Plural Parallel Stages Of Chemical Conversion Patents (Class 208/78)
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Publication number: 20030116470Abstract: A novel apparatus for producing sweet synthetic crude from a heavy hydrocarbon feed comprising: an upgrader for receiving said heavy hydrocarbon feed and producing a distillate fraction including sour products, and high-carbon content by-products; a gasifier for receiving the high-carbon content by-products and producing synthetic fuel gas and sour by-products; a hydroprocessing unit for receiving the sour by-products and hydrogen gas, thereby producing gas and sweet crude; and a hydrogen recovery unit for receiving said synthetic fuel gas and producing further hydrogen gas and hydrogen-depleted synthetic fuel gas, said further hydrogen gas being supplied to said hydroprocessing unit.Type: ApplicationFiled: December 26, 2001Publication date: June 26, 2003Inventors: Philip Rettger, Randall Goldstein, Jim Arnold
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Patent number: 6576119Abstract: The two-stage hydrocracking process of the present invention comprises bringing the first-stage feed oil containing a hydrocarbon component and having a boiling point of 316° C. or higher into contact with the first-stage catalyst in the presence of hydrogen to obtain a first-stage product; separating the first-stage product into heavy component and light component containing the middle distillate products; bringing the second-stage feed oil containing heavy component of the first-stage reaction product into contact with the second-stage catalyst in the presence of hydrogen to obtain the second-stage product; separating the second-stage product into heavy component and light component comprising middle distillate products and recycling part of the heavy component of the second-stage product to the second-stage feed oil. Hydrocracking activity of the first-stage catalyst is higher than hydrocracking activity of the second-stage catalyst.Type: GrantFiled: February 28, 2001Date of Patent: June 10, 2003Assignee: Japan Energy CorporationInventors: Katsuaki Ishida, Manabu Kobayashi, Hiroki Koyama, Seiji Togawa, Futoshi Sakaguchi
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Publication number: 20030098261Abstract: A stable distillate fuel blend useful as a fuel or as a blending component of a fuel that is suitable for use in an internal combustion engine, said fuel blend prepared from at least one highly paraffinic distillate fuel component and at least one highly aromatic petroleum-derived distillate fuel component and a process for preparing same involving the blending of at least two components having antagonistic properties with respect to one another.Type: ApplicationFiled: October 19, 2001Publication date: May 29, 2003Inventors: John D. Bacha, Dennis J. O'Rear
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Patent number: 6497812Abstract: Processes for converting C1 to C3 alkanes into high purity C6 to C24 normal alpha olefins and internal combustion engine grade fuels and/or lubricating oils comprising a sequence of fractionation and thermal cracking and/or hydrocracking operations. The C6 to C24 normal alpha olefin fractions generally have a purity of at least about 90 wt. %.Type: GrantFiled: August 28, 2000Date of Patent: December 24, 2002Assignee: Chevron U.S.A. Inc.Inventor: William L. Schinski
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Patent number: 6475375Abstract: The invention provides a process for the production of a synthetic naphtha fuel suitable for use in compression ignition (CI) engines, the process including at least the steps of hydrotreating at least a fraction of a Fischer-Tropsch (FT) synthesis reaction product of CO and H2, or a derivative thereof, hydrocracking at least a fraction of the FT synthesis product or a derivative thereof, and fractionating the process products to obtain a desired synthetic naphtha fuel characteristic. The invention also provides a synthetic naphtha fuel made by the process as well as a fuel composition and a Cloud Point depressant for a diesel containg fuel composition, said fuel composition and said depressant including the synthetic naphtha of the invention.Type: GrantFiled: December 28, 1999Date of Patent: November 5, 2002Assignee: Sasol Technology (Pty)Ltd.Inventor: Luis Pablo Dancuart
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Patent number: 6379533Abstract: A catalytic hydrocracking process which provides for the simultaneous production of LPG and distillate hydrocarbons. The feedstock is introduced into a denitrification and desulfurization zone and then passed directly to a hot, high pressure stripper utilizing a hot, hydrogen-rich stripping gas to produce a first liquid stream boiling in the range of the feedstock and a first vapor stream comprising hydrocarbonaceous compounds boiling at a temperature below the boiling range of the feedstock. The first liquid stream is hydrocracked in a first hydrocracking zone and then passed to the denitrification and desulfurization zone. At least a portion of the first vapor stream is condensed to produce a second liquid stream comprising hydrocarbonaceous compounds boiling at a temperature below the boiling range of the feedstock.Type: GrantFiled: December 18, 2000Date of Patent: April 30, 2002Assignee: UOP LLCInventors: Vasant P. Thakkar, Tom N. Kalnes, Richard K. Hoehn
