Composite Or Layered Gate Insulator (e.g., Mixture Such As Silicon Oxynitride) Patents (Class 257/411)
  • Patent number: 9263595
    Abstract: Non-volatile memories and methods of fabrication thereof are described. In one embodiment, a method of fabricating a semiconductor device includes forming an oxide layer over a semiconductor substrate, and exposing the oxide layer to a first nitridation step to form a first nitrogen rich region. The first nitrogen rich region is disposed adjacent an interface between the oxide layer and the semiconductor substrate. After the first nitridation step, the oxide layer is exposed to a second nitridation step to form a second nitrogen rich region. A first gate electrode is formed on the oxide layer, wherein the second nitrogen rich region is disposed adjacent an interface between the oxide layer and the first gate electrode.
    Type: Grant
    Filed: July 23, 2013
    Date of Patent: February 16, 2016
    Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.
    Inventors: Chih-Wei Lin, Yi-Fang Lee, Cheng-Ta Wu, Cheng-Yuan Tsai
  • Patent number: 9196711
    Abstract: Fin mask structures are formed over a semiconductor material portion on a crystalline insulator layer. A disposable gate structure and a gate spacer are formed over the fin mask structures. Employing the disposable gate structure and the gate spacer as an etch mask, physically exposed portions of the fin mask structures and the semiconductor material portion are removed by an etch. A source region and a drain region are formed by selective epitaxy of a semiconductor material from physically exposed surfaces of the crystalline insulator layer. The disposable gate structure is removed selective to the source region and the drain region. Semiconductor fins are formed by anisotropically etching portions of the semiconductor material portion, employing the gate spacer and the fin mask structures as etch masks. A gate dielectric and a gate electrode are formed within the gate cavity.
    Type: Grant
    Filed: March 7, 2014
    Date of Patent: November 24, 2015
    Assignee: International Business Machines Corporation
    Inventors: Anirban Basu, Guy M. Cohen, Amlan Majumdar
  • Patent number: 9190520
    Abstract: A fin structure includes an optional doped well, a disposable single crystalline semiconductor material portion, and a top semiconductor portion formed on a substrate. A disposable gate structure straddling the fin structure is formed, and end portions of the fin structure are removed to form end cavities. Doped semiconductor material portions are formed on sides of a stack of the disposable single crystalline semiconductor material portion and a channel region including the top semiconductor portion. The disposable single crystalline semiconductor material portion may be replaced with a dielectric material portion after removal of the disposable gate structure or after formation of the stack. The gate cavity is filled with a gate dielectric and a gate electrode. The channel region is stressed by the doped semiconductor material portions, and is electrically isolated from the substrate by the dielectric material portion.
    Type: Grant
    Filed: September 9, 2014
    Date of Patent: November 17, 2015
    Assignee: GLOBALFOUNDRIES INC.
    Inventors: Henry K. Utomo, Kangguo Cheng, Ramachandra Divakaruni, Dechao Guo, Myung-Hee Na, Ravikumar Ramachandran, Kern Rim, Huiling Shang
  • Patent number: 9177869
    Abstract: The present disclosure relates to a semiconductor device and a method of manufacturing the same. The semiconductor device may include a first metal gate electrode provided in a NMOS region of a substrate; and a second metal gate electrode provided in a PMOS region of the substrate, wherein the first and second metal gate electrodes may be formed of TiN material or TiAlN material. Here, the first metal gate electrode may have a higher titanium (Ti) content than the second metal gate electrode, and the second metal gate electrode may have a higher nitrogen (N) content than the first metal gate electrode.
    Type: Grant
    Filed: March 18, 2015
    Date of Patent: November 3, 2015
    Assignees: SK HYNIX INC., INDUSTRY-UNIVERSITY COOPERATION FOUNDATION HANYANG UNIVERSITY
    Inventor: Chang-Hwan Choi
  • Patent number: 9178031
    Abstract: Provided is a two-step ALD deposition process for forming a gate dielectric involving an erbium oxide layer deposition followed by a hafnium oxide layer deposition. Hafnium oxide can provide a high dielectric constant, high density, large bandgap and good thermal stability. Erbium oxide can act as a barrier against oxygen diffusion, which can lead to increasing an effective oxide thickness of the gate dielectric and preventing hafnium-silicon reactions that may lead to higher leakage current.
    Type: Grant
    Filed: June 10, 2014
    Date of Patent: November 3, 2015
    Assignee: Intermolecular, Inc.
    Inventor: Jinhong Tong
  • Patent number: 9178035
    Abstract: One method of forming replacement gate structures for first and second devices, the first device being a short channel device and the second device being a long channel device, is disclosed which includes forming a first and a second gate cavity above a semiconductor substrate, the first gate cavity being narrower than the second gate cavity, forming a bulk metal layer within the first and second gate cavities, performing an etching process to recess the bulk metal layer within the first and second gate cavities, resulting in the bulk metal layer within the second gate cavity being at its final thickness, forming a masking layer over the bulk metal layer within the second gate cavity, and performing an etching process to further recess the bulk metal layer within the first gate cavity, resulting in the bulk metal layer within the first gate cavity being at its final thickness.
