Composition Patents (Class 361/321.4)
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Patent number: 9190209Abstract: A dielectric ceramic composition includes: a base material powder BamTiO3 (0.995?m?1.010); 0.2 to 2.0 moles of a first accessory ingredient, an oxide or carbide containing at least one of Ba and Ca, based on 100 moles of the base material powder; a second accessory ingredient, an oxide containing Si or a glass compound containing Si; 0.2 to 1.5 moles of a third accessory ingredient, an oxide containing at least one of Sc, Y, La, Ac, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu, based on 100 moles of the base material powder; and 0.05 to 0.80 mole of a fourth accessory ingredient, an oxide containing at least one of Cr, Mo, W, Mn, Fe, Co, and Ni, based on 100 moles of the base material powder, a content ratio of the first accessory ingredient to the second accessory ingredient being 0.5 to 1.7.Type: GrantFiled: June 21, 2013Date of Patent: November 17, 2015Assignee: SAMSUNG ELECTRO-MECHANICS CO., LTD.Inventors: Sung Hyung Kang, Du Won Choi, Ki Yong Lee, Jae Hun Choe, Min Sung Song
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Patent number: 9153643Abstract: A semiconductor ceramic contains a donor element solid-solved in crystal grains of a SrTiO3-based compound, and an acceptor element in a grain boundary layer. The number of tetravalent acceptor elements is 1×1017/g or more, as determined from an electron spin resonance absorption spectrum. A mixture of a calcined powder and an acceptor compound is pulverized to a specific surface area of 5.0 to 7.5 m2/g before mixing with a binder. Semiconductor ceramic layers having a varistor function are formed by using the semiconductor ceramic forming a highly reliable capacitor which can suppress characteristics variations to stably obtain good electrical characteristics.Type: GrantFiled: April 30, 2013Date of Patent: October 6, 2015Assignee: MURATA MANUFACTURING CO., LTD.Inventor: Mitsutoshi Kawamoto
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Patent number: 9105603Abstract: A semiconductor ceramic having a compounding molar ratio m between a Sr site and a Ti site that satisfies 1.000 ?m?1.020, has a donor element present as a solid solution in crystal grains, has an acceptor element present in a grain boundary layer in the range of 0.5 mol or less with respect to 100 mol of the Ti element, contains a Zr element in the range of 0.15 mol or more and 3.0 mol or less with respect to 100 mol of the Ti element, and has the crystal grains of 1.5 ?m or less in average grain size.Type: GrantFiled: March 28, 2014Date of Patent: August 11, 2015Assignee: MURATA MANUFACTURING CO., LTD.Inventor: Mitsutoshi Kawamoto
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Patent number: 9093220Abstract: A multilayer ceramic capacitor includes a multilayer unit, thickness-direction first and second outer layer sections, and width-direction first and second outer layer sections. A dimension of the thickness-direction second outer layer section is greater than a dimension of the thickness-direction first outer layer section. The thickness-direction second outer layer section includes an inner portion and an outer portion. A composition ratio of Si to Ti in a ceramic dielectric layer included in the outer portion is higher than that in the inner portion. A Si content ratio is higher in a boundary portion between the outer portion and the inner portion. A thickness dimension of the multilayer unit is greater than a width dimension thereof, and width dimensions of the width-direction first and second outer layer sections are greater than a thickness dimension of the thickness-direction first outer layer section.Type: GrantFiled: January 9, 2015Date of Patent: July 28, 2015Assignee: Murata Manufacturing Co., Ltd.Inventors: Shota Kitano, Takanobu Katsuyama, Hiroaki Sugita
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Patent number: 9087645Abstract: Described in this patent application are devices for energy storage and methods of making and using such devices. In various embodiments, blocking layers are provided between dielectric material and the electrodes of an energy storage device. The block layers are characterized by higher dielectric constant than the dielectric material. There are other embodiments as well.Type: GrantFiled: January 25, 2013Date of Patent: July 21, 2015Assignee: QuantrumScape CorporationInventors: Tim Holme, Friedrich B. Prinz, Weston Arthur Hermann, Joseph Han, Rainer Fasching
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Patent number: 9082552Abstract: A method of manufacturing a capacitor includes forming, above a first metal foil, a first dielectric film of a ceramic material containing barium oxide by blowing dry ceramic particles to the first metal foil from a nozzle, forming, in the first dielectric film, a first via conductor connected to the first metal foil and a second via conductor connected to the first metal foil, forming, above the first dielectric film, a first electrode pattern connected to the first via conductor, and patterning the first metal foil to form a second electrode pattern connected to the second via conductor.Type: GrantFiled: October 16, 2012Date of Patent: July 14, 2015Assignee: FUJITSU LIMITEDInventors: Yoshihiko Imanaka, Hideyuki Amada, Fumiaki Kumasaka