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Patent number: 6339181Abstract: This invention relates to a process to produce propylene from a hydrocarbon feed stream, preferably a naphtha feed stream, comprising C5 and C6 components wherein a light portion having a boiling point range of 120° C. or less is introduced into a reactor separately from the other components of the feed stream.Type: GrantFiled: November 9, 1999Date of Patent: January 15, 2002Assignee: ExxonMobil Chemical Patents, Inc.Inventors: Tan-Jen Chen, Philip A. Ruziska, Gordon F. Stuntz, Paul K. Ladwig
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Patent number: 6328879Abstract: A catalytic hydrocracking process wherein a first hydrocarbonaceous feedstock is contacted with a hydrogen and a metal promoted hydrocracking catalyst in a hydrocracking reaction zone at elevated temperature and pressure to obtain conversion to lower boiling hydrocarbons. The resulting hot, uncooled effluent from the hydrocracking reaction zone is hot hydrogen stripped in a stripping zone maintained at essentially the same pressure as the hydrocracking zone to produce a first gaseous hydrocarbonaceous stream and a first liquid hydrocarbonaceous stream. At least a portion of the first liquid hydrocarbonaceous stream is preferably recycled to the hydrocracking reaction zone. A second hydrocarbonaceous feedstock having a boiling temperature range lower than that of the first hydrocarbonaceous feedstock is introduced into an upper end of the stripper to serve as reflux.Type: GrantFiled: July 26, 1999Date of Patent: December 11, 2001Assignee: UOP LLCInventor: Tom N. Kalnes
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Patent number: 6312586Abstract: Heavy hydrocarbons are upgraded to higher value distillates in a hydrocarbon conversion process which employs several parallel reaction zones which each contain both hydrotreating and hydrocracking catalyst beds. The feed and liquid recycle from the bottom of the reaction zone is charged to the top of the uppermost catalyst bed. Hydrogen flow is countercurrent to the descending liquid, and products are removed overhead through vapor-liquid contactors. The flow of feed to one of the reaction zones is periodically stopped to allow sequential on-stream hydrogenative regeneration of the catalysts within the reaction zone.Type: GrantFiled: September 27, 1999Date of Patent: November 6, 2001Assignee: UOP LLCInventors: Tom N. Kalnes, Stephen R. Dunne, Vasant P. Thakkar
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Patent number: 6275776Abstract: A method to rapidly characterize the hydrocarbon chemistry of heavy residual petroleum mixtures uses three model equations for predicting aromatic carbon content, aromatic hydrogen content and total hydrogen content of the heavy residual oil. The predictive equations are based on three easily measured bulk properties including refractive index, specific gravity and the Watson K factor.Type: GrantFiled: March 3, 1999Date of Patent: August 14, 2001Assignee: Phillips Petroleum CompanyInventors: Paul F. Meier, Dhananjay B. Ghonasgi, Michael Wardinsky
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Patent number: 6123832Abstract: The invention relates to Fluid Catalytic Cracking (FCC) for producing liquid fuels and light olefins from liquid hydrocarbon mixtures such as petroleum fractions.Type: GrantFiled: January 14, 1999Date of Patent: September 26, 2000Assignee: Exxon Research and Engineering Co.Inventors: Teh Chung Ho, Shun Chong Fung, Gordon Frederick Stuntz, Robert Charles Welch, Daniel Paul Leta
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Patent number: 6123830Abstract: Disclosed is a catalytic cracking process that includes more than one catalytic cracking reaction step. The process integrates catalytic cracking steps with hydroprocessing in order to maximize olefins production, distillate quality and octane level of the overall cracked product. Preferably, one hydroprocessing step is included between the cat cracking reaction steps, and a portion of the hydroprocessed products, i.e., a naphtha and mid distillate fraction, is combined with cracked product for further separation and hydroprocessing. It is also preferred that the first catalytic cracking reaction step be a short contact time reaction step.Type: GrantFiled: December 30, 1998Date of Patent: September 26, 2000Assignee: Exxon Research and Engineering Co.Inventors: Ramesh Gupta, Edward S. Ellis
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Patent number: 6113776Abstract: A high efficiency FCC process obtains the necessary regenerated catalyst temperature for a principally thermal cracking stage by cracking a light feedstock such as naphtha or a middle distillate in a first riser that principally performs thermal cracking and then cracks a heavy FCC feed in a second riser with a blend of catalyst from the principally thermal cracking step and recycle catalyst from the heavy feed to provide the necessary coke content on the catalyst that will produce high regenerated catalyst temperatures. The high temperature of the regenerated catalyst in the first riser provides a convenient means of cracking naphtha under high severity conditions and then using the remaining activity of the contacted catalyst for the principally catalytic reaction of the heavier feed. A separate thermal cracked product may be recovered from an intermediate blending vessel downstream of the first riser.Type: GrantFiled: June 8, 1998Date of Patent: September 5, 2000Assignee: UOP LLCInventor: Lawrence L. Upson