    Type: Grant
    Filed: August 14, 2014
    Date of Patent: November 3, 2015
    Assignee: GLOBALFOUNDRIES Inc.
    Inventors: Min Gyu Sung, Chanro Park, Hoon Kim
  • Patent number: 9153567
    Abstract: A semiconductor device comprises: a memory cell region having a first transistor and a peripheral circuit region having a second transistor. The first transistor has a first source electrode and a first drain electrode, a first buried gate insulating film which is formed along an inner wall of a trench and whose relative dielectric constant is higher than a relative dielectric constant of silicon oxide, and a buried gate electrode. The second transistor has a second source electrode and a second drain electrode, a first on-substrate gate insulating film whose relative dielectric constant is higher than a relative dielectric constant of silicon oxide, and an on-substrate gate electrode. A first Hf content percentage, which is a content percentage of hafnium in the first buried gate insulating film, is different from a second Hf content percentage, which is a content percentage of hafnium in the first on-substrate gate insulating film.
    Type: Grant
    Filed: May 22, 2013
    Date of Patent: October 6, 2015
    Assignee: PS4 Luxco S.a.r.l.
    Inventor: Kanta Saino
  • Patent number: 9087836
    Abstract: A method is disclosed for fabricating a semiconductor structure. The method includes providing a semiconductor substrate having an oxide layer on a surface of the semiconductor substrate, and removing the oxide layer to expose the surface of the semiconductor substrate. The method also includes performing a thermal annealing process on the semiconductor substrate using an inert gas as a thermal annealing protective gas after removing the oxide layer, and forming an insulating layer on the semiconductor substrate after performing the thermal annealing process. Further, the method includes forming a high-K gate dielectric layer on a surface of the insulating layer, and forming a protective layer on a surface of the high-K gate dielectric layer.
    Type: Grant
    Filed: October 15, 2014
    Date of Patent: July 21, 2015
    Assignee: SEMICONDUCTOR MANUFACTURING INTERNATIONAL CORP.
    Inventor: Hualong Song
  • Patent number: 9076669
    Abstract: A semiconductor device having high-k gate insulation films and a method of fabricating the semiconductor device are provided. The semiconductor device includes a first gate insulation film on a substrate and the first gate insulation film includes a material selected from the group consisting of HfO2, ZrO2, Ta2O5, TiO2, SrTiO3 and (Ba,Sr)TiO3, and lanthanum (La). Additionally, the semiconductor device includes a first barrier film on the first gate insulation film, a first gate electrode on the first barrier film, and n-type source/drain regions in the substrate at both sides of the first gate electrode.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: July 7, 2015
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Ju Youn Kim, Young-Hun Kim
  • Publication number: 20150145073
    Abstract: Systems and methods are provided for fabricating a semiconductor structure including sidewall spacers. An example semiconductor structure includes: a gate structure, a first sidewall spacer, and a second sidewall spacer. The gate structure is formed over a substrate. The first sidewall spacer is adjacent to the gate structure, a top part of the first sidewall spacer including a first dielectric material, a bottom part of the first sidewall spacer including a second dielectric material. The second sidewall spacer is adjacent to the first sidewall spacer, the second sidewall spacer including a third dielectric material.
    Type: Application
    Filed: November 26, 2013
    Publication date: May 28, 2015
    Applicant: Taiwan Semiconductor Manufacturing Company Limited
    Inventors: WEI-YANG LEE, CHIA-CHUN LAN
  • Publication number: 20150137271
    Abstract: One method disclosed herein includes, among other things, performing a process operation on an exposed surface of a substrate so as to form an H-terminated silicon surface, selectively forming a sacrificial material layer within a replacement gate cavity but not on the H-terminated silicon surface, forming a high-k layer of insulating material within the replacement gate cavity above the H-terminated silicon surface and laterally between first spaced-apart portions of the sacrificial material layer, and forming a work-function adjusting material layer in the gate cavity, wherein the work-function adjusting material layer has a substantially planar upper surface that extends between second spaced-apart portions of the sacrificial material layer formed on the sidewall spacers.
    Type: Application
    Filed: November 15, 2013
    Publication date: May 21, 2015
    Applicant: GLOBAL FOUNDRIES Inc.
    Inventors: Xiuyu Cai, Xunyuan Zhang
  • Publication number: 20150137272
    Abstract: Techniques related to nanocomposite dielectric materials are generally described herein. These techniques may be embodied in apparatuses, systems, methods and/or processes for making and using such material. An example process may include: providing a film having a plurality of nanoparticles and an organic medium; comminuting the film to form a particulate; and applying the particulate to a substrate. The example process may also include providing a nanoparticle film having nanoparticles and voids located between the nanoparticles; contacting the film with a vapor containing an organic material; and curing the organic material to form the nanocomposite dielectric film. Various described techniques may provide nanocomposite dielectric materials with superior nanoparticle dispersion which may result in improved dielectric properties.