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Patent number: 9076599Abstract: A compact laminated ceramic electronic component having superior moisture resistance and electrical properties is provided. A laminated ceramic electronic component 1 includes an inner layer portion that contains a plurality of dielectric layers 2a and internal electrode layers 3 comprising Ni as a main component that are laminated alternately, and a pair of dielectric outer layer portions 2b which sandwich the inner layer portions. And Ni particles are segregated in the dielectric outer layer portions 2b. And the amount of Ni particles existing in the dielectric layers 2a is smaller than that in the dielectric outer layer portions 2b.Type: GrantFiled: October 12, 2012Date of Patent: July 7, 2015Assignee: TDK CorporationInventors: Makoto Endo, Hirobumi Tanaka, Osamu Kido
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Patent number: 9058936Abstract: A multilayer ceramic capacitor uses internal electrodes which are embedded between the dielectric layers and whose primary constituent is Cu, wherein when the composition of the dielectric layer is expressed by 100CaxZrO3+aMnO2+bLiO1/2+cBO3/2+dSiO2+eAlO3/2, the contents of the respective constituents are 1.5?a?4.5 mol, 0.8?b/(c+d)?2.0, 0.9?d/c?1.5, and 0?e?0.3 mol relative to 100 mol of CaxZrO3 (where 1.005?x?1.06), and when 10?(b+c+d)?14.9, an upper limit of x is defined by a line passing through (10, 1.03) and (14.9, 1.06), and a lower limit of x is defined by a line passing through (10, 1.005) and (14.9, 1.02), wherein the coordinates indicate ((b+c+d), x).Type: GrantFiled: June 27, 2013Date of Patent: June 16, 2015Assignee: TAIYO YUDEN CO., LTD.Inventor: Shinsuke Takeoka
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Patent number: 9054348Abstract: An electrochemical device having one or more solid oxide fuel cells (SOFCs), each of the SOFCs including a cathode, an anode, and an electrolyte layer positioned between the cathode and anode; and at least one additional component comprising a metallic substrate having an electronically conductive, chromium-free perovskite coating deposited directly thereon. The perovskite coating has the formula ABO3, wherein A is a lanthanide element or Y, and B is a mixture of two or more transition elements, with the A site undoped by any alkaline earth element, and the perovskite coating exhibits limited or no ionic transport of oxygen.Type: GrantFiled: April 13, 2012Date of Patent: June 9, 2015Assignee: NextTech Materials, Ltd.Inventors: Matthew M. Seabaugh, Sergio Ibanez, Scott L. Swartz
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Patent number: 9036331Abstract: There is provided a dielectric composition including: a base powder including BaTiO3; a first accessory component including a content (x1) of 0.1 to 1.0 at % of an oxide or a carbonate including transition metals, based on 100 moles of the base powder; a second accessory component including a content (y) of 0.01 to 3.0 at % of oxide or carbonate including a fixed valence acceptor element, based on 100 moles of the base powder; a third accessory component including an oxide or a carbonate including a Ce element (content of z at %) and at least one rare earth element (content of w at %); and a fourth accessory component including a sintering aid, wherein 0.01?z?x1+4y and 0.01?z+w?x1+4y based on 100 moles of the base powder.Type: GrantFiled: January 31, 2012Date of Patent: May 19, 2015Assignee: Samsung Electro-Mechanics Co., Ltd.Inventors: Seok Hyun Yoon, Ji Young Park, Sun Ho Yoon, Sang Hoon Kwon, Chang Hoon Kim
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Patent number: 9019690Abstract: There is provided a conductive resin composition including 10 to 50 wt % of a gel type silicon rubber such as polydimethylsiloxane (PDMS), and 50 to 90 wt % of conductive metal powder particles.Type: GrantFiled: March 11, 2013Date of Patent: April 28, 2015Assignee: Samsung Electro-Mechanics Co., Ltd.Inventors: Kyung Pyo Hong, Hyun Hee Gu, Byoung Jin Chun, Jae Hwan Han
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Patent number: 9001494Abstract: A dielectric ceramic that contains, as its main constituent, a perovskite-type compound containing Ba and Ti, and, with respect to the Ti content of 100 parts by mole, contains Re1 (Re1 is at least one element of La and Nd) in the range of 0.15 to 3 parts by mole, Y in the range of 0.1 to 3 parts by mole, Mg in the range of 0.3 to 13 parts by mole, and Fe in the range of 0.01 to 5 parts by mole.Type: GrantFiled: December 2, 2013Date of Patent: April 7, 2015Assignee: Murata Manufacturing Co., Ltd.Inventors: Kazuji Kushiro, Tatsuya Ishikawa, Tomomitsu Yamanishi, Naoki Kawara
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Patent number: 8980139Abstract: A method of manufacturing a metal paste for an internal electrode according to the present invention includes preparing each of a metal powder and an organic vehicle; preparing a ceramic inhibitor powder in which a nano glass added with a rare-earth element is mixed; manufacturing a primary mixture by mixing the metal powder of 70 to 95 wt % and the ceramic inhibitor powder of 5 to 30 wt % when each of the metal powder, the organic vehicle, and the ceramic inhibitor powder in which the nano glass added with the rare-earth element is mixed is prepared; manufacturing a secondary mixture by mixing the primary mixture of 50 to 70 wt % and the organic vehicle of 30 to 50 wt % when the primary mixture is manufactured; and manufacturing the metal paste for the internal electrode by filtering the secondary mixture when the secondary mixture is manufactured.Type: GrantFiled: March 12, 2013Date of Patent: March 17, 2015Assignee: Samhwa Capacitor Co., Ltd.Inventors: Young Joo Oh, Jung Rag Yoon
