Gravitating Compact Beds Patents (Class 208/165)
  • Patent number: 11059010
    Abstract: A tube heat exchange reactor for carrying out an endothermic catalytic reaction. The tube heat exchange reactor includes: an outer tube with a first and a second end, where the first end is an inlet end and where the second end is a closed end, an inner tube coaxially arranged within the outer tube and spaced apart from the outer tube, where at least a part of the inner tube holds a bed of catalyst material susceptible for induction heating and where the inner tube has an inlet end and an outlet end, an induction coil placed within the annular space confined between the outer and the inner tube, and a power source arranged to supply alternating current to the induction coil in order to generate an alternating magnetic field within at least a part of the inner tube.
    Type: Grant
    Filed: March 28, 2017
    Date of Patent: July 13, 2021
    Assignee: HALDOR TOPSØE A/SE
    Inventors: Peter Mølgaard Mortensen, Poul Erik Højlund Nielsen, Kim Aasberg-Petersen, Martin Østberg
  • Patent number: 10618022
    Abstract: The present invention describes a type of inclined bed reactor which permits a small quantity of catalyst to be employed. Application of the reactor to a regenerative reforming process.
    Type: Grant
    Filed: March 2, 2016
    Date of Patent: April 14, 2020
    Assignee: IFP Energies nouvelles
    Inventors: Joana Fernandes, Julien Gornay, Alexandre Pagot, Fabian Lambert, Pierre-Yves Martin, Christophe Pierre, Francois Sala
  • Patent number: 10350565
    Abstract: Disclosed herein is a catalyst dumping spool assembly for unloading used catalyst from an inside of a reactor, comprising: a reactor, and a catalyst dumping spool comprising a first end operatively connected to the reactor, the first end having a catalyst inlet through which the used catalyst is introduced into, a second end having a catalyst discharge outlet whereby the used catalyst exits the catalyst dumping spool, wherein a first device for controlling used catalyst transfer into the catalyst inlet is positioned proximate the first end, and a second device for controlling the used catalyst transfer from inside the catalyst inlet through the catalyst discharge outlet is positioned proximate the second end, and further wherein the catalyst dumping spool further comprise a gas fluidization inlet and a water fluidization inlet located between the first and second devices.
    Type: Grant
    Filed: March 3, 2017
    Date of Patent: July 16, 2019
    Assignee: Chevron U.S.A. Inc.
    Inventors: Jeff William Johns, Douglas Gayle McDaniel, Anthony Terrell Tanner, Edward Earl Eden, Jr.
  • Patent number: 8759600
    Abstract: Apparatuses and methods are disclosed for contacting radially flowing fluids with solid particles (e.g., catalyst) with reduced tendency for fluidization of the particles, and especially a sealing portion of the particles at the top of a particle retention zone disposed between screens at upstream and downstream positions relative to radial fluid flow. Fluidization is reduced or eliminated by offsetting openings of the screens in the axial direction, such that upstream openings in the upstream screen are above highest downstream openings in a downstream stream. The offset in openings imparts a downward flow component to radially flowing fluid, thereby reducing solid particle fluidization without the need to induce a specific pressure drop profile along the entire axial direction of the screens.
    Type: Grant
    Filed: June 28, 2010
    Date of Patent: June 24, 2014
    Assignee: UOP LLC
    Inventors: Bing Sun, Paul A. Sechrist
  • Patent number: 8747768
    Abstract: An apparatus for contacting a bed of particulate material with a cross flowing fluid, which maintains the bed of particulate material within a retention volume. The apparatus includes partitions for retaining particles, with apertures disposed within the partitions. The apertures are covered by louvers that extend above the edges of the apertures to prevent solid particles from spilling through inlet apertures.
    Type: Grant
    Filed: February 24, 2010
    Date of Patent: June 10, 2014
    Assignee: UOP LLC
    Inventors: Bryan K. Glover, Guy B. Woodle, Joseph E. Zimmermann, John J. Senetar
  • Patent number: 8535542
    Abstract: A method of separating a mixture of liquid and insoluble solids in a filter press may comprise: pumping the mixture into a chamber between two filter plates in the filter press to form a filter cake, wherein the chamber is lined by filter cloths, and wherein, during the pumping, filtrate is forced through the filter cloths and out of the chamber; heating the filter cake in the chamber, wherein, during the heating, filtrate is forced through the filter cloths and out of the chamber, and wherein the heating is by radio frequency irradiation of the filter cake in the chamber; and releasing dried filter cake from the chamber.
    Type: Grant
    Filed: November 2, 2009
    Date of Patent: September 17, 2013
    Inventors: Daniel J. Simpson, Ferdinand Kogler
  • Patent number: 7638664
    Abstract: One exemplary embodiment can include a hydrocarbon conversion process. Generally, the process includes passing a hydrocarbon stream through a hydrocarbon conversion zone comprising a series of reaction zones. Typically, the hydrocarbon conversion zone includes a staggered-bypass reaction system having a first, second, third, and fourth reaction zones, which are staggered-bypass reaction zones, and a fifth reaction zone, which can be a non-staggered-bypass reaction zone, subsequent to the staggered-bypass reaction system.