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Patent number: 6113775Abstract: A large difficult to process hydrocracking feed stream may be processed at lower overall pressure and therefore in a unit of reduced capital cost by first dividing the feed stream into a light fraction and a smaller heavy fraction and then processing these fractions in separate reactors. The heavy fraction will normally contain the more difficult to process species and is processed in a once through reaction zone. The light fraction is processed in a higher conversion reaction zone which also receives the recycle stream produced in the product fractionation/recovery zone. The effluents of the two reaction zones may be charged into a common separator or into different separators to reduce ammonia levels in the recycle reactor.Type: GrantFiled: November 19, 1998Date of Patent: September 5, 2000Assignee: UOP LLCInventors: Ben A. Christolini, Donald B. Ackelson
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Patent number: 6051128Abstract: A full boiling hydrocarbon feed is reformed to enhance para-xylene and benzene yields. First, the hydrocarbon feed is separated into a C.sub.5- cut, a C.sub.6 -C.sub.7 cut, and a C.sub.8+ cut. The C.sub.6 -C.sub.7 cut has less than 5 lv. % of C.sub.8+ hydrocarbon, and the C.sub.8+ cut has less than 10 lv. % of C.sub.7- hydrocarbon. The C.sub.6 -C.sub.7 cut is subjected to catalytic aromatization at elevated temperatures in a first reformer in the presence of hydrogen and using a non-acidic catalyst comprising at least one Group VIII metal and a non-acidic zeolite support to produce a first reformate stream; and the C.sub.8+ cut is subjected to catalytic aromatization at elevated temperatures in a second reformer in the presence of hydrogen and using an acidic catalyst comprising at least one Group VIII metal and a metallic oxide support to produce a second reformate stream. Less than 20 wt. % of the total amount of C.sub.Type: GrantFiled: June 6, 1995Date of Patent: April 18, 2000Assignee: Chevron Chemical CompanyInventors: Gerald J. Nacamuli, Bruce J. Thom
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Patent number: 5958218Abstract: Hydrocarbon feedstocks are hydroprocessed in parallel reactors, while hydrogen flows in series between the reactors. A first hydrocarbon feedstock and a hydrogen-rich recycle gas stream are introduced to a first reactor, where a first reactor effluent stream is produced and fed to a first separator, which separates the first reactor effluent stream into a first hydrogen-rich gas stream and a first hydroprocessed product stream. The first hydrogen-rich gas stream and a second hydrocarbon feedstock are fed to a second reactor, where a second reactor effluent stream is produced and fed to a second separator, which separates the second reactor effluent stream into a second hydrogen-rich gas stream and a second hydroprocessed product stream. A make-up hydrogen stream is added to the second hydrogen-rich gas to form the hydrogen-rich recycle gas stream that is compressed and fed to the first reactor.Type: GrantFiled: January 22, 1996Date of Patent: September 28, 1999Assignee: The M. W. Kellogg CompanyInventors: Michael G. Hunter, Kenneth W. Goebel
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Patent number: 5944982Abstract: A process for the dual riser contacting of a primary feed and a secondary recycle feed fraction uses independent recovery of the separate streams from the riser cracking zone to improve the product yields and properties. Separate recovery segregates the upgraded recracked components from the rest of the primary cracked products. The benefits of selective of recracking are lost if the upgraded products from the recycle stream become recombined with the primary cracked product. The selectively recovered recycle feed may undergo hydroprocessing to hydrogenate, hydrocrack and/or hydrotreatmement before recracking. The process can also make highly efficient use of the high residual activity in the catalyst that has contacted the secondary feed.Type: GrantFiled: October 5, 1998Date of Patent: August 31, 1999Assignee: UOP LLCInventor: David A. Lomas
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Patent number: 5904835Abstract: A large hydrocracking feed stream is processed without resorting to full dual reaction trains by passing a portion of the feed stream into each of two reaction zones, with the effluents of the two reaction zones being charged into a common separation and product recovery facility. Unconverted hydrocarbons recovered in the product recovery facility are passed into only one of the reaction zones.Type: GrantFiled: October 24, 1997Date of Patent: May 18, 1999Assignee: UOP LLCInventor: Vasant P. Thakkar
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Patent number: 5833837Abstract: An integrated process is provided for preparing a dewaxed heavy lube base oil product and a dewaxed light lube base oil product from a waxy feedstock. The process includes separating the waxy feedstock into two or more fractions. A light fraction is upgraded to increase its VI, and dewaxed in an isomerization process using a wax isomerization catalyst such as SAPO-11, SAPO-31 or SAPO-41. A heavy fraction is upgraded to increase its VI, and dewaxed in the presence of a wax cracking catalyst such as ZSM-5.Type: GrantFiled: September 29, 1995Date of Patent: November 10, 1998Assignee: Chevron U.S.A. Inc.Inventor: Stephen J. Miller
