee: INDIAN OIL CORPORATION LIMITEDInventors: Saravanan Subramani, Debasis Bhattacharyya, Reshmi Manna, Satyen Kumar Das, Tridib Sarkar, Santanam Rajagopal
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Patent number: 9428698Abstract: A process and an apparatus used in the catalytic reaction process with feed of petroleum hydrocarbons or alcohols for controlling catalyst in reaction zones, purifying, heat transferring and cooling regenerant are provided. The apparatus comprises a catalyst regenerator, an external heat exchanger, a purifying controller for regenerant, a reactor and catalyst conveying pipes. The regenerator is connected with the external heat exchanger and the purifying controller for regenerant respectively, and the purifying controller for regenerant is connected with the reactor via two conveying pipes.Type: GrantFiled: November 6, 2013Date of Patent: August 30, 2016Inventor: Baozhen Shi
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Patent number: 9403735Abstract: The present invention provides a fluidized bed reactor and its use for producing olefins from oxygenates, the fluidized bed reactor comprises: a reaction zone located in the lower portion of the fluidized bed reactor and comprising a lower dense phase zone and an upper riser, wherein the dense phase zone and the riser are connected with each other transitionally; a separation zone located in the upper portion of the fluidized bed reactor and comprising a settling chamber, a fast gas-solid separation means, a cyclone and a gas collecting chamber, wherein the riser extends upwardly into the separation zone and is connected at its outlet with the inlet of the fast gas-solid separation means, the fast gas-solid separation means is connected at its outlet with the inlet of the cyclone via a fast gas passage, the cyclone is connected at its outlet with the gas collecting chamber, and the gas collecting chamber is located below the reactor outlet and connected therewith; and a catalyst recycle line for recycling theType: GrantFiled: May 30, 2012Date of Patent: August 2, 2016Assignees: FUDE (BEIJING) CHEMICAL & INDUSTRY CO., LTD, TSINGHUA UNIVERSITYInventors: Fei Wei, Xiaobo Wei, Yao Wang, Chang Zhu
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Patent number: 9393556Abstract: An improved hydrocarbon conversion catalyst is obtained through removal and modification by various means, of detrimental large and/or small particle fractions. Such modified fractions may be reused in the same or similar processes. The improved catalyst is advantageous to a wide range of hydrocarbon conversion processes.Type: GrantFiled: March 16, 2012Date of Patent: July 19, 2016Inventor: Augusto Rodolfo Quinones
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Patent number: 9333494Abstract: A process for producing catalyst for biomass catalytic cracking is disclosed herein. The process includes modifying a phyllosilicate to produce a modified phyllosilicate having an improved yield of a pyrolysis reaction. The modification of the phyllosilicate includes leaching the clay with an acid or basic solution to form a leached clay preparation, calcining the leached clay and contacting the treated clay with a suspension comprising metal ions for ion-exchange. The modified clay catalyst can then be mixed with inorganic materials such as zeolites and dried to form fluidizable microspheres.Type: GrantFiled: March 7, 2012Date of Patent: May 10, 2016Assignee: Inaeris Technologies, LLCInventors: Robert Bartek, Michael Brady, Dennis Stamires
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Patent number: 9327277Abstract: The present invention provides a fibrous IM-5 molecular sieve and the preparation process thereof. According to the process according to the present invention, by adding an appropriate amount of a quaternary ammonium salt with a long carbon chain to the preparation system so as to occur a synergistic action with the organic templet agent, an IM-5 molecular sieve which would be otherwise a rodlike form is converted into the fibrous form. The IM-5 molecular sieve according to the present invention has an aspect ratio greater than that of the rodlike IM-5 molecular sieve obtained according to the prior art, such that the proportion of the exposed periphery crystal face is higher, which benefit to increasing the selectivity of the catalytic reaction for the corresponding crystal face.Type: GrantFiled: October 30, 2012Date of Patent: May 3, 2016Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, FUSHUN RESEARCH INSTITUTE OF PETROLEUM AND PETROCHEMICALS, SINOPECInventors: Weiya Yang, Fengxiang Ling, Shaojun Wang, Zhiqi Shen
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Patent number: 9126884Abstract: A method for controlling 2-isomer content in linear alkylbenzene obtained by alkylating benzene with olefins and catalyst used in the method.Type: GrantFiled: October 14, 2013Date of Patent: September 8, 2015Assignee: UOP LLCInventors: Mark G. Riley, Deng-Yang Jan, Stephen W. Sohn
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Publication number: 20150096922Abstract: A process for reactivating an iron-contaminated FCC catalyst is disclosed. The process comprises contacting the iron-contaminated FCC catalyst with an iron transfer agent. The iron transfer agent comprises a magnesia-alumina hydrotalcite material that contains a modifier selected from the group consisting of calcium, manganese, lanthanum, iron, zinc, or phosphate.Type: ApplicationFiled: October 3, 2014Publication date: April 9, 2015Inventors: Paul DIDDAMS, Mehdi ALLAHVERDI, Elbert Arjan DE GRAAF
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Patent number: 8932456Abstract: An integrated process for the manufacture of olefins and intermediates for the production of ammonia and urea, comprising an FCC reactor, a regenerator, a steam reforming unit, an air-separation unit, an ammonia production unit and a urea production unit, is described. This process makes it possible to minimize CO2 emissions to atmosphere, make use of heavy feedstocks of low added value (AR) for the production of light olefins, in addition to making maximum use of all the flows involved, thus increasing the energy efficiency achieved, all at the same time.Type: GrantFiled: October 21, 2009Date of Patent: January 13, 2015Assignee: Petroleo Brasileiro S.A.—PetrobrasInventors: Leonardo Fialho de Mello, Oscar Rene Chamberlain Pravia, Gustavo Torres Moure