    Type: Grant
    Filed: October 29, 2008
    Date of Patent: December 29, 2009
    Assignee: UOP LLC
    Inventors: Kenneth D. Peters, Clayton C. Sadler
  • Patent number: 7622620
    Abstract: One exemplary embodiment can include a hydrocarbon conversion process. Generally, the process includes passing a hydrocarbon stream through a hydrocarbon conversion zone comprising a series of reaction zones. Typically, the hydrocarbon conversion zone includes a staggered-bypass reaction system having a first, second, third, and fourth reaction zones, which are staggered-bypass reaction zones, and a fifth reaction zone, which can be a non-staggered-bypass reaction zone, subsequent to the staggered-bypass reaction system.
    Type: Grant
    Filed: December 22, 2006
    Date of Patent: November 24, 2009
    Assignee: UOP LLC
    Inventors: Kenneth D. Peters, Clayton C. Sadler
  • Patent number: 7399450
    Abstract: A fluidized-bed reactor is disclosed. The fluidized-bed reactor steadies the gas flow through the fluidized bed chamber of the reactor. The swirl chamber of the reactor consists of a conical housing in which a conical insert is also situated. This creates an annular gap between the housing and the insert, which acts as the swirl chamber and which, according to the geometry of the two components, causes a velocity of the gas flow which remains the same along the height, which increases or which decreases. Such a reactor can also be called a constant annular-gap reactor.
    Type: Grant
    Filed: March 16, 2005
    Date of Patent: July 15, 2008
    Inventor: Sebastian Zimmer
  • Patent number: 7279138
    Abstract: A horizontal chemical reactor comprises at least one catalytic bed (5a-5d) arranged horizontally in the reactor and comprising a lower gas-permeable wall (6) for gas outlet, and a holding element (2) of the at least one catalytic bed.
    Type: Grant
    Filed: March 19, 2004
    Date of Patent: October 9, 2007
    Assignee: Methanol Casale S.A.
    Inventors: Giorgio Pagani, Enrico Rizzi, Umberto Zardi
  • Patent number: 6814857
    Abstract: A process for contacting a bed of particulate material, usually catalyst, with a transverse flow of fluid is disclosed. The particulate material moves or is prevented from not moving, while the fluid passes through the bed at a rate greater than the stagnant bed pinning flow rate. This invention is applicable to hydrocarbon conversion processes and allows for higher fluid throughput rates compared to prior art processes.
    Type: Grant
    Filed: January 31, 2002
    Date of Patent: November 9, 2004
    Assignee: UOP LLC
    Inventors: Weikai Gu, Paul A. Sechrist
  • Patent number: 6612731
    Abstract: An apparatus for mixing a fluid feed stock, such as a heavy oil, and particles of a catalyst for gasifying the heavy oil in a reactor, comprises the reactor having in the upper portion a circular port through which the particles are fed, a moving bed-forming section disposed on and in communication with the reactor for forming the particles into an annular or cylindrical high-velocity moving bed by dropping the particles downwardly into the reactor, while dispersing the particles radially, an external fluid feed section located so as to spray the feed stock over the entire upper outer periphery of the annular or cylindrical moving bed passing through the reactor, and an internal fluid-feed section located so as to spray the fluid over the entire upper inner periphery corresponding to the outer periphery of the annular moving bed.
    Type: Grant
    Filed: November 29, 2000
    Date of Patent: September 2, 2003
    Assignees: Nippon Oil Co., Ltd., Petroleum Energy Center
    Inventors: Shozo Nishida, Yuichiro Fujiyama
  • Patent number: 6186658
    Abstract: An apparatus for mixing a fluid feed stock, such as a heavy oil, and particles of a catalyst for gasifying the heavy oil in a reactor, comprises the reactor having in the upper portion a circular port through which the particles are fed, a moving bed-forming section disposed on and in communication with the reactor for forming the particles into an annular or cylindrical high-velocity moving bed by dropping the particles downwardly into the reactor, while dispersing the particles radially, an external fluid feed section located so as to spray the feed stock over the entire upper outer periphery of the annular or cylindrical moving bed passing through the reactor, and an internal fluid-feed section located so as to spray the fluid over the entire upper inner periphery corresponding to the outer periphery of the annular moving bed.
    Type: Grant
    Filed: March 13, 1998
    Date of Patent: February 13, 2001
    Assignees: Nippon Mitsubishi Oil Corporation, Petroleum Energy Center
    Inventors: Shozo Nishida, Yuichiro Fujiyama
  • Patent number: 6010620
    Abstract: An arrangement for the controlled production of an essentially linear array of hydrocarbon feed injection jets maintains stable and reliable jets by passing individual piping for each jet through a support shroud that is located in a contacting vessel. Controlled atomization is provided by independently injecting a uniform quantity of gas medium into each of the plurality of uniformly created feed injection streams upstream of a discharge nozzle that separately discharges each mixed stream of hydrocarbons and gas medium into a stream of catalyst particles at or about the inner end of the support shroud. The feed injection jets are suitable for positioning in an inner location of large contacting vessel. Uniformity of distribution is obtained by dividing the hydrocarbons streams from an oil header into an individual oil conduit for each spray injection nozzle.
