Abstract: A single vane shutter flag is asynchronously controlled so that a measuring system light source is interrupted for a minimum necessary amount of time for standardization/calibration and normalization of InGaAs system detectors. Source/detector hemispheres or serially connected randomly oriented fiber bundles homogenize light passing to the detectors. Light source testing is performed by measuring spectral power distributions at a plurality of light source power levels and comparing the measurements to baseline characteristics established for the light source. Calibration sample life is extended indefinitely by controlling the shutter flag to block source light except for short calibration time periods during which standard light levels are provided.

Abstract: The invention relates to a method for identifying chemical substances, comprising the following steps: analyzing a group of reference substances using a first method of analysis and a second, different method of analysis, especially NIR and Raman spectroscopy; storing the first and second sets of characteristic properties obtained for each reference substance and the combined sets of characteristic properties obtained by combining said first set and said second set, in a reference data base; analyzing the substance to be analyzed with the first and second methods of analysis; comparing the combined set of characteristic properties of the substance to be analyzed with the combined sets of the reference substances; identifying the substance to be analyzed with one of the reference substances when the similarity between the combined set of the substance to be analyzed and the combined set of exactly one reference substance, as established according to a set scale, exceeds a predetermined threshold value.

Abstract: A method and apparatus for temperature-independent determination of a concentration of a probe gas in a sample over a selected temperature range between a low temperature TL corresponding to a lowest temperature expected or found in the sample and a high temperature TH corresponding to a highest temperature expected or found in the sample. In accordance with the method, a probe temperature function of the probe gas is determined over the temperature range using a first spectroscopic technique. Then, a second spectroscopic technique is selected, a reference gas is identified and a reference temperature function of the reference gas is determined using the second spectroscopic technique over the temperature range. In particular, the reference gas is identified such that a ratio of the probe temperature function and the reference temperature function is substantially constant over the temperature range.

Abstract: The present invention relates generally to the field of electrolytic and electroless metal plating. A method and system for determining the presence of analytes in metal plating solutions using Raman spectroscopy is described. High absorbance plating bath samples are analyzed by Raman spectroscopy by minimizing the penetration depth of the incident light beam. A chemical auto-dosing system for controlling the concentration of one or more plating bath additives in a metal plating bath is also provided.

Abstract: A mid-IR spectrometer attachment performs reflection spectroscopy measurements using commercially available infinity corrected light microscopes without degrading the microscope's performance. The mid-IR spectrometer attachment, which is mounted to and supported by the visible light microscope, introduces infrared radiation into the optical path of the microscope. Radiation from the mid-IR spectrometer source is directed by a trichroic radiation director to a mid-IR objective lens affixed to the microscope nosepiece. The objective lens focuses the radiation on to a subject sample surface in order to acquire either internally or externally reflected infrared spectra by subsequently directing the sample encoded reflected mid-infrared radiation to the radiation director and then to a mid-infrared radiation detection system.

Abstract: A process is provided for detecting the position of a paper web, especially in wet offset printing, wherein a strip free from ink or moistening agent is detected. A device is provided for detecting the position of a cut web, especially in wet offset printing. The device has a sensor for detecting the water content in the paper web.

Abstract: Using a nebulizer gas, sub micron and micron size particulates can be generated from a solution containing salts covering a broad range of elements. The fractional concentration of elements can be determined by bubbling the aerosol through aqueous acid and analyzing the aqueous acid for metals. The nebulizer can be coupled to an ICP (Inductively Coupled Plasma) torch and the ICPMS (Inductively Coupled Plasma Mass Spectrometer) or ICPOES (Inductively Coupled Plasma Optical Emission Spectrometer) response to different elements can be determined. This provides the response factor of the ICPMS or ICPOES for different elements.

Abstract: An infra-red analysis system is provided for analysing samples disposed in transparent or translucent containers. The system comprises: an infra-red light source; a container locating device for locating a container in a known position relative to the infra-red light source, a spectrometer disposed to receive infra-red light from the containers, means for reading the identity of a container, means for transmitting spectra recorded by the spectrometer to a database, means for recording the spectra and the identity of the container in the database in a record; and means for comparing spectra recorded by the spectrometer with a previously recorded spectrum for the same container.