    Type: Application
    Filed: November 11, 2014
    Publication date: May 21, 2015
    Inventor: Seth Miller
  • Patent number: 9035398
    Abstract: A semiconductor device includes an interlayer insulating film on a substrate, the interlayer insulating film including a trench, a gate insulating film in the trench, a diffusion film on the gate insulating film, the diffusion film including a first diffusion material, a gate metal structure on the diffusion film, the gate metal structure including a second diffusion material, and a diffusion prevention film between the gate metal structure and the diffusion film, the diffusion prevention film being configured to prevent diffusion of the second diffusion material from the gate metal structure, the first diffusion material diffused from the diffusion film exists in the gate insulating film.
    Type: Grant
    Filed: August 27, 2013
    Date of Patent: May 19, 2015
    Assignee: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Seok-Jun Won, Suk-Hoon Kim, Hyung-Suk Jung
  • Publication number: 20150129989
    Abstract: The present disclosure provides A gate insulating layer comprising: a first silicon nitride film having a first thickness and a first content of N—H bonds; a second silicon nitride film having a second thickness and a second content of N—H bonds, disposed on the first silicon nitride film; and a third silicon nitride film having a third thickness and a third content of N—H bonds, disposed on the second silicon nitride film; wherein both the first thickness and the third thickness are less than the second thickness, both the N—H bonds in the first content and the third content are less than that in the second N—H bonds content, and a difference of the N—H bonds between the third content and the first content is no less than 5%. The present disclosure also provides a method for forming the above gate insulating layer.
    Type: Application
    Filed: August 19, 2014
    Publication date: May 14, 2015
    Inventors: Wei-ting CHEN, Chia-chi HUANG, Chunchieh HUANG, Youyuan HU
  • Publication number: 20150129948
    Abstract: It is made possible to provide an insulating film that can reduce the leakage current. An insulating film includes: an amorphous oxide dielectric film containing a metal, hydrogen, and nitrogen. The nitrogen amount [N] and the hydrogen amount [H] in the oxide dielectric film satisfy the following relationship: {[N]?[H]}/2?1.0×1021 cm?3.
    Type: Application
    Filed: November 12, 2014
    Publication date: May 14, 2015
    Applicant: Kabushiki Kaisha Toshiba
    Inventors: Tatsuo SHIMIZU, Masato KOYAMA
  • Patent number: 9029959
    Abstract: A composite high dielectric constant (high-k) gate dielectric includes a stack of a doped high-k gate dielectric and an undoped high-k gate dielectric. The doped high-k gate dielectric can be formed by providing a stack of a first high-k dielectric material layer and a dopant metal layer and annealing the stack to induce the diffusion of the dopant metal into the first high-k dielectric material layer. The undoped high-k gate dielectric is formed by subsequently depositing a second high-k dielectric material layer. The composite high-k gate dielectric can provide an increased gate-leakage oxide thickness without increasing inversion oxide thickness.
    Type: Grant
    Filed: June 29, 2012
    Date of Patent: May 12, 2015
    Assignee: International Business Machines Corporation
    Inventors: MaryJane Brodsky, Michael P. Chudzik, Min Dai, Joseph F. Shepard, Jr., Shahab Siddiqui, Yanfeng Wang, Jinping Liu
  • Publication number: 20150115375
    Abstract: A semiconductor device includes a gate insulation layer pattern, a lower gate electrode, an upper gate electrode, and a first inner spacer. The gate insulation layer pattern is formed on a substrate. The lower gate electrode is formed on the gate insulation layer pattern. The upper gate electrode is formed on the lower gate electrode and has a width that gradually increases from a bottom portion toward a top portion thereof. The width of the bottom portion of the upper gate electrode is smaller than a width of a top surface of the lower gate electrode. The first inner spacer surrounds a sidewall of the upper gate electrode.
    Type: Application
    Filed: October 1, 2014
    Publication date: April 30, 2015
    Inventor: Jae-Hyun Yoo
  • Patent number: 9018709
    Abstract: A semiconductor device includes: a first field-effect transistor of a first conductivity type formed on a first active region of a semiconductor substrate. The first field-effect transistor includes a first gate insulating film formed on the first active region, and a first gate electrode formed on the first gate insulating film. The first gate electrode includes a first metal electrode formed on the first gate insulating film, a first interface layer formed on the first metal electrode, and a first silicon electrode formed on the first interface layer.
    Type: Grant
    Filed: November 1, 2012
    Date of Patent: April 28, 2015
    Assignee: Panasonic Intellectual Property Management Co., Ltd.
    Inventor: Shinji Takeoka
  • Publication number: 20150108590
    Abstract: Capacitive coupling between a gate electrode and underlying portions of the source and drain regions can be enhanced while suppressing capacitive coupling between the gate electrode and laterally spaced elements such as contact via structures for the source and drain regions. A transistor including a gate electrode and source and drain regions is formed employing a disposable gate spacer. The disposable gate spacer is removed to form a spacer cavity, which is filled with an anisotropic dielectric material to form an anisotropic gate spacer. The anisotropic dielectric material is aligned with an electrical field such that lengthwise directions of the molecules of the anisotropic dielectric material are aligned vertically within the spacer cavity. The anisotropic gate spacer provides a higher dielectric constant along the vertical direction and a lower dielectric constant along the horizontal direction.