    Type: Grant
    Filed: November 11, 1997
    Date of Patent: January 4, 2000
    Assignee: UOP LLC
    Inventors: Daniel N. Myers, Aziz A. Sattar
  • Patent number: 5948240
    Abstract: A process for contacting reactants with a particulate catalyst while indirectly contacting the reactants with a heat exchange medium amid simultaneous exchange of catalyst particles by an operation that sequentially restricts reactant flow while moving catalyst through reaction stacks in which the reactant flow has been restricted. The process permits a change out of catalyst in a channel type reactor arrangement that would normally restrict catalyst flow during operation. Moving catalyst through a heat exchange type reactor having reactant and heat exchange channels permits control of catalyst activity as well as temperatures.
    Type: Grant
    Filed: November 17, 1997
    Date of Patent: September 7, 1999
    Assignee: UOP LLC
    Inventors: Robert C. Mulvaney, III, Kevin J. Brandner, Steven T. Arakawa, Paul Anderson
  • Patent number: 5840176
    Abstract: A method for replacing particles in a process that transfers particles is disclosed. This invention employs a seal zone which is in communication with two zones of the process and in which particles that are being added to the process are purged. This invention allows particles to be replaced without reducing the normal rate of particle transfer through the process, which results in a savings in downtime costs. This invention is adaptable to a multitude of processes for the catalytic conversion of hydrocarbons in which deactivated catalyst particles are regenerated.
    Type: Grant
    Filed: August 12, 1996
    Date of Patent: November 24, 1998
    Assignee: UOP LLC
    Inventors: Roger R. Lawrence, Frank T. Micklich, Charles T. Ressl, Paul A. Sechrist
  • Patent number: 5733440
    Abstract: This invention makes possible substantially continuous flow of uniformly distributed hydrogen and hydrocarbon liquid across a densely packed catalyst bed to fill substantially the entire volume of a reactor vessel by introducing the fluids as alternate annular rings of gas and liquid (i.e. a mixture of liquid hydrocarbon and a hydrogen-containing gas) at a rate insufficient to levitate or ebullate the catalyst bed. Catalyst are selected by density, shape and size at a design feed rate of liquids and gas to prevent ebullation of the packed bed at the design feed rates. Catalysts are selected by measuring bed expansion, such as in a large pilot plant run, with hydrocarbon, hydrogen, and catalyst at the design pressures and flow velocities. The liquid and gas components of the feed flow into the bed in alternate annular rings across the full area of the bed.
    Type: Grant
    Filed: November 14, 1996
    Date of Patent: March 31, 1998
    Assignee: Chevron U.S.A. Inc.
    Inventors: Bruce E. Stangeland, David C. Kramer, David S. Smith, James T. McCall, Georgieanna L. Scheuerman, Robert W. Bachtel, David R. Johnson
  • Patent number: 5660715
    Abstract: This invention makes possible substantially continuous flow of uniformly distributed hydrogen and hydrocarbon liquid across a densely packed catalyst bed which substantially fills the entire volume of a reactor vessel. Catalyst are selected to be essentially the same density, shape and size at a design feed rate of liquids and gas to prevent ebullation of the packed catalyst bed at the design feed rates. The liquid and gas components of the hydrocarbon feed stream flow into the bed of catalyst and a quenching medium, which is preferably a liquid, is injected into the bed of catalyst. Injection of a liquid quench reduces the gas component of the hydrocarbon feed stream while simultaneously increasing the residence time and reducing the liquid velocity of the liquid component of the hydrocarbon feed stream within the substantially packed bed of catalyst.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: August 26, 1997
    Assignee: Chevron U.S.A. Inc.
    Inventors: Harold J. Trimble, Bruce E. Reynolds, Robert W. Bachtel, Robert J. Klett, David N. Brossard, David E. Earls
  • Patent number: 5599440
    Abstract: This invention makes possible substantially continuous flow of uniformly distributed hydrogen and hydrocarbon liquid across a densely packed catalyst bed to fill substantially the entire volume of a reactor vessel by introducing the fluids as alternate annular rings of gas and liquid (i.e. a mixture of liquid hydrocarbon and a hydrogen-containing gas) at a rate insufficient to levitate or ebullate the catalyst bed. Catalyst are selected by density, shape and size at a design feed rate of liquids and gas to prevent ebullation of the packed bed at the design feed rates. Catalysts are selected by measuring bed expansion, such as in a large pilot plant run, with hydrocarbon, hydrogen, and catalyst at the design pressures and flow velocities. The liquid and gas components of the feed flow into the bed in alternate annular rings across the full area of the bed.
    Type: Grant
    Filed: June 30, 1995
    Date of Patent: February 4, 1997
    Assignee: Chevron U.S.A. Inc.
    Inventors: Bruce E. Stangeland, David C. Kramer, David S. Smith, James T. McCall, Georgieanna L. Scheuerman, Robert W. Bachtel, David R. Johnson
  • Patent number: 5545312
    Abstract: A method and apparatus for replacing particles in a process that transfers particles is disclosed. This invention employs a seal zone which is in communication with two zones of the process and in which particles that are being added to the process are purged. This invention allows particles to be replaced without reducing the normal rate of particle transfer through the process, which results in a savings in downtime costs. This invention is adaptable to a multitude of processes for the catalytic conversion of hydrocarbons in which deactivated catalyst particles are regenerated.
