With Sample Vaporizing Means Patents (Class 250/425)
  • Patent number: 8309917
    Abstract: The present invention maintains a stable emission amount from an emitter. In an embodiment of the present invention, a solid sample or a liquid sample is heated to gasify an object to be measured contained in the solid sample or the liquid sample, thereby forming a neutral gaseous molecule, and a metal ion emitted from an emitter having an oxidized surface is attached to the neutral gaseous molecule to ionize the neutral gaseous molecule, which is subjected to mass spectrometry. The solid sample or the liquid sample is a sample that emits a reducing gas by heating. The heating for gasifying the object to be measured is performed at a temperature lower than the vaporization temperature of the solid sample or the liquid sample and not less than the vaporization temperature of the object to be measured, and an oxidizing gas is provided to the emitter.
    Type: Grant
    Filed: December 7, 2009
    Date of Patent: November 13, 2012
    Assignee: Canon Anelva Corporation
    Inventors: Yoshiro Shiokawa, Harumi Maruyama, Yasuyuki Taneda, Megumi Nakamura
  • Patent number: 8299444
    Abstract: This invention relates to a desorption/ionization source operated under ambient conditions for direct analysis of solid or liquid samples on a surface. The source comprises of a laser desorption system and a UV/electrospray combined ionization system. The source is suitable for simultaneously ionizing samples with different polarity in a complex mixture. At the same time, the compact design of the source with multiple channels can maintain the level of local concentration of the analyte ions inside the source for higher efficiency of sample ionization and introduction.
    Type: Grant
    Filed: September 2, 2009
    Date of Patent: October 30, 2012
    Assignee: Shimadzu Research Laboratory (Shanghai) Co. Ltd.
    Inventors: Li Ding, Wenjian Sun
  • Patent number: 8294129
    Abstract: An EUV light source apparatus can reliably detect and accurately judge deterioration of an optical element in a laser beam focusing optics disposed within an EUV light generation chamber. This EUV light source apparatus includes: the EUV light generation chamber; a target material supply unit; an EUV light collector mirror; a driver laser; a window; a parabolic mirror which focuses collimated laser beam by reflection and is disposed within the EUV light generation chamber; an energy detector detecting energy of the laser beam diffused without being applied to a target material after being focused by the laser beam focusing optics when the EUV light is not generated; and a processing unit for judging the deterioration of the window and the parabolic mirror according to the laser beam energy detected by the energy detector.
    Type: Grant
    Filed: April 7, 2011
    Date of Patent: October 23, 2012
    Assignee: Gigaphoton Inc.
    Inventors: Masato Moriya, Tamotsu Abe, Takashi Suganuma, Hiroshi Someya, Takayuki Yabu, Akira Sumitani, Osamu Wakabayashi
  • Patent number: 8294119
    Abstract: The invention concerns an electrospray source having a structure comprising at least one flat and thin tip (3) in cantilever in relation to the rest (1) of the structure, the tip (3) being provided with a capillary slot (5) formed through the complete thickness of the tip and which ends up at the end (6) of the tip (3) to form an ejection orifice of the electrospray source, the source comprising means of supplying (4) the capillary slot (5) with liquid to be nebulised and means of applying an electrospray voltage to the liquid. The invention further concerns a method of manufacturing said electrospray source.
    Type: Grant
    Filed: November 10, 2004
    Date of Patent: October 23, 2012
    Assignees: Universite des Sciences et Technologies de Lille, Centre National de la Recherche Scientifique
    Inventors: Steve Arscott, Severine Le Gac, Christian Druon, Christian Rolando
  • Patent number: 8288716
    Abstract: An aerosol particle analyzer includes a laser ablation chamber, a gas-filled conduit, and a mass spectrometer. The laser ablation chamber can be operated at a low pressure, which can be from 0.1 mTorr to 30 mTorr. The ablated ions are transferred into a gas-filled conduit. The gas-filled conduit reduces the electrical charge and the speed of ablated ions as they collide and mix with buffer gases in the gas-filled conduit. Preferably, the gas filled-conduit includes an electromagnetic multipole structure that collimates the nascent ions into a beam, which is guided into the mass spectrometer. Because the gas-filled conduit allows storage of vast quantities of the ions from the ablated particles, the ions from a single ablated particle can be analyzed multiple times and by a variety of techniques to supply statistically meaningful analysis of composition and isotope ratios.
    Type: Grant
    Filed: April 6, 2009
    Date of Patent: October 16, 2012
    Assignee: UT-Battelle, LLC
    Inventor: Peter T. A. Reilly
  • Patent number: 8288743
    Abstract: An ion withdrawal apparatus that withdraws ions emitted from a plasma in an EUV light production apparatus in which a target at an EUV light production point is irradiated with laser light to be made in a plasma state and the target emits EUV light, the ion withdrawal apparatus which includes: a collector mirror that is disposed in a direction opposite to a laser light incidence direction to collect the EUV light and has a hole for the ions to pass therethrough; magnetic line of force production means that produces a magnetic line of force that is parallel or approximately parallel to the laser light incidence direction at or in the vicinity of the EUV light production point; and ion withdrawal means that is disposed on the opposite side of the collector mirror from the EUV light production point and withdraws the ions.
    Type: Grant
    Filed: March 18, 2009
    Date of Patent: October 16, 2012
    Assignee: Gigaphoton, Inc.