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Patent number: 5817226Abstract: There is provided a process and a device with a convection zone (A) and a radiation zone (B) in a furnace (10), whereby the process includes: a first stage of precracking a feedstock of light hydrocarbons (1) and a second stage of final co-cracking of the mixture that is composed of this precracked light feedstock (7) and a feedstock of heavy hydrocarbons (2). The process further includes: separate heating of the two feedstock streams (1 and 2) in the convection zone (A), in which the preheating temperature of each feedstock stream remains below the initial cracking temperature in each case; precracking (5) of the preheated light hydrocarbons; mixing of precracked light hydrocarbon stream (8) while a mixed stream (9) is formed; intense heating of mixed stream (9) to a temperature that is higher than the initial cracking temperature by virtue of the fact that the mixture is introduced into the radiation zone (B) of the furnace (10); and cooling (15) of cracked gases outside the furnace (10).Type: GrantFiled: July 10, 1996Date of Patent: October 6, 1998Assignees: Linde Aktiengesellschaft, Procedes Petroliers Petrochimiques et SARLInventor: Eric Lenglet
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Patent number: 5770044Abstract: Disclosed is a catalytic cracking process which includes more than one catalytic cracking reaction step. The process integrates a hydroprocessing step between the catalytic cracking reaction steps in order to maximize olefins production, distillate quality and octane level of the overall cracked product. Preferably, the hydroprocessing step is included between the reaction stages, and a portion of the hydroprocessed products, i.e., a naphtha and mid distillate fraction, is combined with cracked product for further separation and hydroprocessing. It is also preferred that the first catalytic cracking reaction step be a short contact time reaction step.Type: GrantFiled: August 23, 1996Date of Patent: June 23, 1998Assignee: Exxon Research and Engineering CompanyInventors: Edward S. Ellis, Ramesh Gupta, Martin G. Bienstock
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Patent number: 5770043Abstract: Disclosed is a catalytic cracking process which includes more than one catalytic cracking reaction step. The process integrates a hydroprocessing process step between the catalytic cracking reaction steps in order to maximize olefins production, mid-distillate quality and naphtha octane level in the cracked products. Preferably, a first cracked hydrocarbon product is obtained from a first cracking stage and separated into a mid-distillate and gas oil containing fraction having an initial boiling point of at least 300.degree. F., the distillate and gas oil containing fraction is hydroprocessed, and a naphtha fraction and a gas oil containing bottoms fraction of the hydroprocessed material are cracked in a second cracking stage.Type: GrantFiled: August 23, 1996Date of Patent: June 23, 1998Assignee: Exxon Research and Engineering CompanyInventors: Edward S. Ellis, Ramesh Gupta, Martin G. Bienstock
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Patent number: 5730859Abstract: A process for contemporaneously catalytically cracking a paraffin rich feedstock and a heavy feedstock wherein the feedstocks are segregated prior to catalytic cracking in separate reactors with regenerated particulate catalyst solids. The process provides for the separate optimal cracking of paraffinic constituents and heavy naphthenic constituents while maintaining an overall heat balance.Type: GrantFiled: July 16, 1996Date of Patent: March 24, 1998Assignee: Stone & Webster Engineering CorporationInventors: Axel R. Johnson, Joseph L. Ross, Atulya V. Saraf
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Patent number: 5707511Abstract: A process for simultaneously removing heteroatoms, such as sulfur, from a virgin distillate stream and a light catalytic cyclic stream in two reaction zones in a hydrotreating process unit. One reaction zone will be a low temperature reaction zone and the other will be the high temperature zone. In the low temperature reaction zone, the cracked stream is reacted with a hydrotreating catalyst at a predetermined temperature and in high temperature reaction zone, the virgin distillate stream is reacted with a catalyst which is less reactive than that of the first reaction zone. When catalyst in the high reaction zone is replaced with fresh catalyst the temperature is lowered so that it now becomes the low temperature zone in which the cracked stream is redirected.Type: GrantFiled: December 22, 1994Date of Patent: January 13, 1998Assignee: Exxon Research and Engineering CompanyInventors: Gerald E. Markley, George C. Hadjiloizou