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Patent number: 8964356Abstract: A dielectric ceramic which is suitable for use in a laminated ceramic capacitor under a high-temperature environment, such as encountered in, for example, automobile use has a composition represented by the composition formula: (1?x) (Ba1-yCay)mTiO3+xCaTiO3+aRe2O3+bMgO+cMnO+dV2O3+eSiO2 in which Re is Gd, Dy, Y, Ho, and/or Er), 0.001?x?0.02, 0.08?y?0.20, 0.99?m?1.05, 0.01?a?0.04, 0.005?b?0.035, 0?c?0.01, 0?d?0.01, 0.01?e?0.04 when a, b, c, d, and e are each expressed in terms of parts by mol with respect to 1 mol of (1?x) (Ba,Ca)TiO3+xCaTiO3. This dielectric ceramic can constitute the dielectric ceramic layers of a laminated ceramic capacitor.Type: GrantFiled: March 13, 2012Date of Patent: February 24, 2015Assignee: Murata Manufacturing Co., Ltd.Inventors: Shoichiro Suzuki, Toshikazu Takeda, Jun Ikeda, Megumi Morita
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Patent number: 8962506Abstract: There is provided a dielectric composition, including: a base powder including BamTiO3, where 0.995?m?1.010; a first subcomponent including 0.1 to 1.0 at % (x) of an oxide or carbonate containing at least one variable-valence acceptor element based on 100 moles of the base powder; a second subcomponent including 0.01 to 3.0 at % (y) of an oxide or carbonate containing at least one fixed valence acceptor element; a third subcomponent including an oxide or carbonate containing cerium (z) at % and at least one other rare-earth element (w) at %, where 0.01?z?x+4y and 0.01?z+w?x+4y; a fourth subcomponent including at least one of an oxide or carbonate containing at least one of Barium, Calcium, Aluminum, and Silicon and glass containing silicon; and a fifth subcomponent including 0.01 to 10.0 at % of an oxide containing zirconium.Type: GrantFiled: March 15, 2013Date of Patent: February 24, 2015Assignee: Samsung Electro-Mechanics Co., Ltd.Inventors: Kyu Ree Kim, Seok Hyun Yoon, Sun Ho Yoon, Chang Hoon Kim
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Publication number: 20150036264Abstract: A multi-layer ceramic capacitor has a structure where its dielectric layers are constituted by a sintered compact that contains a mol of ReO3/2, b mol of SiO2, c mol of MOx, d mol of ZrO2, and e mol of MgO (where Re is a rare earth element, M is a metal element (except for Ba, Ti, Re, Si, Zr, Mg, and rare earth elements), and x is a valance) per 100 mol of BaTiO3, and a, b, c, d, and e mentioned above which indicate the mol numbers of respective constituents per 100 mol of BaTiO3 are 0.1?a?1.0, 0.1?b?1.5, 0.1?c?0.4, 0?d?1.0, and 0?e?0.03, respectively. Provide a multi-layer ceramic capacitor that allows for high-density layering and still achieves improved reliability by means of suppressing the grain growth when the dielectric grains constituting the dielectric layers are sintered and thereby ensuring sufficient grain boundary, while also setting a high dielectric constant per unit grain size.Type: ApplicationFiled: November 13, 2012Publication date: February 5, 2015Inventors: Koichiro Morita, Tetsuo Shimura, Kunihiko Nagaoka
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Patent number: 8946104Abstract: A dielectric ceramic whose primary component is an ABO3 compound (A contains Ba and B contains Ti) has a per-layer thickness of approx. 0.5 ?m or less, where the volume ratio to all dielectric sintered grains of those whose grain size is in a range of 0.02 ?m to 0.15 ?m is adjusted to a grain size distribution of 1% to 10%. High dielectric constant and high reliability can be achieved at the same time with the dielectric ceramic.Type: GrantFiled: June 19, 2013Date of Patent: February 3, 2015Assignee: Taiyo Yuden Co., Ltd.Inventors: Yukihiro Konishi, Yusuke Kowase, Kazumichi Hiroi, Kotaro Mizuno, Ayumu Sato
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Patent number: 8921248Abstract: Dielectric ceramic composition comprising a compound shown by a general formula {A1-x(RE)2x/3}y-B2O5+y and has a tungsten bronze-type structure. In the formula, “A” is at least one selected from a group comprising Ba, Ca, Sr and Mg, “B” is at least one selected from Nb and Ta, “RE” is at least one selected from Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu, and said “x” and “y” satisfies 0<x<1 and y<1.000, respectively. The dielectric ceramic composition further comprises an oxide of at least one selected from V, Mo, Fe, W, Mn and Cr.Type: GrantFiled: February 21, 2013Date of Patent: December 30, 2014Assignee: TDK CorporationInventors: Toshihiro Iguchi, Akitoshi Yoshii, Tatsuya Kojima, Satoshi Takagi
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Patent number: 8908353Abstract: A laminated ceramic capacitor has multiple layered dielectric ceramic layers of a dielectric ceramic constituted by primary phase grains whose primary component is BaTiO3, secondary phase grains containing at least Re (Re represents at least one of Eu, Gd, Dy, Ho, Er, Yb, and Y), Ba, and Ti, and grain boundary phase containing at least one of B and Li or both; and internal electrodes which are made of Cu or Cu alloy. When a thickness of the dielectric ceramic layer is given by t, and when grain sizes at cumulative 20%, cumulative 50%, and cumulative 95% points of a cumulative count distribution of the primary phase grains are given by D20, D50, and D95, respectively, D20?D50×70%, D50?t/4, D95?t/2, and CV value ((standard deviation between D20 and D95)/D50)<40% are satisfied.Type: GrantFiled: September 26, 2011Date of Patent: December 9, 2014Assignee: Taiyo Yuden Co., Ltd.Inventors: Kenji Takashima, Shinsuke Takeoka