    Inventors: Yoshifumi Ueno, Osamu Wakabayashi, Tamotsu Abe, Akira Sumitani, Hideo Hoshino, Akira Endo, Georg Soumagne
  • Patent number: 8283638
    Abstract: A method for preparing an ion source from nanoparticles is provided. The method includes the steps of: providing nanoparticles, vaporizing the nanoparticles from a solid state to a gaseous state, and ionizing the gas to form the ion source. The ion source is prepared by placing solid nanoparticles in a stainless tube, heating and vaporizing the solid nanoparticles into a gaseous state, and ionizing the gas. The gas can be formed at a lower heating temperature than when solid lumps are used because solid nanoparticles have a lower melting point than solid lumps. Thus, the heating temperature is lowered, and the preparing time of the ion source is shortened. Besides, under the same temperature, an ion source prepared from nanoparticles provides higher vapor pressure and allows a higher implantation dose than when the ion source is prepared from solid lumps, thus expanding the applicability of ion implantation technology.
    Type: Grant
    Filed: September 16, 2009
    Date of Patent: October 9, 2012
    Assignee: National Central University
    Inventors: Gou-Chung Chi, Ping-Jung Huang, Chung-Wei Chen, Ching-Jen Pan, Yu-Lun Liu, Fu-Chun Tsao
  • Patent number: 8278626
    Abstract: In a device for mass spectrometry, an analyte contained in a sample is desorbed from a surface of the device by irradiating the sample in contact with the surface with measurement light. The device includes a micro-structure having a plurality of metal bodies on a surface of a substrate, and the plurality of metal bodies have sizes that can excite localized plasmons by irradiation with the measurement light. Further, the device includes an initiator fixed at least to a part of a surface of the micro-structure.
    Type: Grant
    Filed: September 16, 2009
    Date of Patent: October 2, 2012
    Assignee: FUJIFILM Corporation
    Inventors: Naoki Murakami, Hisashi Ohtsuka, Morihito Ikeda
  • Patent number: 8253114
    Abstract: An ion source includes a plasma generating chamber into which an ionization gas containing fluorine is introduced, a hot cathode provided on one side in the plasma generating chamber, an opposing reflecting electrode which is provided on other side in the plasma generating chamber and reflects electrons when a negative voltage is applied from a bias power supply to the opposing reflecting electrode, and a magnet for generating a magnetic field along a line, which connects the hot cathode and the opposing reflecting electrode, in the plasma generating chamber. The opposing reflecting electrode is formed of an aluminum containing material.
    Type: Grant
    Filed: August 25, 2009
    Date of Patent: August 28, 2012
    Assignee: Nissin Ion Equipment Co., Ltd.
    Inventors: Takatoshi Yamashita, Tadashi Ikejiri, Tetsuya Igo
  • Patent number: 8242459
    Abstract: The current invention involves a desorption corona beam ionization source/device for analyzing samples under atmospheric pressure without sample pretreatment. It includes a gas source, a gas flow tube, a gas flow heater, a metal tube, a DC power supply and a sample support/holder for placing the samples. A visible corona beam is formed at a sharply pointed tip at the exit of the metal tube when a stream of inert gas flows through the metal tube that is applied with a high DC voltage. The gas is heated for desorbing the analyte from solid samples and the desorbed species are ionized by the energized particles embedded in the corona beam. The ions formed are then transferred through an adjacent inlet into a mass spectrometer or other devices capable of analyzing ions. Visibility of the corona beam in the current invention greatly facilitates pinpointing a sampling area on the analyte and also makes profiling of sample surfaces possible.
    Type: Grant
    Filed: December 29, 2009
    Date of Patent: August 14, 2012
    Assignee: Shimadzu Corporation
    Inventors: Wenjian Sun, Xiaohui Yang, Li Ding
  • Patent number: 8242441
    Abstract: An electrospray ion source comprises a source of analyte-bearing liquid; a source of sheath gas; a plurality of liquid conduits, each configured so as to receive a portion of the analyte-bearing liquid; at least one electrode associated with the plurality of liquid conduits for producing electrospray emission of charged droplets from an outlet of each of the liquid conduits; a power supply electrically coupled to the at least one electrode for maintaining the at least one electrodes at an electrical potential; and either one or a plurality of sheath gas conduits, each sheath gas conduit comprising an inlet configured to receive sheath gas and an outlet configured to emit a sheath gas flow that circumferentially surrounds, in at least two dimensions, a portion of the emitted charged droplets.
    Type: Grant
    Filed: December 18, 2009
    Date of Patent: August 14, 2012
    Assignee: Thermo Finnigan LLC
    Inventors: Eloy R. Wouters, Maurizio A. Splendore, Jean-Jacques Dunyach
  • Patent number: 8237115
    Abstract: An electrospray ion source apparatus comprises: a plurality of emitter capillaries, each comprising an internal bore for transporting a portion of a liquid sample from a source, an electrode portion for providing a first applied electric potential and an emitter tip for emitting charged particles generated from the liquid sample portion; a counter electrode for providing a second applied electric potential different from the first applied electric potential; and at least one shield electrode disposed at least partially between the counter electrode and the emitter tip of at least one of the emitter capillaries for providing a third applied electric potential intermediate to the first and second applied electric potentials, wherein the at least one shield electrode is configured such that provision of the third applied electric potential to the at least one shield electrode provides a uniformity of emission of charged particles from the plurality of emitter tips.