    Type: Application
    Filed: October 22, 2013
    Publication date: April 23, 2015
    Applicant: International Business Machines Corporation
    Inventors: Emre Alptekin, Hari V. Mallela, Reinaldo Vega
  • Publication number: 20150108589
    Abstract: A semiconductor structure may be formed by forming a sacrificial gate above a substrate covered by a hard mask, depositing a first interlevel dielectric (ILD) layer above the sacrificial gate, recessing the first ILD layer to a thickness less than the height of the sacrificial gate, depositing an etch barrier layer above the first ILD layer, depositing a second ILD layer above the etch barrier layer, planarizing the second ILD layer and the etch barrier layer to expose the hard mask using the hard mask as a planarization stop, removing the hard mask and sacrificial gate to form a gate cavity, forming a replacement metal gate in the gate cavity, removing the second ILD layer, and planarizing the replacement metal gate using the etch barrier layer as a planarization stop. A supplementary electrode layer may be formed above the replacement metal gate prior to planarizing the replacement metal gate.
    Type: Application
    Filed: October 22, 2013
    Publication date: April 23, 2015
    Applicant: International Business Machines Corporation
    Inventors: Kangguo Cheng, Ali Khakifirooz, Alexander Reznicek, Charan V. Surisetty
  • Patent number: 9013009
    Abstract: The present invention addresses the problem of providing a technique capable of efficiently and stably providing a method for producing high-purity lanthanum, the method characterized in that: a crude lanthanum oxide starting material having a purity of 2N-3N, excluding gas components, is used; the material is subjected to molten salt electrolysis at a bath temperature of 450-700° C. to produce lanthanum crystals; the lanthanum crystals are subsequently desalted: and electron beam melting is then performed to remove volatile substances. The present invention also addresses the problem of providing a technique capable of efficiently and stably providing high-purity lanthanum, high-purity lanthanum itself, a sputtering target formed from high-purity material lanthanum; and a thin film for metal gates that has high purity lanthanum as the main component.
    Type: Grant
    Filed: January 17, 2012
    Date of Patent: April 21, 2015
    Assignee: JX Nippon Mining & Metals Corporation
    Inventors: Masahiro Takahata, Kazuyuki Satoh, Satoyasu Narita, Takeshi Gohara
  • Publication number: 20150102431
    Abstract: Embodiments of mechanisms for forming a semiconductor device are provided. The semiconductor device includes a semiconductor substrate and a nitride buffer layer over the semiconductor substrate, and the nitride buffer layer is in an amorphous state. The semiconductor device also includes a crystalline gate dielectric layer over the nitride buffer layer and a gate electrode over the crystalline gate dielectric layer.
    Type: Application
    Filed: October 11, 2013
    Publication date: April 16, 2015
    Applicant: Taiwan Seminconductor Manufacturing Co., Ltd.
    Inventors: Liang-Chen CHI, Chia-Ming TSAI, Chin-Kun WANG, Jhih-Jie HUANG, Miin-Jang CHEN
  • Publication number: 20150102430
    Abstract: Disclosed herein is a semiconductor device comprising a first dielectric disposed over a channel region of a transistor formed in a substrate and a gate disposed over the first dielectric. The semiconductor device further includes a second dielectric disposed vertically, substantially perpendicular to the substrate, at an edge of the gate, and a spacer disposed proximate to the second dielectric. The spacer includes a cross-section with a perimeter that includes a top curved portion and a vertical portion substantially perpendicular to the substrate. The perimeter further includes a discontinuity at an interface of the top curved portion with the vertical portion. Further, disclosed herein are methods associated with the fabrication of the aforementioned semiconductor device.
    Type: Application
    Filed: October 11, 2013
    Publication date: April 16, 2015
    Applicant: Spansion LLC
    Inventors: Angela Tai Hui, Scott Bell, Shenqing Fang
  • Patent number: 9006064
    Abstract: A gate dielectric can be formed by depositing a first silicon oxide material by a first atomic layer deposition process. The thickness of the first silicon oxide material is selected to correspond to at least 10 deposition cycles of the first atomic layer deposition process. The first silicon oxide material is converted into a first silicon oxynitride material by a first plasma nitridation process. A second silicon oxide material is subsequently deposited by a second atomic layer deposition process. The second silicon oxide material is converted into a second silicon oxynitride material by a second plasma nitridation process. Multiple repetitions of the atomic layer deposition process and the plasma nitridation process provides a silicon oxynitride material having a ratio of nitrogen atoms to oxygen atoms greater than 1/3, which can be advantageously employed to reduce the leakage current through a gate dielectric.
    Type: Grant
    Filed: March 11, 2013
    Date of Patent: April 14, 2015
    Assignee: International Business Machines Corporation
    Inventors: Michael P. Chudzik, Barry P. Linder, Shahab Siddiqui
  • Patent number: 9006092
    Abstract: A semiconductor structure includes a substrate, a dielectric layer and a fluoride metal layer. The dielectric layer is located on the substrate. The fluoride metal layer is located on the dielectric layer. Furthermore, the present invention also provides a semiconductor process to form said semiconductor structure.