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Patent number: 5699270Abstract: A method for controlling the manufacture of lubricating oils involving the steps of distillation, extracting, dewaxing and optionally hydrofining; or for controlling operating units associated with refinery or chemical processes with feed stocks and products boiling above 350.degree. C. The method comprises selecting one or more chemical or perceptual or physical or performance properties of the lubricating oil or the feedstock, distillate or raffinate used in the manufacturing process; or of the refinery or chemical process feed stocks or products; creating a training set from reference samples which contain characteristic molecular species present in the lubricating oil, feedstock, distillate or raffinate used in the manufacturing process or from the refining or chemical operations. The reference samples are subjected to GC/MS analysis wherein the often collinear data generated is treated by multivariate correlation methods.Type: GrantFiled: June 23, 1995Date of Patent: December 16, 1997Assignee: Exxon Research and Engineering CompanyInventors: Terrence Rodney Ashe, Ross William Kapala, Stilianos George Roussis
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Patent number: 5690810Abstract: Disclosed is a one-step process intended as an alternative to catalytic reforming which upgrades naphthas by simultaneously saturating aromatics, isomerizing paraffins and selectively cracking heavier hydrocarbons which comprises contacting heavy naphtha feedstock in a reforming zone with a catalyst comprising a solid acid, optionally with a binder of Group III and/or IV of the Periodic Table, having a metal from Group VIII of the Periodic Table deposited thereon, wherein the reaction conditions are much milder than those typically used in catalytic reforming.Type: GrantFiled: November 14, 1994Date of Patent: November 25, 1997Assignee: Texaco Inc.Inventors: Richard Vance Lawrence, Pei-Shing Eugene Dai
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Patent number: 5651878Abstract: A naphtha or a middle distillate hydrocarbon is hydrodearomatized by hydrotreating in the presence of a catalyst containing a carbon support bearing (i) molybdenum or tungsten, (ii) a metal or non-noble Group VIII, and (iii) chromium.Type: GrantFiled: April 4, 1996Date of Patent: July 29, 1997Assignee: Texaco Inc.Inventors: Chakka Sudhakar, Frank Dolfinger, Jr., Max Raphael Cesar
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Patent number: 5616237Abstract: A fluid catalytic cracking unit equipped with multiple feed injection points along the length of the riser is operated such that portions of the same fresh feed are charged to different feed injection points. Preferably, the hydrocarbon fresh feed can be split into two or more non-distinct fractions, with one fraction charged to the bottom injection point along the length of the riser reactor, and the remaining fractions charged to injection points progressively higher up along the length of the riser reactor with the temperature of the upper injection feed fractions being different from that of the lowest injection point fraction prior to entry into the FCC riser reactor. Hydrocarbon products from the cracking process can be recycled to one or more of the various injection points along the length of the riser.Type: GrantFiled: April 1, 1996Date of Patent: April 1, 1997Assignee: Chevron Research and Technology Company, A Division of Chevron U.S.A. Inc.Inventors: Ashok S. Krishna, Robert C. Skocpol, Lewis A. Frederickson
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Patent number: 5582711Abstract: Disclosed is a catalytic cracking process which includes more than one catalytic cracking reaction step. The process integrates a hydroprocessing step between the catalytic cracking reaction steps in order to maximize olefins production, distillate quality and octane level of the overall cracked product. Preferably, the hydroprocessing step is included between the reaction stages, and a portion of the hydroprocessed products, i.e., a naphtha and mid distillate fraction, is combined with cracked product for further separation and hydroprocessing. It is also preferred that the first catalytic cracking reaction step be a short contact time reaction step.Type: GrantFiled: August 17, 1994Date of Patent: December 10, 1996Assignee: Exxon Research and Engineering CompanyInventors: Edward S. Ellis, Ramesh Gupta, Martin G. Bienstock
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Patent number: 5536391Abstract: This invention discloses an enhanced process for the hydroprocessing of a feed, the feed comprising a highly aromatic refinery distillate stream boiling in the range between 300.degree. and 900.degree. F. The feed is separated into light and heavy streams such that the light stream contains from 0.1 to 5 wt. % dibenzothiophene, substituted dibenzothiophenes, and heavier polycyclic thiophenes. The lighter stream is hydrotreated at pressures from 300.degree. to 1000.degree. F. with a commercial catalyst having a hydrogenation component. The heavier stream is treated in the presence of hydrogen at higher pressure, from 600 to 2000 psig with a catalyst comprising active material having a Constraint Index of less than 2 in addition to a hydrogenation component in order to achieve over 35% conversion of material boiling above 630.degree. F. The active material of the catalyst is a highly siliceous zeolite or an acidic amorphous silica-alumina material.Type: GrantFiled: January 17, 1995Date of Patent: July 16, 1996Inventors: Paul A. Howley, Gregory A. Jablonski, L. Deane Rollmann, Hye K. C. Timken