    Type: Grant
    Filed: May 6, 1994
    Date of Patent: August 13, 1996
    Assignee: UOP
    Inventors: Roger R. Lawrence, Frank T. Micklich, Charles T. Ressl, Paul A. Sechrist
  • Patent number: 5492617
    Abstract: This invention makes possible substantially continuous flow of uniformly distributed hydrogen and hydrocarbon liquid across a densely packed catalyst bed which substantially fills the entire volume of a reactor vessel. Catalyst are selected to be essentially the same density, shape and size at a design feed rate of liquids and gas to prevent ebullation of the packed catalyst bed at the design feed rates. The liquid and gas components of the hydrocarbon feed stream flow into the bed of catalyst and a quenching medium, which is preferably a liquid, is injected into the bed of catalyst. Injection of a liquid quench reduces the gas component of the hydrocarbon feed stream while simultaneously increasing the residence time and reducing the liquid velocity of the liquid component of the hydrocarbon feed stream within the substantially packed bed of catalyst.
    Type: Grant
    Filed: July 11, 1994
    Date of Patent: February 20, 1996
    Inventors: Harold J. Trimble, Bruce E. Reynolds, Robert W. Bachtel, Robert J. Klett, David N. Brossard, David E. Earls
  • Patent number: 5409598
    Abstract: On-stream catalyst replacement hydroprocessing method wherein an upstream mixture of hydrogen and hydrocarbon liquid counter flows through a downwardly moving bed of hydroprocessing catalyst in a reactor vessel. The mixed feed stream of hydrogen and liquid hydrocarbon components enters a surge zone between the lower end of the reactor and a plenum zone to form a common pool under a conical support for the lower end of the downflowing catalyst bed. The mixed feed enters the plenum chamber through a plurality of passageways extending downwardly from the plenum zone to the same depth adjacent the lower end of the surge zone so that the liquid component normally prevents hydrogen from establishing independent paths before entering the plenum zone. Separation of the hydrogen and hydrocarbon liquid components from the mixed feed is thus assured to occur in the plenum zone directly below the pervious conical support to form a plurality of stepped concentric local reservoir rings under the conical support.
    Type: Grant
    Filed: March 21, 1994
    Date of Patent: April 25, 1995
    Assignee: Chevron Research Company
    Inventors: David C. Kramer, Bruce E. Stangeland, David S. Smith, James T. McCall, Georgieanna Scheuerman, Robert W. Bachtel
  • Patent number: 5277880
    Abstract: Apparatus for regenerating spent hydrocarbon conversion catalyst. Catalyst particles in a vertically-elongated movable tapered bed are contacted with a hot oxygen-containing gas stream in order to remove, by means of combustion, coke which accumulated on the catalyst particles while they were used in a hydrocarbon conversion zone. Catalyst moves downward under the influence of gravity. The catalyst bed is tapered such that the thickness of the bed, in a dimension which is transverse to the direction of catalyst movement, varies from a minimum at the top of the tapered bed to a maximum at the bottom of the tapered bed. Gas passes through the tapered bed in a direction which is substantially transverse to the direction of catalyst movement. Substantially, all of the catalyst in the bed is in contact with the flowing gas.
    Type: Grant
    Filed: January 27, 1992
    Date of Patent: January 11, 1994
    Assignee: UOP
    Inventors: Paul A. Sechrist, William J. Koves
  • Patent number: 5089115
    Abstract: Method for effecting contact of a gas with light particles of solid matter, where the particles are retained within particle retention screens to form a bed of particles and the particles move downward in plug flow by means of gravity. When the particles are light, that is, of relatively small size and low density, the velocity of the gas may be sufficiently high that downward movement of particles is hindered by the horizontal forces exerted on the particles by the flowing gas. This invention provides that gas flows through the bed of particles in a downwardly sloping direction instead of in a horizontal direction, so that the force exerted on a particle has a horizontal component and a downward vertical component. The vertical component of the force resulting from gas flow, along with the gravity force on a particle, is sufficient to overcome the frictional resistance to downward movement of a particle which results from the horizontal component of the flowing gas force.
    Type: Grant
    Filed: July 20, 1990
    Date of Patent: February 18, 1992
    Assignee: UOP
    Inventor: William J. Koves
  • Patent number: 5076908
    Abstract: This invention makes possible substantially continuous flow of uniformly distributed hydrogen and hydrocarbon liquid across a densely packed catalyst bed to fill substantially the entire volume of a reactor vessel by introducing the fluids as alternate annular rings of gas and liquid at a rate insufficient to levitate the bed and with catalyst selected by a density, shape and size at a design feed rate of liquids and gas to prevent ebulation of the packed bed at the design feed rates. Catalysts are selected by measuring bed expansion in a large pilot plant run with hydrocarbon, hydrogen, and catalyst at the design pressures and flow velocities. The liquid and gas components of the feed flow into the bed in alternate annular rings across the full area of the bed.