    Type: Grant
    Filed: November 3, 2011
    Date of Patent: April 14, 2015
    Assignee: United Microelectronics Corp.
    Inventors: Kun-Hsien Lin, Chun-Hsien Lin, Hsin-Fu Huang
  • Patent number: 9006094
    Abstract: A stratified gate dielectric stack includes a first high dielectric constant (high-k) gate dielectric comprising a first high-k dielectric material, a band-gap-disrupting dielectric comprising a dielectric material having a different band gap than the first high-k dielectric material, and a second high-k gate dielectric comprising a second high-k dielectric material. The band-gap-disrupting dielectric includes at least one contiguous atomic layer of the dielectric material. Thus, the stratified gate dielectric stack includes a first atomic interface between the first high-k gate dielectric and the band-gap-disrupting dielectric, and a second atomic interface between the second high-k gate dielectric and the band-gap-disrupting dielectric that is spaced from the first atomic interface by at least one continuous atomic layer of the dielectric material of the band-gap-disrupting dielectric.
    Type: Grant
    Filed: April 18, 2012
    Date of Patent: April 14, 2015
    Assignee: International Business Machines Corporation
    Inventors: Hemanth Jagannathan, Paul C. Jamison
  • Patent number: 9006837
    Abstract: A complementary metal oxide semiconductor structure including a scaled 0 and a scaled pFET which do not exhibit an increased threshold voltage and reduced mobility during operation is provided. The method includes forming a plasma nitrided, nFET threshold voltage adjusted high k gate dielectric layer portion within an nFET gate stack, and forming at least a pFET threshold voltage adjusted high k gate dielectric layer portion within a pFET gate stack. The pFET threshold voltage adjusted high k gate dielectric layer portion in the pFET gate stack can also be plasma nitrided. The plasma nitrided, nFET threshold voltage adjusted high k gate dielectric layer portion contains up to 15 atomic % N2 and an nFET threshold voltage adjusted species, while the plasma nitrided, pFET threshold voltage adjusted high k gate dielectric layer portion contains up to 15 atomic % N2 and a pFET threshold voltage adjusted species.
    Type: Grant
    Filed: March 11, 2013
    Date of Patent: April 14, 2015
    Assignee: International Business Machines Corporation
    Inventors: Michael P. Chudzik, Dechao Guo, Siddarth A. Krishnan, Unoh Kwon, Carl J. Radens, Shahab Siddiqui
  • Patent number: 9006816
    Abstract: A memory device may include a semiconductor substrate, and a memory transistor in the semiconductor substrate. The memory transistor may include source and drain regions in the semiconductor substrate and a channel region therebetween, and a gate stack. The gate stack may include a first dielectric layer over the channel region, a first diffusion barrier layer over the first dielectric layer, a first electrically conductive layer over the first diffusion barrier layer, a second dielectric layer over the first electrically conductive layer, a second diffusion barrier layer over the second dielectric layer, and a second electrically conductive layer over the second diffusion barrier layer. The first and second dielectric layers may include different dielectric materials, and the first diffusion barrier layer may be thinner than the second diffusion barrier layer.
    Type: Grant
    Filed: March 28, 2013
    Date of Patent: April 14, 2015
    Assignees: STMicroelectronics, Inc., International Business Machines Corporation
    Inventors: Prasanna Khare, Stephane Allegret-Maret, Nicolas Loubet, Qing Liu, Hemanth Jagannathan, Lisa Edge, Kangguo Cheng, Bruce Doris
  • Patent number: 9000531
    Abstract: A method of forming transistors and structures thereof. A CMOS device includes high k gate dielectric materials. A PMOS device includes a gate that is implanted with an n type dopant. The NMOS device may be doped with either an n type or a p type dopant. The work function of the CMOS device is set by the material selection of the gate dielectric materials. A polysilicon depletion effect is reduced or avoided.
    Type: Grant
    Filed: February 28, 2014
    Date of Patent: April 7, 2015
    Assignee: Infineon Technologies AG
    Inventor: Hong-Jyh Li
  • Patent number: 9000540
    Abstract: The performances of semiconductor elements disposed in a multilayer wiring layer are improved. A semiconductor device includes: a first wire disposed in a first wiring layer; a second wire disposed in a second wiring layer stacked over the first wiring layer; a gate electrode arranged between the first wire and the second wire in the direction of stacking of the first wiring layer and the second wiring layer, and not coupled with the first wire and the second wire; a gate insulation film disposed over the side surface of the gate electrode; and a semiconductor layer disposed over the side surface of the gate electrode via the gate insulation film, and coupled with the first wire and the second wire.
    Type: Grant
    Filed: January 10, 2013
    Date of Patent: April 7, 2015
    Assignee: Renesas Electronics Corporation
    Inventors: Hiroshi Sunamura, Naoya Inoue, Kishou Kaneko
  • Patent number: 8993455
    Abstract: Atomic layer deposition (ALD) can be used to form a dielectric layer of zirconium aluminum oxynitride (ZrAlON) for use in a variety of electronic devices. Forming the dielectric layer may include depositing zirconium oxide using atomic layer deposition and precursor chemicals, followed by depositing aluminum nitride using precursor chemicals, and repeating. The dielectric layer may be used as the gate insulator of a MOSFET, a capacitor dielectric, and a tunnel gate insulator in flash memories.