    Type: Grant
    Filed: December 18, 2009
    Date of Patent: August 7, 2012
    Assignee: Thermo Finnigan LLC
    Inventors: Viatcheslav V. Kovtoun, Eloy R. Wouters, R. Paul Atherton
  • Patent number: 8232520
    Abstract: The invention provides an ionization source for mass spectrometers named Universal Soft Ionization Source (USIS), wherein the ionization chamber combines various physical effects including InfraRed and UltraViolet normal or laser light, ultrasound, electrostatic potential and differential temperature to analyze polar, non-polar, low, medium or high molecular weight molecules, in order to ionize a variety of compounds.
    Type: Grant
    Filed: May 9, 2007
    Date of Patent: July 31, 2012
    Assignee: I.S.B.—Ion Source & Biotechnologies S.r.l.
    Inventor: Simone Cristoni
  • Patent number: 8227765
    Abstract: This invention provides a method of combining an array-type nanospray ionization source comprising a set of externally wetted proud features and a contact electrode with a pneumatic nebuliser acting to enhance the flux of sprayed ions. Methods of fabricating a substrate combining a set of proud features with analyte delivery and gas flow channels in silicon-based materials are described.
    Type: Grant
    Filed: June 25, 2010
    Date of Patent: July 24, 2012
    Assignee: Microsaic Systems PLC
    Inventor: Richard Syms
  • Patent number: 8207496
    Abstract: An electrospray ion source for a mass spectrometer includes an electrode comprising at least a first plurality of protrusions protruding from a base, each protrusion of the at least a first plurality of protrusions having a respective tip; a conduit for delivering an analyte-bearing liquid to the electrode; and a voltage source, wherein, in operation of the electrospray ion source, the analyte-bearing liquid is caused to move, in the presence of a gas or air, from the base to each protrusion tip along a respective protrusion exterior so as to form a respective stream of charged particles emitted towards an ion inlet aperture of the mass spectrometer under application of voltage applied to the electrode from the voltage source.
    Type: Grant
    Filed: February 5, 2010
    Date of Patent: June 26, 2012
    Assignee: Thermo Finnigan LLC
    Inventors: Alexander A. Makarov, Eloy R. Wouters
  • Patent number: 8193513
    Abstract: A hybrid ion source, comprising a source body configured to create plasma therein, from a first material, wherein the first material comprises one of monatomic gases, small molecule gases, large molecule gases, reactive gases, and solids, a low power plasma generation component operably associated with the source body, a high power plasma generation component operably associated with the source body and an extraction aperture configured to extract ions of the ion plasma from the source body.
    Type: Grant
    Filed: July 31, 2008
    Date of Patent: June 5, 2012
    Assignee: Axcelis Technologies, Inc.
    Inventors: William F. DiVergilio, Daniel R. Tieger, Michael A. Graf
  • Patent number: 8173984
    Abstract: An EUV light source apparatus can reliably detect and accurately judge deterioration of an optical element in a laser beam focusing optics disposed within an EUV light generation chamber. This EUV light source apparatus includes: the EUV light generation chamber; a target material supply unit; an EUV light collector mirror; a driver laser; a window; a parabolic mirror which focuses collimated laser beam by reflection and is disposed within the EUV light generation chamber; an energy detector detecting energy of the laser beam diffused without being applied to a target material after being focused by the laser beam focusing optics when the EUV light is not generated; and a processing unit for judging the deterioration of the window and the parabolic mirror according to the laser beam energy detected by the energy detector.
    Type: Grant
    Filed: March 27, 2009
    Date of Patent: May 8, 2012
    Assignees: Komatsu Ltd., Gigaphoton Inc.
    Inventors: Masato Moriya, Tamotsu Abe, Takashi Suganuma, Hiroshi Someya, Takayuki Yabu, Akira Sumitani, Osamu Wakabayashi
  • Patent number: 8173958
    Abstract: In a conventional mass spectrometer in which a pipe to be electrically heated is provided between a separation wall separating an ionization chamber for ionizing a sample and a separation wall separating an analysis chamber, and an ion in the ionization chamber is introduced through the pipe to the analysis chamber, the pipe is attached or detached by screwing or unscrewing a connector portion of an electrode connected to the pipe and a connector portion of a support disposed at the separation wall. However, with this structure, the screw needs to be loosened until it is completely unscrewed every time it is washed or exchanged, and thus the operability is deteriorated. According to the present invention, a screw hole for screwing the electrode connector portion is in the form of a cut-out portion facing in the direction of rotation centering on an axis of the pipe. Accordingly, the pipe can be attached or detached by only loosening the screw without completely unscrewing it.
    Type: Grant
    Filed: November 22, 2007
    Date of Patent: May 8, 2012
    Assignee: Shimadzu Corporation
    Inventor: Tomohito Nakano
  • Publication number: 20120097846
    Abstract: The invention relates generally to sample ionization, and provides ionization probe assemblies, systems, computer program products, and methods useful for this purpose.
    Type: Application
    Filed: January 3, 2012
    Publication date: April 26, 2012
    Applicant: IBIS BIOSCIENCES, INC.