    Type: Grant
    Filed: July 19, 1989
    Date of Patent: December 31, 1991
    Assignee: Chevron Research & Technology Company
    Inventors: Bruce E. Stangeland, David C. Kramer, David S. Smith, James T. McCall, Georgieanna L. Scheuerman, Robert W. Bachtel
  • Patent number: 4902407
    Abstract: An improved method of controlling catalyst inventory in the reactor of an ebullated bed process has been discovered. Pressure differentials are measured to calculate a catalyst inventory characterization factor. Aged catalyst is withdrawn and fresh catalyst added in an amount to reestablish the value of the factor.The catalyst to oil ratio is maintained despite changes in bed ebullation, gas and liquid holdups and oil residence time changes.
    Type: Grant
    Filed: June 9, 1988
    Date of Patent: February 20, 1990
    Assignee: Texaco Inc.
    Inventors: Ting Y. Chan, John C. Strickland
  • Patent number: 4880604
    Abstract: Method and apparatus for effecting treatment needed to regenerate spent hydrocarbon conversion catalyst. The invention may be termed a variable gas flow catalyst bed. Catalyst particles in a vertically-elongated movable bed are contacted with a hot oxygen-containing gas stream in order to remove, by means of combustion, coke which accumulated on the catalyst particles while they were used in a hydrocarbon conversion zone. The catalyst particles are confined in the bed by means of catalyst retention screens. The catalyst retention screens are configured such that gas flow through the bed varies from a maximum at the top of the bed to a minimum at the bottom of the bed. The variation in gas flow is accomplished by varying the size of gas flow apertures in the retention screens from a maximum at the top of the bed to a minimum at the bottom of the bed.
    Type: Grant
    Filed: November 4, 1987
    Date of Patent: November 14, 1989
    Assignee: UOP
    Inventor: William J. Koves
  • Patent number: 4859643
    Abstract: A method for regenerating coke-contaminated catalyst particles achieves better utilization of oxygen and minimizes surface area loss of the catalyst by confining particles in the combustion section of a regeneration zone to a tapered bed configuration. In this method, catalyst particles move through the regeneration zone in continuous or semi-continuous flow and are formed into a vertically elongated bed of particles in the regeneration zone. An oxygen-containing gas is passed through the particle bed in a transverse direction and initiates combustion of the coke deposits along a burn front that extends diagonally through the catalyst bed from the inlet surface of the bed to the outlet surface of the bed.
    Type: Grant
    Filed: May 11, 1988
    Date of Patent: August 22, 1989
    Assignee: UOP
    Inventors: Paul A. Sechrist, WIlliam J. Koves
  • Patent number: 4659455
    Abstract: The invention concerns a process for withdrawing catalyst, particularly from a moving bed.The device is characterized in that fins (4) (see FIG. 1A), shaped as corner-plates, are arranged, on a plate (6) which supports the catalyst bed radially around each vertical duct for catalyst withdrawal, so that the flow of catalyst particles converges towards the withdrawing ducts.The apparatus is useful for example in hydroconversion reactions, particularly in hydrotreatments of heavy oil cuts.
    Type: Grant
    Filed: February 7, 1985
    Date of Patent: April 21, 1987
    Assignee: Institut Francais du Petrole
    Inventors: Didier Dall, Jean-Paul Euzen, Remy Patoux, Pierre Renard
  • Patent number: 4615792
    Abstract: A system is disclosed for circulating an ancillary hydrogen-rich gas stream through a part of a moving bed hydrocarbon conversion process. The gas stream may be employed in lockhopper systems, catalyst transfer equipment and catalyst treating zones as for reducing the catalyst. The used ancillary gas is discharged into a partitioned vapor-liquid separation vessel. The partially condensed reaction zone effluent stream is discharged into a different chamber of the same vessel. The net off gas stream is withdrawn from the chamber receiving the used ancillary gas to prevent contamination of a recycle gas stream, which is drawn off the other chamber.
    Type: Grant
    Filed: April 25, 1985
    Date of Patent: October 7, 1986
    Assignee: UOP Inc.
    Inventor: Arthur R. Greenwood
  • Patent number: 4591428
    Abstract: The present invention relates to a continuous process for the catalytic treatment of a hydrocarbon oil and an apparatus for carrying out such process, by passing said oil through one or more catalyst beds within a reactor wherein catalyst is withdrawn from the bottom of the reactor and fresh catalyst is supplied to the top thereof, said catalyst being withdrawn through a discharge funnel contained in the bottom of said reactor, which funnel allows for separation of product from the catalyst via a first main screen located in the funnel upstream of the exit end of said funnel, the withdrawal of product being effected via a product outlet, in which process use is made of a second screen forming part of the discharge funnel system, located between the main screen of the funnel and the product outlet and having a larger mesh size.
    Type: Grant
    Filed: March 1, 1984
    Date of Patent: May 27, 1986
    Assignee: Shell Oil Company
    Inventor: Gerrit J. Pronk
  • Patent number: 4590045
    Abstract: The present invention relates to a movable catalyst bed reactor provided with catalyst bed supporting and guiding means in the shape of one or more downwardly converging conical surfaces with one or more vertical outlet channels connected to the lower end(s) of the conical surface(s), the supporting and guiding means comprising one or more screen sections for withdrawal of reactor effluent from the catalyst, and separate outlet means for reactor effluent and catalyst, wherein the vessel is further provided with conduit means for forming a protecting layer of substantially spherical particles along the surface(s) of the screen section(s) facing catalyst, which layer is movable along the screen section(s).
