Hydrocracking In All Stages Patents (Class 208/59)
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Patent number: 6589415Abstract: The present invention is directed to a method for hydroprocessing Fischer-Tropsch products. The invention in particular relates to an integrated method for producing liquid fuels from a hydrocarbon stream provided by Fischer-Tropsch synthesis. The method involves separating the Fischer-Tropsch products into a light fraction with normal boiling points below 700° F. and including predominantly C5-20 components and a heavy fraction with normal boiling points above 650° F. and including predominantly C20+ components. The heavy fraction is subjected to hydrocracking conditions, preferably through multiple catalyst beds, to reduce the chain length. The light fraction is used as all or part of a quench fluid between each catalyst bed.Type: GrantFiled: April 4, 2001Date of Patent: July 8, 2003Assignee: Chevron U.S.A., Inc.Inventors: Ben D. Smith, Krishniah Parimi, Richard O. Moore, Jr.
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Publication number: 20030111387Abstract: In the refining of crude oil, vacuum gas oil hydrotreaters and hydrocrackers are used to remove impurities such as sulfur, nitrogen, and metals from the crude oil. Typically, the middle distillate boiling material (boiling in the range from 250° F.-735° F.) from VGO hydrotreating or moderate severity hydrocrackers does not meet the smoke point, the cetane number or the aromatic specification. In most cases, this middle distillate is separately upgraded by a middle distillate hydrotreater or, alternatively, the middle distillate is blended into the general fuel oil pool or used as home heating oil. With this invention, the middle distillate is hydrotreated in the same high pressure loop as the vacuum gas oil hydrotreating reactor or the moderate severity hydrocracking reactor.Type: ApplicationFiled: December 17, 2001Publication date: June 19, 2003Inventors: Ujjal Kumar Mukherjee, Wai Seung W. Louie, Arthur J. Dahlberg
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Publication number: 20030111385Abstract: A VGO stream is initially hydrocracked in a hydrocracking reaction zone within an integrated hydroconversion process. Effluent from the hydrocracking reaction zone is combined with a light aromatic-containing feed stream, and the blended stream hydrotreated in a hydrotreating reaction zone. Heat exchange occurs between the hydrocracking reaction zone and the hydrotreating reaction zone, permitting the temperature control of the initial hydrocracking zone. The integrated reaction system provides a single hydrogen supply and recirculation system for use in two reaction processes.Type: ApplicationFiled: December 19, 2001Publication date: June 19, 2003Inventors: Dennis R. Cash, Arthur J. Dahlberg
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Patent number: 6579069Abstract: The invention relates to the field of petrochemistry, in particular to a method of compressing a gaseous hydrocarbon-containing medium, for example, different hydrocarbon gases including flares produced in the oil refining and petrochemical industries. A distillate of a rectifying column of an atmosphere-vacuum oil refining unit is fed as the fresh liquid working medium into a circulation loop of a liquid hydrocarbon-containing medium, which contains a liquid-gas jet device, a separator and a pump. The liquid hydrocarbon-containing medium is removed from the circulation loop to a cracking and rectifying unit in which the liquid hydrocarbon-containing medium is subjected to cracking with subsequent rectification in the rectifying column of that unit.Type: GrantFiled: December 10, 2001Date of Patent: June 17, 2003Inventor: Valery Grigorievich Tsegelsky
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Patent number: 6576119Abstract: The two-stage hydrocracking process of the present invention comprises bringing the first-stage feed oil containing a hydrocarbon component and having a boiling point of 316° C. or higher into contact with the first-stage catalyst in the presence of hydrogen to obtain a first-stage product; separating the first-stage product into heavy component and light component containing the middle distillate products; bringing the second-stage feed oil containing heavy component of the first-stage reaction product into contact with the second-stage catalyst in the presence of hydrogen to obtain the second-stage product; separating the second-stage product into heavy component and light component comprising middle distillate products and recycling part of the heavy component of the second-stage product to the second-stage feed oil. Hydrocracking activity of the first-stage catalyst is higher than hydrocracking activity of the second-stage catalyst.Type: GrantFiled: February 28, 2001Date of Patent: June 10, 2003Assignee: Japan Energy CorporationInventors: Katsuaki Ishida, Manabu Kobayashi, Hiroki Koyama, Seiji Togawa, Futoshi Sakaguchi
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Publication number: 20030085152Abstract: The instant invention comprises a hydroprocessing method having at least two stages. The first stage employs a hydroprocessing catalyst which may contain hydrotreating catalyst, hydrocracking catalyst, or a combination of both. The second stage is limited to hydrocracking. Conversion in the second stage may be improved by the addition of multiple reaction zones for hydrocracking, with flash separation zones between the stages. Middle distillate yield is thereby increased and the volume of the recycle stream is reduced. This invention reduces the need for equipment which would normally be required for a large recycle stream.Type: ApplicationFiled: October 25, 2001Publication date: May 8, 2003Inventors: Arthur J. Dahlberg, Jerome F. Mayer