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Patent number: 8904609Abstract: A capacitor with a combined with a resistor and/or fuse is described. This safe capacitor can rapidly discharge through the resistor when shorted. The presence of a fuse in series with the capacitor and results in a resistive failure when this opens during and overcurrent condition. Furthermore, the presence of a resistor in parallel to the capacitor allows the energy to be rapidly dissipated when a failure occurs.Type: GrantFiled: December 8, 2011Date of Patent: December 9, 2014Assignee: Kemet Electronics CorporationInventors: John Bultitude, John E. McConnell
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Patent number: 8884350Abstract: This semiconductor device according to the present invention includes a plurality of cylindrical lower electrodes aligned densely in a memory array region; a plate-like support which is contacted on the side surface of the cylindrical lower electrodes, and links to support the plurality of the cylindrical lower electrodes; a pore portion provided in the plate-like support; a dielectric film covering the entire surface of the cylindrical lower electrodes and the plate-like support in which the pore portion is formed; and an upper electrode formed on the surface of the dielectric film, wherein the boundary length of the part on the side surface of the cylindrical lower electrode which is exposed on the pore portion is shorter than the boundary length of the part on the side surface of the cylindrical lower electrode which is not exposed on the pore portion.Type: GrantFiled: January 23, 2013Date of Patent: November 11, 2014Assignee: PS4 Luxco S.A.R.L.Inventor: Toshiyuki Hirota
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Patent number: 8861182Abstract: There are provided a conductive paste composition for an internal electrode, a multilayer ceramic capacitor having the same, and a fabrication method thereof. The conductive paste composition for an internal electrode includes a binder, a solvent, and metal powder for an internal electrode, including a nickel particle coated with a nickel nitride.Type: GrantFiled: August 21, 2012Date of Patent: October 14, 2014Assignee: Samsung Electro-Mechanics Co., Ltd.Inventors: Ye Jun Park, Yoon Hee Lee, Dong Hoon Kim
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Patent number: 8853115Abstract: A dielectric ceramic composition comprising a compound shown by a general formula {A1?x(RE)2x/3}y-D2O5+y having tungsten bronze-type structure and an oxide of “M”. “A” is at least one selected from Ba, Ca, Sr and Mg, “D” is at least one selected from Nb and Ta, “RE” is at least one selected from Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu, “x” and “y” satisfies 0<x<1 and y>0, respectively and said “M” is at least one selected from Al, Si, B and Li. It is preferable to further comprise Mg oxide.Type: GrantFiled: February 21, 2013Date of Patent: October 7, 2014Assignee: TDK CorporationInventors: Toshihiro Iguchi, Akitoshi Yoshii, Tatsuya Kojima, Satoshi Takagi
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Patent number: 8848336Abstract: A crystalline perovskite crystalline composite paraelectric material includes nano-regions containing rich N3? anions dispersed in a nano-grain sized matrix of crystalline oxide perovskite material, wherein (ABO3-?)?-(ABO3-?-?N?)1-?. A represents a divalent element, B represents a tetravalent element, ? satisfies 0.005???1.0, 1-? satisfies 0.05?1-??0.9, and 1-? is an area ratio between the regions containing rich N3? anions and the matrix of remaining oxide perovskite material.Type: GrantFiled: September 14, 2012Date of Patent: September 30, 2014Assignee: Murata Manufacturing Co., Ltd.Inventors: Ivoyl Koutsaroff, Shinichi Higai, Akira Ando
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Patent number: 8841225Abstract: A dielectric ceramic that includes a sintered body of BaTiO3 based ceramic grains, in which the ceramic grains each include a shell part as a surface layer part and a core part inside the shell part. The ceramic grains contain, as accessory constituents, R (R, which is a rare-earth element, is at least one selected from the group consisting of Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, and Y) and M (M is at least one selected from the group consisting of Mg, Mn, Ni, Co, Fe, Cr, Cu, Al, Mo, W, and V). R and M are present in the shell part of the ceramic grain, and concentrations of R and M contained in the shell part are increased from a grain boundary toward the core part.Type: GrantFiled: October 2, 2012Date of Patent: September 23, 2014Assignee: Murata Manufacturing Co., Ltd.Inventors: Tomomi Koga, Koichi Banno