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Patent number: 5447622Abstract: Disclosed is a method which combines catalytic cracking and olefin production using a coked catalytic cracking catalyst as a dehydrogenation catalyst to dehydrogenate an alkane feed stream and form an olefin rich product stream. The method uses a staged backmixed regeneration system to form the dehydrogenation catalyst and to fully reactivate deactivated cracking catalyst for reuse in the cracking reaction. The catalyst preferably comprises a crystalline tetrahedral framework oxide component.Type: GrantFiled: November 19, 1993Date of Patent: September 5, 1995Assignee: Exxon Research & Engineering Co.Inventors: Michael C. Kerby, Roby Bearden, Jr., Stephen M. Davis
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Patent number: 5435906Abstract: A process for contemporaneously catalytically cracking a paraffin rich feedstock and a heavy feedstock wherein the feedstocks are segregated prior to catalytic cracking in separate reactors with regenerated particulate catalyst solids. The process provides for the separate optimal cracking of paraffinic constituents and heavy naphthenic constituents while maintaining an overall heat balance.Type: GrantFiled: August 9, 1993Date of Patent: July 25, 1995Assignee: Stone & Webster Engineering CorporationInventors: Axel R. Johnson, Joseph L. Ross, Atulya V. Saraf
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Patent number: 5403469Abstract: Hydrotreated and hydrocracked liquid/vapor effluents are separated in a common separating vessel under elevated pressure. High quality middle distillates and low-sulfur/low-hydrogen-containing FCC feedstocks are produced.Type: GrantFiled: November 1, 1993Date of Patent: April 4, 1995Assignee: Union Oil Company of CaliforniaInventors: Dennis A. Vauk, Christopher J. Anderle
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Patent number: 5401388Abstract: A process combination is disclosed to selectively upgrade naphtha to obtain gasoline which is in accordance with current standards for reformulated fuels. A naphtha feedstock is fractionated to selectively direct light naphtha to isomerization or blending, a head-cut fraction to reforming, and a heavy potion to selective isoparaffin synthesis to yield light and heavy synthesis naphtha and isobutane. The heavy potion of the synthesis naphtha is processed by reforming. Light naphtha may be isomerized, with or without recycle of low-octane components of the product. A gasoline component is blended from light, synthesis, and reformate products from the process combination.Type: GrantFiled: September 7, 1993Date of Patent: March 28, 1995Assignee: UOPInventors: Robert J. Schmidt, Michael B. Russ, Paula L. Bogdan, R. Joe Lawson, Norman L. Gilsdorf
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Patent number: 5401387Abstract: A process for multi-stage catalytic cracking is disclosed. A first stage cracks a first feed at atmospheric to 100 psig over a shape selective zeolite to convert from 10 to 90%, by volume, to lighter products rich in iso-compounds which may be used to make ethers. A second feed, which may include 700.degree. F.+ liquid from the selective cracking reaction, is cracked in a catalytic cracking (FCC) unit. Preferably all or some of the products from the shape selective cracking reactor are fractionated in the FCC main column.Type: GrantFiled: August 3, 1993Date of Patent: March 28, 1995Assignee: Mobil Oil CorporationInventors: Mohsen N. Harandi, Hartley Owen
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Patent number: 5401385Abstract: A process combination is disclosed to selectively upgrade catalytically cracked gasoline to obtain products suitable for further upgrading to reformulated fuels. A naphtha feedstock, preferably heavy naphtha, is hydrogenated to saturate aromatics, followed by selective isoparaffin synthesis to yield light and heavy synthesis naphtha and isobutane. The heavy synthesis naphtha may be processed by reforming, light naphtha may be isomerized, and isobutane may be upgraded by dehydrogenation, etherification and/or alkylation to yield gasoline components from the process combination suitable for production of reformulated gasoline.Type: GrantFiled: August 10, 1993Date of Patent: March 28, 1995Assignee: UOPInventors: Robert J. Schmidt, Paula L. Bogdan, R. Joe Lawson, J. W. Adriaan Sachtler
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Patent number: 5382349Abstract: A method of hydrotreatment of heavy hydrocarbon oil in the presence of catalysts which comprises hydrodemetallizing and hydrocracking the heavy hydrocarbon oil successively and thereafter hydrodesulfurizing and hydrodenitrogenating the treated heavy hydrocarbon oil. The hydrocracking is carried out in the presence of a catalyst comprising at least one metal or metal compound of the group VIA or the group VIII of the Periodic Table supported on a carrier comprising 10 to 90 weight % of an iron-containing aluminosilicate and 90 to 10 weight % of an inorganic oxide. Other methods of treatment of heavy hydrocarbon oil comprise the hydrotreatment in conjunction with fluid catalytic cracking and/or thermal hydrocracking. The methods provide a naphtha fraction, a kerosene fraction and a gas oil fraction which can be obtained from the heavy hydrocarbon oil efficiently with high yield.Type: GrantFiled: September 14, 1992Date of Patent: January 17, 1995Assignee: Idemitsu Kosan Co., Ltd.Inventors: Mitsuru Yoshita, Kenichi Ii, Kazuhiro Kashima, Eiichiro Kanda, Takanori Ohno, Naotake Takeuchi