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Patent number: 6547956Abstract: The invention relates to a hydrotreating and hydrocracking process for various oils nominally boiling between 600 and 1500° F. to produce diesel oil and lighter materials. The process includes a first hydrogenation reaction in the presence of multiple hydrogenation catalyst beds which is limited to the hydrogenation level needed for the removal of sulfur and nitrogen and for aromatic saturation and to produce an effluent of both hydrocracked oil and uncracked heavy oil. The effluent is then flashed to produce hydrocracked oil vapors and liquid uncracked heavy oil. The hydrocracked oil fraction is further hydrotreated by catalytic distillation in a post-treatment reactor to give the final product quality while the liquid uncracked heavy oil bypasses the post-treatment reactor. The process significantly reduces hydrogen consumption and reduces the overall reactor and catalyst volumes for a given level of performance.Type: GrantFiled: April 20, 2000Date of Patent: April 15, 2003Assignee: ABB Lummus Global Inc.Inventors: Ujjal Kumar Mukherjee, Wai Seung Louie
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Patent number: 6547958Abstract: The present invention relates to new crystalline zeolite SSZ-59 and processes employing SSZ-59 as a catalyst.Type: GrantFiled: July 13, 2001Date of Patent: April 15, 2003Assignee: Chevron U.S.A. Inc.Inventor: Saleh Elomari
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Publication number: 20030062292Abstract: A four stage process for producing high quality white oils, particularly food or medicinal grade mineral oils from mineral oil distillates. The first reaction stage employs a sulfur resistant hydrotreating catalyst and produces a product suitable for use as a high quality lubricating oil base stock. The second reaction stage employs a hydrogenation/hydrodesulfurization catalyst. The third stage employs a reduced metal sulfur sorbent producing a product stream which is low in aromatics and which has substantially “nil” sulfur. The final reaction stage employs a selective hydrogenation catalyst that produces a product suitable as a food or medicinal grade white oil.Type: ApplicationFiled: February 27, 2002Publication date: April 3, 2003Inventors: Sylvain S. Hantzer, Jean Willem Beeckman, Stephen J. McCarthy, Arthur Paul Werner
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Patent number: 6540906Abstract: The present invention relates to new crystalline zeolite SSZ-60 and processes employing SSZ-60 as a catalyst.Type: GrantFiled: July 13, 2001Date of Patent: April 1, 2003Assignee: Chevron U.S.A. Inc.Inventor: Saleh Elomari
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Patent number: 6540905Abstract: The present invention relates to new crystalline zeolite SSZ-58 and processes employing SSZ-58 as a catalyst.Type: GrantFiled: July 13, 2001Date of Patent: April 1, 2003Assignee: Chevron U.S.A. Inc.Inventor: Saleh Elomari
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Publication number: 20030047491Abstract: A process for hydroprocessing a hydrocarbon feedstock, includes the steps of providing a hydrocarbon feed having an initial characteristic; providing a first hydrogen-containing gas; feeding the hydrocarbon feed and the first hydrogen-containing gas cocurrently to a first hydroprocessing zone so as to provide a first hydrocarbon product; providing a plurality of additional hydroprocessing zones including a final zone and an upstream zone; feeding the first hydrocarbon product cocurrently with a recycled gas to the upstream zone so as to provide an intermediate hydrocarbon product; and feeding the intermediate hydrocarbon product cocurrently with a second hydrogen-containing gas to the final zone so as to provide a final hydrocarbon product having a final characteristic which is improved as compared to the initial characteristic.Type: ApplicationFiled: May 23, 2002Publication date: March 13, 2003Applicant: INTEVEP, S.A.Inventors: Carlos Gustavo Dassori, Nancy Fernandez, Rosa Arteca, Carlos Castillo
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Patent number: 6514403Abstract: The invention relates to a hydrocracking and hydrotreating process for hydrocracking feedstock oils such as vacuum gas oil to produce diesel and lighter distillate products. A first hydrogenation process is carried out in a main reactor with the feedstock and hydrogen flowing cocurrently down through a top section containing a layered system of hydrotreating and hydrocracking catalyst. The feedstock is substantially desulfurized and denitrified, the aromatics are at least partially saturated and cracked products are formed. The vapor and liquid are separated in a disengaging zone below the top section and the liquid flows down through a bottom section also containing a layered catalyst system countercurrent to make-up hydrogen flowing up. The vapor removed from the disengaging zone and the liquid bottoms are then further processed in a post treatment catalytic distillation reactor having an upper catalytic distillation section and a lower stripping section which may also contain a catalyst.Type: GrantFiled: April 20, 2000Date of Patent: February 4, 2003Assignee: ABB Lummus Global Inc.Inventors: Wai Seung Louie, Ujjal Kumar Mukherjee, Gary Lee Hamilton