Abstract: A method of calibrating a spectrographic inspection system, comprises providing a plurality of packages, each of the plurality of packages containing a group of items, wherein each of the groups of items has a known composition, measuring the reflectance value of each of the groups of items and thereby obtaining a reference reflectance value set, normalizing the reference reflectance value set and thereby creating a normalized reference reflectance value set, and storing the normalized reference reflectance value set.

Abstract: The present invention relates to a device and method for analyzing agricultural products. More particularly, the present invention relates to a device and method for real time, non-destructive analysis of the physical and chemical characteristics of one or more seeds.

Abstract: An infrared spectrophotometer is described wherein an infrared source is provided for emitting infrared energy. A sample cell is provided for containing gases to be analyzed and is positioned in the path of infrared energy emitted by the source. A detector assembly includes first, second and third thermopile detectors mounted in thermal proximity to each other and being responsive to impinging infrared energy to produce an electrical response. The first and second detectors are positioned in the path of infrared energy emitted by the source and the third detector is positioned out of the path of infrared energy emitted by the source. The spectrophotometer further comprises a narrow band filter corresponding to an absorption wavelength band for a gas of interest and a narrow band reference filter corresponding to a reference wavelength band.

Abstract: An optical measuring arrangement, particularly for quality control in continuous material flow processes, comprising a measuring head which is arranged immediately adjacent to a measurement object, a measurement light source which is held at the measuring head for illuminating a measurement spot on the measurement object, a measurement light reception device, at least one spectrometer which is optically coupled with the measurement light reception device via a light-conducting device, wherein the spectrometer and the light-conducting device are received in the measuring head, and a signal processing device which is likewise received in the measuring head. This results in a compact arrangement for reflection measurement which is easy to assemble and which, beyond this, supplies very accurate measurement results. Further, a measuring arrangement operating on the principle of spectroscopy is suggested for transmission measurement.

Abstract: Method for determining chemical constituents in an electrolysis cell for the production of metal, in particular aluminum, involving the use of light spectroscopy such as Raman spectroscopy that analyses the light emitted from the cell constituents and represents the light as a spectrum, wherein the analysis is performed directly in the cell while the cell is in its production mode, whereby the spectrum is analysed on the basis of reference spectrums based on known compositions, to determine chemical constituents in the cell. Also provided is an apparatus for performing this method.

Abstract: Apparatus and method for in situ measurements of at least one property of a liquid contained within a vessel.

Abstract: A spectrometer (110) having an interferometer, a detector (120) that produces a detector signal (20), and a dual-digitizer system including two analog-to-digital converters that simultaneously digitize low-gain and high-gain versions of the detector signal, and suitable data structures and associated firmware for merging the two resulting sets of digitized data into a single, high dynamic range set of data.

Abstract: In an infrared analysis instrument, a fiber optic probe, designed to be inserted into a particulate sample, is formed from distal ends of transmitting and receiving optic fibers. The distal ends of the transmitting fibers are located centrally in the probe and the distal ends of the receiving fibers are formed in a ring around the distal ends of the transmitting fibers. The distal ends of the receiving fibers are set back from the distal ends of the transmitting fibers. The receiving fibers carrying diffusely scattered light reflected from and transmitted through the particulate sample to a spectrophotometer housing containing fixed grating and an array of silicon photodetectors arranged to detect the spectrum dispersed by the grating in the range of 500 to 1100 nm.

Abstract: The invention relates to a system for the on-line measurement of a parameter in a processing stream. The system comprises a scanning head mounted adjacent a continuous stream of processed material, the scanning head comprising a remote light source and reflected light gathering and transmission apparatus; a near infrared spectrophotometer which includes a monochromator for resolving the reflected light into light of a discrete wavelength; a database containing a reference calibration equation linking absorption characteristics by wavelength and the quantified presence of the parameter of interest; and a computer for measuring the parameter by application of the calibration equation to the obtained spectrum for a sample and managing said system. The invention also comprises a method of on-line measurement of a parameter in a processing stream by NIR spectroscopy and networks comprising systems according to the invention.