    Type: Grant
    Filed: May 28, 2010
    Date of Patent: March 31, 2015
    Assignee: Micron Technology, Inc.
    Inventors: Kie Y. Ahn, Leonard Forbes
  • Patent number: 8994025
    Abstract: The present invention relates to a visible ray sensor and a light sensor capable of improving photosensitivity by preventing photodegradation. The visible ray sensor may include: a substrate, a light blocking member formed on the substrate, and a visible ray sensing thin film transistor formed on the light blocking member. The light blocking member may be made of a transparent electrode, a band pass filter, or an opaque metal.
    Type: Grant
    Filed: December 28, 2010
    Date of Patent: March 31, 2015
    Assignee: Samsung Display Co., Ltd.
    Inventors: Sang-Youn Han, Jun-Ho Song, Kyung-Sook Jeon, Mi-Seon Seo, Sung-Hoon Yang, Suk-Won Jung, Seung Mi Seo
  • Patent number: 8994123
    Abstract: Variation resistant metal-oxide-semiconductor field effect transistors (MOSFETs) are manufactured using a high-K, metal-gate ‘channel-last’ process. A cavity is formed between spacers formed over a well area having separate drain and source areas, and then a recess into the well area is formed. The active region is formed in the recess, comprising an optional narrow highly doped layer, essentially a buried epitaxial layer, over which a second un-doped or lightly doped layer is formed which is a channel epitaxial layer. The high doping beneath the low doped epitaxial layer can be achieved utilizing low-temperature epitaxial growth with single or multiple delta doping, or slab doping. A high-K dielectric stack is formed over the channel epitaxial layer, over which a metal gate is formed within the cavity boundaries. In one embodiment of the invention a cap of poly-silicon or amorphous silicon is added on top of the metal gate.
    Type: Grant
    Filed: March 20, 2012
    Date of Patent: March 31, 2015
    Assignee: Gold Standard Simulations Ltd.
    Inventors: Asen Asenov, Gareth Roy
  • Patent number: 8987126
    Abstract: Integrated circuits and methods of fabricating integrated circuits are provided herein. In an embodiment, a method of fabricating an integrated circuit includes depositing a layer of a high-k dielectric material; depositing a layer of a work function shifter material over a portion of the high-k dielectric material to form an overlapping region; heat treating the layer of the high-k dielectric material and the layer of the work function shifter material to as to form a transformed dielectric material via thermal diffusion that is a combination of the high-k dielectric and work function shifter materials in the overlapping region; and depositing a layer of a first replacement gate fill material to obtain multiple threshold voltages.
    Type: Grant
    Filed: May 9, 2012
    Date of Patent: March 24, 2015
    Assignee: GLOBALFOUNDRIES, Inc.
    Inventors: Kisik Choi, Hoon Kim
  • Patent number: 8988626
    Abstract: A liquid crystal display device and method for manufacturing the same are provided. A liquid crystal display (LCD) with a touch function includes: a pixel thin film transistor (TFT) in a display area, and a buffer TFT of a gate driver in a non-display area, wherein a lightly-doped drain (LDD) length of the buffer TFT is shorter than a lightly doped drain (LDD) length of the pixel TFT.
    Type: Grant
    Filed: December 17, 2012
    Date of Patent: March 24, 2015
    Assignee: LG Display Co., Ltd.
    Inventor: Sangwon Lee
  • Patent number: 8987806
    Abstract: Memories, systems, and methods for forming memory cells are disclosed. One such memory cell includes a charge storage node that includes nanodots over a tunnel dielectric and a protective film over the nanodots. In another memory cell, the charge storage node includes nanodots that include a ruthenium alloy. Memory cells can include an inter-gate dielectric over the protective film or ruthenium alloy nanodots and a control gate over the inter-gate dielectric. The protective film and ruthenium alloy can be configured to protect at least some of the nanodots from vaporizing during formation of the inter-gate dielectric.
    Type: Grant
    Filed: September 13, 2012
    Date of Patent: March 24, 2015
    Assignee: Micron Technology, Inc.
    Inventors: D. V. Nirmal Ramaswamy, Matthew N. Rocklein, Rhett Brewer
  • Patent number: 8980715
    Abstract: Multilayer dielectric structures are provided having silicon nitride (SiN) and silicon oxynitride (SiNO) films for use as capping layers, liners, spacer barrier layers, and etch stop layers, and other components of semiconductor nano-devices. For example, a semiconductor structure includes a multilayer dielectric structure having multiple layers of dielectric material including one or more SiN layers and one or more SiNO layers. The layers of dielectric material in the multilayer dielectric structure have a thickness in a range of about 0.5 nanometers to about 3 nanometers.