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Publication number: 20030019788Abstract: The invention concerns a process for producing middle distillates from an effluent produced by a Fischer-Tropsch unit, comprising optional fractionation to obtain at least one heavy fraction with an initial boiling point in the range 120-200° C., said heavy fraction or said effluent optionally being hydrotreated, then bringing it into contact with a first amorphous hydrocracking/hydroisomerization catalyst that contains at least one noble group VIII metal, the effluent obtained is distilled, then the residual fraction boiling above the middle distillates and/or a portion of the middle distillates is brought into contact with a second amorphous hydrocracking/hydroisomerization catalyst containing at least one noble group VIII metal. The invention also concerns a unit.Type: ApplicationFiled: July 8, 2002Publication date: January 30, 2003Applicant: Institut Francais du PetroleInventors: Eric Benazzi, Christophe Gueret
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Publication number: 20030000867Abstract: This invention relates to a crude oil desulfurization process which comprises hydrodesulfurizing a crude oil feed in a crude desulfurization unit. The desulfurized crude oil is then separated into a light gas oil fraction, a vacuum gas oil fraction and a vacuum residuum fraction. The vacuum gas oil is hydrocracked to form at least one low sulfur fuel product. The light gas oil fraction is hydrotreated. The vacuum gas oil may be hydrocracked in one or more stages. Hydrocracking in the second stage, if present, will convert of at least 20% of the first zone effluent, to create a low sulfur light gas oil fraction. The light gas oil fraction may then be hydrotreated.Type: ApplicationFiled: June 28, 2001Publication date: January 2, 2003Applicant: Chevron U.S.A. Inc.Inventor: Bruce E. Reynolds
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Patent number: 6500329Abstract: A two stage process useful for cetane upgrading of diesel fuels. More particularly, the invention relates to a process for selective naphthenic ring-opening utilizing an extremely low acidic distillate selective catalyst having highly dispersed Pt. The process is a two stage process wherein the first stage is a hydrotreating stage for removing sulfur from the feed and the second stage is the selective ring-opening stage.Type: GrantFiled: October 16, 2001Date of Patent: December 31, 2002Assignee: ExxonMobil Research and Engineering CompanyInventors: Ying-Yen P. Tsao, Tracy J. Huang, Philip J. Angevine
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Publication number: 20020195375Abstract: A process for hydrotreating gas oils comprises:Type: ApplicationFiled: April 9, 2002Publication date: December 26, 2002Applicant: Institut Francais du PetroleInventors: Thierry Chapus, Frederic Morel
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Patent number: 6497810Abstract: A process for upgrading a liquid petroleum or chemical stream wherein said stream flows countercurrent to the flow of a treat gas, such as a hydrogen-containing gas, in at least one reaction zone. Injecting feed into one or more downstream reaction zones controls the temperature of at least one reaction zone.Type: GrantFiled: December 7, 1999Date of Patent: December 24, 2002Inventors: Larry L. Laccino, James J. Schorfheide
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Publication number: 20020179488Abstract: The invention provides a process for the production of a synthetic naphtha fuel suitable for use in compression ignition (CI) engines, the process including at least the steps of hydrotreating at least a fraction of a Fischer-Tropsch (FT) synthesis reaction product of CO and H2, or a derivative thereof, hydrocracking at least a fraction of the FT synthesis product or a derivative thereof, and fractionating the process products to obtain a desired synthetic naphtha fuel characteristic. The invention also provides a synthetic naphtha fuel made by the process as well as a fuel composition and a Cloud Point depressant for a diesel containg fuel composition, said fuel composition and said depressant including the synthetic naphtha of the invention.Type: ApplicationFiled: October 5, 2001Publication date: December 5, 2002Inventor: Luis Pablo Dancuart
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Patent number: 6454934Abstract: A petroleum processing method comprising the steps of: performing an atmospheric distillation of crude oil; collectively hydrodesulfurizing the resultant distillates consisting of gas oil and fractions whose boiling point is lower than that of gas oil in a reactor in the presence of a hydrogenation catalyst at 310 to 370° C. under 30 to 70 kg/cm2G (first hydrogenation step); and further performing hydrodesulfurization at lower temperatures (second hydrogenation step). When the second hydrogenation step is carried out only for the heavy naphtha obtained by separating the distillates after the first hydrogenation step, the second hydrogenation temperature can be in the range of 250 to 400° C.Type: GrantFiled: September 10, 1998Date of Patent: September 24, 2002Assignee: JGC CorporationInventors: Makoto Inomata, Toshiya Okumura, Shigeki Nagamatsu