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Patent number: 8841224Abstract: Dielectric ceramic composition comprising a compound shown by a general formula {A1?x(RE)2x/3}y-B2O5+y and has a tungsten bronze-type structure. In the formula, “A” is at least one selected from a group comprising Ba, Ca, Sr and Mg, “B” is at least one selected from Nb and Ta, “RE” is at least one selected from Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu, and said “x” and “y” satisfies 0<x<1 and y>1.000, respectively. The dielectric ceramic composition further comprises an oxide of at least one selected from V, Mo, Fe, W, Mn and Cr.Type: GrantFiled: February 21, 2013Date of Patent: September 23, 2014Assignee: TDK CorporationInventors: Toshihiro Iguchi, Akitoshi Yoshii, Tatsuya Kojima, Satoshi Takagi
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Publication number: 20140268492Abstract: There is provided a dielectric composition containing barium calcium tin titanate powder composed of (Ba(1-x-y)CaxSny)zTiO3, satisfying 0.01?x?0.15, 0.01?y?0.20, and 0.99?z?1.01.Type: ApplicationFiled: June 28, 2013Publication date: September 18, 2014Inventors: Han Soung JEONG, Doo Yeon HWANG, Chang Hoon KIM, Sun Ho YOON, Seok Hyun YOON, Hyo Jung KIM
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Patent number: 8797713Abstract: Provided is a laminated ceramic capacitor that can suppress the decrease in insulation resistance after a moisture-resistance loading test. It contains ceramic layers which include: main-phase grains that have a perovskite-type compound containing Ba and Ti and optionally containing Ca, Sr, Zr, and Hf; and secondary-phase grains that have an average grain size of 100 nm or more and have a Si content of 50 mol % or more per grain, the average grain boundary number, represented by (Average Thickness for Ceramic Layers 3)/(Average Grain Size for Main Phase Grains)?1, is greater than 0 and 3.0 or less, and the average grain size for the secondary-phase grains is ¼ or more of the average thickness for the ceramic layers 3.Type: GrantFiled: October 28, 2013Date of Patent: August 5, 2014Assignee: Murata Manufacturing Co., Ltd.Inventor: Takayuki Yao
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Publication number: 20140177133Abstract: There is provided a multilayer ceramic electronic component, including: a ceramic body including dielectric layer; and first and second internal electrodes formed inside the ceramic body and disposed to face each other with the dielectric layer interposed therebetween, wherein, on a cross section of the ceramic body taken in length-thickness (L-T) directions thereof, a secondary phase material is formed at interfaces between the first and second internal electrodes and the dielectric layers, and a ratio of an area occupied by the secondary phase material to an overall area of the ceramic body is 0.1% to 0.5%.Type: ApplicationFiled: March 18, 2013Publication date: June 26, 2014Applicant: SAMSUNG ELECTRO-MECHANICS CO., LTD.Inventors: Ro Woon LEE, Young Ho KIM, Kyung Jin CHOI, Yoon Hee LEE, Ki Chun YANG
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Patent number: 8748329Abstract: A dielectric ceramic composition that contains, as its main constituent, (Ba1-x-yCaxSry)(Ti1-z-wZrzHfw)O3 (in the formula, 0?x+y?0.2, 0?z+w?0.1), and contains CuO and Bi2O3, and the dielectric ceramic composition has a feature that the total content of the CuO and Bi2O3 is 10 parts by weight or more with respect to 100 parts by weight of the main constituent, and the molar ratio CuO/(CuO+Bi2O3) is 0.5 or less.Type: GrantFiled: December 14, 2012Date of Patent: June 10, 2014Assignee: Murata Manufacturing Co., Ltd.Inventors: Masanori Nakamura, Masahiro Otsuka, Shoichiro Suzuki, Koichi Banno, Taisuke Kanzaki, Akihiro Shiota
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Patent number: 8730648Abstract: An electrical component includes a ceramic base body. The ceramic base body includes several ceramic layers including a function layer and a composite layer bordering the function layer. The composite layer can include a zirconium oxide-glass filler mixture.Type: GrantFiled: October 20, 2006Date of Patent: May 20, 2014Assignee: Epcos AGInventors: Uwe Wozniak, Thomas Feichtinger, Hermann Gruenbichler, Pavol Dudesek, Thomas Puerstinger
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Patent number: 8724296Abstract: To provide a solid electrolytic capacitor having a high capacitance and an excellent heat resistance. A solid electrolytic capacitor includes: an anode 2; a dielectric layer 3 provided on the surface of the anode 2; a first conductive polymer layer 4a provided on the dielectric layer 3; a second conductive polymer layer 4b provided on the first conductive polymer layer 4a; a third conductive polymer layer 4c provided on the second conductive polymer layer 4b; and a cathode layer provided on the third conductive polymer layer 4c, wherein the first conductive polymer layer 4a is made of a conductive polymer film formed by polymerizing pyrrole or a derivative thereof, the second conductive polymer layer 4b is made of a conductive polymer film formed by polymerizing thiophene or a derivative thereof, and the third conductive polymer layer 4c is made of a conductive polymer film formed by electropolymerizing pyrrole or a derivative thereof.Type: GrantFiled: April 27, 2010Date of Patent: May 13, 2014Assignee: Sanyo Electric Co., Ltd.Inventors: Toru Ishikawa, Masayuki Fujita, Takeshi Sano, Gaku Harada