Abstract: An optical channel monitor (OCM) or filter for analyzing an incident light carrying a number of narrow band signal channels such as WDM or DWDM channels. The OCM or filter use an acousto-optic tunable filter to receive and refract from an incident light a refracted light such that the refracted light contains a test channel with a center frequency &ngr;0. A first birefringent element is provided for filtering from the refracted light a first polarized light and a second polarized light orthogonal to the first polarized light. The transmission curves are engineered such that the transmissions of the first and second polarized light are substantially equal at the center frequency &ngr;0 of the test channel. The OCM or filter has a second birefringent element for filtering from the first polarized light a first polarized portion and a second polarized portion.

Abstract: An apparatus for verifying the identity of a dispensed pharmaceutical comprises an analysis unit adapted to determine a property of the dispensed pharmaceutical, an input device adapted to receive predetermined identifying information corresponding to the dispensed pharmaceutical, and a comparison unit adapted to compare the determined property of the dispensed pharmaceutical with the predetermined identifying information. In addition, a method of verifying a prescription, wherein the prescription comprises a pharmaceutical compound, comprises associating the prescription with a unique identifier, storing the unique identifier, determining the identity of the pharmaceutical compound, and comparing the identity of the pharmaceutical compound with the unique identifier.

Abstract: A process for detecting low levels of a predetermined quality trait present in an inhomogeneously distributed particulate substrate involving the steps of: (a) providing a particulate substrate to be analyzed; (b) providing a spectrometer with an electromagnetic detector capable of performing spectroscopic measurements with electromagnetic radiation; (c) providing a rotatable sample holder having a transparent area through which electromagnetic radiation may pass; (d) providing a tumbling member located within the rotatable sample holder for tumbling the particulate substrate contained therein; (e) introducing the particulate substrate into the rotatable sample holder; (f) simultaneously rotating and tumbling the particulate substrate contained within the rotatable sample holder; and (g) activating the spectrometer, thereby illuminating the particulate substrate contained within the rotatable sample holder with electromagnetic radiation.

Abstract: A method for determining the mechanical properties of decayed wood that has been exposed to wood decay microorganisms, comprising: a) illuminating a surface of decayed wood that has been exposed to wood decay microorganisms with wavelengths from visible and near infrared (VIS-NIR) spectra; b) analyzing the surface of the decayed wood using a spectrometric method, the method generating a first spectral data of wavelengths in VIS-NIR spectra region; and c) using a multivariate analysis to predict mechanical properties of decayed wood by comparing the first spectral data with a calibration model, the calibration model comprising a second spectrometric method of spectral data of wavelengths in VIS-NIR spectra obtained from a reference decay wood, the second spectral data being correlated with a known mechanical property analytical result obtained from the reference decayed wood.

Abstract: A method of processing data from at least one spectrophotometer characterized by the steps of transferring the data from the spectrophotometer to a control processing unit, processing the data at the central processing unit, and transferring the processed data to the output device.

Abstract: A topocompositional image of an inanimate object or surface can be generated that comprises data that relates to a topographical image, data that relates to a chemical compositional image, and combining such topographical and chemical compositional data to form a composite image. Conceptually a laser or other suitable imaging source that functions to induce both topographical and chemical compositional data directs a laser beam into a scanning optics source. The scanning optics source directs an active beam to a point on a surface. A sensor subsequently collects data and information from the surface by receiving the reflection or deflection of the active beams in order to provide position, chemical compositional and topographical data that represent the interaction of the active beam with a point. Position data, chemical compositional data and topographical data are transmitted along individual feeds to a data analysis component where they are analyzed and combined in order to generate a composite image.

Abstract: An optic device with a variable operating mode comprises a micromirror which can be obscured by means of an electrostatically controlled microshutter. In the operating condition of the microshutter, the petal of this adheres over a substrate to allow a beam of light to reach the mirror. In the condition at rest, the petal is curled up and one of its surfaces receives the beam of light and reflects it in all directions, at the same time preventing this from reaching the mirror.

Abstract: The invention relates to a process and an apparatus for identifying articles which are at least partly made from at least one polymer, using an optical spectrometer and a transport system, said process comprising the steps of:

Abstract: A method and apparatus of determining the analyte concentration of a test sample is described. A temperature gradient is introduced in the test sample and infrared radiation detectors measure radiation at selected analyte absorbance peak and reference wavelengths. The modulation of the temperature gradient is controlled by a surface temperature modulation. A transfer function is determined that relates the surface temperature modulation to the modulation of the measured infrared radiation. Reference and analytical signals are detected. In the presence of the selected analyte, phase and magnitude differences in the transfer function are detected. These phase and magnitude differences, having a relationship to analyte concentration, are measured, correlated, and processed to determine analyte concentration in the test sample.