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Patent number: 6454932Abstract: High boiling hydrocarbon materials are hydrocracked in a multiple stage process having ebullating catalyst bed hydrogenation reactor stages in series. Between the hydrogenation reactors is an interstage separator/stripper to separate a vapor phase and to strip the liquid phase with hydrogen to produce a heavier, more concentrated liquid phase as the feed to the next ebullating bed reactor stage in the series. The feed to the second stage may be blended with an aromatic solvent and/or a portion of the high boiling hydrocarbon feedstock.Type: GrantFiled: August 15, 2000Date of Patent: September 24, 2002Assignee: ABB Lummus Global Inc.Inventors: Mario C. Baldassari, Wai Seung Louie, Ujjal Kumar Mukherjee
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Publication number: 20020130063Abstract: A process is described that can limit pressure drops during a catalytic hydrotreatment process carried out in a fixed bed reactor. The liquid feed and gaseous reactant are injected into the reactor either side of the bed and flow as a counter-current. Pressure drops are limited by homogeneously mixing solid catalytic and/or inert particles of different diameters in the bed.Type: ApplicationFiled: December 20, 2001Publication date: September 19, 2002Applicant: Institut Francais du PetroleInventors: Daniel Vuillemot, Laurence Carpot, Thierry Chapus, Philippe Rocher, Frederic Morel
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Patent number: 6444116Abstract: An integrated process for treating a vacuum gas oil, kerosene, naphtha and Diesel-containing feed, includes the steps of providing a reaction feed containing residue, vacuum gas oil, kerosene, naphtha, Diesel, hydrogen sulfide, ammonia, and C1-C4 gas phase compounds; providing a stripping gas; providing a washing feed; and feeding the reaction feed, the stripping gas and the washing feed to a stripping and washing zone so as to obtain a gas phase containing the hydrogen sulfide, the ammonia, the C1-C4 gas phase compounds, the naphtha, the kerosene, the Diesel and the vacuum gas oil and a liquid phase, wherein the reaction feed is provided at a reaction feed pressure of between bout 700 psig and about 3500 psig, and wherein the stripping and washing zone is operated at a pressure within about 80 psig of the reaction feed pressure.Type: GrantFiled: October 10, 2000Date of Patent: September 3, 2002Assignee: Intevep, S.A.Inventors: Roberto Galiasso, Edilberto Rodriguez
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Patent number: 6428686Abstract: A process where the need to circulate hydrogen through the catalyst is eliminated. This is accomplished by mixing and/or flashing the hydrogen and the oil to be treated in the presence of a solvent or diluent in which the hydrogen solubility is “high” relative to the oil feed. The type and amount of diluent added, as well as the reactor conditions, can be set so that all of the hydrogen required in the hydroprocessing reactions is available in solution. The oil/diluent/hydrogen solution can then be fed to a plug flow reactor packed with catalyst where the oil and hydrogen react. No additional hydrogen is required, therefore, hydrogen recirculation is avoided and trickle bed operation of the reactors is avoided. Therefore, the large trickle bed reactors can be replaced by much smaller tubular reactor.Type: GrantFiled: June 22, 2000Date of Patent: August 6, 2002Assignee: Process Dynamics, Inc.Inventors: Michael D. Ackerson, Michael S. Byars
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Publication number: 20020074264Abstract: A hydrocarbonaceous feed is hydroprocessed in a single vessel containing two reaction stages and a stripping stage. The feed is fed into the first reaction stage to produce a vapor and liquid effluent which are separated, and the liquid stripped. The stripped liquid is passed as feed into the second stage, in which it meets with fresh hydrogen to produce a hydroprocessed liquid product and a hydrogen-rich vapor. The vapor is passed into the first stage, to provide the hydrogen for that stage. The use of a single vessel provides an efficient and economical addition to, or replacement for, a vessel for an existing hydroprocessing facility.Type: ApplicationFiled: September 21, 2001Publication date: June 20, 2002Inventor: Ramesh Gupta
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Patent number: 6402936Abstract: The invention relates to a catalyst that contains at least one partially amorphous Y zeolite, at least one metal of group VB, preferably niobium, at least one amorphous or poorly crystallized matrix, optionally at least one metal that is selected from group VIB and group VIII, optionally at least one element that is selected from the group that is formed by P, B, and Si, and optionally at least one element of group VIIA. The invention also relates to the use of this catalyst in hydrocracking and hydrorefining of hydrocarbon feedstocks.Type: GrantFiled: May 18, 2000Date of Patent: June 11, 2002Assignee: Institut Francais du PetroleInventors: Eric Benazzi, Jean-Marie Deves, Slavik Kasztelan
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Patent number: 6387245Abstract: A hydrocracking process wherein a hydrocarbonaceous feedstock and a hot hydrocracking zone effluent containing hydrogen is passed to a hydrocracking reaction zone to produce lower boiling hydrocarbon compounds. The resulting hot, uncooled effluent from the hydrocracking zone is hydrogen stripped in a stripping zone maintained at essentially the same pressure as the preceding hydrocracking reaction zone with a hydrogen-rich gaseous stream to produce a vapor stream comprising hydrogen, hydrocarbonaceous compounds boiling at a temperature below the boiling range of the fresh feedstock, hydrogen sulfide and ammonia, and a liquid hydrocarbonaceous stream which is countercurrently contacted with hydrogen in a hydrogenation zone located in the bottom end of the stripping zone.Type: GrantFiled: September 26, 2000Date of Patent: May 14, 2002Assignee: UOP LLCInventors: Tom N. Kalnes, David B. Gates