    Inventors: Steven A. Hofstadler, Jose R. Gutierrez, James C. Hannis, Jared J. Drader, Rex O. Bare, Jeffrey C. Smith, Paul J. Gleason, Jared Nathanson
  • Patent number: 8158959
    Abstract: An extreme ultraviolet light source apparatus generating an extreme ultraviolet light from plasma generated by irradiating a target material with a laser light within a chamber, and controlling a flow of ions generated together with the extreme ultraviolet light using a magnetic field or an electric field, the extreme ultraviolet light source apparatus comprises an ion collector device collecting the ion via an aperture arranged at a side of the chamber, and an interrupting mechanism interrupting movement of a sputtered particle in a direction toward the aperture, the sputtered particle generated at an ion collision surface collided with the ion in the ion collector device.
    Type: Grant
    Filed: February 12, 2010
    Date of Patent: April 17, 2012
    Assignee: Gigaphoton Inc.
    Inventors: Takeshi Asayama, Kouji Kakizaki, Akira Endo, Shinji Nagai
  • Patent number: 8158936
    Abstract: The invention relates generally to sample ionization, and provides ionization probe assemblies, systems, computer program products, and methods useful for this purpose.
    Type: Grant
    Filed: February 12, 2010
    Date of Patent: April 17, 2012
    Assignee: Ibis Biosciences, Inc.
    Inventors: Steven A. Hofstadler, Jose R. Gutierrez, James C. Hannis, Jared J. Drader, Rex O. Bare, Jeffrey C. Smith, Paul J. Gleason, Jared Nathanson
  • Patent number: 8153992
    Abstract: Provided is an ionization emitter which can reduce a dead volume without deteriorating separating capacity. An ionization emitter (2) is provided with a tip (1) composed of a columnar or conical porous self-standing structure, and a channel for supplying a solution sample into the tip (1) from the base end side of the tip (1). The channel is formed by filling a pipe line with a packing, and the tip (1) is exposed from the pipe line of the channel. The packing and the porous self-standing structure constituting the tip (1) have an integrated structure composed of a same porous body formed at the same time.
    Type: Grant
    Filed: January 7, 2008
    Date of Patent: April 10, 2012
    Assignee: Shimadzu Corporation
    Inventors: Shigeyoshi Horiike, Hiroaki Nakanishi
  • Patent number: 8134122
    Abstract: Systems, methods and computer program products for the multi-modal detection of particles are described herein. An embodiment of the present invention is a particle detector that includes a first chamber wherein analyte particles are subjected to a first particle detection mechanism, and a second chamber coupled to the first chamber, wherein the analyte particles are subjected to a second particle detection mechanism, and wherein the detection characteristics of second particle detection mechanism are orthogonal to detection characteristics of the first particle detection mechanism.
    Type: Grant
    Filed: January 19, 2010
    Date of Patent: March 13, 2012
    Assignee: The Mitre Corporation
    Inventor: Samar K. Guharay
  • Patent number: 8110797
    Abstract: A method of enhanced speciation of both positive and negatives species in an analyte is disclosed. The method can include producing a first analyte solution comprising an analyte composition and an effective amount of silver triflate, and analyzing the first analyte solution with an electrospray ionization mass spectrometer. The method can also include producing a second analyte solution comprising a portion of the analyte composition and an effective amount of a compound of formula I, and analyzing the second analyte solution with an electrospray ionization mass spectrometer. The compound of formula I is [NX+][OH?], where X is a linear, branched, or cyclic C1-C10 alkane; an aryl; a heterocyclic aromatic; or a heterocyclic moiety.
    Type: Grant
    Filed: February 5, 2010
    Date of Patent: February 7, 2012
    Assignee: Florida State University Research Foundation, Inc.
    Inventors: Alan G. Marshall, Priyanka Juyal, Ryan P. Rodgers
  • Patent number: 8110815
    Abstract: Providing vapor to a vapor-receiving device housed in a high vacuum chamber. An ion beam implanter, as an example, has a removable high voltage ion source within a high vacuum chamber and a vapor delivery system that delivers vapor to the ion source and does not interfere with removal of the ion source for maintenance. For delivering vapor to a vapor-receiving device, such as the high voltage ion source under vacuum, a flow interface device is in the form of a thermally conductive valve block. A delivery extension of the interface device automatically connects and disconnects within the high vacuum chamber with the removable vapor receiving device by respective installation and removal motions. In an ion implanter, the flow interface device or valve block and source of reactive cleaning gas are mounted in a non-interfering way on the electrically insulating bushing that insulates the ion source from the vacuum housing and the ion source may be removed without disturbing the flow interface device.
    Type: Grant
    Filed: June 11, 2007
    Date of Patent: February 7, 2012
    Assignee: Semequip, Inc.
    Inventors: Frank Sinclair, Douglas R. Adams, Brent M. Copertino
  • Patent number: 8110794
    Abstract: Methods and systems are provided for the soft desorption of analyte from a sample, in which an optical beam absorbed within an irradiate zone of the sample causes vibrational excitations of a component within the sample. The optical beam, providing sufficient energy to superheat the component, is provided for a time interval that is less than the time duration required for the loss of energy out of the irradiated zone due to thermal diffusion and acoustic expansion. The superheated component thus drives ablation within the irradiated zone, resulting in the soft desorption of analyte without ionization and fragmentation. The ejected ablation plume may be directed towards the inlet of a mass analysis device for detection of the desorbed analyte, which is preferably ionized by a linear resonant photo-ionization step.