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Publication number: 20140125194Abstract: A multilayer ceramic electronic component includes: a ceramic body including dielectric layers; an oxide film formed on one surface of the ceramic body; first and second external electrodes formed on both sides of the oxide film on one surface of the ceramic body; a first internal electrode formed on the dielectric layer and including a first electrode lead-out portion exposed to the first external electrode and a first insulating lead-out portion exposed to the oxide film and having a composite-metal-oxide region formed in an exposed edge portion thereof; a second internal electrode facing the first internal electrode, having the dielectric layer interposed therebetween, and including a second electrode lead-out portion exposed to the second external electrode and a second insulating lead-out portion exposed to the oxide film, having a composite-metal-oxide region formed in an exposed edge portion thereof, and overlapped with the first insulating lead-out portion to form additional capacitance.Type: ApplicationFiled: December 14, 2012Publication date: May 8, 2014Applicant: SAMSUNG ELECTRO-MECHANICS CO., LTD.Inventors: Jong Ho LEE, Jae Yeol CHOI, Doo Young KIM, Hang Kyu CHO, Eung Soo KIM, Byung Woo HAN
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Patent number: 8713770Abstract: A ceramic multilayer surface-mount capacitor with inherent crack mitigation void patterning to channel flex cracks into a safe zone, thereby negating any electrical failures.Type: GrantFiled: June 29, 2011Date of Patent: May 6, 2014Assignee: Kemet Electronics CorporationInventor: John D. Prymak
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Patent number: 8673799Abstract: A dielectric ceramic composition comprises barium titanate as a main component, and as subcomponents, 1.00 to 2.50 moles of an oxide of Mg, 0.01 to 0.20 mole of an oxide of Mn and/or Cr, 0.03 to 0.15 mole of an oxide of at least one element selected from a group consisting of V, Mo and W, 0.20 to 1.50 mole of an oxide of R1 where R1 is at least one selected from a group consisting of Y and Ho, 0.20 to 1.50 mole of an oxide of R2 where R2 is at least one selected from a group consisting of Eu, Gd and Tb and 0.30 to 1.50 mole of an oxide of Si and/or B, in terms of each oxide with respect to 100 moles of the barium titanate.Type: GrantFiled: March 26, 2012Date of Patent: March 18, 2014Assignee: TDK CorporationInventors: Jun Sato, Fumiaki Satoh, Saori Takeda, Masakazu Hosono
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Patent number: 8675344Abstract: A high energy density multilayer ceramic capacitor, having at least two electrode layers and at least one substantially dense polycrystalline dielectric layer positioned therebetween. The at polycrystalline dielectric layer has an average grain size of less than about 300 nanometers, a particle size distribution of between about 150 nanometers and about 3 micrometers, and a maximum porosity of about 1 percent. The dielectric layer is selected from the group including TiO2, BaTiO3, Al2O3, ZrO2, lead zirconium titanate, and combinations thereof and has a breakdown strength of at least about 1100 kV per centimeter.Type: GrantFiled: March 19, 2012Date of Patent: March 18, 2014Inventor: Fatih Dogan
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Publication number: 20140049877Abstract: There are provided a dielectric ceramic having large specific resistance and even capacitance characteristic at 150° C., as well as a laminated ceramic electronic component employing such a dielectric ceramic. A ceramic layer includes crystal grains, the ceramic layer containing a perovskite type compound containing Ba, Ca, Ti, and Zr, containing Si, and optionally containing Mn. When the total content of Ti and Zr is 1 molar part, the content of Mn is 0.015 molar part or less, the content of Si is 0.005 molar part or more and less than 0.03 molar part, the molar ratio x of Ca/(Ba+Ca) satisfies 0.05<x<0.20, and the molar ratio y of Zr/(Ti+Zr) satisfies 0.03<y<0.18. The crystal grains have an average grain size of less than 130 nm.Type: ApplicationFiled: October 30, 2013Publication date: February 20, 2014Applicant: MURATA MANUFACTURING CO., LTD.Inventors: Shoichiro Suzuki, Shinichi Yamaguchi
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Publication number: 20140049876Abstract: Provided is a laminated ceramic capacitor that can suppress the decrease in insulation resistance after a moisture-resistance loading test. It contains ceramic layers which include: main-phase grains that have a perovskite-type compound containing Ba and Ti and optionally containing Ca, Sr, Zr, and Hf; and secondary-phase grains that have an average grain size of 100 nm or more and have a Si content of 50 mol % or more per grain, the average grain boundary number, represented by (Average Thickness for Ceramic Layers 3)/(Average Grain Size for Main Phase Grains)?1, is greater than 0 and 3.0 or less, and the average grain size for the secondary-phase grains is 1/4 or more of the average thickness for the ceramic layers 3.Type: ApplicationFiled: October 28, 2013Publication date: February 20, 2014Applicant: MURATA MANUFACTURING CO., LTD.Inventor: Takayuki Yao