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Patent number: 6379532Abstract: A hydrocracking process wherein the undesirable production of polynuclear aromatic compounds is controlled by removing a small dragstream of high pressure product stripper bottoms to reject polynuclear aromatic compounds and recovering valuable diesel boiling range hydrocarbons and unconverted feedstock by routing the dragstream to a hot flash separator and subsequently to a divided wall fractionation zone to produce a concentrated stream of polynuclear aromatic compounds while recovering the valuable hydrocarbon compounds.Type: GrantFiled: February 17, 2000Date of Patent: April 30, 2002Assignee: UOP LLCInventors: Richard K. Hoehn, Bradford L. Bjorklund
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Patent number: 6379533Abstract: A catalytic hydrocracking process which provides for the simultaneous production of LPG and distillate hydrocarbons. The feedstock is introduced into a denitrification and desulfurization zone and then passed directly to a hot, high pressure stripper utilizing a hot, hydrogen-rich stripping gas to produce a first liquid stream boiling in the range of the feedstock and a first vapor stream comprising hydrocarbonaceous compounds boiling at a temperature below the boiling range of the feedstock. The first liquid stream is hydrocracked in a first hydrocracking zone and then passed to the denitrification and desulfurization zone. At least a portion of the first vapor stream is condensed to produce a second liquid stream comprising hydrocarbonaceous compounds boiling at a temperature below the boiling range of the feedstock.Type: GrantFiled: December 18, 2000Date of Patent: April 30, 2002Assignee: UOP LLCInventors: Vasant P. Thakkar, Tom N. Kalnes, Richard K. Hoehn
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Publication number: 20020038775Abstract: There is provided macrostructures of porous inorganic material which can have controlled size, shape, and/or porosity and a process for preparing the macrostructures. The macrostructures comprise a three-dimension network of particles of porous inorganic materials. The process for preparing the macrostructures involves forming an admixture containing a porous organic ion exchanger and a synthesis mixture capable of forming a porous inorganic material and then converting the synthesis mixture to a solid porous inorganic material. After formation of the composite material, the porous organic ion exchanger can be removed from the composite material to obtain the macrostructures, either before or after the porous inorganic material is hydrothermally treated with a structure directing agent to convert at least a portion of such porous inorganic material to a crystalline molecular sieve composition. The resulting macrostructure is composed of particles of the crystalline molecular sieve composition.Type: ApplicationFiled: January 5, 2001Publication date: April 4, 2002Inventors: Per Johan Sterte, Lubomira Borislavova Tosheva-Jivkova
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Patent number: 6361683Abstract: A catalytic hydrocracking process wherein a hydrocarbonaceous feedstock and a liquid recycle stream having a temperature greater than about 500° F. and saturated with hydrogen is contacted with hydrogen in a hydrocracking reaction zone at elevated temperature and pressure to obtain conversion to lower boiling hydrocarbons. The resulting hot, uncooled effluent from the hydrocracking reaction zone is hot hydrogen stripped in a stripping zone maintained at essentially the same pressure as the hydrocracking zone to produce a first gaseous hydrocarbonaceous stream and a first liquid hydrocarbonaceous stream. The first gaseous hydrocarbonaceous stream is passed through a post-treat hydrogenation zone to saturate aromatic compounds and at least partially condensed to produce a second liquid hydrocarbonaceous stream and a second hydrogen-rich gaseous stream.Type: GrantFiled: February 22, 2000Date of Patent: March 26, 2002Assignee: UOP LLCInventor: Tom N. Kalnes
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Publication number: 20020033355Abstract: A catalyst comprising 0.1-99.7% by weight of at least one alumina matrix; 0.1-80% by weight of at least one globally non dealuminated Y zeolite with a lattice parameter of more than 2.438 nm, a global SiO2/Al2O3 mole ratio of less than 8, and a framework SiO2/Al2O3 mole ratio of less than 21 and more than the global SiO2/Al2O3 mole ratio; 0.1-30% by weight of at least one group VIII metal and/or 1-40% by weight of at least one group VIB metal (% oxide); 0.1-20% by weight of at least one promoter element selected from the group formed by boron and silicon (% oxide); 0-20% by weight of at least one group VIIA element; 0-20% by weight of phosphorous (% oxide); 0.1-20% by weight of at least one group VIIB element, useful for hydrocracking processes, especially at low pressures of 7.5 to 11 MPa.Type: ApplicationFiled: October 1, 2001Publication date: March 21, 2002Applicant: Institut Francais du PetroleInventors: Samuel Mignard, Nathalie George-Marchal, Slavik Kasztelan