    Type: Grant
    Filed: February 2, 2010
    Date of Patent: February 7, 2012
    Inventor: R. J. Dwayne Miller
  • Publication number: 20120018632
    Abstract: An Atmospheric Pressure Chemical Ionization (APCI) source interfaced to a mass spectrometer is configured with a corona discharge needle positioned inside the APCI inlet probe assembly. Liquid sample flowing into the APCI inlet probe is nebulized and vaporized prior to passing through the corona discharge region all contained in the APCI inlet probe assembly Ions produced in the corona discharge region are focused toward the APCI probe centerline to maximize ion transmission through the APCI probe exit. External electric fields penetrating into the APCI probe exit end opening providing additional centerline focusing of sample ions exiting the APCI probe. The APCI probe is configured to shield the electric field from the corona discharge region while allowing penetration of an external electric field to focus APCI generated ions into an orifice into vacuum for mass to charge analysis.
    Type: Application
    Filed: July 15, 2011
    Publication date: January 26, 2012
    Applicant: PerkinElmer Health Sciences, Inc.
    Inventors: Craig Whitehouse, Victor Laiko
  • Patent number: 8101923
    Abstract: A method and system for desorbing and ionizing molecules from a sample for mass spectrometry using a microplasma device is disclosed. The system and method relies upon a microplasma device, or array of such devices, to partially ionize a gas to form a microplasma. The ionized gas can be a mixture of a noble gas, such as neon or argon, and hydrogen (H2). The ionized gas can form a effluent stream directed onto the surface of a sample to desorb molecules from the remainder of the sample. The desorbed molecules can be ionized by the effluent stream as they leave the surface of the sample. The ionization process can include: photoionization, penning ionization, chemical ionization (proton transfer), and electron impact ionization. The ionized particles from the sample can be directed to a mass spectrometer for analysis. This can produce spatially-resolved mass spectral data, and can be conducted concurrently with another imaging system, such as a microscope.
    Type: Grant
    Filed: November 12, 2008
    Date of Patent: January 24, 2012
    Assignee: Georgia Tech Research Corporation
    Inventors: Thomas Michael Orlando, Joshua Milbourne Symonds
  • Patent number: 8097860
    Abstract: A gas cluster ion beam (GCIB) processing system using multiple nozzles for forming and emitting at least one GCIB and methods of operating thereof are described. The GCIB processing system may be configured to treat a substrate, including, but not limited to, doping, growing, depositing, etching, smoothing, amorphizing, or modifying a layer thereupon. Furthermore, the GCIB processing system may be operated to produce a first GCIB and a second GCIB, and to irradiate a substrate simultaneously and/or sequentially with the first GCIB and second GCIB.
    Type: Grant
    Filed: March 26, 2010
    Date of Patent: January 17, 2012
    Assignee: TEL Epion Inc.
    Inventors: Martin D. Tabat, Matthew C. Gwinn, Robert K. Becker, Avrum Freytsis, Michael Graf
  • Patent number: 8080783
    Abstract: A multiple function atmospheric pressure ion source interfaced to a mass spectrometer comprises multiple liquid inlet probes configured such that the sprays from two or more probes intersect in a mixing region. Gas phase sample ions or neutral species generated in the spray of one probe can react with reagent gas ions generated from one or more other probes by such ionization methods as Electrospray, photoionization, corona discharge and glow discharge ionization. Reagent ions may be optimally selected to promote such processes as Atmospheric Pressure Chemical Ionization of neutral sample molecules, or charge reduction or electron transfer dissociation of multiply charged sample ions. Selected neutral reagent species can also be introduced into the mixing region to promote charge reduction of multiply charged sample ions through ion-neutral reactions. Different operating modes can be performed alternately or simultaneously, and can be rapidly turned on and off under manual or software control.
    Type: Grant
    Filed: February 10, 2009
    Date of Patent: December 20, 2011
    Assignees: PerkinElmer Health Sciences, Inc., CHEMSPACE Associates, Inc.
    Inventors: Craig Whitehouse, Thomas White, Ross Willoughby, Ed Sheehan
  • Patent number: 8071958
    Abstract: A method of manufacturing a semiconductor device includes the steps of: providing a supply of molecules containing a plurality of dopant atoms into an ionization chamber, ionizing said molecules into dopant cluster ions, extracting and accelerating the dopant cluster ions with an electric field, selecting the desired cluster ions by mass analysis, modifying the final implant energy of the cluster ion through post-analysis ion optics, and implanting the dopant cluster ions into a semiconductor substrate. In general, dopant molecules contain n dopant atoms, where n is an integer number greater than 10. This method enables increasing the dopant dose rate to n times the implantation current with an equivalent per dopant atom energy of 1/n times the cluster implantation energy, while reducing the charge per dopant atom by the factor n.
    Type: Grant
    Filed: November 11, 2008
    Date of Patent: December 6, 2011
    Assignee: SemEquip, Inc.
    Inventors: Thomas N. Horsky, Dale C. Jacobson
  • Patent number: 8030621
    Abstract: An apparatus for producing ions can include an emitter having a first end and a second end. The emitter can be coated with an ionic liquid room-temperature molten salt. The apparatus can also include a power supply and a first electrode disposed downstream relative to the first end of the emitter and electrically connected to a first lead of the power supply. The apparatus can also include a second electrode disposed downstream relative to the second end of the emitter and electrically connected to a second lead of the power supply.