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Patent number: 8654506Abstract: A laminate type semiconductor ceramic capacitor with a varistor function is achieved which allows for an improvement in product yield while ensuring such insulation performance that can withstand practical use, and is suitable for mass production with a favorable ESD withstanding voltage. The semiconductor ceramic forming the semiconductor ceramic layers has a compounding molar ratio m between the Sr site and the Ti site of 0.990?m<1.000, has a donor element such as La present as a solid solution in crystal grains, has an acceptor element such as Mn present in a grain boundary layer in the range of 0.5 mol or less (preferably 0.3 mol to 0.5 mol) with respect to 100 mol of the Ti element, and has the crystal grains with an average grain size of 1.5 ?m or less.Type: GrantFiled: July 20, 2011Date of Patent: February 18, 2014Assignee: Murata Manufacturing Co., Ltd.Inventor: Mitsutoshi Kawamoto
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Publication number: 20140043725Abstract: A method for manufacturing a laminated ceramic capacitor by firing a laminated body which includes dielectric ceramic layers containing a dielectric ceramic raw material powder and internal electrodes. The firing is carried out in accordance with a temperature profile in which the average rate of temperature rise is 40° C./second or more from room temperature to a maximum temperature. The dielectric ceramic raw material powder contains a BaTiO3 system as its main constituent, and contains R (R is Sc, etc.), M (M is Mn, etc.), and Mg as accessory constituents, in which, when the total amount of the accessory constituents contained is denoted by D parts by mol with respect to 100 parts by mol of the main constituent, an the specific surface area of the main constituent is denoted by E m2/g, then D/E is 0.2 to 0.8.Type: ApplicationFiled: October 25, 2013Publication date: February 13, 2014Applicant: MURATA MANUFACTURING CO., LTD.Inventors: Makoto Matsuda, Tomoyuki Nakamura
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Publication number: 20140016243Abstract: Provided in a dielectric ceramic having flat capacitance characteristics and a high dielectric constant, and a multilayer ceramic electronic component (such as a multilayer ceramic capacitor) in which the dielectric ceramic is used. A multilayer ceramic capacitor includes a multilayer body having a plurality of dielectric ceramic layers and a plurality of internal electrodes, and external electrodes formed on the multilayer body. The composition of the multilayer body includes any of a bismuth layered compound containing Sr, Bi and Ti, a bismuth layered compound containing Sr, Bi and Nb, and a bismuth layered compound containing Ca, Bi and Ti as a primary ingredient, Bi and at least one of Cu, Ba, Zn and Li, and satisfies the conditions that if the Ti content is 400 molar parts or the Nb content is 200 molar parts, then (Bi content-Ti content) or (Bi content-Nb content) is equal to or greater than 1 molar part and less than 7.Type: ApplicationFiled: September 19, 2013Publication date: January 16, 2014Applicant: MURATA MANUFACTURING CO., LTD.Inventors: Shoichiro Suzuki, Koichi Banno, Taisuke Kanzaki, Akihiro Shiota
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Publication number: 20140009868Abstract: A dielectric ceramic that contains, as its main constituent, main-phase grains including a perovskite-type compound containing Ba, Ca, and Ti; first heterogeneous-phase grains containing Ca, a rare-earth element, and Si; and second heterogeneous-phase grains containing no Ca and containing the rare-earth element and Si. The second heterogeneous-phase grains are present in the dielectric ceramic in a ratio of 0.05 or less (including 0) of the number of the second heterogeneous-phase grains to the total of the first heterogeneous-phase grains and the second heterogeneous-phase grains. In the first heterogeneous-phase grains, the content of Ca is preferably 8% or more in terms of molar ratio with respect to the total content of Ca, the rare-earth element, and Si.Type: ApplicationFiled: September 10, 2013Publication date: January 9, 2014Applicant: MURATA MANUFACTURING CO., LTDInventor: Shinichi Yamaguchi
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Publication number: 20140002955Abstract: A dielectric ceramic composition is represented by BaTiO3+aRe2O3+bMnO+cV2O5+dMoO3+eCuO+fB2O3+gLi2O+xSrO+yCaO (wherein Re represents one or more elements selected from among Eu, Gd, Dy, Ho, Er, Yb, and Y; and a-h each represents the mole number of each component with respect to 100 mol of the main component that is composed of BaTiO3). When the molar ratio of (Ba+Sr+Ca)/Ti contained in the dielectric ceramic composition is represented by m, the 0.10?a?0.50, 0.20?b?0.80, 0?c?0.12, 0?d?0.07, 0.04?c+d?0.12, 0?e?1.00, 0.50?f?2.00, 0.6?(100(m?1)+2g)/2f?1.3, and 0.5?100(m?1)/2g?5.1 are satisfied.Type: ApplicationFiled: September 26, 2011Publication date: January 2, 2014Applicant: TAIYO YUDEN CO., LTD.Inventor: Shinsuke Takeoka
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Patent number: 8592334Abstract: A dielectric ceramic composition comprises, a main component including barium titanate, a first subcomponent including MgO, a second subcomponent including sintering aids of SiO2 compound, a third subcomponent including at least one of V2O5, Nb2O5 and WO3, a fourth A subcomponent including RA oxide (note that, RA is at least one selected from Tb, Gd and Dy), a fourth B subcomponent including RB oxide (note that, RB is at least one selected from Ho, Y and Yb), and a fifth subcomponent including MnO or Cr2O3.Type: GrantFiled: March 30, 2009Date of Patent: November 26, 2013Assignee: TDK CorporationInventors: Kosuke Takano, Mari Miyauchi, Nobuto Morigasaki, Hideaki Seki, Makoto Maeda, Takahiro Yamada