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Publication number: 20020008049Abstract: A petroleum processing method comprising the steps of: performing an atmospheric distillation of crude oil; collectively hydrodesulfurizing the resultant distillates consisting of gas oil and fractions whose boiling point is lower than that of gas oil in a reactor in the presence of a hydrogenation catalyst at 310 to 370° C. under 30 to 70 kg/cm2G (first hydrogenation step); and further performing hydrodesulfurization at lower temperatures (second hydrogenation step). When the second hydrogenation step is carried out only for the heavy naphtha obtained by separating the distillates after the first hydrogenation step, the second hydrogenation temperature can be in the range of 250 to 400° C. The hydrodesulfurization having been performed for each of gas oil, kerosene, heavy naphtha and light naphtha in the art can be collectively and efficiently carried out, so that the oil refinery plant can be simplified and so that the cost of oil refinery equipment and running cost can be reduced.Type: ApplicationFiled: September 10, 1998Publication date: January 24, 2002Inventors: MAKOTO INOMATA, TOSHIYA OKUMURA, SHIGEKI NAGAMATSU
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Publication number: 20020008051Abstract: The two-stage hydrocracking process of the present invention comprises bringing the first-stage feed oil containing a hydrocarbon component and having a boiling point of 316° C. or higher into contact with the first-stage catalyst in the presence of hydrogen to obtain a first-stage product; separating the first-stage product into heavy component and light component containing the middle distillate products; bringing the second-stage feed oil containing heavy component of the first-stage reaction product into contact with the second-stage catalyst in the presence of hydrogen to obtain the second-stage product; separating the second-stage product into heavy component and light component comprising middle distillate products and recycling part of the heavy component of the second-stage product to the second-stage feed oil. Hydrocracking activity of the first-stage catalyst is higher than hydrocracking activity of the second-stage catalyst.Type: ApplicationFiled: February 28, 2001Publication date: January 24, 2002Inventors: Katsuaki Ishida, Manabu Kobayashi, Hiroki Koyama, Seiji Togawa, Futoshi Sakaguchi
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Patent number: 6340430Abstract: A hydrotreating process is presented for both dewaxing the diesel fraction and reducing the aromatic content of kerosene fraction of a distillate boiling range feed stream. The feed stream is flashed to generate vapor and liquid phase streams. The portion which comprises most of the heavy diesel is passed into a dewaxing zone. The vapor-phase stream, preferably rich in kerosene and light diesel, is used to quench the effluent of the dewaxing zone before it is passed into a downstream aromatics hydrogenation zone. Depending on the composition of the feed to the process, a second flashing step performed in the presence of added hydrogen may be employed to produce the feed to the dewaxing zone. PNA's may be hydrogenated prior to recycling to a hydrocracking zone.Type: GrantFiled: September 15, 1999Date of Patent: January 22, 2002Assignee: UOP LLCInventor: Brian Murray Wood
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Publication number: 20020005373Abstract: The invention relates to a method and dual reactor system for hydrotreating a wide cut cat naphtha stream comprising heavy cat naphtha (HCN) and intermediate cat naphtha (ICN). Accordingly, a HCN fraction is hydrotreated under non-selective hydrotreating conditions and an ICN fraction is hydrotreated under selective hydrotreating conditions. The hydrotreated HCN and ICN effluents may be conducted to heat exchangers to pre-heat the ICN feed, obviating the need for a furnace.Type: ApplicationFiled: March 23, 2001Publication date: January 17, 2002Inventors: Brij Gupta, John P. Greeley, Thomas R. Halbert
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Publication number: 20010054572Abstract: Catalyst activation of a platinum reforming catalyst system contained in a multiple reactor system by simultaneously reducing the catalyst with hydrogen while introducing a nonmetallic chlorine-containing compound into a reactor of the multiple reactor system in an amount to provide from about 0.05 to about 0.3 weight percent chlorine on the catalyst and thereafter purging the system with about 100 to about 50,000 cubic feet of hydrogen per cubic foot of catalyst resulting in a reforming system having increased activity and providing enhanced RON values with reduced cracking of feedstock.Type: ApplicationFiled: July 31, 2001Publication date: December 27, 2001Applicant: Phillips Petroleum CompanyInventor: Fan-Nan Lin
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Publication number: 20010047952Abstract: A process for the hydrodesulfurization of a cracked naphtha stream is disclosed where very little of the valuable olefins are saturated. The process is a two staged process wherein the H2S is removed between the stages to prevent recombinant mercaptans formation. Because the H2S is removed between the stages milder conditions can be used in the second stage polishing reactor to achieve the same desulfurization levels with less olefin loss.Type: ApplicationFiled: June 21, 2001Publication date: December 6, 2001Applicant: CATALYTIC DISTILLATION TECHNOLOGIESInventors: Gary G. Podrebarac, Gary R. Gildert, Willibrord A. Groten