    Type: Grant
    Filed: February 19, 1985
    Date of Patent: May 20, 1986
    Assignee: Shell Oil Company
    Inventors: Hans van der Wal, Hendrik J. Scheffer
  • Patent number: 4578370
    Abstract: A method is disclosed for regenerating particulate catalyst used in a hydrocarbon conversion process such as catalytic reforming. The method is especially applicable to moving bed reactor systems. The catalyst being regenerated slowly moves downward as a dense bed which is contacted with different gas streams at different elevations within the regeneration zone. The invention involves employing a portion of relatively hot combustion gas as a heating gas stream, with the remainder of the combustion gas being cooled and recycled to the combustion zone. This eliminates the need to employ a heater to provide a suitable heating gas stream.
    Type: Grant
    Filed: April 25, 1985
    Date of Patent: March 25, 1986
    Assignee: UOP Inc.
    Inventor: Arthur R. Greenwood
  • Patent number: 4473658
    Abstract: An improved moving bed continuous catalytic cracking process for cracking hydrocarbon feedstocks, such as gas oil, in the absence of added hydrogen, which includes the use of a minute amount of dispersed platinum supported directly on a cracking catalyst. The trace of platinum induces a substantial increase in the heat efficiency with which coke on catalyst is converted to CO.sub.2 in the regenerator section with minimal or no detriment to the cracking reaction.
    Type: Grant
    Filed: August 17, 1983
    Date of Patent: September 25, 1984
    Assignee: Mobil Oil Corporation
    Inventor: Albert B. Schwartz
  • Patent number: 4250019
    Abstract: A multiple stage hydrocarbon conversion system wherein a hydrogen-hydrocarbonaceous feedstock reaction mixture is processed serially through a plurality of reaction zones, each of which contains a particulate catalyst disposed as an annular-form bed movable downwardly through the reaction zone, and wherein said reaction mixture is processed in radial flow through said annular-form bed. Pinning of the catalyst particles within the annular-form bed is substantially alleviated by the device of charging only a portion of the total hydrogen to the first reaction zone, and charging the balance of the total hydrogen to a subsequent reaction zone.
    Type: Grant
    Filed: September 6, 1979
    Date of Patent: February 10, 1981
    Assignee: UOP Inc.
    Inventor: Kenneth D. Peters
  • Patent number: 4250018
    Abstract: A multiple stage hydrocarbon conversion system wherein a hydrogen-hydrocarbonaceous feedstock reaction mixture is processed serially through a plurality of reaction zones, each of which contains a particulate catalyst disposed as an annular-form bed movable downwardly through the reaction zone, and wherein said reaction mixture is processed in radial flow through said annular-form bed. Pinning of the catalyst particles within the annular-form bed is substantially obviated by the combined effect of charging only a portion of the total hydrogen to the first reaction zone, charging the balance of the total hydrogen to a subsequent reaction zone, and restricting the effluent flow of at least one reaction zone.
    Type: Grant
    Filed: September 6, 1979
    Date of Patent: February 10, 1981
    Assignee: UOP Inc.
    Inventor: Kenneth D. Peters
  • Patent number: 4167553
    Abstract: A catalytic reaction chamber for contacting a reactant stream with catalyst particles which are disposed as an annular-form bed and are downwardly movable therethrough via gravity-flow. The annular catalyst bed is spaced between a catalyst-retaining screen and a scalloped, perforated centerpipe. A plurality of vertically-positioned catalyst-transfer, or withdrawal, conduits are circumferentially-disposed substantially adjacent the outer surface of the scalloped centerpipe and extend the entire length of the catalyst bed. These contain a first plurality of apertures which face into the bed of catalyst particles and which are sized to permit catalyst particles to flow therethrough. A second plurality of apertures is disposed opposite the first plurality of apertures, and sized to inhibit the flow of catalyst particles therethrough.
    Type: Grant
    Filed: February 13, 1978
    Date of Patent: September 11, 1979
    Assignee: UOP Inc.
    Inventors: Paul J. Persico, Robert F. Millar, Robert H. Jensen
  • Patent number: 4155877
    Abstract: Catalyst regeneration process and apparatus wherein air introduced to a midsection of a downwardly-moving mass of catalyst particles is taken off at the top and at the bottom of said bed through provided outlets and a third outlet is provided at the bottom portion of the said bed adapted to be controlled responsive to change in the flows through the top outlet and first mentioned bottom outlet to maintain substantially constant the total upward and downward flows through said bed. In an embodiment in which coke laydown on a hydrocarbon treated catalyst is burned off flue gases flow upwardly and out from the bed, e.g., through a carbon monoxide or flue gas burning boiler while downwardly flowing flue gas is taken off through a pressure control outlet or opening on which suction is taken by a blower passing flue gases to a boiler, a third outlet also flow controlled is operated responsive to change in the desired upward and downward flows of the flue gases.