Abstract: A method of determining the analyte concentration of a test sample is described. A temperature gradient is introduced in the test sample and infrared radiation detectors measure radiation at selected analyte absorbance peak and reference wavelengths. Reference and analytical signals are detected. In the presence of the selected analyte, parameter differences between reference and analytical signals are detectable. These parameter differences, having a relationship to analyte concentration, are measured, correlated, and processed to determine analyte concentration in the test sample. Accuracy is enhanced by inducing a periodically modulated temperature gradient in the test sample. The analytical and reference signals may be measured continuously and the parameter difference integrated over the measurement period to determine analyte concentration.

Abstract: An assembly and method provide sensitive high speed spectroscopic gas detection via the use of a non-collimated convergent light path through a birefringent crystal in a birefringent filter design to allow improved light collection and a reduction in the number of optical elements required to produce a useful absorption signal for the detection of gases.

Abstract: The present invention provides a method and apparatus for detecting a presence of an analyte in a fluid medium. Specifically, the present invention provides a detection probe comprising an analyte affinity compound which has a higher affinity for the analyte in a fluid medium than the fluid medium itself. In this manner, the analyte in the fluid medium is concentrated onto the detection probe. The present invention also provides a method for using the same in qualitative or quantitative analysis of the analyte in a fluid medium.

Abstract: The present invention relates to a method for identification of plastic materials of interest by optical measurements, preferably spectroscopic measurements, comprising the steps of measuring a sample and providing a sample spectrum, providing reference spectra for a given group of reference materials of interest, determining spectral distances between sample spectrum and reference spectra, material identification by associating the sample to the material having the reference spectrum with the smallest spectral distance to the sample spectrum. In this method at least one identification frequency range having a high absolute deviation ratio D and/or a high smoothed deviation ratio D′ between all pairs of possible plastic materials of interest is determined, and that said spectral distance is only determined within said at least one identification frequency range.

Abstract: A photometric device and method for determining the gross calorific value of a test gas, especially natural gas having a radiation source that produces a measuring beam and a modulation unit to modulate the measuring beam. A test cell with test gas and a receiver for the beam are arranged successively in the path of the measuring beam. The measuring signals of the receiver are supplied to an evaluation unit that includes at least one signal amplifier for the amplification of the signals. The signal amplifier is provided with adjustment devices to adjust the signal amplifier according the spectral properties of the measuring beam. The gross calorific value of the gas is indicated by the sum of the amplified measuring signals produced in a computing machine.

Abstract: A method of determining the analyte concentration of a test sample is described. A temperature gradient is introduced in the test sample and infrared radiation detectors measure radiation at selected analyte absorbance peak and reference wavelengths. Reference and analytical signals are detected. In the presence of the selected analyte, parameter differences between reference and analytical signals are detectable. These parameter differences, having a relationship to analyte concentration, are measured, correlated, and processed to determine analyte concentration in the test sample. Accuracy is enhanced by inducing a periodically modulated temperature gradient in the test sample. The analytical and reference signals may be measured continuously and the parameter difference integrated over the measurement period to determine analyte concentration.

Abstract: A method and a device are disclosed for determining the thickness and growth rate of an ice layer on structural component parts, particularly of aircraft, wherein the thickness and growth rate of an ice layer are determined and displayed in a simple, economical and dependable manner. To this end, a method is disclosed by which the radiation incident on a surface covered by an ice layer or disturbing layer is separated spectrally by a holographic grating connected with a line receiver into enough wavelength regions that a correction of the ice absorption is achieved by comparing the measured radiation with a stored reflection curve of an uncoated surface and by combining the comparison values and determining the peak area in the wavelength region of the ice absorption, and wherein from the thickness of the ice layer and disturbing layer and the ice thickness values obtained in the measurement intervals the growth rate of the ice layer is determined and displayed.