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Patent number: 6315889Abstract: A feed stream is processed in a hydrotreating reaction zone and then the hydrotreating effluent is separated into two fractions in a first high pressure separator. The vapor fraction is passed into a second high pressure separator. A controlled portion of the liquid fraction from the first high pressure separator and the liquid from the second high pressure separator are passed into a hydrocracking zone. The remaining portion of the liquid from the first high pressure separator is passed into the product recovery zone.Type: GrantFiled: October 21, 1999Date of Patent: November 13, 2001Assignee: UOP LLCInventors: Vasant P. Thakkar, Christopher J. Anderle, Hemant B. Gala
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Patent number: 6312586Abstract: Heavy hydrocarbons are upgraded to higher value distillates in a hydrocarbon conversion process which employs several parallel reaction zones which each contain both hydrotreating and hydrocracking catalyst beds. The feed and liquid recycle from the bottom of the reaction zone is charged to the top of the uppermost catalyst bed. Hydrogen flow is countercurrent to the descending liquid, and products are removed overhead through vapor-liquid contactors. The flow of feed to one of the reaction zones is periodically stopped to allow sequential on-stream hydrogenative regeneration of the catalysts within the reaction zone.Type: GrantFiled: September 27, 1999Date of Patent: November 6, 2001Assignee: UOP LLCInventors: Tom N. Kalnes, Stephen R. Dunne, Vasant P. Thakkar
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Patent number: 6303020Abstract: A process for the hydrodesulfurization of a cracked naphtha stream is disclosed where very little of the valuable olefins are saturated. The process is a two staged process wherein the H2S is removed between the stages to prevent recombinant mercaptans formation. Because the H2S is removed between the stages milder conditions can be used in the second stage polishing reactor to achieve the same desulfurization levels with less olefin loss.Type: GrantFiled: February 11, 2000Date of Patent: October 16, 2001Assignee: Catalytic Distillation TechnologiesInventors: Gary G. Podrebarac, Gary R. Gildert, Willibrord A. Groten
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Patent number: 6299759Abstract: A method and reactor system for catalytic hydrotreating and hydrocracking liquid hydrocarbon feedstock for producing a cracked liquid feedstock having a reduced contaminant level involves introducing the feedstock into the first reaction zone of a reactor system having a plurality of successive reaction zones, each reaction zone having a hydroprocessing catalyst bed therein, at least the first reaction zone comprising a hydrotreating reaction zone and at least one downstream reaction zone comprising a hydrocracking reaction zone, introducing hydrogen gas into the reactor system for flow through and over the catalyst beds in contact with the liquid in the reaction zones, the hydrogen exothermically reacting with the liquid in the reaction zones for producing an effluent for each reaction zone having a temperature greater than the temperature of the influent feedstock to that reaction zone, introducing liquid feedstock having the same composition as the liquid feedstock introduced into the first reaction zone iType: GrantFiled: February 13, 1998Date of Patent: October 9, 2001Assignee: Mobil Oil CorporationInventors: Robert A. Bradway, Yingyen P. Tsao
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Patent number: 6296758Abstract: A hydrocracking process wherein a hydrocarbonaceous feedstock and a hot hydrocracking zone effluent containing hydrogen is passed to a denitrification and desulfurization reaction zone to produce hydrogen sulfide and ammonia to thereby clean up the fresh feedstock. The resulting hot, uncooled effluent from the denitrification and desulfurization zone is hydrogen stripped in a stripping zone maintained at essentially the same pressure as the preceding reaction zone with a hydrogen-rich gaseous stream to produce a vapor stream comprising hydrogen, hydrocarbonaceous compounds boiling at a temperature below the boiling range of the fresh feedstock, hydrogen sulfide and ammonia, and a liquid hydrocarbonaceous stream.Type: GrantFiled: June 23, 1999Date of Patent: October 2, 2001Assignee: UOP LLCInventors: Tom N. Kalnes, Vasant P. Thakkar
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Patent number: 6294079Abstract: A feed stream is first processed in a hydrotreating reaction zone and then the effluent is separated into three fractions in an augmented first high pressure separator. Controlled portions of the middle and heavy hydrocarbon fractions are passed into a high severity hydrocracking zone, while the remaining portions of these two fractions are passed into a second high pressure separator for recovery. The effluent of the hydrocracking zone is also fed to the second high pressure separator.Type: GrantFiled: October 21, 1999Date of Patent: September 25, 2001Assignee: UOP LLCInventors: Vasant P. Thakkar, Christopher J. Anderle, Hemant B. Gala