    Type: Grant
    Filed: March 21, 1978
    Date of Patent: May 22, 1979
    Assignee: Phillips Petroleum Company
    Inventor: Joe Van Pool
  • Patent number: 4141690
    Abstract: A catalytic reaction chamber for contacting a reactant stream with catalyst particles which are disposed as an annular-form bed and are downwardly movable therethrough via gravity-flow. The annular bed is spaced between a catalyst-retaining screen and a perforated centerpipe. A plurality of vertically-positioned catalyst-transfer, or withdrawal, conduits are circumferentially-disposed substantially adjacent the outer surface of the centerpipe and extend the entire length of the catalyst bed. These contain a first plurality of apertures which face into the bed of catalyst particles and which are sized to permit catalyst particles to flow therethrough. A second plurality of apertures is disposed substantially 180.degree. opposite the first plurality of apertures, and sized to inhibit the flow of catalyst particles therethrough.
    Type: Grant
    Filed: August 5, 1977
    Date of Patent: February 27, 1979
    Assignee: UOP Inc.
    Inventors: Paul J. Persico, Robert F. Millar, Robert H. Jensen
  • Patent number: 4135886
    Abstract: A catalytic reaction chamber for contacting a reactant stream with catalyst particles which are disposed as an annular-form bed and are downwardly movable therethrough via gravity-flow. The annular bed is formed between a catalyst-retaining screen and a perforated center-pipe. A plurality of vertically-positioned catalyst-transfer, or withdrawal, conduits are circumferentially-disposed substantially adjacent the outer surface of the centerpipe and extend the entire length of the catalyst bed. These contain a plurality of apertures which face into the bed of catalyst particles and which are sized to permit catalyst particles to flow therethrough. The use of these perforated catalyst-transfer conduits serves to alleviate the problems associated with the occurrence of stagnant catalyst areas which result from catalyst particles being "pinned" against the perforated centerpipe within the reaction zone, and unable to assume a downward flow pattern.
    Type: Grant
    Filed: August 5, 1977
    Date of Patent: January 23, 1979
    Assignee: UOP Inc.
    Inventor: Paul J. Kuchar
  • Patent number: 4119530
    Abstract: A startup method for moving-bed reactors used in hydrocarbon conversion processes wherein the reactor is brought on-stream at full capacity while it contains less than a full loading of catalyst, and quantities of catalyst are intermittently added to the reactor while the hydrocarbons are being processed. Catalyst removal is then begun at a rate lower than the rate of catalyst addition and adjusted when the catalyst retention volume of the reactor becomes filled. The method is specifically adaptable to the hydrogenation of olefinic materials, the desulfurization of petroleum fractions and the production of liquid products from coal.
    Type: Grant
    Filed: January 21, 1977
    Date of Patent: October 10, 1978
    Assignee: UOP Inc.
    Inventors: George J. Czajkowski, Frank Stolfa
  • Patent number: 4119526
    Abstract: A multiple-stage catalytic conversion system in which a hydrocarbonaceous charge stock and hydrogen flow serially through a plurality of catalytic reaction zones in each of which the catalyst particles are downwardly movable via gravity-flow. The flow of the product effluent from at least one reaction zone is restricted, as is the flow of the hydrogen-rich vaporous phase separated from the effluent from the last reaction zone and recycled to the first reaction zone. This technique increases the density of the reaction zone feed and the pressure drop within the entire reactor circuit, and thus serves to alleviate the problems associated with the occurrence of stagnant catalyst areas as a result of catalyst particles being "pinned" within the reaction zone and thus unable to assume a downward, gravity-flow pattern. Flow restriction may be effected either before, or after the inter-reaction zone heaters, preferably the former.
    Type: Grant
    Filed: May 9, 1977
    Date of Patent: October 10, 1978
    Assignee: UOP Inc.
    Inventors: Kenneth D. Peters, Elliot Veinerman, Donald E. Felch
  • Patent number: 4119527
    Abstract: A multiple-stage catalytic conversion system in which a hydrocarbonaceous charge stock and hydrogen flow serially through a plurality of catalytic reaction zones in each of which the catalyst particles are movable via gravity-flow. The flow of the product effluent from at least one reaction zone is restricted. This technique increases the pressure drop within the entire reactor circuit, and serves to alleviate the problems associated with the occurrence of stagnant catalyst areas as a result of catalyst particles being "pinned" within the reaction zone and thus unable to assume a downward gravity-flow pattern. Flow restriction may be effected either before, or after the inter-reaction zone heaters, preferably the former.
    Type: Grant
    Filed: May 9, 1977
    Date of Patent: October 10, 1978
    Assignee: UOP Inc.
    Inventor: Kenneth D. Peters
  • Patent number: 4110081
    Abstract: An improved radial flow moving bed reactor, or other type of fluid-solid contacting vessel, in which stagnant catalyst volumes are reduced. The improvement results from the placement of a plurality of catalyst collection scoops or a single discoid cover plate just above the catalyst withdrawal conduits in a manner which directs the removal of catalyst through an annular opening adjacent the inner catalyst retention screen.
    Type: Grant
    Filed: June 9, 1977
    Date of Patent: August 29, 1978
    Assignee: UOP Inc.