    Type: Grant
    Filed: August 28, 2013
    Date of Patent: March 17, 2015
    Assignee: International Business Machines Corporation
    Inventors: Alfred Grill, Seth L. Knupp, Son V. Nguyen, Vamsi K. Paruchuri, Deepika Priyadarshini, Hosadurga K. Shobha
  • Publication number: 20150069534
    Abstract: A method for fabricating semiconductor device is disclosed. The method includes the steps of: providing a substrate; forming an interfacial layer on the substrate; forming a high-k dielectric layer on the interfacial layer; forming a first bottom barrier metal (BBM) layer on the high-k dielectric layer; performing a thermal treatment; removing the first BBM layer; and forming a second BBM layer on the high-k dielectric layer.
    Type: Application
    Filed: September 11, 2013
    Publication date: March 12, 2015
    Applicant: UNITED MICROELECTRONICS CORP.
    Inventors: Jian-Cun Ke, Chih-Wei Yang, Kun-Yuan Lo, Chia-Fu Hsu, Shao-Wei Wang
  • Publication number: 20150069535
    Abstract: A semiconductor device includes a metal gate stack. The metal gate stack includes a high-k gate dielectric and a metal gate electrode over the high-k gate dielectric. The metal gate electrode includes a first top surface and a second bottom surface substantially diametrically opposite the first top surface. The first top surface includes a first surface length and the second bottom surface includes a second surface length. The first surface length is larger than the second surface length. A method of forming a semiconductor device is provided.
    Type: Application
    Filed: September 12, 2013
    Publication date: March 12, 2015
    Inventors: Che-Cheng Chang, Chang-Yin Chen, Yi - Jen Chen, Yung Jung Chang
  • Patent number: 8975143
    Abstract: Fluorine is located in selective portions of a gate oxide to adjust characteristics of the gate oxide. In some embodiments, the fluorine promotes oxidation which increases the thickness of the selective portion of the gate oxide. In some embodiments, the fluorine lowers the dielectric constant of the oxide at the selective portion. In some examples, having fluorine at selective portions of a select gate oxide of a non volatile memory may reduce program disturb of the memory.
    Type: Grant
    Filed: April 29, 2013
    Date of Patent: March 10, 2015
    Assignee: Freescale Semiconductor, Inc.
    Inventor: Byoung W. Min
  • Publication number: 20150054029
    Abstract: An integrated circuit device includes a semiconductor substrate; and a gate stack disposed over the semiconductor substrate. The gate stack further includes a gate dielectric layer disposed over the semiconductor substrate; a multi-function blocking/wetting layer disposed over the gate dielectric layer, wherein the multi-function blocking/wetting layer comprises tantalum aluminum carbon nitride (TaAlCN); a work function layer disposed over the multi-function blocking/wetting layer; and a conductive layer disposed over the work function layer.
    Type: Application
    Filed: November 4, 2014
    Publication date: February 26, 2015
    Inventors: SHIU-KO JANGJIAN, TING-CHUN WANG, CHI-CHERNG JENG, CHI-WEN LlU
  • Publication number: 20150041925
    Abstract: Provided are P type MOSFETs and methods for manufacturing the same. The method may include forming source/drain regions in a semiconductor substrate; forming an interfacial oxide layer on the semiconductor substrate; forming a high K gate dielectric layer on the interfacial oxide layer; forming a first metal gate layer on the high K gate dielectric layer; implanting dopants into the first metal gate layer through conformal doping; and performing annealing to change an effective work function of a gate stack including the first metal gate layer, the high K gate dielectric, and the interfacial oxide layer.
    Type: Application
    Filed: December 7, 2012
    Publication date: February 12, 2015
    Inventors: Huilong Zhu, Qiuxia Xu, Yanbo Zhang, Hong Yang
  • Patent number: 8952462
    Abstract: The present disclosure provides an apparatus that includes a semiconductor device. The semiconductor device includes a substrate. The semiconductor device also includes a first gate dielectric layer that is disposed over the substrate. The first gate dielectric layer includes a first material. The first gate dielectric layer has a first thickness that is less than a threshold thickness at which a portion of the first material of the first gate dielectric layer begins to crystallize. The semiconductor device also includes a second gate dielectric layer that is disposed over the first gate dielectric layer. The second gate dielectric layer includes a second material that is different from the first material. The second gate dielectric layer has a second thickness that is less than a threshold thickness at which a portion of the second material of the second gate dielectric layer begins to crystallize.
    Type: Grant
    Filed: February 5, 2010
    Date of Patent: February 10, 2015
    Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.
    Inventors: Jian-Hao Chen, Da-Yuan Lee, Kuang-Yuan Hsu
  • Patent number: 8952459
    Abstract: A gate structure includes a gate dielectric over a substrate, and a gate electrode over the gate dielectric, wherein the gate dielectric contacts sidewalls of the gate electrode. The gate structure further includes a nitrogen-containing dielectric layer surrounding the gate electrode, and a contact etch stop layer (CESL) surrounding the nitrogen-containing dielectric layer. The gate structure further includes an interlayer dielectric layer surrounding the CESL and a lightly doped region in the substrate, the lightly doped region extends beyond an interface of the sidewalls of the gate electrode and the gate dielectric.