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Patent number: 6287454Abstract: Lubricant oils of low pour point and improved oxidation stability are produced by catalytically dewaxing a lube feedstock over a zeolite dewaxing catalyst such as ZSM-5 in the hydrogen or decationized form. The use of these catalysts enables products of excellent oxidative stability to be obtained and reduces the catalyst aging rate in the first and subsequent dewaxing cycles to values below 5° F./day. The duration of the dewaxing cycles may be extended, particularly in the second and subsequent cycles after hydrogen reactivation.Type: GrantFiled: August 16, 1994Date of Patent: September 11, 2001Assignee: Mobil Oil CorporationInventors: Thomas R. Forbus, Jr., Chwan P. Kyan
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Patent number: 6280606Abstract: Process for converting a hydrocarbon fraction that is obtained from atmospheric distillation of a crude, comprising a vacuum distillation stage (a) of said feedstock that makes it possible to obtain a vacuum distillate and a vacuum residue; a stage b) for treating at least a portion of the vacuum distillate in the presence of hydrogen; a stage c) for treating at least a portion of the vacuum residue in the presence of hydrogen, whereby said stages b) and c) are each carried out in at least one separate triphase reactor that contains at least one ebullated-bed hydrotreatment catalyst that operates with an upward flow of liquid and gas; a stage d) in which at least a portion of the product that is obtained in stage b) is sent to an atmospheric distillation zone from which a light fraction and a heavier liquid fraction are recovered; a stage e) in which at least a portion of the product that is obtained in stage c) is sent to an atmospheric distillation zone from which a light fraction and a heavier liquid fractType: GrantFiled: March 22, 1999Date of Patent: August 28, 2001Assignee: Institut Francais du PetroleInventors: Frédéric Morel, Jean-Luc Duplan, Alain Billon, Stéphane Kressmann
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Patent number: 6277270Abstract: Process for converting a hydrocarbon fraction that is obtained from atmospheric distillation of a crude, comprising a vacuum distillation stage (a) of said feedstock that makes it possible to obtain a vacuum distillate and a vacuum residue; a stage b) for treating at least a portion of the vacuum distillate in the presence of hydrogen in at least one reactor that contains at least one fixed-bed hydrotreatment catalyst under conditions that make it possible to obtain a liquid effluent with a low sulfur content; a stage c) for treating at least a portion of the vacuum residue in the presence of hydrogen in at least one triphase reactor that contains at least one ebullated-bed hydrotreatment catalyst; a stage d) in which at least a portion of the product that is obtained in stage b) is sent to an atmospheric distillation zone from which a light fraction and a heavier liquid fraction are recovered; a stage e) in which at least a portion of the product that is obtained in stage c) is sent to an atmospheric distillType: GrantFiled: March 22, 1999Date of Patent: August 21, 2001Assignee: Institut Francais du PetroleInventors: Frédéric Morel, Jean-Luc Duplan, Alain Billon, Stéphane Kressmann
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Patent number: 6270654Abstract: A process for catalytic multi-stage hydrogenation of heavy carbonaceous feedstocks using catalytic ebullated bed reactors is operated at selected flow and operating conditions so as to provide improved reactor operations and produce increased yield of lower boiling hydrocarbon liquid and gas products. The disclosed process advantageously takes advantage of an external gas/liquid separation unit associated with the first stage reactor to allow for a more efficient and effective catalytic hydrocracking process. The more efficient process is primarily a result of the increased catalyst loading and lower gas hold-up in the ebullated reactors.Type: GrantFiled: May 29, 1998Date of Patent: August 7, 2001Assignee: IFP North America, Inc.Inventors: James J. Colyar, James B. MacArthur, Eric D. Peer
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Patent number: 6235190Abstract: An integrated hydrotreating/hydrocracking process employs two hydrotreating catalysts of different relative activities in sequence to provide improved products. A more active second catalyst is employed after the first hydrotreating catalyst. The jet fuel fraction recovered from the effluent of the downstream hydrocracking reaction zone has a reduced aromatic hydrocarbon content compared to the prior art.Type: GrantFiled: August 5, 1999Date of Patent: May 22, 2001Assignee: UOP LLCInventor: Ricky Val Bertram
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Patent number: RE38170Abstract: A gas conversion process in which both hydrocarbons and hydrogen are produced from a synthesis gas feed which comprises a mixture of H2 and CO, uses hydrogen from a portion of the feed for one or more of (i) hydrocarbon synthesis catalyst rejuvenation and (ii) hydroconversion upgrading of at least a portion of the synthesized hydrocarbons. Hydrogen is produced from a slipstream of the synthesis gas fed into the hydrocarbon synthesis reactor by one or more of (i) physical separation means such as pressure swing adsorption and (ii) chemical means such as a water gas shift reactor. If a shift reactor is used due to insufficient capacity of the synthesis gas generator, physical separation means such as pressure swing adsorption will still be used to separate a pure stream of hydrogen from the shift reactor gas effluent.Type: GrantFiled: March 28, 2002Date of Patent: July 1, 2003Assignee: ExxonMobil Research and Engineering CompanyInventors: Charles William DeGeorge, Robert Dean Denton