Abstract: A method for segregating qualities of an agricultural product during processing of the product comprises the step of setting a desired range of a measurement value (2). The measurement value represents a property of the product and defines a first quality of the product for which the measurement value is inside the range and a second quality of the product for which the measurement value is outside the range. The method further comprises the step of analyzing (4) the quality of the product that is being processed. The step of analyzing comprises the steps of continuously extracting samples of the product (4a), irradiating each sample by electromagnetic radiation (4d), spatially separating electromagnetic radiation of different wavelengths (4e), and detecting electromagnetic radiation emitted from the sample (4f). The step of detecting produces intensity signals indicative of detected electromagnetic radiation of different wavelengths.

Abstract: A hemispherical detector comprising a plurality of photodetectors arranged in a substantially contiguous array, the array being substantially in the shape of a half-sphere, the half-sphere defining a closed end and an open end, the open end defining a substantially circular face. Also provided is a method for constructing a hemispherical detector comprising the steps of making a press mold of the desired shape of the hemispherical detector, pouring a material into the press mold to form a cast, finishing the cast to remove any defects, coating the cast with a coating material, and attaching a plurality of photodetectors to the cast.

Abstract: A robust, compact spectrometer apparatus for determining respective concentrations or partial pressures of multiple gases in a gas sample with single as well as multiple and even overlapping, absorption or emission spectra that span a wide spectral range.

Abstract: In a method for determining the dry mechanical strength for a green wood, the improvement comprising: (a) illuminating a surface of the wood to be determined with a reduced range of wavelengths in the VIS-NIR spectra 400 to 1150 nm, said wood having a green moisture content; (b) analyzing the surface of the wood using a spectrometric method, the method generating a first spectral data of a reduced range of wavelengths in VIS-NIR spectra; and (c) using a multivariate analysis technique to predict the mechanical strength of green wood when dry by comparing the first spectral data with a calibration model, the calibration model comprising a second spectrometric method of spectral data of a reduced range of wavelengths in VIS-NIR spectra obtained from a reference wood having a green moisture content, the second spectral being correlated with a known mechanical strength analytical result obtained from the reference wood when dried and a having a dry moisture content.

Abstract: A mid-infrared (mid-IR) spectrometer attachment performs reflection spectroscopy measurements using commercially available infinity corrected light microscopes. The mid-IR spectrometer attachment introduces infrared radiation into the optical path of a visible light microscope. Radiation from the mid-IR spectrometer source is directed by a radiation director to a mid-IR objective lens affixed to the microscope nosepiece. The objective lens focuses the radiation on to a subject sample surface in order to acquire either internally or externally reflected infrared spectra by subsequently directing the sample encoded reflected infrared radiation to an infrared radiation detection system. The mid-IR spectrometer attachment is mechanically and optically compatible with a plurality of commercial infinity-corrected visible light microscopes.

Abstract: Methods and apparatus for measuring the millimeter or submillimeter wave absorption spectra in a sample of DNA molecules are provided.

Abstract: An interference filter transmission wavelength scanning photometer wherein the angle of inclination of an interference filter (3) is periodically varied, the wavelength of the light to be transmitted is modulated with the periodical variation centered at the maximum absorption wavelength of the interesting component, the variation of the intensity of the light transmitted through a sample is extracted by an infrared sensor (11) as an electrical signal. The time between the rise and fall zero cross points of the AC component of the electric signal is determined by a microprocessor (16), the ratio (T−2T1)/T.

Abstract: The invention relates to a method and an apparatus for measuring the properties of paper from a moving paper web in a paper machine. An infrared beam is directed to the paper web. The infrared beam, passed through or reflected from the paper web, is split into wavelength components with a spectrograph, and signals of the different wavelength components are measured, and the properties of paper are determined on the basis of the signals.

Abstract: An absorption spectroscopy apparatus having a fluid inlet and a fluid outlet. The apparatus includes a sample cell including an axis, a side wall having at least one curved reflective surface arrayed about the axis and facing inwardly with respect to the cell such that a beam of energy directed against a predetermined location on the reflective surface is reflected back and forth off the reflective surface and remains in substantially the same plane while inside the cell, and at least one port in the sidewall. The apparatus also includes at least one source/detector reflector having a curved profile in a plane extending perpendicular to the axis of the cell. The reflector is positioned with respect to the port of the cell to reflect energy through the port of the cell and against the predetermined location on the reflective surface of the side wall of the cell.