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Patent number: 8933286Abstract: A process is described for maximization of light olefins, preferably ethylene, by the catalytic cracking of feeds of saturated hydrocarbons, with molecular size in the range from 4 to 6 carbon atoms. The process uses a catalyst based on a zeolite of type ZSM-5 with low sodium content and modified with nickel, with concentration by weight of nickel, expressed in the form of oxide, in the range from 0.1% to 20% relative to the weight of zeolite in the catalyst, and operating conditions that involve a temperature between 400° C. and 650° C. and feed partial pressure between 0.1 and 1.0 MPa, so that the product recovered is rich in light olefins, with ethylene/propylene ratio in the range from 0.25 to 2.00.Type: GrantFiled: November 23, 2009Date of Patent: January 13, 2015Assignee: Petroleo Brasileiro S.A.—PetrobrasInventors: Aline Barbosa Junqueira de Souza, Marcelo Maciel Pereira, Lam Yiu Lau, Janaina Gorne, Andrea de Rezende Pinho
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Patent number: 8901026Abstract: A catalytic cracking catalyst composition is disclosed that is suitable for reducing the sulfur content of catalytically cracking liquid products, in particularly gasoline products, produced during a catalytic cracking process. Preferably, the catalytic cracking process is a fluidized catalytic cracking (FCC) process. The composition comprises zeolite, zinc and at least one rare earth element having an ionic radius of less than 0.95 ? at a coordination number of 6. Preferably, zinc and the rare earth element are present as cations that have been exchanged on the zeolite. The zeolite is preferably a Y-type zeolite.Type: GrantFiled: January 28, 2008Date of Patent: December 2, 2014Assignee: W. R. Grace & Co.-Conn.Inventors: Richard Franklin Wormsbecher, Ruizhong Hu
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Patent number: 8895790Abstract: A catalyst composition useful for producing olefins and aromatic compounds from a feedstock is formed from a fluidized catalytic cracking (FCC) catalyst and a ZSM-5 zeolite catalyst, wherein the amount of ZSM-5 zeolite catalyst makes up from 10 wt. % or more by total weight of the FCC catalyst and the ZSM-5 zeolite catalyst. The catalyst composition may be used in a method of producing olefins and aromatic compounds from a feedstock by introducing a hydrocarbon feedstock and the catalyst composition within a reactor, at least a portion of the reactor being at a reactor temperature of 550° C. or higher. The feedstock and catalyst composition are introduced into the reactor at a catalyst-to-feed (C/F) ratio of from 6 or greater.Type: GrantFiled: February 12, 2013Date of Patent: November 25, 2014Assignee: Saudi Basic Industries CorporationInventors: Ravichander Narayanaswamy, Krishna Kumar Ramamurthy, P. S. Sreenivasan
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Patent number: 8859836Abstract: A crystalline molecular sieve of MFS framework type manufactured by the method disclosed herein. A hydrocarbon conversion process using the crystalline molecular sieve is disclosed.Type: GrantFiled: May 1, 2012Date of Patent: October 14, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: Machteld M. Mertens, An Verberckmoes, Ivy D. Johnson
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Patent number: 8845882Abstract: Catalytic cracking catalyst compositions and processes for cracking hydrocarbons to maximize light olefins production are disclosed. Catalyst compositions comprise at least one zeolite having catalytic cracking activity under catalytic cracking conditions, preferably Y-type zeolite, which zeolite has low amounts of yttrium in specified ratios to rare earth metals exchanged on the zeolite. Catalyst and processes of the invention provide increased yields of light olefins and gasoline olefins during a FCC process as compared to conventional lanthanum containing Y-type zeolite FCC catalysts.Type: GrantFiled: March 8, 2011Date of Patent: September 30, 2014Assignee: W. R. Grace & Co.-Conn.Inventors: Yuying Shu, Richard F. Wormsbecher, Wu-Cheng Cheng
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Patent number: 8840779Abstract: A supported catalyst comprises a zeolite having a silica to alumina molar ratio of 500 or less, a first metal oxide binder having a crystallite size greater than 200 ? and a second metal oxide binder having a crystallite size less than 100 ?, wherein the second metal oxide binder is present in an amount less than 15 wt % of the total weight of the catalyst.Type: GrantFiled: February 7, 2011Date of Patent: September 23, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: Stephen J. McCarthy, Wenyih F. Lai, Darryl Donald Lacy, Robert Ellis Kay
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Catalyst for converting acid-containing inferior crude oil and process for making and using the same
Patent number: 8809216Abstract: The present invention relates to a catalyst for converting inferior acid-containing crude oil. Based on the total amount of the catalyst, said catalyst comprises from 1 to 50 wt % of a mesopore material, from 1 to 60 wt % of molecular sieves and from 5 to 98 wt % of thermotolerant inorganic oxides and from 0 to 70 wt % of clays. Said mesopore material is an amorphous material containing alkaline earth oxide, silica and alumina, and has an anhydrous chemical formula of (0-0.3)Na2O.(1-50)MO.(6-58)Al2O3.(40-92)SiO2, based on the weight percent of the oxides, wherein M is one or more selected from Mg, Ca and Ba. Said mesopore material has a specific surface area of 200-400 m2/g, a pore volume of 0.5-2.0 ml/g, an average pore diameter of 8-20 nm, and a most probable pore size of 5-15 nm. The catalyst provided in the present invention is suitable for the catalytic conversion of crude oil having a total acid number of greater than 0.Type: GrantFiled: January 9, 2009Date of Patent: August 19, 2014Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing, SinopecInventors: Jun Long, Jiushun Zhang, Huiping Tian, Yuxia Zhu