    Type: Grant
    Filed: October 15, 2008
    Date of Patent: October 4, 2011
    Assignee: Massachusetts Institute of Technology
    Inventors: Paulo Lozano, Manuel Martinez-Sanchez
  • Publication number: 20110220787
    Abstract: A cycling electrospray ionization device includes a driving mechanism and a nozzle. The nozzle is configured to sequentially form liquid droplets of an electrospray medium thereat, and is adapted to establish a traveling path with a receiving unit of a mass spectrometer such that when a potential difference is applied between the nozzle and the receiving unit to lade the liquid droplets with a plurality of electric charges for ionizing analytes to form ionized analytes, the charged droplets are forced to move toward the receiving unit along the traveling path. The nozzle defines a nozzle axis, and is driven by the driving mechanism to proceed with a cycling route about a cycling axis such that the nozzle axis tracks along the cycling route, and such that immediately after leaving the nozzle, the liquid droplets cooperate to form a substantially columnar plume with a cross section substantially surrounded by the cycling route.
    Type: Application
    Filed: October 28, 2010
    Publication date: September 15, 2011
    Inventor: Jentaie SHIEA
  • Patent number: 8017920
    Abstract: A spin polarized ion beam generation apparatus (30) can efficiently generate a spin polarized ion by using a pumping light generator (33) to an ion in a high frequency discharge tube (15) to irradiate optical pumping (33,34) by circularly polarized light and linearly polarized light orthogonal to each other to a metastable atom. For example, a polarized helium ion beam having a spin polarization rate that exceeds 18% and that is as high as 25% can be generated. The spin polarized ion beam generation apparatus (30) also can be applied to a processing apparatus and an analysis apparatus that can irradiate a polarized ion beam to a specimen. According to the spin polarized ion scattering spectroscopy apparatus, the spin status in a region at a depth of about 2 to 3 atomic layers from the surface of the specimen can be measured while discriminating the elements from the atomic layer with a reduced measurement time and with a high accuracy impossible in the conventional technique.
    Type: Grant
    Filed: November 29, 2007
    Date of Patent: September 13, 2011
    Assignee: Japan Science and Technology Agency
    Inventors: Taku Suzuki, Yasushi Yamauchi
  • Patent number: 8013312
    Abstract: Vapor delivery systems and methods that control the heating and flow of vapors from solid feed material, especially material that comprises cluster molecules for semiconductor manufacture. The systems and methods safely and effectively conduct the vapor to a point of utilization, especially to an ion source for ion implantation. Ion beam implantation is shown employing ions from the cluster materials. The vapor delivery system includes reactive gas cleaning of the ion source, control systems and protocols, wide dynamic range flow-control systems and vaporizer selections that are efficient and safe. Borane, decarborane, carboranes, carbon clusters and other large molecules are vaporized for ion implantation. Such systems are shown cooperating with novel vaporizers, ion sources, and reactive cleaning systems.
    Type: Grant
    Filed: November 21, 2007
    Date of Patent: September 6, 2011
    Assignee: SemEquip, Inc.
    Inventor: Douglas Adams
  • Patent number: 8003954
    Abstract: An ion source has an arc chamber with an electron-emitting element and a repeller. A manifold assembly defines a cavity and a gas outlet configured to allow gas flow to the arc chamber. This gas outlet is closer to the repeller than the electron-emitting element. In one embodiment, the ion source has a first crucible and a second crucible. The first crucible and the second crucible are connected to the manifold assembly. In one instance, the crucibles have tamper-resistant features.
    Type: Grant
    Filed: December 19, 2008
    Date of Patent: August 23, 2011
    Assignee: Varian Semiconductor Equipment Associates, Inc.
    Inventors: John Slocum, Kevin M. Keen, Chris Campbell, Robert Lindberg, Stefan Casey
  • Patent number: 8003962
    Abstract: A nozzle protection device capable of protecting a target nozzle from heat of plasma without disturbing formation of a stable flow of a target material in an LPP type EUV light source apparatus. This nozzle protection device includes a cooling unit which is formed with an opening for passing the target material therethrough, and which is formed with a flow path for circulating a cooling medium inside, and an actuator which changes a position or a shape of the cooling unit between a first state of evacuating the cooling unit from a trajectory of the target material and a second state of blocking heat radiation from the plasma to the nozzle by the cooling unit while securing a path of the target material in the cooling unit.
    Type: Grant
    Filed: April 24, 2009
    Date of Patent: August 23, 2011
    Assignee: Gigaphoton Inc.
    Inventors: Hiroshi Someya, Tamotsu Abe, Hideo Hoshino
  • Patent number: 7989762
    Abstract: In an ion source that generates ions by matrix-assisted laser desorption (MALDI), ion acceleration diaphragms having apertures though which ions are accelerated and which have become contaminated by matrix material, are cleaned by temporarily heating the diaphragms. During the cleaning process, the sample support plate is moved aside but remains in the ion source housing, and the heating is preferably limited to regions surrounding the apertures in the diaphragms. In one embodiment, the diaphragms are heated by irradiation generated by infrared laser diodes.