    Inventors: Robert F. Millar, Paul J. Persico, Robert H. Jensen
  • Patent number: 4110197
    Abstract: A multiple-stage catalytic conversion system in which a hydrocarbonaceous charge stock and hydrogen flow serially through a plurality of catalytic reaction zones in each of which the catalyst particles are movable via gravity-flow. The reaction product effluent from each zone, in admixture with added hydrogen is heated prior to the introduction thereof into the succeeding reaction zone. The proportions of added hydrogen (portions of a recycled hydrogen-rich phase) are such that (i) vapor density decreases, and, (ii) lateral pressure drop across the catalyst bed increases in the direction of reactant stream flow through the plurality of reaction zones. The disclosed technique alleviates problems associated with the occurrence of stagnant catalyst areas as a result of catalyst particles being "pinned" within the reaction zone and thus unable to assume a downward gravity-flow pattern. In addition, the technique allows utilization of excess heater capacities before and between reaction zones.
    Type: Grant
    Filed: May 12, 1977
    Date of Patent: August 29, 1978
    Assignee: UOP Inc.
    Inventors: Joel G. Herning, James B. Shelton
  • Patent number: 4104149
    Abstract: A multiple-stage catalytic conversion system in which a hydrocarbonaceous charge stock and hydrogen flow serially through a plurality of catalytic reaction zones, in each of which the catalyst particles are downwardly movable via gravity-flow. At least three reaction zones are utilized, with the fresh feed and hydrogen reactant stream being split between the first and second. The flow of that portion introduced into the second zone is restricted. Effluent flow from the first reaction zone is also restricted and combined with the effluent from the second reaction zone; the mixture is introduced into a third reaction zone. Where the catalytic conversion system consists of four reaction zones, the flow of effluent from the third is restricted prior to the introduction thereof into the fourth reaction zone.
    Type: Grant
    Filed: August 29, 1977
    Date of Patent: August 1, 1978
    Assignee: UOP Inc.
    Inventors: Elliot Veinerman, Donald E. Felch, Kenneth D. Peters
  • Patent number: 4069134
    Abstract: A multiple-stage catalytic conversion system in which a hydrocarbonaceous charge stock is reacted in a plurality of catalytic reaction zones, through all of which the catalyst particles flow downwardly via gravity-flow. The charge stock, in the absence of added, or recycle hydrogen, is reacted in a first reaction zone (1) into which fresh, or regenerated catalyst particles are introduced and, (2) from which deactivated catalyst particles are withdrawn for regeneration. The reaction product effluent emanating from the first reaction zone is further reacted in a multiple-zone stacked reaction system (1) into the uppermost zone of which fresh, or regenerated catalyst particles are introduced and (2) from the lowermost zone of which deactivated catalyst particles are withdrawn for regeneration. The product effluent from the lowermost reaction zone in the stacked system is separated to recover the intended product.
    Type: Grant
    Filed: October 26, 1976
    Date of Patent: January 17, 1978
    Assignee: UOP Inc.
    Inventor: Arthur R. Greenwood
  • Patent number: 4069137
    Abstract: A multiple-stage catalytic conversion system in which a hydrocarbonaceous charge stock is reacted in a plurality of stacked catalytic reaction zones through which catalyst particles flow downwardly via gravity-flow. The charge stock, in the absence of added, or recycle hydrogen, is reacted first in the lowermost reaction zone, from which deactivated catalyst particles are withdrawn from the system. Resulting reaction zone effluent is further reacted in the uppermost reaction zone, through which fresh, or regenerated catalyst particles are introduced into the system, and serially in one or more subsequent, lower reaction zones. Product effluent from the reaction zone immediately above the lowermost zone is separated to recover the desired normally liquid product.
    Type: Grant
    Filed: October 26, 1976
    Date of Patent: January 17, 1978
    Inventor: Arthur R. Greenwood
  • Patent number: 4069135
    Abstract: A multiple-stage catalytic conversion system in which a hydrocarbonaceous charge stock is reacted in a plurality of catalytic reaction zones, through all of which the catalyst particles flow downwardly via gravity-flow. The charge stock, in the absence of added, or recycled hydrogen, is reacted in the last reaction zone, from which deactivated catalyst particles are withdrawn for regeneration. The reaction product effluent emanating therefrom is further reacted in an intermediate reaction zone. Additional reaction of the product effluent, from the intermediate zone, is effected in the first reaction zone, through which fresh, or regenerated catalyst particles are introduced into the system. The effluent from the first reaction zone is separated to recover the intended product. The system may comprise three or more reaction zones in side-by-side relationship, with the catalyst particles being transported from the lower end of one zone to the upper end of the next succeeding reaction zone.
    Type: Grant
    Filed: October 26, 1976
    Date of Patent: January 17, 1978
    Assignee: UOP Inc.
    Inventor: Chester J. Giuliani
  • Patent number: RE32239
    Abstract: An improved moving bed continuous catalytic cracking process for cracking hydrocarbon feedstocks, such as gas oil, in the absence of added hydrogen, which includes the use of a minute amount of dispersed platinum supported directly on a cracking catalyst. The trace of platinum induces a substantial increase in the heat efficiency with which coke on catalyst is converted to CO.sub.2 in the regenerator section with minimal or no detriment to the cracking reaction.
    Type: Grant
    Filed: May 24, 1985
    Date of Patent: September 2, 1986
    Assignee: Mobil Oil Corporation
    Inventor: Albert B. Schwartz