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Patent number: 8592335Abstract: A dielectric ceramic composition contains a barium titanate based composite oxide as its main constituent, and contains a first accessory constituent including at least Al and a second accessory constituent including one or more elements selected from among Fe, Co, Ni, Cu, and Zn, wherein the content of the Al is 0.02 to 6 parts by mol with respect to 100 parts by mol of the main constituent, and the content ratio of the second accessory constituent to the Al is 0.01 to 0.4 in terms of mols. Dielectric layers are formed from a sintered body of the dielectric ceramic composition. The addition of various types of accessory elements such as rare-earth elements is possible, if necessary. This invention achieves a dielectric ceramic composition which is capable of ensuring favorable DC bias characteristics while ensuring high reliability, and a laminated ceramic capacitor using the dielectric ceramic composition.Type: GrantFiled: February 21, 2012Date of Patent: November 26, 2013Assignee: Murata Manufacturing Co., Ltd.Inventors: Takafumi Okamoto, Noriyuki Inoue, Hitoshi Nishimura
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Patent number: 8582277Abstract: A multilayer ceramic electronic component comprising an element body in which a dielectric layer and an internal electrode layer are stacked. The dielectric layer is constituted from a dielectric ceramic composition including; a compound having a perovskite structure expressed by a formula of ABO3 (A is at least one selected from Ba, Ca, and Sr; B is at least one selected from Ti, Zr, and Hf); an oxide of Mg; an oxide of rare earth elements including Sc and Y; and an oxide including Si. The dielectric ceramic composition comprises a plurality of dielectric particles and a grain boundary present in between the dielectric particles. In the grain boundary, when content ratios of Mg and Si are set to D(Mg) and D(Si) respectively, D(Mg) is 0.2 to 1.8 wt % in terms of MgO, and D(Si) is 0.4 to 8.0 wt % in terms of SiO2.Type: GrantFiled: November 21, 2011Date of Patent: November 12, 2013Assignee: TDK CorporationInventors: Hirobumi Tanaka, Makoto Endo, Satoko Ueda, Daisuke Ueda, Shogo Murosawa, Daisuke Yoshida, Kenta Ono, Minoru Ogasawara, Tatsuya Kikuchi
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Patent number: 8576537Abstract: A ceramic multilayer surface-mount capacitor with inherent crack mitigation void patterning to channel flex cracks into a safe zone, thereby negating any electrical failures.Type: GrantFiled: October 17, 2008Date of Patent: November 5, 2013Assignee: Kemet Electronics CorporationInventor: John D. Prymak
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Publication number: 20130286541Abstract: A laminated semiconductor ceramic capacitor with a varistor function includes a component body having a plurality of semiconductor ceramic layers formed of a SrTiO3-based grain boundary insulated semiconductor ceramic and a plurality of internal electrode layers predominantly composed of Ni, and external electrodes on both ends of the component body. The external electrodes are electrically connected to the internal electrode layers. A thickness of each of the semiconductor ceramic layers, excluding the outermost semiconductor ceramic layers, is 20 ?m or more, and an average grain diameter of crystal grains in the semiconductor ceramic layers is 1.5 ?m or less. When a central part or the vicinity of the central part in a laminating direction of the semiconductor ceramic layer is analyzed by a WDX method, a ratio x/y of the intensity x of the Ni element to the intensity y of the Ti element is 0.06 or less.Type: ApplicationFiled: June 28, 2013Publication date: October 31, 2013Inventor: Mitsutosho Kawamoto
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Patent number: 8561271Abstract: A method for making a capacitor having improved capacitance efficiency which results from increasing the effective area of an electrode surface is disclosed. Specifically, an improved “three-dimensional” capacitor may be constructed with electrode layers having three-dimensional aspects at the point of interface with a dielectric such that portions of the electrode extend into the dielectric layer. Advantageously, embodiments of a three-dimensional capacitor drastically reduce the space footprint that is required in a circuit to accommodate the capacitor, when compared to current capacitor designs. Increased capacitance density may be realized without using high k (high constant) dielectric materials, additional “electrode-dielectric-electrode” arrangements in an ever increasing stack, or serially stringing together multiple capacitors.Type: GrantFiled: December 15, 2010Date of Patent: October 22, 2013Inventors: Liang Chai, Alan Rae, James M Wison
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Publication number: 20130250482Abstract: A dielectric ceramic material comprises a primary component of barium titanate (BaTiO3) and at least one additive component. The additive component has a mole percentage from 1% to 50% and is selected from the group consisting of lithium tantalite (LiTaO3), barium cerate (BaCeO3), sodium metaniobate (NaNbO3) and the combinations thereof.Type: ApplicationFiled: August 8, 2012Publication date: September 26, 2013Applicant: HOLY STONE ENTERPRISE CO., LTD.Inventors: Sea-Fue Wang, Yuan-Cheng Lai, Jian-Hua Li, Ming-Hua Chen