    Type: Grant
    Filed: February 9, 2009
    Date of Patent: August 2, 2011
    Assignee: Bruker Daltonik GmbH
    Inventors: Armin Holle, Jens Hörndorf
  • Patent number: 7973292
    Abstract: A neutralizer 1 includes: a power supply circuit 11; an output controlling circuit 12 configured to convert a DC voltage generated by the power supply circuit 11 to a high-frequency voltage with frequency equal to or higher than an audible frequency, and thus to output the resultant high-frequency voltage alternately to two output lines at regular intervals; a transforming circuit 13 configured to raise the high-frequency voltage; a discharger 20 including 2n (n is an integer equal to one or more) discharge needles configured to output positive ions in response to application of a positive polarity voltage, and to output negative ions in response to application of a negative polarity voltage, the discharge needles being disposed while being divided into first and second groups each including n discharge needles; a polarity reversing circuit 14 configured to convert the high-frequency high voltage outputted from the transforming circuit 13, to two rectangular-wave DC high voltages with different polarities dur
    Type: Grant
    Filed: December 18, 2007
    Date of Patent: July 5, 2011
    Assignee: Midori Anzen Co., Ltd.
    Inventors: Tomonori Tsumori, Naoki Sugita
  • Patent number: 7939810
    Abstract: An electrically conductive heat-blocking plate 11 with an opening 12 for allowing thermions to pass through is provided between a filament 3, whose temperature can be as high as 2000° to 3000° C., and an ionization chamber 2. The heat-blocking plate 11 is thermally connected via an aluminum block 10 to a heater for maintaining the ionization chamber 2 within a range temperature from 200° to 300° C., and also electrically set at a ground potential, which is approximately equal to the potential of the ionization chamber 2. The heat-blocking plate 11 blocks the radiation heat that the filament 3 emits when energized. Thus, the wall of the ionization chamber 2 is prevented from being locally heated to an abnormally high temperature. As a result, the inner space of the ionization chamber 2 is maintained at an approximately uniform temperature, and the noise due to the decomposition of a metallic material by abnormal heating is prevented.
    Type: Grant
    Filed: March 9, 2006
    Date of Patent: May 10, 2011
    Assignee: Shimadzu Corporation
    Inventors: Shuichi Kawana, Manabu Shimomura
  • Patent number: 7928418
    Abstract: In an extreme ultra violet light source apparatus of a laser produced plasma type, charged particles such as ions emitted from plasma are promptly ejected to the outside of a chamber. The extreme ultra violet light source apparatus includes a chamber in which extreme ultra violet light is generated, a target supply unit for supplying a target material to a predetermined position within the chamber, a driver laser for applying a laser beam to the target material supplied by the target supply unit to generate plasma, a collector mirror for collecting the extreme ultra violet light radiated from the plasma to output the extreme ultra violet light, a magnetic field forming unit for forming an asymmetric magnetic field in a generation position of the plasma by using a coil, and a charged particle collection mechanism provided on at least one of two surfaces of the chamber to which lines of magnetic force generated by the coil extend.
    Type: Grant
    Filed: April 13, 2009
    Date of Patent: April 19, 2011
    Assignees: Gigahoton Inc., Osaka University
    Inventors: Georg Soumagne, Yoshifumi Ueno, Hiroshi Komori, Akira Sumitani, Katsunobu Nishihara, Young Gwang Kang, Masanori Nunami
  • Patent number: 7923705
    Abstract: An EUV light source apparatus capable of easily detecting deterioration etc. of a window of an EUV light generating chamber. The EUV light source apparatus includes a driver laser, an EUV light generating chamber, a window which passes the laser beam into the EUV light generating chamber, an EUV light collector mirror, laser beam focusing optics which focuses a laser beam onto a trajectory of a target material, a temperature sensor which detects a temperature of the window, and a laser beam optics deterioration determination processing unit which determines deterioration of the window based on the temperature of the window detected by the temperature sensor when extreme ultra violet light is generated.
    Type: Grant
    Filed: April 21, 2009
    Date of Patent: April 12, 2011
    Assignee: Gigaphoton Inc.
    Inventors: Masato Moriya, Tamotsu Abe, Takashi Suganuma, Hiroshi Someya, Takayuki Yabu, Akira Sumitani, Osamu Wakabayashi
  • Patent number: 7923679
    Abstract: In relation with a laser-induced transport process of an object from a carrier to a collecting device, the invention provides a collecting medium in the collecting device in a liquid state. Prior to the laser-induced transport process, the object is separated from a mass on the carrier by laser irradiation. After the laser-induced transport process, the object, thus selected and separated, is transferred together with the collecting medium to a destination, for example, a container, for further treatment. To this end, a manipulation system for liquids is provided, the system permitting manipulation of the collecting medium with the object contained therein with a high degree of reliability and a high throughput.
    Type: Grant
    Filed: June 1, 2006
    Date of Patent: April 12, 2011
    Assignee: Carl Zeiss MicroImaging GmbH
    Inventors: Bernd Sägmüller, Yilmaz Niyaz, Thomas Staltmeier
  • Patent number: 7905199
    Abstract: A method for growing material on a substrate is described. The method comprises directionally growing a thin film on one or more surfaces of a substrate using a gas cluster ion beam (GCIB) formed from a source of precursor for the thin film, wherein the growth occurs on surfaces oriented substantially perpendicular to the direction of incidence of the GCIB, and growth is substantially avoided on surfaces oriented substantially parallel to the direction of incidence.