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Patent number: 5376257Abstract: A process for feed oil refining for production of lubricating oil, by using an equipment for lubricating oil production including a fulfural refining unit, a hydrotreating unit and a ketone dewaxing unit, all connected in series. In this process, operations associated with the switch of feed oil are conducted by carrying out the first to seventh step groups successively. Each step group is initiated when a given time has passed since the start of the previous step group, or when the value of a particular measurement item has reached a target value, or when the value of a particular measurement item has shown a change. First, in the first step group, the amount of feed oil supplied to each unit, etc. is adjusted and, in the second step group, the feed oil to the furfural refining unit is switched.Type: GrantFiled: August 2, 1993Date of Patent: December 27, 1994Assignee: Nippon Petroleum Refining Company, LimitedInventors: Akinori Odan, Noboru Shimizu, Norihiko Ageishi
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Patent number: 5364514Abstract: This invention provides an integrated process for converting a hydrocarbon feedstock having components boiling above 300.degree. F. into liquid fuel products boiling in the range of from about 80.degree. F. to about 700.degree. F.Type: GrantFiled: April 13, 1993Date of Patent: November 15, 1994Assignee: Shell Oil CompanyInventors: Laura J. Sanborn, Stanley N. Milam, Woodrow K. Shiflett
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Patent number: 5348642Abstract: A catalytic cracking process and apparatus wherein particles of cracking catalyst circulate continuously between a reaction zone and a regeneration zone and hot regenerated catalyst from the regeneration zone contacts hydrocarbon feed in the reaction zone to produce cracked hydrocarbon products and spent catalyst. The spent catalyst is recovered and subjected to stripping in a stripping zone to remove strippable material therefrom. The stripped spent catalyst is circulated to the regeneration zone for oxidative exothermic regeneration. Some hot regenerated catalyst is passed directly from the regenerator to the stripping zone via a conduit provided for this purpose. Another hydrocarbon stream is passed into contact with the hot regenerated catalyst in this conduit. The said other hydrocarbon stream is converted to products of enhanced value (e.g., olefins) during contact with catalyst in the conduit, and the said products are recovered.Type: GrantFiled: February 11, 1993Date of Patent: September 20, 1994Assignee: Exxon Research Engineering Co.Inventors: Willibald Serrand, Philip Holmes, Todd R. Steffens, Patrick H. Terry, Paul E. Eberly
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Patent number: 5314610Abstract: A staged catalytic cracking process and apparatus is disclosed where each stage has a catalyst to oil ratio of at least 15 and there are individual hydrocarbon feeds to each stage and product removal from each stage. There is a residence time profile with the first stage having a short residence time and the successive stages having progressively longer residence times. Further, there is a feed profile with the lighter components of the total feed going to the first stage and the heavier components being fed to the later stages. The apparatus has a generally vertical orientation which permits it to be incorporated into existing cracking units for upgrading and also easily provides for both short and long residence times.Type: GrantFiled: May 29, 1992Date of Patent: May 24, 1994Assignee: ABB Lummus Crest Inc.Inventor: Robert J. Gartside
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Patent number: 5310477Abstract: FCC process uses an open reactor vessel to house cyclones or other separation devices that reduce the carry through of product gases with the catalyst into the reactor vessel to less than 10 wt. % so that the catalyst in the reactor vessel provides a secondary dealkylation zone. By using a highly efficient separation device to remove product from the catalyst, the environment in the reactor vessel receives a low volume of cracked hydrocarbons from the riser conversion zone and provides a convenient secondary reaction zone that receives a recycled heavy gasoline fraction separated from the riser product stream. Dealkylation in the secondary reaction zone provides additional light gasoline to satisfy T90 requirements.Type: GrantFiled: April 22, 1992Date of Patent: May 10, 1994Assignee: UOPInventor: David A. Lomas
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Patent number: 5244565Abstract: A process for the production of distillate hydrocarbon from atmospheric fractionation residue and waste lubricants by means of contacting the waste lubricant with a hot hydrogen-rich gaseous stream to increase the temperature of this feed stream to vaporize at least a portion of the distillable hydrocarbonaceous compounds thereby producing a distillable hydrocarbonaceous stream which is immediately hydrogenated in an integrated hydrogenation zone. The vaporization of the waste oil is also conducted in the presence of a vacuum fractionation residue which is produced in the integrated process. The resulting effluent from the integrated hydrogenation zone and a distillable hydrocarbon stream recovered from the atmospheric fraction residue is catalytically converted to produce lower molecular weight hydrocarbon compounds.Type: GrantFiled: December 26, 1991Date of Patent: September 14, 1993Assignee: UOPInventors: Steven P. Lankton, Tom N. Kalnes, Robert B. James, Jr.