    Type: Grant
    Filed: August 20, 2013
    Date of Patent: February 10, 2015
    Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.
    Inventors: Fung Ka Hing, Haiting Wang, Han-Ting Tsai, Chun-Fai Cheng, Wei-Yuan Lu, Hsien-Ching Lo, Kuan-Chung Chen
  • Publication number: 20150035088
    Abstract: A method is provided for fabricating a semiconductor structure. The method includes providing a semiconductor substrate having a plurality of first doped regions and second doped regions; and forming a first dielectric layer on the semiconductor substrate. The method also includes forming a first gate dielectric layer and a second gate dielectric layer; and forming a first metal gate and a second metal gate on the first gate dielectric layer and the second gate dielectric layer, respectively. Further, the method includes forming a third dielectric layer on the second metal gate; and forming a second dielectric layer on the first dielectric layer. Further, the method also includes forming at least one opening exposing at least one first metal gate and one first doped region; and forming a contact layer contacting with the first metal gate and the first doped region to be used as a share contact structure.
    Type: Application
    Filed: October 21, 2014
    Publication date: February 5, 2015
    Inventor: ZHONGSHAN HONG
  • Publication number: 20150035087
    Abstract: A method for manufacturing a dummy gate in a gate-last process and a dummy gate in a gate-last process are provided. The method includes: providing a semiconductor substrate; growing a gate oxide layer on the semiconductor substrate; depositing bottom-layer amorphous silicon on the gate oxide layer; depositing an ONO structured hard mask on the bottom-layer amorphous silicon; depositing top-layer amorphous silicon on the ONO structured hard mask; depositing a hard mask layer on the top-layer amorphous silicon; forming photoresist lines on the hard mask layer, and trimming the formed photoresist lines so that the trimmed photoresist lines a width less than or equal to 22 nm; and etching the hard mask layer, the top-layer amorphous silicon, the ONO structured hard mask and the bottom-layer amorphous silicon in accordance with the trimmed photoresist lines, and removing the photoresist lines, the hard mask layer and the top-layer amorphous silicon.
    Type: Application
    Filed: December 12, 2012
    Publication date: February 5, 2015
    Inventors: Chunlong Li, Junfeng Li, Jiang Yan, Chao Zhao
  • Publication number: 20150035086
    Abstract: One method disclosed herein includes forming an etch stop layer above recessed sidewall spacers and a recessed replacement gate structure and, with the etch stop layer in position, forming a self-aligned contact that is conductively coupled to the source/drain region after forming the self-aligned contact. A device disclosed herein includes an etch stop layer that is positioned above a recessed replacement gate structure and recessed sidewall spacers, wherein the etch stop layer defines an etch stop recess that contains a layer of insulating material positioned therein. The device further includes a self-aligned contact.
    Type: Application
    Filed: August 2, 2013
    Publication date: February 5, 2015
    Applicant: GLOBALFOUNDRIES Inc.
    Inventors: Ruilong Xie, Xiuyu Cai, Larry Zhao
  • Patent number: 8946830
    Abstract: Embodiments related to metal oxide protective layers formed on a surface of a halogen-sensitive metal-including layer present on a substrate processed in a semiconductor processing reactor are provided. In one example, a method for forming a metal oxide protective layer is provided. The example method includes forming a metal-including active species on the halogen-sensitive metal-including layer, the metal-including active species being derived from a non-halogenated metal oxide precursor. The example method also includes reacting an oxygen-containing reactant with the metal-including active species to form the metal oxide protective layer.
    Type: Grant
    Filed: April 4, 2012
    Date of Patent: February 3, 2015
    Assignee: ASM IP Holdings B.V.
    Inventor: Sung-Hoon Jung
  • Publication number: 20150028429
    Abstract: A method is disclosed for fabricating a semiconductor structure. The method includes providing a semiconductor substrate having an oxide layer on a surface of the semiconductor substrate, and removing the oxide layer to expose the surface of the semiconductor substrate. The method also includes performing a thermal annealing process on the semiconductor substrate using an inert gas as a thermal annealing protective gas after removing the oxide layer, and forming an insulating layer on the semiconductor substrate after performing the thermal annealing process. Further, the method includes forming a high-K gate dielectric layer on a surface of the insulating layer, and forming a protective layer on a surface of the high-K gate dielectric layer.
    Type: Application
    Filed: October 15, 2014
    Publication date: January 29, 2015
    Inventor: HUALONG SONG
  • Publication number: 20150028428
    Abstract: A semiconductor structure comprises a substrate including a III-V material, and a high-k interfacial layer overlaying the substrate. The interfacial layer includes a rare earth aluminate. The present disclosure also relates to an n-type FET device comprising the same, and a method for manufacturing the same.
    Type: Application
    Filed: July 25, 2014
    Publication date: January 29, 2015
    Applicants: KATHOLIEKE UNIVERSITEIT LEUVEN, KU LEUVEN R&D, IMEC VZW
    Inventors: Han Chung Lin, Laura Nyns, Tsvetan Ivanov, Dennis Van Dorp