    Type: Grant
    Filed: June 24, 2008
    Date of Patent: March 15, 2011
    Assignee: TEL Epion Inc.
    Inventors: John J. Hautala, Martin D. Tabat
  • Patent number: 7893408
    Abstract: A method for ionizing and desorbing a sample for analysis includes energizing a first and second electrode to produce a glow discharge at atmospheric pressure. The method further includes supplying a carrier gas to at least a portion of the glow discharge to create effluents thereof. The method further includes conducting the effluents of the glow discharge to the sample to ionize and desorb the sample for analysis. An associated apparatus is also disclosed.
    Type: Grant
    Filed: October 31, 2007
    Date of Patent: February 22, 2011
    Assignee: Indiana University Research and Technology Corporation
    Inventors: Gary M. Hieftje, Steven J. Ray, Francisco J. Andrade, William C. Wetzel, Michael R. Webb, Gerardo Gamez, Jacob T. Shelley
  • Publication number: 20110012024
    Abstract: A method for preparing an ion source from nanoparticles is provided. The method includes the steps of: providing nanoparticles, vaporizing the nanoparticles from a solid state to a gaseous state, and ionizing the gas to form the ion source. The ion source is prepared by placing solid nanoparticles in a stainless tube, heating and vaporizing the solid nanoparticles into a gaseous state, and ionizing the gas. The gas can be formed at a lower heating temperature than when solid lumps are used because solid nanoparticles have a lower melting point than solid lumps. Thus, the heating temperature is lowered, and the preparing time of the ion source is shortened. Besides, under the same temperature, an ion source prepared from nanoparticles provides higher vapor pressure and allows a higher implantation dose than when the ion source is prepared from solid lumps, thus expanding the applicability of ion implantation technology.
    Type: Application
    Filed: September 16, 2009
    Publication date: January 20, 2011
    Applicant: National Central University
    Inventors: Gou-Chung Chi, Ping-Jung Huang, Chung-Wei Chen, Ching-Jen Pan, Yu-Lun Liu, Fu-Chun Tsao
  • Patent number: 7863581
    Abstract: An apparatus for producing negative ions including an emitter coated with an ionic liquid room-temperature molten salt, an electrode positioned downstream relative to the emitter, a power supply that applies a voltage to the emitter with respect to the electrode. The power supply is sufficient to generate a stable high brightness beam of negative ions having minimal chromatic and spherical aberrations in the beam. An electrostatic lens and deflector is used to focus and direct the beam to a target.
    Type: Grant
    Filed: June 9, 2008
    Date of Patent: January 4, 2011
    Assignee: Massachusetts Institute of Technology
    Inventors: Paulo Lozano, Manuel Martinez-Sanchez
  • Patent number: 7855358
    Abstract: A method of obtaining ions of an analyte is disclosed. The method includes aerosolizing a sample using a thermal liquid jetting device or a piezoelectric liquid jetting device to obtain an aerosol without ionizing the sample. The sample includes the analyte in a solvent. The method further includes drying the aerosol to obtain gas phase solvent and gas phase analyte, and ionizing the gas phase analyte to obtain ions thereof. An ion source using the method for obtaining ions of an analyte is also disclosed.
    Type: Grant
    Filed: December 23, 2007
    Date of Patent: December 21, 2010
    Assignee: Agilent Technologies, Inc.
    Inventors: Arthur Schleifer, Steven Michael Fischer
  • Patent number: 7829870
    Abstract: An apparatus for in-situ specimen preparation is described. The apparatus includes an ion beam column 21 including at least: an liquid metal alloy ion source 56 including a first element for providing a light ion species with a mass of 10 g/mol to 60 g/mol and a second element for providing a heavy ions species with a mass of 150 g/mol or higher, a mass separator 58 for selectively separating the light ion species and the heavy ion species, and a focusing element for focusing the ion beam on a specimen. The apparatus further includes a specimen-beam-tilt unit for tilting the ion beam with respect to the specimen.
    Type: Grant
    Filed: October 26, 2007
    Date of Patent: November 9, 2010
    Assignee: ICT Integrated Circuit Testing Gesellschaft für Halbleiterprüftechnik mbH
    Inventor: Juergen Frosien
  • Patent number: 7829848
    Abstract: A gas monitoring apparatus includes a sample introducing portion, a measurement portion, an ionization portion, a mass analysis portion, a data processing portion and a display. The sample introducing portion introduces a sample gas including an object material to be measured. The measurement portion measures a concentration of a predetermined coexisting material, which coexists with the object material in the sample gas. The ionization portion ionizes the sample gas. The mass analysis portion analyzes mass of an ion produced by the ionization portion. The data processing portion analyzes signals detected by the mass analysis portion to calculate a concentration of the object material. And the display displays results of analysis conducted by the data processing portion. The data processing portion includes an adjustment portion which adjusts the concentration of the object material according to the concentration of the predetermined coexisting material.
    Type: Grant
    Filed: October 2, 2008
    Date of Patent: November 9, 2010
    Assignees: Hitachi, Ltd., National Research Institute of Police Science
    Inventors: Yasuaki Takada, Masao Suga, Hisashi Nagano, Izumi Waki, Hidehiro Okada, Tatsuo Nojiri, Yasuo Seto, Yasuhiro Sano, Shigeharu Yamashiro, Isaac Ohsawa