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Patent number: 5242576Abstract: A process combination is disclosed to selectively upgrade naphtha to obtain gasoline which is in accordance with current standards for reformulated fuels. A naphtha feedstock is fractionated to selectively direct light naphtha to isomerization or blending, a heart-cut fraction to reforming, and a heavy portion to selective isoparaffin synthesis to yield light and heavy synthesis naphtha and isobutane. The heavy portion of the synthesis naphtha is processed by reforming. Light naphtha may be isomerized, with or without recycle of low-octane components of the product. A gasoline component is blended from light, synthesis, and reformate products from the process combination.Type: GrantFiled: November 21, 1991Date of Patent: September 7, 1993Assignee: UOPInventors: Robert J. Schmidt, Michael B. Russ, Paula L. Bogdan, Randy J. Lawson
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Patent number: 5200059Abstract: A process combination is disclosed to reduce the aromatics content and increase the oxygen content of a key component of gasoline blends. A naphtha feedstock having a boiling range usually suitable as catalytic-reforming feed is processed by selective isoparaffin synthesis to yield lower-molecular weight hydrocarbons including a high yield of isobutane. The isobutane is processed to yield an ether component by dehydrogenation and etherification. The cracked light naphtha may be upgraded by isomerization. The heavier portion of the cracked naphtha is processed in a reformer. A gasoline component containing oxygen as ether and having a reduced aromatics content and increased volumetric yield relative to reformate of the same octane number is blended from the net products of the above processing steps. The process combination is particularly suited for use in an existing refinery.Type: GrantFiled: November 21, 1991Date of Patent: April 6, 1993Assignee: UOPInventors: Paula L. Bogdan, R. Joe Lawson, J. W. Adriaan Sachtler
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Patent number: 5198097Abstract: A process combination is disclosed to reduce the aromatics content and increase the oxygen content of a key component of gasoline blends. A naphtha feedstock having a boiling range usually suitable as catalytic-reforming feed is processed by selective isoparaffin synthesis to yield lower-molecular weight hydrocarbons including a high yield of isobutane. A portion of the isobutane is processed to yield an ether component by dehydrogenation to yield isobutene followed by etherification. Part of the isobutane and isobutene are alkylated to produce an alkylate component. The synthesis light naphtha may be upgraded by isomerization. The heavier portion of the synthesis naphtha is processed in a reformer. A gasoline component containing oxygen as ether and having a reduced aromatics content and increased volumetric yield relative to reformate of the same octane number is blended from the net products of the above processing steps.Type: GrantFiled: November 21, 1991Date of Patent: March 30, 1993Assignee: UOPInventors: Paula L. Bogdan, R. Joe Lawson, J. W. Adriaan Sachtler
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Patent number: 5194227Abstract: The conventional wye (where the clean regenerated catalyst returns from the regenerator to contact the feed as it enters the riser) is replaced with two or more wyes, all connected between the regenerator outlet and the inlet to a common short cracking riser. Each wye has a separate injector which can inject; e.g., diesel oil, so that neat (unmixed) diesel contacts clean catalyst and the mixture rises up a smaller riser before entering a short main riser where the largely cracked mixture is admixed with similar cat-vacuum bottoms, etc. mixtures from the other wyes. Most cracking occurs before entering the common riser so the effect is similar to a riser cracker operating on a single unmixed feed.Type: GrantFiled: October 2, 1991Date of Patent: March 16, 1993Assignee: Ashland Oil, Inc.Inventors: Charles B. Miller, Howard F. Moore
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Patent number: 5188725Abstract: An improvement in iso-olefin etherification is obtained in an integrated process combining a fluidized catalytic cracking reaction and a fluidized catalyst etherification reaction wherein zeolite catalyst particles are withdrawn in partially deactivated form from the ether reaction stage and added as part of the catalyst in the FCC reaction.Type: GrantFiled: March 15, 1991Date of Patent: February 23, 1993Assignee: Mobil Oil CorporationInventor: Mohsen N. Harandi
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Patent number: 5176815Abstract: An FCC process uses an open reactor vessel to house cyclones or other separation devices that reduce the carry though of product gases with the catalyst into the reactor vessel to less than 5 wt. % so that the catalyst in the reactor vessel can contact a secondary feedstock. By using a highly efficient separation device to remove product from the catalyst the environment in the reactor vessel receives a low volume of feed hydrocarbons and riser by-products. These by products comprise mainly C.sub.2 and lighter gases which are inert to a variety of other feedstreams. Possible secondary feedstreams include hydrotreated heavy naphtha, hydrotreated light cycle oil, light reformate and olefins. It is highly useful to use the secondary feedstream to heat the catalyst in the reactor vessel to facilitate hot stripping of the catalyst. Heat may be introduced in this manner by heating the secondary feedstream or using a feedstream that produces an exothermic reaction in the reactor vessel.Type: GrantFiled: December 17, 1990Date of Patent: January 5, 1993Assignee: UOPInventor: David A. Lomas
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Patent number: 5139645Abstract: Process for producing gasoline components from a hydrocarbonaceous feed containing hydrocarbons comprising at least 4 carbon atoms, and hydrocarbons obtained thereby. The process comprises:a. separating feed into a heavy fraction containing hydrocarbons comprising at least 7 carbon atoms and a light fraction containing hydrocarbons comprising at most 7 carbon atoms,b. isomerizing at least part of the light fraction at a temperature between 50.degree. and 300.degree. C.,c. separating effluent of step b) into a stream containing branched hydrocarbons and a stream containing normal hydrocarbons, andd. isomerizing at least part of the stream containing normal hydrocarbons at a temperature which is higher than the temperature applied in step b).Type: GrantFiled: May 13, 1991Date of Patent: August 18, 1992Assignee: Shell Oil CompanyInventors: Ian E. Maxwell, Gerrit J. D. Otter, Gregory V. Tonks