Abstract: The present invention has applications that include detecting color variation in a region, for example, color variations due to temperature changes in an area of ocean water, and, in a more specific application, detecting bioluminescence of certain organisms known to attach themselves to various objects. In one aspect of the invention, an acousto-optic tunable filter hyperspectral imaging system is moved across the region to collect a series of images in which each image represents the intensity of light at a different wavelength. In one embodiment, the acousto-optic tunable filter hyperspectral imaging system includes a motion platform for positioning the acousto-optic tunable filter hyperspectral imaging system over successive Y-coordinates of a region in a direction substantially parallel to a direction of motion of the motion platform.

Abstract: Tomographic approaches to hyperspectral imaging, such as CTHIS13 (Chromotomographic Hyperspectral Imaging Sensor), can eliminate the need for the slit, filter, or resonant cavity and substantially increase the optical throughput of the system. These systems capture most of the photon energy from the entire spectral band over the entire measurement interval. Uncooled LWIR imaging technology uses thermal based detecting elements that are less sensitive than the competing photon based cooled detecting elements, and require high optical throughput. An uncooled LWIR hyperspectral imager is described that combines a new high optical efficiency spectral imaging technique combined with a high performance uncooled thermal imager. The merging of these technologies in the current invention will significantly reduce the size, weight, and power requirements of LWIR hyperspectral systems.

Abstract: A system for the remote detection and analysis of trace chemical agents in the air. A beam of electromagnetic radiation is used to radiate a cloud. The radiation energy that is absorbed by the cloud is thermalized by collisional energy transfer between the molecules that absorb the radiation. Increases in the cloud temperature increase the emission intensity of the molecules against the background, resulting in improved detection of the target molecules. A tracking telescope is used to collect the thermal emissions generated by the radiation beam. A spectrometer is used to resolve the emissions from the cloud and generate an emissions spectrum. The wavelength of the electromagnetic radiation can be selected to be in resonance with the absorption lines of water or oxygen molecules in the cloud, or to be in resonance with absorption lines of known target molecules in the cloud to generate the heat.

Abstract: A method for determining the mechanical properties of decayed wood that has been exposed to wood decay microorganisms, comprising:

Abstract: A method for measuring trace quantities of OH groups in quartz glass comprises preparing a set of test pieces comprising a reference test piece from a blank of a quartz glass body whose OH group content is known and a sample test piece from a quartz glass body whose OH group content is to be measured, having two planar planes faced to each other, setting the sample test piece and the reference test piece in an infrared spectrophotometer; successively irradiating perpendicular to one of the two planar planes an incident infrared radiation in a wavelength region of approximately 2500 nm to approximately 2950 nm, while simultaneously detecting the outgoing radiation spectrum from the other plane; obtaining the difference of the outgoing radiation spectrum of each of the test pieces; selecting the absorbance peak assigned to OH groups at a wavelength of 2720 nm to obtain the peak height thereof; and calculating the concentration of OH groups from the peak height in the sample test piece.

Abstract: An apparatus for analyzing a spectrum includes an elongated source of light, a device for producing a spectrum of the light, a sample stage, and an array of photosensitive elements for detecting the spectrum and providing an output representative of an intensity of the spectrum as a function of wavelength. The sample stage is interposed between the elongated source and the spectrum-producing device. The light propagates along a length of the sample stage from the elongated source to the spectrum-producing device. The elongated source has a length greater than or equal to a length of the array.

Abstract: An infrared absorption spectrometer features an optical microcavity, and a waveguide that evanescently couples light into the microcavity. The optical resonance frequency of the microcavity is tuned to coincide with an atomic or molecular resonance frequency of a selected atom or molecule. In this way, light coupled into the microcavity will experience absorption in the presence of an atomic or molecular subtance. The absorption causes a measurable change in the evanescent light coupling into the microcavity. The detection sensitivity of the spectrometer is significantly increased, compared to prior art spectrometers, because of the high Q value of the microcavity and the ensuing long optical path lengths of the resonant modes traveling within the microcavity.

Abstract: A system for determining the presence and optionally the position of an ophthalmic product such as a contact lens in a container is provided.